KR850005999A - 알킬 방향족 화합물의 합성방법 - Google Patents

알킬 방향족 화합물의 합성방법 Download PDF

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KR850005999A
KR850005999A KR1019850000716A KR850000716A KR850005999A KR 850005999 A KR850005999 A KR 850005999A KR 1019850000716 A KR1019850000716 A KR 1019850000716A KR 850000716 A KR850000716 A KR 850000716A KR 850005999 A KR850005999 A KR 850005999A
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compound
aluminosilicate
xylene
mixture
carbon monoxide
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KR1019850000716A
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KR890003781B1 (ko
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이마이 타모트수
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패트릭 제이. 링크
유오피 인코오포레이티드
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Publication of KR850005999A publication Critical patent/KR850005999A/ko
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Publication of KR890003781B1 publication Critical patent/KR890003781B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/06—Toluene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

알킬 방향족 화합물의 합성방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (17)

  1. 구리, 아연, 알루미늄 또는 크롬의 산화합믈과 알루미노실리케이트를 함유하는 촉매시스템 존재하에 반응조건을 사용하여 수소화 일산화탄소의 혼합물과 방향족화합물을 반응시켜 산출된 알킬방향족 화합물을 회수하는 것을 특징으로 하는 알킬방향족 화합물의 합성방법.
  2. 제1항에 있어서, 상기의 반응조건은 200℃내지 400℃의 온도와 1내지 100기압인 것을 특징으로 하는 방법.
  3. 제1항에 있어서, 상기의 알루미노 실리케이트는 결정질 형태 또는 무정형인 것을 특징으로 하는 방법.
  4. 제1항에 있어서, 상기의 산화합성물은 주기율표의 제Ⅰ족A그룹의 금속인 것을 특징으로 하는 방법.
  5. 제4항에 있어서, 상기의 금속은 오늘날 백금인 것을 특징으로 하는 방법.
  6. 제1항에 있어서, 상기의 산화합물은 붕소인 것을 특징으로 하는 방법.
  7. 제1항에 있어서, 상기의 알루미노실리케이트중의 알루미늄 대(對) 실리콘의 비는 2 : 1이상인 것을 특징으로 하는 방법.
  8. 제1항에 있어서, 상기의 촉매 시스템은 상기의 화합물과 상기의 알루미노실리케이트의 혼합물인 것을 특징으로 하는 방법.
  9. 제1항에 있어서, 상기의 촉매시스템은 상기의 합성물과 상기의 알루미노실리케이트의 균일한 혼합물인 것을 특징으로 하는 방법.
  10. 제1항에 있어서, 상기의 촉매시스탬은 상기의 합성물과 상기의 알루미노실리케이트의 분리된 층인 것을 특징으로 하는 방법.
  11. 제1항에 있어서, 상기의 반응은 수소와 일산화탄소의 몰비가 수소 : 일산화탄소=1 : 1내지 5 : 1인 것을 특징으로 하는 방법.
  12. 제1항에 있어서, 수소와 일산화탄소의 상기 혼합물은 일산화탄소 몰당 이산화탄소의 몰비가 0.01 : 1내지 1 : 1인 것을 특징으로 하는 방법.
  13. 제1항에 있어서, 상기의 합성물은 구리, 아연, 알루미늄의 산화물인 것을 특징으로 하는 방법.
  14. 제1항에 있어서, 상기의 합성물은 구리, 아연, 크롬 등의 산화물인 것을 특징으로 하는 방법.
  15. 제1항에 있어서, 상기의 방향족 화합물은 벤젠을 포함하며 상기의 알킬방향족 화합물은 톨루엔, 에틸벤젠,p-크실렌,m-크실렌,o-크실렌, 쿠멘을 함유하는 혼합물인 것을 특징으로 하는 방법.
  16. 제1항에 있어서, 상기의 방향족화합물은 톨루엔을 포함하여 상기의 알킬방향족 화합물은p-크실렌,m-크실렌,o-크실렌,p-에틸톨루엔,m-에틸톨루엔,o-에틸톨루엔,p-이소프로필톨루엔,m-이소프로필톨루엔,o-이소프로필톨루엔을 함유하는 혼합물인 것을 특징으로 하는 방법.
  17. 구리, 아연, 알루미늄 또는 크롬의 합성물과 알루미노실리케이트를 함유하는 것을 특징으로 하는알킬방향족화합물의 합성을 위한 촉매시스템
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019850000716A 1984-02-28 1985-02-05 알킬방향족 화합물의 합성방법 KR890003781B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US584,375 1984-02-28
US06/584,375 US4487984A (en) 1984-02-28 1984-02-28 Synthesis of alkylaromatic compounds

Publications (2)

Publication Number Publication Date
KR850005999A true KR850005999A (ko) 1985-09-28
KR890003781B1 KR890003781B1 (ko) 1989-10-04

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KR1019850000716A KR890003781B1 (ko) 1984-02-28 1985-02-05 알킬방향족 화합물의 합성방법

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Country Link
US (1) US4487984A (ko)
EP (1) EP0154753B1 (ko)
JP (1) JPS60215637A (ko)
KR (1) KR890003781B1 (ko)
AT (1) ATE43827T1 (ko)
AU (1) AU572265B2 (ko)
BR (1) BR8500822A (ko)
CA (1) CA1224455A (ko)
DE (1) DE3478596D1 (ko)
NO (1) NO160508C (ko)
NZ (1) NZ210832A (ko)
PH (1) PH21681A (ko)
ZA (1) ZA8541B (ko)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4487984A (en) * 1984-02-28 1984-12-11 Uop Inc. Synthesis of alkylaromatic compounds
US4665238A (en) * 1985-01-22 1987-05-12 Uop Inc. Process for the synthesis of alkylaromatic compounds
JP2562746B2 (ja) * 1991-04-26 1996-12-11 ブラウン アンド ウイリアムソン タバココーポレーション シガレットとその製造方法
US6459006B1 (en) 1999-05-14 2002-10-01 Exxonmobil Chemical Patents Inc. Selective methylation to para-xylene using fuel syngas
US6388156B1 (en) 1999-05-14 2002-05-14 Exxonmobil Chemical Patents Inc. Direct selective synthesis of para-xylene by reacting an aromatic compound with a methylating agent formed from CO, Co2 and H2
US6613708B1 (en) 1999-06-07 2003-09-02 Exxonmobil Chemical Patents Inc. Catalyst selectivation
US6664207B2 (en) * 2001-09-26 2003-12-16 Conocophillips Company Catalyst for converting carbon dioxide to oxygenates and processes therefor and therewith
ITMI20012707A1 (it) * 2001-12-20 2003-06-20 Enichem Spa Processo per l'alchilazione di composti aromatici
US20040097769A1 (en) * 2002-11-14 2004-05-20 Ou John D. Y. Para-xylene production process employing in-situ catalyst selectivation
US7919661B2 (en) * 2008-08-18 2011-04-05 Fina Technology, Inc. Method for production of styrene from toluene and syngas
JP5416861B2 (ja) † 2011-03-03 2014-02-12 日本水産株式会社 リパーゼによる高度不飽和脂肪酸含有油脂の製造方法
CN107970988B (zh) * 2016-10-24 2020-05-12 中国科学院大连化学物理研究所 一种用于合成芳烃的催化剂和其制备方法
CN107999118B (zh) * 2016-10-28 2021-08-06 中国石油化工股份有限公司 一种芳烃和合成气烷基化催化剂及其制备方法与应用
CN109776249B (zh) 2017-11-15 2021-05-25 中国科学院大连化学物理研究所 一种由合成气与芳烃直接制取对二甲苯的方法
CN109776250B (zh) * 2017-11-15 2021-05-11 中国科学院大连化学物理研究所 一种由合成气与甲苯直接制取对二甲苯的方法
CN109824470B (zh) * 2017-11-23 2022-01-04 中国石油天然气股份有限公司 一种合成气转化富苯汽油中的苯为甲苯、二甲苯的方法
DE112020004251T5 (de) * 2019-09-10 2022-05-19 Eneos Corporation Verfahren zur Herstellung von alkylaromatischen Kohlenwasserstoff, Verfahren zur Herstellung von aromatischen C8-Kohlenstoff und Verfahren zur Fixierung von Kohlendioxid
CN115106080B (zh) * 2021-03-23 2024-06-07 中国科学院大连化学物理研究所 一种催化剂及其制备方法和应用

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US3718704A (en) * 1971-01-08 1973-02-27 Ashland Oil Inc Methylation process
US4086289A (en) * 1977-07-05 1978-04-25 Sun Oil Company Of Pennsylvania Manufacture of xylenes
NZ199001A (en) * 1981-01-30 1984-02-03 Mobil Oil Corp Alkylation of aromatic compounds using catalyst with metal component and a zeolite
US4409412A (en) * 1981-01-30 1983-10-11 Mobil Oil Corporation Process for producing alkyl aromatic compounds
AU538731B2 (en) * 1981-05-07 1984-08-23 Mobil Oil Corp. Conversion of syngas to dimethyl ether
US4487984A (en) * 1984-02-28 1984-12-11 Uop Inc. Synthesis of alkylaromatic compounds

Also Published As

Publication number Publication date
EP0154753A2 (en) 1985-09-18
ATE43827T1 (de) 1989-06-15
DE3478596D1 (en) 1989-07-13
NO160508B (no) 1989-01-16
ZA8541B (en) 1986-04-30
NZ210832A (en) 1988-05-30
BR8500822A (pt) 1985-10-15
JPS60215637A (ja) 1985-10-29
AU572265B2 (en) 1988-05-05
AU3928285A (en) 1985-09-05
EP0154753B1 (en) 1989-06-07
CA1224455A (en) 1987-07-21
PH21681A (en) 1988-01-13
NO160508C (no) 1989-04-26
EP0154753A3 (en) 1986-01-02
NO850799L (no) 1985-08-29
US4487984A (en) 1984-12-11
KR890003781B1 (ko) 1989-10-04

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