FR2060622A5 - Pure esters recovery - from a crude esterification mixture - Google Patents
Pure esters recovery - from a crude esterification mixtureInfo
- Publication number
- FR2060622A5 FR2060622A5 FR7029864A FR7029864A FR2060622A5 FR 2060622 A5 FR2060622 A5 FR 2060622A5 FR 7029864 A FR7029864 A FR 7029864A FR 7029864 A FR7029864 A FR 7029864A FR 2060622 A5 FR2060622 A5 FR 2060622A5
- Authority
- FR
- France
- Prior art keywords
- water
- mixt
- cpds
- esterification mixture
- esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/56—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/60—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Abstract
The esters are those of 4-12C aliphatic or aromatic dicarboxylic acids or their anhydrides with 4-12C alcohols, e.g. plasticisers. The esters are obtd. using as catalyst Sn, Ti or Zr organic cpds. or cpds. of alkaline substances and amphoteric metal cpds. After reaction the mixt. is neutralised and steam distilled. The ester is purified by (a) cooling the reacted mixt. below the b.pt. of water at ambient press., (b) adding >=0.5 wt.% of water based on the ester in the mixt. (pref. 0.8 to 2 wt.% water is added at 95 to 100 degrees), (c) stirring the mixt. intensively for 15 mins. at a temp. below the b.pt. of water, (d) removing the added water by vacuum distillation.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19691945359 DE1945359B2 (en) | 1969-09-08 | 1969-09-08 | METHOD OF OBTAINING ESTERS |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2060622A5 true FR2060622A5 (en) | 1971-06-18 |
Family
ID=5744854
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7029864A Expired FR2060622A5 (en) | 1969-09-08 | 1970-08-13 | Pure esters recovery - from a crude esterification mixture |
Country Status (3)
Country | Link |
---|---|
JP (1) | JPS5017043B1 (en) |
DE (1) | DE1945359B2 (en) |
FR (1) | FR2060622A5 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10072133B2 (en) | 2014-01-09 | 2018-09-11 | Basf Se | Plasticizer composition containing furan derivatives and 1,2-cyclohexanedicarboxylic ester |
US10273345B2 (en) | 2014-09-04 | 2019-04-30 | Basf Se | Plasticizer composition which contains a polymer dicarboxylic acid ester |
US10287415B2 (en) | 2014-10-09 | 2019-05-14 | Basf Se | Plasticizer composition which comprises cycloalkyl esters of saturated dicarboxylic acids and terephthalic esters |
US10329402B2 (en) | 2014-10-09 | 2019-06-25 | Basf Se | Plasticizer composition which comprises cycloalkyl esters of saturated dicarboxylic acids and 1,2-cyclohexanedicarboxylic esters |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4007218A (en) * | 1973-12-07 | 1977-02-08 | Standard Oil Company (Indiana) | Esterification reaction |
DE2604751A1 (en) * | 1976-02-06 | 1977-08-18 | Lentia Gmbh | PROCESS FOR CLEANING RAW, HIGH-HIGH-HIGH-HIGH CHARACTERISTICS |
DE19721347B9 (en) | 1997-05-22 | 2005-09-29 | Celanese Chemicals Europe Gmbh | Process for the preparation of ester plasticizers |
DE10236279A1 (en) | 2002-08-08 | 2004-02-19 | Basf Ag | Removing esterification catalyst from crude plasticizer ester, e.g. di-isononyl phthalate, involves hydrolysis with aqueous alkali, addition of multi-valent metal salt, e.g. aluminum sulfate, and phase separation under gravity |
US7291748B2 (en) | 2005-07-28 | 2007-11-06 | Basf Corporation | C10/C7 ester mixtures based on 2-propylheptanol |
US8729292B2 (en) | 2008-12-16 | 2014-05-20 | Basf Se | Method for regeneration of raw ester |
ES2464516T3 (en) | 2009-11-05 | 2014-06-03 | Basf Se | Adhesives and sealants containing 2-propylheptanol-based ester |
US9365715B2 (en) | 2010-12-23 | 2016-06-14 | Styrolution Europe Gmbh | Thermoplastic elastomer composition and method for the production thereof |
DE102013015289A1 (en) | 2013-09-14 | 2015-03-19 | Oxea Gmbh | Process for the post-treatment of polyol esters |
CA2932240A1 (en) | 2013-12-06 | 2015-06-11 | Basf Se | Softener composition which contains tetrahydrofuran derivatives and 1,2-cyclohexane dicarboxylic acid esters |
DE102015207291A1 (en) | 2014-04-24 | 2016-03-10 | Basf Se | Plasticizer composition containing furan derivatives and 1,2-cyclohexanedicarboxylic acid ester |
TW201609628A (en) | 2014-07-08 | 2016-03-16 | 巴斯夫歐洲公司 | Plasticizer composition which comprises diesters of aliphatic dicarboxylic acids and dialkylesters of terephthalic acid |
TW201605945A (en) | 2014-07-08 | 2016-02-16 | 巴斯夫歐洲公司 | Molding compounds containing esters of dicarboxylic acids and esters of 1,2-cyclohexanedicarboxylic acid |
WO2016016285A1 (en) | 2014-08-01 | 2016-02-04 | Basf Se | Process for workup of a crude ester comprising esterification catalyst hydrolysis product in suspended particulate form |
US10224485B2 (en) | 2014-08-18 | 2019-03-05 | Basf Se | Process for preparing a crystalline organic semiconductor material |
TWI706979B (en) | 2014-08-19 | 2020-10-11 | 德商巴斯夫歐洲公司 | Plasticizer composition comprising polymeric dicarboxylic esters |
TR201819358T4 (en) | 2015-01-30 | 2019-01-21 | Basf Se | Softener composition containing polymer dicarboxylic acid ester and terephthalic acid dialkyl ester. |
JP2018516914A (en) | 2015-05-29 | 2018-06-28 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | Method for producing cyclic ester |
PL3356456T3 (en) | 2015-09-30 | 2019-11-29 | Basf Se | Plasticizer composition containing polymeric dicarboxylic acid esters and terephthalic acid dialkyl esters |
WO2017055431A1 (en) | 2015-09-30 | 2017-04-06 | Basf Se | Plasticizer composition containing polymeric dicarboxylic acid esters and dicarboxylic acid diesters |
PL3356457T5 (en) | 2015-09-30 | 2023-04-24 | Basf Se | Plasticizer composition containing polymeric dicarboxylic acid esters and 1,2-cyclohexane dicarboxylic acid esters |
EP3178908A1 (en) | 2015-12-11 | 2017-06-14 | Basf Se | The use of 2,5-furandicarboxylic acid esters as lubricants |
WO2017125458A1 (en) | 2016-01-20 | 2017-07-27 | Basf Se | Plasticiser composition containing aliphatic dicarboxylic acid esters and diesters selected from 1,2-cyclohexane dicarboxylic acid esters and terephthalic acid esters |
CN109196034B (en) | 2016-03-23 | 2021-06-08 | 巴斯夫欧洲公司 | Polymer compositions comprising cycloalkylalkyl dicarboxylic diesters as plasticizers |
WO2018024597A1 (en) | 2016-08-01 | 2018-02-08 | Basf Se | Plasticizer composition |
WO2018024591A1 (en) | 2016-08-01 | 2018-02-08 | Basf Se | Plasticizer composition |
EP3491053A1 (en) | 2016-08-01 | 2019-06-05 | Basf Se | Plasticizer composition |
RU2019105682A (en) | 2016-08-01 | 2020-09-01 | Басф Се | PLASTIFIER'S COMPOSITION |
WO2019185409A1 (en) | 2018-03-29 | 2019-10-03 | Basf Se | Pvc composition containing at least one plasticizer having at least one carboxylic acid ester group, and containing at least one carbodiimide compound |
EP3747860B1 (en) | 2019-06-04 | 2023-07-26 | Basf Se | Novel cyclohexanone based plasticisers |
WO2024133359A1 (en) | 2022-12-21 | 2024-06-27 | Basf Se | Plasticizer |
WO2024133358A1 (en) | 2022-12-21 | 2024-06-27 | Basf Se | Plasticizer compound |
WO2024153687A1 (en) | 2023-01-19 | 2024-07-25 | Basf Se | Method for producing 1,2-cyclohexane dicarboxylic acid dialkyl esters |
-
1969
- 1969-09-08 DE DE19691945359 patent/DE1945359B2/en active Granted
-
1970
- 1970-08-13 FR FR7029864A patent/FR2060622A5/en not_active Expired
- 1970-09-07 JP JP7784470A patent/JPS5017043B1/ja active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10072133B2 (en) | 2014-01-09 | 2018-09-11 | Basf Se | Plasticizer composition containing furan derivatives and 1,2-cyclohexanedicarboxylic ester |
US10273345B2 (en) | 2014-09-04 | 2019-04-30 | Basf Se | Plasticizer composition which contains a polymer dicarboxylic acid ester |
US10287415B2 (en) | 2014-10-09 | 2019-05-14 | Basf Se | Plasticizer composition which comprises cycloalkyl esters of saturated dicarboxylic acids and terephthalic esters |
US10329402B2 (en) | 2014-10-09 | 2019-06-25 | Basf Se | Plasticizer composition which comprises cycloalkyl esters of saturated dicarboxylic acids and 1,2-cyclohexanedicarboxylic esters |
Also Published As
Publication number | Publication date |
---|---|
DE1945359B2 (en) | 1973-05-10 |
DE1945359C3 (en) | 1973-12-13 |
DE1945359A1 (en) | 1971-03-11 |
JPS5017043B1 (en) | 1975-06-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |