KR20010071594A - 폴리카보네이트 및 그래프트 중합체를 포함하는 방염성성형 조성물 - Google Patents
폴리카보네이트 및 그래프트 중합체를 포함하는 방염성성형 조성물 Download PDFInfo
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- KR20010071594A KR20010071594A KR1020007014747A KR20007014747A KR20010071594A KR 20010071594 A KR20010071594 A KR 20010071594A KR 1020007014747 A KR1020007014747 A KR 1020007014747A KR 20007014747 A KR20007014747 A KR 20007014747A KR 20010071594 A KR20010071594 A KR 20010071594A
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- 239000003973 paint Substances 0.000 description 1
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- 125000005342 perphosphate group Chemical group 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
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- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
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- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920003245 polyoctenamer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920003246 polypentenamer Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- XRVCFZPJAHWYTB-UHFFFAOYSA-N prenderol Chemical compound CCC(CC)(CO)CO XRVCFZPJAHWYTB-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- RSNQKPMXXVDJFG-UHFFFAOYSA-N tetrasiloxane Chemical compound [SiH3]O[SiH2]O[SiH2]O[SiH3] RSNQKPMXXVDJFG-UHFFFAOYSA-N 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/14—Macromolecular materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/5399—Phosphorus bound to nitrogen
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
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- C—CHEMISTRY; METALLURGY
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- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
- C08L69/005—Polyester-carbonates
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- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/22—Thermoplastic resins
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- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
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- Fireproofing Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Description
1 | 2 | 3 | 4(비교) | |
성분 (중량부)A | 66.7 | 66.7 | 66.7 | 66.7 |
B.1 | 7.3 | - | - | - |
B.2 | - | 7.3 | - | - |
B.3 | - | - | 7.3 | - |
B.4 | - | - | - | 7.3 |
C | 9.4 | 9.4 | 9.4 | 9.4 |
D | 12.0 | 12.0 | 12.0 | 12.0 |
E | 4.2 | 4.2 | 4.2 | 4.2 |
이형제 | 0.4 | 0.4 | 0.4 | 0.4 |
특성ak (ISO 180/1A) (kJ/㎡) | 61 | 61 | 64 | 51 |
비스캣 B120 (ISO 306) (℃) | 107 | 107 | 108 | 103 |
ESC 특성파단 at el.= 2.4% (분:초) | 7:30 | 5:50 | 9:10 | 4:20 |
UL 94V 1.6 ㎜ | V-0 | V-0 | V-0 | V-0 |
Claims (12)
- A) 폴리카보네이트 및(또는) 폴리에스테르-카보네이트,B) 그래프트 기재로서 실리콘 고무, EP(D)M 고무 및 아크릴레이트 고무로 이루어진 군으로부터 선택되는 하나 이상의 고무-탄성 그래프트 중합체,C) 비닐 (공)중합체 및 폴리알킬렌 테레프탈레이트로 이루어진 군으로부터 선택되는 하나 이상의 열가소성 중합체, 및D) 하기 화학식 Ia 및 Ib의 포스파젠으로 이루어진 군으로부터 선택되는 하나 이상의 포스파젠을 포함하는 열가소성 성형 조성물.<화학식 Ia><화학식 Ib>상기식에서,R은 각각의 경우에 동일하거나 상이하며, 아미노, 각각의 경우에 임의로 할로겐화된 C1- 내지 C8-알킬 또는 C1- 내지 C8-알콕시, 또는 각각의 경우에 알킬로 임의로 치환된 C5-C6-시클로알킬, C6-C20-아릴 또는 C7-C12-아르알킬 및(또는) 할로겐을 나타내고;k는 0 또는 1 내지 15의 수를 나타낸다.
- 제 1 항에 있어서, 성분 A 40 내지 99 중량부, 성분 B 0.5 내지 60 중량부, 성분 C 0 내지 45 중량부, 성분 D 0.1 내지 50 중량부, 및 불소화된 폴리올레핀 0.05 내지 5 중량부를 포함하는 성형 조성물.
- 제 1 항 또는 2 항에 있어서, 성분 B)가 B.2) 실리콘 고무, 아크릴레이트 고무 및 EP(D)M 고무로 이루어진 군으로부터 선택되며 유리전이온도가 10℃ 미만인 하나 이상의 그래프트 기재 5 내지 95 중량% 상의 B.1) 하나 이상의 비닐 단량체 5 내지 95 중량%의 하나 이상의 그래프트 중합체를 포함하는 성형 조성물.
- 제 3 항에 있어서, 비닐 단량체 B.1)이 B.1.1) 비닐방향족 화합물 및(또는) 핵 상에서 치환된 비닐방향족 화합물 및(또는) 메타크릴산 (C1-C8)-알킬 에스테르 50 내지 99 중량부 및 B.1.2) 비닐시아나이드, (메트)아크릴산 (C1-C8)-알킬 에스테르 및(또는) 불포화 카복실산의 유도체 1 내지 50 중량부인 성형 조성물.
- 제 4 항에 있어서, 단량체 B.1.1)이 단량체 스티렌, α-메틸스티렌 및 메틸메타크릴레이트 중의 적어도 하나로부터 선택되며, 단량체 B.1.2)가 단량체 아크릴로니트릴, 말레산 무수물 및 메틸메타크릴레이트 중의 적어도 하나로부터 선택되는 성형 조성물.
- 제 1 항에 있어서, 성분 C.1)이 비닐방향족 화합물, 비닐시아나이드, (메트)아크릴산 (C1-C8)-알킬 에스테르, 불포화된 카복실산 및 불포화된 카복실산의 유도체로 이루어진 군으로부터 선택되는 하나 이상의 단량체의 비닐 (공)중합체인 성형 조성물.
- 제 1 항 내지 6 항 중 어느 한 항에 있어서, 윤활제 및 이형제, 핵생성제, 정전기방지제, 안정화제, 염료 및 안료로 이루어진 군으로부터 선택되는 하나 이상의 첨가제를 포함하는 성형 조성물.
- 제 1 항 내지 7 항 중 어느 한 항에 있어서, 성분 D와는 상이한 방염제를 포함하는 성형 조성물.
- 성분 A 내지 E 및 임의의 첨가제를 혼합하고, 혼합물을 용융배합함을 특징으로하는, 제 1 항 내지 8 항 중 어느 한 항에 따른 성형 조성물을 제조하는 방법.
- 성형품의 제조를 위한 제 1 항 내지 8 항 중 어느 한 항에 따른 성형 조성물의 용도.
- 제 1 항 내지 8 항 중 어느 한 항에 따른 성형 조성물로부터 제조된 성형품 또는 성형물.
- 제 11 항에 따른 하우징(Housing) 부품.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DE19828539.6 | 1998-06-26 | ||
DE19828539A DE19828539A1 (de) | 1998-06-26 | 1998-06-26 | Flammwidrige Formmassen enthaltend Polycarbonat und Pfropfpolymerisate |
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KR20010071594A true KR20010071594A (ko) | 2001-07-28 |
KR100584072B1 KR100584072B1 (ko) | 2006-05-29 |
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KR1020007014747A KR100584072B1 (ko) | 1998-06-26 | 1999-06-12 | 폴리카보네이트 및 그래프트 중합체를 포함하는 방염성성형 조성물 |
Country Status (12)
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US (1) | US6433082B1 (ko) |
EP (1) | EP1196498B1 (ko) |
JP (1) | JP4246392B2 (ko) |
KR (1) | KR100584072B1 (ko) |
CN (1) | CN1198870C (ko) |
AR (1) | AR016997A1 (ko) |
AU (1) | AU4512399A (ko) |
BR (1) | BR9912222A (ko) |
CA (1) | CA2335958A1 (ko) |
DE (2) | DE19828539A1 (ko) |
HK (1) | HK1039256A1 (ko) |
WO (1) | WO2000000030A1 (ko) |
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KR100422778B1 (ko) * | 2001-09-03 | 2004-03-12 | 제일모직주식회사 | 난연성 열가소성 수지조성물 |
KR100427531B1 (ko) * | 2001-09-13 | 2004-04-30 | 제일모직주식회사 | 난연성 열가소성 수지 조성물 |
KR100431020B1 (ko) * | 2001-04-30 | 2004-05-10 | 제일모직주식회사 | 난연성 폴리카보네이트계 열가소성 수지 조성물 |
KR20150023463A (ko) * | 2012-05-24 | 2015-03-05 | 사빅 글로벌 테크놀러지스 비.브이. | 난연성 폴리카보네이트 조성물, 이의 제조 방법 및 이를 포함하는 물품 |
KR20150093753A (ko) * | 2012-12-07 | 2015-08-18 | 바이엘 머티리얼사이언스 아게 | 난연성 폴리카르보네이트 성형 물질 vi |
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DE19941823A1 (de) * | 1999-09-02 | 2001-03-08 | Bayer Ag | Flammwidrige Polycarbonat-Blends |
EP1167448A3 (en) * | 2000-06-28 | 2002-05-15 | Idemitsu Petrochemical Co., Ltd. | Polycarbonate resin composition and shaped article |
JP2002322478A (ja) * | 2001-04-24 | 2002-11-08 | Chemiprokasei Kaisha Ltd | 難燃剤、それを含む難燃性樹脂組成物および成形品 |
DE10152318A1 (de) * | 2001-10-26 | 2003-05-08 | Bayer Ag | Schlagzähmodifizierte flammwidrig ausgerüstete Polycarbonat-Formmassen |
EP1500682A4 (en) * | 2002-04-30 | 2006-09-27 | Kaneka Corp | POLYORGANOSILOXAN-CONTAINING PFROPOPOPOLYMER COMPOSITION |
KR101148691B1 (ko) * | 2004-09-17 | 2012-05-25 | 도레이 카부시키가이샤 | 수지 조성물 및 이것으로 이루어지는 성형품 |
JP2008274365A (ja) * | 2007-05-01 | 2008-11-13 | Shin Etsu Chem Co Ltd | Si含有膜形成材料、Si含有膜及びその製造方法、並びに半導体デバイス |
US9023922B2 (en) | 2012-05-24 | 2015-05-05 | Sabic Global Technologies B.V. | Flame retardant compositions, articles comprising the same and methods of manufacture thereof |
CA2893886A1 (en) | 2012-12-07 | 2014-06-12 | Bayer Materialscience Ag | Flame-retardant polycarbonate molding materials i |
MX2015007081A (es) | 2012-12-07 | 2015-09-28 | Bayer Materialscience Ag | Compuestos ii de moldeo de policarbonato ignifugos. |
US9637634B2 (en) | 2012-12-07 | 2017-05-02 | Covestro Deutschland Ag | Flame-retardant polycarbonate molding materials V |
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MX2022014287A (es) | 2020-05-13 | 2022-12-07 | Covestro Deutschland Ag | Composicion de policarbonato retardante de llama. |
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US4111883A (en) * | 1976-12-16 | 1978-09-05 | General Electric Company | Plasticized polycarbonate composition |
DE3913114A1 (de) * | 1989-04-21 | 1990-10-25 | Bayer Ag | Waermeformbestaendige polycarbonat-formmassen |
JPH06211610A (ja) | 1993-04-01 | 1994-08-02 | Ishihara Sangyo Kaisha Ltd | 水田除草用組成物及び錠剤 |
JPH07292233A (ja) * | 1994-04-27 | 1995-11-07 | Denki Kagaku Kogyo Kk | 難燃性樹脂組成物 |
CZ293254B6 (cs) | 1995-02-24 | 2004-03-17 | Basf Aktiengesellschaft | Pyrazolylbenzoylový derivát, způsob jeho přípravy, herbicidní prostředek s jeho obsahem a způsob potírání nežádoucích rostlin |
EP0728811B1 (en) | 1995-02-27 | 2003-09-17 | Mitsubishi Chemical Corporation | Flame retardant thermoplastic resin composition |
WO1997023135A1 (fr) | 1995-12-25 | 1997-07-03 | Idemitsu Kosan Co., Ltd. | Composition herbicide |
DE19615230A1 (de) | 1996-04-18 | 1997-10-23 | Basf Ag | Flammgeschützte thermoplastische Formmassen |
ATE264856T1 (de) | 1996-04-26 | 2004-05-15 | Nippon Soda Co | Heterocyclisch substituierte benzolderivate und herbizide |
DE19616968A1 (de) | 1996-04-27 | 1997-11-06 | Daimler Benz Ag | Polymerisierbares Phosphazenderivat, Verfahren zu dessen Herstellung und dessen Verwendung |
DE19650563A1 (de) * | 1996-12-05 | 1998-06-10 | Basf Ag | Flammwidrige thermoplastische Formmassen |
WO1998028981A1 (fr) | 1996-12-27 | 1998-07-09 | Nippon Soda Co., Ltd. | Composition herbicide |
-
1998
- 1998-06-26 DE DE19828539A patent/DE19828539A1/de not_active Withdrawn
-
1999
- 1999-06-12 JP JP2000556624A patent/JP4246392B2/ja not_active Expired - Fee Related
- 1999-06-12 AU AU45123/99A patent/AU4512399A/en not_active Abandoned
- 1999-06-12 CA CA002335958A patent/CA2335958A1/en not_active Abandoned
- 1999-06-12 CN CNB998079286A patent/CN1198870C/zh not_active Expired - Lifetime
- 1999-06-12 US US09/720,334 patent/US6433082B1/en not_active Expired - Lifetime
- 1999-06-12 WO PCT/EP1999/004058 patent/WO2000000030A1/de active IP Right Grant
- 1999-06-12 KR KR1020007014747A patent/KR100584072B1/ko not_active IP Right Cessation
- 1999-06-12 EP EP99927965A patent/EP1196498B1/de not_active Expired - Lifetime
- 1999-06-12 BR BR9912222-7A patent/BR9912222A/pt not_active IP Right Cessation
- 1999-06-12 DE DE59911210T patent/DE59911210D1/de not_active Expired - Lifetime
- 1999-06-25 AR ARP990103072A patent/AR016997A1/es not_active Application Discontinuation
-
2002
- 2002-02-01 HK HK02100800.8A patent/HK1039256A1/zh unknown
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100431020B1 (ko) * | 2001-04-30 | 2004-05-10 | 제일모직주식회사 | 난연성 폴리카보네이트계 열가소성 수지 조성물 |
KR100422778B1 (ko) * | 2001-09-03 | 2004-03-12 | 제일모직주식회사 | 난연성 열가소성 수지조성물 |
KR100427531B1 (ko) * | 2001-09-13 | 2004-04-30 | 제일모직주식회사 | 난연성 열가소성 수지 조성물 |
KR20150023463A (ko) * | 2012-05-24 | 2015-03-05 | 사빅 글로벌 테크놀러지스 비.브이. | 난연성 폴리카보네이트 조성물, 이의 제조 방법 및 이를 포함하는 물품 |
KR20150023453A (ko) * | 2012-05-24 | 2015-03-05 | 사빅 글로벌 테크놀러지스 비.브이. | 난연제 폴리카보네이트 조성물, 이것의 제조 방법 및 그것을 포함하는 물품 |
KR20150093753A (ko) * | 2012-12-07 | 2015-08-18 | 바이엘 머티리얼사이언스 아게 | 난연성 폴리카르보네이트 성형 물질 vi |
Also Published As
Publication number | Publication date |
---|---|
EP1196498A1 (de) | 2002-04-17 |
CA2335958A1 (en) | 2000-01-06 |
JP2002519444A (ja) | 2002-07-02 |
AU4512399A (en) | 2000-01-17 |
DE59911210D1 (de) | 2005-01-05 |
HK1039256A1 (zh) | 2002-04-19 |
BR9912222A (pt) | 2001-04-24 |
CN1307447A (zh) | 2001-08-08 |
AR016997A1 (es) | 2001-08-01 |
WO2000000030A1 (de) | 2000-01-06 |
DE19828539A1 (de) | 1999-12-30 |
JP4246392B2 (ja) | 2009-04-02 |
CN1198870C (zh) | 2005-04-27 |
EP1196498B1 (de) | 2004-12-01 |
WO2000000030A9 (de) | 2001-06-14 |
US6433082B1 (en) | 2002-08-13 |
KR100584072B1 (ko) | 2006-05-29 |
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