KR860000234A - 에탄올 에틸렌으로 산화탈수소화하는 방법 - Google Patents

에탄올 에틸렌으로 산화탈수소화하는 방법 Download PDF

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Publication number
KR860000234A
KR860000234A KR1019850004582A KR850004582A KR860000234A KR 860000234 A KR860000234 A KR 860000234A KR 1019850004582 A KR1019850004582 A KR 1019850004582A KR 850004582 A KR850004582 A KR 850004582A KR 860000234 A KR860000234 A KR 860000234A
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KR
South Korea
Prior art keywords
ethanol
oxidative dehydrogenation
ethanol ethylene
ethylene
ethane
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KR1019850004582A
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English (en)
Inventor
허돈 멕케인 제이스
Original Assignee
에드워드 지. 그리어
유니온 카바이드 코포레이션
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 에드워드 지. 그리어, 유니온 카바이드 코포레이션 filed Critical 에드워드 지. 그리어
Publication of KR860000234A publication Critical patent/KR860000234A/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethylene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

에탄올 에틸렌으로 산화탈수소화하는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. 450℃미만의 저온에서 에탄올 가스상으로 발열성, 촉매성 산화탈수소함으로써 에탄올 에틸렌으로 전화시키는 방법에 있어서, 산화물형태로 다음을 함유하는 소성된 촉매를 사용하는 것을 특징으로 하는 개선된 방법.
    MoaVbNbcSbd
    상기에서, a는 0.5 내지 0.9; b는 0.1 내지 0.4; c는 0.001 내지 0.2; d는 0.001 내지 0.1이다.
  2. 제1항에 있어서, 에탄의 50% 전화율에 대한 에틸렌 선택성이 63%이상인 방법.
  3. 제1항에 있어서, 에탄의 50% 전화율에 대한 에틸렌 선택성이 75%이상인 방법.
    ※ 참고사항 : 최초출원내용에 의하여 공개하는 것임.
KR1019850004582A 1984-06-28 1985-06-27 에탄올 에틸렌으로 산화탈수소화하는 방법 KR860000234A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US625778 1984-06-28
US06/625,778 US4568790A (en) 1984-06-28 1984-06-28 Process for oxydehydrogenation of ethane to ethylene

Publications (1)

Publication Number Publication Date
KR860000234A true KR860000234A (ko) 1986-01-27

Family

ID=24507552

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019850004582A KR860000234A (ko) 1984-06-28 1985-06-27 에탄올 에틸렌으로 산화탈수소화하는 방법

Country Status (12)

Country Link
US (1) US4568790A (ko)
EP (1) EP0166438B1 (ko)
JP (1) JPS6118729A (ko)
KR (1) KR860000234A (ko)
AU (1) AU588814B2 (ko)
BR (1) BR8503105A (ko)
CA (1) CA1229352A (ko)
DE (1) DE3561010D1 (ko)
MX (1) MX167426B (ko)
NO (1) NO160917C (ko)
YU (1) YU108085A (ko)
ZA (1) ZA854884B (ko)

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US4769357A (en) * 1986-02-27 1988-09-06 Mitsubishi Petrochemical Company Limited Process for producing composite oxide catalyst
US5162578A (en) * 1987-06-12 1992-11-10 Union Carbide Chemicals & Plastics Technology Corporation Acetic acid from ethane, ethylene and oxygen
US4777319A (en) * 1987-07-01 1988-10-11 Northwestern University Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons
US5210293A (en) * 1989-07-05 1993-05-11 Bp Chemicals Limited Process and catalyst for the production of ethylene and acetic acid
US5260250A (en) * 1989-07-05 1993-11-09 Bp Chemicals Limited Catalyst for the production of ethylene and acetic acid
US5472925A (en) * 1991-08-08 1995-12-05 Mitsubishi Chemical Corporation Catalyst for the production of nitriles
US5527979A (en) * 1993-08-27 1996-06-18 Mobil Oil Corporation Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen
WO1996033152A1 (en) * 1995-04-17 1996-10-24 Mobil Oil Corporation Catalytic dehydrogenation of alkanes with simultaneous oxidation of hydrogen
US6013597A (en) * 1997-09-17 2000-01-11 Saudi Basic Industries Corporation Catalysts for the oxidation of ethane to acetic acid processes of making same and, processes of using same
US6030920A (en) 1997-12-24 2000-02-29 Saudi Basic Industries Corporation Catalysts for producing acetic acid from ethane oxidation, processes of making same and method of using same
GB9807142D0 (en) * 1998-04-02 1998-06-03 Bp Chem Int Ltd Catalyst and process utilising the catalyst
US6087297A (en) * 1998-06-29 2000-07-11 Saudi Basic Industries Corporation Catalysts for gas phase production of acetic acid from ethane, processes of making the same and methods of using same
US6028221A (en) 1998-06-29 2000-02-22 Saudi Basic Industries Corporation Catalyst systems for the one step gas phase production of acetic acid from ethylene and methods of making and using the same
US6514902B1 (en) * 1998-08-28 2003-02-04 Asahi Kasei Kogyo Kabushiki Kaisha Method for producing an oxide catalyst for use in producing acrylonitrile or methacrylonitrile from propane or isobutane
US6060421A (en) * 1998-12-23 2000-05-09 Saudi Basic Industries Corporation Catalysts for the oxidation of ethane to acetic acid, methods of making and using the same
US6017846A (en) * 1999-01-11 2000-01-25 Saudi Basic Industries Corporation Highly active and selective catalysts for the production of unsaturated nitriles, methods of making and using the same
US6037304A (en) * 1999-01-11 2000-03-14 Saudi Basic Industries Corporation Highly active and selective catalysts for the production of unsaturated nitriles, methods of making and using the same
US6436871B1 (en) 1999-02-22 2002-08-20 Symyx Technologies, Inc. Catalysts for oxidative dehydrogenation
EP1153005A1 (en) * 1999-02-22 2001-11-14 Symyx Technologies Compositions comprising nickel and their use as catalyst in oxidative dehydrogenation of alkanes
US6355854B1 (en) * 1999-02-22 2002-03-12 Symyx Technologies, Inc. Processes for oxidative dehydrogenation
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KR100407528B1 (ko) * 2000-09-18 2003-11-28 아사히 가세이 가부시키가이샤 산화 또는 가암모니아산화용 산화물 촉매의 제조 방법
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Also Published As

Publication number Publication date
AU4429085A (en) 1986-01-02
AU588814B2 (en) 1989-09-28
US4568790A (en) 1986-02-04
JPH0456808B2 (ko) 1992-09-09
NO160917C (no) 1989-06-14
BR8503105A (pt) 1986-03-18
JPS6118729A (ja) 1986-01-27
YU108085A (en) 1987-10-31
CA1229352A (en) 1987-11-17
NO852593L (no) 1985-12-30
DE3561010D1 (en) 1987-12-23
EP0166438A2 (en) 1986-01-02
MX167426B (es) 1993-03-22
ZA854884B (en) 1986-02-26
EP0166438B1 (en) 1987-11-19
NO160917B (no) 1989-03-06
EP0166438A3 (en) 1986-04-23

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