KR850006687A - 폴리우레탄 조성물용 촉매 시스템 - Google Patents
폴리우레탄 조성물용 촉매 시스템 Download PDFInfo
- Publication number
- KR850006687A KR850006687A KR1019850001482A KR850001482A KR850006687A KR 850006687 A KR850006687 A KR 850006687A KR 1019850001482 A KR1019850001482 A KR 1019850001482A KR 850001482 A KR850001482 A KR 850001482A KR 850006687 A KR850006687 A KR 850006687A
- Authority
- KR
- South Korea
- Prior art keywords
- composition
- component
- aliphatic
- iii
- polyol
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
- C08G2/06—Catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
- C08G18/163—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
- C08G18/7628—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2120/00—Compositions for reaction injection moulding processes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (18)
- 지방족 히드록실-함유 화합물과 차폐된 지방족 2차 또는 3차이소시아네이트기 함유 화합물 간의 반응을 촉매하며, 하기 (i), (ii) 및 (iii)으로 구성되는 촉매 조성물. (i) 1,8-디아자비시클로(5,4,0)-운데센-7 또는 그외염; (ii) 유기 주석 화합물; 및, 임의적으로 (iii) 유기 납 화합물[(i):(ii):(iii)의 중량비는 각각 약 0.5:1:0 내지 약 2:1:3이다.]
- 제1항에 있어서, 성분(i)이 페놀산염인 조성물.
- 제1항에 있어서, 성분(ii)가 디카르복실산디알킬주석인 조성물.
- 제1항에 있어서, 상기 디카르복실산디알킬주석이 다음과 같은 구조를 갖는 조성물.상기식에서, R은 C1-C8알킬이고, R'은 C1-C18알킬이다.
- 제4항에 있어서, 상기 디카르복실산디알킬주석이 디라우릴산 디메틸주석 및 디라우릴산디부틸주석으로 부터 선택되는 조성물.
- 제1항에 있어서, 성분(iii)이 나프텐산납인 조성물.
- 하기 (a),(b) 및 (c)로 구성되는 경화성 조성물, (a) 지방족 히드록실 함유 화합물; (b) 차폐된 지방족 2차 또는 3차 이소시아네이트기를 갖는 화합물; 및 (c) 하기 (i),(ii) 및 (iii)으로 구성되는, 촉매적 유효량의 촉매조성물. (i) 1,8-디아자비시클로(5,4,0)-운덴센-7 또는 그의 염; (ii) 유기 주석 화합물; 및, 임의적으로, (iii) 유기 납화합물, [(i):(ii):(iii)의 중량비는, 각각 약 0.5:1:0 내지 약 2:1:3이다.]
- 제7항에 있어서, 성분(a)가 중합체 폴리올로 구성되는 조성물.
- 제8항에 있어서, 성분(a)가 지방족 폴리올 또는 지방족폴리아민 폴리올과 결합된 중합체 폴리올로 구성되는 조성물.
- 제8항에 있어서, 성분(a)가 폴리에테르 폴리올로 구성되는 조성물.
- 제8항에 있어서, 성분(a)가 지방족 폴리올과 결합된 폴리에테르 폴리올로 구성되는 조성물.
- 제8항에 있어서, 성분(a)가 하기 구조를 갖는 조성물.상기식에서, R1과 R2는 각기 수소 또는 C1-C4알킬기이다.
- 제8항에 있어서, 성분(a)가 α,α',α'-테트라메틸-m-크실틸 디이소시아네이트인 조성물.
- 반응 혼합물 내에서 지방족 히드록실-함유 화합물과 차폐된 지방족 2차 및/또는 3차 이소시아네이트 화합물과의 반응에 대한 촉매 공정에 있어서, 제1항의 촉매 조성물 약 0.05-약 5중량%를 상기 반응 혼합물 내에 첨가하는 것으로 구성되는 방법.
- 제14항에 있어서, 상기 반응 혼합물이 하기 구조의 이소시아네이트 화합물로 구성되는 방법.상기식에서 R1과 R2는 각기 수소 또는 C1-C4알킬이다.
- 제15항에 있어서, 상기 이소시아네이트 화합물이 α,α,α',α'-테트라메틸-m-크실틸 디이소시아네이트인 방법.
- 제14항에 있어서, 상기 지방족 히드록실-함유화합물이 중합체폴리올 또는 폴리에테르 폴리올리거나, 또는 지방족 폴리올 또는 지방족 폴리아민 폴리올과의 결합상태의 것인 방법.
- 제14항에 있어서, 상기 촉매 조성물의 성분(i)은 1,8-디아자비시클로(5,4,0)-운데센-7이고; 성분(ii)는 디카르복실산 디알킬주석이며; 성분(iii)이 존재할 경우 이것은 나프텐산납인 방법.※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US588,015 | 1984-03-09 | ||
US06/588,015 US4547478A (en) | 1984-03-09 | 1984-03-09 | Catalyst systems for polyurethane compositions |
US588015 | 1984-03-09 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR850006687A true KR850006687A (ko) | 1985-10-16 |
KR930004364B1 KR930004364B1 (ko) | 1993-05-26 |
Family
ID=24352112
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019850001482A KR930004364B1 (ko) | 1984-03-09 | 1985-03-08 | 폴리우레탄 조성물용 촉매시스템 |
Country Status (8)
Country | Link |
---|---|
US (2) | US4547478A (ko) |
EP (1) | EP0154180B1 (ko) |
JP (1) | JPS60190411A (ko) |
KR (1) | KR930004364B1 (ko) |
AT (1) | ATE88199T1 (ko) |
CA (1) | CA1262595A (ko) |
DE (1) | DE3587254T2 (ko) |
ES (1) | ES8606434A1 (ko) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3326566A1 (de) * | 1983-07-22 | 1985-01-31 | Bayer Ag, 5090 Leverkusen | Reversibel blockierte katalysatoren enthaltende polyisocyanat-zubereitungen, ein verfahren zu ihrer herstellung, ihre verwendung zur herstellung von polyurethankunststoffen, sowie anlagerungsprodukte von sulfonylisocyanaten an katalysatoren mit zinn (ii)- bzw. zinn (iv)-carboxylat-struktur |
US4601995A (en) * | 1985-11-04 | 1986-07-22 | Ashland Oil, Inc. | Organo tin catalysts modified with bicyclic amide acetals |
JPS62132913A (ja) * | 1985-12-05 | 1987-06-16 | Inoue Mtp Co Ltd | 光で変色しない無色透明なウレタン樹脂の製造方法 |
US4663302A (en) * | 1986-10-01 | 1987-05-05 | Ashland Oil | Bicyclic amide acetal modified catalysts for polyurethane polymer formation |
JPS6416619A (en) * | 1987-07-11 | 1989-01-20 | Nippon Polyurethane Kogyo Kk | Manufacture of polyurethane composite |
US5536529A (en) * | 1989-05-11 | 1996-07-16 | Borden, Inc. | Ultraviolet radiation-curable coatings for optical fibers and optical fibers coated therewith |
CA1321671C (en) * | 1989-05-11 | 1993-08-24 | Paul J. Shustack | Ultraviolet radiation-curable coatings for optical fibers and optical fibers coated therewith |
US5352712A (en) * | 1989-05-11 | 1994-10-04 | Borden, Inc. | Ultraviolet radiation-curable coatings for optical fibers |
US5070110A (en) * | 1989-08-25 | 1991-12-03 | The Dow Chemical Company | Blends of alkylene glycols and relatively high equivalent weight active hydrogen compounds containing multipurpose additives |
US5057543A (en) * | 1989-08-25 | 1991-10-15 | The Dow Chemical Company | Blends of alkylene glycols and relatively high equivalent weight active hydrogen compounds containing additives |
US4981877A (en) * | 1989-08-25 | 1991-01-01 | The Dow Chemical Company | Blends of alkylene glycols and relatively high equivalent weight active hydrogen compounds containing multipurpose additives |
US5171818A (en) * | 1990-03-23 | 1992-12-15 | Bruce Wilson | Sprayable aliphatic polyurea-polyurethane coating compositions and methods |
US5212209A (en) * | 1991-11-18 | 1993-05-18 | The Dow Chemical Company | Compatibilized internal mold release composition for preparations of foamed and fiber-reinforced polymeric articles |
WO1995008579A1 (en) * | 1993-09-22 | 1995-03-30 | Ashland Oil, Inc. | Polyurethane reaction system having a blocked catalyst combination |
US5502150A (en) * | 1994-06-29 | 1996-03-26 | Bayer Corporation | Linear HDI urethane prepolymers for rim application |
US5965685A (en) * | 1998-01-14 | 1999-10-12 | Reichhold Chemicals, Inc. | Rapid curing aliphatic hot melt adhesive |
US20020068808A1 (en) * | 2000-10-13 | 2002-06-06 | Hiroyuki Kometani | Catalyst for production of a two component polyurethane sealant |
US20030212236A1 (en) * | 2001-05-01 | 2003-11-13 | Luigi Pellacani | Process for producing polyurethane elastomer |
US20030044690A1 (en) * | 2001-06-27 | 2003-03-06 | Imation Corp. | Holographic photopolymer data recording media, method of manufacture and method of holographically reading, recording and storing data |
US6743552B2 (en) * | 2001-08-07 | 2004-06-01 | Inphase Technologies, Inc. | Process and composition for rapid mass production of holographic recording article |
WO2004000905A1 (en) * | 2002-06-21 | 2003-12-31 | Recticel | Micro-cellular or non-cellular light-stable polyurethane material and method for the production thereof |
US8258198B2 (en) * | 2004-05-28 | 2012-09-04 | Air Products And Chemicals, Inc. | Fast demold/extended cream time polyurethane formulations |
US20060160977A1 (en) * | 2005-01-14 | 2006-07-20 | Jung-Shun Ou | Prescription for preparation of non-yellowing polyurethane foam |
US20060266472A1 (en) * | 2005-05-06 | 2006-11-30 | Kipp Michael D | Vacuum bagging methods and systems |
US20080008836A1 (en) * | 2006-05-01 | 2008-01-10 | Kipp Michael D | Method for extending the useful life of mold type tooling |
US20080105997A1 (en) * | 2006-10-17 | 2008-05-08 | Ridges Michael D | Method for enhancing the sealing potential of formable, disposable tooling materials |
US20080106007A1 (en) * | 2006-10-17 | 2008-05-08 | Kipp Michael D | Resin infusion process utilizing a reusable vacuum bag |
WO2008070110A1 (en) * | 2006-12-04 | 2008-06-12 | American Consulting Technology & Research, Inc. | Shrinkable film barrier for mandrel tooling members |
WO2010019802A1 (en) | 2008-08-15 | 2010-02-18 | Gesturetek, Inc. | Enhanced multi-touch detection |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL6610758A (ko) * | 1965-08-09 | 1967-02-10 | ||
DE1720633A1 (de) * | 1967-03-15 | 1971-07-01 | Bayer Ag | Verfahren zur Herstellung von Polyurethanen |
LU74540A1 (ko) * | 1976-03-12 | 1977-09-27 | ||
US4078257A (en) * | 1976-08-23 | 1978-03-07 | Hewlett-Packard Company | Calculator apparatus with electronically alterable key symbols |
DE2737671A1 (de) * | 1977-08-20 | 1979-02-22 | Bayer Ag | Verfahren zur herstellung von schaumstoff-formkoerpern |
US4293658A (en) * | 1980-05-12 | 1981-10-06 | Abbott Laboratories | Process for rigid foams of improved friability |
-
1984
- 1984-03-09 US US06/588,015 patent/US4547478A/en not_active Expired - Lifetime
- 1984-12-19 JP JP59266505A patent/JPS60190411A/ja active Granted
-
1985
- 1985-02-06 DE DE85101222T patent/DE3587254T2/de not_active Expired - Fee Related
- 1985-02-06 AT AT85101222T patent/ATE88199T1/de active
- 1985-02-06 EP EP85101222A patent/EP0154180B1/en not_active Expired - Lifetime
- 1985-03-07 CA CA000475898A patent/CA1262595A/en not_active Expired
- 1985-03-08 ES ES541095A patent/ES8606434A1/es not_active Expired
- 1985-03-08 KR KR1019850001482A patent/KR930004364B1/ko not_active IP Right Cessation
- 1985-07-22 US US06/757,710 patent/US4598103A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE3587254D1 (de) | 1993-05-19 |
ATE88199T1 (de) | 1993-04-15 |
US4547478A (en) | 1985-10-15 |
ES541095A0 (es) | 1986-04-16 |
EP0154180B1 (en) | 1993-04-14 |
EP0154180A2 (en) | 1985-09-11 |
DE3587254T2 (de) | 1993-11-25 |
JPH0562610B2 (ko) | 1993-09-08 |
KR930004364B1 (ko) | 1993-05-26 |
CA1262595A (en) | 1989-10-31 |
EP0154180A3 (en) | 1986-10-01 |
US4598103A (en) | 1986-07-01 |
ES8606434A1 (es) | 1986-04-16 |
JPS60190411A (ja) | 1985-09-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR850006687A (ko) | 폴리우레탄 조성물용 촉매 시스템 | |
KR950703590A (ko) | 차단된 이소시아네이트의 저온 경화용 촉매(Catalysts for low temperature cure of blocked isocyanates) | |
KR930013052A (ko) | 고온 내성을 가진 이성분 무프라이머 우레탄-이소시안우레이트 접착제 조성물 | |
DE1134377B (de) | Verfahren zur Beschleunigung der Reaktion zwischen einer wenigstens einen Isocyanat-oder Isothiocyanatrest enthaltenden organischen Verbindung und einer reaktionsfaehigen Wasserstoff enthaltenden organischen Verbindung | |
GB1352810A (en) | Polyurethane-based adhesives | |
DE2138403A1 (de) | Katalysator für die Herstellung von Polyurethan | |
JPS5589328A (en) | Isocyanate composition | |
ES8305796A1 (es) | Procedimiento para mejorar la estabilidad en el tiempo de compuestos polihidroxilicos. | |
KR860003055A (ko) | 폴리이소시아네이트의 촉매 시클로트리머화 반응에 의한 폴리이소시아누레이트-폴리이소시아네이트의 제조방법 | |
KR950025049A (ko) | 폴리우레탄 제조용 히드록시-작용성 트리아민 촉매 조성물 | |
ES454068A1 (es) | Procedimiento para revestir por recubrimiento sustratos ar- bitrarios. | |
US4211804A (en) | Polyisocyanate compositions | |
KR880009103A (ko) | 하전성기를 가진 개질 에폭시수지 함유 전착도료 조성물 | |
ATE12133T1 (de) | Verwendung von ein- oder mehrkomponentensystemen als bzw. zur herstellung von verbundmassen fuer glaskonstruktionen. | |
GB1312589A (en) | Liquid castable elastomers | |
KR930016458A (ko) | 폴리우레탄 포움의 제조를 위한 3-퀴누클리디놀 촉매 조성물 | |
KR910006355A (ko) | 신규한 발포용 화학약품 | |
EP0045090B1 (en) | Urethane catalysis | |
GB1311095A (en) | Alkylene oxide orthotolylene diamine compositions | |
ES405585A1 (es) | Procedimiento para preparar composiciones adhesivas. | |
CA1095496A (en) | Organotin catalyst system for isocyanate reactions | |
KR910007976A (ko) | 폴리우레탄계에 유용한 중합체성 이유기주석촉매 | |
KR920012174A (ko) | 폴리우레탄을 제조하기 위한 히드록실-함유 유기 주석 촉매 | |
KR960701913A (ko) | 산성 첨가제 함유 반응 사출 성형 (RIM) 시스템 사용을 위한 신규 촉매 패키지(Novel Catalyst Package for use in RIM Systems Containing Acidic Additives) | |
US3480656A (en) | N-tin carbamic acid derivatives |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
G160 | Decision to publish patent application | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
FPAY | Annual fee payment |
Payment date: 19970404 Year of fee payment: 5 |
|
LAPS | Lapse due to unpaid annual fee |