KR101724280B1 - Mixed coating material for anti-biofouling of submerged structures and coating method using the same - Google Patents

Mixed coating material for anti-biofouling of submerged structures and coating method using the same Download PDF

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KR101724280B1
KR101724280B1 KR1020150127633A KR20150127633A KR101724280B1 KR 101724280 B1 KR101724280 B1 KR 101724280B1 KR 1020150127633 A KR1020150127633 A KR 1020150127633A KR 20150127633 A KR20150127633 A KR 20150127633A KR 101724280 B1 KR101724280 B1 KR 101724280B1
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coating
paint
water
antifouling
present
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KR1020150127633A
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Korean (ko)
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KR20170030694A (en
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하준수
하대환
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주식회사 블루텍
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Priority to KR1020150127633A priority Critical patent/KR101724280B1/en
Priority to PCT/KR2016/010221 priority patent/WO2017043938A1/en
Priority to CN201680052277.6A priority patent/CN108026395A/en
Publication of KR20170030694A publication Critical patent/KR20170030694A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C09D5/1612—Non-macromolecular compounds
    • C09D5/1618—Non-macromolecular compounds inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C09D5/1637—Macromolecular compounds

Abstract

[0001] The present invention relates to a mixed coating for blushing of a water-immersion structure and a coating film method using the same, and more particularly to an antifouling coating composition comprising an epoxy-based binder, an antifouling functional additive, a curing agent and other auxiliaries, The present invention relates to a mixed paint for blending and a coating method which are improved in adhesion and abrasion resistance as compared with an antifouling paint for controlling the attachment of marine life due to an improvement in surface roughness and a longer service life than paint.
The blending paints for blushing according to the present invention exhibit more excellent antifouling performance not only by the components contained in the blending paints for blushing but also by the coating method. The coating method of the present invention can improve the surface roughness coefficient In order to form a homogeneous coating film, the coating is performed by spraying without air so as to prevent the inflow of condensed water or impurities. In the case of painting for maintenance of existing facilities, The alternative is to paint directly in water. The underwater painting method is characterized in that the blended mixed paint of the present invention is painted by using an underwater paint apparatus capable of automatically controlling the inflow of paint with a pressure paint storage tank, a painting brush, a connecting tube and a brush in water.

Description

TECHNICAL FIELD [0001] The present invention relates to a mixed coating material for an abrasion resistant structure and a coating method using the same,

The present invention relates to a mixed paint for blur prevention of a water-immersion structure and a coating film method using the same.

Industries that require large-scale water such as thermal power plants or steel mills are constructed in the coastal area to use the seawater in order to secure economical water, and pipes for the inflow and outflow of these water are installed in the coastal water in units of several km The cost of maintenance for maintenance of the material corrosion due to attachment of marine life (fouling) and the prevention of loss due to frictional resistance is being consumed. In other respects, even in the case of long-time voyages, the bottom of the ship is kept flooded, resulting in marine life adherence, resulting in an increase in resistance due to friction, resulting in a decrease in the speed of operation or a corresponding energy loss The problem is constantly occurring. In ships, it is known that fouling of 150kg fouls / m 2 occurs on the flooded area within 6 months. Such fouling causes an increase in hydraulic coefficient of friction (increase of migration resistance), resulting in a fuel consumption increase of about 40% Therefore, when considering only oil tankers, the annual consumption of about 72,000 tons / year of additional fuel causes about 210,000 tons of CO 2 and 5,600,000 tons of SO 2 per year, which is a cause of environmental pollution.

In order to control the effects of the fouling of marine infiltration facilities, a variety of functional paint-based technologies have been developed. However, since January 2003, the environmental risk of TBT (Tri Butyl Tin) The use of antifouling paints containing TBT compounds in the International Maritime Organization (IMO) has been limited. For the past decade, the market for alternative antioxidants has been rapidly expanding.

The prior art related to functional antifouling paints that replace antifouling paints containing TBT, a marine ecosystem disturbing environmental substance, has been proposed to include a biocide-functioning additive, such as ZnO or CuO, (Fig. 1) which performs the anti-fouling process (Fig. 1) and anti-fouling technology (Fig. 2) which prevents contamination by adjusting the surface tension by using a paint of hydrophobic material such as deformed silicone.

However, in the case of the former, inhomogeneous peeling phenomenon due to low adhesive strength occurs, and if maintenance problems and dirt are generated, the coated surface penetrates into the inside of the material and proceeds to corrosion. In the latter case, the occurrence of fouling is relatively delayed due to the hydrophobic property at the beginning, but when the fouling occurs, the fouling performance is the same as that of the general coating paint (Cho, Seung-Yun et al., 2012 Korean Society of Coastal and Environmental Energy Science)

As an example of the prior art for preventing biofouling (pollution), Korean Patent Laid-Open Publication No. 2008-0047589 discloses a metal salt containing a metal ion such as zinc, copper and silver, which is an antifouling ingredient, or a tributyl A technique relating to a ship anti-fouling coating composition relating to a biocide-functioning antifouling paint in which various anticorrosives selected from the group consisting of ultramethacrylate copolymer, tributyltin oxide and combinations thereof are combined with an organic medium is disclosed As an example of an antifouling paint and coating technique excluding TBT, Korean Patent Publication No. 2008-0041252 discloses a technique of applying a thermoplastic coating to the surface of a metal medium, a step of laminating a tie coat on the surface of the medium, A method of applying a thermoplastic coating comprising laminating a coat of a thermoplastic material on a tie coat, And a thermoplastic top coat using a polyamide as a hardening agent to provide a clean surface. Korean Patent No. 1489640 discloses an anti-corrosive composite antifouling coating layer of marine steel structure, In order to prevent the adhesion of marine organisms, it is necessary to form a fused composite coating layer on the surface of base material such as ship or offshore structure by coating a metal spray layer containing Zn-Al-Zr and an organic / inorganic hybrid layer. And low frictional resistance at the same time.

However, the conventional anti-fouling mechanism based on biocide function is a type of self-abrading antifouling coating film, and since the coating film is lost over time, the durability is very low, and therefore, maintenance is required from time to time. , And other types of antifouling technologies are paints that utilize the hydrophobic properties of paints as antifouling functions rather than biocide functions. They have less impact on marine ecosystems and relatively strong durability. However, Functional restoration is required due to the limitations of the coating application to other materials such as concrete and wood other than the material, and the adhesion strength between the coating material and the binder.

Various attempts have been made to solve the problem due to the contamination of the submerged structure, but no description has been made on the eco-friendly antifouling coating composition, antifouling coating film and coating film method according to the present invention.

SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned needs, and it is an object of the present invention to provide a mixed paint for blur prevention of a water immersion structure and a coating film method using the same, and to provide an antifouling coating film- The inventors of the present invention have completed the present invention by confirming that the occurrence of contamination is less than that of conventional products and that the adhering organisms can be easily peeled off from the surface of the product, the adhesion to the base material of the coating film is excellent, and the abrasion resistance is improved.

In order to attain the above object, the present invention provides a water-borne structure or an exterior blend paint for external blindness comprising an epoxy resin-based binder, a functional additive, a binder hardener and an auxiliary agent.

Further, the present invention comprises (a) a nozzle aperture with respect to the base material 0.019 ~ 0.029 inchi (inch), and the injection pressure of the epoxy coating material in 70 ~ 200kg / cm 2 of the conditions in the machine-pressure injection-free air at 10 ~ 20 ℃ manner A bottom coating step using a bottom coating;

(b) after the lower coating step of the step (a), drying for 6 to 8 hours; And

(c) a step of applying a top coat using the mixed paint for blasting according to the present invention after the step (b); and do.

The present invention also provides a water immersion structure or hull exterior painted by the painting method of the present invention.

The present invention relates to an antifouling composite coating material for a water-immersion structure, and a coating film method using the same, wherein the antifouling composite coating material of the present invention is environmentally friendly, has less occurrence of bio-fouling, It is possible to peel easily, so that the surface of the base material can be maintained in a clean state by easily removing the contamination.

In addition, since the surface of the water immersion structure can effectively maintain the initial surface characteristics of the water immersion structure after the adhered organisms are removed through the maintenance work of the water immersion structure, the service life of the water immersion structure can be prolonged, There is an advantage that maintenance costs can be minimized.

BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a view showing the action mechanism of a conventional biocide functional antifouling paint.
2 is a view showing a mechanism of action of a conventional hydrophobic surface-improving functional antifouling paint. A, B, and C are the spherical ratios of the water particle shape as the surface tension of the base material decreases and the decrease of the adhesion surface as the base material contact angle θ increases.
3 is a schematic view of an automatic painting apparatus.
4 is a bird's-eye view of the automatic painting machine.
Fig. 5 shows the result of the antifouling test according to the immersion time of the seawater of the paint sample.
6 is a view showing a pressure paint supply brush for underwater painting.
Figure 7 is a schematic view of an underwater painting operation.

The present invention relates to a water-borne structure or a water-borne mixed coating material on the outside of a watercraft including an epoxy resin-based binder, a functional additive, a binder curing agent and an auxiliary agent, wherein the epoxy resin-based binder is bisphenol A type or F type epoxy resin The functional additive may be selected from the group consisting of copper oxide (CuO), which performs a biocide function; As a water repellent paint, fluoropolymer and polyethylene powder, which can control the adhesion of marine life such as barnacle, by improving the surface roughness coefficient by lowering the surface energy, And fillers; , And it is more preferable to include polyethylene powder and a filler.

The binder curing agent is preferably a triethylenetetramine (TETA) or a Mannich-Base having an amine value of 300 to 400, but is not limited thereto. The triethylene tetramine (TETA) ) The hardener is used for external (exposure) coating, which is a typical atmospheric condition, and the ammonia-base hardener having an amine value of 300 to 400 is preferably used in underwater painting, but it is not limited thereto.

The adjuvant is a dispersant and a defoaming agent as a paint auxiliary agent that allows each component of the mixed paint to maintain physical properties and maintain a simple physical mixing state in the same phase rather than a chemical bond. Examples of preferred dispersants include , And BYK-065 is used as an example of a preferable antifoaming agent. However, the present invention is not limited thereto.

The material constituting the water immersion structure or the exterior of the hull is preferably made of any one material selected from the group consisting of iron, concrete, wood and FRP (fiber reinforced plastics), but is not limited thereto. The water repellency paint of the present invention or the outside of the hull according to the present invention has an effect of enhancing the adhesion to the base material and the abrasion resistance of the coating film compared to the case of using the existing similar function antifouling paint. As an example of the existing similar functional antifouling paints, an epoxy resin-based binder may be used, but the present invention is not limited thereto.

Further, the present invention comprises (a) a nozzle aperture with respect to the base material 0.019 ~ 0.029 inchi (inch), and the injection pressure of the epoxy coating material in 70 ~ 200kg / cm 2 of the conditions in the machine-pressure injection-free air at 10 ~ 20 ℃ manner A bottom coating step using a bottom coating;

(b) after the lower coating step of the step (a), drying for 6 to 8 hours; And

(c) a step of topcoating the mixture using the blending paint for blasting according to the present invention after the step (b). will be.

In the above coating method, in order to enhance the adhesiveness between the mixed coating material and the base material, an epoxy-based paint is applied to the bottom coat, and the blend-coating material according to the present invention is applied to the top coat ), Thereby realizing an antifouling treatment which is superior in antifouling performance and service life to the existing antifouling paint.

Table 1 shows an example of the standard mixed composition ratio of the antifouling paint components according to the present invention. The epoxy resin-based bottom coat and the basic binder resin for binding the antifouling functional component to the base material are bisphenol-A type F type epoxy resin together with an amine-based curing agent capable of curing a room temperature at room temperature.

It is preferable that the coating is formed so that the thickness of the coating film formed by the top coating is 150 to 300 mu m depending on the function or the importance of the base material. However, if the thickness of the coating film is less than 150 탆, there may be a peeling phenomenon with the undercoat. If the thickness exceeds 300 탆, it is not only unnecessarily thick but also difficult to uniformly coat.

The spraying device is preferably a device for automatically spraying the base material while controlling the thickness of the coating film, but is not limited thereto.

The coating for achieving the antifouling function by using the mixed liquid coating material blended in the composition of Table 1 may be performed by manual brushing according to the requirements of the material of the base material and the management life, but basically, But it is not limited to this, but it is preferable to apply external coating by using an automatic painting equipment as shown in FIG. 3 or a conventional automatic control type spraying apparatus so that dense painting can be performed for the realization of the function.

The painting according to the coating method of the present invention can be applied to an external (exposure) coating method in a production process of a new product and an existing on-site method of repairing and repainting a mother- (Exposure) paint) and an in-situ underwater painting that is directly applied in a flooded state.

The composition content of the antifouling paint according to the present invention  Detailed composition Composition ratio,% (v / v) bookbinder Epoxy resin (Bis-Phenol A or F Type) 55 to 65% Functional
additive Ascorbic acid (CuO) 10-30% PTFE-Modified Polyethylene Wax 3-10% Polyethylene powder 3-10% Filler (CaCO 3 ) 10-30% bookbinder
Hardener Triethylene Tetramine - for exterior coating 5-10% Hardener (Mannich-Base, Amine Value 300 ~ 400) - Underwater painting 5-10% varnish
Auxiliary material Dispersant (BYK P-104S) 0.5-1.0% Defoamer (BYK-065) 0.5-1.0%

The underwater coating in the present invention means that the coating is performed under saturated water soaking condition, unlike the case where the above-mentioned exposure coating is applied to the outside air condition with a relative humidity of 85% or less, Because of coating and maintenance, the adhesion of existing antifouling painted surfaces is very low. Therefore, it is preferable to remove the sand or unnecessary deposits by sandblasting or the like to uniformize the surface to a thickness of about 50 to 100 탆, and then perform coating, but the present invention is not limited thereto. When the antifouling coating is an underwater coating, it is preferable to use an underwater painting device capable of automatically controlling the inflow of the paint with the pressure paint storage tank, painting brush, connecting tube and brush as disclosed in Fig. 7 But is not limited to.

An example of the coating method of the present invention is an exposure coating method when the base material is a new product. In the same manner as the conventional antifouling coating, a top coat for coating a primer and a top coat for coating an antifouling functional coating, As shown in FIG. 3, the automatic painting is performed by the movable type spray nozzle on the base material mounted on the automatic coating apparatus, and the adhesion to the antifouling paint is evaluated in consideration of the composition of the antifouling functional paint to be used in the present invention. The epoxy resin is pre-coated with the epoxy resin. The top coat to perform the antifouling function is to be painted at 10 to 20 ° C for at least 5 hours after coating and then to be painted using a mobile paint system by replacing the paint tank shown in FIG. In order to prevent the inflow of air bubbles or impurities that may affect the roughness coefficient on the surface of the paint, the injection pump performs painting by spraying without air using mechanical pressure.

The underwater painting is performed by the underwater painting brush illustrated in FIG. 6. Specifically, the underwater painting operator supplies the antifouling paint supplied through the paint transfer pressure cable to the roller The roller brush for underwater work is rotated and the connected sense of rotation is operated so that the paint is automatically supplied through the paint conveying pressure cable through the signal received by the rotation sense cable, It is possible to efficiently perform the painting work while preventing the loss caused by the painting.

The most efficient optimum spray conditions for minimizing the roughness of the coating film formed by the antifouling paint under various exposure conditions are 0.019-0.029 inch of injection nozzle diameter and injection pressure of 70-200 kg / cm 2 996 to 2,845 psi). The coating of the top coat is best achieved with a coating thickness of 150 ㎛ which is achieved by the one-time automatic coating method. It should be coated with a minimum thickness of 150 ㎛ based on the dry thickness so that there is no desorption of the top coat in the base material or undercoat. Depending on the function and importance, the coating is performed with a thickness of 200 탆 to 300 탆. If the thickness of the coating exceeds 150 탆, the coating should be applied twice. At this time, the coating should be dried at 15 캜 for at least 6 hours and the second coating should be performed to form the most stable coating.

The present invention also relates to a water immersion structure painted by the painting method of the present invention or an exterior of a hull.

Hereinafter, the present invention will be described in more detail with reference to Examples. It is to be understood by those skilled in the art that these embodiments are merely illustrative of the present invention and that the scope of the present invention is not limited thereto.

Example  1. The coating film of the base product and the Antifouling  Paints Physical properties of coatings Adhesion strength Wear resistance  Comparative test for

 A comparative test was conducted on the adhesion strength and wear resistance, which are the physical characteristics of the coated films of the finished products 1 and 2 and the antifouling coating film according to the present invention. Adhesion tests were carried out on the painted specimens according to ASTM-D4541 Dolly test method, and the wear resistance was tested according to ASTM-D4060-10. The results of the comparative test of this example are shown in Table 2 and the adhesive strength of the blend paints of the present invention was about 1120 psi, about 3.7 times that of the finished product 1 and about 3.8 times that of the finished product 2. The abrasion resistance of the antifouling composite coating of the present invention was 17 mg, which was about 37% of that of the base product 1 and about 31% of that of the base product 2, confirming physical properties greatly improved in adhesion and abrasion resistance.

Comparison test results of physical properties of antifouling coating Ready-made products 1 Ready-made products 2 Developed products Adhesion psi (kg / cm 2 )  305 (21.4)  290 (20.4)  1120 (78.7) Wear amount mg 45 55 17

Example  2. When iron and wood specimens painted with a thickness of 100 ㎛ or 300 ㎛ on the lower 150 ㎛ are immersed in seawater for a long time Antifouling  Characteristic test

Antifouling properties were tested by immersing iron and wood specimens painted with a thickness of 100 탆 or 300 탆 on a 150 탆 top coat, respectively, by using the tested antifouling paints of the present invention for a long time in seawater.

As a result, as shown in FIG. 5, a specimen of a steel material coated with a blend paint for antifouling according to the present invention as a top coat in a thickness of 100 μm showed a partial peeling phenomenon after about 58 days, In both cases, both steel and wood were found to maintain steady state conditions. Therefore, it was confirmed that the top coat having a thickness of 100 탆 had a problem that the time taken for the antifouling function was relatively short.

Thereafter, the wood specimen was subjected to bio-fouling at 82 days (c-2 in FIG. 5) and to the steel material at 146 days (d-1 in FIG. 5) (D-2 in FIG. 5), and the amount of surface fouling (e-1 in FIG. 5) was increased in the 183-day additional water immersion test, but the surface was kept clean even with the simple removal operation And the excellent antifouling performance of the antifouling functional coating material according to the present invention was confirmed.

delete

Claims (11)

And FRP resin, which comprises an epoxy resin-based binder, a polyethylene powder for controlling the attachment of a barnacle, a binder hardener, a dispersant and an antifoaming agent, and has improved adhesion to the base material and abrasion resistance of the coating film. A water-repellent structure made of any one material selected from the group consisting of water, delete The paint for attachment control of a barnacle structure or a barnacle outside the hull according to claim 1, wherein the binder hardener is triethylene tetramine or an ammonia-base having an amine value of 300 to 400. 4. The water-borne structure or the water-borne structure according to claim 3, wherein the triethylene tetramine is used for external coating and the Mannish-base having an amine value of 300 to 400 is used for underwater coating Coating control paint for the barnacle outside the hull. delete delete delete (a) An epoxy-based paint using an airless mechanical spraying method at a temperature of 10 to 20 ° C under a condition that a nozzle diameter is 0.019 to 0.029 inch (inch) and an injection pressure is 70 to 200 kg / cm 2 , (bottom coat);
(b) after the lower coating step of the step (a), drying for 6 to 8 hours; And
(c) a step of applying topcoat using the paint for attachment control of the barnacle of claim 1 after the step (b). . The coating method according to claim 8, wherein the thickness of the coating film formed by the top coating is 150 to 300 占 퐉. 9. The water-borne structure or the water-borne structure according to claim 8, wherein when the topcoat is an underwater paint, a water-based paint system capable of controlling the inflow of the paint with the pressure paint storage tank, painting brush, connecting tube and brush is used Coating method for controlling the attachment of the barn outside the hull. delete
KR1020150127633A 2015-09-09 2015-09-09 Mixed coating material for anti-biofouling of submerged structures and coating method using the same KR101724280B1 (en)

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Application Number Priority Date Filing Date Title
KR1020150127633A KR101724280B1 (en) 2015-09-09 2015-09-09 Mixed coating material for anti-biofouling of submerged structures and coating method using the same
PCT/KR2016/010221 WO2017043938A1 (en) 2015-09-09 2016-09-09 Antifouling paint for immersed structure and painting method using same
CN201680052277.6A CN108026395A (en) 2015-09-09 2016-09-09 The antifouling paint and method of lacquering of immersion structure

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KR1020150127633A KR101724280B1 (en) 2015-09-09 2015-09-09 Mixed coating material for anti-biofouling of submerged structures and coating method using the same

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KR101724280B1 true KR101724280B1 (en) 2017-04-19

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KR20210057541A (en) 2019-11-12 2021-05-21 한국해양과학기술원 Underwater coating equipment using air pressure and brush

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