KR850001260A - 중합체 염료 - Google Patents

중합체 염료 Download PDF

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Publication number
KR850001260A
KR850001260A KR1019840004209A KR840004209A KR850001260A KR 850001260 A KR850001260 A KR 850001260A KR 1019840004209 A KR1019840004209 A KR 1019840004209A KR 840004209 A KR840004209 A KR 840004209A KR 850001260 A KR850001260 A KR 850001260A
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KR
South Korea
Prior art keywords
polymer
acid
group
solvent
film
Prior art date
Application number
KR1019840004209A
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English (en)
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KR870000751B1 (ko
Inventor
일라이어스 짜아르 십오지
Original Assignee
도늘드 에이 호오스
이 아이 듀우판 디 네모아 앤드 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 도늘드 에이 호오스, 이 아이 듀우판 디 네모아 앤드 캄파니 filed Critical 도늘드 에이 호오스
Publication of KR850001260A publication Critical patent/KR850001260A/ko
Priority to KR868611321A priority Critical patent/KR890000491B1/ko
Application granted granted Critical
Publication of KR870000751B1 publication Critical patent/KR870000751B1/ko

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Classifications

    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
    • G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
    • G11B7/245—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing a polymeric component
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B69/00—Dyes not provided for by a single group of this subclass
    • C09B69/10—Polymeric dyes; Reaction products of dyes with monomers or with macromolecular compounds
    • C09B69/105—Polymeric dyes; Reaction products of dyes with monomers or with macromolecular compounds containing a methine or polymethine dye
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
    • G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
    • G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
    • G11B7/247—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes methine or polymethine dyes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Optical Record Carriers And Manufacture Thereof (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

내용 없음

Description

중합체 염료
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (23)

  1. 방향족 폴리아민과 하기 구조식의 디카보닐화합물을 강수소산 존재하에 중축합시켜 얻은 반응생성물인 필름형성폴리(공액 폴리메틴-형) 염료.
    상기식에서, R1과 R5는 독립적으로 -H, C1-4알킬, 페닐, C7-12아르알킬, C7-12알크아릴 및 C5-8사이클로알킬로 구성된 군으로부터 선택되며, R1과 R5가 함께 취해져 각기 C2-5알킬렌인 경우 이들은 C5-8원소고리를 형성하는, R2,R3및 R4는 각기 -H, C1-3알킬 및 할로겐으로 구성된 군으로부터 독립적으로 선택되며, X는 0 또는 1-3의 정수이다.
  2. 제1항에 있어서, 방향족 폴리아민이 가변색성인 중합체 염료.
  3. 제1항에 있어서, 고극성 반양자성 용매중에서 생성된 중합체 염료.
  4. 제1항에 있어서, 방향족 폴리아민이 티오닌인 중합체 염료.
  5. 제1항에 있어서, 방향족 폴리아민이 N,N,N',N'-테트라키스-(p-아미노-페닐)-p-페닐렌디아민인 중합체 염료.
  6. 제1항에 있어서, X가 0 또는 1인 중합체.
  7. 제1항에 있어서, 산화제로 처리된 중합체.
  8. 제1항에 있어서, 산화제가 AgAsF6인 중합체.
  9. 제1항에 있어서, X가 0이고 R1-R5가 -H인 중합체.
  10. 제1항에 있어서, 전도도가 23℃, 상대습도 0%에서 적어도 약 10-3ohm-1㎝-1인 중합체 필름.
  11. 제1항에 있어서, 고극성반양자성 용매중 중합체 용액.
  12. 제11항에 있어서, 반양자성 용매가 디메틸 포름아미드, 디메틸 아세트아미드, 디메틸설폭사이드 및 N-메틸피졸리돈과 그 혼합물로 구성된 군으로 부터 선택된 용액.
  13. 방향족 폴리아민 또는 그의 염과 적어도 1몰 당량의 디카보닐 화합물을 고극성반양자성 용매중에서 용해시킨 다음, 거기에 방향족 폴리아민 1몰당 적어도 1몰의 강산을 첨가하는 것으로 구성된 제1항의 중합체를 제조하는 방법.
  14. 제13항에 있어서, 필름이 용액으로 부터 주조되는 방법.
  15. 제13항에 있어서, 강산이 과염소산, 플루오로설폰산, 트리플루오로 메탄설폰산 및 p-톨루엔설폰산과 요드화수소산으로 구성된 군으로 부터 선택되는 방법.
  16. 제13항에 있어서, 용매가 디메틸포름아미드, 디메틸아세트아미드, 디메틸설폭사이드 및 N-메틸피졸리돈과 그 혼합물로 구성된 군으로부터 선택되는 방법.
  17. 하기 구조식을 가진 폴리아조메틴염
    상기 구조에서 HX는 산 또는 산들의 혼합물임.
  18. 제17항에 있어서, 상기 필름이 23℃, 상대습도 0%에서 적어도 약 10-3ohm-1㎝-1의 전도도를 갖는 폴리아조멘틴염으로 된 필름.
  19. 제17항에 있어서, 용매가 디메틸포름아미드, 디메틸아세트아미드, 디메틸설폭사이드 및 N-메틸피졸리돈과 그 혼합물로 구성된 군으로 부터 선택되는 폴리아조메틴염 용액.
  20. 4,4'-디아미노 디페닐 아민 또는 그의 염과 말론알데히드 비스(디메틸 아세탈)을 통상적인 용매인 4,4'-디아미노페닐아민 몰당 말론알데히드비스(디메틸아세탈) 동몰량 부터 1.5몰까지의 비율로 용해시킨 다음 4,4'-디아미노 디페닐아민 각 몰당 적어도 약 1몰의 강산을 첨가하는 것으로 구성된 신규한 폴리아조메틴염 용액을 제조하는 방법.
  21. 제20항에 있어서, 용액으로 부터 필름이 주조되는 방법.
  22. 제20항에 있어서, 강산이 과염소산, 플루오로설폰산, 트리플루오로 메탄설폰산 및 p-톨루엔설폰산으로부터 선택되는 방법.
  23. 제20항에 있어서, 용매가 디메틸포름아미드, 디메틸아세트아미드, 디메틸설폭사이드, N-메틸피졸리돈과 그 혼합물로 구성된 군으로 부터 선택되는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019840004209A 1983-07-18 1984-07-18 광학기록매체용 중합체의 제조방법 KR870000751B1 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR868611321A KR890000491B1 (en) 1983-07-18 1986-12-26 Polymeric dye

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US51489083A 1983-07-18 1983-07-18
US514,890 1983-07-18
US06/585,107 US4501876A (en) 1983-07-18 1984-03-01 Film-forming poly(conjugated polymethine-type)dye
US585,107 1984-03-01

Publications (2)

Publication Number Publication Date
KR850001260A true KR850001260A (ko) 1985-03-16
KR870000751B1 KR870000751B1 (ko) 1987-04-13

Family

ID=27058350

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019840004209A KR870000751B1 (ko) 1983-07-18 1984-07-18 광학기록매체용 중합체의 제조방법

Country Status (6)

Country Link
US (1) US4501876A (ko)
EP (1) EP0134500B1 (ko)
KR (1) KR870000751B1 (ko)
BR (1) BR8403527A (ko)
CA (1) CA1224786A (ko)
DE (1) DE3467768D1 (ko)

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Also Published As

Publication number Publication date
KR870000751B1 (ko) 1987-04-13
EP0134500A2 (en) 1985-03-20
BR8403527A (pt) 1985-06-25
DE3467768D1 (en) 1988-01-07
US4501876A (en) 1985-02-26
EP0134500B1 (en) 1987-11-25
EP0134500A3 (en) 1985-10-23
CA1224786A (en) 1987-07-28

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