KR20020000761A - 증가된 형광성을 지닌 페놀-디카보닐 축합물의 제조방법,이를 이용하여 제조된 에폭시 수지, 에폭시 수지 시스템및 라미네이트 - Google Patents
증가된 형광성을 지닌 페놀-디카보닐 축합물의 제조방법,이를 이용하여 제조된 에폭시 수지, 에폭시 수지 시스템및 라미네이트 Download PDFInfo
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/032—Organic insulating material consisting of one material
- H05K1/0326—Organic insulating material consisting of one material containing O
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
- C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
- C08G59/063—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols with epihalohydrins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
- C08G59/3218—Carbocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/62—Alcohols or phenols
- C08G59/625—Hydroxyacids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/02—Condensation polymers of aldehydes or ketones with phenols only of ketones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/259—Coating or impregnation provides protection from radiation [e.g., U.V., visible light, I.R., micscheme-change-itemave, high energy particle, etc.] or heat retention thru radiation absorption
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2926—Coated or impregnated inorganic fiber fabric
- Y10T442/2992—Coated or impregnated glass fiber fabric
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Epoxy Resins (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Laminated Bodies (AREA)
Abstract
Description
실험 | 1 | 2 | 3 | 4 | 5(대조) | 6(대조) | 7(대조) | 8(대조) |
TPE 제조: | ||||||||
사용된 산 촉매(1) | 말레산 | 말레산 | ADCA(2) | DHBA(2) | 옥살산 | 프탈산 | 숙신산 | 포름산 |
산 또는 무수물,g(eq 산) | 21.45(0.437) | 21.45(0.437) | 24.95(0.437) | 33.70(0.219) | 27.5(0.438) | 32.4(0.438) | 21.82(0.436) | 27.59(0.60) |
페놀, g(몰) | 564.6(6) | 564.6(6) | 564.6(6) | 564.6(6) | 564.6(6) | 564.6(6) | 564.6(6) | 564.6(6) |
40%수성 글리옥살,g(몰) | 116.08(0.8) | 116.08(0.8) | 116.08(0.8) | 116.08(0.8) | 116.08(0.8) | 116.08(0.8) | 116.08(0.8) | 116.08(0.8) |
페놀(몰)/글리옥살(몰) | 7.5 | 7.5 | 7.5 | 7.5 | 7.5 | 7.5 | 7.5 | 7.5 |
산(당량)/페놀(몰) | 0.073 | 0.073 | 0.073 | 0.036 | 0.073 | 0.073 | 0.073 | 0.100 |
반응 온도,℃ | 120 | 190 | 190 | 190 | 120 | 190 | 190 | 120(3) |
정해진 온도에서시간, h | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 |
TPE산물, g(충진물%) | 156.5(22.3) | 162.6(23.2) | 169.6(24.0) | 134.5(18.8) | 182.72(25.8) | 141(19.8) | 103.3(14.7) | 80.4(11.4) |
가드너 색(5%IPA) | 17 | 15 | 16 | >18 | 12.5 | 18 | >18 | >18 |
형광성 | 3.24 | 5.11 | 6.01 | 5.11 | 1.07 | 2.35 | 2.97 | |
에폭시 수지 제조: | ||||||||
WPE(g/에폭사이드그룹 eq) | 220.4 | 234.1 | 213.4 | 208.9 | ||||
가드너 색(5%메틸 에틸케톤) | 11.5 | 12 | 12.5 | 11 | ||||
형광성, 임의 단위 | 2.74 | 3.76 | 1.11 |
실험 | 1 | 2 | 3 | 4 | 5 |
TPE 제조: | |||||
사용된 산 촉매(1) | 말레산 | 말레산 | 말레산 | 말레산 | 말레산 |
산 또는 무수물,g(eq 산) | 5.36(0.109) | 21.45(0.437) | 21.45(0.437) | 21.45(0.437) | 34.32(0.7) |
페놀,g(몰) | 564.6(6) | 564.6(6) | 564.6(6) | 564.6(6) | 451.68(4.8) |
40% 수성 글리옥살,g(몰) | 116.08(0.8) | 116.08(0.8) | 116.08(0.8) | 116.08(0.8) | 185.73(1.28) |
페놀(몰)/글리옥살(몰) | 7.5 | 7.5 | 7.5 | 7.5 | 3.75 |
산(당량)/페놀(몰) | 0.018 | 0.073 | 0.073 | 0.073 | 0.146 |
정해진 반응 온도,℃ | 190 | 190 | 100 | 190 | 190 |
정해진 온도에서 시간, h | 2 | 2 | 2 | 2 | 2 |
TPE 산물,g(충진물%) | 140.6(20.5) | 106.7(16.2) | 156.5(22.3) | 162.6(23.2) | 260(38.7) |
가드너 색(5% IPA) | 17 | 13 | 17 | 15 | 16.5 |
형광성 | 1.35 | 2.53 | 3.24 | 5.11 | 8.22 |
에폭시 수지 제조: | |||||
WPE(g/에폭사이드 그룹의 eq) | 224.8 | 220.4 | 234.1 | 227.0 | |
가드너 색(5% 메틸 에틸 케톤) | 12.5 | 10.5 | 11.5 | 12 | 13.5 |
형광성, 임의 단위 | 0.94 | 2 | 2.74 | 3.76 | 6.75 |
흡수성, L/g-cm, 441 nm, THF 용액 | 0.212 | 0.297 | 0.305 | 0.39 | 0.591 |
흡수성, L/g-cm, 365 nm, THF 용액 | 1.76 | 3.16 | 3.17 | 3.48 | 5.44 |
실험 | 6 | 7 | 8 | 9 | 10 | 11 |
TPE 제조: | ||||||
사용된 산 촉매(1) | 옥살산 | 옥살산 | 옥살산 | 옥살산 | 옥살산 | 옥살산 |
산 또는 무수물, g(eq 산) | 55.18(0.875)) | 55.18(0.875) | 27.59(0.438) | 24.52(0.389) | 24.52(0.389) | 12.26(0.194) |
페놀,g(몰) | 1129.2(12) | 1129.2(12) | 564.6(6) | 564.6(6) | 564.6(6) | 564.6(6) |
40% 수성 글리옥살,g(몰) | 116.08(0.8) | 174.12(1.2) | 116.08(0.8) | 232.16(1.6) | 232.16(1.6) | 232.16(1.6) |
페놀(몰)/글리옥살(몰) | 15 | 10 | 7.5 | 3.75 | 3.75 | 3.75 |
산(당량)/페놀(몰) | 0.073 | 0.073 | 0.073 | 0.065 | 0.065 | 0.032 |
정해진 반응 온도,℃ | 120 | 120 | 120 | 120 | 120 | 120 |
정해진 온도에서 시간,h | 6 | 6 | 6.5 | 2.5 | 4 | 4 |
TPE 산물,g(충진물%) | 190.8(14.7) | 286.6(21.1) | 182.72(25.8) | 313.87(38.2) | 312.53(38.1) | 254.74(31.5) |
가드너 색(5% IPA) | 10 | 11.5 | 12.5 | 18 | 18 | 18 |
에폭시 수지 제조: | ||||||
WPE(g/에폭사이드 그룹 eq) | 203.2 | 205.9 | 208.9 | 222.1 | 221.4 | 210 |
가드너 색(5% 메틸 에틸 케톤) | 8.5 | 9.5 | 11 | 12.5 | 14 | 15.5 |
형광성, 임의 단위 | 0.68 | 0.99 | 1.11 | 1.52 | 1.92 | 1.49 |
흡수성, L/g-cm, 441 nm, THF 용액 | 0.108 | 0.176 | 0.226 | 0.464 | 0.413 | 0.48 |
흡수성, L/g-cm, 365 nm, THF 용액 | 1.9 | 2.48 | 3.42 | 4.31 | 4.1 | 3.8 |
190℃에서시간,hr | 말레산 무수물,g (충진물의중량%) | 17.16(2.62%) | 25.5(3.85%) | 34.32(5.11%) | 68.64(9.72%) |
0 | 수율/색/형광성 | 34.9/18/4.94 | 36.2/18/5.4936.3/18/5.94 | 37.7/17/4.73 | |
1 | 수율/색/형광성 | 36.3/18+/7.09 | 37.9/15.8/1.11,37.6/17.8/1.53 | 40.0/17/3.83 | |
2 | 수율/색/형광성 | 35.4/18/7.11,35.2/18+/7.75 | 37.5/17.8/10.9,37.4/18/7.07 | 38.6/17.5/7.04,38.9/17.8/8.06 | 40.9/17.0/3.51 |
2(175℃) | 수율/색/형광성 | 39.2/17.5/5.6 | |||
5 | 수율/색/형광성 | 35.8/18.0/7.58 | 37.2/17.8/7.52 | 39.9/17.8/6.56 | 43.9/17.5/3.24 |
형광 성분 | EPON Resin 1031(시판 대조) | TPE | TPE | TPE |
표 2a로부터 TPE 제조 # | 3 | 4 | 5 | |
형광 성분의 상대적 형광성 (1) | 1.0 | 3.24 | 5.11 | 8.22 |
제형 (부): (2) | ||||
EPON Resin 1124 | 90.9 | 93.8 | 96.0 | 97.5 |
TPE 또는 EPON Resin 1031 | 9.1 | 6.2 | 4.0 | 2.5 |
디시안디아미드(dicy) | 2.8 | 2.8 | 2.8 | 2.8 |
2-메틸이미다졸 | 0.07 | 0.07 | 0.07 | 0.07 |
공정 처리: | ||||
171℃ 바니시 겔 시간, 초 | 150 | 165 | 210 | 190 |
171℃ 프리프레그 겔 시간, 초 | 90 | 81 | 120 | 135 |
B-스테이징 시간, 163℃, 분 | 5 | 4 | 5 | 5 |
유동, 177℃ 프레스 경화 | 유사 | 유사 | 유사 | 유사 |
경화된 성질: | ||||
형광 지수 (1) | 1.0 | 0.88 | 1.0 | |
색 | 황색 | 가장 짙음 | 좀더 짙음 | 짙음 |
Tg, ℃ (DSC) | 136 | 131 | 132 | 131 |
Claims (20)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12024799P | 1999-02-16 | 1999-02-16 | |
US60/120,247 | 1999-02-16 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20020000761A true KR20020000761A (ko) | 2002-01-05 |
KR100469199B1 KR100469199B1 (ko) | 2005-01-31 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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KR10-2001-7010068A KR100469199B1 (ko) | 1999-02-16 | 2000-02-15 | 증가된 형광성을 지닌 페놀-디카보닐 축합물의 제조방법, 이를 이용하여 제조된 에폭시 수지, 에폭시 수지 조성물 및 라미네이트 |
Country Status (12)
Country | Link |
---|---|
US (1) | US6608161B1 (ko) |
EP (1) | EP1183294B1 (ko) |
KR (1) | KR100469199B1 (ko) |
CN (1) | CN1156504C (ko) |
AT (1) | ATE258942T1 (ko) |
AU (1) | AU2805200A (ko) |
BR (1) | BR0008263A (ko) |
DE (1) | DE60008100T2 (ko) |
ES (1) | ES2215026T3 (ko) |
MY (1) | MY121469A (ko) |
TW (1) | TWI262932B (ko) |
WO (1) | WO2000049061A1 (ko) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
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US6201094B1 (en) * | 1998-09-22 | 2001-03-13 | Borden Chemical, Inc. | Phenol-novolacs with improved optical properties |
JP6069047B2 (ja) * | 2012-04-27 | 2017-01-25 | 花王株式会社 | 鋳型造型用硬化剤組成物 |
US10138325B2 (en) * | 2016-05-12 | 2018-11-27 | Chang Chun Plastics Co., Ltd. | Polyphenolic condensates and epoxy resins thereof |
US10600664B2 (en) * | 2017-05-03 | 2020-03-24 | Applied Materials, Inc. | Fluorescence based thermometry for packaging applications |
CN110423203B (zh) * | 2019-07-31 | 2022-11-01 | 湘潭大学 | 一种具有聚集诱导发光性质的荧光胺类化合物及其制备方法和应用 |
CN110526820B (zh) * | 2019-07-31 | 2022-11-01 | 湘潭大学 | 一种具有聚集诱导发光性质的荧光羧酸类化合物及其制备方法和应用 |
CN110343081B (zh) * | 2019-07-31 | 2022-09-27 | 湘潭大学 | 一种具有聚集诱导发光性质的荧光酸酐类化合物及其制备方法和应用 |
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US3005797A (en) * | 1958-01-13 | 1961-10-24 | Koppers Co Inc | Resins of controlled properties |
BE576372A (ko) * | 1958-03-07 | |||
GB1314183A (en) * | 1969-08-07 | 1973-04-18 | Courtaulds Ltd | Synthetic tanning agent |
US3738862A (en) * | 1971-11-08 | 1973-06-12 | Shell Oil Co | Process for preparing reinforced laminates in situ with epoxy-polyhydric phenol condensates |
JPH01132654A (ja) * | 1987-11-18 | 1989-05-25 | Hitachi Chem Co Ltd | 耐荷重性耐熱巻線体の製造法 |
US5134204A (en) * | 1989-05-12 | 1992-07-28 | Mitsui Toatsu Chemicals, Inc. | Resin composition for sealing semiconductors |
JPH0676973B2 (ja) * | 1989-05-30 | 1994-09-28 | 松下電工株式会社 | 回路パターンの検査法 |
US5012016A (en) | 1990-03-20 | 1991-04-30 | Shell Oil Company | Process for preparing tetraphenolic compounds |
JP2501154B2 (ja) * | 1990-11-26 | 1996-05-29 | 三井東圧化学株式会社 | テトラキスキシレノ―ルエタンの製造方法 |
JPH05323604A (ja) * | 1992-05-27 | 1993-12-07 | Sumitomo Chem Co Ltd | ポジ型レジスト組成物 |
US5508328A (en) * | 1994-11-17 | 1996-04-16 | Alliedsignal Inc. | Curing epoxy resins using dicy, imidazole and acid |
AU717795B2 (en) * | 1996-05-24 | 2000-03-30 | Rohm And Haas Company | Fluorescent polymers and coating compositions |
JPH10130189A (ja) * | 1996-10-25 | 1998-05-19 | Sumitomo Chem Co Ltd | 多価フェノール化合物、およびそれを用いた樹脂組成物 |
US6001950A (en) * | 1998-09-22 | 1999-12-14 | Borden Chemical, Inc. | Phenol-novolacs with improved optical properties |
-
2000
- 2000-02-11 MY MYPI20000479A patent/MY121469A/en unknown
- 2000-02-15 AT AT00906338T patent/ATE258942T1/de not_active IP Right Cessation
- 2000-02-15 EP EP00906338A patent/EP1183294B1/en not_active Expired - Lifetime
- 2000-02-15 ES ES00906338T patent/ES2215026T3/es not_active Expired - Lifetime
- 2000-02-15 BR BR0008263-5A patent/BR0008263A/pt not_active Application Discontinuation
- 2000-02-15 AU AU28052/00A patent/AU2805200A/en not_active Abandoned
- 2000-02-15 CN CNB008038597A patent/CN1156504C/zh not_active Expired - Lifetime
- 2000-02-15 WO PCT/EP2000/001288 patent/WO2000049061A1/en active IP Right Grant
- 2000-02-15 KR KR10-2001-7010068A patent/KR100469199B1/ko active IP Right Grant
- 2000-02-15 DE DE60008100T patent/DE60008100T2/de not_active Expired - Lifetime
- 2000-02-22 TW TW089103046A patent/TWI262932B/zh not_active IP Right Cessation
- 2000-03-03 US US09/518,506 patent/US6608161B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP1183294B1 (en) | 2004-02-04 |
BR0008263A (pt) | 2001-11-06 |
CN1156504C (zh) | 2004-07-07 |
WO2000049061A1 (en) | 2000-08-24 |
AU2805200A (en) | 2000-09-04 |
ATE258942T1 (de) | 2004-02-15 |
ES2215026T3 (es) | 2004-10-01 |
KR100469199B1 (ko) | 2005-01-31 |
EP1183294A1 (en) | 2002-03-06 |
US6608161B1 (en) | 2003-08-19 |
DE60008100D1 (de) | 2004-03-11 |
DE60008100T2 (de) | 2004-11-18 |
MY121469A (en) | 2006-01-28 |
CN1340067A (zh) | 2002-03-13 |
TWI262932B (en) | 2006-10-01 |
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