JPS63218779A - Pigment ink composition for ball point pen - Google Patents
Pigment ink composition for ball point penInfo
- Publication number
- JPS63218779A JPS63218779A JP62052108A JP5210887A JPS63218779A JP S63218779 A JPS63218779 A JP S63218779A JP 62052108 A JP62052108 A JP 62052108A JP 5210887 A JP5210887 A JP 5210887A JP S63218779 A JPS63218779 A JP S63218779A
- Authority
- JP
- Japan
- Prior art keywords
- pigment
- parts
- ink composition
- ink
- writing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000049 pigment Substances 0.000 title claims abstract description 74
- 239000000203 mixture Substances 0.000 title claims abstract description 48
- 239000002245 particle Substances 0.000 claims abstract description 30
- 239000002270 dispersing agent Substances 0.000 claims abstract description 25
- 239000011347 resin Substances 0.000 claims abstract description 21
- 229920005989 resin Polymers 0.000 claims abstract description 21
- 229920000642 polymer Polymers 0.000 claims abstract description 18
- 239000007788 liquid Substances 0.000 claims abstract description 11
- 239000006229 carbon black Substances 0.000 claims abstract description 8
- 229920003229 poly(methyl methacrylate) Polymers 0.000 abstract description 3
- 239000004926 polymethyl methacrylate Substances 0.000 abstract description 3
- 238000007599 discharging Methods 0.000 abstract 1
- 230000009191 jumping Effects 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 70
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 239000006185 dispersion Substances 0.000 description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 239000000975 dye Substances 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 4
- 239000012964 benzotriazole Substances 0.000 description 4
- 239000011362 coarse particle Substances 0.000 description 4
- 239000010419 fine particle Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 239000001023 inorganic pigment Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000012860 organic pigment Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- HMLSBRLVTDLLOI-UHFFFAOYSA-N 1-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)C(C)OC(=O)C(C)=C HMLSBRLVTDLLOI-UHFFFAOYSA-N 0.000 description 1
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 1
- ZUAURMBNZUCEAF-UHFFFAOYSA-N 2-(2-phenoxyethoxy)ethanol Chemical compound OCCOCCOC1=CC=CC=C1 ZUAURMBNZUCEAF-UHFFFAOYSA-N 0.000 description 1
- AWFYPPSBLUWMFQ-UHFFFAOYSA-N 2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]-1-(1,4,6,7-tetrahydropyrazolo[4,3-c]pyridin-5-yl)ethanone Chemical group C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1=NN=C(O1)CC(=O)N1CC2=C(CC1)NN=C2 AWFYPPSBLUWMFQ-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical group C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 1
- GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 239000010866 blackwater Substances 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- PPSZHCXTGRHULJ-UHFFFAOYSA-N dioxazine Chemical compound O1ON=CC=C1 PPSZHCXTGRHULJ-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000008164 mustard oil Substances 0.000 description 1
- -1 mustard oil fatty acids Chemical class 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- DGBWPZSGHAXYGK-UHFFFAOYSA-N perinone Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13 DGBWPZSGHAXYGK-UHFFFAOYSA-N 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、ボールペン用インキに関し、更に詳しく云え
ば、顔料、分散剤及び液媒体からなるインキに、球状樹
脂粒子を含有させることにより、古き出し時のインキの
出がスムーズであり、連続筆記においても描線の飛びが
なく、滑らかな筆記が可能なボールペン用顔料インキ組
成物に関するものである。Detailed Description of the Invention (Field of Industrial Application) The present invention relates to ink for ballpoint pens, and more specifically, by incorporating spherical resin particles into an ink consisting of a pigment, a dispersant, and a liquid medium, The present invention relates to a pigment ink composition for a ballpoint pen, which allows smooth ink to flow out during dispensing, does not cause skipped lines even in continuous writing, and allows smooth writing.
（従来の技術）
従来、ボールペンは筆記具の一種として非常に広く使用
されており、これらのボールペン用インキとしては、従
来高粘度の油性インキが使用されてきたが、近年になっ
て、乾燥性に優れた水性インキも広く使用されるように
なった。(Prior art) Ballpoint pens have been very widely used as a type of writing instrument, and high-viscosity oil-based inks have been used for these ballpoint pens, but in recent years, ink with drying properties has been used. Superior water-based inks also became widely used.
これらのボールペン用インキに使用される色材としては
、水溶性の染料及び顔料に大別されるが、染料の場合に
は、ペン先における目詰り等に問題は生じないが、記録
物の耐光性や耐水性に多くの問題が生じる。The coloring materials used in these ballpoint pen inks are broadly classified into water-soluble dyes and pigments, but dyes do not cause problems such as clogging at the pen tip, but the light resistance of recorded materials There are many problems with durability and water resistance.
一方、顔料の場合には、優れた耐光性や耐水性の記録物
が得られるため、近年は、顔料インキが広く使用される
ようになっている。On the other hand, in the case of pigments, recorded matter with excellent light resistance and water resistance can be obtained, so pigment inks have become widely used in recent years.
（発明が解決しようとしている問題点）ボールペン用イ
ンキにおいて、染料タイプに関してはいろいろな添加剤
が開発され実用に供されてきたが、顔料タイプについて
は色料である顔料そのものが微粒子で存在するため、表
面活性も大きく染料ときわだった対照を示し、顔料が粒
子であるためにボールペンのボールの摩耗を著しく早め
、また粒子の凝集に基づくインキの流動性の欠如等を引
き起こす。(Problem to be solved by the invention) Regarding ballpoint pen ink, various additives have been developed and put into practical use for dye type inks, but for pigment type inks, the pigment itself exists in the form of fine particles. The pigment has a large surface activity, which is in sharp contrast to that of the dye, and since the pigment is in the form of particles, it significantly accelerates the wear of the ball of a ballpoint pen, and also causes a lack of fluidity in the ink due to the agglomeration of particles.
従来、顔料を用いたボールペン用インキにおいては、特
にインキ自体の■滑性が不足しているため、ボールの回
転がスムーズに行われず、書き出し時のインキの吐出が
不十分であり、また、連続筆記した時の線飛びが生じた
り、滑らかな筆記感が無く、またインキ吐出の極端な減
少をきたし、また長時間の使用により、ボール受座の摩
耗によりボールの欠落をきたすに至り、インキが消費さ
れる前に筆記不能となる等の欠点を有していた。Conventionally, ink for ballpoint pens using pigments has been lacking in lubricity, especially the ink itself, so the ball does not rotate smoothly, the ink is not ejected sufficiently at the beginning of writing, and the ink does not flow continuously. Lines may skip when writing, the writing will not feel smooth, and ink discharge will be extremely reduced.Also, after long-term use, the balls may become missing due to wear on the ball catch, resulting in ink being lost. It had the disadvantage that it became impossible to write on before it was consumed.
そのため顔料インキの特性である優れた耐水性、耐光性
等を有しているにもかかわらず、染料インキに比べて実
用性において一歩譲っているのが現状である。Therefore, despite having the excellent water resistance and light resistance that pigment inks have, they are currently inferior in practicality compared to dye inks.
本発明者らは、この様な欠点を改良し、顔料の特徴を充
分に保持したまま、筆記性に優れたボールペン用顔料イ
ンキ組成物を完成すべく鋭意研究の結果、顔料、分散剤
及び液媒体からなる顔料インキ組成物に、球状樹脂粒子
を添加することにより、部分に筆記性の改善されたボー
ルペン用顔料インキ組成物が得られることを知見して本
発明を完成した。The inventors of the present invention have conducted intensive research to improve these drawbacks and create a pigment ink composition for ballpoint pens that has excellent writing properties while fully retaining the characteristics of the pigment. The present invention was completed based on the finding that by adding spherical resin particles to a pigment ink composition consisting of a medium, a pigment ink composition for a ballpoint pen with improved writing properties can be obtained.
（問題点を解決するための手段）
すなわち、本発明は顔料、分散剤及び液媒体からなるボ
ールペン用顔料インキにおいて、更に球状樹脂粒子を含
有させたことを特徴とするボールペン用顔料インキ組成
物である。(Means for Solving the Problems) That is, the present invention provides a pigment ink composition for a ballpoint pen, which further contains spherical resin particles in a pigment ink for a ballpoint pen consisting of a pigment, a dispersant, and a liquid medium. be.
本発明の詳細な説明すると、本発明で使用する顔料は、
従来公知の有機及び無機顔料がすべて使用でき、例えば
、アゾ系、フタロシアニン系、キナクリドン系、アンス
ラキノン系、ジオキサジン系、インジゴ・チオインジゴ
系、ペリノン・ペリレン系、イソインドレノン系、アゾ
−メチンアゾ系等の有機顔料、酸化チタン、酸化鉄系、
カーボンブラック系等の無機顔料である。To explain the present invention in detail, the pigment used in the present invention is
All conventionally known organic and inorganic pigments can be used, such as azo, phthalocyanine, quinacridone, anthraquinone, dioxazine, indigo/thioindigo, perinone/perylene, isoindorenone, azo-methineazo, etc. organic pigments, titanium oxide, iron oxide,
Inorganic pigments such as carbon black.
これらの顔料は粉末状でも濾過ケーキの水性ペースト状
でも使用されるが、分散のし易さからは水性ペーストを
使用することが好ましい。These pigments can be used either in powder form or in the form of an aqueous paste such as a filter cake, but it is preferable to use an aqueous paste from the viewpoint of ease of dispersion.
ボールペン用顔料インキ組成物中の顔料の含有量はイン
キとして使用して書かれたり、記録された情報が読めた
り、認識されたりする等、記録物が部分に識別される濃
さであることが必要であり、特に規定されるものではな
いが、好ましくは組成物全量中で３〜３０重量％を占め
る量である。The pigment content in the pigment ink composition for ballpoint pens must be of such a density that recorded matter can be distinguished into parts, such as when used as an ink to read or recognize written or recorded information. Although necessary and not particularly specified, the amount preferably accounts for 3 to 30% by weight of the total composition.
特にカーボンブラック顔料は、筆記及び記録用のインキ
として最も多く使用される黒色インキに使用される顔料
であるが、この顔料は、極性が強くまた粒子が著しく細
かいため、通常は分散が困難で且つ分散安定性に劣る顔
料とされていたが、本発明において球状樹脂粒子を使用
することにより、インキ中での分散安定性が著しく向上
し、優れた筆記性をもたらすことができ、黒色の優れた
ボールペン用顔料インキ組成物を得ることができた。In particular, carbon black pigment is the pigment used in black ink, which is the most commonly used ink for writing and recording, but this pigment is usually difficult to disperse because of its strong polarity and extremely fine particles. The pigment was considered to have poor dispersion stability, but by using spherical resin particles in the present invention, the dispersion stability in the ink is significantly improved, resulting in excellent writability and excellent black color. A pigment ink composition for ballpoint pens could be obtained.
本発明のインキ組成物が水性インキである場合の分散剤
としては、従来公知の顔料の分散剤はいずれも使用でき
るが、特に好ましいものはポリマー分散剤であり、この
ようなポリマー分散剤の中では、親水性部分と親油性部
分とからなるポリマー分散剤が特に好適である、このよ
うなポリマー分散剤は、構造的には大別して縮合系重合
体及び付加重合体に分けられ、既存のものがいずれも使
用可能であり、好ましいものとして、縮合系のものにつ
いては、例えば、特開昭６０−２６０７０号公報に記載
のポリエステル系分散剤があり、また付加重合体系の分
散剤としては、α、β−エチレン性不飽和基を有する千
ツマ−の付加重合体か挙げられる。特に好ましいものは
、付加重合体系分散剤であり、これらの分散剤は親油性
部分を形成する千ツマ−と親水性部分を形成する千ツマ
−から得られる。As the dispersant when the ink composition of the present invention is an aqueous ink, any conventionally known pigment dispersant can be used, but particularly preferred are polymer dispersants, and among such polymer dispersants, Therefore, polymer dispersants consisting of a hydrophilic part and a lipophilic part are particularly suitable.Such polymer dispersants can be roughly divided into condensation polymers and addition polymers in terms of structure. Any of these can be used, and preferred condensation type dispersants include, for example, the polyester type dispersants described in JP-A-60-26070, and addition polymer type dispersants include α , addition polymers having β-ethylenically unsaturated groups. Particularly preferred are addition polymer-based dispersants, which are derived from a combination of 100% polymers forming the lipophilic portion and 100% polymers forming the hydrophilic portion.
本発明において使用する上記の如きポリマー分散剤は、
七ツマ−を適切に混合し、従来公知の混合重合方法、例
えば、溶液重合方法、懸濁重合方法、乳化重合方法等い
ずれの重合方法によっても得ることができる。必要に応
じて重合調節剤等公知の添加剤も使用される。その際に
使用される液媒体は、インキの液媒体として使用され得
る水又は有機溶剤或いはそれらの混合物であれば、その
まま得られた重合液をインキの液媒体として使用するこ
ともできるし、また重合体を溶液から分離した後再度溶
解させて使用することもできる。The polymer dispersant as described above used in the present invention is
It can be obtained by suitably mixing seven polymers and by any conventionally known mixed polymerization method, such as solution polymerization method, suspension polymerization method, emulsion polymerization method, etc. Known additives such as polymerization regulators may also be used if necessary. The liquid medium used in this case may be water, an organic solvent, or a mixture thereof that can be used as an ink liquid medium, and the polymerization liquid obtained as is may be used as an ink liquid medium. It is also possible to use the polymer by separating it from the solution and then redissolving it.
このように重合して得られるポリマー分散剤は、特にそ
の分子量によって規定されるものではないが、１，００
０〜ｉｏ０．０００の範囲の分子量を有するものが、溶
液中の重合体含有率、溶液粘度及びそれを使用したボー
ルペン用顔料インキ組成物の粘度等の性質、記録物の堅
牢性等の品質等から好ましいものである。The polymer dispersant obtained by polymerization in this way is not particularly defined by its molecular weight, but it has a molecular weight of 1,000
Those having a molecular weight in the range of 0 to io0.000 are important for properties such as the polymer content in the solution, the viscosity of the solution and the viscosity of the pigment ink composition for ballpoint pens using the same, and the quality such as the fastness of recorded materials. It is preferable because
又、本発明のインキ組成物が油性インキの場合は、ケト
ン樹脂、ポリビニルピロリドン樹脂、ヘキサトリオール
フタレート樹脂、クマロンインデン樹脂等が使用される
。Further, when the ink composition of the present invention is an oil-based ink, ketone resin, polyvinylpyrrolidone resin, hexatriol phthalate resin, coumaron indene resin, etc. are used.
本発明のボールペン用顔料インキ組成物において上記の
分散剤の使用量は、顔料の種類及びそれぞれの銘柄によ
って顔料の性質が異なるものであるため、−概に規定し
得るものではないが、顔料ｉｏｏ重量部に対し、約３〜
３００重量部、好ましくは約５〜１００重量部の割合で
ある。無機系顔料は密度も高く、粒子も比較的大きいの
で表面積は比較的小さく、従って分散剤は比較的少ない
量でよい。有機系顔料は密度は比較的低く、粒子は細か
いものが使用されることが多く、従って比較的多く使用
される。The amount of the dispersant used in the pigment ink composition for ballpoint pens of the present invention cannot be generally specified, since the properties of the pigment vary depending on the type of pigment and each brand. Approximately 3 to parts by weight
The proportion is 300 parts by weight, preferably about 5 to 100 parts by weight. Since inorganic pigments have a high density and relatively large particles, their surface area is relatively small, and therefore a relatively small amount of dispersant is required. Organic pigments have a relatively low density and are often used in fine particles, so they are used in relatively large amounts.
特に、カーボンブラック顔料は粒子が特に細かいため比
較的多量に使用することが特に好ましいものである。In particular, carbon black pigment has particularly fine particles, so it is particularly preferable to use it in a relatively large amount.
本発明で使用する球状樹脂粒子とは、インキ液媒体に不
溶性であり且つ被膜を形成せず、粒子径が０．０１〜１
．０ μｍの比較的粒子径の揃った白色、無色又は有色
の樹脂粒子であり、一般的にプラスチックピグメントと
称されている。The spherical resin particles used in the present invention are insoluble in the ink liquid medium, do not form a film, and have a particle size of 0.01 to 1.
．． They are white, colorless, or colored resin particles with a relatively uniform particle size of 0 μm, and are generally called plastic pigments.
このような樹脂粒子としては、ポリスチレン、ポリメチ
ルメタクリレート、ポリ塩化ビニル、ベンゾグアナミン
樹脂、エポキシ樹脂、或いはα。Such resin particles include polystyrene, polymethyl methacrylate, polyvinyl chloride, benzoguanamine resin, epoxy resin, or α.
β−モノエチレン性不飽和単量体をエマルジョン重合や
懸濁重合して得られるもの等が挙げられる。これらの樹
脂粒子の使用量はインキ１００重量部中で０．５〜３０
重量部、好ましくは１〜２０ｆｆｉ量部が使用される。Examples include those obtained by emulsion polymerization or suspension polymerization of β-monoethylenically unsaturated monomers. The amount of these resin particles used is 0.5 to 30 parts per 100 parts by weight of the ink.
Parts by weight are used, preferably from 1 to 20 ffi parts.
また、本発明のボールペン用顔料インキ組成物を構成す
る液媒体は、水性インキの場合は、低揮発性ないし不揮
発性の親水性有機溶媒の水溶液が使用される。例えば、
エチレングリコール、ジエチレングリコール、トリエチ
レングリコール、プロピレングリコール、ジプロピレン
グリコール、グリセリン、ジグリセリン、メチルカルピ
トール、エチルカルピトール、ブチルカルピトール等を
水１００部に対して５〜２００部の比率で混和及び溶解
した水溶液が好ましいものである。又、油性インキの場
合には、グリセリン、ベンジルアルコール、エチレング
リコール、１．２−プロピレングリコール、ブチレンゲ
リコール、ヘキシレングリコール、ジエチレングリコー
ルモノフェニルエーテル等が使用される。Further, in the case of an aqueous ink, the liquid medium constituting the pigment ink composition for a ballpoint pen of the present invention is an aqueous solution of a hydrophilic organic solvent with low volatility or non-volatility. for example,
Mix and dissolve ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, glycerin, diglycerin, methyl calpitol, ethyl calpitol, butyl calpitol, etc. in a ratio of 5 to 200 parts per 100 parts of water. An aqueous solution is preferred. In the case of oil-based ink, glycerin, benzyl alcohol, ethylene glycol, 1,2-propylene glycol, butylene gelicol, hexylene glycol, diethylene glycol monophenyl ether, etc. are used.
更に、従来公知の添加剤、保湿剤、防錆剤、防腐剤、分
散剤、耐滑剤等は必要に応じて添加される。Furthermore, conventionally known additives, humectants, rust preventives, preservatives, dispersants, anti-slip agents, etc. may be added as necessary.
本発明のボールペン用顔料インキ組成物は上記の構成成
分及び配合からなり、その製造方法は各種の方法が採用
できる。例えば、上記の各成分を配合し、これをボール
ミル、ホモミキサー、サンドグラインダー、スピードラ
インミル、ロールミル等の従来公知の分散機により混合
摩砕する方法が代表的である。The pigment ink composition for ballpoint pens of the present invention consists of the above-mentioned components and formulations, and various methods can be employed for its production. For example, a typical method is to mix and grind the above-mentioned components using a conventionally known dispersing machine such as a ball mill, homomixer, sand grinder, speed line mill, or roll mill.
上記製造方法において、球状樹脂粒子の添加方法は、顔
料分散時に添加してもよいし、顔料の分散処理後に添加
してもよく特に限定されない。In the above manufacturing method, the method of adding the spherical resin particles is not particularly limited, and may be added at the time of dispersing the pigment, or may be added after the dispersion treatment of the pigment.
（作用・効果）
本発明のボールペン用顔料インキ組成物を用いたボール
ペンは、インキ中に潤滑性に優れた球状樹脂粒子が添加
された結果、書き出し時のインキの吐出が滑らかであり
、筆記中に描線の飛等が認められず、連続筆記において
もインキの吐出量の減少等による描線のかすれや細くな
る現象も認められず、経時安定性が良好である。更に長
期間使用してもボールやその受座の摩耗が無く長期間安
定に使用することができる。(Function/Effect) A ballpoint pen using the pigment ink composition for a ballpoint pen of the present invention has spherical resin particles with excellent lubricity added to the ink, so that the ink ejects smoothly at the beginning of writing. No skipping of drawn lines was observed, and even in continuous writing, no phenomena of blurring or thinning of drawn lines due to a decrease in the amount of ink discharged were observed, and the stability over time was good. Furthermore, even after long-term use, there is no wear on the ball or its catch, and it can be used stably for a long time.
従って、従来の顔料インキの種々の欠点が解決され、本
発明の顔料インキによれば、優れた筆記性で耐光性や耐
水性等に優れた記録が実現できた。Therefore, various drawbacks of conventional pigment inks have been solved, and the pigment ink of the present invention has achieved recording with excellent writing properties and excellent light fastness, water resistance, etc.
次に参考例及び実施例を挙げて本発明を具体的に説明す
る。なお、文中、部及び％とあるのは重量を表わす。Next, the present invention will be specifically explained with reference to reference examples and examples. In addition, parts and % in the text represent weight.
参考例１
水溶性ポリマー分散剤の４０％溶液（メチルメタクリレ
ート３０部、ヒドロキシエチルメタクリレート２０ＰＩ
ｓ、ブチルアクリレート２０部、Ｎ。Reference Example 1 40% solution of water-soluble polymer dispersant (30 parts of methyl methacrylate, 20 parts of hydroxyethyl methacrylate
s, 20 parts of butyl acrylate, N.
Ｎ−ジメチルアミノエチルメタクリレート１５部及びメ
タクリル酸１５部からなるコポリマーのイソプロピルア
ルコール５０部及びブチルカルピトール５０部中の溶液
）６部に、カーボンブラック顔料１０部、水２５．０部
及びジェタノールアミン２．０部を加え、ボールミルで
約２０時間分散し、顔料濃度が１０％になる様にエチレ
ングリコール２７部及び水２９．０部を加え、更に３０
分間分散させ、黒色の顔料分散液を得た。6 parts of a solution of a copolymer of 15 parts of N-dimethylaminoethyl methacrylate and 15 parts of methacrylic acid in 50 parts of isopropyl alcohol and 50 parts of butylcarpitol, 10 parts of carbon black pigment, 25.0 parts of water and jetanolamine. Add 2.0 parts of ethylene glycol and disperse in a ball mill for about 20 hours, add 27 parts of ethylene glycol and 29.0 parts of water so that the pigment concentration is 10%, and then disperse for about 30 hours.
The mixture was dispersed for a minute to obtain a black pigment dispersion.
次に、この顔料分散液を超遠心分離機にかけ、分散不良
の粗大粒子を除き、さらに防錆剤としてベンゾトリアゾ
ールの１０％エチレングリコール溶液１．０部を添加し
、粒度の均一な黒色水性インキ組成物を得た。Next, this pigment dispersion was subjected to an ultracentrifuge to remove poorly dispersed coarse particles, and 1.0 part of a 10% ethylene glycol solution of benzotriazole was added as a rust preventive agent to create a black water-based ink with uniform particle size. A composition was obtained.
参考例２
水溶性ポリマー分散剤５０％溶液（エチルアクリレート
１２．５部、ブチルメタクリレート１５部、スチレン１
５部及びメタクリル酸７．５部からなるコポリマーのブ
チルセロソルブ３５部及びメチルカルピトール１５部中
の溶液）５部に、フタロシアニン顔料１０部、水２５．
θ部及び水酸化カリウム０．３部を加え、ペイントシェ
ーカーで２時間分散し、エチレングリコール２８部及び
水３１．７部を加え、更に３０分間分散させ、後は参考
例１と同様な処置により粒度の均一な青色水性インキ組
成物を得た。Reference Example 2 50% solution of water-soluble polymer dispersant (12.5 parts of ethyl acrylate, 15 parts of butyl methacrylate, 1 part of styrene)
5 parts of a copolymer of 5 parts of methacrylic acid and 7.5 parts of methacrylic acid in 35 parts of butyl cellosolve and 15 parts of methylcarpitol), 10 parts of phthalocyanine pigment, 25 parts of water.
Add θ parts and 0.3 parts of potassium hydroxide, disperse with a paint shaker for 2 hours, add 28 parts of ethylene glycol and 31.7 parts of water, disperse for another 30 minutes, and then perform the same procedure as in Reference Example 1. A blue water-based ink composition with uniform particle size was obtained.
参考例３
脱水とマシ油脂肪酸の高度マレイン化油（９藤製油製、
ハイマレインＤＦ−２０）及びビスフェノールＡのプロ
ピレンオキサイド付加物との縮合エステル化物（特開昭
６０−２６０７０号公報参照）６部（固形分５０％のジ
ェタノールアミン水溶液）に、ジェタノールアミン３．
３部、エチレングリコール２．０部、エチレンジアミン
四酢酸２ナトリウム塩３．０部、水２０．０部及びカー
ボンブラック顔料１０．０部を加え、ボールミルで約２
０時間分散し、顔料濃度が１０％になる様にエチレング
リコール２８．５部及び水２９．２部を加え、更に３０
分間分散させ、以下参考例１と同様な処理により、粒度
の均一な黒色水性インキ組成物を得た。Reference example 3 Highly maleated oil of dehydrated and mustard oil fatty acids (manufactured by 9 Fuji Oil Co., Ltd.,
Hymalein DF-20) and a condensation ester of bisphenol A with a propylene oxide adduct (see JP-A-60-26070) (6 parts of a jetanolamine aqueous solution with a solid content of 50%) are added with 3 parts of jetanolamine.
3 parts of ethylene glycol, 2.0 parts of ethylene glycol, 3.0 parts of ethylenediaminetetraacetic acid disodium salt, 20.0 parts of water, and 10.0 parts of carbon black pigment, and milled about 2.0 parts by ball mill.
Disperse for 0 hours, add 28.5 parts of ethylene glycol and 29.2 parts of water so that the pigment concentration is 10%, and then add 28.5 parts of ethylene glycol and 29.2 parts of water.
The mixture was dispersed for a minute, and then treated in the same manner as in Reference Example 1 to obtain a black aqueous ink composition with uniform particle size.
参考例４
スチレン無水マレイン酸コポリマーのメトキシポリエチ
レングリコール付加物６部（固形分４０％の水酸化ナト
リウム水溶液）及び不溶性アゾ顔料ペースト３６部（顔
料分９．０部）をボールミルにて６時間分散し、更にエ
チレングリコール１０．２部、ジエチレングリコール６
．３部、水４１．０部及びベンゾトリアゾールｏ、ｉ部
を添加し更に１５分間混合分散し、粗大粒子を除去する
ためカートリッジフィルターを通過させ、赤色水性イン
キ組成物を得た。Reference Example 4 6 parts of methoxypolyethylene glycol adduct of styrene maleic anhydride copolymer (aqueous sodium hydroxide solution with solid content of 40%) and 36 parts of insoluble azo pigment paste (9.0 parts of pigment) were dispersed in a ball mill for 6 hours. , further 10.2 parts of ethylene glycol, 6 parts of diethylene glycol
．． 3 parts of water, 41.0 parts of water, and o and i parts of benzotriazole were added, mixed and dispersed for further 15 minutes, and passed through a cartridge filter to remove coarse particles to obtain a red aqueous ink composition.
参考例５
下記成分をボールミルで２０時間分散処理した後、超遠
心分離機により粗大粒子を除去して黒色油性インキ組成
物を得た。Reference Example 5 After dispersing the following components in a ball mill for 20 hours, coarse particles were removed using an ultracentrifuge to obtain a black oil-based ink composition.
ベンジルアルコール ３０部エチレンゲ
ルコールフェニルエーテル３０部プロピレングリコール
５部ベンゾトリアゾール
ｏ、ｉ部ボッビニルピロリドン ５
部カーボンブラック（三菱化成工業製、ＭＡ−１ｏｏ）
１０部
ジラウリルチオプロピオネート ０．２部参考例６
下記成分をボールミルで２０時間分散処理した後、超遠
心分離機により粗大粒子を除去して青色油性インキ組成
物を得た。Benzyl alcohol 30 parts Ethylene gelcol Phenyl ether 30 parts Propylene glycol 5 parts Benzotriazole
o, part i bobbinylpyrrolidone 5
Carbon black (manufactured by Mitsubishi Chemical Industries, MA-1oo)
10 parts dilauryl thiopropionate 0.2 parts Reference Example 6 After dispersing the following components in a ball mill for 20 hours, coarse particles were removed using an ultracentrifuge to obtain a blue oil-based ink composition.
ジエチレンゲルコールモノフェニルエーテル３０部
ブチレンゲリコール ５部ケトン樹１
１ １０部フタロシアニンブルー
（大日精化工１Ｌ製フタロシアニンブルー４９３３）
１０部オレイン酸
５部ベンゾトリアゾール ０．１
部ハイドロキノン ０．１部実施例
１
参考例１で得た水性インキ組成物１００部にポリスチレ
ン系プラスチックピグメント（旭ダウ製５５０％水分散
液、粒子径０．５μｍ）１０部をかきまぜながら添加し
、本発明のボールペン用顔料インキ組成物を作製した。Diethylene gelcol monophenyl ether 30 parts Butylene gellicol 5 parts Ketone tree 1
1 10 parts Phthalocyanine Blue (Phthalocyanine Blue 4933 manufactured by Dainichisei Kako 1L)
10 parts oleic acid
5 parts benzotriazole 0.1
Part Hydroquinone 0.1 part Example 1 To 100 parts of the aqueous ink composition obtained in Reference Example 1, 10 parts of polystyrene plastic pigment (Asahi Dow 550% aqueous dispersion, particle size 0.5 μm) was added with stirring, A pigment ink composition for a ballpoint pen of the present invention was prepared.
更にこのインキを内締式のボールペンに充填し筆記性の
テストをした。その結果を第１表に示す。Furthermore, this ink was filled into an internal ballpoint pen and the writing properties were tested. The results are shown in Table 1.
実施例２
参考例２の配合中にポリメチルメタクリレート白色樹脂
粒子（綜研化学製、ＭＰ−１０００） ５部を添加し、
実施例１と同様に本発明のボールペン用顔料インキ組成
物を作製し、ボールペンでのテストを行い、その結果を
第１表に示す。Example 2 5 parts of polymethyl methacrylate white resin particles (manufactured by Soken Chemical, MP-1000) were added to the formulation of Reference Example 2,
A pigment ink composition for a ballpoint pen of the present invention was prepared in the same manner as in Example 1, and a test was conducted using a ballpoint pen. The results are shown in Table 1.
実施例３
参考例３で得た水性インキ組成物１００部にエポキシ白
色Ｓ＋脂粒子（東し製、トレパールＢＰ−８３０００、
粒子径０．５ ｐｍ、 ３０％水分散液）１８部を添加
し、実施例１と同様に本発明のボールペン用顔料インキ
組成物を作製しボールペンでのテストを行い、その結果
を第１表に示す。Example 3 100 parts of the aqueous ink composition obtained in Reference Example 3 was added with epoxy white S+ fat particles (Torepar BP-83000, manufactured by Toshi Co., Ltd.).
A pigment ink composition for a ballpoint pen of the present invention was prepared in the same manner as in Example 1 by adding 18 parts of a 30% aqueous dispersion with a particle size of 0.5 pm, and a ballpoint pen test was conducted. The results are shown in Table 1. Shown below.
実施例４
参考例４で得た水性インキ組成物１００部にポリスチレ
ン系プラスチックピグメント（旭ダウ製、５０％水分散
液、粒子径０．５μｍ）２０部を添加し、実施例１と同
様に本発明のボールペン用顔料インキ組成物を作製し、
ボールペンでのテストを行い、結果を第１表に示す。Example 4 20 parts of a polystyrene plastic pigment (manufactured by Asahi Dow, 50% aqueous dispersion, particle size 0.5 μm) was added to 100 parts of the aqueous ink composition obtained in Reference Example 4. Producing a pigment ink composition for ballpoint pens of the invention,
A ballpoint pen test was conducted and the results are shown in Table 1.
実施例５
参考例５の配合中にエポキシ白色樹脂粒子（東し製、ト
レバールＢＰ−８３０００、粒子径０．５ μｍ） ５
部を添加し、実施例１と同様な本発明のボールペン用顔
料インキ組成物を作製しボールペンでのテストを行い、
その結果を第１表に示す。Example 5 Epoxy white resin particles (manufactured by Toshi Co., Ltd., Treval BP-83000, particle size 0.5 μm) were added to the formulation of Reference Example 5.
A pigment ink composition for a ballpoint pen of the present invention similar to that in Example 1 was prepared by adding 1.5% of the pigment, and a ballpoint pen test was conducted.
The results are shown in Table 1.
実施例６
参考例６の配合中にポリスチレン系プラスチックピグメ
ント（旭ダウ製、粒子径０．５μｍ）１０部を添加し、
実施例１と同様な本発明のボールペン用顔料インキ組成
物を作製し、ボールペンでのテストを行い、結果を第１
表に示す。Example 6 10 parts of polystyrene plastic pigment (manufactured by Asahi Dow, particle size 0.5 μm) was added to the formulation of Reference Example 6,
A pigment ink composition for a ballpoint pen of the present invention similar to that in Example 1 was prepared, and a test was conducted using a ballpoint pen.
Shown in the table.
γ、 １ 〜
■ ■ 貝 ｒＶＶ
参考例１ △ × ◎ ◎ ◎２
Δ × ○ ◎ ◎３
× × Ｏ◎ ◎４ △
△ Ｏ◎ ◎５ △ Δ
Ｏ◎ ◎６ △ △ Ｏ◎
◎実施例１ ◎ Ｏ◎ ◎ ◎２
◎ Ｏ◎ ◎ ◎３ ◎
Ｏ◎ ◎ ◎４ ◎ Ｏ◎
◎ ◎５ ◎ ＯＯ〜◎ ◎
◎６ ◎ ＯＯ〜◎ ◎ ◎肘鍔
。 ｏ ｏ ｘｘ
工・・・初期書味：手で書いて調べる。γ, 1 ~ ■ ■ Shell rVV Reference example 1 △ × ◎ ◎ ◎2
Δ × ○ ◎ ◎３
× × O◎ ◎４ △
△ O◎ ◎5 △ Δ
○◎ ◎6 △ △ ○◎
◎Example 1 ◎ O◎ ◎ ◎2
◎ O◎ ◎ ◎３ ◎
O◎ ◎ ◎４ ◎ O◎
◎ ◎5 ◎ OO〜◎ ◎
◎6 ◎ OO〜◎ ◎ ◎Elbow Tsuba. o o xx Technique: Initial writing style: Examine by writing by hand.
Ｈ＝ ６００ ｍ筆記後の香味：５００部描画試験機で
筆記した後、手で書いて調べる。H = 600 m Flavor after writing: 500 copies After writing with a drawing tester, test by hand.
ｍ−・貯蔵安定性＝５０℃、３ケ月保存後取出し、その
書味を調べる。m-・Storage stability = After storage at 50°C for 3 months, take out and examine the writing quality.
■−耐光性：フェードメーター２００時間掛けて、画線
の褪色度を調べる。■-Light resistance: Check the degree of fading of the image by using a fade meter for 200 hours.
■・−耐氷性：筆記直後、水でぬらして滲みの有無を調
べる。■・-Ice resistance: Immediately after writing, wet it with water and check for bleeding.
評価基準；
◎：優秀 Ｏ：良好
Δ：可 ×：不可
以上第１表の結果より、実施例１〜６で得た本発明のボ
ールペン用顔料インキ組成物は、顔料の特性である耐水
性、耐光性を充分に満たし、しかも従来の染料タイプの
ものと同等の書味、貯蔵安定性を付与したものとなり、
ボールペン用顔料インキ組成物として極めて優れたもの
であった。Evaluation criteria: ◎: Excellent O: Good Δ: Fair ×: Not good or better From the results in Table 1, the pigment ink compositions for ballpoint pens of the present invention obtained in Examples 1 to 6 had good water resistance, which is a characteristic of pigments. It satisfies light fastness and has the same writing quality and storage stability as conventional dye-type products.
It was an extremely excellent pigment ink composition for ballpoint pens.
Claims (4)
料インキ組成物において、更に球状樹脂粒子を含有させ
たことを特徴とするボールペン用顔料インキ組成物。(1) A pigment ink composition for a ballpoint pen comprising a pigment, a dispersant, and a liquid medium, further comprising spherical resin particles.
ある特許請求の範囲第（１）項に記載のボールペン用顔
料インキ組成物。(2) The pigment ink composition for a ballpoint pen according to claim (1), wherein the spherical resin particles have a diameter of 0.01 to 1.0 μm.
第（１）項に記載のボールペン用顔料インキ組成物。(3) The pigment ink composition for a ballpoint pen according to claim (1), wherein the pigment is carbon black.
第（１）項に記載のボールペン用顔料インキ組成物。(4) The pigment ink composition for a ballpoint pen according to claim (1), wherein the dispersant is a polymer dispersant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62052108A JPS63218779A (en) | 1987-03-09 | 1987-03-09 | Pigment ink composition for ball point pen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62052108A JPS63218779A (en) | 1987-03-09 | 1987-03-09 | Pigment ink composition for ball point pen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63218779A true JPS63218779A (en) | 1988-09-12 |
Family
ID=12905666
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62052108A Pending JPS63218779A (en) | 1987-03-09 | 1987-03-09 | Pigment ink composition for ball point pen |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63218779A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05148443A (en) * | 1991-11-26 | 1993-06-15 | Mitsubishi Pencil Co Ltd | Pigment ink composition |
| US5439514A (en) * | 1993-04-01 | 1995-08-08 | Canon Kabushiki Kaisha | Ink, production thereof, and ink-jet recording method and apparatus employing the same |
| WO1997039070A1 (en) * | 1996-04-15 | 1997-10-23 | Mitsubishi Pencil Kabushiki Kaisha | Oil-base pigment ink composition for writing utensils |
| JP2002275406A (en) * | 2001-03-19 | 2002-09-25 | Mitsubishi Pencil Co Ltd | Ink composition for oil-based ball-point pen and ball- point pen |
| JP2004506808A (en) * | 2000-08-24 | 2004-03-04 | ビック コーポレイション | Solvent-based fluorescent ink for writing implements based on pigment dispersion in non-aqueous solvent |
| JP2017095582A (en) * | 2015-11-24 | 2017-06-01 | 株式会社パイロットコーポレーション | Aqueous ink composition for ball-point pen and ball-point pen including the same |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6160768A (en) * | 1984-08-31 | 1986-03-28 | Pentel Kk | Ball point pen ink |
-
1987
- 1987-03-09 JP JP62052108A patent/JPS63218779A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6160768A (en) * | 1984-08-31 | 1986-03-28 | Pentel Kk | Ball point pen ink |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05148443A (en) * | 1991-11-26 | 1993-06-15 | Mitsubishi Pencil Co Ltd | Pigment ink composition |
| US5439514A (en) * | 1993-04-01 | 1995-08-08 | Canon Kabushiki Kaisha | Ink, production thereof, and ink-jet recording method and apparatus employing the same |
| WO1997039070A1 (en) * | 1996-04-15 | 1997-10-23 | Mitsubishi Pencil Kabushiki Kaisha | Oil-base pigment ink composition for writing utensils |
| JP2004506808A (en) * | 2000-08-24 | 2004-03-04 | ビック コーポレイション | Solvent-based fluorescent ink for writing implements based on pigment dispersion in non-aqueous solvent |
| JP2002275406A (en) * | 2001-03-19 | 2002-09-25 | Mitsubishi Pencil Co Ltd | Ink composition for oil-based ball-point pen and ball- point pen |
| JP2017095582A (en) * | 2015-11-24 | 2017-06-01 | 株式会社パイロットコーポレーション | Aqueous ink composition for ball-point pen and ball-point pen including the same |
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