KR20010060425A - 착색투명 무기도료 조성물과 제조방법 및 조성물 코팅방법 - Google Patents
착색투명 무기도료 조성물과 제조방법 및 조성물 코팅방법 Download PDFInfo
- Publication number
- KR20010060425A KR20010060425A KR1019990060626A KR19990060626A KR20010060425A KR 20010060425 A KR20010060425 A KR 20010060425A KR 1019990060626 A KR1019990060626 A KR 1019990060626A KR 19990060626 A KR19990060626 A KR 19990060626A KR 20010060425 A KR20010060425 A KR 20010060425A
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- oxide
- colloidal
- water
- alcohol
- Prior art date
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 110
- 239000003973 paint Substances 0.000 title claims description 34
- 238000004040 coloring Methods 0.000 title claims description 24
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 239000002131 composite material Substances 0.000 title claims description 5
- 239000011248 coating agent Substances 0.000 claims abstract description 85
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 70
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 65
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000001023 inorganic pigment Substances 0.000 claims abstract description 39
- 239000008199 coating composition Substances 0.000 claims abstract description 36
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000002612 dispersion medium Substances 0.000 claims abstract description 33
- 239000007787 solid Substances 0.000 claims abstract description 31
- 239000002245 particle Substances 0.000 claims abstract description 29
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 18
- 239000002253 acid Substances 0.000 claims abstract description 17
- 239000000084 colloidal system Substances 0.000 claims abstract description 16
- 230000007062 hydrolysis Effects 0.000 claims abstract description 15
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims abstract description 12
- 239000003054 catalyst Substances 0.000 claims abstract description 8
- 125000000962 organic group Chemical group 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 45
- 238000000034 method Methods 0.000 claims description 33
- 239000010936 titanium Substances 0.000 claims description 16
- 239000011651 chromium Substances 0.000 claims description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 14
- 150000004767 nitrides Chemical class 0.000 claims description 14
- 239000000243 solution Substances 0.000 claims description 14
- -1 aliphatic alcohols Chemical class 0.000 claims description 13
- 239000011259 mixed solution Substances 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 11
- 239000011701 zinc Substances 0.000 claims description 11
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 150000007522 mineralic acids Chemical class 0.000 claims description 5
- 150000007524 organic acids Chemical class 0.000 claims description 5
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 4
- 239000005751 Copper oxide Substances 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 4
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 4
- 229910000431 copper oxide Inorganic materials 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- 235000019253 formic acid Nutrition 0.000 claims description 3
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical group CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 3
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 claims description 3
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 claims description 3
- KSCAZPYHLGGNPZ-UHFFFAOYSA-N 3-chloropropyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)CCCCl KSCAZPYHLGGNPZ-UHFFFAOYSA-N 0.000 claims description 2
- OXYZDRAJMHGSMW-UHFFFAOYSA-N 3-chloropropyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCCCl OXYZDRAJMHGSMW-UHFFFAOYSA-N 0.000 claims description 2
- 239000005711 Benzoic acid Substances 0.000 claims description 2
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 2
- 235000011054 acetic acid Nutrition 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 235000010233 benzoic acid Nutrition 0.000 claims description 2
- CXKCTMHTOKXKQT-UHFFFAOYSA-N cadmium oxide Inorganic materials [Cd]=O CXKCTMHTOKXKQT-UHFFFAOYSA-N 0.000 claims description 2
- CFEAAQFZALKQPA-UHFFFAOYSA-N cadmium(2+);oxygen(2-) Chemical compound [O-2].[Cd+2] CFEAAQFZALKQPA-UHFFFAOYSA-N 0.000 claims description 2
- 229910000423 chromium oxide Inorganic materials 0.000 claims description 2
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 2
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 2
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 claims description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 2
- 235000011007 phosphoric acid Nutrition 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 2
- 229910052723 transition metal Inorganic materials 0.000 claims description 2
- 150000003624 transition metals Chemical class 0.000 claims description 2
- DENFJSAFJTVPJR-UHFFFAOYSA-N triethoxy(ethyl)silane Chemical compound CCO[Si](CC)(OCC)OCC DENFJSAFJTVPJR-UHFFFAOYSA-N 0.000 claims description 2
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 claims description 2
- 229910000859 α-Fe Inorganic materials 0.000 claims description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims 2
- PBHRBFFOJOXGPU-UHFFFAOYSA-N cadmium Chemical compound [Cd].[Cd] PBHRBFFOJOXGPU-UHFFFAOYSA-N 0.000 claims 2
- MTEZSDOQASFMDI-UHFFFAOYSA-N 1-trimethoxysilylpropan-1-ol Chemical compound CCC(O)[Si](OC)(OC)OC MTEZSDOQASFMDI-UHFFFAOYSA-N 0.000 claims 1
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims 1
- 229910018185 Al—Co Inorganic materials 0.000 claims 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims 1
- 229910004349 Ti-Al Inorganic materials 0.000 claims 1
- 229910004692 Ti—Al Inorganic materials 0.000 claims 1
- 235000005985 organic acids Nutrition 0.000 claims 1
- 239000007800 oxidant agent Substances 0.000 claims 1
- 150000003568 thioethers Chemical class 0.000 claims 1
- JPMBLOQPQSYOMC-UHFFFAOYSA-N trimethoxy(3-methoxypropyl)silane Chemical compound COCCC[Si](OC)(OC)OC JPMBLOQPQSYOMC-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 26
- 239000011521 glass Substances 0.000 abstract description 17
- 239000000123 paper Substances 0.000 abstract description 17
- 229910052751 metal Inorganic materials 0.000 abstract description 16
- 239000002184 metal Substances 0.000 abstract description 16
- 239000004033 plastic Substances 0.000 abstract description 11
- 229920003023 plastic Polymers 0.000 abstract description 11
- 239000000126 substance Substances 0.000 abstract description 7
- 150000002739 metals Chemical class 0.000 abstract description 4
- 238000001723 curing Methods 0.000 description 16
- 238000002845 discoloration Methods 0.000 description 16
- 229910052782 aluminium Inorganic materials 0.000 description 15
- 238000012360 testing method Methods 0.000 description 15
- 239000010935 stainless steel Substances 0.000 description 14
- 229910001220 stainless steel Inorganic materials 0.000 description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 13
- 230000000694 effects Effects 0.000 description 10
- 239000000758 substrate Substances 0.000 description 10
- 230000000704 physical effect Effects 0.000 description 9
- 238000005238 degreasing Methods 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 238000002203 pretreatment Methods 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000975 dye Substances 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 238000005498 polishing Methods 0.000 description 6
- 230000005855 radiation Effects 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- 239000003086 colorant Substances 0.000 description 5
- 239000011737 fluorine Substances 0.000 description 5
- 229910052731 fluorine Inorganic materials 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- 238000010998 test method Methods 0.000 description 5
- 229910052725 zinc Inorganic materials 0.000 description 5
- 229910000838 Al alloy Inorganic materials 0.000 description 4
- 229910001200 Ferrotitanium Inorganic materials 0.000 description 4
- 230000005856 abnormality Effects 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000003377 acid catalyst Substances 0.000 description 3
- 238000004220 aggregation Methods 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000004566 building material Substances 0.000 description 3
- 235000011089 carbon dioxide Nutrition 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 239000007769 metal material Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 230000004224 protection Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 150000004763 sulfides Chemical class 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 235000010724 Wisteria floribunda Nutrition 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- FRLJSGOEGLARCA-UHFFFAOYSA-N cadmium sulfide Chemical class [S-2].[Cd+2] FRLJSGOEGLARCA-UHFFFAOYSA-N 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000007809 chemical reaction catalyst Substances 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000010411 cooking Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- 239000005357 flat glass Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000012860 organic pigment Substances 0.000 description 2
- 238000000053 physical method Methods 0.000 description 2
- 238000005240 physical vapour deposition Methods 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- 235000008247 Echinochloa frumentacea Nutrition 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 229920004142 LEXAN™ Polymers 0.000 description 1
- 239000004418 Lexan Substances 0.000 description 1
- 240000004072 Panicum sumatrense Species 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000032900 absorption of visible light Effects 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- YJVBLROMQZEFPA-UHFFFAOYSA-L acid red 26 Chemical compound [Na+].[Na+].CC1=CC(C)=CC=C1N=NC1=C(O)C(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=CC=C12 YJVBLROMQZEFPA-UHFFFAOYSA-L 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 238000002048 anodisation reaction Methods 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000005524 ceramic coating Methods 0.000 description 1
- NCEXYHBECQHGNR-UHFFFAOYSA-N chembl421 Chemical compound C1=C(O)C(C(=O)O)=CC(N=NC=2C=CC(=CC=2)S(=O)(=O)NC=2N=CC=CC=2)=C1 NCEXYHBECQHGNR-UHFFFAOYSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 238000009503 electrostatic coating Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 description 1
- 238000013035 low temperature curing Methods 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- QDVXOTZUGXHBAO-UHFFFAOYSA-N methoxy(dipropyl)silane Chemical compound CCC[SiH](OC)CCC QDVXOTZUGXHBAO-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 230000000191 radiation effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229910001256 stainless steel alloy Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000005341 toughened glass Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
- 239000011882 ultra-fine particle Substances 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
- C08K3/11—Compounds containing metals of Groups 4 to 10 or of Groups 14 to 16 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/28—Nitrogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/80—Processes for incorporating ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3009—Sulfides
- C08K2003/3027—Sulfides of cadmium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Description
Claims (13)
- 오르가노알콕실란의 가수분해물 및 축합물로 환산하여 0.7∼41.7중량%;물 또는 알코올을 분산매로하는 평균입자크기가 5∼100m㎛ 인 콜로이드 지르코니아를 고형분으로 환산하여 0.27∼18.6중량%;물 또는 알코올을 분산매로하는 평균입자크기가 5∼100m㎛ 인 콜로이드 알루미나를 고형분으로 환산하여 0.02∼3.8중량%;물 또는 알코올을 분산매로하는 평균입자크기가 5∼300m㎛ 인 콜로이드 무기안료를 고형분으로 환산하여 0.02∼27.9중량%;상기 물을 분산매로한 콜로이드 지르코니아·콜로이드 알루미나·콜로이드 무기안료에 함유된 물을 포함하여 물 0.6∼45.4중량%;상기 오르가노알콕실란에 함유된 알코올과 상기 알코올을 분산매로한 콜로이드 지르코니아·콜로이드 알루미나·콜로이드 무기안료에 함유된 저급지방족 알코올을 포함하여 저급지방족 알코올 15.9∼95.4중량%;가수분해 촉매로 사용되는 산 0.01∼3 중량%를 포함하여 이루어진 것을 특징으로 하는 착색투명 무기도료 조성물.
- 제 1 항에 있어서;상기 오르가노 알콜실란은 메틸트리메톡실란, 메틸트리에톡실란, 에틸트리메톡실란, 에틸트리에톡실란, n-프로필트리에톡실란, i-프로필트리메톡실란, n-프로필트리에톡실란, γ-클로로프로필트리메톡실란, γ-클로로프로필트리에톡실란, 비닐트리메톡실란, 비닐트리에톡실란, 3.3.3-트리플로로프로필트리메톡실란, γ-그리시드키시프로필트리메톡실란, γ-메타크록시프로필트리메톡실란,γ-메카프트프로필트리메톡실란, 페닐트리메톡실란, γ-아미노프로필트리메톡실란, 3.4-에폭시시클로헥실에틸트리메톡실란 중 선택하여 1종 또는 2종 이상을 병용하여 사용하는 것을 특징으로 하는 착색투명 무기도료 조성물.
- 제 1 항에 있어서;상기 콜로이드 지르코니아 및 콜로이드 알루미나는 pH 2∼10 인 것을 특징으로 하는 착색투명 무기도료 조성물.
- 제 1 항에 있어서;상기 무기안료는 pH 2∼10 의 산화물, 질화물, 황화물, 카드늄화물 중에서 선택하여 1종 또는 2종이상의 화합물로 이루어진 것을 특징으로 하는 착색투명 무기도료 조성물.
- 제 4 항에 있어서;상기 산화물로써 단독산화물로는 TiO2(티타늄디옥사이드, anatase, rutile), ZnO(징크옥사이드, 아연화), CoO(산화코발트), Cr2O3(산화크롬), Fe3O4(페라이트), Fe2O3, FeO(산화 제일철, 산화제이철), CuO(산화구리) 등의 전이금속 단일 산화물과, (Cu·Cr)산화물, (Ti·Co)산화물, (T·Ni)산화물, (Al·Co)산화물, (Co·P)산화물, (Cr·Al)산화물, (Cr·Sn)산화물, (Fe·Zr)산화물, (Fe·Zn)산화물, (Fe·Cr·Zn)산화물, (Fe·Co·Cr)산화물, (Co·Cr·Al)산화물, (Ti·Fe·Zn)산화물, (Cr·Cu·Mn)산화물, (Ti·Ni·Co)산화물, (Fe·Cr·Al·Zn)산화물, (Ti·Ni·Co·Al)산화물 등의 2~4종 복합 산화물 중 선택하여 사용하는 것을 특징으로 하는 착색투명 무기도료 조성물.
- 제 4 항에 있어서;상기 질화물은 Ti질화물, Zr질화물 등의 단독 질화물과, (Ti·Al)질화물, (Ti·Al·C)질화물등의 2∼3 종 복합 질화물 중 선택하여 사용하는 것을 특징으로 하는 착색투명 무기도료 조성물
- 제 4 항에 있어서;상기 황화물은 (Cd·Zn)황화물 인 것을 특징으로 하는 착색투명 무기도료 조성물.
- 상기 제 4 항에 있어서;상기 카드늄화물은 (S·Se)카드늄화물인 것을 특징으로 하는 착색투명 무기도료 조성물.
- 제 1 항에 있어서;상기 산은 무기산 또는 유기산을 1종 또는 2종이상 병용하여 사용하는 것을 특징으로 하는 착색투명 무기도료 조성물.
- 제 1 항 또는 제 9 항에 있어서;상기 산은 염산, 황산, 질산, 인산, 개미산, 초산, 안식향산, 파라톨루엔술폰산, 구엔산 중에서 선택하여 사용하는 것을 특징으로 하는 착색투명 무기도료 조성물.
- 가수분해물 및 축합물로 환산하여 0.7∼41.7중량%인 오르가노알콕실란과, 알코올을 분산매로하고 고형분으로 환산하여 0.02∼27.9중량%이며 평균입경이 5~300m㎛인 콜로이드 무기안료를 교반·혼합하는 a 단계와,물을 분산매로하는 고형분으로 환산하여 0.27∼18.6중량%이며 평균입경이 5~100m㎛인 콜로이드 지르코니아, 물을 분산매로하는 고형분으로 환산하여 0.02∼3.8중량%이며 평균입경이 5~100m㎛인 콜로이드 알루미나, 상기 물을 분산매로한 콜로이드 지르코니아·콜로이드 알루미나가 함유한 물을 포함하여 물 0.6∼45.4중량%, 상기 콜로이드 지르코니아·콜로이드 알루미나가 함유한 산을 포함하여 0.01∼3 중량% 의 산을 반응촉매로 첨가하여 교반·혼합하는 b 단계와,상기 b 단계에 의해 제조된 액을 교반하면서 a 단계에 의해 제조된 액을 적하·반응하고, 반응 종료후 약 30~90분 교반을 유지하는 c 단계와,상기 c 단계에 의해 제조된 액을 코팅방법에 따라 저급지방족 알코올 15.9∼95.4중량%을 넣은 후 밀봉하고, 상온(25℃)에서 1시간 ~24시간 숙성하는 d 단계를 통해, 오르가노알콕실란의 가수분해물 및 축합물로 환산하여 0.7∼41.7중량%; 평균입자크기가 5∼100m㎛ 인 콜로이드 지르코니아를 고형분으로 환산하여 0.27∼18.6중량%; 평균입자크기가 5∼100m㎛ 인 콜로이드 알루미나를 고형분으로 환산하여 0.02∼3.8중량%; 평균입자크기가 5∼300m㎛ 인 콜로이드 무기안료를 고형분으로 환산하여 0.02∼27.9중량%; 물 0.6∼45.4중량%; 저급지방족 알코올 15.9∼95.4중량%; 가수분해 촉매로 사용되는 산 0.01∼3 중량% 로 이루어지도록한 것을 특징으로 하는 착색투명 무기도료 조성물 제조방법.
- 제 11 항에 있어서;상기 b 단계의 혼합액은 pH 2∼7 인 것을 특징으로 하는 착색투명 무기도료 조성물 제조방법.
- 오르가노알콕실란의 가수분해물 및 축합물로 환산하여 0.7∼41.7중량%;물 또는 알코올을 분산매로하는 평균입자크기가 5∼100m㎛ 인 콜로이드 지르코니아를 고형분으로 환산하여 0.27∼18.6중량%;물 또는 알코올을 분산매로하는 평균입자크기가 5∼100m㎛ 인 콜로이드 알루미나를 고형분으로 환산하여 0.02∼3.8중량%;물 또는 알코올을 분산매로하는 평균입자크기가 5∼300m㎛ 인 콜로이드 무기안료를 고형분으로 환산하여 0.02∼27.9중량%;상기 물을 분산매로한 콜로이드 지르코니아·콜로이드 알루미나·콜로이드 무기안료에 함유된 물을 포함하여 물 0.6∼45.4중량%;상기 오르가노알콕실란에 함유된 알코올과 상기 알코올을 분산매로 한 콜로이드 지르코니아·콜로이드 알루미나·콜로이드 무기안료에 함유된 저급지방족 알코올을 포함하여 저급지방족 알코올 15.9∼95.4중량%;가수분해 촉매로 사용되는 산 0.01∼3 중량%를 포함하여 이루어진 착색투명 무기도료 조성물을 도포하는 것을 특징으로 하는 착색투명 무기도료 조성물을 이용한 코팅방법.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-1999-0060626A KR100374172B1 (ko) | 1999-12-22 | 1999-12-22 | 착색투명 무기도료 조성물과 제조방법 및 조성물 코팅방법 |
JP2000117112A JP3621626B2 (ja) | 1999-12-22 | 2000-04-18 | 着色透明無機塗料組成物とその製造方法及び組成物コーティング方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-1999-0060626A KR100374172B1 (ko) | 1999-12-22 | 1999-12-22 | 착색투명 무기도료 조성물과 제조방법 및 조성물 코팅방법 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20010060425A true KR20010060425A (ko) | 2001-07-07 |
KR100374172B1 KR100374172B1 (ko) | 2003-03-03 |
Family
ID=19628347
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR10-1999-0060626A KR100374172B1 (ko) | 1999-12-22 | 1999-12-22 | 착색투명 무기도료 조성물과 제조방법 및 조성물 코팅방법 |
Country Status (2)
Country | Link |
---|---|
JP (1) | JP3621626B2 (ko) |
KR (1) | KR100374172B1 (ko) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100887724B1 (ko) | 2008-01-07 | 2009-03-12 | 주식회사 미지나노텍 | 음이온 투명도료 및 그 제조방법 |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3919000B2 (ja) * | 2002-07-30 | 2007-05-23 | 信越化学工業株式会社 | 非汚染性シリコーン樹脂系コーティング剤 |
KR101225818B1 (ko) | 2004-03-26 | 2013-01-24 | 유로케라 | 유리-세라믹 및 유리 플레이트, 가열 플레이트, 및제조방법 |
US7553519B2 (en) * | 2004-03-26 | 2009-06-30 | Eurokera | Glass-ceramic and glass plates, heating plates, and preparation |
US20070218028A1 (en) | 2004-04-07 | 2007-09-20 | Masanori Takai | Hair-Treating Agent And Methods Of Treating Hair |
JP2006063427A (ja) * | 2004-08-30 | 2006-03-09 | Takasago Tekko Kk | 耐テンパーカラー性の優れたステンレス鋼 |
KR100653402B1 (ko) | 2005-01-18 | 2006-12-01 | T. Y. 라이팅(주) | 적외선 램프 착색제, 그의 제조방법, 및 그를 사용하는착색방법 |
KR100633177B1 (ko) * | 2005-03-24 | 2006-10-12 | 김정하 | pH 조절을 이용한 상온건조 무기도료 조성물과 그제조방법 및 용도 |
JP2007238950A (ja) * | 2007-03-30 | 2007-09-20 | Univ Nihon | 硬化体 |
KR100941954B1 (ko) * | 2007-06-22 | 2010-02-11 | 대한화인세라믹 주식회사 | 비점착성 코팅 조성물,그 코팅방법,그로 코팅된 패널 및가열조리기기 |
KR100908455B1 (ko) * | 2008-10-14 | 2009-07-20 | 김태웅 | 비점착성 도료의 조성물 및 그 제조방법 |
CN106634063B (zh) * | 2015-07-24 | 2019-03-19 | 广东骏丰频谱股份有限公司 | 一种耐高温远红外涂料及其制备方法和应用 |
US11939490B2 (en) * | 2017-07-31 | 2024-03-26 | Momentive Performance Materials Inc. | Curable surface-protective coating composition, processes for its preparation and application to a metallic substrate and resulting coated metallic substrate |
US11370937B2 (en) * | 2019-03-04 | 2022-06-28 | Momentive Performance Materials Inc. | Protective coating composition and coated metallic substrate comprising same |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6232157A (ja) * | 1985-08-02 | 1987-02-12 | Yoshio Ichikawa | コ−テイング用組成物 |
JP2619241B2 (ja) * | 1986-08-14 | 1997-06-11 | 日本合成ゴム株式会社 | コーティング用組成物 |
JPS6456773A (en) * | 1987-08-28 | 1989-03-03 | Japan Synthetic Rubber Co Ltd | Coating composition |
JPH08295844A (ja) * | 1995-04-25 | 1996-11-12 | Sekisui Chem Co Ltd | 被覆用組成物及び積層体の製造方法 |
JPH11293197A (ja) * | 1998-02-13 | 1999-10-26 | Nippon Arc Kk | アクリル系樹脂成型品用耐擦傷性被覆組成物 |
KR100307190B1 (ko) * | 1998-07-31 | 2001-12-28 | 김정하 | 무기도료조성물과그제조방법및용도 |
-
1999
- 1999-12-22 KR KR10-1999-0060626A patent/KR100374172B1/ko active IP Right Grant
-
2000
- 2000-04-18 JP JP2000117112A patent/JP3621626B2/ja not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100887724B1 (ko) | 2008-01-07 | 2009-03-12 | 주식회사 미지나노텍 | 음이온 투명도료 및 그 제조방법 |
Also Published As
Publication number | Publication date |
---|---|
JP3621626B2 (ja) | 2005-02-16 |
JP2001181572A (ja) | 2001-07-03 |
KR100374172B1 (ko) | 2003-03-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR100374172B1 (ko) | 착색투명 무기도료 조성물과 제조방법 및 조성물 코팅방법 | |
EP2058374B1 (en) | Pearlescent pigment | |
US4731264A (en) | Sol-gel compositions containing silane and alumina | |
KR920004191B1 (ko) | 유기 알콕시 실란/금속 산화물의 중합 생성물과 이것의 코우팅 및 그 제조방법 | |
KR101302540B1 (ko) | 하드 코트층 형성용 조성물 및 광학 렌즈 | |
EP2213705B1 (en) | Bright Pigment | |
JP2007138053A (ja) | 光輝性顔料 | |
JP4907076B2 (ja) | 光学的に密な着色コーティングを有する透明無色なガラスまたはガラスセラミックパネル及び同パネルの製造方法 | |
CN103571255A (zh) | 核/壳型四方晶系氧化钛颗粒水分散液、制造方法、紫外线遮蔽性有机硅涂布组合物和涂覆物品 | |
EP0486469A1 (en) | Organic-inorganic hybrid polymer | |
JP2005290369A (ja) | 酸化チタンコーティング剤、及び酸化チタン塗膜形成方法 | |
WO2010143645A1 (ja) | 常温硬化性近赤外線遮蔽コーティング剤及びそれを用いた近赤外線遮蔽膜並びにその製造方法 | |
JP2019519458A (ja) | ガラスセラミックガラス物品及びこれを得るための方法 | |
JP2000072990A (ja) | 熱線遮蔽塗料 | |
KR20220160005A (ko) | 지르코니아 피복 산화티탄 미립자의 제조방법, 지르코니아 피복 산화티탄 미립자 및 그의 용도 | |
KR20090080644A (ko) | 플라스틱 렌즈용 하드코팅용액 및 그 제조방법 | |
EP1808465A1 (en) | A pearl pigment used for external outside | |
KR100307190B1 (ko) | 무기도료조성물과그제조방법및용도 | |
JP4896641B2 (ja) | 光輝性顔料 | |
KR20090006695A (ko) | 금속 표면용 세라믹 코팅제 및 이를 이용한 금속 표면의세라믹 코팅 방법 | |
KR101847785B1 (ko) | 가시광선이 투과하는 투명방음벽용 나노컬러 접합유리 제조 방법 | |
JP2594042B2 (ja) | 反射防止膜 | |
WO2019239808A1 (ja) | 光触媒複合材、サイネージ用ディスプレイ保護部材、タッチパネル用保護部材、太陽電池用保護部材、センサカバー用保護部材、サイネージ用ディスプレイ、タッチパネル、太陽電池、及び、センサカバー | |
TW201500188A (zh) | 玻璃片之搪瓷方法 | |
US20220195206A1 (en) | Doped alkali silicate protective layers on metal |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
E902 | Notification of reason for refusal | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
FPAY | Annual fee payment |
Payment date: 20130206 Year of fee payment: 11 |
|
FPAY | Annual fee payment |
Payment date: 20140204 Year of fee payment: 12 |
|
FPAY | Annual fee payment |
Payment date: 20160107 Year of fee payment: 14 |
|
FPAY | Annual fee payment |
Payment date: 20170203 Year of fee payment: 15 |
|
FPAY | Annual fee payment |
Payment date: 20180207 Year of fee payment: 16 |
|
FPAY | Annual fee payment |
Payment date: 20190116 Year of fee payment: 17 |