KR100839989B1 - 경화형 수지 조성물, 접착제 및 그 제조방법 - Google Patents
경화형 수지 조성물, 접착제 및 그 제조방법 Download PDFInfo
- Publication number
- KR100839989B1 KR100839989B1 KR1020060067488A KR20060067488A KR100839989B1 KR 100839989 B1 KR100839989 B1 KR 100839989B1 KR 1020060067488 A KR1020060067488 A KR 1020060067488A KR 20060067488 A KR20060067488 A KR 20060067488A KR 100839989 B1 KR100839989 B1 KR 100839989B1
- Authority
- KR
- South Korea
- Prior art keywords
- meth
- resin composition
- acrylate
- curable resin
- weight
- Prior art date
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- 150000001875 compounds Chemical class 0.000 title claims description 5
- 238000004519 manufacturing process Methods 0.000 title abstract description 21
- 239000011347 resin Substances 0.000 title description 2
- 229920005989 resin Polymers 0.000 title description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 90
- 239000000853 adhesive Substances 0.000 claims abstract description 66
- 230000001070 adhesive effect Effects 0.000 claims abstract description 64
- 239000011342 resin composition Substances 0.000 claims abstract description 41
- 239000000178 monomer Substances 0.000 claims abstract description 25
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000002562 thickening agent Substances 0.000 claims abstract description 23
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- -1 diol compounds Chemical class 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 24
- 229920005862 polyol Polymers 0.000 claims description 16
- 150000003077 polyols Chemical class 0.000 claims description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 15
- 125000005442 diisocyanate group Chemical group 0.000 claims description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 3
- 229910021485 fumed silica Inorganic materials 0.000 claims description 3
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims description 2
- UZDMJPAQQFSMMV-UHFFFAOYSA-N 4-oxo-4-(2-prop-2-enoyloxyethoxy)butanoic acid Chemical compound OC(=O)CCC(=O)OCCOC(=O)C=C UZDMJPAQQFSMMV-UHFFFAOYSA-N 0.000 claims description 2
- KLNUMMZNTWJQIQ-UHFFFAOYSA-N C=CC(=O)OOC(=O)C1CCCCC1C(=O)O Chemical compound C=CC(=O)OOC(=O)C1CCCCC1C(=O)O KLNUMMZNTWJQIQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- AOFFRVQVWKIQEV-UHFFFAOYSA-N 2-(2-hydroxy-4-prop-2-enoyloxybutoxy)carbonylbenzoic acid Chemical compound C=CC(=O)OCCC(O)COC(=O)C1=CC=CC=C1C(O)=O AOFFRVQVWKIQEV-UHFFFAOYSA-N 0.000 claims 1
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 claims 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims 1
- 239000000463 material Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 30
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- 239000000203 mixture Substances 0.000 description 20
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 14
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 description 13
- XLPJNCYCZORXHG-UHFFFAOYSA-N 1-morpholin-4-ylprop-2-en-1-one Chemical compound C=CC(=O)N1CCOCC1 XLPJNCYCZORXHG-UHFFFAOYSA-N 0.000 description 13
- 239000002518 antifoaming agent Substances 0.000 description 13
- 229910002018 Aerosil® 300 Inorganic materials 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
- 239000012748 slip agent Substances 0.000 description 11
- CYUZOYPRAQASLN-UHFFFAOYSA-N 3-prop-2-enoyloxypropanoic acid Chemical compound OC(=O)CCOC(=O)C=C CYUZOYPRAQASLN-UHFFFAOYSA-N 0.000 description 9
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 8
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 7
- 238000009849 vacuum degassing Methods 0.000 description 7
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 6
- 150000002009 diols Chemical class 0.000 description 6
- 239000002202 Polyethylene glycol Substances 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- 229920001451 polypropylene glycol Polymers 0.000 description 5
- 230000009974 thixotropic effect Effects 0.000 description 5
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 4
- 238000001723 curing Methods 0.000 description 4
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 4
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- 238000000016 photochemical curing Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 3
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- 239000004417 polycarbonate Substances 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 229920005906 polyester polyol Polymers 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 description 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 238000004566 IR spectroscopy Methods 0.000 description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 description 2
- LKDRXBCSQODPBY-AMVSKUEXSA-N L-(-)-Sorbose Chemical compound OCC1(O)OC[C@H](O)[C@@H](O)[C@@H]1O LKDRXBCSQODPBY-AMVSKUEXSA-N 0.000 description 2
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
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- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 229940059574 pentaerithrityl Drugs 0.000 description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 2
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- 229920003023 plastic Polymers 0.000 description 2
- 229920001748 polybutylene Polymers 0.000 description 2
- 229920001610 polycaprolactone Polymers 0.000 description 2
- 239000004632 polycaprolactone Substances 0.000 description 2
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- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
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- 238000003756 stirring Methods 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 1
- QWQFVUQPHUKAMY-UHFFFAOYSA-N 1,2-diphenyl-2-propoxyethanone Chemical compound C=1C=CC=CC=1C(OCCC)C(=O)C1=CC=CC=C1 QWQFVUQPHUKAMY-UHFFFAOYSA-N 0.000 description 1
- VGHSXKTVMPXHNG-UHFFFAOYSA-N 1,3-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC(N=C=O)=C1 VGHSXKTVMPXHNG-UHFFFAOYSA-N 0.000 description 1
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- VZXPHDGHQXLXJC-UHFFFAOYSA-N 1,6-diisocyanato-5,6-dimethylheptane Chemical compound O=C=NC(C)(C)C(C)CCCCN=C=O VZXPHDGHQXLXJC-UHFFFAOYSA-N 0.000 description 1
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- OEURXIFGOPBMJF-UHFFFAOYSA-N 1-o-(2-hydroxyethyl) 2-o-(2-prop-2-enoyloxyethyl) benzene-1,2-dicarboxylate Chemical compound OCCOC(=O)C1=CC=CC=C1C(=O)OCCOC(=O)C=C OEURXIFGOPBMJF-UHFFFAOYSA-N 0.000 description 1
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- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 1
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- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 description 1
- ACWBYVIQVCTYBJ-UHFFFAOYSA-N 3-methyloctane-1,8-diol Chemical compound OCCC(C)CCCCCO ACWBYVIQVCTYBJ-UHFFFAOYSA-N 0.000 description 1
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- 229910002012 Aerosil® Inorganic materials 0.000 description 1
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- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 description 1
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- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
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- DKKXSNXGIOPYGQ-UHFFFAOYSA-N diphenylphosphanyl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(C=1C=CC=CC=1)C1=CC=CC=C1 DKKXSNXGIOPYGQ-UHFFFAOYSA-N 0.000 description 1
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- MHCLJIVVJQQNKQ-UHFFFAOYSA-N ethyl carbamate;2-methylprop-2-enoic acid Chemical compound CCOC(N)=O.CC(=C)C(O)=O MHCLJIVVJQQNKQ-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
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Abstract
Description
실시예 3 | 실시예 4 | 실시예 5 | 비교예 5 | 비교예 6 | 비교예 7 | |
부착성 | 100/100 | 100/100 | 100/100 | 40/100 | 25/100 | 30/100 |
인장강도 (kgf/㎠) | 112 | 110 | 115 | 130 | 132 | 135 |
신율(%) | 180 | 182 | 177 | 125 | 121 | 115 |
경도 | 71 | 70 | 72 | 76 | 77 | 79 |
실시예 3 | 실시예 4 | 실시예 5 | 실시예 6 | 비교예 3 | 비교예 9 | |
부착성 | 100/100 | 100/100 | 100/100 | 100/100 | 100/100 | 75/100 |
인장강도 (kgf/㎠) | 112 | 110 | 115 | 118 | 114 | 117 |
신율(%) | 180 | 182 | 177 | 170 | 178 | 181 |
경도 | 71 | 70 | 72 | 73 | 72 | 73 |
칙소성 | 도 2 참조 |
실시예 4 | 실시예 5 | 비교예 1 | 비교예 2 | 비교예 4 | 비교예 8 | |
부착성 | 100/100 | 100/100 | 100/100 | 100/100 | 100/100 | 100/100 |
인장강도 (kgf/㎠) | 110 | 115 | 116 | 115 | 113 | 115 |
신율(%) | 182 | 177 | 175 | 176 | 172 | 177 |
경도 | 70 | 72 | 72 | 72 | 70 | 72 |
칙소성 | 도 3 참조 | |||||
기포유무 | 양호 | 양호 | 양호 | 양호 | 양호 | 불량 |
Claims (17)
- 적어도 하나 이상의 디이소시아네이트 화합물, 적어도 하나 이상의 디올 화합물, 폴리올 및 적어도 하나 이상의 수산기 함유 (메타)아크릴레이트의 공중합물인 우레탄(메타)아크릴레이트 프리폴리머(A);(메타)아크릴레이트 모노머(B); 및카르복실레이티드(메타)아크릴레이트 모노머(C);를 포함하는 것을 특징으로 하는 경화성 수지 조성물
- 제 1항에 있어서,상기 우레탄(메타)아크릴레이트 프리폴리머(A)는 중량평균분자량이 3000 내지 10000인 것을 특징으로 하는 경화성 수지 조성물
- 제 1항에 있어서,상기 우레탄(메타)아크릴레이트 프리폴리머(A)는 분자당 평균우레탄 결합이 8 내지 20개 존재하는 것인 것을 특징으로 하는 경화성 수지 조성물
- 제1항에 있어서,상기 디올 화합물은 200미만의 분자량을 갖는 단분자 화합물인 것을 특징으로 하는 경화성 수지 조성물
- 제1항에 있어서,상기 폴리올은 중량평균분자량이 200내지 3000인 것을 특징으로 하는 경화성 수지 조성물
- 제1항에 있어서,상기 수산기 함유 (메타)아크릴레이트는 2-하이드록시에틸(메타)아크릴레이트, 2-하이드록시프로필(메타)아크릴레이트 및 2-하이드록시부틸(메타)아크릴레이트로 이루어진 군으로부터 적어도 하나 이상 선택된 것임을 특징으로 하는 경화성 수지 조성물
- 제1항에 있어서,상기 카르복실레이티드(메타)아크릴레이트 모노머(C)로는 2-(메타)아크릴로일옥시에틸석시네이트, 2-(메타)아크릴로일옥시헥사하이드로프탈레이트, 2-(메타)아크릴로일옥시에틸프탈레이트, 2-(메타)아크릴로일옥시에틸2-하이드록시에틸프탈레이트, β-카르복실에틸(메타)아크릴레이트로 이루어진 군으로부터 적어도 하나 이상 선택된 것임을 특징으로 하는 경화성 수지 조성물
- 제 1항에 있어서,증점제(D)를 더 포함하는 것을 특징으로 하는 경화성 수지 조성물
- 제8항에 있어서,상기 증점제(D)는 클레이(clay structure), 폴리아마이드(polyamide structure), 체인 인텡글먼트(chain entanglement), 회합성시크너(associative thickner), 알카리스웰러블(alkali swellerble), 퓸드실리카(fumed silica)로 이루어진 군으로부터 적어도 하나 이상 선택된 것임을 특징으로 하는 경화성 수지 조성물
- 제1항에 있어서,상기 경화성 수지 조성물은 광경화형인 것을 특징으로 하는 경화성 수지 조성물
- 제10항에 있어서,광개시제(E)를 더 포함하는 것을 특징으로 하는 경화성 수지 조성물
- 삭제
- 제8항에 있어서,상기 증점제(D)가 경화성 수지 조성물 총 중량의 0.5 내지 4 중량%로 포함되는 것을 특징으로 하는 경화성 수지 조성물
- 제11항에 있어서,상기 광개시제(E)는 경화성 수지 조성물 총 중량의 1 내지 7 중량%로 포함되는 것을 특징으로 하는 경화성 수지 조성물
- 제1항 내지 제11항 또는 제13항 내지 제14항 중 어느 한 항에 있어서의 경화성 수지 조성물을 포함하는 것을 특징으로 하는 접착제
- 제1항 내지 제11항 또는 제13항 내지 제14항 중 어느 한 항에 있어서의 경화성 수지 조성물을 제조하는 단계; 및상기 경화성 수지 조성물을 40 내지 70℃의 온도에서, 5 내지 30분간, 0.1 내지 50 torr의 압력으로 감압하여 상기 경화성 수지 조성물 내에 존재하는 기포를 제거하는 단계;를 포함하는 것을 특징으로 하는 경화형 접착제 제조 방법
- 제15항의 접착제를 이어폰 또는 헤드폰의 내부 코일 리드선 보호용 접착제로 사용하는 것을 특징으로 하는 접착제 사용방법
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