JPS63240912A - Ceramic filter for dustcollecting from exhaust gas - Google Patents

Ceramic filter for dustcollecting from exhaust gas

Info

Publication number
JPS63240912A
JPS63240912A JP7298187A JP7298187A JPS63240912A JP S63240912 A JPS63240912 A JP S63240912A JP 7298187 A JP7298187 A JP 7298187A JP 7298187 A JP7298187 A JP 7298187A JP S63240912 A JPS63240912 A JP S63240912A
Authority
JP
Japan
Prior art keywords
exhaust gas
fine grain
average pore
pore diameter
dust
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7298187A
Other languages
Japanese (ja)
Inventor
Hiroshi Hasegawa
宏 長谷川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NGK Insulators Ltd
Original Assignee
NGK Insulators Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NGK Insulators Ltd filed Critical NGK Insulators Ltd
Priority to JP7298187A priority Critical patent/JPS63240912A/en
Publication of JPS63240912A publication Critical patent/JPS63240912A/en
Pending legal-status Critical Current

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  • Filtering Materials (AREA)
  • Filtering Of Dispersed Particles In Gases (AREA)

Abstract

PURPOSE:To obtain a filter having high efficiency of dustcollecting from exhaust gas by providing a fine grain part having 1-10mum mean hole diameter and thickness of >=10 times of fine hole diameter on the one side of supporting layer composed of ceramic porous body. CONSTITUTION:The ceramic filter 3 for dustcollecting from exhaust gas is provided with the fine grain part 2 on the supporting layer 1 composed of ceramic porous body 1 so that the mean hole diameter of the fine grain part 2 is 1-10mum and the thickness of said part 2 is >=10 times the mean hole diameter. When the filter 3 is cylindrical the fine grain part 2 may be placed on any surface of outer or inner side of the filter 3. Then, the mean fine pore size of the supporting layer 1 is 50-200mum and is more preferably 80-150mum. SiC, Al2O2, cordielite, zirconia, mullite and these complex is used as ceramics material composing the supporting layer, the fine grain part and the middle part.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、鉄鋼、全屈分野などのダスト含有排ガスおよ
び石炭ガス化ガスおよび重油・石炭燃焼排ガスなどから
ダストを集塵する集塵用セラミ・ンクフィルターに関す
るものである。
Detailed Description of the Invention (Industrial Field of Application) The present invention provides a dust-collecting ceramic for collecting dust from dust-containing exhaust gas from steel and steel fields, coal gasification gas, and heavy oil/coal combustion exhaust gas.・This is related to link filters.

(従来の技術) 従来、ダスト含有排ガスや燃焼排ガス等の高温ガス中か
らダストを捕集するセラミックフィルターとしては単層
構造のセラミックフィルターが使用されているが、近年
特開昭60−61019号公報にあるように複層構造の
セラミンクフィルターが低圧損として注目されている。
(Prior Art) Conventionally, a single-layer ceramic filter has been used as a ceramic filter to collect dust from high-temperature gases such as dust-containing exhaust gas and combustion exhaust gas, but recently Japanese Patent Laid-Open No. 60-61019 discloses a ceramic filter with a single layer structure. As shown in , multi-layered ceramic filters are attracting attention for their low pressure loss.

(発明が解決しようとする問題点) 一般に、排ガスは約1μm前後の粒径を有しまたダスト
を必ず含有しており、適切な構造を有するセラミックフ
ィルターを採用しない場合複層構造とは言えども集塵後
の圧力損失が大きくなったjり、集塵効率が低いなどの
問題点が起きる。
(Problems to be Solved by the Invention) In general, exhaust gas has a particle size of about 1 μm and always contains dust, and if a ceramic filter with an appropriate structure is not used, even if it has a multilayer structure, Problems arise such as increased pressure loss after dust collection and low dust collection efficiency.

例えば細粒部の平均細孔径が大きい場合ダストが細粒部
潔くまで侵入し、逆洗しても圧力1員失の増加があり実
用レベルの圧力損失以上になるとともに、更に集塵効率
が低いなどの問題点がある。
For example, if the average pore diameter of the fine grain part is large, dust will penetrate into the fine grain part, and even if it is backwashed, there will be an increase in pressure loss, which will exceed the practical level of pressure loss, and the dust collection efficiency will further decrease. There are other problems.

一方、逆に細粒部の平均細孔径が非常に小さい場合ダス
トは組粒部表面で堆積するが、平均細孔径が小さいため
圧力損失は集塵するn(1でもすでに高いなどの問題点
がある。
On the other hand, if the average pore diameter of the fine grain part is very small, dust will accumulate on the surface of the aggregate part, but because the average pore diameter is small, the pressure loss is already high. be.

本発明の目的は上述した不具合を罫消して、集塵後の圧
力損失の経時変化が小さいとともに集塵効率が高く実用
面で秀れた排ガス集塵用セラミックフィルターを提供し
ようとするものである。
The purpose of the present invention is to eliminate the above-mentioned drawbacks and provide a ceramic filter for exhaust gas dust collection that has a small change in pressure loss after dust collection over time, has high dust collection efficiency, and is excellent in practical use. .

(問題点を解決するための手段) 本発明の排ガス集塵用セラミックフィルターは、セラミ
ック多孔体よりなる支持層の片側の表面に、平均細孔径
が1〜10μmで厚さが平均細孔径の少なくとも10倍
以上の細粒部を備えたことを特徴とするものである。
(Means for Solving the Problems) The ceramic filter for exhaust gas dust collection of the present invention has an average pore diameter of 1 to 10 μm and a thickness of at least at least the average pore diameter on one surface of a support layer made of a ceramic porous body. It is characterized by having a fine grain part that is 10 times or more larger.

(作 用) 上述した構成において、セラミック多孔体よりなる支持
層の片側の表面に細粒部を設けるとともに、この細粒部
の平均細孔径を1〜10μm、厚さを平均細孔径の少な
くとも10倍以上とすることにより、排ガス中の粒径1
μm前後のダスト分を低圧損かつ高い集塵効率で集塵す
ることができる。
(Function) In the above structure, a fine grain part is provided on one surface of the support layer made of a porous ceramic body, and the fine grain part has an average pore diameter of 1 to 10 μm and a thickness of at least 10 μm of the average pore diameter. By increasing the particle size by more than twice as much, the particle size in the exhaust gas becomes
Dust around μm can be collected with low pressure loss and high dust collection efficiency.

なお、本発明で細粒部の平均細孔径を1〜10μm、厚
さを平均細孔径の少なくとも10倍以上としたのは以下
の理由による。
In addition, the reason why the average pore diameter of the fine grain portion is set to 1 to 10 μm and the thickness is set to at least 10 times the average pore diameter in the present invention is as follows.

第2図に示すように、約1μm′のダスト含有排ガスの
ダスト侵入深さを調べたところ、ダスト侵入深さは細粒
部の平均細孔径が10μmまではその細粒部の平均細孔
径の約10倍の深さまで侵入しており、10μm以上で
は細粒部の平均細孔径の10倍以上の深さまで侵入して
おり、次いで細粒部の平均細孔径が太き(なればなる程
更に奥深くまでダストが侵入することが解った。言い換
えれば、高い集塵効率及び低圧損を得る為の細粒部の必
要最小深さは第2図にて決めることができる。
As shown in Figure 2, when the dust penetration depth of dust-containing exhaust gas of approximately 1 μm' was investigated, it was found that the dust penetration depth is smaller than the average pore diameter of the fine grain portion until the average pore diameter of the fine grain portion is 10 μm. It penetrates to a depth of about 10 times, and when it is 10 μm or more, it penetrates to a depth of more than 10 times the average pore diameter of the fine grain part, and then the average pore diameter of the fine grain part becomes thicker (the more It was found that dust penetrates deeply.In other words, the required minimum depth of the fine grain part to obtain high dust collection efficiency and low pressure loss can be determined from Figure 2.

また、第3図は第2図にて得られた細粒部必要最小厚さ
を有するセラミックフィルターを各細粒部の平均細孔径
を変えて作製し、それらについて初期圧力損失と集塵後
の圧力損失及び集塵効率を測定したものである。第3図
において、細粒部の平均細孔径が10μm以上の場合は
初期圧力損失が低いけれども、集塵後の圧力損失は平均
細孔径が大きくなるに従い増大が激しい。これは、ダス
トが奥深くまで侵入する為逆洗を行っても回復が小さい
為である。また、集塵効率も低下が激しい。
In addition, Figure 3 shows ceramic filters having the required minimum thickness of the fine grain part obtained in Figure 2, which were fabricated by changing the average pore diameter of each fine grain part, and the initial pressure loss and after dust collection. This is a measurement of pressure loss and dust collection efficiency. In FIG. 3, when the average pore diameter of the fine grain portion is 10 μm or more, the initial pressure loss is low, but the pressure loss after dust collection increases rapidly as the average pore diameter increases. This is because the dust penetrates deep and recovery is small even if backwashing is performed. Furthermore, the dust collection efficiency is also significantly reduced.

一方、細粒部の平均細孔径が1μm以下の場合集塵効率
は高いが、初期圧力損失が平均細孔径が小さくなるに従
い指数関数的に高くなり実用上問題である。
On the other hand, when the average pore diameter of the fine particle portion is 1 μm or less, the dust collection efficiency is high, but the initial pressure loss increases exponentially as the average pore diameter becomes smaller, which is a practical problem.

以上のことから、通常要求される集塵後の圧、力1員失
が1000100O以下および集塵効率が99.9%以
上の条件を満たすとともに初期圧力損失も低い範囲とし
て細粒部の平均細孔径を1〜10μmと規定した。また
、同様に細粒部の厚さは平均細孔部の10倍以上と限定
した。厚さは好ましくは平均細孔径の10〜80倍がよ
い。
Based on the above, the average fineness of the fine grain part is set as a range that satisfies the normally required conditions of pressure and force loss of 1000100 O or less and dust collection efficiency of 99.9% or more and that the initial pressure loss is low. The pore diameter was defined as 1 to 10 μm. Similarly, the thickness of the fine grain part was limited to 10 times or more the average pore part. The thickness is preferably 10 to 80 times the average pore diameter.

さらに、支持層を形成するセラミック多孔体の厚さは特
に限定するものではないが、50〜200μmであると
好ましいのは、その平均細孔径と曲げ強さとの関係を示
す第4図から明らかなように、200μm以下であれば
フィルターとしての曲げ強度が200 kg/cm”を
超えるとともに、50μm未満では全体の圧力損失が大
きくなりすぎるからである。
Further, the thickness of the ceramic porous body forming the support layer is not particularly limited, but it is preferably 50 to 200 μm, as is clear from Figure 4, which shows the relationship between the average pore diameter and bending strength. If the thickness is 200 μm or less, the bending strength as a filter exceeds 200 kg/cm”, and if it is less than 50 μm, the overall pressure loss becomes too large.

(実施例) 第1図(a)、 (b)、 (c)はそれぞれ本発明の
排ガス集塵用セラミックフィルターの一実施例を示す部
分断面図である。第1図(a)に示す実施例では、セラ
ミック多孔体よりなる支持N1の表面に平均細孔径が1
〜10μmで厚さが平均細孔径の少なくとも10倍以上
となるように細粒部2を設けて、本発明の排ガス集塵用
セラミックフィルター3を構成した例を示している。第
1図(b)に示す実施例では、支持層1の表面の外側に
露出した粒子4の間に細粒部2を形成して排ガス集塵用
セラミックフィルター3を構成した例を示している。さ
らに、第1図(c)に示す実施例では、支持層1と細粒
部2との間に平均細孔径が支持層1と細粒部2の平均細
孔径の中間の値である中間部5を設けて排ガス集塵用セ
ラミックフィルター3を構成した例を示している。  
(Example) FIGS. 1(a), 1(b), and 1(c) are partial sectional views showing an example of the ceramic filter for collecting exhaust gas dust of the present invention. In the embodiment shown in FIG. 1(a), the average pore diameter is 1 on the surface of the support N1 made of a ceramic porous body.
An example is shown in which the ceramic filter 3 for collecting exhaust gas dust of the present invention is constructed by providing the fine grain portion 2 so as to have a thickness of ~10 μm and at least 10 times the average pore diameter. The embodiment shown in FIG. 1(b) shows an example in which a fine particle portion 2 is formed between the particles 4 exposed on the outside of the surface of the support layer 1 to constitute a ceramic filter 3 for collecting exhaust gas dust. . Furthermore, in the embodiment shown in FIG. 1(c), there is an intermediate portion between the support layer 1 and the fine grain portion 2 in which the average pore diameter is an intermediate value between the average pore diameters of the support layer 1 and the fine grain portion 2. 5 is provided to configure a ceramic filter 3 for collecting exhaust gas dust.
.

また、細粒部2の位置はフィルター3の形状が円筒状の
場合はその外面又は内面のどちらかの面に形成してあれ
ばよい。さらに、フィルター3の強度の面から、支持N
1の平均細孔径は50〜200μm好ましくは80〜1
50μmとしている。支持層、細粒部および中間部を構
成するセラミックスの材質としては、SiC,A 42
20:l、  コージェライト、ジルコニア、ムライト
及びその複合体を使用すると好適である。
Furthermore, when the filter 3 has a cylindrical shape, the fine grain portion 2 may be formed on either the outer surface or the inner surface. Furthermore, from the viewpoint of the strength of the filter 3, the support N
1 has an average pore diameter of 50 to 200 μm, preferably 80 to 1
It is set to 50 μm. The material of the ceramics constituting the support layer, the fine grain part and the intermediate part is SiC, A42
20:l, cordierite, zirconia, mullite and composites thereof are preferably used.

以下、実際の例について説明する。An actual example will be explained below.

裏立健 外径60mm、内径40mm、長さ300mmの円筒形
状であって、外周面に平均細孔径100μmの支持層と
平均細孔径5μmで厚さ100μmの細粒部とを第1図
(a)に示すように形成したセラミックフィルターを準
備した。準備したセラミックフィルターにタストe度1
0g/Nm’、ダスト平均粒径1μm、排ガス温度20
0°Cの重油燃焼排ガスを、濾過速度6m/分、排ガス
圧力2000mm A qの条件で流通して集塵試験を
行なった。なお、逆洗はN2ガスを5kg/cm2の圧
力で10分に1回の間隔で1回当り0.5秒間実施した
It has a cylindrical shape with an outer diameter of 60 mm, an inner diameter of 40 mm, and a length of 300 mm, and has a support layer with an average pore diameter of 100 μm on the outer peripheral surface and a fine grain part with an average pore diameter of 5 μm and a thickness of 100 μm on the outer peripheral surface. A ceramic filter formed as shown in ) was prepared. Tast e degree 1 on the prepared ceramic filter
0g/Nm', dust average particle size 1μm, exhaust gas temperature 20
A dust collection test was conducted by flowing heavy oil combustion exhaust gas at 0°C under conditions of a filtration rate of 6 m/min and an exhaust gas pressure of 2000 mm Aq. Note that backwashing was performed using N2 gas at a pressure of 5 kg/cm2 at intervals of once every 10 minutes for 0.5 seconds each time.

以上の条件で集塵試験を行なった結果、初期圧力損失は
150mmAqに対し集塵開始1000時間後でも圧力
損失は1000100Oで安定しており、集塵効率も9
9.9%であった。
As a result of conducting a dust collection test under the above conditions, the initial pressure loss was 150 mmAq, but even after 1000 hours after the start of dust collection, the pressure loss was stable at 1000100 O, and the dust collection efficiency was 9.
It was 9.9%.

(発明の効果) 以上詳細に説明したところから明らがなように、本発明
の排ガス集塵用セラミックフィルターによれば、集塵後
の圧力損失の経時変化が小さいとともに集塵効率が高く
実用面で秀れた排ガス集塵用セラミックフィルターを得
ることができる。
(Effects of the Invention) As is clear from the above detailed explanation, according to the ceramic filter for collecting exhaust gas dust of the present invention, the change in pressure loss over time after dust collection is small, and the dust collection efficiency is high enough for practical use. It is possible to obtain a ceramic filter for exhaust gas dust collection that is excellent in terms of both aspects.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図(a) 、 (b) 、 (c)はそれぞれ本発
明の排ガス集塵用セラミックフィルターの1実施例を示
す部分断面図、 第2図はダスト侵入深さと細粒部の平均細孔径との関係
を示すグラフ、 第3図は圧力損失及び集塵効率と細粒部の平均細孔径と
の関係を示すグラフ、 第4図はフィルターの曲げ強度と支持層の平均細孔径と
の関係を示すグラフである。 1・・・支持層 2・・・細粒部 3・・・セラミックフィルター 4・・・粒子 5・・・中間部 特許出願人  日本碍子株式会社 第1図 (a〕(b)    (c> 第3図
Figures 1 (a), (b), and (c) are partial cross-sectional views showing one embodiment of the ceramic filter for collecting exhaust gas dust of the present invention, and Figure 2 shows the dust penetration depth and the average pore diameter of the fine particle portion. Figure 3 is a graph showing the relationship between pressure loss and dust collection efficiency and the average pore diameter of the fine particle part. Figure 4 is the relationship between the bending strength of the filter and the average pore diameter of the support layer. This is a graph showing. 1...Supporting layer 2...Fine particle portion 3...Ceramic filter 4...Particle 5...Intermediate portion Patent applicant Nippon Insulator Co., Ltd. Figure 1 (a) (b) (c> Figure 3

Claims (1)

【特許請求の範囲】 1、セラミック多孔体よりなる支持層の片側の表面に、
平均細孔径が1〜10μmで厚さが平均細孔径の少なく
とも10倍以上の細粒部を備えたことを特徴とする排ガ
ス集塵用セラミックフィルター。 2、前記セラミック多孔体の平均細孔径が50〜200
μmである特許請求の範囲第1項記載の排ガス集塵用セ
ラミックフィルター。
[Claims] 1. On one surface of a support layer made of a ceramic porous body,
1. A ceramic filter for collecting dust from exhaust gas, characterized by having fine grain portions having an average pore diameter of 1 to 10 μm and a thickness of at least 10 times the average pore diameter. 2. The average pore diameter of the ceramic porous body is 50 to 200.
The ceramic filter for collecting exhaust gas dust according to claim 1, which has a diameter of μm.
JP7298187A 1987-03-28 1987-03-28 Ceramic filter for dustcollecting from exhaust gas Pending JPS63240912A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7298187A JPS63240912A (en) 1987-03-28 1987-03-28 Ceramic filter for dustcollecting from exhaust gas

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7298187A JPS63240912A (en) 1987-03-28 1987-03-28 Ceramic filter for dustcollecting from exhaust gas

Publications (1)

Publication Number Publication Date
JPS63240912A true JPS63240912A (en) 1988-10-06

Family

ID=13505074

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7298187A Pending JPS63240912A (en) 1987-03-28 1987-03-28 Ceramic filter for dustcollecting from exhaust gas

Country Status (1)

Country Link
JP (1) JPS63240912A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5073178A (en) * 1989-04-07 1991-12-17 Asahi Glass Company, Ltd. Ceramic filter for a dust-containing gas and method for its production
US5198006A (en) * 1989-04-07 1993-03-30 Asahi Glass Company, Ltd. Ceramic filter for a dust-containing gas and method for its production
US5545243A (en) * 1993-12-15 1996-08-13 Ngk Insulators, Ltd. Porous ceramic honeycomb filter
WO2008136232A1 (en) * 2007-04-27 2008-11-13 Ngk Insulators, Ltd. Honeycomb filter
JP2009172604A (en) * 2009-03-26 2009-08-06 Kyocera Corp Ceramic filter and its manufacturing method
WO2010110011A1 (en) 2009-03-26 2010-09-30 日本碍子株式会社 Honeycomb filter and method for producing honeycomb filter
WO2011040554A1 (en) * 2009-09-30 2011-04-07 住友大阪セメント株式会社 Exhaust gas purification filter
JP2011189246A (en) * 2010-03-12 2011-09-29 Ngk Insulators Ltd Honeycomb filter, and method of producing the same

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4918326A (en) * 1972-06-10 1974-02-18
JPS6061019A (en) * 1983-09-13 1985-04-08 Asahi Glass Co Ltd Ceramic filter for dust collection
JPS6372319A (en) * 1986-09-12 1988-04-02 Ebara Corp Filter for use at high temperature

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4918326A (en) * 1972-06-10 1974-02-18
JPS6061019A (en) * 1983-09-13 1985-04-08 Asahi Glass Co Ltd Ceramic filter for dust collection
JPS6372319A (en) * 1986-09-12 1988-04-02 Ebara Corp Filter for use at high temperature

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5073178A (en) * 1989-04-07 1991-12-17 Asahi Glass Company, Ltd. Ceramic filter for a dust-containing gas and method for its production
US5198006A (en) * 1989-04-07 1993-03-30 Asahi Glass Company, Ltd. Ceramic filter for a dust-containing gas and method for its production
US5545243A (en) * 1993-12-15 1996-08-13 Ngk Insulators, Ltd. Porous ceramic honeycomb filter
WO2008136232A1 (en) * 2007-04-27 2008-11-13 Ngk Insulators, Ltd. Honeycomb filter
JP5616059B2 (en) * 2007-04-27 2014-10-29 日本碍子株式会社 Honeycomb filter
US8444739B2 (en) 2007-04-27 2013-05-21 Ngk Insulators, Ltd. Honeycomb filter
WO2010110010A1 (en) 2009-03-26 2010-09-30 日本碍子株式会社 Honeycomb filter and method for producing honeycomb filter
WO2010110011A1 (en) 2009-03-26 2010-09-30 日本碍子株式会社 Honeycomb filter and method for producing honeycomb filter
US8470254B2 (en) 2009-03-26 2013-06-25 Ngk Insulators, Ltd. Honeycomb filter and method for producing honeycomb filter
US8470255B2 (en) 2009-03-26 2013-06-25 Ngk Insulators, Ltd. Honeycomb filter and method for producing honeycomb filter
JP2009172604A (en) * 2009-03-26 2009-08-06 Kyocera Corp Ceramic filter and its manufacturing method
WO2011040554A1 (en) * 2009-09-30 2011-04-07 住友大阪セメント株式会社 Exhaust gas purification filter
JPWO2011040554A1 (en) * 2009-09-30 2013-02-28 住友大阪セメント株式会社 Exhaust gas purification filter
EP2484423A4 (en) * 2009-09-30 2014-01-08 Sumitomo Osaka Cement Co Ltd Exhaust gas purifying filter
JP2011189246A (en) * 2010-03-12 2011-09-29 Ngk Insulators Ltd Honeycomb filter, and method of producing the same

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