KR101104821B1 - Foam-Spray Type Insecticide - Google Patents

Foam-Spray Type Insecticide Download PDF

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KR101104821B1
KR101104821B1 KR1020090032525A KR20090032525A KR101104821B1 KR 101104821 B1 KR101104821 B1 KR 101104821B1 KR 1020090032525 A KR1020090032525 A KR 1020090032525A KR 20090032525 A KR20090032525 A KR 20090032525A KR 101104821 B1 KR101104821 B1 KR 101104821B1
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trans
insect repellent
methyl
foam
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KR20100113954A (en
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전찬민
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(주)팜클
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/16—Foams
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A01N25/06—Aerosols
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/06—Oxygen or sulfur directly attached to a cycloaliphatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

본 발명은 거품분사식 방충제에 관한 것으로, 구성성분의 조성을 적의 선택함으로써 도포식 방충제이면서도 도포면에 거품이 잔존하여 도포량 및 도포부위의 확인이 용이한 새로운 거품분사식 방충제에 관한 것이다. 본 발명의 거품분사식 방충제는 분사방식을 채택함으로써 종래 붓을 이용하여 액제를 도포하는 방식에 비해 도포가 현저히 용이하다. 나아가, 도포된 분사물에 거품이 일정 시간 잔존하여 도포부위를 확인하며 도포하는 것이 가능하고, 따라서 종래 분사식 방충제보다도 도포작업을 훨씬 쉽게 수행할 수 있다. 아울러, 거품의 양에 따른 도포량이 바로 확인됨에 따라, 종래 분사식 방충제와 달리 지나치게 적거나 지나치게 많이 도포하는 현상을 예방할 수 있으며, 그 결과 도포효율 및 방충효율을 증대시키는 장점이 있다.The present invention relates to a foam spraying insect repellent, and relates to a new foam spraying insect repellent which is easy to check the coating amount and the application site by remaining the foam on the coating surface by applying the composition of the components appropriately. Foam spraying insect repellent of the present invention by applying the spray method is significantly easier to apply than the conventional method of applying a liquid using a brush. In addition, it is possible to apply the spray to the coated spray by confirming the coating site by remaining the foam for a certain time, and thus, the coating operation can be performed much easier than the conventional spray insect repellent. In addition, as the coating amount according to the amount of the foam is immediately confirmed, unlike the conventional spray insect repellent can prevent the phenomenon of applying too little or too much, as a result has the advantage of increasing the coating efficiency and insect repellent efficiency.

거품, 분사, 방충, 살충 Foam, spraying, insect repellent, insecticide

Description

거품분사식 방충제 {Foam-Spray Type Insecticide}Foam-Insect Repellent {Foam-Spray Type Insecticide}

본 발명은 거품분사식 방충제에 관한 것으로, 구성성분의 조성을 적의 선택함으로써 도포식 방충제이면서도 도포면에 거품이 잔존하여 도포량 및 도포부위의 확인이 용이한 새로운 거품분사식 방충제에 관한 것이다.The present invention relates to a foam spraying insect repellent, and relates to a new foam spraying insect repellent which is easy to check the coating amount and the application site by remaining the foam on the coating surface by applying the composition of the components appropriately.

방충제 (防蟲劑, insecticide)란 일반적으로 농작물이나 사람 또는 가축에 해를 입히는 곤충을 방제하려고 사용하는 약을 통틀어 가리키는 것으로, 해충을 유인하여 죽이는 유인제, 냄새로 사람 등에 접근하지 못하게 하는 기피제, 해충이 번식하지 못하게 하는 화학불임제 등을 포함한다. Insecticides are generally used to refer to drugs used to control crops, insects that harm humans or livestock, and attract insects that attract and kill pests. Includes chemical infertility agents to prevent pests from breeding.

위생곤충의 방제와 농작물, 산림보호 측면에서의 방충제 살포는 증가되어 가고 있는 추세이다. 하지만, 종래 다량으로 사용되던 디디티(DDT)와 다른 유기염소제는 잔류성 농약의 원인 때문에 더 이상 살포되지 않고 있으며, 저독성인 천연산 방충제 사용량이 증가되고 있는 실정이다.Insect repellents, crops and forest protection have been increasing. However, DDT and other organochlorine agents, which have been conventionally used in large quantities, are no longer sprayed due to the cause of residual pesticides, and the use of low-toxic natural insect repellents is increasing.

상기 방충제 중 주요 부분을 차지하는 살충제는 해충의 체내에 침입하는 경로에 따라 먹으면 죽는 식독제, 외피에 닿게 되면 죽는 접촉독제, 가스 상태를 들어 마시면 죽게 되는 흡입독제로 나누고, 해충의 체내에 침투하는 정도에 따라서 침투성과 비침투성으로 나눈다.Insecticides, which occupy the main part of the insect repellent, are divided into insecticides that die when eaten according to the path of infestation of insects, contact poisons that die when they come in contact with the skin, and inhalation poisons that die when they drink gas. Depending on the permeability and non-invasive.

상기 살충제 중 접촉독제는 해충의 외피에 묻어 당해 곤충을 죽이는 것으로서, 직접 곤충을 향해 분사하는 유형과 상기 곤충이 자주 다니는 표면에 도포하여 당해 곤충이 그 위를 지나간 후 죽게 되는 유형을 포함한다.Among the insecticides, contact poisons are those which kill the insect by being buried in the outer shell of the pest, and include a type that directly sprays toward the insect and a type that is applied to a surface on which the insect frequently travels so that the insect dies after passing over the insect.

이 중 두 번째 도포 유형의 종래 살충제는 액제를 붓에 묻혀 곤충이 자주 다니는 곳에 바르는 유형이 있었으나, 이는 도포량의 조절이 용이하지 않고 무엇보다 후술할 분사형에 비해 도포 자체가 불편한 단점이 있다.Of these, there was a type of conventional insecticides of the second application type applied to the place where insects are often buried in the brush, but this is not easy to control the amount of application and above all, there is a disadvantage in that the application itself is inconvenient compared to the spray type to be described later.

이에 반해 분사형은 해충이 자주 다니는 경로에 분사함으로써 도포가 용이하나, 도포면의 확인이 곤란하고, 상기 붓을 사용하는 방법과 마찬가지로 도포량의 조절이 용이하지 않은 단점이 있다.On the other hand, the spray type is easy to apply by spraying a path frequented by pests, but it is difficult to identify the coated surface, and similar to the method of using the brush, there is a disadvantage in that the amount of coating is not easy to control.

본 발명은 상기와 같은 문제점을 해결하기 위하여 안출된 것으로서, 도포가 용이한 분사형 접촉독제이면서도, 도포된 분사물에 거품이 잔존하여 도포부위와 도포량의 확인이 용이한 거품분사식 방충제를 제공하는 것을 그 목적으로 한다.The present invention has been made to solve the above problems, and to provide a foam spray insect repellent easy to confirm the application site and the coating amount by remaining a bubble in the applied spray, yet easy to apply spray type poisoning agent The purpose.

본 발명의 거품분사식 방충제는 상술한 바와 같은 목적을 달성하기 위하여,Foam spray insect repellent of the present invention to achieve the object as described above,

물 100 중량부, 100 parts by weight of water,

용해보조제 54 내지 105 중량부, Dissolution aid 54 to 105 parts by weight,

분사제 22 내지 45 중량부, 22 to 45 parts by weight of propellant,

방충제 0.5 내지 1.5 중량부, Insect repellent 0.5 to 1.5 parts by weight,

유화제 5 내지 15 중량부, 5 to 15 parts by weight of an emulsifier,

방청제 1.2 내지 2.5 중량부, 1.2 to 2.5 parts by weight of a rust preventive agent,

안정제 0.1 내지 0.5 중량부, 및 0.1 to 0.5 parts by weight of a stabilizer, and

향료 0.1 내지 0.5 중량부0.1 to 0.5 parts by weight of fragrance

를 포함하는 것을 특징으로 한다.Characterized in that it comprises a.

또한, 상기 용해보조제는 메탄올, 에탄올, 이소프로판올 및 그 혼합물로 이루어진 군에서 선택된 것이 바람직하다.In addition, the dissolution aid is preferably selected from the group consisting of methanol, ethanol, isopropanol and mixtures thereof.

상기 분사제는 액화석유가스(LPG), 액화천연가스(LNG), 프로판, 부탄, 이소부틸렌, 디메틸에테르, 탄산가스, 질소가스, 프론가스 및 그 혼합물로 이루어진 군 에서 선택된 것이 바람직하다.The propellant is preferably selected from the group consisting of liquefied petroleum gas (LPG), liquefied natural gas (LNG), propane, butane, isobutylene, dimethyl ether, carbon dioxide gas, nitrogen gas, proton gas and mixtures thereof.

상기 방충제는 d-T80-시페노트린 : (±)-α-시아노-3-페녹시벤질(+)-cis/trans-크리산테메이트 [스미토모가가쿠고교], 아레스린 : 3-알릴-2-메틸시클로펜타-2-엔-4-온-1-일 dl-시스/트랜스-크리산테마트 [피나민, 스미토모가가쿠고교], dl·d-T80-아레스린 : 3-알릴-2-메틸시클로펜타-2-엔-4-온-1-일 d-시스/트랜스-크리산테마트 [피나민포르테, 스미토모가가쿠고교], dl·d-T-아레스린 : 3-알릴-2-메틸시클로펜타-2-엔-4-온-1-일 d-트랜스-크리산테마트(바이오아레스린), d·d-T-아레스린 : d-3-알릴-2-메틸시클로펜타-2-엔-4-온-1-일 d-트랜스-크리산테마트(에스비올), d·d-T80-프라레트린 : d-2-메틸-4-옥소-3-프로피닐시클로펜토-2-에닐 d-시스/트랜스-크리산테마트 [에톡, 스미토모가가쿠고교], 프탈스린 : N-(3,4,5,6-테트라히드로프탈리미드)-메틸 dl-시스/트랜스-크리산테마트 [네오피나민,스미토모가가쿠고교], dl·d-T80-프탈스린 : N-(3,4,5,6-테트라히드로프탈리미드)-메틸 d-시스/트랜스-크리산테마트 [네오피나민포르테, 스미토모가가쿠고교], 레스메트린 : 5-벤질-3-프릴메틸 dl-시스/트랜스-크리산테마트[크리슬론, 스미토모가가쿠고교], dl·d-T80-레스메트린 : 5-벤질-3-프릴메틸 d-시스/트랜스-크리산테마트[크리슬론포르테, 스미토모가가쿠고교], 프라메트린 : 5-(2-프로피닐)-3-프릴메틸 크리산테마트 [피나민 D, 스미토모가가쿠고교], 펠메트린 : 3-페녹시벤질 dl-시스/트랜스-2,2-디메틸-3-(2,2-디클로로비닐)시클로프로판카르복시라트 [엑스민, 스미토모가가쿠고교], 페노트린 : 3-페녹시벤질 d-시스/트랜스-크리산테마트 [스미스린, 스미토모가가쿠고교], 펜바렐레이트 : α-시아노-3-페녹시벤질-2-(4-클로로페닐)-3-메틸부틸 레이트 [스미사이딘, 스미토모가가쿠고교], 시펠메트린 : α-시아노-3-페녹시벤질 dl-시스/트랜스-3-(2,2-디클로로비닐)-2,2-디메틸시클로프로판카르복시라트 [아글로스린, 스미토모가가쿠고교], 시페노트린 : α-시아노-3-페녹시벤질 d-시스/트랜스-크리산테마트 [고키라트, 스미토모가가쿠고교], 이미프로트린 : [2,5-디옥소-3-(2-프로피닐)-1-이미다졸리디닐] 메틸 (1R)-cis-트랜스크리산테메이트 [프랄, 스미토모가가쿠고교], 에토펜프록스 : 2-(4-에톡시페닐)-2-메틸프로필-3-페녹시벤질에테르 [트레본, 미쓰이도아츠가가쿠], 테플스린 : 2,3,5,6-테트라플루오로-4-메틸벤질-3-(2-클로로-3,3,3-트리플루오로-1-프로페닐)-2,2-디메틸-1-시클로프로판칼복시라트, 펜프로파트린 : α-시아노-3-페녹시벤질 시스/트랜스-2,2,3,3-테트라메틸시클로프로판카르복시라트, 펜플스린 : 2,3,4,5,6-펜타플루오로벤질-dl-시스/트랜스 3-(2,2-디클로로비닐)2,2-디메틸-1-시클로프로판카르복시라트, 디에칠톨루아미드 : N,N-디에틸-meta-톨루아미드, 퍼메트린 : [3-페녹시벤질 (1RS)-cis,trans-3-(2,2-디클로로비닐)-2,2-디메틸시클로-프로판카르복실레이트], 알파싸이퍼메트린 : [1a(S*), 3a]-(-시아노(3-페녹시페닐)메틸 3-(2, 2-디클로로에테닐)-2,2-디메틸시클로프로판카르복실레이트, 데카메트린 : [1R-[1a(S*),3a]]-시아노(3-페녹시페닐)메틸3-(2,2-디브로모에테닐)-2,2-디메틸시클로프로판카르복실레이트, 피레트린 : (1S)-2-메틸-4-옥소-3-(2Z)-2,4-펜타디에닐-2-시클로펜텐-1-일 (1R,3R)-3-[(1E)-3-메톡시-2-메틸-3-옥소-1-프로페닐]-2,2-디메틸시클로프로판카르복실레이트, 페니트로치온 : 0,0-디메틸-0-(3-메틸-4-니트로페닐)-티오포스페이트, 프로폭술 : S,S'-(2-디메틸아미노트리메틸렌)bis(티오카르바메이트) 하이드로클로라이드; S,S'-[2- (디메틸아미노)-1,3-프로판디일] 디카르바모티오에이트 하이드로클로라이드, 싸이퍼메트린 : (+/-)alpha-시아노-(3-페녹시페닐)메틸(+)-cis,trans- 3-(2,2-디클로로에테닐)-2,2-디메틸시클로-프로판카르복실레이트, 히드라메칠논 : 테트라히드로-5,5-디메틸-2(1H)-피리미디논 [3-[4-(트리플루오로메틸)페닐]-1-[2-[4-(트리플루오로메틸)페닐]에테닐]-2-프로페닐리덴]히드라존, 및 그 혼합물로 이루어진 군에서 선택된 살충제 또는 N,N-디에틸-m-톨아미드(약칭 DEET), 디메틸프탈레이트, 디부틸프탈레이트, 2-에틸-1,3-헥산디올, 디-n-프로필 이소신코멜로네이트, P-디클로로벤젠, 디-n-부틸삭시네이트, 카란-3,4-디올, 1-메틸프로필2-(2-히드록시에틸)-1-피페리딘카르복시라트, 및 그 혼합물로 이루어진 군에서 선택된 기피제에서 선택된 것이 바람직하다.The insect repellent is d-T80-cyphenothrin: (±) -α-cyano-3-phenoxybenzyl (+)-cis / trans-crylate temate [Sumitomogagaku Kogyo], aresrin: 3-allyl- 2-methylcyclopenta-2-en-4-one-1-yl dl-cis / trans-Chrysanthate [Pinamin, Sumitomogagaku Kogyo], dl-d-T80-Asrin: 3-allyl-2 -Methylcyclopenta-2-en-4-one-1-yl d-cis / trans-crysantemat [pinamine forte, Sumitomogagaku Kogyo], dl-dT- arerin: 3-allyl-2-methyl Cyclopenta-2-en-4-one- 1-yl d-trans-Chrysanthemat (Bio Arerin), d-dT-Aresrin: d-3-allyl-2-methylcyclopenta-2-ene- 4-on-1-yl d-trans-crysantemat (esbiol), d-d80-prarethrin: d-2-methyl-4-oxo-3-propynylcyclopento-2-enyl d -Cis / trans-Chrysanthate [Etok, Sumitomogagaku Kogyo], phthalinsine: N- (3,4,5,6-tetrahydrophthalimide) -methyl dl-cis / trans-Chrysanthate [ Neofinamin Tomogagaku High School], dl.d-T80-phthaline: N- (3,4,5,6-tetrahydrophthalimide) -methyl d-cis / trans-Chrysanthate [neopinaminforte, Sumitomogagaku High School], Resmethrin: 5-benzyl-3-primethylmethyl dl-cis / trans-Chrysanthate [Chrislon, Sumitomogagaku High School], dl-d80-resmethrin: 5-benzyl -3-primethylmethyl d-cis / trans-Chrysanthate [Chryslon Forte, Sumitomogagaku Kogyo], pramethrin: 5- (2-propynyl) -3-primethylmethyl chrysanthate [Pinamin D, Sumitomogagaku Kogyo Co., Ltd., Pelmetrin: 3-phenoxybenzyl dl-cis / trans-2,2-dimethyl-3- (2,2-dichlorovinyl) cyclopropanecarboxylated [Xmine, Sumitomogagaku Co., Ltd.] , Phenotrine: 3-phenoxybenzyl d-cis / trans-xanthatemat [Smithrin, Sumitomogagaku Kogyo], phenbarrelate: α-cyano-3-phenoxybenzyl-2- (4-chloro Phenyl) -3-methylbutylate [Smicidine, Sumitomo Gaku Kogyo, Ciffelmethrin: α-cyano-3-phenoxybenzyl dl-cis / trans-3- (2,2-dichlorovinyl) -2,2-dimethylcyclopropanecarboxylated [Agglosrin, Sumitomo Kagaku High School], Cifenotrine: α-cyano-3-phenoxybenzyl d-cis / trans-Chrysanthate [Gokirat, Sumitomogagaku High School], Imiprotrin: [2,5-dioxo -3- (2-propynyl) -1-imidazolidinyl] methyl (1R) -cis-transsanthatemate [pral, Sumitomogagaku Kogyo], etofenprox: 2- (4-ethoxyphenyl) -2-Methylpropyl-3-phenoxybenzyl ether [Treborn, Mitsui Adogagaku], Teflin: 2,3,5,6-tetrafluoro-4-methylbenzyl-3- (2-chloro -3,3,3-trifluoro-1-propenyl) -2,2-dimethyl-1-cyclopropanekalboxyrat, phenpropatrine: α-cyano-3-phenoxybenzyl cis / trans- 2,2,3,3-tetramethylcyclopropanecarboxylated, penfleslin: 2,3,4,5,6-pentafluorobenzyl-dl-cis / trat 3- (2,2-dichlorovinyl) 2,2-dimethyl-1-cyclopropanecarboxylate, diethylluamide: N, N-diethyl-meta-toluamide, permethrin: [3-phenoxybenzyl (1RS) -cis, trans-3- (2,2-dichlorovinyl) -2,2-dimethylcyclo-propanecarboxylate], alpha ciphermethrin: [1a (S *), 3a]-(-cyano (3-phenoxyphenyl) methyl 3- (2,2-dichloroethenyl) -2,2-dimethylcyclopropanecarboxylate, decametrine: [1R- [1a (S *), 3a]]-sia No (3-phenoxyphenyl) methyl3- (2,2-dibromoethenyl) -2,2-dimethylcyclopropanecarboxylate, pyrethrin: (1S) -2-methyl-4-oxo-3- (2Z) -2,4-pentadienyl-2-cyclopenten-1-yl (1R, 3R) -3-[(1E) -3-methoxy-2-methyl-3-oxo-1-propenyl ] -2,2-dimethylcyclopropanecarboxylate, phenytrothion: 0,0-dimethyl-0- (3-methyl-4-nitrophenyl) -thiophosphate, propoxyl: S, S '-(2- Dimethylaminotrimethylene) bis (thiocarbamate) hydrochlora DE; S, S '-[2- (dimethylamino) -1,3-propanediyl] dicarbamothioate hydrochloride, ciphermethrin: (+/-) alpha-cyano- (3-phenoxyphenyl) methyl ( +)-cis, trans- 3- (2,2-dichloroethenyl) -2,2-dimethylcyclo-propanecarboxylate, hydramcinolone: tetrahydro-5,5-dimethyl-2 (1H) -pyri Midinone [3- [4- (trifluoromethyl) phenyl] -1- [2- [4- (trifluoromethyl) phenyl] ethenyl] -2-propenylidene] hydrazone, and mixtures thereof Pesticides selected from the group consisting of or N, N-diethyl-m-tolamide (abbreviated DEET), dimethylphthalate, dibutylphthalate, 2-ethyl-1,3-hexanediol, di-n-propyl isosyncomellonate, Group consisting of P-dichlorobenzene, di-n-butylsuccinate, caran-3,4-diol, 1-methylpropyl2- (2-hydroxyethyl) -1-piperidinecarboxylate, and mixtures thereof Preferred is selected from the repellent selected from.

또한, 상기 유화제는 양이온성, 음이온성, 또는 비이온성 계면활성제인 것이 바람직하고, 특히 NP-10 (nonylphehol 10 mole ethoxylates. 유성화연테크, 한국)인 것이 보다 바람직하다.In addition, the emulsifier is preferably a cationic, anionic, or nonionic surfactant, and more preferably NP-10 (nonylphehol 10 mole ethoxylates. Yusung Chemical, Korea).

또한, 상기 방청제는 RV-50 (한국하우톤, 한국)인 것이 바람직하다.In addition, the rust inhibitor is preferably RV-50 (Korea Houghton, Korea).

또한, 상기 안정제는 유기산인 것이 바람직하고, 특히 구연산, 젖산, 초산, 사과산, 푸마르산, 글루콘산, 케토글루타르산, 호박산 및 그 혼합물로 이루어진 군에서 선택된 유기산인 것이 더욱 바람직하다.In addition, the stabilizer is preferably an organic acid, and more preferably an organic acid selected from the group consisting of citric acid, lactic acid, acetic acid, malic acid, fumaric acid, gluconic acid, ketoglutaric acid, succinic acid and mixtures thereof.

또한, 상기 향료는 동물성/식물성 천연향료, 탄화수소, 알콜, 페놀, 알데히드, 케톤, 락톤, 옥시드, 에스테르류 등의 인공향료일 수 있고, 그린퀸스향 (고려에프앤에프, 한국)이 더욱 바람직하다.In addition, the fragrance may be artificial flavors of animal / vegetable natural flavor, hydrocarbon, alcohol, phenol, aldehyde, ketone, lactone, oxide, ester, etc., Green Queen's flavor (Korea F & F, Korea) is more preferred. .

또한, 상기 거품분사식 방충제의 거품이 완전 소포되는 데 걸리는 시간은 분사 후 10 초 내지 30 분인 것이 바람직하다.In addition, the time it takes for the foam of the foam injection insect repellent is completely defoamed is preferably 10 seconds to 30 minutes after the injection.

본 발명의 거품분사식 방충제는 분사방식을 채택함으로써 종래 붓을 이용하여 액제를 도포하는 방식에 비해 도포가 현저히 용이하다. 나아가, 도포된 분사물에 거품이 일정 시간 잔존하여 도포부위를 확인하며 도포하는 것이 가능하고, 따라서 종래 분사식 방충제보다도 도포작업을 훨씬 쉽게 수행할 수 있다. 아울러, 거품의 양에 따른 도포량이 바로 확인됨에 따라, 종래 분사식 방충제와 달리 지나치게 적거나 지나치게 많이 도포하는 현상을 예방할 수 있으며, 그 결과 도포효율 및 방충효율을 증대시키는 장점이 있다.Foam spraying insect repellent of the present invention by applying the spray method is significantly easier to apply than the conventional method of applying a liquid using a brush. In addition, it is possible to apply the spray to the coated spray by confirming the coating site by remaining the foam for a certain time, and thus, the coating operation can be performed much easier than the conventional spray insect repellent. In addition, as the coating amount according to the amount of the foam is immediately confirmed, unlike the conventional spray insect repellent can prevent the phenomenon of applying too little or too much, as a result has the advantage of increasing the coating efficiency and insect repellent efficiency.

이하, 본 발명의 바람직한 실시예에 대하여 첨부도면을 참조하여 상세히 설명한다. 우선 각 도면의 구성요소들에 참조부호를 부가함에 있어서, 동일한 구성요소들에 한해서는 비록 다른 도면상에 표시되더라도 가능한 한 동일한 부호로 표기되었음에 유의하여야 한다. 또한, 하기의 설명에서는 구체적인 구성요소 등과 같은 많은 특정사항들이 도시되어 있는데, 이는 본 발명의 보다 전반적인 이해를 돕기 위해서 제공된 것일 뿐 이러한 특정 사항들 없이도 본 발명이 실시될 수 있음은 이 기술분야에서 통상의 지식을 가진 자에게는 자명하다 할 것이다. 그리고, 본 발명을 설명함에 있어서, 관련된 공지 기능 혹은 구성에 대한 구체적인 설명이 본 발명의 요지를 불필요하게 흐릴 수 있다고 판단되는 경우 그 상세한 설명을 생 략한다.Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings. First, in adding reference numerals to the elements of each drawing, it should be noted that the same elements are denoted by the same reference numerals as much as possible even if they are displayed on different drawings. In addition, in the following description there are shown a number of specific details such as specific components, which are provided only to help a more comprehensive understanding of the present invention, it is common in the art that the present invention may be practiced without these specific details. It is self-evident to those who have knowledge of the world. In the following description of the present invention, detailed descriptions of related known functions or configurations will be omitted when it is determined that the detailed description of the present invention may unnecessarily obscure the subject matter of the present invention.

본 발명의 거품분사식 방충제는 물 100 중량부에 대해, 용해보조제 54 내지 105 중량부, 분사제 22 내지 45 중량부, 방충제 0.5 내지 1.5 중량부, 유화제 5 내지 15 중량부, 방청제 1.2 내지 2.5 중량부, 안정제 0.1 내지 0.5 중량부, 및 향료 0.1 내지 0.5 중량부를 포함함으로써 종래 붓으로 도포하는 접촉독식 방충제와 동일한 방충효과를 발휘하면서도 분사시 거품이 잔존하여 도포가 용이한 장점을 가진다. 본 발명의 이러한 장점은 상기 제 성분들의 조성비를 최적화함으로써 달성된 것이며, 이 점이 본 발명의 가장 주요한 특징이다.Foam spraying insect repellent agent of the present invention with respect to 100 parts by weight of water, 54 to 105 parts by weight of dissolution aid, 22 to 45 parts by weight of propellant, 0.5 to 1.5 parts by weight of insect repellent, 5 to 15 parts by weight of emulsifier, 1.2 to 2.5 parts by weight of rust inhibitor , 0.1 to 0.5 parts by weight of the stabilizer, and 0.1 to 0.5 parts by weight of fragrance, while exhibiting the same insect repellent effect as a conventional poisonous insect repellent applied with a brush, it has the advantage that the coating is easy because the remaining bubbles during spraying. This advantage of the present invention is achieved by optimizing the composition ratio of the above components, which is the main feature of the present invention.

상기 용해보조제는 주용제인 물에 나머지 성분들이 잘 용해될 수 있도록 보조하는 역할과 함께, 저온 보관시 방충원액이 동결되는 현상을 예방하는 기능까지 수행할 수 있다. 이러한 용해보조제로서 본 발명에는 메탄올, 에탄올, 이소프로판올 및 그 혼합물로 이루어진 군에서 선택된 성분이 첨가되는 것이 바람직하고, 특히 에탄올이 바람직하다. 상기 용해보조제의 함량이 54 중량부 미만이면, 나머지 성분을 완전히 용해시키기 어려우며 특히 기온이 낮은 겨울철에 일부 성분이 석출되는 현상이 발생할 수 있다. 반대로 105 중량부를 초과하면 경제성이 떨어질 뿐만 아니라, 기온이 높은 여름철에 일부 용해보조제의 높은 휘발성으로 인해 안전문제가 발생할 수 있다.The dissolution aid may serve to assist the remaining components to be well dissolved in water, which is the main solvent, and may function to prevent freezing of the insect repellent solution during low temperature storage. As such a dissolution aid, in the present invention, a component selected from the group consisting of methanol, ethanol, isopropanol and mixtures thereof is preferably added, and ethanol is particularly preferable. When the content of the dissolution aid is less than 54 parts by weight, it is difficult to completely dissolve the remaining components, and in particular, a phenomenon may occur in which some components are precipitated, especially in winter, when the temperature is low. Conversely, exceeding 105 parts by weight not only decreases the economic efficiency, but also may cause safety problems due to the high volatility of some of the dissolution aids during the high temperature summer.

상기 분사제는 본 발명의 방충제가 분사될 수 있도록 하여 종래 붓으로 도포하는 접촉독제에 비해 월등히 편리한 장점을 부여한다. 이러한 기능을 수행하는 성분이라면 본 발명의 분사제로서 제한 없이 사용될 수 있으나, 특히 액화석유가 스(LPG), 액화천연가스(LNG), 프로판, 부탄, 이소부틸렌, 디메틸에테르, 탄산가스, 질소가스, 프론가스 및 그 혼합물로 이루어진 군에서 선택되는 것이 바람직하다. 상기 분사제의 함량이 22 중량부 미만이면 분사력이 떨어져 방충원액이 잘 방출되지 않고, 반대로 45 중량부를 초과하면 앞서 용해보조제의 경우와 마찬가지로 기온이 높은 여름철에 높은 휘발성으로 인해 안전문제가 발생할 수 있다.The propellant allows the insect repellent of the present invention to be sprayed, thereby providing an advantage that is much more convenient than the conventional contact poison applied with a brush. If the component to perform this function can be used without limitation as the propellant of the present invention, in particular, liquefied petroleum gas (LPG), liquefied natural gas (LNG), propane, butane, isobutylene, dimethyl ether, carbon dioxide, nitrogen It is preferably selected from the group consisting of gas, proton gas and mixtures thereof. If the content of the propellant is less than 22 parts by weight, the spraying power is insufficient to release the insect repellent solution, on the contrary, if it exceeds 45 parts by weight, safety problems may occur due to high volatility in the summer when the temperature is high as in the case of the dissolution aid. .

상기 방충제는 목적하는 해충에 작용하는 방충제라면 제한 없이 사용될 수 있으며, 앞서 열거한 유인제, 기피제, 화학불임제, 식독제, 접촉독제가 모두 사용될 수 있다. 특히, d-T80-시페노트린 : (±)-α-시아노-3-페녹시벤질(+)-cis/trans-크리산테메이트 [스미토모가가쿠고교], 아레스린 : 3-알릴-2-메틸시클로펜타-2-엔-4-온-1-일 dl-시스/트랜스-크리산테마트 [피나민, 스미토모가가쿠고교], dl·d-T80-아레스린 : 3-알릴-2-메틸시클로펜타-2-엔-4-온-1-일 d-시스/트랜스-크리산테마트 [피나민포르테, 스미토모가가쿠고교], dl·d-T-아레스린 : 3-알릴-2-메틸시클로펜타-2-엔-4-온-1-일 d-트랜스-크리산테마트(바이오아레스린), d·d-T-아레스린 : d-3-알릴-2-메틸시클로펜타-2-엔-4-온-1-일 d-트랜스-크리산테마트(에스비올), d·d-T80-프라레트린 : d-2-메틸-4-옥소-3-프로피닐시클로펜토-2-에닐 d-시스/트랜스-크리산테마트 [에톡, 스미토모가가쿠고교], 프탈스린 : N-(3,4,5,6-테트라히드로프탈리미드)-메틸 dl-시스/트랜스-크리산테마트 [네오피나민,스미토모가가쿠고교], dl·d-T80-프탈스린 : N-(3,4,5,6-테트라히드로프탈리미드)-메틸 d-시스/트랜스-크리산테마트 [네오피나민포르테, 스미토모가가쿠고교], 레스메트린 : 5-벤질-3-프릴메틸 dl-시스/트랜스-크리산테마트[크리슬론, 스미토모가가쿠고교], dl· d-T80-레스메트린 : 5-벤질-3-프릴메틸 d-시스/트랜스-크리산테마트[크리슬론포르테, 스미토모가가쿠고교], 프라메트린 : 5-(2-프로피닐)-3-프릴메틸 크리산테마트 [피나민 D, 스미토모가가쿠고교], 펠메트린 : 3-페녹시벤질 dl-시스/트랜스-2,2-디메틸-3-(2,2-디클로로비닐)시클로프로판카르복시라트 [엑스민, 스미토모가가쿠고교], 페노트린 : 3-페녹시벤질 d-시스/트랜스-크리산테마트 [스미스린, 스미토모가가쿠고교], 펜바렐레이트 : α-시아노-3-페녹시벤질-2-(4-클로로페닐)-3-메틸부틸레이트 [스미사이딘, 스미토모가가쿠고교], 시펠메트린 : α-시아노-3-페녹시벤질 dl-시스/트랜스-3-(2,2-디클로로비닐)-2,2-디메틸시클로프로판카르복시라트 [아글로스린, 스미토모가가쿠고교], 시페노트린 : α-시아노-3-페녹시벤질 d-시스/트랜스-크리산테마트 [고키라트, 스미토모가가쿠고교], 이미프로트린 : [2,5-디옥소-3-(2-프로피닐)-1-이미다졸리디닐] 메틸 (1R)-cis-트랜스크리산테메이트 [프랄, 스미토모가가쿠고교], 에토펜프록스 : 2-(4-에톡시페닐)-2-메틸프로필-3-페녹시벤질에테르 [트레본, 미쓰이도아츠가가쿠], 테플스린 : 2,3,5,6-테트라플루오로-4-메틸벤질-3-(2-클로로-3,3,3-트리플루오로-1-프로페닐)-2,2-디메틸-1-시클로프로판칼복시라트, 펜프로파트린 : α-시아노-3-페녹시벤질 시스/트랜스-2,2,3,3-테트라메틸시클로프로판카르복시라트, 펜플스린 : 2,3,4,5,6-펜타플루오로벤질-dl-시스/트랜스 3-(2,2-디클로로비닐)2,2-디메틸-1-시클로프로판카르복시라트, 디에칠톨루아미드 : N,N-디에틸-meta-톨루아미드, 퍼메트린 : [3-페녹시벤질 (1RS)-cis,trans-3-(2,2-디클로로비닐)-2,2-디메틸시클로-프로판카르복실레이트], 알파싸이퍼메트린 : [1a(S*), 3a]-(-시아노(3-페녹시페닐)메틸 3-(2, 2-디클로로에테닐)-2,2-디메틸시 클로프로판카르복실레이트, 데카메트린 : [1R-[1a(S*),3a]]-시아노(3-페녹시페닐)메틸3-(2,2-디브로모에테닐)-2,2-디메틸시클로프로판카르복실레이트, 피레트린 : (1S)-2-메틸-4-옥소-3-(2Z)-2,4-펜타디에닐-2-시클로펜텐-1-일 (1R,3R)-3-[(1E)-3-메톡시-2-메틸-3-옥소-1-프로페닐]-2,2-디메틸시클로프로판카르복실레이트, 페니트로치온 : 0,0-디메틸-0-(3-메틸-4-니트로페닐)-티오포스페이트, 프로폭술 : S,S'-(2-디메틸아미노트리메틸렌)bis(티오카르바메이트) 하이드로클로라이드; S,S'-[2-(디메틸아미노)-1,3-프로판디일] 디카르바모티오에이트 하이드로클로라이드, 싸이퍼메트린 : (+/-)alpha-시아노-(3-페녹시페닐)메틸(+)-cis,trans- 3-(2,2-디클로로에테닐)-2,2-디메틸시클로-프로판카르복실레이트, 히드라메칠논 : 테트라히드로-5,5-디메틸-2(1H)-피리미디논 [3-[4-(트리플루오로메틸)페닐]-1-[2-[4-(트리플루오로메틸)페닐]에테닐]-2-프로페닐리덴]히드라존, 및 그 혼합물로 이루어진 군에서 선택된 살충제 또는 N,N-디에틸-m-톨아미드(약칭 DEET), 디메틸프탈레이트, 디부틸프탈레이트, 2-에틸-1,3-헥산디올, 디-n-프로필 이소신코멜로네이트, P-디클로로벤젠, 디-n-부틸삭시네이트, 카란-3,4-디올, 1-메틸프로필2-(2-히드록시에틸)-1-피페리딘카르복시라트, 및 그 혼합물로 이루어진 군에서 선택된 기피제에서 선택된 것이 바람직하다.The insect repellent may be used without limitation as long as the insect repellent acts on the desired pest, all of the above-mentioned attractant, repellent, chemical infertility, poisoning agent, contact poisoning agent can be used. In particular, d-T80-cyphenothrin: (±) -α-cyano-3-phenoxybenzyl (+)-cis / trans-crysanthate [Sumitomogagaku Kogyo], aresrin: 3-allyl-2 -Methylcyclopenta-2-en-4-one- 1-yl dl-cis / trans-Chrysanthate [pinamine, Sumitomogagaku Kogyo], dl-d-T80- arerin: 3-allyl-2- Methylcyclopenta-2-en-4-one-1-yl d-cis / trans-Chrysanthate [Pinamin Forte, Sumitomogagaku Kogyo], dl-dT-Asrin: 3-allyl-2-methylcyclo Penta-2-en-4-one-1-yl d-trans-xanthatemate (bioarrestrin), d.dT-arrestrin: d-3-allyl-2-methylcyclopenta-2-ene-4 -On-1-yl d-trans-crysantemat (esbiol), d-d80-prarethrin: d-2-methyl-4-oxo-3-propynylcyclopento-2-enyl d- Cis / trans-Chrysanthate [E-Tox, Sumitomogagaku Kogyo], Phthalin: N- (3,4,5,6-tetrahydrophthalimide) -methyl dl-cis / trans-Chrysanthate [Neo Pinamine and Sumitomoga Cougo bridge], dl.d-T80-phthaline: N- (3,4,5,6-tetrahydrophthalimide) -methyl d-cis / trans-Chrysanthate [neopinaminforte, Sumitomoga Gakugokyo], Resmethrin: 5-benzyl-3-primethylmethyl dl-cis / trans-Chrysanthemat [Chrislon, Sumitomogagaku Kogyo], dl-d-T80-resmethrin: 5-benzyl-3 -Prillmethyl d-cis / trans-Chrysanthemat [Chryslon Forte, Sumitomogagaku Kogyo], Pramethrin: 5- (2-propynyl) -3-prilmethyl chrysanthate [Pinamin D, Sumitomoga Gakugokyo], Pelmetrin: 3-phenoxybenzyl dl-cis / trans-2,2-dimethyl-3- (2,2-dichlorovinyl) cyclopropanecarboxylated [Exmine, Sumitomogagaku Kogyo], Phen Notreline: 3-phenoxybenzyl d-cis / trans-xanthatemat [Smithrin, Sumitomogagaku Kogyo], Fenbarrelate: α-cyano-3-phenoxybenzyl-2- (4-chlorophenyl) 3-Methyl butyrate [Sumisaidine, Sumitomogagakugo ], Ciffelmethrin: α-cyano-3-phenoxybenzyl dl-cis / trans-3- (2,2-dichlorovinyl) -2,2-dimethylcyclopropanecarboxylate [Aglossrin, Sumitomogagaku High School], Cifenotrine: α-Cyano-3-phenoxybenzyl d-cis / trans-Chrysanthate [Gokirat, Sumitomogagaku Kogyo], Imiprotrin: [2,5-dioxo-3 -(2-propynyl) -1-imidazolidinyl] methyl (1R) -cis-transxatetemate [pral, Sumitomogagaku Kogyo], etofenprox: 2- (4-ethoxyphenyl) -2 -Methylpropyl-3-phenoxybenzyl ether [Trebon, Mitsui Atsugagaku], Teflin: 2,3,5,6-tetrafluoro-4-methylbenzyl-3- (2-chloro-3 , 3,3-trifluoro-1-propenyl) -2,2-dimethyl-1-cyclopropanecalcoxyrat, phenpropatrine: α-cyano-3-phenoxybenzyl cis / trans-2, 2,3,3-tetramethylcyclopropanecarboxylatin, fenthrin: 2,3,4,5,6-pentafluorobenzyl-dl-cis / trans 3- (2,2- Dichlorovinyl) 2,2-dimethyl-1-cyclopropanecarboxylated, diethylluamide: N, N-diethyl-meta-toluamide, permethrin: [3-phenoxybenzyl (1RS) -cis, trans- 3- (2,2-dichlorovinyl) -2,2-dimethylcyclo-propanecarboxylate], alphacypermethrin: [1a (S *), 3a]-(-cyano (3-phenoxyphenyl) methyl 3- (2,2-dichloroethenyl) -2,2-dimethylcyclopropanecarboxylate, decametrine: [1R- [1a (S *), 3a]]-cyano (3-phenoxyphenyl ) Methyl3- (2,2-dibromoethenyl) -2,2-dimethylcyclopropanecarboxylate, pyrethrin: (1S) -2-methyl-4-oxo-3- (2Z) -2,4 -Pentadienyl-2-cyclopenten-1-yl (1R, 3R) -3-[(1E) -3-methoxy-2-methyl-3-oxo-1-propenyl] -2,2-dimethyl Cyclopropanecarboxylate, phenytrothion: 0,0-dimethyl-0- (3-methyl-4-nitrophenyl) -thiophosphate, propoxyl: S, S '-(2-dimethylaminotrimethylene) bis ( Thiocarbamate) hydrochloride; S, S '-[2- (dimethylamino) -1,3-propanediyl] dicarbamothioate hydrochloride, ciphermethrin: (+/-) alpha-cyano- (3-phenoxyphenyl) methyl ( +)-cis, trans- 3- (2,2-dichloroethenyl) -2,2-dimethylcyclo-propanecarboxylate, hydramcinolone: tetrahydro-5,5-dimethyl-2 (1H) -pyri Midinone [3- [4- (trifluoromethyl) phenyl] -1- [2- [4- (trifluoromethyl) phenyl] ethenyl] -2-propenylidene] hydrazone, and mixtures thereof Pesticides selected from the group consisting of or N, N-diethyl-m-tolamide (abbreviated DEET), dimethylphthalate, dibutylphthalate, 2-ethyl-1,3-hexanediol, di-n-propyl isosyncomellonate, Group consisting of P-dichlorobenzene, di-n-butylsuccinate, caran-3,4-diol, 1-methylpropyl2- (2-hydroxyethyl) -1-piperidinecarboxylate, and mixtures thereof Preferred is selected from the repellent selected from.

상기 방충제의 함량이 0.5 중량부 미만이면 방충효과가 떨어질 수 있고, 1.5 중량부를 초과하면 경제성이 감소하는 결과가 초래된다.If the content of the insect repellent is less than 0.5 parts by weight, the insect repellent effect may be lowered, and when the content of the insect repellent exceeds 1.5 parts by weight, the economical efficiency is reduced.

상기 유화제는 거품을 일으킬 수 있는 성분이라면 제한 없이 사용할 수 있으며, 특히 양이온성, 음이온성, 또는 비이온성 계면활성제인 것이 바람직하고, 특히 NP-10 (nonylphehol 10 mole ethoxylates. 유성화연테크, 한국)인 것이 보다 바람직하다. 상기 유화제의 함량이 5 중량부 미만이면 분사 후 거품 형성이 모자라 본 발명의 효과를 거두기 어려울 수 있고, 반대로 15 중량부를 초과하면 거품이 지나치게 오래 남아 미관상 불리한 단점이 있다.The emulsifier can be used without limitation as long as it is a component capable of foaming, and particularly preferably cationic, anionic or nonionic surfactant, and especially NP-10 (nonylphehol 10 mole ethoxylates. Yusung Chemical Co., Korea) It is more preferable. If the content of the emulsifier is less than 5 parts by weight, it may be difficult to achieve the effect of the present invention because the lack of foaming after spraying, on the contrary, if the content exceeds 15 parts by weight, the bubbles remain too long to have an aesthetic disadvantage.

본 발명의 방충제에 포함되는 방청제는 제품 용기 내부의 부식을 방지하는 성분이라면 제한 없이 사용될 수 있고, 예컨대 RV-50 (한국하우톤, 한국)을 들 수 있다. 상기 방청제의 함량이 1.2 미만이면 제품 용기 내부가 부식될 수 있고, 반대로 2.5 중량부를 초과한다고 하여도 방청효과가 개선되는 바 없으므로 경제성만 떨어뜨리는 결과를 초래한다.The rust preventive agent included in the insect repellent of the present invention can be used without limitation so long as it is a component that prevents corrosion inside the product container, and examples thereof include RV-50 (Korea Houghton, Korea). If the content of the rust inhibitor is less than 1.2 may be corroded inside the product container, on the contrary, even if it exceeds 2.5 parts by weight does not improve the rust preventive effect results in only economic efficiency.

또한, 상기 안정제는 무기산보다는 유기산인 것이 바람직하고, 특히 구연산, 젖산, 초산, 사과산, 푸마르산, 글루콘산, 케토글루타르산, 호박산 및 그 혼합물로 이루어진 군에서 선택된 유기산인 것이 더욱 바람직하다. 상기 안정제의 함량이 0.1 내지 0.5 중량부 범위를 벗어나면 효과적인 pH 범위를 벗어날 수 있어 방충효과의 저하를 초래할 수 있다.In addition, the stabilizer is preferably an organic acid rather than an inorganic acid, and particularly preferably an organic acid selected from the group consisting of citric acid, lactic acid, acetic acid, malic acid, fumaric acid, gluconic acid, ketoglutaric acid, succinic acid and mixtures thereof. If the content of the stabilizer is out of the range 0.1 to 0.5 parts by weight can be out of the effective pH range can lead to a decrease in the insect repellent effect.

마지막으로, 상기 향료는 동물성/식물성 천연향료, 탄화수소, 알콜, 페놀, 알데히드, 케톤, 락톤, 옥시드, 에스테르류 등의 인공향료일 수 있고, 예컨대 그린퀸스향 (고려에프앤에프, 한국)을 들 수 있다. 제시한 함량 범위를 벗어난 향료 첨가는 방충효과에는 영향이 없으나 사용자의 기호도를 떨어뜨릴 수 있어 바람직하지 않다.Finally, the flavor may be artificial flavors of animal / vegetable natural flavor, hydrocarbons, alcohols, phenols, aldehydes, ketones, lactones, oxides, esters, and the like, for example, Green Queens flavor (Korea F & K, Korea) Can be. Addition of fragrance outside the suggested content range does not affect the insect repellent effect, but it is not preferable because it may reduce the user's preference.

본 발명의 거품분사식 방충제의 거품이 완전 소포되는 데 걸리는 시간은 분 사 후 10 초 내지 30 분인 것이 바람직한데, 10 초 이내 거품이 꺼지면 도포부위 및 도포량의 확인이 미흡하여 본 발명의 효과를 십분 발휘하기 어렵고, 30 분이 경과하여도 거품이 꺼지지 않으면 미관상 좋지 않아 본 발명의 방충제에 의해 발생한 거품은 상기 시간 범위 내에 소포되는 것이 바람직하다.The time it takes for the foam of the foam injection insect repellent of the present invention to fully deflate is preferably 10 seconds to 30 minutes after injection, and when the foam is turned off within 10 seconds, the application site and the application amount are insufficient to confirm the effect of the present invention. If the foam is not extinguished even after 30 minutes has elapsed, the foam generated by the insect repellent of the present invention is preferably defoamed within the above time range.

이하, 본 발명의 실시예에 대하여 설명한다.EMBODIMENT OF THE INVENTION Hereinafter, the Example of this invention is described.

실시예Example

실시예Example

물 43.6 g에 에탄올 35.6 g을 혼합한 후, 상기 혼합액에 [2,5-디옥소-3-(2-프로피닐)-1-이미다졸리디닐] 메틸 (1R)-cis-트랜스크리산테메이트 0.1 g, (±)-α-시아노-3-페녹시벤질(+)-cis/trans-크리산테메이트 0.3 g, NP-10 (nonylphehol 10 mole ethoxylates. 유성화연테크, 한국) 4.2 g, RV-50 (한국하우톤, 한국) 1 g, 구연산 0.1 g, 및 그린퀸스향 (고려에프앤에프, 한국) 0.1 g을 혼합하여 방충원액 85 g을 제조하고, 이를 용기에 넣은 후 상기 용기에 액화석유가스 15 g을 주입하여 본 발명의 거품분사식 방충제를 제조하였다.35.6 g of ethanol were mixed with 43.6 g of water, and then [2,5-dioxo-3- (2-propynyl) -1-imidazolidinyl] methyl (1R) -cis-transxatemate was added to the mixture. 0.1 g, (±) -α-cyano-3-phenoxybenzyl (+)-cis / trans-xanthatemate, 0.3 g, NP-10 (nonylphehol 10 mole ethoxylates. Yusung Chemical, Korea) 4.2 g, RV 1 g of -50 (Korea Houghton, Korea), 0.1 g of citric acid, and 0.1 g of Green Queen's fragrance (Korea F & F, Korea) were mixed to prepare 85 g of insect repellent solution, which was placed in a container and liquefied petroleum oil in the container. 15 g of gas was injected to prepare a foam jet insect repellent of the present invention.

시험예 1: 액체 상태Test Example 1: Liquid State

2 개의 30 × 20 cm 사육통 바닥에 실시예의 거품분사식 방충제를 분사한 결과, 도 1과 같이 거품이 도포면에 잔존함을 알 수 있다. 이러한 거품의 존재로 인해 분사방향 및 분사량의 조절이 용이하여 도포효율 및 후술할 방충효율이 제고되었다.As a result of spraying the foam spray insect repellent of the embodiment on the bottom of the two 30 × 20 cm cage, it can be seen that the foam remains on the coating surface as shown in FIG. Due to the presence of such bubbles it is easy to control the injection direction and the injection amount to improve the coating efficiency and the insect-proof efficiency to be described later.

상기 도포 후 40 분이 경과하면 분사물에 더 이상 거품이 관찰되지 않고 액 체 상태로 나타나며, 이때 하나의 사육통에는 독일바퀴 20 마리를 다른 사육통에는 미국바퀴 20 마리를 각각 도입하였다. 그 결과 도입 10 분 후 독일바퀴는 모두 죽었으며, 도입 15 분 뒤에는 미국바퀴도 모두 죽은 것을 관찰할 수 있었다. 상기 미국바퀴가 죽은 모습은 도 2에 나타내었으며, 시간에 따른 생존 바퀴 수의 변화를 도 4에 도시하였다.After 40 minutes after the application, no bubbles were observed in the spray, and the liquid appeared. In this case, 20 German wheels were introduced into one feeding barrel and 20 American wheels into the other feeding barrel. As a result, it was observed that 10 minutes after the introduction, all the German wheels died, and 15 minutes after the introduction, all the American wheels were dead. The death of the American wheel is shown in Figure 2, the change in the number of survival wheels with time is shown in Figure 4.

시험 결과, 본 발명의 거품분사식 방충제는 종래 접촉독제식 방충제에 비해 도포가 월등히 용이하면서도 바퀴 방충효과 역시 뛰어남을 확인할 수 있었다.As a result of the test, the foam spray insect repellent of the present invention was found to be superior to the conventional contact poison insect repellent, but also excellent wheel insect repellent effect.

시험예 2: 고체 상태Test Example 2: Solid State

시험예 1과 동일한 과정을 거치되, 도포 후 40 분이 아닌 도포 후 90 분이 경과한 후 바퀴를 사육통에 도입하였다. 도포 후 90 분이 경과하면 분사물은 더 이상 액체 상태가 아니라 담황색의 흔적을 남기고 마르며 바퀴가 그 위를 지나가는 경우 죽는지를 관찰한 것이다.After the same process as in Test Example 1, but 90 minutes after the application, not 40 minutes after the application of the wheel was introduced into the cage. After 90 minutes of application, the spray was no longer liquid, but dried, leaving a pale yellow trace, and if the wheels passed over it, it died.

시간 경과에 따른 생존 바퀴 수의 변화를 도 4에 도시하였으며, 시험 결과 본 발명의 거품분사식 방충제는 마른 상태에서도 우수한 접촉독제 효과를 발휘함을 알 수 있었다.The change in the number of surviving wheels over time is shown in FIG. 4, and the test results show that the foam spray insect repellent of the present invention exhibits excellent contact poisoning effect even in a dry state.

시험예 3: 기타 방충제와의 비교Test Example 3: Comparison with Other Insect Repellents

시험예 1과 동일한 과정을 거치되, 사육통을 3 개 준비하여 하나의 사육통에는 실시예의 거품분사식 방충제를 분사하고, 또 하나의 사육통에는 도포 살충제 (비교예 1. 클로르피리포스)를 붓으로 도포하고, 나머지 사육통에는 일반 바퀴 에어졸 제품 (비교예 2. 팜클, 한국)을 분사하였다.The same process as in Test Example 1, but prepared three carcasses to spray one of the foam spray type insect repellent of the embodiment, to another carcasses to apply a pesticide (Comparative Example 1. Chlorpyriphos) with a brush , The remaining cages were sprayed with ordinary wheel aerosol products (Comparative Example 2. Palmel, Korea).

시간 경과에 따른 생존 바퀴 수의 변화를 도 5에 도시하였으며, 시험 결과 본 발명의 거품분사식 방충제는 도포가 용이한 장점을 가지면서도, 붓으로 도포한 도포 살충제 (비교예 1)에 필적하는 방충효과를 나타내었으며, 일반 바퀴 에어졸 제품 (비교예 2)보다는 월등히 우수한 방충효과를 나타냈다.The change in the number of surviving wheels over time is shown in FIG. 5, and the test results show that the foam spray insect repellent has the advantage of being easy to apply, and the insect repellent effect comparable to the applied insecticide applied to the brush (Comparative Example 1). It showed significantly better insect repellent effect than the general wheel aerosol product (Comparative Example 2).

이상에서는 본 발명의 바람직한 실시예에 대해서 도시하고 설명하였으나, 본 발명은 상술한 특정의 실시예에 한정되지 아니하며, 당해 기술분야에서 통상의 지식을 가진 자라면 본원 발명의 요지를 벗어남이 없이 다양한 변형 실시가 가능함은 물론이다. 따라서, 본 발명의 범위는 위의 실시예에 국한해서 해석되어서는 안되며, 후술하는 특허청구범위 뿐만 아니라 이 특허청구범위와 균등한 것들에 의해 정해져야 할 것이다.Although the above has been illustrated and described with respect to the preferred embodiments of the present invention, the present invention is not limited to the specific embodiments described above, those skilled in the art without departing from the gist of the present invention various modifications Of course, implementation is possible. Accordingly, the scope of the present invention should not be construed as being limited to the above-described embodiments, but should be determined by equivalents to the appended claims, as well as the following claims.

도 1은 본 발명 실시예의 거품분사식 방청제를 도포한 직후의 도포면을 촬영한 사진이다.1 is a photograph of the application surface immediately after applying the foam-injection type rust preventive agent of the embodiment of the present invention.

도 2는 본 발명 실시예의 거품분사식 방청제를 도포하고 40 분 경과 후의 도포면을 촬영한 사진이다.Figure 2 is a photograph of the coated surface after 40 minutes after the foam spray type rust preventive agent of the present invention was applied.

도 3은 본 발명 실시예의 거품분사식 방청제를 도포하고 40 분 경과 후 바퀴를 도입하고, 다시 15 분이 경과한 후의 도포면을 촬영한 사진이다.Figure 3 is a photograph of the coated surface after the application of the foam injection type rust preventive agent of the present invention 40 minutes after the introduction of the wheel, and after 15 minutes.

도 4는 본 발명 실시예의 거품분사식 방청제를 도포하고 90 분 경과 후 바퀴를 도입하여 시간 경과에 따른 생존 바퀴 수를 나타낸 그래프이다.Figure 4 is a graph showing the number of surviving wheels over time by applying the wheel after the 90 minutes after the foam spray type rust inhibitor of the present invention.

도 5는 본 발명 실시예 및 비교예의 방청제를 도포하고 90 분 경과 후 바퀴를 도입하여 시간 경과에 따른 생존 바퀴 수를 나타낸 그래프이다.Figure 5 is a graph showing the number of surviving wheels over time by introducing the wheel after 90 minutes after applying the rust preventive agent of the present invention and comparative examples.

Claims (5)

물 100 중량부, 100 parts by weight of water, 용해보조제 54 내지 105 중량부, Dissolution aid 54 to 105 parts by weight, 분사제 22 내지 45 중량부, 22 to 45 parts by weight of propellant, 방충제 0.5 내지 1.5 중량부, Insect repellent 0.5 to 1.5 parts by weight, 유화제 5 내지 15 중량부, 5 to 15 parts by weight of an emulsifier, 방청제 1.2 내지 2.5 중량부, 1.2 to 2.5 parts by weight of a rust preventive agent, 안정제 0.1 내지 0.5 중량부, 및 0.1 to 0.5 parts by weight of a stabilizer, and 향료 0.1 내지 0.5 중량부0.1 to 0.5 parts by weight of fragrance 를 포함하고, Including, 상기 용해보조제는 메탄올, 에탄올, 이소프로판올 및 그 혼합물로 이루어진 군에서 선택되고, The dissolution aid is selected from the group consisting of methanol, ethanol, isopropanol and mixtures thereof, 상기 분사제는 액화석유가스(LPG), 액화천연가스(LNG), 프로판, 부탄, 이소부틸렌, 디메틸에테르, 탄산가스, 질소가스, 프론가스 및 그 혼합물로 이루어진 군에서 선택되고, The propellant is selected from the group consisting of liquefied petroleum gas (LPG), liquefied natural gas (LNG), propane, butane, isobutylene, dimethyl ether, carbon dioxide gas, nitrogen gas, proton gas and mixtures thereof. 상기 안정제는 구연산, 젖산, 초산, 사과산, 푸마르산, 글루콘산, 케토글루타르산, 호박산 및 그 혼합물로 이루어진 군에서 선택되고, The stabilizer is selected from the group consisting of citric acid, lactic acid, acetic acid, malic acid, fumaric acid, gluconic acid, ketoglutaric acid, succinic acid and mixtures thereof, 상기 거품분사식 방충제의 거품이 완전 소포되는 데 걸리는 시간은 분사 후 10 초 내지 30 분인 것을 특징으로 하는 거품분사식 방충제.Foam blowing insect repellent, characterized in that the time it takes for the foam of the foaming insect repellent is completely defoamed 10 seconds to 30 minutes after the injection. 삭제delete 삭제delete 청구항 1에 있어서, The method according to claim 1, 상기 방충제는 d-T80-시페노트린 : (±)-α-시아노-3-페녹시벤질(+)-cis/trans-크리산테메이트 [스미토모가가쿠고교], 아레스린 : 3-알릴-2-메틸시클로펜타-2-엔-4-온-1-일 dl-시스/트랜스-크리산테마트 [피나민, 스미토모가가쿠고교], dl·d-T80-아레스린 : 3-알릴-2-메틸시클로펜타-2-엔-4-온-1-일 d-시스/트랜스-크리산테마트 [피나민포르테, 스미토모가가쿠고교], dl·d-T-아레스린 : 3-알릴-2-메틸시클로펜타-2-엔-4-온-1-일 d-트랜스-크리산테마트(바이오아레스린), d·d-T-아레스린 : d-3-알릴-2-메틸시클로펜타-2-엔-4-온-1-일 d-트랜스-크리산테마트(에스비올), d·d-T80-프라레트린 : d-2-메틸-4-옥소-3-프로피닐시클로펜토-2-에닐 d-시스/트랜스-크리산테마트 [에톡, 스미토모가가쿠고교], 프탈스린 : N-(3,4,5,6-테트라히드로프탈리미드)-메틸 dl-시스/트랜스-크리산테마트 [네오피나민,스미토모가가쿠고교], dl·d-T80-프탈스린 : N-(3,4,5,6-테트라히드로프탈리미드)-메틸 d-시스/트랜스-크리산테마트 [네오피나민포르테, 스미토모가가쿠고교], 레스메트린 : 5-벤질-3-프릴메틸 dl-시스/트랜스-크리산테마트[크리슬론, 스미토모가가쿠고교], dl·d-T80-레스메트린 : 5-벤질-3-프릴메틸 d-시스/트랜스-크리산테마트[크리슬론포르테, 스미토모가가쿠고교], 프라메트린 : 5-(2-프로피닐)-3-프릴메틸 크리산테마트 [피나민 D, 스미토모가가쿠고교], 펠메트린 : 3-페녹시벤질 dl-시스/트랜스-2,2-디메틸-3-(2,2-디클로로비닐)시클로프로판카르복시라트 [엑스민, 스미토모가가쿠고교], 페노트린 : 3-페녹시벤질 d-시스/트랜스-크리산테마트 [스미스린, 스미토모가 가쿠고교], 펜바렐레이트 : α-시아노-3-페녹시벤질-2-(4-클로로페닐)-3-메틸부틸레이트 [스미사이딘, 스미토모가가쿠고교], 시펠메트린 : α-시아노-3-페녹시벤질 dl-시스/트랜스-3-(2,2-디클로로비닐)-2,2-디메틸시클로프로판카르복시라트 [아글로스린, 스미토모가가쿠고교], 시페노트린 : α-시아노-3-페녹시벤질 d-시스/트랜스-크리산테마트 [고키라트, 스미토모가가쿠고교], 이미프로트린 : [2,5-디옥소-3-(2-프로피닐)-1-이미다졸리디닐] 메틸 (1R)-cis-트랜스크리산테메이트 [프랄, 스미토모가가쿠고교], 에토펜프록스 : 2-(4-에톡시페닐)-2-메틸프로필-3-페녹시벤질에테르 [트레본, 미쓰이도아츠가가쿠], 테플스린 : 2,3,5,6-테트라플루오로-4-메틸벤질-3-(2-클로로-3,3,3-트리플루오로-1-프로페닐)-2,2-디메틸-1-시클로프로판칼복시라트, 펜프로파트린 : α-시아노-3-페녹시벤질 시스/트랜스-2,2,3,3-테트라메틸시클로프로판카르복시라트, 펜플스린 : 2,3,4,5,6-펜타플루오로벤질-dl-시스/트랜스 3-(2,2-디클로로비닐)2,2-디메틸-1-시클로프로판카르복시라트, 디에칠톨루아미드 : N,N-디에틸-meta-톨루아미드, 퍼메트린 : [3-페녹시벤질 (1RS)-cis,trans-3-(2,2-디클로로비닐)-2,2-디메틸시클로-프로판카르복실레이트], 알파싸이퍼메트린 : [1a(S*), 3a]-(-시아노(3-페녹시페닐)메틸 3-(2, 2-디클로로에테닐)-2,2-디메틸시클로프로판카르복실레이트, 데카메트린 : [1R-[1a(S*),3a]]-시아노(3-페녹시페닐)메틸3-(2,2-디브로모에테닐)-2,2-디메틸시클로프로판카르복실레이트, 피레트린 : (1S)-2-메틸-4-옥소-3-(2Z)-2,4-펜타디에닐-2-시클로펜텐-1-일 (1R,3R)-3-[(1E)-3-메톡시-2-메틸-3-옥소-1-프로페닐]-2,2-디메틸시클로프로판카르복실레이트, 페니트로치온 : 0,0-디메틸-0-(3-메틸-4-니트로페닐)-티오포스페이트, 프로폭술 : S,S'-(2-디메틸아미노트리메틸렌)bis(티오카르바메이트) 하이드로클로라이드; S,S'-[2-(디메틸아미노)-1,3-프로판디일] 디카르바모티오에이트 하이드로클로라이드, 싸이퍼메트린 : (+/-)alpha-시아노-(3-페녹시페닐)메틸(+)-cis,trans- 3-(2,2-디클로로에테닐)-2,2-디메틸시클로-프로판카르복실레이트, 히드라메칠논 : 테트라히드로-5,5-디메틸-2(1H)-피리미디논 [3-[4-(트리플루오로메틸)페닐]-1-[2-[4-(트리플루오로메틸)페닐]에테닐]-2-프로페닐리덴]히드라존, N,N-디에틸-m-톨아미드(약칭 DEET), 디메틸프탈레이트, 디부틸프탈레이트, 2-에틸-1,3-헥산디올, 디-n-프로필 이소신코멜로네이트, P-디클로로벤젠, 디-n-부틸삭시네이트, 카란-3,4-디올, 1-메틸프로필2-(2-히드록시에틸)-1-피페리딘카르복시라트, 및 그 혼합물로 이루어진 군에서 선택된 것을 특징으로 하는 거품분사식 방충제.The insect repellent is d-T80-cyphenothrin: (±) -α-cyano-3-phenoxybenzyl (+)-cis / trans-crylate temate [Sumitomogagaku Kogyo], aresrin: 3-allyl- 2-methylcyclopenta-2-en-4-one-1-yl dl-cis / trans-Chrysanthate [Pinamin, Sumitomogagaku Kogyo], dl-d-T80-Asrin: 3-allyl-2 -Methylcyclopenta-2-en-4-one-1-yl d-cis / trans-crysantemat [pinamine forte, Sumitomogagaku Kogyo], dl-dT- arerin: 3-allyl-2-methyl Cyclopenta-2-en-4-one- 1-yl d-trans-Chrysanthemat (Bio Arerin), d-dT-Aresrin: d-3-allyl-2-methylcyclopenta-2-ene- 4-on-1-yl d-trans-crysantemat (esbiol), d-d80-prarethrin: d-2-methyl-4-oxo-3-propynylcyclopento-2-enyl d -Cis / trans-Chrysanthate [Etok, Sumitomogagaku Kogyo], phthalinsine: N- (3,4,5,6-tetrahydrophthalimide) -methyl dl-cis / trans-Chrysanthate [ Neofinamin Tomogagaku High School], dl.d-T80-phthaline: N- (3,4,5,6-tetrahydrophthalimide) -methyl d-cis / trans-Chrysanthate [neopinaminforte, Sumitomogagaku High School], Resmethrin: 5-benzyl-3-primethylmethyl dl-cis / trans-Chrysanthate [Chrislon, Sumitomogagaku High School], dl-d80-resmethrin: 5-benzyl -3-primethylmethyl d-cis / trans-Chrysanthate [Chryslon Forte, Sumitomogagaku Kogyo], pramethrin: 5- (2-propynyl) -3-primethylmethyl chrysanthate [Pinamin D, Sumitomogagaku Kogyo Co., Ltd., Pelmetrin: 3-phenoxybenzyl dl-cis / trans-2,2-dimethyl-3- (2,2-dichlorovinyl) cyclopropanecarboxylated [Xmine, Sumitomogagaku Co., Ltd.] , Phenotrine: 3-phenoxybenzyl d-cis / trans-Chrysanthate [Smithrin, Sumitomoga Kaku Kogyo], fenbarrelate: α-cyano-3-phenoxybenzyl-2- (4-chloro Phenyl) -3-methylbutylate [Smicidine, Sumitomo Gaku Kogyo, Ciffelmethrin: α-cyano-3-phenoxybenzyl dl-cis / trans-3- (2,2-dichlorovinyl) -2,2-dimethylcyclopropanecarboxylated [Agglosrin, Sumitomo Kagaku High School], Cifenotrine: α-cyano-3-phenoxybenzyl d-cis / trans-Chrysanthate [Gokirat, Sumitomogagaku High School], Imiprotrin: [2,5-dioxo -3- (2-propynyl) -1-imidazolidinyl] methyl (1R) -cis-transsanthatemate [pral, Sumitomogagaku Kogyo], etofenprox: 2- (4-ethoxyphenyl) -2-Methylpropyl-3-phenoxybenzyl ether [Treborn, Mitsui Adogagaku], Teflin: 2,3,5,6-tetrafluoro-4-methylbenzyl-3- (2-chloro -3,3,3-trifluoro-1-propenyl) -2,2-dimethyl-1-cyclopropanekalboxyrat, phenpropatrine: α-cyano-3-phenoxybenzyl cis / trans- 2,2,3,3-tetramethylcyclopropanecarboxylated, penfleslin: 2,3,4,5,6-pentafluorobenzyl-dl-cis / trat 3- (2,2-dichlorovinyl) 2,2-dimethyl-1-cyclopropanecarboxylate, diethylluamide: N, N-diethyl-meta-toluamide, permethrin: [3-phenoxybenzyl (1RS) -cis, trans-3- (2,2-dichlorovinyl) -2,2-dimethylcyclo-propanecarboxylate], alpha ciphermethrin: [1a (S *), 3a]-(-cyano (3-phenoxyphenyl) methyl 3- (2,2-dichloroethenyl) -2,2-dimethylcyclopropanecarboxylate, decametrine: [1R- [1a (S *), 3a]]-sia No (3-phenoxyphenyl) methyl3- (2,2-dibromoethenyl) -2,2-dimethylcyclopropanecarboxylate, pyrethrin: (1S) -2-methyl-4-oxo-3- (2Z) -2,4-pentadienyl-2-cyclopenten-1-yl (1R, 3R) -3-[(1E) -3-methoxy-2-methyl-3-oxo-1-propenyl ] -2,2-dimethylcyclopropanecarboxylate, phenytrothion: 0,0-dimethyl-0- (3-methyl-4-nitrophenyl) -thiophosphate, propoxyl: S, S '-(2- Dimethylaminotrimethylene) bis (thiocarbamate) hydrochlora DE; S, S '-[2- (dimethylamino) -1,3-propanediyl] dicarbamothioate hydrochloride, ciphermethrin: (+/-) alpha-cyano- (3-phenoxyphenyl) methyl ( +)-cis, trans- 3- (2,2-dichloroethenyl) -2,2-dimethylcyclo-propanecarboxylate, hydramcinolone: tetrahydro-5,5-dimethyl-2 (1H) -pyri Midinone [3- [4- (trifluoromethyl) phenyl] -1- [2- [4- (trifluoromethyl) phenyl] ethenyl] -2-propenylidene] hydrazone, N, N- Diethyl-m-tolamide (abbreviated DEET), dimethylphthalate, dibutylphthalate, 2-ethyl-1,3-hexanediol, di-n-propyl isosyncomellonate, P-dichlorobenzene, di-n-butyl A foam jet insect repellent, characterized in that selected from the group consisting of saxinate, caran-3,4-diol, 1-methylpropyl2- (2-hydroxyethyl) -1-piperidinecarboxylate, and mixtures thereof. 삭제delete
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05238903A (en) * 1991-03-15 1993-09-17 Dainippon Jochugiku Co Ltd Foaming aerosol insecticide and its application
JP2000247803A (en) * 1999-02-25 2000-09-12 Takeda Engei Kk Dual-structured aerosol for agricultural and horticultural use
JP2002114614A (en) * 2000-07-31 2002-04-16 Chugai Pharmaceut Co Ltd Foaming agent for controlling mite and flea, method for controlling mite and flea using the same foaming agent and method for cleaning
KR100712937B1 (en) * 1999-07-09 2007-05-02 후마킬라 가부시키가이샤 Foamed aerosol

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05238903A (en) * 1991-03-15 1993-09-17 Dainippon Jochugiku Co Ltd Foaming aerosol insecticide and its application
JP2000247803A (en) * 1999-02-25 2000-09-12 Takeda Engei Kk Dual-structured aerosol for agricultural and horticultural use
KR100712937B1 (en) * 1999-07-09 2007-05-02 후마킬라 가부시키가이샤 Foamed aerosol
JP2002114614A (en) * 2000-07-31 2002-04-16 Chugai Pharmaceut Co Ltd Foaming agent for controlling mite and flea, method for controlling mite and flea using the same foaming agent and method for cleaning

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