JPH10287504A - Aerosol - Google Patents
AerosolInfo
- Publication number
- JPH10287504A JPH10287504A JP9090910A JP9091097A JPH10287504A JP H10287504 A JPH10287504 A JP H10287504A JP 9090910 A JP9090910 A JP 9090910A JP 9091097 A JP9091097 A JP 9091097A JP H10287504 A JPH10287504 A JP H10287504A
- Authority
- JP
- Japan
- Prior art keywords
- aerosol
- solvent
- present
- injection
- propellant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000443 aerosol Substances 0.000 title claims abstract description 99
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 48
- 239000002904 solvent Substances 0.000 claims abstract description 45
- 239000003380 propellant Substances 0.000 claims abstract description 30
- 238000002347 injection Methods 0.000 claims description 69
- 239000007924 injection Substances 0.000 claims description 69
- 239000011550 stock solution Substances 0.000 claims description 28
- 239000000575 pesticide Substances 0.000 claims description 9
- 239000002917 insecticide Substances 0.000 abstract description 35
- 230000000749 insecticidal effect Effects 0.000 abstract description 17
- 241000238631 Hexapoda Species 0.000 abstract description 12
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 abstract description 8
- 239000003350 kerosene Substances 0.000 abstract description 7
- 239000004094 surface-active agent Substances 0.000 abstract description 6
- VPRAQYXPZIFIOH-UHFFFAOYSA-N imiprothrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)N(CC#C)CC1=O VPRAQYXPZIFIOH-UHFFFAOYSA-N 0.000 abstract description 5
- 239000005871 repellent Substances 0.000 abstract description 3
- 230000002940 repellent Effects 0.000 abstract description 3
- 239000004599 antimicrobial Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000002383 tung oil Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 23
- 241000238876 Acari Species 0.000 description 13
- -1 empentrin Chemical compound 0.000 description 12
- 230000001965 increasing effect Effects 0.000 description 11
- 241000238662 Blatta orientalis Species 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 239000004480 active ingredient Substances 0.000 description 6
- 238000003197 gene knockdown Methods 0.000 description 6
- 241000238713 Dermatophagoides farinae Species 0.000 description 5
- 241000255925 Diptera Species 0.000 description 5
- 238000005070 sampling Methods 0.000 description 5
- 241000238657 Blattella germanica Species 0.000 description 4
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 241001674044 Blattodea Species 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 241000257303 Hymenoptera Species 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000003915 liquefied petroleum gas Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229930003658 monoterpene Natural products 0.000 description 3
- 235000002577 monoterpenes Nutrition 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000002728 pyrethroid Substances 0.000 description 3
- 239000000741 silica gel Substances 0.000 description 3
- 229910002027 silica gel Inorganic materials 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000000341 volatile oil Substances 0.000 description 3
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 2
- 101100327917 Caenorhabditis elegans chup-1 gene Proteins 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 241000254173 Coleoptera Species 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- FUWUEFKEXZQKKA-UHFFFAOYSA-N beta-thujaplicin Chemical compound CC(C)C=1C=CC=C(O)C(=O)C=1 FUWUEFKEXZQKKA-UHFFFAOYSA-N 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- 239000000073 carbamate insecticide Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- YPHMISFOHDHNIV-FSZOTQKASA-N cycloheximide Chemical compound C1[C@@H](C)C[C@H](C)C(=O)[C@@H]1[C@H](O)CC1CC(=O)NC(=O)C1 YPHMISFOHDHNIV-FSZOTQKASA-N 0.000 description 2
- 239000002781 deodorant agent Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 2
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 2
- 239000005556 hormone Substances 0.000 description 2
- 229940088597 hormone Drugs 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229940124530 sulfonamide Drugs 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 description 1
- FJDPATXIBIBRIM-QFMSAKRMSA-N (1R)-trans-cyphenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 FJDPATXIBIBRIM-QFMSAKRMSA-N 0.000 description 1
- SBNFWQZLDJGRLK-RTWAWAEBSA-N (1R)-trans-phenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-RTWAWAEBSA-N 0.000 description 1
- ZMKHZNCBQCXECQ-UHFFFAOYSA-N (2,4-dimethyl-4h-1,3-dioxin-6-yl) acetate Chemical compound CC1OC(C)C=C(OC(C)=O)O1 ZMKHZNCBQCXECQ-UHFFFAOYSA-N 0.000 description 1
- SDOFMBGMRVAJNF-KVTDHHQDSA-N (2r,3r,4r,5r)-6-aminohexane-1,2,3,4,5-pentol Chemical compound NC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO SDOFMBGMRVAJNF-KVTDHHQDSA-N 0.000 description 1
- ZFHGXWPMULPQSE-SZGBIDFHSA-N (Z)-(1S)-cis-tefluthrin Chemical compound FC1=C(F)C(C)=C(F)C(F)=C1COC(=O)[C@@H]1C(C)(C)[C@@H]1\C=C(/Cl)C(F)(F)F ZFHGXWPMULPQSE-SZGBIDFHSA-N 0.000 description 1
- LNJXZKBHJZAIKQ-UHFFFAOYSA-N 1,1,1,2-tetrachloro-3-(2,3,3,3-tetrachloropropoxy)propane Chemical compound ClC(Cl)(Cl)C(Cl)COCC(Cl)C(Cl)(Cl)Cl LNJXZKBHJZAIKQ-UHFFFAOYSA-N 0.000 description 1
- UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 description 1
- WXGNWUVNYMJENI-UHFFFAOYSA-N 1,1,2,2-tetrafluoroethane Chemical compound FC(F)C(F)F WXGNWUVNYMJENI-UHFFFAOYSA-N 0.000 description 1
- GNEPLYVYORHREW-UHFFFAOYSA-N 1,1,3,3,6-pentamethyl-7-nitro-2h-inden-5-amine Chemical compound CC1=C(N)C=C2C(C)(C)CC(C)(C)C2=C1[N+]([O-])=O GNEPLYVYORHREW-UHFFFAOYSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 1
- NFGXHKASABOEEW-UHFFFAOYSA-N 1-methylethyl 11-methoxy-3,7,11-trimethyl-2,4-dodecadienoate Chemical compound COC(C)(C)CCCC(C)CC=CC(C)=CC(=O)OC(C)C NFGXHKASABOEEW-UHFFFAOYSA-N 0.000 description 1
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- NCDBYAPSWOPDRN-UHFFFAOYSA-N 2-[dichloro(fluoro)methyl]sulfanylisoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(SC(Cl)(Cl)F)C(=O)C2=C1 NCDBYAPSWOPDRN-UHFFFAOYSA-N 0.000 description 1
- KQYRYPXQPKPVSP-UHFFFAOYSA-N 2-butylhexanoic acid Chemical compound CCCCC(C(O)=O)CCCC KQYRYPXQPKPVSP-UHFFFAOYSA-N 0.000 description 1
- WTIBVHDUWJIUJE-UHFFFAOYSA-N 2-hydroxyethyl octyl sulfate Chemical compound CCCCCCCCOS(=O)(=O)OCCO WTIBVHDUWJIUJE-UHFFFAOYSA-N 0.000 description 1
- TWAJMNWATCLYSK-UHFFFAOYSA-N 2-methylidenepropanedinitrile 2-nitroethenylbenzene Chemical compound C(#N)C(C#N)=C.[N+](=O)([O-])C=CC1=CC=CC=C1 TWAJMNWATCLYSK-UHFFFAOYSA-N 0.000 description 1
- IMOYOUMVYICGCA-UHFFFAOYSA-N 2-tert-butyl-4-hydroxyanisole Chemical compound COC1=CC=C(O)C=C1C(C)(C)C IMOYOUMVYICGCA-UHFFFAOYSA-N 0.000 description 1
- MRBKEAMVRSLQPH-UHFFFAOYSA-N 3-tert-butyl-4-hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1 MRBKEAMVRSLQPH-UHFFFAOYSA-N 0.000 description 1
- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 description 1
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 241000239290 Araneae Species 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 241001034435 Brevipalpus obovatus Species 0.000 description 1
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 1
- 241000257161 Calliphoridae Species 0.000 description 1
- 241000218645 Cedrus Species 0.000 description 1
- 241000258920 Chilopoda Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000005944 Chlorpyrifos Substances 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- HNWYKYCMOGXBJW-UHFFFAOYSA-N Cl.C(CCC)[Sn](CCCC)CCCC Chemical compound Cl.C(CCC)[Sn](CCCC)CCCC HNWYKYCMOGXBJW-UHFFFAOYSA-N 0.000 description 1
- 241000256059 Culex pipiens Species 0.000 description 1
- 240000004784 Cymbopogon citratus Species 0.000 description 1
- 235000017897 Cymbopogon citratus Nutrition 0.000 description 1
- 244000166675 Cymbopogon nardus Species 0.000 description 1
- 235000018791 Cymbopogon nardus Nutrition 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical class CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 241000258963 Diplopoda Species 0.000 description 1
- UPEZCKBFRMILAV-JNEQICEOSA-N Ecdysone Natural products O=C1[C@H]2[C@@](C)([C@@H]3C([C@@]4(O)[C@@](C)([C@H]([C@H]([C@@H](O)CCC(O)(C)C)C)CC4)CC3)=C1)C[C@H](O)[C@H](O)C2 UPEZCKBFRMILAV-JNEQICEOSA-N 0.000 description 1
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- MMOXZBCLCQITDF-UHFFFAOYSA-N N,N-diethyl-m-toluamide Chemical compound CCN(CC)C(=O)C1=CC=CC(C)=C1 MMOXZBCLCQITDF-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
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- 241001510001 Periplaneta brunnea Species 0.000 description 1
- 241001510010 Periplaneta fuliginosa Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241001674048 Phthiraptera Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
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- ISRUGXGCCGIOQO-UHFFFAOYSA-N Rhoden Chemical compound CNC(=O)OC1=CC=CC=C1OC(C)C ISRUGXGCCGIOQO-UHFFFAOYSA-N 0.000 description 1
- 241000545593 Scolytinae Species 0.000 description 1
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- 239000005939 Tefluthrin Substances 0.000 description 1
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- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- 241001222097 Xenocypris argentea Species 0.000 description 1
- HHPJUPFYSPRRDT-UHFFFAOYSA-N [butyl-[4-(2,2-dimethyl-3H-1-benzofuran-7-yl)butyl]amino]sulfanyl-methylcarbamic acid Chemical compound CCCCN(CCCCC1=CC=CC2=C1OC(C2)(C)C)SN(C)C(=O)O HHPJUPFYSPRRDT-UHFFFAOYSA-N 0.000 description 1
- 229940024113 allethrin Drugs 0.000 description 1
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- 150000001408 amides Chemical class 0.000 description 1
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- 238000004458 analytical method Methods 0.000 description 1
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- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000003388 anti-hormonal effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229960005286 carbaryl Drugs 0.000 description 1
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 description 1
- 150000001851 cinnamic acid derivatives Chemical class 0.000 description 1
- WJSDHUCWMSHDCR-VMPITWQZSA-N cinnamyl acetate Natural products CC(=O)OC\C=C\C1=CC=CC=C1 WJSDHUCWMSHDCR-VMPITWQZSA-N 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- WCMMILVIRZAPLE-UHFFFAOYSA-M cyhexatin Chemical compound C1CCCCC1[Sn](C1CCCCC1)(O)C1CCCCC1 WCMMILVIRZAPLE-UHFFFAOYSA-M 0.000 description 1
- NMCCNOZOBBWFMN-UHFFFAOYSA-N davicil Chemical compound CS(=O)(=O)C1=C(Cl)C(Cl)=NC(Cl)=C1Cl NMCCNOZOBBWFMN-UHFFFAOYSA-N 0.000 description 1
- 230000034994 death Effects 0.000 description 1
- 231100000517 death Toxicity 0.000 description 1
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 1
- 229950001327 dichlorvos Drugs 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- HXTCWLNZDIPLCA-UHFFFAOYSA-N dodecanoic acid;2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.CCCCCCCCCCCC(O)=O HXTCWLNZDIPLCA-UHFFFAOYSA-N 0.000 description 1
- UPEZCKBFRMILAV-JMZLNJERSA-N ecdysone Chemical compound C1[C@@H](O)[C@@H](O)C[C@]2(C)[C@@H](CC[C@@]3([C@@H]([C@@H]([C@H](O)CCC(C)(C)O)C)CC[C@]33O)C)C3=CC(=O)[C@@H]21 UPEZCKBFRMILAV-JMZLNJERSA-N 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
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Landscapes
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- Catching Or Destruction (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、害虫を防除するエ
アゾール、好ましくは大量噴射型エアゾールに関する。
詳しくは、エアゾール噴射後の害虫の移動距離を顕著に
抑制でき、且つ優れた殺虫効果を有するエアゾールに関
する。The present invention relates to an aerosol for controlling pests, preferably a mass jet aerosol.
More specifically, the present invention relates to an aerosol that can significantly suppress the moving distance of a pest after aerosol injection and has an excellent insecticidal effect.
【０００２】[0002]
【従来技術】害虫を防除する為に用いられる製剤の１つ
としてエアゾールが挙げられる。エアゾールは従来から
広く知られており、その使用が簡単であることから商品
としても多くが上市されている。そしてこれらはその効
力を高めるための手段について様々な検討がなされてお
り、例えば、殺虫効力の強い殺虫剤を有効成分として用
いたり、殺虫剤を含む原液の組成物について検討した
り、噴射量を調整するなどが行われている。2. Description of the Related Art One of the preparations used for controlling pests is an aerosol. Aerosols have been widely known in the past, and many of them have been put on the market because of their easy use. Various studies have been made on means for increasing their efficacy, for example, using an insecticide having a strong insecticidal effect as an active ingredient, examining the composition of a stock solution containing an insecticide, and measuring the injection amount. Adjustments have been made.
【０００３】[0003]
【発明が解決しようとする課題】ところが、対象とする
害虫に対するエアゾールの効果は、常に使用者の満足で
きるものとは限らず、害虫の殺虫剤に対する抵抗性の発
生、生活環境の変化、さらには法律上の規制などによっ
て変化している。その為に、従来より優れたエアゾール
の開発がしばしば望まれている。例えば、ゴキブリなど
の害虫は、俊敏性が高く、更に殺虫剤に対する抵抗性が
発生しやすいことから、エアゾールを噴射しても、害虫
は暫く移動してしまう。これに対して多くの使用者は、
害虫がノックダウンするまで更に繰り返しエアゾールを
噴射することになる。このように繰り返し噴射すると、
エアゾールを無駄に使用することになるばかりか、使用
者の生活環境をも悪化させてしまう。However, the effect of the aerosol on the target pest is not always satisfactory for the user, and the resistance of the pest to the insecticide, the change in the living environment, and the effect of the aerosol on the pest are not always satisfactory. It is changing due to legal regulations. Therefore, it is often desired to develop an aerosol that is superior to the conventional aerosol. For example, pests such as cockroaches have high agility and are liable to develop resistance to pesticides. Therefore, even if an aerosol is sprayed, the pests move for a while. Many users, on the other hand,
The aerosol will be sprayed repeatedly until the pest knocks down. Repeated injection in this way,
Not only will the aerosol be wasted, but it will also worsen the living environment of the user.
【０００４】本発明の目的は、上記の欠点を解決した従
来より優れた新たなエアゾールを提供することにある。
本発明の更なる目的は、エアゾール噴射後の害虫の移動
距離を抑制でき、それによってエアゾールの無駄な使用
を減らすことができ且つ環境衛生上好ましく、更に殺虫
効果が優れるエアゾールを提供することにある。[0004] An object of the present invention is to provide a new aerosol which is superior to the conventional one and which solves the above-mentioned drawbacks.
It is a further object of the present invention to provide an aerosol which can reduce the moving distance of the pests after aerosol injection, thereby reducing wasteful use of the aerosol, and which is preferable in terms of environmental hygiene and further has an excellent insecticidal effect. .
【０００５】[0005]
【課題を解決するための手段】本発明者らは鋭意検討し
た結果、下記の特定の構成のエアゾールによって上記の
目的を達成することを見いだし、本発明に到達した。 （１） 殺虫剤と溶剤を含む原液及び噴射剤を含有し、
害虫を防除するエアゾールにおいて、該原液と噴射剤と
の割合（ｖ／ｖ）が１：３〜１：５であり、溶剤の噴射
量が４．０ｍｌ／１０秒以上であることを特徴とするエ
アゾール。 （２） 大量噴射型であることを特徴とする上記（１）
に記載のエアゾール。Means for Solving the Problems As a result of intensive studies, the present inventors have found that the above-mentioned object is achieved by an aerosol having the following specific structure, and have reached the present invention. (1) It contains a stock solution containing a pesticide and a solvent and a propellant,
In the aerosol for controlling pests, the ratio (v / v) between the stock solution and the propellant is 1: 3 to 1: 5, and the injection amount of the solvent is 4.0 ml / 10 seconds or more. aerosol. (2) The above (1) characterized in that it is a mass injection type.
The aerosol according to the above.
【０００６】本発明は、エアゾールにおいて原液と噴射
剤の割合（ｖ／ｖ）を特定の範囲に設定し、且つ原液に
含まれる溶剤の噴射量を４．０ｍｌ／１０秒とすること
により、エアゾールを害虫に対して噴射処理した場所か
らの害虫の移動を顕著に抑制する効果を有し、且つ優れ
た殺虫効果を発揮するエアゾールを提供することができ
る。具体的には、本発明のエアゾールを害虫に向かって
噴射すると、とりわけゴキブリなど徘徊行動をとり、俊
敏性の高いタイプの害虫に対して、その場からほとんど
移動することなくその活動を停止させることができ、且
つその害虫を有効に殺虫することができる。According to the present invention, the ratio of the stock solution and the propellant (v / v) in the aerosol is set in a specific range, and the injection amount of the solvent contained in the stock solution is set to 4.0 ml / 10 seconds, thereby making the aerosol. It is possible to provide an aerosol which has an effect of remarkably suppressing the movement of the pest from the place where the pest was sprayed on the pest, and which exhibits an excellent insecticidal effect. Specifically, when the aerosol of the present invention is sprayed toward a pest, it particularly wanders, such as a cockroach, and stops the activity of a highly aggressive type of pest without moving almost from the place. And the pests can be effectively killed.
【０００７】前述の如く、従来のエアゾールでは、噴射
処理をしてもその場所から害虫があちこちに移動するの
で、その活動が停止するまでエアゾールの噴射を続けて
しまう。しかしながら、本発明においては、エアゾール
を害虫に対して噴射処理した場所からの害虫の移動を抑
制することができるので、噴射する回数を減らすことが
でき、エアゾールの消費を少なくでき、無駄をなくすこ
とができる。そして効果的に害虫をノックダウンさせる
ことができるので、周囲環境へ噴射するエアゾールの量
が適正となり、人の生活環境の汚染を抑制できるという
有用性がもたらされる。As described above, in the conventional aerosol, even when the spraying process is performed, the pests move from the place to the next place, so that the spraying of the aerosol is continued until the activity stops. However, in the present invention, since the movement of the pest from the place where the aerosol has been sprayed against the pest can be suppressed, the number of times of spraying can be reduced, the consumption of the aerosol can be reduced, and the waste can be eliminated. Can be. Since the pests can be effectively knocked down, the amount of the aerosol sprayed to the surrounding environment becomes appropriate, and the usefulness that the pollution of the living environment of humans can be suppressed is brought.
【０００８】エアゾールにおいて、殺虫剤の量を増やす
ことなく原液中の溶剤の量を従来よりも増やし、原液と
噴射剤との割合〔ｖ／ｖ（容量／容量）〕を１：３〜
１：５に調整し、エアゾールを噴射した際の溶剤の噴射
量を１０秒あたり４．０ｍｌ以上とすることにより、噴
射された原液中の殺虫剤と所定量の溶剤が有効に相互作
用し、害虫に対して相乗効果的に作用して、素早く且つ
効果的に害虫をノックダウンさせることができ、且つ優
れた殺虫効果を発現させることができたものと考えられ
る。本発明の効果において、上記エアゾール噴射後の害
虫の移動距離の抑制効果は、単なる殺虫効果とは異質の
ものである（即ち、殺虫効果が優れたものでも、エアゾ
ール噴射後の害虫の移動距離の抑制効果が良くなるとは
限らない）。In the aerosol, the amount of the solvent in the stock solution is increased without increasing the amount of the insecticide and the ratio of the stock solution to the propellant [v / v (volume / volume)] is 1: 3 to
The insecticide in the injected stock solution and the predetermined amount of the solvent effectively interact by adjusting the ratio to 1: 5 and setting the injection amount of the solvent when the aerosol is injected to 4.0 ml or more per 10 seconds, It is considered that they acted synergistically on the pests, were able to knock down the pests quickly and effectively, and exhibited an excellent insecticidal effect. In the effect of the present invention, the effect of suppressing the moving distance of the pest after the aerosol injection is different from the mere insecticidal effect (that is, even if the insecticidal effect is excellent, the moving distance of the pest after the aerosol injection is reduced. The suppression effect is not always better).
【０００９】[0009]
【発明の実施の形態】本発明における殺虫剤と溶剤を含
む原液と噴射剤との割合（ｖ／ｖ）は、１：３〜１：５
となるように調整すればよい。本発明において、前記割
合（ｖ／ｖ）が１：３未満であると、エアゾール噴射後
の害虫の移動距離の抑制効果が不十分となる。また、前
記割合（ｖ／ｖ）が１：５を越えると、エアゾール噴射
後の害虫の移動距離の抑制効果が不十分となる。更に十
分な殺虫効果を得られないことがある。BEST MODE FOR CARRYING OUT THE INVENTION In the present invention, the ratio (v / v) of a stock solution containing an insecticide and a solvent to a propellant is 1: 3 to 1: 5.
It may be adjusted so that In the present invention, if the ratio (v / v) is less than 1: 3, the effect of suppressing the moving distance of the pest after aerosol injection becomes insufficient. On the other hand, if the ratio (v / v) exceeds 1: 5, the effect of suppressing the moving distance of the pest after the aerosol injection becomes insufficient. Further, a sufficient insecticidal effect may not be obtained.
【００１０】本発明のエアゾールはそれを噴射した際の
溶剤の噴射量が４．０ｍｌ／１０秒以上となる。ここ
で、溶剤の噴射量としては、５．０ｍｌ／１０秒以上が
好ましく、より好ましくは６．０ｍｌ／１０秒以上であ
る。溶剤の噴射量としては、上限としては、本発明の効
果が奏されている量であれば特に制限はされないが、好
ましくは１０．０ｍｌ／１０秒程度である。溶剤の噴射
量が４．０ｍｌ／１０秒未満であると、エアゾール噴射
後の害虫の移動距離の抑制効果、更に殺虫効果が不十分
となる。The aerosol of the present invention has a solvent injection amount of 4.0 ml / 10 seconds or more when injected. Here, the injection amount of the solvent is preferably 5.0 ml / 10 seconds or more, and more preferably 6.0 ml / 10 seconds or more. The upper limit of the solvent injection amount is not particularly limited as long as the effect of the present invention is exerted, but is preferably about 10.0 ml / 10 seconds. When the injection amount of the solvent is less than 4.0 ml / 10 seconds, the effect of suppressing the moving distance of the pest after the aerosol injection and the insecticidal effect become insufficient.
【００１１】更に、本発明のエアゾールは、大量噴射型
であることが好ましい。これにより本発明の効果がより
有効に発現されるようになる。本発明において、大量噴
射型とは、従来のエアゾールの噴射量と比べて、単位時
間当りの噴射量が３〜７倍程度に増大されたことを意味
し、具体的には全体の噴射量が、好ましくは２０〜１０
０ｍｌ／１０秒であり、より好ましくは２５〜７０ｍｌ
／１０秒であることを意味する。上記の溶剤及びエアゾ
ール全体の噴射量は１０秒あたりに噴射される量を意味
し、エアゾールを１０秒間噴射し、その間に噴射された
溶剤又は噴射物の量を測定することにより得られる。こ
のような大量噴射を可能とするための手段としては、目
的とする噴射が可能となるバルブ孔径やボタン孔径を選
択したり、噴射圧を調整するなどの手段があるが本発明
にいう大量噴射が可能となる手段を選べばよい。Furthermore, the aerosol of the present invention is preferably of a mass injection type. Thereby, the effect of the present invention can be more effectively exhibited. In the present invention, the term “mass injection type” means that the injection amount per unit time is increased to about 3 to 7 times as compared with the injection amount of the conventional aerosol. , Preferably 20 to 10
0 ml / 10 seconds, more preferably 25 to 70 ml
/ 10 seconds. The above-mentioned injection amount of the solvent and the entire aerosol means an amount to be injected per 10 seconds, and is obtained by injecting the aerosol for 10 seconds and measuring the amount of the solvent or the injected material during the injection. As means for enabling such large-volume injection, there is a means for selecting a valve hole diameter or a button hole diameter capable of performing a target injection, or adjusting an injection pressure. What is necessary is just to choose the means which becomes possible.
【００１２】本発明において、原液と噴射剤との特定の
割合（ｖ／ｖ）、溶剤の噴射量及び大量噴射型と、本発
明の効果との関係を本発明の具体例を挙げて更に説明す
れば次のとおりである。 （Ａ）殺虫剤を０．５グラム含む原液５０ｍｌ（溶剤で
トータル５０ｍｌとする）と噴射剤２５０ｍｌからなる
大量噴射型エアゾール〔原液と噴射剤との割合（容
量）、１：５．００〕。 （Ｂ）殺虫剤を０．５グラム含む原液７０ｍｌ（溶剤で
トータル７０ｍｌとする）と噴射剤２３０ｍｌからなる
大量噴射型エアゾール〔原液と噴射剤との割合（容
量）、１：３．３３〕。In the present invention, the relationship between the specific ratio (v / v) of the undiluted solution and the propellant, the injection amount of the solvent and the mass injection type, and the effects of the present invention will be further described with reference to specific examples of the present invention. It is as follows. (A) A large-volume aerosol [proportion (volume) of stock solution and propellant, 1: 5.00] consisting of 50 ml of stock solution containing 0.5 g of insecticide (total 50 ml with solvent) and 250 ml of propellant. (B) A large-volume aerosol [proportion (volume) of a stock solution and a propellant, 1: 3.33] consisting of 70 ml of a stock solution containing 0.5 g of an insecticide (total 70 ml with a solvent) and 230 ml of a propellant.
【００１３】上記（Ａ）と（Ｂ）のエアゾールは、本発
明における効果を比べたときに、その噴射量が同じで
（例えばどちらも従来のものより３倍程度増大された大
量噴射型）、エアゾール中の殺虫剤の量が同じであって
も、（Ｂ）の方が（Ａ）より優れたものとなる。即ち、
原液中の溶剤の量を増やして噴射剤に対する原液の割合
を特定量増やすことで、溶剤の噴射量がより多くなり、
本発明の効果をさらに増大させることができる。また上
記（Ａ）のエアゾールにおいて、噴射量を増大させた
（例えば５倍程度に）大量噴射型エアゾールを（Ｃ）と
した時、（Ａ）に比して（Ｃ）の噴射量がより多くな
り、効果はより優れたものとなる。本発明においては、
噴射量が大きいほうが好ましい。The aerosols of the above (A) and (B) have the same injection amount when compared with the effects of the present invention (for example, both are a large injection type which is about three times as large as the conventional one), (B) is better than (A), even if the amount of insecticide in the aerosol is the same. That is,
By increasing the amount of solvent in the undiluted solution and increasing the ratio of the undiluted solution to the propellant by a specific amount, the injection amount of the solvent is increased,
The effect of the present invention can be further increased. In the aerosol of the above (A), when the injection amount is increased (for example, about 5 times) and the mass injection type aerosol is (C), the injection amount of (C) is larger than that of (A). And the effect is better. In the present invention,
It is preferable that the injection amount is large.
【００１４】本発明においては、有効成分である殺虫剤
の量は増やさず、従来のエアゾールと比較して噴射後の
雰囲気中の有効成分である殺虫剤の気中濃度は殆ど同じ
であるにもかかわらず、本発明のエアゾールは、上記の
ように噴射後の害虫の移動距離を著しく抑制でき、且つ
その殺虫効果も優れる。このことを具体的に説明する。
本発明のエアゾール（後述の実施例のサンプル２）と従
来のエアゾール（後述の比較例１のサンプル）を噴射し
て、その噴射空間内の殺虫剤（イミプロトリン）の濃度
を求めた。 （測定方法）容積３３ｍ2 （３．５ｍ×３．５ｍ×２．
７ｍ）のチャンバーに、壁から距離１ｍ、高さ１ｍの位
置に、内部にシリカゲル約３ｇが入ったサンプリング管
（直径１５ｍｍ、長さ１０ｃｍ）を取り付ける。このチ
ャンバーの壁から０．５ｍ、高さ０．５ｍの位置より、
上記各エアゾールを、チャンバー内の床と壁の角に向か
って所定時間噴射した。尚、噴射時間は、殺虫剤が噴射
される量を両サンプルにおいて同じになるように設定し
た。上記サンプリング管の位置より、１５リットル／分
で、チャンバー内の空気を３分間吸入して、チャンバー
内の空気中の噴霧粒子をシリカゲルの入ったサンプリン
グ管で均一にトラップする。In the present invention, the amount of the pesticide, which is the active ingredient, is not increased, and the air concentration of the pesticide, which is the active ingredient, in the atmosphere after the injection is almost the same as that of a conventional aerosol. Regardless, as described above, the aerosol of the present invention can significantly suppress the moving distance of the pest after the injection, and also has an excellent insecticidal effect. This will be described specifically.
The aerosol of the present invention (sample 2 of the below-mentioned example) and a conventional aerosol (sample of the below-mentioned comparative example 1) were jetted, and the concentration of the insecticide (imiprothrin) in the jet space was determined. (Measurement method) Volume 33 m 2 (3.5 m × 3.5 m × 2.
At 7 m), a sampling tube (diameter 15 mm, length 10 cm) containing about 3 g of silica gel is attached at a distance of 1 m from the wall and at a height of 1 m. From the position of 0.5m and height 0.5m from the wall of this chamber,
Each of the aerosols was sprayed toward a corner of a floor and a wall in the chamber for a predetermined time. The injection time was set so that the amount of the insecticide to be injected was the same in both samples. The air in the chamber is sucked in from the position of the sampling tube at 15 liter / min for 3 minutes, and the spray particles in the air in the chamber are uniformly trapped by the sampling tube containing silica gel.
【００１５】サンプリングは、噴射直後より所定の間隔
で、２０分間まで行い、シリカゲルにトラップした殺虫
剤を、ガスクロマトグラフィーを用いて分析を行い、次
式により１ｍ3 あたりの殺虫剤の濃度を求めた。 殺虫剤の気中濃度（μｇ／ｍ3 ）＝殺虫剤分析値（μ
ｇ）／〔サンプリング流量（リットル／分）×吸引時間
（分）×１０００〕Sampling is performed at a predetermined interval from the time immediately after the injection to 20 minutes, and the insecticide trapped on the silica gel is analyzed using gas chromatography, and the concentration of the insecticide per 1 m 3 is calculated by the following equation. Was. Aerial concentration of insecticide (μg / m 3 ) = Insecticide analysis value (μ
g) / [Sampling flow rate (l / min) x suction time (min) x 1000]
【００１６】尚、各々のエアゾールにおいて２回の測定
を行い、その平均値をグラフにしたものを図１に示す。
図１は、噴射後の時間と各々のエアゾールの噴射後の殺
虫剤の噴射空間内の気中濃度の関係を示すグラフであ
る。図１をみると明らかなように、本発明のエアゾール
と従来のエアゾールとでは、有効成分である殺虫剤の気
中濃度は殆ど同じであった。従って、このように噴射後
の雰囲気中の有効成分である殺虫剤の気中濃度は殆ど同
じであるにもかかわらず、本発明のサンプルは、後述の
ように噴射後の害虫の移動距離を著しく抑制でき、且つ
その殺虫効果も優れる。従って、本発明の効果は、有効
成分の殺虫剤のみによらず、殺虫剤、溶剤、噴射剤とそ
れら量比、及び噴射量、溶剤の噴射量が適正に相互作用
して、有効に発現されるものである。FIG. 1 is a graph showing the average of two measurements of each aerosol.
FIG. 1 is a graph showing the relationship between the time after the injection and the air concentration in the injection space of the insecticide after the injection of each aerosol. As is clear from FIG. 1, the aerosol of the present invention and the conventional aerosol had almost the same air concentration of the insecticide as an active ingredient. Therefore, despite the fact that the air concentration of the insecticide, which is the active ingredient in the atmosphere after the injection, is almost the same, the sample of the present invention remarkably increases the moving distance of the pest after the injection as described later. It can be suppressed and its insecticidal effect is also excellent. Therefore, the effect of the present invention is effectively expressed not only by the pesticide of the active ingredient, but also by the pesticide, the solvent, the propellant and their ratio, and the injection amount, and the injection amount of the solvent interact properly. Things.
【００１７】尚、本発明のエアゾールは、内容物を一気
に全量噴出させるものではなく、適宜繰り返し噴射して
害虫を防除することのできるエアゾールである。Incidentally, the aerosol of the present invention is not an aerosol which does not eject the entire contents at once, but is capable of controlling pests by repeatedly injecting it appropriately.
【００１８】本発明のエアゾールにおける原液とは、殺
虫剤と溶剤を含み、更にこれらの他に、必要に応じて界
面活性剤などを含む組成物である。殺虫剤としては、ピ
レスロイド系殺虫剤、有機リン系殺虫剤、カーバメイト
系殺虫剤等を挙げることができる。ピレスロイド系殺虫
剤としては、フラメトリン、シフェノトリン、フェノト
リン、ペルメトリン、レスメトリン、アレスリン、フタ
ルスリン、エムペントリン、テフルスリン、プラレトリ
ン、イミプロトリン、トランスフルスリン（ベンフルス
リン）等が挙げられる。有機リン系殺虫剤としては、フ
ェニトロチオン、クロルピリホス、マラソン、ジクロル
ボス、ピリダフェンチオン、トリクロルホン等が挙げら
れる。カーバメイト系殺虫剤としては、カルバリル、ベ
ンフラカルブ、プロポキスル等を挙げることができる。
そして、上記ピレスロイド系化合物の殺虫効力を増強す
る化合物（共力剤）としては、例えばピペロニルブトキ
サイド、オクタクロロジプロピルエーテル、Ｎ−（２−
エチルヘキシル）−１−イソプロピル−４−メチルビシ
クロ〔２，２，２〕オクト−５−エン−２，３−ジカル
ボキシイミド、イソボルニルチオシアノアセテートおよ
びＮ−（２−エチニル）−ビシクロ〔２，２，１〕−ヘ
プタ−５−エン−２，３−ジカルボキシイミドなどが挙
げられる。The undiluted solution in the aerosol of the present invention is a composition containing an insecticide and a solvent, and further, if necessary, a surfactant and the like. Examples of the insecticide include a pyrethroid insecticide, an organic phosphorus insecticide, a carbamate insecticide, and the like. Examples of the pyrethroid insecticide include framethrin, cyphenothrin, phenothrin, permethrin, resmethrin, allethrin, phthalthrin, empentrin, tefluthrin, praletrin, imiprotrin, transfluthrin (benfluthrin) and the like. Examples of the organophosphorus insecticide include fenitrothion, chlorpyrifos, marathon, dichlorvos, pyridafenthion, and trichlorfon. Carbamate insecticides include carbaryl, benfracarb, propoxur and the like.
Examples of the compound (synergist) for enhancing the insecticidal effect of the pyrethroid compound include, for example, piperonyl butoxide, octachlorodipropyl ether, N- (2-
Ethylhexyl) -1-isopropyl-4-methylbicyclo [2,2,2] oct-5-ene-2,3-dicarboximide, isobornylthiocyanoacetate and N- (2-ethynyl) -bicyclo [2 , 2,1] -Hept-5-ene-2,3-dicarboximide and the like.
【００１９】本発明においてこの他の殺虫剤としては、
ヒノキ、スギ及びヒバの精油、メントール、キハダ類の
抽出物、柑橘類の果皮及び種子からの抽出物、芳香族ス
ルフォンアミド誘導体、水酸化トリシクロヘキシル錫、
４，４’−ジブロムベンジル酸イソプロピル、２，３−
ジヒドロ−２，２−ジメチル−７−ベンゾ〔ｂ〕フラニ
ルニ−Ｎ−ジブチルアミノチオ−Ｎ−メチルカーバメイ
ト、シラン化合物、ケイ皮酸誘導体、酢酸シンナミル、
ブフロフェジン、イソプロチオラン、パラオキシ安息香
酸エステル、ヨウ素化ホルマール、フェノール類、フタ
ル酸エステル、３−ブロモ−２，３−ヨード−２−プロ
ペニル−エチルカルボナート、モノテルペン系ケトン
類、モノテルペン系アルデヒド類、モノテルペン系エポ
キサイド類、サリチル酸ベンジル、サリチル酸フェニル
などが挙げられる。In the present invention, other insecticides include
Hinoki, cedar and hiba essential oils, menthol, extracts of yellowfins, extracts from citrus peel and seeds, aromatic sulfonamide derivatives, tricyclohexyltin hydroxide,
Isopropyl 4,4'-dibromobenzylate, 2,3-
Dihydro-2,2-dimethyl-7-benzo [b] furanyl-N-dibutylaminothio-N-methylcarbamate, a silane compound, a cinnamic acid derivative, cinnamyl acetate,
Bufofezin, isoprothiolane, paraoxybenzoate, iodinated formal, phenols, phthalate, 3-bromo-2,3-iodo-2-propenyl-ethyl carbonate, monoterpene ketones, monoterpene aldehydes, Monoterpene epoxides, benzyl salicylate, phenyl salicylate and the like can be mentioned.
【００２０】また、殺虫剤としては、メトプレンなどの
昆虫幼若ホルモン剤、プレコセンなどの抗幼若ホルモン
剤、エクダイソンなどの脱皮ホルモン剤等の害虫のホル
モン剤、あるいは抗ホルモン剤も挙げることができる。Examples of insecticides include insect juvenile hormones such as methoprene, antijuvenile hormones such as plecosene, pest hormones such as molting hormones such as ecdysone, and antihormones. .
【００２１】本発明において使用される殺虫剤の添加量
としては、従来のエアゾールにおいて用いられている量
を使用することができるが、目安としては溶剤に対して
０．１〜２．０ｗｔ／ｖ％（重量／容量％）が好まし
い。The amount of the insecticide used in the present invention can be the amount used in conventional aerosols, but the standard is 0.1 to 2.0 wt / v with respect to the solvent. % (Weight / volume%) is preferred.
【００２２】そして、上記殺虫剤以外にも各種の薬剤が
添加できる。例えば、害虫忌避剤、殺菌剤、防黴剤、消
臭剤、芳香剤、着色料などを配合することもできる。害
虫忌避剤として２，３，４，５−ビス（δ−ブチレン）
−テトラヒドロフルフラール、Ｎ，Ｎ−ジエチル−ｍ−
トルアミド、ジ−ｎ−プロピルイソシンコロメート、ジ
−ｎ−ブチル酢酸、２−ハイドロキシエチルオクチル硫
酸、２−ｔ−ブチル−４−ヒドロキシアニソール、３−
ｔ−ブチル−４−ヒドロキシアニソール、シクロヘキシ
ミド、β−ニトロスチレンシアノアクリルニトリル、ト
リブチル錫塩酸塩、トリニトロベンゼン−アニリン複合
体、ナフタリンなど、殺菌剤あるいは防黴剤としては、
２，４，４’−トリクロロ−２’−ハイドロキシジフェ
ニルエーテル、２，３，５，６−テトラクロロ−４−
（メチルスルホニル）ピリジン、アルキルベンジルメチ
ルアンモニウムクロライド、ベンジルメチル−｛２−
〔２−（ｐ−１，１，３，３−テトラメチルブチルフェ
ノキシ）エトキシ〕エチル｝アンモニウムクロライド、
４−イソプロピルトロポロン、Ｎ，Ｎ−ジメチル−Ｎ’
−フェニル−Ｎ’−（フルオロジクロロメチルチオ）ス
ルフォンアミド、２−（４’−チアゾリル）ベンズイミ
ダゾール、Ｎ−（フルオロジクロロメチルチオ）−フタ
ルイミド、６−アセトキシ−２，４−ジメチル−ｍ−ジ
オキシン、イソプロピルメチルフェノール、Ｏ−フェニ
ルフェノール、ｐ−クロロ−ｍ−キシレノール等が用い
られ、消臭剤としては、ラウリル酸メタアクリレートな
ど、そして、芳香剤としてはイグサの精油成分、ヒノキ
の精油成分、シトロネラ、レモン、レモングラス、オレ
ンジ、ユーカリ、ラベンダーなどが配合できる。Various chemicals other than the above insecticides can be added. For example, pest repellents, bactericides, fungicides, deodorants, fragrances, coloring agents, and the like can be added. 2,3,4,5-bis (δ-butylene) as a pest repellent
-Tetrahydrofurfural, N, N-diethyl-m-
Toluamide, di-n-propyl isosine colomate, di-n-butyl acetic acid, 2-hydroxyethyl octyl sulfate, 2-t-butyl-4-hydroxyanisole, 3-
T-butyl-4-hydroxyanisole, cycloheximide, β-nitrostyrene cyanoacrylonitrile, tributyltin hydrochloride, trinitrobenzene-aniline complex, naphthalene, etc.
2,4,4'-trichloro-2'-hydroxydiphenyl ether, 2,3,5,6-tetrachloro-4-
(Methylsulfonyl) pyridine, alkylbenzylmethylammonium chloride, benzylmethyl- {2-
[2- (p-1,1,3,3-tetramethylbutylphenoxy) ethoxy] ethyl} ammonium chloride,
4-isopropyltropolone, N, N-dimethyl-N ′
-Phenyl-N '-(fluorodichloromethylthio) sulfonamide, 2- (4'-thiazolyl) benzimidazole, N- (fluorodichloromethylthio) -phthalimide, 6-acetoxy-2,4-dimethyl-m-dioxin, isopropyl Methylphenol, O-phenylphenol, p-chloro-m-xylenol and the like are used. As a deodorant, lauric acid methacrylate and the like, and as an aromatic, rush essential oil component, hinoki essential oil component, citronella, Lemon, lemongrass, orange, eucalyptus, lavender, etc. can be blended.
【００２３】本発明において用いることができる溶剤と
しては、脂肪族炭化水素類、芳香族炭化水素類、ハロゲ
ン化炭化水素類、アルコール類、エーテル類、エステル
類等を挙げることができる。これら溶剤としては、例え
ば、ヘキサン、ケロシン（灯油）、ｎ−ペンタン、ｉｓ
ｏ−ペンタン、シクロペンタン等の脂肪族炭化水素類：
ベンゼン、トルエン、キシレン等の芳香族炭化水素類：
ジクロロメタン、四塩化炭素等のハロゲン化炭化水素
類：エタノール、イソプロピルアルコール、エチレング
リコール、ブチルジグリコール等のアルコール類：アセ
トン、メチルエチルケトン、ジエチルエーテル等のエー
テル類：酢酸エチル、ミリスチン酸イソプロピル等のエ
ステル類を挙げることができる。この他にもアセトニト
リルなどのニトリル類：ジメチルホルムアミドなどのア
ミド類：大豆油、綿実油等の植物油、及び水などを使用
することができる。さらにはこれらの混合溶剤であって
もよい。本発明においては、溶剤としては有機溶剤が好
ましく、より好ましくはアルコール類、芳香族炭化水素
類、脂肪族炭化水素類である。更に好ましくは炭素数１
０〜１６個の脂肪族炭化水素類が挙げられる。本発明に
おける溶剤の含有量としては、上記原液と噴射剤との割
合を満たし、溶剤の噴射量が上記範囲になるような量で
あればいずれでもよいが、目安としてエアゾール中１６
ｖ／ｖ％〜２５ｖ／ｖ％が好ましい。このような溶剤の
含有量とすることで、本発明の効果をより有効に発現さ
せることができる。Examples of the solvent that can be used in the present invention include aliphatic hydrocarbons, aromatic hydrocarbons, halogenated hydrocarbons, alcohols, ethers, esters and the like. Examples of these solvents include hexane, kerosene (kerosene), n-pentane, is
Aliphatic hydrocarbons such as o-pentane and cyclopentane:
Aromatic hydrocarbons such as benzene, toluene and xylene:
Halogenated hydrocarbons such as dichloromethane and carbon tetrachloride: alcohols such as ethanol, isopropyl alcohol, ethylene glycol and butyl diglycol: ethers such as acetone, methyl ethyl ketone and diethyl ether: esters such as ethyl acetate and isopropyl myristate Can be mentioned. In addition, nitriles such as acetonitrile: amides such as dimethylformamide: vegetable oils such as soybean oil and cottonseed oil, and water can be used. Further, these mixed solvents may be used. In the present invention, the solvent is preferably an organic solvent, more preferably an alcohol, an aromatic hydrocarbon, or an aliphatic hydrocarbon. More preferably, it has 1 carbon atom
0 to 16 aliphatic hydrocarbons. The content of the solvent in the present invention may be any amount that satisfies the ratio between the stock solution and the propellant and the amount of the solvent sprayed falls within the above range.
v / v% to 25 v / v% is preferred. By setting the content of such a solvent, the effects of the present invention can be more effectively exerted.
【００２４】本発明において界面活性剤としては、例え
ば、ソルビタンモノオレート、ソルビタンモノラウレー
ト、ポリオキシエチレンノニルフェニルエーテル、ポリ
オキシエチレン硬化ヒマシ油、デカグリセリンモノオレ
ートなどが挙げられる。In the present invention, examples of the surfactant include sorbitan monooleate, sorbitan monolaurate, polyoxyethylene nonylphenyl ether, polyoxyethylene hydrogenated castor oil, decaglycerin monooleate and the like.
【００２５】また、界面活性剤は、主に溶剤に殺虫剤を
乳化、分散もしくは可溶化するために使用することがで
きるが、本発明の殺虫効果を高める場合もありうる。界
面活性剤の添加量としては、目的とする効果が得られる
量を適宜加えればよく、溶剤と殺虫剤との親和性に影響
されるが、例えば、原液中０．５〜１０ｗｔ／ｖ％％程
度を加えればよい。The surfactant can be used mainly for emulsifying, dispersing, or solubilizing the insecticide in a solvent, but may enhance the insecticidal effect of the present invention. The amount of the surfactant to be added may be appropriately determined so that the desired effect can be obtained. The amount of the surfactant is affected by the affinity between the solvent and the insecticide. Just add the degree.
【００２６】本発明において噴射剤としては、例えば、
液化石油ガス（ＬＰＧ）、プロパン、イソブタン、ｎ−
ブタン、イソペンタン、ｎ−ペンタン、シクロペンタ
ン、ジメチルエーテル（ＤＭＥ）、窒素ガス、液化炭酸
ガス、塩素を含まないフロンガス（代替フロンと呼ばれ
ているガス、例えばＨＦＣ−１２５、ＨＦＣ−１３４
ａ、ＨＦＣ−１４３ａ、ＨＦＣ−１５２ａ、ＨＦＣ−３
２など）、及びこれらの混合物などが挙げられる。本発
明において、エアゾール中の噴射剤の量としては、上記
原液との割合を満たすような量であればよい。In the present invention, as the propellant, for example,
Liquefied petroleum gas (LPG), propane, isobutane, n-
Butane, isopentane, n-pentane, cyclopentane, dimethyl ether (DME), nitrogen gas, liquefied carbon dioxide gas, and chlorofluorocarbon-free fluorocarbon gas (gases called alternative fluorocarbons, such as HFC-125, HFC-134
a, HFC-143a, HFC-152a, HFC-3
2 etc.), and mixtures thereof. In the present invention, the amount of the propellant in the aerosol may be an amount that satisfies the ratio with the stock solution.
【００２７】本発明のエアゾールは、主に溶剤と殺虫剤
を含む原液と噴射剤とからなり、これらを加圧充填でき
る容器と、ここから所定量を所望の空域にスプレーする
ための手段（バルブ、操作ボタンなど）とを具備してい
るものである。そしてスプレーする為の手段としては、
この他にもトリガータイプのものであってもよく、大量
噴射を行う上ではその操作性からいってトリガータイプ
のものが好適な手段として挙げられる。The aerosol of the present invention mainly comprises a stock solution containing a solvent and an insecticide, and a propellant, which can be filled under pressure, and means for spraying a predetermined amount from the container into a desired space (valve). , Operation buttons, etc.). And as a means to spray,
In addition to this, a trigger type may be used, and in terms of operability, a trigger type is preferred as a means for performing large-volume injection.
【００２８】本発明における防除対象としては、屋内外
に生息する害虫および屋内塵性ダニ類など全般に亘る。
屋内外に生息する害虫としては衛生害虫あるいは生活害
虫等が挙げられる。例えば衛生害虫としてはゴキブリ類
（チャバネゴキブリ、クロゴキブリ、ワモンゴキブリ
等）、ハエ類（イエバエ、クロバエ、ニクバエ等）、カ
類（イエカ、ヤブカ、シマカ等）、シラミ類、ノミ類等
が挙げられ、更に生活害虫としてはシロアリ（羽ア
リ）、クロアリ、クモ、ハチ、ケムシ、ムカデ、ゲジゲ
ジ、ヤスデ、シバンムシ、アリガタバチ、ユスリカ、チ
ョウバエ、カメムシ、キクイムシ、ダンゴムシ、ワラジ
ムシ、シミ、イガ、コイガ、カツオブシムシおよびヌカ
カ等が例示できる。更に屋内塵性ダニ類としては室内で
繁殖増殖するダニ類、あるいは室内に迷入してくるダニ
類として例えば、コナヒョウヒダニ、ヤケヒョウヒダニ
等のヒョウヒダニ類、ケナガコナダニ、ムギコナダニ等
のコナダニ類、チリニクダニ、イエニクダニ等のニクダ
ニ類、フトツメダニ、ミナミツメダニ等のツメダニ類、
ホコリダニ類、ササラダニ類、イエダニ、トリサシダ
ニ、ワクモ、マダニ類等の動物寄生性ダニ類などが挙げ
られる。本発明のエアゾールは、飛翔性害虫はもちろん
のこと、俊敏性の高い徘徊行動をとる害虫に対して特に
有効である。The objects to be controlled in the present invention include all pests living indoors and outdoors and indoor dust mites.
Pests that live indoors and outdoors include sanitary pests and living pests. For example, examples of the sanitary pests include cockroaches (such as German cockroaches, black cockroaches, brown cockroaches), flies (such as house flies, blow flies, and flies), mosquitoes (such as house mosquitoes, falcons, and striped mosquitoes), lice, and fleas. Examples of living pests are termites (wing ants), black ants, spiders, bees, pitworms, centipedes, gejigeji, millipedes, shibanmushi, arigatabachi, chironomid, fly flies, stink bugs, bark beetles, dung beetles, warad beetles, spots, iga, kiga, katsuobushi mushi, and the like. Can be exemplified. Further, as indoor dust mites, mites that breed and proliferate indoors, or mites that enter the room, for example, Dermatophagoids such as Dermatophagoides farinae, Dermatophagoides farinae, Dermatophagoides farinae, Dermatophagoides farinae, Dermatophagoides farinae, and Nichinite mites such as Scarlet mite. , Mites, red mites, and red mites,
Animal parasite mites such as dust mites, scorpion mites, house dust mites, common ticks, mites and ticks. The aerosol of the present invention is particularly effective against not only flying pests but also pests that take a highly aggressive wandering behavior.
【００２９】[0029]
【実施例】以下に実施例によって、本発明をさらに詳し
く説明するが、本発明はこれらに限定されるものではな
い。 実施例１ （害虫の噴射後の移動距離の試験） （１）試験サンプルの作成 〔サンプル１〕（原液：噴射剤＝１：３．４４（ｖ／
ｖ）） エアゾール（全量３００ｍｌ）として、殺虫剤（イミプ
ロトリン０．６重量％）を含む原液（溶剤として１号灯
油）６７．５ｍｌと噴射剤（ＤＭＥおよびＬＰＧ、比率
５４．５：４５．５）２３２．５ｍｌをエアゾール用容
器に充填した。そして噴射量が２７ｍｌ／１０秒となる
ように調整した大量噴射型エアゾールを得た。ここで、
溶剤の噴射量としては、６ｍｌ／１０秒である。EXAMPLES The present invention will be described in more detail with reference to the following Examples, but it should not be construed that the present invention is limited thereto. Example 1 (Test of moving distance after pest injection) (1) Preparation of test sample [Sample 1] (stock solution: propellant = 1: 3.44 (v /
v)) As an aerosol (300 ml in total), 67.5 ml of a stock solution (kerosene No. 1 as solvent) containing an insecticide (0.6% by weight of imiprothrin) and a propellant (DME and LPG, ratio 54.5: 45.5). 232.5 ml was filled into an aerosol container. And the mass injection type aerosol adjusted so that injection amount might be set to 27 ml / 10 second was obtained. here,
The injection amount of the solvent is 6 ml / 10 seconds.
【００３０】〔サンプル２〕（原液：噴射剤＝１：３．
４４（ｖ／ｖ）） エアゾール（全量３００ｍｌ）として、殺虫剤（イミプ
ロトリン０．６重量％）を含む原液（溶剤として１号灯
油）６７．５ｍｌと噴射剤（サンプル１と同じもの）２
３２．５ｍｌをエアゾール用容器に加圧充填した。そし
て噴射量が４５ｍｌ／１０秒となるように調整した大量
噴射型エアゾールを得た。ここで、溶剤の噴射量として
は、１０ｍｌ／１０秒である。[Sample 2] (stock solution: propellant = 1: 3.
44 (v / v)) As an aerosol (300 ml in total), 67.5 ml of a stock solution (kerosene 1 as a solvent) containing an insecticide (0.6% by weight of imiprothrin) and a propellant (the same as sample 1) 2
32.5 ml was filled into an aerosol container under pressure. And the mass injection type aerosol adjusted so that injection amount became 45 ml / 10 second was obtained. Here, the injection amount of the solvent is 10 ml / 10 seconds.
【００３１】〔比較例１のサンプル〕（原液：噴射剤＝
１：１．２２（ｖ／ｖ）） エアゾール（全量３００ｍｌ）として、殺虫剤（イミプ
ロトリン１．５重量％）を含む原液（溶剤として１号灯
油）１３５ｍｌと噴射剤（上記サンプル１と同じ）１６
５ｍｌをエアゾール用容器に充填した。そして噴射量が
９ｍｌ／１０秒となるように調整したエアゾールを得
た。ここで、溶剤の噴射量としては、４ｍｌ／１０秒で
ある。[Sample of Comparative Example 1] (stock solution: propellant =
1: 1.22 (v / v)) As an aerosol (300 ml in total), 135 ml of a stock solution containing a pesticide (1.5% by weight of imiprothrin) (kerosene No. 1 as a solvent) and a propellant (same as the above sample 1) 16
5 ml was filled into an aerosol container. Then, an aerosol adjusted so that the injection amount was 9 ml / 10 seconds was obtained. Here, the injection amount of the solvent is 4 ml / 10 seconds.
【００３２】〔比較例２のサンプル〕（原液：噴射剤＝
１：５．６７（ｖ／ｖ）） エアゾール（全量３００ｍｌ）として、殺虫剤（イミプ
ロトリン０．９重量％）を含む原液（溶剤として１号灯
油）４５ｍｌと噴射剤（サンプル１と同じ）２５５ｍｌ
をエアゾール用容器に加圧充填した。そして噴射量が２
７ｍｌ／１０秒となるように調整した大量噴射型エアゾ
ールを得た。ここで、有機溶剤の噴射量としては、４ｍ
ｌ／１０秒である。[Sample of Comparative Example 2] (stock solution: propellant =
1: 5.67 (v / v)) As an aerosol (300 ml in total), 45 ml of a stock solution containing a pesticide (imiprotrin 0.9% by weight) (kerosene No. 1 as a solvent) and 255 ml of a propellant (same as sample 1)
Was pressure-filled into an aerosol container. And the injection amount is 2
A mass injection aerosol adjusted to 7 ml / 10 seconds was obtained. Here, the injection amount of the organic solvent is 4 m
1/10 seconds.
【００３３】（２）供試虫 クロゴキブリ成虫雌（Periplaneta fuliginosa）および
チャバネゴキブリ雌成虫（Blattella germanica)を試験
に用いた。 （３）試験方法 容積３５ｍ3 のチャンバー内の床面に、半径１０〜７０
ｃｍの同心円を書いた模造紙を敷き、その円の中心部に
供試虫１０頭を入れた円筒（直径２０ｃｍ、高さ４５ｃ
ｍ）を置き、円筒上部に、中央に５ｃｍの孔が開いた蓋
をした。次にサンプルを蓋の孔から６秒間噴射し、その
後直ぐに円筒を除去し、床面に敷いた同心円上での供試
虫の状況を観察し、併せて同心円中央部からの移動距離
を測定した。（図２参照）(2) Test Insects Adult female black cockroaches (Periplaneta fuliginosa) and adult female German cockroaches (Blattella germanica) were used for the test. (3) Test method A radius of 10 to 70 was applied to the floor in a chamber having a capacity of 35 m 3.
cm on a circle with a concentric circle of 10 cm, and a cylinder (diameter 20 cm, height 45 c) containing 10 test insects at the center of the circle.
m) and placed on top of the cylinder with a lid with a 5 cm hole in the center. Next, the sample was sprayed from the hole of the lid for 6 seconds, and immediately thereafter, the cylinder was removed, the condition of the test insect on the concentric circle laid on the floor was observed, and the movement distance from the center of the concentric circle was measured. . (See Fig. 2)
【００３４】供試虫の移動距離（ｃｍ）についてはＭＤ
５０値（供試虫の５０％がノックダウンするまでに上記
円の中心から移動する距離）およびＭＤ９５値（供試虫
の９５％がノックダウンするまでに上記円の中心から移
動する距離）を測定した。さらに、ノックダウンした供
試虫を別の容器に移して観察を続け、噴射後２４時間に
その致死率（％）も算出した。なお試験結果は上記試験
を２回行った時の値の平均値で示した。本試験の概略を
図２に、また試験結果を第１表に示した。For the moving distance (cm) of the test insect, MD
The 50 value (the distance traveled from the center of the circle until 50% of the test insects knocked down) and the MD95 value (the distance traveled from the center of the circle until 95% of the test insects knocked down) were calculated. It was measured. Further, the knocked down test insects were transferred to another container and the observation was continued, and the mortality (%) was calculated 24 hours after the injection. In addition, the test result was shown by the average value of the value when the said test was performed twice. The outline of this test is shown in FIG. 2, and the test results are shown in Table 1.
【００３５】[0035]
【表１】 [Table 1]
【００３６】（４）試験結果 クロゴキブリに対する効果（第１表）において、本発明
の大量噴射型エアゾールであるサンプル１と２は、いず
れも比較例１サンプルおよび比較例２サンプルより、噴
射後のクロゴキブリの移動距離が著しく小さく、且つそ
の殺虫効果も十分であった。比較例２のサンプルは、溶
剤の噴射量が本発明の範囲内で、大量噴射型のエアゾー
ルであるが、原液と噴射剤の割合が本発明の範囲から外
れているため、噴射後のクロゴキブリの移動距離が大き
くなってしまった。従って、本発明においては、本発明
の原液と噴射剤の割合及び溶剤の噴射量のすべてを満た
さないと、本発明の効果が得られないことが判る。上記
試験をチャバネゴキブリについても行ったところ、上記
と同様の結果が得られ、本発明のサンプル１、２は噴射
後の移動距離が著しく小さく、且つその殺虫効果も十分
であった。(4) Test Results In the effects on black cockroaches (Table 1), Samples 1 and 2, which are the mass injection type aerosols of the present invention, were both better than Samples 1 and 2 of Comparative Example after injection. The moving distance of the black cockroach was extremely small, and its insecticidal effect was also sufficient. The sample of Comparative Example 2 was a large-aerosol type aerosol with a solvent injection amount within the range of the present invention, but the ratio of the stock solution and the propellant was out of the range of the present invention. Travel distance has increased. Therefore, in the present invention, it is understood that the effects of the present invention cannot be obtained unless all of the ratio of the stock solution and the propellant of the present invention and the injection amount of the solvent are satisfied. When the above test was carried out for German cockroaches, the same results as above were obtained. Samples 1 and 2 of the present invention had a remarkably small moving distance after jetting and had a sufficient insecticidal effect.
【００３７】実施例２ （ノックダウン試験）上記実施例１において用いた本発
明のサンプル１及び２、比較例１及び２用サンプルを用
いてＫＴ５０（５０％の供試虫がノックダウンする時間
（秒））及びＫＴ９０（９０％の供試虫がノックダウン
する時間（秒））及び２４時間後の致死率を測定した。
測定方法と評価方法を下記に示す。ノックダウン試験の
概要を図３に示す。カップ１（直径１０ｃｍ、深さ１０
ｃｍ）に、１０匹のクロゴキブリ（供試虫２）を入れ
る。クロゴキブリを入れたカップを床面に対して斜めに
設置し、カップ１から約５０ｃｍ離れ、床面からの高さ
約４０ｃｍのところから、各サンプル（検体３）を１秒
間噴射する。噴射後、直ちにクロゴキブリを観察容器
（直径５０ｃｍ、高さ１２ｃｍ）に移し、時間経過毎に
クロゴキブリのノックダウン数を記録する。また、ノッ
クダウンの観察終了後、クロゴキブリを別の清潔な容器
に移し、餌と水を与えて２４時間後の死亡数を記録し
た。これらの結果を下記第２表に示す。Example 2 (Knockdown test) Using the samples 1 and 2 of the present invention and the samples for Comparative Examples 1 and 2 used in Example 1 described above, KT50 (time during which 50% of the test insects were knocked down ( Second)), KT90 (time (seconds) at which 90% of the test insects are knocked down), and the mortality after 24 hours.
The measuring method and the evaluation method are shown below. FIG. 3 shows the outline of the knockdown test. Cup 1 (diameter 10cm, depth 10
cm), put 10 black cockroaches (test insect 2). The cup containing the black cockroach is placed obliquely to the floor, and each sample (specimen 3) is sprayed for 1 second from a position approximately 50 cm away from the cup 1 and approximately 40 cm above the floor. Immediately after the injection, the black cockroaches are transferred to an observation container (50 cm in diameter, 12 cm in height), and the number of knock downs of black cockroaches is recorded every time. After completion of the knockdown observation, the black cockroaches were transferred to another clean container, fed with water, and the number of deaths 24 hours later was recorded. The results are shown in Table 2 below.
【００３８】[0038]
【表２】 [Table 2]
【００３９】第２表を見ると、本発明のサンプル１及び
２は、比較例１及び２のサンプルと比較すると、ＫＴ５
０値とＫＴ９０値において、著しく優れていることが判
る。また、本発明のサンプル１とサンプル２を比べる
と、噴射量のより多いサンプル２のほうが優れているこ
とが判る。As can be seen from Table 2, Samples 1 and 2 of the present invention showed KT5 when compared with the samples of Comparative Examples 1 and 2.
It turns out that it is remarkably excellent in 0 value and KT90 value. In addition, comparing Sample 1 and Sample 2 of the present invention, it can be seen that Sample 2 having a larger injection amount is more excellent.
【００４０】[0040]
【発明の効果】本発明のエアゾールは、エアゾールを噴
射処理した場所からの害虫の移動を抑制する効果に優れ
ており、従来のエアゾールのように害虫の活動が停止す
るまでエアゾールを噴射し続ける必要がなく、エアゾー
ルの無駄な消費を軽減でき且つ環境衛生上でも好まし
く、更に殺虫効力も優れている。The aerosol of the present invention has an excellent effect of suppressing the movement of the pest from the place where the aerosol has been sprayed, and it is necessary to continuously spray the aerosol until the activity of the pest stops as in the conventional aerosol. Therefore, wasteful consumption of aerosol can be reduced, and it is preferable from the viewpoint of environmental hygiene. Further, the insecticidal effect is excellent.
【図１】 本発明と比較例のエアゾールの噴射後の殺虫
剤の気中濃度の経過時間での変化を示すグラフを示す図
である。BRIEF DESCRIPTION OF DRAWINGS FIG. 1 is a graph showing a change in aerial concentration of an insecticide in the air after injection of an aerosol of the present invention and a comparative example over time.
【図２】 エアゾールを噴射した害虫の移動距離を測定
する試験の概略を示すための図である。FIG. 2 is a diagram showing an outline of a test for measuring a moving distance of a pest sprayed with an aerosol.
【図３】 エアゾールにおけるノックダウン試験の概略
を示すための図である。FIG. 3 is a diagram showing an outline of a knockdown test in an aerosol.
Claims (2)
有し、害虫を防除するエアゾールにおいて、該原液と噴
射剤との割合（ｖ／ｖ）が１：３〜１：５であり、溶剤
の噴射量が４．０ｍｌ／１０秒以上であることを特徴と
するエアゾール。1. An aerosol containing a stock solution containing a pesticide and a solvent and a propellant and controlling pests, wherein the ratio (v / v) between the stock solution and the propellant is 1: 3 to 1: 5, An aerosol, characterized in that the injection amount of the solvent is 4.0 ml / 10 seconds or more.
項１に記載のエアゾール。2. The aerosol according to claim 1, wherein the aerosol is of a mass injection type.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP09091097A JP3922659B2 (en) | 1997-04-09 | 1997-04-09 | Cockroach aerosol |
| MYPI9706075 MY136637A (en) | 1997-04-09 | 1997-12-16 | Aerosol spraying apparatus |
| IDP973898A ID20772A (en) | 1997-04-09 | 1997-12-17 | AEROSOL SPRAY EQUIPMENT |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP09091097A JP3922659B2 (en) | 1997-04-09 | 1997-04-09 | Cockroach aerosol |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH10287504A true JPH10287504A (en) | 1998-10-27 |
| JP3922659B2 JP3922659B2 (en) | 2007-05-30 |
Family
ID=14011575
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP09091097A Expired - Fee Related JP3922659B2 (en) | 1997-04-09 | 1997-04-09 | Cockroach aerosol |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP3922659B2 (en) |
| ID (1) | ID20772A (en) |
| MY (1) | MY136637A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000273001A (en) * | 1999-01-19 | 2000-10-03 | Earth Chem Corp Ltd | Spray for air conditioner |
| JP2003238321A (en) * | 2002-02-08 | 2003-08-27 | Dainippon Jochugiku Co Ltd | Mothproof and antifungal agent |
| JP2004091452A (en) * | 2002-07-11 | 2004-03-25 | Dainippon Jochugiku Co Ltd | Aerosol agent containing volatile drug, tool for displaying its efficacy, and method for displaying the efficacy in environmental atmosphere |
| JP2005272012A (en) * | 2004-02-26 | 2005-10-06 | Daizo:Kk | Aerosol product |
| JP2005330264A (en) * | 2004-04-21 | 2005-12-02 | Earth Chem Corp Ltd | Aerosol product for repelling small flies |
-
1997
- 1997-04-09 JP JP09091097A patent/JP3922659B2/en not_active Expired - Fee Related
- 1997-12-16 MY MYPI9706075 patent/MY136637A/en unknown
- 1997-12-17 ID IDP973898A patent/ID20772A/en unknown
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000273001A (en) * | 1999-01-19 | 2000-10-03 | Earth Chem Corp Ltd | Spray for air conditioner |
| JP2003238321A (en) * | 2002-02-08 | 2003-08-27 | Dainippon Jochugiku Co Ltd | Mothproof and antifungal agent |
| JP2004091452A (en) * | 2002-07-11 | 2004-03-25 | Dainippon Jochugiku Co Ltd | Aerosol agent containing volatile drug, tool for displaying its efficacy, and method for displaying the efficacy in environmental atmosphere |
| JP4535673B2 (en) * | 2002-07-11 | 2010-09-01 | 大日本除蟲菊株式会社 | Efficacy indicator of aerosol agent containing volatile drug, and medicinal effect indication method in environmental atmosphere using the same |
| JP2005272012A (en) * | 2004-02-26 | 2005-10-06 | Daizo:Kk | Aerosol product |
| JP2005330264A (en) * | 2004-04-21 | 2005-12-02 | Earth Chem Corp Ltd | Aerosol product for repelling small flies |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3922659B2 (en) | 2007-05-30 |
| MY136637A (en) | 2008-11-28 |
| ID20772A (en) | 1999-03-04 |
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