KR20020050314A - Disposable absorptive product for prevention of rash - Google Patents
Disposable absorptive product for prevention of rash Download PDFInfo
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- KR20020050314A KR20020050314A KR1020000079433A KR20000079433A KR20020050314A KR 20020050314 A KR20020050314 A KR 20020050314A KR 1020000079433 A KR1020000079433 A KR 1020000079433A KR 20000079433 A KR20000079433 A KR 20000079433A KR 20020050314 A KR20020050314 A KR 20020050314A
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- nonwoven fabric
- sores
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/44—Medicaments
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/00051—Accessories for dressings
- A61F13/00063—Accessories for dressings comprising medicaments or additives, e.g. odor control, PH control, debriding, antimicrobic
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/40—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing ingredients of undetermined constitution or reaction products thereof, e.g. plant or animal extracts
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- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
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- Heart & Thoracic Surgery (AREA)
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- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Medicines Containing Plant Substances (AREA)
- Absorbent Articles And Supports Therefor (AREA)
Abstract
Description
본 발명은 피부 짓무름 억제를 위한 피부보호제를 포함하는 유상조성물이 적용된 일회용 흡수제품에 관한 것이다. 보다 상세하게는, 본 발명은 피부보호제로서 퀘르세틴(quercetin), 바이칼린(baicalin), 지실 추출물(synephrine extracts) 또는 이들 중 2 이상의 혼합물로 이루어진 그룹 중에서 선택된 것을 포함하는 유상 조성물이 액체 투과성 상부시트에 적용된 피부 짓무름 억제용 일회용 흡수제품에 관한 것이다.The present invention relates to a disposable absorbent product to which an oil composition containing a skin protectant for inhibiting skin sores is applied. More specifically, the present invention provides a liquid-permeable topsheet comprising an oily composition comprising a quercetin, a baicalin, a synephrine extract or a mixture of two or more thereof. The present invention relates to a disposable absorbent article for suppressing skin sores applied.
일반적으로 시중에서 판매되고 있는 일회용 흡수제품은 장시간 착용시 피부의 짓무름을 유발하여 사용이 기피되는 경우가 종종 있었다. 이를 해소하기 위해서 통기성을 강화하고 상부시트의 구조를 개선하는 등의 여러 방법을 시도하였지만 짓무름 발생을 효과적으로 억제하지는 못했다. 피부 짓무름은 상부시트와 피부와의 장시간에 걸친 마찰 및 배뇨 성분에 의한 피부의 pH의 변화에 의한 자극에 기인하는 것으로 마찰 및 배설물과의 접촉을 효과적으로 차단하지 않고는 짓무름 발생을 억제할 수 없다.In general, commercially available disposable absorbent products often cause skin sores when worn for a long time and are often avoided. In order to solve this problem, various attempts have been made to enhance breathability and improve the structure of the top sheet, but they have not effectively suppressed the occurrence of sores. Skin sores are caused by prolonged friction between the topsheet and the skin and stimulation caused by changes in the pH of the skin due to the urination component, and the occurrence of sores cannot be suppressed without effectively blocking friction and contact with feces.
이러한 피부 짓무름을 억제하기 위해서 상부시트에 바셀린이 처리된 제품이 개발되었다. 이는 바셀린이 피부에 코팅되어 마찰을 완화하고 배설물의 피부 접촉을 일부 차단하기는 하지만, 완벽하게 차단하는 것은 불가능했기 때문에 그 효과는 미미하였다.In order to suppress the skin sores, petrolatum-treated products have been developed in the top sheet. This effect was negligible because petrolatum was coated on the skin to relieve friction and partially block skin contact with feces, but it was impossible to completely block.
따라서, 보다 효과적인 짓무름 완화를 위해서 2차적으로 발생되는 짓무름 또는 염증을 억제 및 완화할 수 있는 소염 또는 살균 기능을 가지는 물질을 첨가해야 할 필요성이 대두되었다.Therefore, there is a need to add a substance having an anti-inflammatory or bactericidal function capable of suppressing and alleviating secondary occurring sores or inflammations for more effective sores relief.
본 발명의 목적은 사용시 상부시트에 피부보호제를 포함하는 유상 조성물이 적용되어 피부 짓무름의 발생을 효과적으로 억제시킬 수 있는 일회용 흡수제품을 제공하는 데 있다.An object of the present invention is to provide a disposable absorbent product that can effectively suppress the occurrence of skin sores by applying an oil-based composition comprising a skin protector to the top sheet during use.
도 1은 본 발명에 따른 피부 짓무름 억제용 일회용 흡수제품에 사용되는 액체 투과성 상부시트의 제조과정을 간략하게 도시한 구성도이다.Figure 1 is a schematic diagram illustrating a manufacturing process of the liquid permeable top sheet used in the disposable absorbent product for inhibiting skin sores according to the present invention.
※ 도면의 주요부분에 대한 부호의 설명※ Explanation of code for main part of drawing
1: 부직포 원료 공급기 2: 유상조성물 공급기1: nonwoven fabric feeder 2: oil composition feeder
3: 압축성형기 4: 부직포 회수롤3: compression molding machine 4: nonwoven fabric recovery roll
5: 산화아연 공급기5: zinc oxide feeder
본 발명에 따른 피부 짓무름 억제용 일회용 흡수제품은 피부보호제로서 퀘르세틴, 바이칼린, 지실 추출물 또는 이들 중 2 이상의 혼합물을 포함하는 유상조성물을 액체 투과성 상부시트에 적용시켜 이루어짐을 특징으로 한다.Disposable absorbent products for skin soak suppression according to the present invention is characterized in that by applying a liquid composition containing a quercetin, Baikal, fruity extract or a mixture of two or more thereof as a skin protector to a liquid permeable top sheet.
상기 상부시트는 산화아연 분말 1 내지 10 중량%를 함유하는 부직포임을 특징으로 한다.The top sheet is characterized in that the nonwoven fabric containing 1 to 10% by weight of zinc oxide powder.
이하 본 발명의 구체적인 실시예를 상세히 설명한다.Hereinafter, specific embodiments of the present invention will be described in detail.
본 발명에 따른 피부 짓무름 억제용 일회용 흡수제품은 피부보호제로서 퀘르세틴, 바이칼린, 지실 추출물 또는 이들 중 2 이상의 혼합물을 포함하는 유상조성물을 액체 투과성 상부시트에 적용시켜 이루어짐을 특징으로 한다.Disposable absorbent products for skin soak suppression according to the present invention is characterized in that by applying a liquid composition containing a quercetin, Baikal, fruity extract or a mixture of two or more thereof as a skin protector to a liquid permeable top sheet.
상기 피부보호제로서의 퀘르세틴, 바이칼린 및 지실 추출물은 천연 성분으로서 피부 자극에 의한 짓무름 또는 염증을 억제 및 완화하는 성질이 있다. 퀘르세틴은 식물체에 널리 분포하는 플라보노이드의 일종으로 항산화제 또는 항모세혈관 투과제로 사용되고 있으며 또한 항염증 효과가 알려져 있다. 바이칼린은 황금에서 추출한 것으로 항알레르기 및 항염증 효과가 알려져 있다. 지실은 어린 탱자로서 예로부터 아토피성 피부에 지실 달인 물을 바르곤 했으며, 주성분은 시네프린 및 플라보노이드 배당체로서 위염 및 소화 장애에 사용되어 왔다. 이러한 퀘르세틴, 바이칼린 및 지실 추출물은 오래 전부터 사용해 온 천연 성분으로서 피부에 대한 자극이 거의 없고 극히 안전하다. 특히 이들 물질을 2종 이상 혼합하여 사용하면 그 효과가 증대된다.Quercetin, Baikallin and fruit juice extracts as skin protectants have natural properties of inhibiting and alleviating sores or inflammation caused by skin irritation. Quercetin is a kind of flavonoids widely distributed in plants and is used as an antioxidant or an anticapillary permeation agent and also has an anti-inflammatory effect. Baikalin is extracted from gold and is known for its anti-allergic and anti-inflammatory effects. Fruits have been used as a juvenile tank for atopic dermatitis, and the main ingredients have been used for gastritis and digestive disorders as cinephrine and flavonoid glycosides. These quercetin, bacalin, and fruit extracts are natural ingredients that have been used for a long time with little irritation to the skin and extremely safe. In particular, when two or more kinds of these materials are mixed and used, the effect is increased.
본 발명에서는 상기한 피부보호제를 통상의 바셀린 기재 로션에 포함시킨 유상조성물을 흡수제품의 액체 투과성 상부시트에 적용시켜 피부 짓무름 등을 예방토록 한 점에 특징이 있다.The present invention is characterized in that the oil composition comprising the above-described skin protection agent in a conventional petrolatum-based lotion is applied to the liquid permeable top sheet of the absorbent product to prevent skin sores.
본 발명에 따른 유상조성물은 상온에서는 고형이며 40℃ 내외에서 반고형 상태가 되도록 조성되었으며, 각 성분의 함량은 0.01 내지 10 중량%, 바람직하게는 0.05 내지 1 중량%이다.The oily composition according to the present invention is solid at room temperature and is formulated to be in a semi-solid state at about 40 ° C, and the content of each component is 0.01 to 10% by weight, preferably 0.05 to 1% by weight.
기존의 바셀린 기재 로션에 퀘르세틴, 바이칼린, 지실 추출물 또는 이들 중 2 이상의 혼합물을 포함하는 유상조성물을 첨가하여 상부시트에 적용시킴으로써 피부 짓무름의 발생을 효과적으로 억제 및 완화할 수 있었다. 특히 이들 물질을 2종 이상 혼합하여 사용하면 그 효과가 증대되었다. 유상조성물을 상부시트에 처리하는 방법으로는 이미 제조된 부직포에 유상조성물을 분무 코팅하는 방법과 부직포 제작시 압출 성형 전에 유상조성물을 분무 코팅하는 방법이 있다. 도 1에 나타낸 바와 같이, 부직포 원료 공급기(1)로부터 공급되는 원료가 압축성형기(3)를 거쳐 압축성형되기 전에 산화아연 공급기(5)를 통해 산화아연을 공급하여 상부시트에 적용시킬 수 있다. 또한, 유상조성물 공급기(2)로부터 공급되는 피부보호제를 포함하는 유상조성물도 유사하게 상부시트에 적용시킬 수 있다. 제조된 부직포는 부직포 회수롤(4)에 감겨 회수된다.It was possible to effectively suppress and alleviate the occurrence of skin sores by adding an oil composition comprising a quercetin, a bicalin, a fruit extract or a mixture of two or more thereof to an existing petroleum jelly based lotion. In particular, when two or more kinds of these materials are mixed and used, the effect is increased. Methods of treating the oil composition to the top sheet include spray coating the oil composition on the already prepared nonwoven fabric and spray coating the oil composition before extrusion molding during nonwoven fabric production. As shown in FIG. 1, before the raw material supplied from the nonwoven fabric raw material feeder 1 is compression molded via the compression molding machine 3, zinc oxide may be supplied through the zinc oxide feeder 5 and applied to the upper sheet. In addition, an oil composition including a skin protectant supplied from the oil composition feeder 2 can be similarly applied to the top sheet. The produced nonwoven fabric is wound around the nonwoven fabric recovery roll 4 and recovered.
상기 상부시트는 산화아연 분말 1 내지 10 중량% 함유하는 부직포임을 특징으로 한다. 산화아연 분말을 첨가하여 제조한 부직포를 상부시트로 하여 상기의 피부보호제를 포함하는 유상조성물을 적용시킬 경우 그 효과가 증대되었다.The top sheet is characterized in that the nonwoven fabric containing 1 to 10% by weight of zinc oxide powder. When the nonwoven fabric prepared by adding zinc oxide powder was used as the top sheet, the oil composition containing the skin protection agent was applied, and the effect was increased.
이하에서 본 발명의 바람직한 실시예 및 비교예들이 기술되어질 것이다.Hereinafter, preferred embodiments and comparative examples of the present invention will be described.
이하의 실시예들은 본 발명을 예증하기 위한 것으로서 본 발명의 범위를 국한시키는 것으로 이해되어져서는 안될 것이다.The following examples are intended to illustrate the invention and should not be understood as limiting the scope of the invention.
비교예 1Comparative Example 1
기존의 바셀린 기재 로션을 제조하고 부직포에 적용시켜 상부시트를 제조하였다.Existing petrolatum based lotions were prepared and applied to a nonwoven fabric to prepare a topsheet.
실시예 1 내지 3Examples 1 to 3
하기 표 1에 기재된 바와 같이, 피부 짓무름 효과를 높이고자 퀘르세틴, 바이칼린 및 지실 추출물의 천연 성분을 2종 이상 혼합 사용하여 유상조성물을 제조하고, 이것을 이미 제조된 부직포에 적용시켜 상부시트를 제조하였다. 천연 성분 각각의 농도는 짓무름 억제 효과와 용해도를 감안하여 예비 실험을 통해 설정하였다. 각각의 천연 성분은 1,3-부티렌글리콜에 녹여 유화하여 사용하였다. 바셀린, 고형 파라핀 및 유동 파라핀 등을 주성분으로 하였고 상기 유효 성분 외에 계면활성제(3%) 등이 포함되었다. 고형 파라핀은 실온에서는 고체이고 42 내지 50 ℃에서 녹는점을 가지는 것을 사용하였다. 따라서, 분무에 적합한 유동성을 확보하기 위해서는 유상조성물 저장 장치의 온도를 55 내지 90 ℃로 유지하여야 한다.As shown in Table 1 below, in order to enhance the skin crushing effect, an oily composition was prepared using a mixture of two or more natural components of quercetin, baikal, and lychee extract, and the topsheet was prepared by applying the oily composition to an already prepared nonwoven fabric. . The concentrations of each of the natural components were set through preliminary experiments in consideration of the sour suppression effect and solubility. Each natural component was used by dissolving in 1,3-butylene glycol. Vaseline, solid paraffin and liquid paraffin were the main components, and in addition to the active ingredients, surfactants (3%) were included. Solid paraffin was used that was solid at room temperature and had a melting point at 42 to 50 ° C. Therefore, in order to ensure the fluidity suitable for spraying, the temperature of the oil composition storage device should be maintained at 55 to 90 ° C.
산화아연을 함유하는 상부시트는 부직포 제조 공정 중에 산화아연 분말을 첨가하여 제조하였다.The top sheet containing zinc oxide was prepared by adding zinc oxide powder during the nonwoven fabric manufacturing process.
상기 유상조성물을 부직포에 분무 코팅시, 유상조성물 분무의 폭은 부직포 너비의 90% 수준으로 하였으며, 수분의 통과성을 고려하여 0.5 내지 1 cm 너비의 띠 형태로 코팅하였으며, 띠간 간격은 0.5 cm 로 조절하였다. 분무압은 유상조성물이 0.003 g/㎠ 정도로 코팅될 수 있도록 조절하였다.When spray coating the oil composition on the nonwoven fabric, the width of the oil composition spray was 90% of the width of the nonwoven fabric, and was coated in the form of a band having a width of 0.5 to 1 cm in consideration of water permeability, and the interval between the bands was 0.5 cm. Adjusted. Spray pressure was adjusted so that the oily composition could be coated to about 0.003 g / ㎠.
실험예 1: 유상조성물이 처리된 상부시트의 짓무름 억제 효과 측정Experimental Example 1: Measurement of the anti-soiling effect of the top sheet treated with the oil composition
비교예 1 및 실시예 1 내지 3에서 수득된 유상조성물이 처리된 상부시트의 짓무름 억제 효과를 측정하기 위하여 등판 패치 시험을 수행하였다. 유상조성물이 처리 되지 않은 부직포를 대조군으로 하였다. 대조군, 비교예 및 실시예의 상부시트를 등판에 부착하고 24시간 경과 후 유효 성분이 피부에 전달되게 한 다음, 자극 유발 물질인 컴파운드 48/80(미국 시그마사)을 함침한 부직포를 다시 부착하여 24시간 경과 후 피부 자극도를 측정하였다. 그 결과가 표 2에 기재되어 있다.The back patch test was conducted to measure the anti-soiling effect of the topsheet treated with the oil compositions obtained in Comparative Examples 1 and 1 to 3. The nonwoven fabric not treated with oil composition was used as a control. Attach the top sheet of the control, comparative and example to the back plate and allow the active ingredient to be delivered to the skin after 24 hours, and then re-attach the nonwoven fabric impregnated with compound 48/80 (Sigma, USA), which is an irritant. Skin irritation was measured after the passage of time. The results are shown in Table 2.
상기 표 2에 나타난 바와 같이, 본 발명에 따른 퀘르세틴, 바이칼린 및 지실 추출물의 천연 성분을 2종 이상 혼합 사용한 유상조성물의 피부 짓무름 효과가 대조군에 비해 우수하였으며, 특히 부직포에 산화아연 분말을 첨가시킨 상부시트에 적용시 그 효과가 가장 좋았다.As shown in Table 2, the skin soaking effect of the oily composition using a mixture of two or more natural ingredients of quercetin, Baikallin and Jissil extract according to the present invention was superior to the control, in particular zinc oxide powder added to the nonwoven fabric The effect was best when applied to the top sheet.
실험예 2: 유상조성물이 도포된 상부시트를 활용한 일회용 기저귀의 짓무름 억제 효과Experimental Example 2: Anti-scorching effect of the disposable diaper using the top sheet coated with an oil composition
실험예 1의 결과로부터 효과가 가장 좋았던 실시예 3의 유상조성물이 도포된상부시트를 활용한 일회용 기저귀를 시험군으로 하고, 실시예의 유상조성물 및 바셀린이 전혀 도포되지 않은 상부시트를 활용한 일회용 기저귀를 대조군으로 하여 실제 기저귀의 짓무름 억제효과 시험을 수행하였다. 짓무름 때문에 고생하는 아이 각각 10명에게 7일간 대조군과 시험군의 기저귀를 착용하게 한 후, 짓무름 억제 정도를 비교하였다. 그 결과, 대조군 실험자에게서 별다른 유의 사항이 관찰되지 않음에 비해 10명의 시험군 실험자 중 8명이 짓무름 완화 효과를 보였으며, 대조군 대비 약 90% 정도 완화되어 거의 짓무름이 관찰되지 않았다.The disposable diaper using the upper sheet coated with the oil composition of Example 3, which had the best effect from the results of Experimental Example 1, was used as the test group, and the disposable diaper using the oil-based composition of the example and the top sheet not coated with petroleum jelly at all. Was used as a control to test the effect of inhibiting the soak of the actual diaper. Ten children who suffered from sores were asked to wear diapers of the control and test groups for 7 days, and then the degree of suppression of sores was compared. As a result, 8 out of 10 test group showed an effect of mitigating erosion compared to no significant notice in the control group, and about 90% of the control group was mitigated.
상기 실시예 및 실험예를 종합한 결과, 퀘르세틴, 바이칼린, 지실 추출물 또는 이들 중 2 이상의 혼합물로 이루어진 그룹 중에서 선택된 피부보호제를 포함하는 유상조성물을 일회용 기저귀의 상부시트에 적용시킴으로써 피부 짓무름의 발생을 효과적으로 완화 및 억제시킬 수 있다는 것을 확인하였다.As a result of the synthesis of the above examples and experimental examples, the occurrence of skin sores was applied by applying an oil composition comprising a skin protection agent selected from the group consisting of quercetin, baikal, fruit juice extract or a mixture of two or more thereof to the top sheet of the disposable diaper. It was confirmed that it can be effectively alleviated and suppressed.
따라서, 본 발명에 의하면 상부시트에 피부보호제를 포함하는 유상 조성물이 적용되어 사용시 피부 짓무름의 발생을 효과적으로 억제시킬 수 있는 일회용 흡수제품을 제공하는 효과가 있다.Therefore, according to the present invention, an oily composition including a skin protectant is applied to the top sheet, thereby providing a disposable absorbent product which can effectively suppress the occurrence of skin sores during use.
이상에서 본 발명은 기재된 구체예에 대해서만 상세히 설명되었지만 본 발명의 기술사상 범위 내에서 다양한 변형 및 수정이 가능함은 당업자에게 있어서 명백한 것이며, 이러한 변형 및 수정이 첨부된 특허청구범위에 속함은 당연한 것이다.Although the present invention has been described in detail only with respect to the described embodiments, it will be apparent to those skilled in the art that various modifications and variations are possible within the technical scope of the present invention, and such modifications and modifications are within the scope of the appended claims.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100537492B1 (en) * | 2002-06-28 | 2005-12-19 | 이영근 | Novel natural compound having antibacterial activity |
| KR100887619B1 (en) * | 2007-05-04 | 2009-03-12 | 그린텍이십일 주식회사 | Composition for inhibiting a diaper rash and disposable absorbent article containing the same |
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| CN102335449B (en) * | 2011-10-11 | 2013-10-02 | 天津工业大学 | Method for prepaing nanometer composite gel dressing containing baicalin and soapstone |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPS6150918A (en) * | 1984-08-20 | 1986-03-13 | Ichimaru Fuarukosu Kk | Liquid composition containing baicalin or baicalein and external drug for skin or skin cosmetic containing same |
| KR950012183B1 (en) * | 1992-11-17 | 1995-10-14 | 주식회사 엘지화학 | Disposable diapers |
| FR2774287B1 (en) * | 1998-01-30 | 2000-05-12 | Oreal | CLEANSING PATCH, DEVELOPING THE SKIN CONDITION |
| KR19990084624A (en) * | 1998-05-08 | 1999-12-06 | 성재갑 | Disposable absorbent products |
| FR2781668B1 (en) * | 1998-07-31 | 2001-06-01 | Oreal | SKIN TREATMENT PROCESS AND PATCH FOR IMPLEMENTING THE PROCESS |
| CA2373027A1 (en) * | 1999-05-19 | 2000-11-23 | The Procter & Gamble Company | Absorbent article with skin care composition |
| KR100552923B1 (en) * | 1999-07-31 | 2006-02-22 | 주식회사 엘지생활건강 | Hair care composition containing Quercetin |
| KR20020046400A (en) * | 2000-12-14 | 2002-06-21 | 성재갑 | Disposable diaper comprising skin protecting agent |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| KR100537492B1 (en) * | 2002-06-28 | 2005-12-19 | 이영근 | Novel natural compound having antibacterial activity |
| KR100887619B1 (en) * | 2007-05-04 | 2009-03-12 | 그린텍이십일 주식회사 | Composition for inhibiting a diaper rash and disposable absorbent article containing the same |
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