KR101023181B1 - 광학필름, 편광자 보호필름, 이를 이용한 편광판, 및 이를이용한 화상표시장치 - Google Patents
광학필름, 편광자 보호필름, 이를 이용한 편광판, 및 이를이용한 화상표시장치 Download PDFInfo
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- KR101023181B1 KR101023181B1 KR1020070050754A KR20070050754A KR101023181B1 KR 101023181 B1 KR101023181 B1 KR 101023181B1 KR 1020070050754 A KR1020070050754 A KR 1020070050754A KR 20070050754 A KR20070050754 A KR 20070050754A KR 101023181 B1 KR101023181 B1 KR 101023181B1
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- Prior art keywords
- film
- alkene
- copolymer
- polarizer
- monomer
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Images
Classifications
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
- C08J7/123—Treatment by wave energy or particle radiation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/08—Homopolymers or copolymers of acrylic acid esters
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- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
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- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
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- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
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Abstract
Description
|
반응 투입량 | 중합조건 | ||||
[용매] /[단량체] (부피비) |
[루이스산] /[MMA] (mole비) |
[개시제] /[단량체] (mole비) |
에틸렌 압력 (bar) |
온도 (℃) |
시간 (h) |
|
비교예1 | 9 | 1 | 0.003 | 35 | 75 | 18 |
비교예2 | 9 | 0 | 0.003 | 35 | 75 | 18 |
Tg(℃) | Mn | Mw | PDI | Td_50 (℃) |
에틸렌함량 (mole%) |
|
비교예1 | 92 | 29900 | 49000 | 1.64 | 433 | 14 |
비교예2 | 99 | 50500 | 71700 | 1.42 | 427 | 9.7 |
|
반응투입량 | 루이스 산 | 단량체 투입량 | 개시제 | 중합조건 | |||||
[용매] /[단량체] (부피비) |
[알루미나] /[MMA] (mole비) |
[산화티타늄] /[MMA] (mole비) |
[MAA] /[MMA] (mole비) |
[Maleic acid] /[MMA] (mole비) |
[Maleic anhydride] /[MMA] (mole비) |
에틸렌 압력 (bar) |
[AIBN] /[단량체] (mole비) |
온도 (℃) |
시간 (h) |
|
실시예1 | 9 | 1 | - | 0.2 | - | - | 35 | 0.002 | 65 | 18 |
실시예 2 | 6 | 1 | - | 0.25 | - | - | 35 | 0.002 | 65 | 18 |
실시예3 | 9 | 1 | - | 1 | - | - | 35 | 0.002 | 65 | 18 |
실시예 4 | 9 | - | - | 0.25 | - | - | 35 | 0.002 | 65 | 18 |
실시예 5 | 15 | 1 | - | 0.1 | - | - | 35 | 0.001 | 70 | 6 |
실시예 6 | 10 | - | 1 | 0.1 | - | - | 35 | 0.001 | 70 | 6 |
실시예 7 | 10 | 1 | - | - | 0.1 | - | 35 | 0.001 | 75 | 6 |
실시예 8 | 6 | 1 | - | - | - | 0.25 | 35 | 0.002 | 65 | 18 |
실시예 9 | 9 | 1 | - | - | - | - | 35 | 0.003 | 75 | 18 |
|
고분자조성비(mole%) | 물성 | ||||||||
MMA | 에틸렌 | MAA | Maleic acid | Tg(℃) | Mn | Mw | PDI | Td_50 (℃) |
투명도(%) | |
실시예 1 |
63 | 11 | 26 | - | 155 | 78600 | 195000 | 2.48 | 461 | 90 |
실시예 2 |
55 | 13 | 32 | - | 146 | 61600 | 251000 | 4.08 | 456.5 | 90 |
실시예 3 |
35 | 7 | 58 | - | 181 | 88400 | 192000 | 2.17 | 457 | 89 |
실시예 4 |
57 | 2 | 35 | - | 156 | 59700 | 123000 | 2.05 | 461.9 | 90 |
실시예 5 |
64 | 23 | 13 | - | 121 | 97000 | 207000 | 2.14 | 451 | 89 |
실시예 6 |
72 | 17 | 11 | - | 128 | 81200 | 140000 | 1.72 | 442 | 91 |
실시예 7 |
67 | 15 | - | 18 | 118 | 59100 | 91500 | 1.55 | 448 | 89 |
실시예 8 |
65 | 8 | - | 27 | 123 | 96500 | 172000 | 1.78 | 400.7 | 90 |
실시예 9 |
65 | 14 | 21 | - | 151 | 26200 | 45300 | 1.73 | 452 | 89 |
반응 투입량 | 루이스 산 | 단량체 투입량 | 개시제 | 중합조건 | ||||||
[용매] /[단량 체] (부피 비) |
[알루 미나] /[MMA] (mole 비) |
[산화 지르코늄] /[MMA] (mole 비) |
[MAA] /[MMA] (mole 비) |
[1-butene] /[MMA] (mole 비) |
[1-hexene] /[MMA] (mole 비) |
[1- decen e] /[MMA] (mole 비) |
[AIBN] /단량체] (mole 비) |
온도 (℃) |
시간 (h) |
|
실시예 10 | 9 | 1 | - | 0.1 | 5 | - | - | 0.002 | 65 | 18 |
실시예11 | 6 | 1 | - | 0.1 | - | 3 | - | 0.002 | 65 | 18 |
실시예 12 | 9 | - | 1 | 0.1 | - | 3 | - | 0.002 | 65 | 18 |
실시예 13 | 9 | 1 | - | 0.1 | - | - | 3 | 0.002 | 65 | 18 |
|
고분자조성비(mole%) | 물성 | ||||||
MMA | 1-알켄 | MAA | Tg(℃) | Mn | Mw | PDI | 투명도(%) | |
실시예 10 |
74 | 9 | 17 | 138 | 96500 | 172000 | 1.78 | 90 |
실시예 11 |
71 | 17 | 12 | 120 | 56700 | 84000 | 1.68 | 90 |
실시예 12 |
74 | 12 | 14 | 131 | 64500 | 96600 | 1.79 | 89 |
실시예 13 |
66 | 15 | 19 | 103 | 102000 | 165000 | 1.61 | 89 |
Rin (nm) | Rth (nm) | 광탄성계수 (10-12 m2/N) | 열팽창계수 (ppm/K) | 투습도 (g/(m2 day)) |
|
비교예 1 | 0.1 | 2.0 | -3.2 | 113 | 76 |
비교예 2 | 0.1 | 2.3 | -3.4 | 101 | 83 |
비교예 3 | 1.0 | -50.0 | 12.7 | 57 | 720 |
실시예 5 | 0.0 | 2.7 | -0.6 | 71 | 200 |
실시예 6 | 0.1 | 1.2 | -0.6 | 72 | 211 |
실시예 7 | 0.3 | 3.4 | -0.5 | 87 | 203 |
실시예 8 | 0.6 | 2.5 | -0.6 | 81 | 207 |
실시예 11 | 0.4 | 3.6 | -0.5 | 74 | 221 |
실시예 13 | 0.4 | 3.5 | -0.6 | 73 | 217 |
사용 보호필름 |
단체투과도 (%) | 직교투과도 (%) |
|
비교예 4 | 비교예1 | 42.3 | 0.012 |
비교예 5 | 비교예2 | 42.0 | 0.013 |
비교예 6 | 비교예3 | 42.4 | 0.011 |
실시예 14 | 실시예5 | 41.8 | 0.014 |
실시예 15 | 실시예6 | 42.6 | 0.013 |
실시예 16 | 실시예7 | 41.9 | 0.015 |
실시예 17 | 실시예8 | 41.7 | 0.013 |
실시예 18 | 실시예11 | 42.3 | 0.016 |
실시예 19 | 실시예13 | 42.4 | 0.016 |
Claims (17)
- 삭제
- 알켄 단량체 0.1~30몰%, 아크릴레이트계 단량체 30~99몰% 및 이중결합을 하나 이상 가지는 불포화 유기산 단량체 0.1~50몰%를 포함하는 공중합체를 포함하며,상기 알켄 단량체는 1-알켄, 2-알켄 및 3-알켄 중에서 선택되는 적어도 하나를 포함하는 것인 광학필름.
- 청구항 2에 있어서, 상기 불포화 유기산 단량체는 1가 카르복실산 또는 다가 카르복실산인 것인 광학 필름.
- 청구항 2에 있어서, 상기 공중합체는 유리 전이 온도가 80~220℃, 수평균 분자량이 5,000 내지 400,000 범위, 중량평균 분자량이 10,000 내지 800,000, 공중합체의 초기 중량의 50%가 분해되는 온도(Td50)가 350 내지 550℃인 것인 광학 필름.
- 청구항 2에 있어서, 상기 공중합체는 알켄 단량체, 아크릴레이트계 단량체 및 이중결합을 하나 이상 가지는 불포화 유기산 단량체를 루이스산 또는 금속산화물 존재하에서 라디칼 중합개시제에 의하여 중합시키는 단계를 포함하는 방법에 의하여 제조된 것인 광학 필름.
- 알켄 단량체 0.1~30몰%, 아크릴레이트계 단량체 30~99몰% 및 이중결합을 하나 이상 가지는 불포화 유기산 단량체 0.1~50몰%를 포함하는 공중합체를 이용하며,상기 알켄 단량체는 1-알켄, 2-알켄 및 3-알켄 중에서 선택되는 적어도 하나를 포함하는 광학필름을 제조하는 방법.
- 청구항 2 내지 6 중 어느 하나의 항의 광학 필름으로 이루어진 편광자 보호필름.
- 청구항 8에 있어서, 표면 적어도 1면이 접착력 향상 처리된 것인 편광자 보호필름.
- 청구항 9에 있어서, 상기 처리는 코로나 처리, 플라즈마 처리, UV 처리, 프라이머층 형성 중에서 선택되는 1 이상을 포함하는 것인 편광자 보호필름.
- 편광자 및 상기 편광자의 적어도 일면에 구비된 보호필름을 포함하고, 상기 보호필름은 청구항 8에 따른 편광자 보호필름인 것인 편광판.
- 청구항 11에 있어서, 상기 편광자와 보호필름 사이에 접착제층이 구비된 것인 편광판.
- 청구항 11에 있어서, 적어도 하나의 표면에 점착제층을 추가로 구비한 편광판.
- 청구항 11의 편광판에, 위상차판, 광확산판, 시야각 확대판, 휘도 향상판 및 반사판 중에서 선택되는 적어도 하나의 광학층이 적층된 복합 편광판.
- 청구항 11의 편광판을 포함하는 화상표시장치.
- 광원, 제1 편광판, 액정셀, 제2 편광판을 순차적으로 적층된 상태로 포함하고, 상기 제1 편광판 및 제2 편광판 중 적어도 하나는 상기 청구항 11의 편광판인 액정표시장치인 화상표시장치.
- 청구항 16에 있어서, 상기 액정표시장치는 횡전계방식(In-Plane Switching mode; IPS mode), 수직배향방식(Vertically Aligned mode; VA mode), OCB 방식(Optically Compensated Birefringence mode), 비틀린 네마틱(Twisted Nematic mode; TN mode) 또는 FFS(Fringe Field Switching mode; FFS mode) 방식인 것인 화상표시장치.
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