JPH05238903A - Foaming aerosol insecticide and its application - Google Patents
Foaming aerosol insecticide and its applicationInfo
- Publication number
- JPH05238903A JPH05238903A JP7704591A JP7704591A JPH05238903A JP H05238903 A JPH05238903 A JP H05238903A JP 7704591 A JP7704591 A JP 7704591A JP 7704591 A JP7704591 A JP 7704591A JP H05238903 A JPH05238903 A JP H05238903A
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- JP
- Japan
- Prior art keywords
- weight
- insecticide
- insecticidal
- foaming
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、ゴキブリ等の大小様々
な家住性害虫の駆除用として好適な発泡エアゾール殺虫
剤ならびにこれを用いた塗布方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a foamed aerosol insecticide suitable for controlling household insects of various sizes, such as cockroaches, and a coating method using the same.
【０００２】[0002]
【従来の技術】家住性害虫の駆除方法としては、従来殺
虫剤を噴霧する方法あるいは粘着テープを含む捕獲器を
使用する方法などが知られている。前者のスプレー式の
ものは噴霧により空気中に殺虫剤が飛散するため人体へ
の付着あるいは呼吸による吸入の危険が伴う。一方、捕
獲器を用いる方法は、害虫の発生、増殖に対しては防止
効果がなく家屋内の害虫の一部のみしか退治することが
できないなどの問題を有している。2. Description of the Related Art Conventionally, as a method for exterminating domestic pests, a method of spraying an insecticide or a method of using a trap containing an adhesive tape is known. In the former spray type, the pesticide is scattered in the air by spraying, so that there is a risk of inhalation by adhesion to human body or breathing. On the other hand, the method using a trap has a problem that it is not effective in preventing the generation and multiplication of harmful insects and that only a part of the harmful insects in the house can be exterminated.
【０００３】また、最近実公昭６２−１６８４０号公報
に開示されているように、殺虫剤収納筒に塗布チップを
備えた害虫駆除用具も提案されているが、塗布時の滲出
量のバラツキや、特に垂直面では液ダレ等により、処理
薬量が不均一となって所望の駆除効果が得られなかった
り、あるいは処理面の汚染を招くなどの欠点がある。Further, recently, as disclosed in Japanese Utility Model Publication No. 62-16840, there has been proposed a pest control tool having an application tip in an insecticide storage cylinder, but variations in the amount of exudation during application, Especially on a vertical surface, liquid sagging or the like causes an uneven treatment amount, so that a desired extermination effect cannot be obtained, or there is a drawback that the treated surface is contaminated.
【０００４】[0004]
【発明が解決しようとする課題】本発明は、ゴキブリ等
の家住性害虫駆除用に供される殺虫剤について、飛散薬
剤を吸入することの危険性がない発泡塗布式殺虫剤に着
目し、従来からの提案ではいまだ十分に果たし得なかっ
た均一塗布、液ダレ防止、汚染防止などの要求を全て満
足させることを目的としてなされたものである。DISCLOSURE OF THE INVENTION The present invention focuses on foaming-applied insecticides which are not dangerous for inhaling scattered chemicals among insecticides used for exterminating domestic pests such as cockroaches. The proposal was made with the aim of satisfying all the requirements for uniform coating, prevention of liquid dripping, prevention of contamination, etc., which could not yet be fully achieved.
【０００５】[0005]
【課題を解決するための手段】上記目的を達成するため
の本発明は、（イ）殺虫成分０．０５〜２５．０重量
％、（ロ）非イオン系界面活性剤０．１〜５．０重量
％、（ハ）増粘剤０．０１〜３．０重量％、（ニ）低級
アルコール４０〜７０重量％、（ホ）水３０〜５０重量
％、を含有する殺虫原液７０重量％以上と、噴射剤３０
重量％以下とからなる内溶液をエアゾール容器に充填
し、前記内溶液を泡沫状に噴出させるようにした発泡エ
アゾール殺虫剤、ならびにこれを用いた塗布方法に係
る。Means for Solving the Problems The present invention for achieving the above object comprises (a) an insecticidal component of 0.05 to 25.0% by weight, (b) a nonionic surfactant of 0.1 to 5. 70 wt% or more of an insecticidal stock solution containing 0 wt%, (c) a thickener 0.01 to 3.0 wt%, (d) a lower alcohol 40 to 70 wt%, and (e) water 30 to 50 wt%. And propellant 30
The present invention relates to a foamed aerosol insecticide in which an aerosol solution is filled with an inner solution containing 1% by weight or less and the inner solution is ejected in the form of foam, and a coating method using the same.
【０００６】[0006]
【作用】本発明で用いられる殺虫成分としては、ピレス
ロイド系殺虫剤、ピレスロイド様殺虫剤、有機リン剤、
カーバメート剤、昆虫成長撹乱剤などをあげることがで
きるが、効力と安全性の点からピレスロイド系殺虫剤、
ピレスロイド様殺虫剤が好ましい。例えば、フェノトリ
ン、シフェノトリン、アレスリン、フタールスリン、レ
スメトリン、フラメトリン、プラレトリン、ペルメトリ
ン、シペルメトリン、エトフェンプロックス、シラフル
オフェンなどを例示できるが、これらに限定されるもの
でなく、また光学異性体あるいは幾何異性体が存在する
場合は、それらの各々ならびに任意の混合物が包含され
ることはもちろんである。本発明では、これらの殺虫成
分の１種または２種以上が殺虫原液中に０．０５〜２
５．０重量％配合されるが、さらに忌避剤、殺菌剤、防
カビ剤、共力剤、安定剤、香料などを適宣配合して多目
的組成物とすることもできる。The insecticidal ingredient used in the present invention includes pyrethroid insecticides, pyrethroid-like insecticides, organophosphorus agents,
Carbamate agents, insect growth disruptors, etc. can be mentioned, but from the viewpoint of efficacy and safety, pyrethroid insecticides,
Pyrethroid-like insecticides are preferred. For example, phenothrin, cyphenothrin, allethrin, phtalthrin, resmethrin, flamethrin, pralethrin, permethrin, cypermethrin, etofenprox, silafluophene, etc. can be exemplified, but not limited to these, and optical isomers or geometric isomers. When present, each of them as well as any mixtures are, of course, included. In the present invention, one or two or more of these insecticidal components are contained in the insecticidal stock solution in an amount of 0.05 to 2
Although it is mixed in an amount of 5.0% by weight, a multipurpose composition can be prepared by appropriately blending a repellent, a bactericide, an antifungal agent, a synergist, a stabilizer, and a fragrance.
【０００７】非イオン系界面活性剤は、本発明発泡エア
ゾール殺虫剤において、発泡性を付与すると共に、前記
殺虫成分を殺虫原液中で安定に均一に分散させるために
配合される。例えば、ポリオキシエチレンノニルフェニ
ルエーテル等のアルキルアリルエーテル型、ポリオキシ
エチレンラウリルエーテル等のアルキルエーテル型、ポ
リオキシエチレンオレエート等のアルキルエステル型、
ポリオキシエチレンラウリルアミン等のアルキルアミン
型、ソルビタンモノオレエートやポリオキシエチレンソ
ルビタンオレエート等の多価アルコール型、アルキルア
リルエーテルホルマリン縮合物等がある。これらは、１
種または２種以上の混合物として使用することもでき、
殺虫原液中に０．１〜５．０重量％配合される。なお、
ステアリルアルコール、セタノールなどの高級アルコー
ルを発泡調整剤として添加することもできる。The nonionic surfactant is added to the foamed aerosol insecticide of the present invention to impart foamability and to stably and uniformly disperse the insecticidal component in the stock solution of insecticide. For example, alkyl allyl ether type such as polyoxyethylene nonyl phenyl ether, alkyl ether type such as polyoxyethylene lauryl ether, alkyl ester type such as polyoxyethylene oleate,
There are alkylamine type such as polyoxyethylene lauryl amine, polyhydric alcohol type such as sorbitan monooleate and polyoxyethylene sorbitan oleate, and alkylallyl ether formalin condensate. These are 1
Can be used as a seed or a mixture of two or more,
0.1 to 5.0% by weight is added to the insecticidal stock solution. In addition,
Higher alcohols such as stearyl alcohol and cetanol can also be added as a foaming regulator.
【０００８】本発明発泡エアゾール殺虫剤においては、
液の展がりすぎを抑え、良好な塗布性能を得るために、
増粘剤の添加が必要とされる。増粘剤としては、アクリ
ル酸等からなる水溶性樹脂、ポリビニルアルコール、ア
ラビアゴム、カラギナン、ＣＭＣなどの水溶性高分子、
水溶性シリコーン樹脂などがあげられるが、これらに限
定されるものではない。In the foamed aerosol insecticide of the present invention,
To prevent the liquid from spreading too much and to obtain good coating performance,
Thickener addition is required. As the thickener, water-soluble resins such as acrylic acid, polyvinyl alcohol, gum arabic, carrageenan, water-soluble polymers such as CMC,
Examples of the water-soluble silicone resin include, but are not limited to.
【０００９】本発明で用いられる低級アルコールとして
は、エタノール、ｎ−プロパノール、イソプロパノー
ル、ｎ−ブタノールなどがあげられ、殺虫原液中に４０
〜７０重量％配合される。４０重量％以下の場合、殺虫
成分の溶解性が劣り、また７０重量％を越えると発泡性
が悪くなるので不適当である。なお、使用する低級アル
コールは、変成、未変成を問わないことはもちろん、性
状を損なわない限りにおいて、他の種の溶剤、例えば、
アセトン、メチルエチルケトンなどのケトン系溶剤、エ
チレングリコール、プロピレングリコールなどの多価ア
ルコール類、ジエチルエーテル、エチレングリコールモ
ノエチルエーテル、ジエチレングリコールモノブチルエ
ーテルなどのエーテル類、イソプロピルミリステート、
ブチルステアレート、ヒマシ油などのエステル類、ケロ
シン、灯油などを適宣添加してもよい。Examples of the lower alcohol used in the present invention include ethanol, n-propanol, isopropanol, n-butanol and the like.
˜70% by weight. If it is less than 40% by weight, the solubility of the insecticidal component is inferior, and if it exceeds 70% by weight, the foaming property is deteriorated, which is not suitable. The lower alcohol used may be modified or unmodified, as long as the properties are not impaired, other types of solvents, for example,
Ketone-based solvents such as acetone and methyl ethyl ketone, polyhydric alcohols such as ethylene glycol and propylene glycol, ethers such as diethyl ether, ethylene glycol monoethyl ether and diethylene glycol monobutyl ether, isopropyl myristate,
Butyl stearate, esters such as castor oil, kerosene, and kerosene may be added as appropriate.
【００１０】本発明ではさらに水が３０〜５０重量％配
合されるが、殺虫原液の性状を安定に保持するために、
脱イオン等の処理を施した精製水の使用が好ましい。In the present invention, water is further added in an amount of 30 to 50% by weight, but in order to stably maintain the properties of the insecticidal stock solution,
It is preferable to use purified water that has been subjected to treatment such as deionization.
【００１１】本発明発泡エアゾール殺虫剤は、こうして
得られた殺虫原液７０重量％以上と、噴射剤３０重量％
以下を配合してなる内容液をエアゾール容器に充填して
調製される。噴射剤としては、プロパン、ブタンなどの
液化石油ガス、ジメチルエーテル、フロンガス、炭酸ガ
ス、窒素ガスなどがあげられる。ジメチルエーテルは消
泡性を高めるために有用で、例えばジメチルエーテルと
液化石油ガスとの混合ガスであって前者が５０重量％以
上のものは、塗布性能において特に良好な結果を与える
ことが認められた。The foamed aerosol insecticide of the present invention comprises 70% by weight or more of the insecticidal stock solution thus obtained and 30% by weight of a propellant.
It is prepared by filling an aerosol container with a content liquid containing the following components. Examples of the propellant include liquefied petroleum gas such as propane and butane, dimethyl ether, freon gas, carbon dioxide gas, nitrogen gas and the like. It is recognized that dimethyl ether is useful for enhancing the defoaming property, and for example, a mixed gas of dimethyl ether and liquefied petroleum gas, the former of which is 50% by weight or more, gives particularly good results in coating performance.
【００１２】本発明は、発泡性かつ消泡性にすぐれた前
記内溶液処方をエアゾール容器に充填し、該内溶液を泡
沫状に噴出させ塗布することに特徴を有する。エアゾー
ル容器の構造は、耐圧容器と噴射バルブから構成され、
従来の噴霧用エアゾールと比べて何ら特別な機構を必要
としないが、例えば、ノズル孔径を従来のものから変更
させて目的に応じた噴出量を適宣選択することができ
る。The present invention is characterized in that the above-mentioned inner solution formulation excellent in foamability and defoaming property is filled in an aerosol container, and the inner solution is sprayed and applied in the form of foam. The structure of the aerosol container consists of a pressure resistant container and an injection valve,
Although no special mechanism is required as compared with the conventional spray aerosol, for example, the injection amount can be appropriately selected according to the purpose by changing the nozzle hole diameter from the conventional one.
【００１３】こうして得られた本発明発泡エアゾール殺
虫剤は、発泡性が安定しているため、均一に塗布するこ
とができ、溶液を塗布する場合のような液ダレの心配が
なく、しかも増粘剤の働きにより液の展がりすぎを抑え
ているので塗布性、使用性はきわめて良好である。さら
に、消泡性が高いので処理後の汚染感が少ないというメ
リットも有している。従って、本発明は家屋内の台所、
居間、玄関、窓サッシ、壁などに塗布処理をほどこし、
ゴキブリ、アリ類、ダニ類、ナンキンムシ、各種害虫に
高い駆除・予防効果を奏する発泡エアゾール殺虫剤なら
びにこれを用いた塗布方法を提供するものである。The foamed aerosol insecticide of the present invention thus obtained has a stable foaming property, so that it can be applied uniformly, and there is no fear of liquid dripping when applying a solution, and the viscosity is increased. Since the spread of the liquid is suppressed by the action of the agent, the coatability and usability are extremely good. Further, since it has a high defoaming property, it has an advantage that the feeling of contamination after treatment is small. Therefore, the present invention is a kitchen in a house,
Apply coating to living room, entrance, window sash, wall, etc.
It is intended to provide a foam aerosol insecticide having a high control and prevention effect against cockroaches, ants, mites, bed bugs, and various harmful insects, and a coating method using the same.
【００１４】次に、本発明を試験例、実施例によりさら
に詳細に説明するが、本発明はその要旨を越えない限
り、以下の例に限定されるものではない。Next, the present invention will be described in more detail with reference to test examples and examples, but the present invention is not limited to the following examples as long as the gist thereof is not exceeded.
【００１５】試験例１ 下記処方の殺虫原液ならびに噴射剤からなる内容液を耐
圧エアゾール容器に充填し、噴射バルブを装填して発泡
エアゾール殺虫剤を調製した。約１０ｃｍ離れたところ
からデコラ板に１０秒間噴出させ、塗布性能、使用性を
調べたところ次の通りであった。Test Example 1 A pressure-resistant aerosol container was filled with an insecticidal stock solution having the following formulation and a content liquid containing a propellant, and a spray valve was loaded to prepare a foamed aerosol insecticide. When the coating performance and usability were examined by spraying the decorating plate for 10 seconds from a distance of about 10 cm, the results were as follows.
【００１６】[0016]
【表１】 [Table 1]
【００１７】試験の結果、本発明発泡エアゾール殺虫剤
は、発泡安定性、消泡性ともにすぐれ、塗布の状態も良
好で、従来の噴霧式エアゾールのような薬液の飛散がな
く、また溶液を滲出塗布する方式にみられる液ダレの心
配も少ないことから極めて効率的・実用的な発泡塗布方
式を提供することが認められた。これに対し、対照発泡
エアゾール殺虫剤で示されるように、殺虫原液調製に用
いるアルコール系溶剤の配合量を７０重量％以上、ある
いは４０重量％以下にした場合や、殺虫原液／噴射剤の
比率を７／３以下に減らした場合、良好な発泡性が得ら
れず不適であった。さらに、増粘剤を配合しない処方に
ついては、噴射塗布後の液の展がりが早すぎて好ましく
ない結果が得られた。As a result of the test, the foamed aerosol insecticide of the present invention is excellent in foaming stability and defoaming property, has a good application condition, does not scatter a chemical solution as in the conventional spray type aerosol, and exudes the solution. It has been confirmed that an extremely efficient and practical foam coating method can be provided because there is little concern about liquid dripping seen in the coating method. On the other hand, as shown in the control foamed aerosol insecticide, when the amount of the alcohol-based solvent used for preparing the insecticidal stock solution is 70% by weight or more, or 40% by weight or less, or the insecticide stock solution / propellant ratio is When it was reduced to 7/3 or less, good foaming property could not be obtained, which was unsuitable. Furthermore, in the case of the formulation in which the thickener was not added, the spread of the liquid after spray coating was too fast, and unfavorable results were obtained.
【００１８】実施例１ 有効成分としてシフェノトリン０．８重量％、ディート
１．５重量％、及びＰＯＥノニルフェニルエーテル０．
５重量％、ステアリルアルコール０．４重量％、水溶性
シリコーン樹脂０．１重量％、未変成エタノール６５重
量％、精製水３１．７重量％を含有する殺虫原液を調製
した。この殺虫原液２３０ｇを３００ｍｌ耐圧エアゾー
ル容器に充填し、噴射バルブを装填した後、噴射ガス
（ジメチルエーテル７０重量％とＬＰＧ３０重量％の混
合ガス）２５ｇを圧入して、本発明発泡エアゾール殺虫
剤を得た。本殺虫剤を台所の床、食器棚、壁面に発泡塗
布処理したところ、ゴキブリ等の害虫に対し十分な駆除
・忌避効果を示し、６カ月以上にわたって効力が持続し
た。Example 1 As active ingredients, 0.8% by weight of ciphenothrin, 1.5% by weight of diet, and 0.1% of POE nonylphenyl ether.
An insecticidal stock solution containing 5% by weight, stearyl alcohol 0.4% by weight, water-soluble silicone resin 0.1% by weight, unmodified ethanol 65% by weight, and purified water 31.7% by weight was prepared. 230 g of this insecticidal stock solution was filled in a 300 ml pressure-resistant aerosol container, a jet valve was loaded, and then 25 g of a jet gas (a mixed gas of 70% by weight of dimethyl ether and 30% by weight of LPG) was injected under pressure to obtain a foamed aerosol insecticide of the present invention. . When this insecticide was applied to the kitchen floor, cupboard, and wall surface by foaming treatment, it showed a sufficient control and repellent effect against harmful insects such as cockroaches, and the effect persisted for more than 6 months.
【００１９】[0019]
【発明の効果】本発明は、発泡安定性、消泡性ともにす
ぐれ、塗布の状態も良好で、従来の噴霧式エアゾールの
ような薬液の飛散がなく、また溶液を滲出塗布するタイ
プにみられる液ダレの心配も少ない極めて効率的・実用
的な発泡エアゾール殺虫剤ならびにこれを用いた塗布方
法を提供するものである。INDUSTRIAL APPLICABILITY The present invention is excellent in both foaming stability and defoaming property, has a good coating state, does not scatter a chemical solution unlike conventional spray type aerosols, and is found in a type in which a solution is exuded and coated. (EN) An extremely efficient and practical foaming aerosol insecticide with little fear of liquid dripping, and a coating method using the same.
Claims (2)
イオン系界面活性剤０．１〜５．０重量％、増粘剤０．
０１〜３．０重量％、低級アルコール４０〜７０重量
％、水３０〜５０重量％、を含有する殺虫原液７０重量
％以上と、噴射剤３０重量％以下とからなる内溶液をエ
アゾール容器に充填し、前記内溶液を泡沫状に噴出させ
るようにしたことを特徴とする発泡エアゾール殺虫剤。1. An insecticidal component 0.05 to 25.0% by weight, a nonionic surfactant 0.1 to 5.0% by weight, a thickener 0.
An aerosol container is filled with an inner solution consisting of 70% by weight or more of a pesticidal stock solution containing 01 to 3.0% by weight, 40 to 70% by weight of lower alcohol, and 30 to 50% by weight of water, and 30% by weight or less of a propellant. A foamed aerosol insecticide, characterized in that the inner solution is ejected in the form of foam.
イオン系界面活性剤０．１〜５．０重量％、増粘剤０．
０１〜３．０重量％、低級アルコール４０〜７０重量
％、水３０〜５０重量％、を含有する殺虫原液７０重量
％以上と、噴射剤３０重量％以下とからなる内溶液をエ
アゾール容器に充填し、前記内溶液を泡沫状に噴出さ
せ、塗布することを特徴とする塗布方法。2. An insecticidal component 0.05 to 25.0% by weight, a nonionic surfactant 0.1 to 5.0% by weight, a thickener 0.
An aerosol container is filled with an internal solution consisting of 70% by weight or more of the insecticidal stock solution containing 01 to 3.0% by weight, 40 to 70% by weight of lower alcohol and 30 to 50% by weight of water, and 30% by weight or less of a propellant. Then, the internal solution is jetted in the form of foam to apply.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7704591A JP2756614B2 (en) | 1991-03-15 | 1991-03-15 | Foamed aerosol insecticide and application method using the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7704591A JP2756614B2 (en) | 1991-03-15 | 1991-03-15 | Foamed aerosol insecticide and application method using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05238903A true JPH05238903A (en) | 1993-09-17 |
| JP2756614B2 JP2756614B2 (en) | 1998-05-25 |
Family
ID=13622808
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7704591A Expired - Fee Related JP2756614B2 (en) | 1991-03-15 | 1991-03-15 | Foamed aerosol insecticide and application method using the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2756614B2 (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998016106A1 (en) * | 1996-10-16 | 1998-04-23 | Globol Chemicals (Uk) Limited | Pesticidal methods, compositions and devices |
| WO1998021955A1 (en) * | 1996-11-21 | 1998-05-28 | Colgate-Palmolive Company | Foam cleaning compositions |
| WO1998021954A1 (en) * | 1996-11-22 | 1998-05-28 | Colgate-Palmolive Company | Foam cleaning compositions |
| JP2001172104A (en) * | 1999-12-14 | 2001-06-26 | Yushiro Chem Ind Co Ltd | Spreader, agrochemical composition with the same added thereto, and method for spraying agrochemical |
| JP2002047101A (en) * | 2000-08-03 | 2002-02-12 | Yushiro Chem Ind Co Ltd | Foamable vermicide for exterminating unpleasant vermin and method for exterminating unpleasant vermin by using the same |
| KR100712937B1 (en) * | 1999-07-09 | 2007-05-02 | 후마킬라 가부시키가이샤 | Foamed aerosol |
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| US20120164081A1 (en) * | 2007-06-25 | 2012-06-28 | The Dial Corporation | Non-hazardous foaming ant spray based on natural oils, carboxylate salts and optional synergists |
| JP5671118B1 (en) * | 2013-10-09 | 2015-02-18 | 近代化学株式会社 | Foamable composition for repelling harmful animals |
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1991
- 1991-03-15 JP JP7704591A patent/JP2756614B2/en not_active Expired - Fee Related
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998016106A1 (en) * | 1996-10-16 | 1998-04-23 | Globol Chemicals (Uk) Limited | Pesticidal methods, compositions and devices |
| WO1998021955A1 (en) * | 1996-11-21 | 1998-05-28 | Colgate-Palmolive Company | Foam cleaning compositions |
| WO1998021954A1 (en) * | 1996-11-22 | 1998-05-28 | Colgate-Palmolive Company | Foam cleaning compositions |
| KR100712937B1 (en) * | 1999-07-09 | 2007-05-02 | 후마킬라 가부시키가이샤 | Foamed aerosol |
| JP2001172104A (en) * | 1999-12-14 | 2001-06-26 | Yushiro Chem Ind Co Ltd | Spreader, agrochemical composition with the same added thereto, and method for spraying agrochemical |
| JP2002047101A (en) * | 2000-08-03 | 2002-02-12 | Yushiro Chem Ind Co Ltd | Foamable vermicide for exterminating unpleasant vermin and method for exterminating unpleasant vermin by using the same |
| US20120164081A1 (en) * | 2007-06-25 | 2012-06-28 | The Dial Corporation | Non-hazardous foaming ant spray based on natural oils, carboxylate salts and optional synergists |
| JP2010083797A (en) * | 2008-09-30 | 2010-04-15 | Sumika Enviro-Science Co Ltd | Pest insect eliminator |
| KR101104821B1 (en) * | 2009-04-14 | 2012-01-16 | (주)팜클 | Foam-Spray Type Insecticide |
| US8980294B2 (en) | 2009-04-28 | 2015-03-17 | Basf Corporation | Methods for controlling pests |
| WO2011025789A3 (en) * | 2009-08-28 | 2011-08-25 | Basf Corporation | Foamable pesticide compositions and methods of application |
| CN102595881A (en) * | 2009-08-28 | 2012-07-18 | 巴斯夫公司 | Foamable pesticide compositions and methods of application |
| JP2013503169A (en) * | 2009-08-28 | 2013-01-31 | ビー・エイ・エス・エフ、コーポレーション | Effervescent pesticide composition and application method |
| US9339030B2 (en) | 2009-08-28 | 2016-05-17 | Basf Corporation | Foamable pesticide compositions and methods of application |
| JP5671118B1 (en) * | 2013-10-09 | 2015-02-18 | 近代化学株式会社 | Foamable composition for repelling harmful animals |
| JP2015074631A (en) * | 2013-10-09 | 2015-04-20 | 近代化学株式会社 | Foamable composition for evading noxious animal |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2756614B2 (en) | 1998-05-25 |
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