JPS63218613A - Temporary hair-dye composition - Google Patents
Temporary hair-dye compositionInfo
- Publication number
- JPS63218613A JPS63218613A JP5173487A JP5173487A JPS63218613A JP S63218613 A JPS63218613 A JP S63218613A JP 5173487 A JP5173487 A JP 5173487A JP 5173487 A JP5173487 A JP 5173487A JP S63218613 A JPS63218613 A JP S63218613A
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- weight
- water
- hair
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 32
- 239000001027 temporary hair color Substances 0.000 title claims description 13
- 229920000642 polymer Polymers 0.000 claims abstract description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000000178 monomer Substances 0.000 claims abstract description 28
- 239000000049 pigment Substances 0.000 claims abstract description 19
- 239000002904 solvent Substances 0.000 claims abstract description 19
- 239000002253 acid Substances 0.000 claims abstract description 14
- 230000002378 acidificating effect Effects 0.000 claims abstract description 13
- 239000000470 constituent Substances 0.000 claims abstract description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 230000001568 sexual effect Effects 0.000 claims 1
- 210000004209 hair Anatomy 0.000 abstract description 40
- 238000001035 drying Methods 0.000 abstract description 12
- 238000005406 washing Methods 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 239000003086 colorant Substances 0.000 abstract description 3
- 239000003599 detergent Substances 0.000 abstract description 3
- 239000004094 surface-active agent Substances 0.000 abstract description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract description 2
- 150000002430 hydrocarbons Chemical group 0.000 abstract description 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 29
- 239000011347 resin Substances 0.000 description 15
- 229920005989 resin Polymers 0.000 description 15
- 238000009472 formulation Methods 0.000 description 14
- 239000000243 solution Substances 0.000 description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 12
- -1 phosphooxy acrylate Chemical compound 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 9
- 150000001412 amines Chemical class 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 229910021529 ammonia Inorganic materials 0.000 description 6
- 239000006229 carbon black Substances 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 4
- 239000000443 aerosol Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 238000004043 dyeing Methods 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 230000003472 neutralizing effect Effects 0.000 description 4
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000004594 Masterbatch (MB) Substances 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002453 shampoo Substances 0.000 description 3
- 210000004243 sweat Anatomy 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 235000007716 Citrus aurantium Nutrition 0.000 description 2
- 244000183685 Citrus aurantium Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- VVNRQZDDMYBBJY-UHFFFAOYSA-M sodium 1-[(1-sulfonaphthalen-2-yl)diazenyl]naphthalen-2-olate Chemical compound [Na+].C1=CC=CC2=C(S([O-])(=O)=O)C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C21 VVNRQZDDMYBBJY-UHFFFAOYSA-M 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- KEROTHRUZYBWCY-UHFFFAOYSA-N tridecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCOC(=O)C(C)=C KEROTHRUZYBWCY-UHFFFAOYSA-N 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- XLTMWFMRJZDFFD-UHFFFAOYSA-N 1-[(2-chloro-4-nitrophenyl)diazenyl]naphthalen-2-ol Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C([N+]([O-])=O)C=C1Cl XLTMWFMRJZDFFD-UHFFFAOYSA-N 0.000 description 1
- IUVCFHHAEHNCFT-INIZCTEOSA-N 2-[(1s)-1-[4-amino-3-(3-fluoro-4-propan-2-yloxyphenyl)pyrazolo[3,4-d]pyrimidin-1-yl]ethyl]-6-fluoro-3-(3-fluorophenyl)chromen-4-one Chemical compound C1=C(F)C(OC(C)C)=CC=C1C(C1=C(N)N=CN=C11)=NN1[C@@H](C)C1=C(C=2C=C(F)C=CC=2)C(=O)C2=CC(F)=CC=C2O1 IUVCFHHAEHNCFT-INIZCTEOSA-N 0.000 description 1
- GNCOVOVCHIHPHP-UHFFFAOYSA-N 2-[[4-[4-[(1-anilino-1,3-dioxobutan-2-yl)diazenyl]-3-chlorophenyl]-2-chlorophenyl]diazenyl]-3-oxo-n-phenylbutanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C(=O)C)N=NC(C(=C1)Cl)=CC=C1C(C=C1Cl)=CC=C1N=NC(C(C)=O)C(=O)NC1=CC=CC=C1 GNCOVOVCHIHPHP-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- SFPNZPQIIAJXGL-UHFFFAOYSA-N 2-ethoxyethyl 2-methylprop-2-enoate Chemical compound CCOCCOC(=O)C(C)=C SFPNZPQIIAJXGL-UHFFFAOYSA-N 0.000 description 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 1
- UBVSIAHUTXHQTD-UHFFFAOYSA-N 2-n-(4-bromophenyl)-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(NC=2C=CC(Br)=CC=2)=N1 UBVSIAHUTXHQTD-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- FSJDKFLADYBZLE-UHFFFAOYSA-N C(C(=C)C)(=O)OOP(=O)=O Chemical compound C(C(=C)C)(=O)OOP(=O)=O FSJDKFLADYBZLE-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- AUNGANRZJHBGPY-SCRDCRAPSA-N Riboflavin Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-SCRDCRAPSA-N 0.000 description 1
- FHNINJWBTRXEBC-UHFFFAOYSA-N Sudan III Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC(C=C1)=CC=C1N=NC1=CC=CC=C1 FHNINJWBTRXEBC-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- RMKZLFMHXZAGTM-UHFFFAOYSA-N [dimethoxy(propyl)silyl]oxymethyl prop-2-enoate Chemical compound CCC[Si](OC)(OC)OCOC(=O)C=C RMKZLFMHXZAGTM-UHFFFAOYSA-N 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- DGOBMKYRQHEFGQ-UHFFFAOYSA-L acid green 5 Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C=CC(=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 DGOBMKYRQHEFGQ-UHFFFAOYSA-L 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- POJOORKDYOPQLS-UHFFFAOYSA-L barium(2+) 5-chloro-2-[(2-hydroxynaphthalen-1-yl)diazenyl]-4-methylbenzenesulfonate Chemical compound [Ba+2].C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O.C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O POJOORKDYOPQLS-UHFFFAOYSA-L 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- PVEOYINWKBTPIZ-UHFFFAOYSA-N but-3-enoic acid Chemical compound OC(=O)CC=C PVEOYINWKBTPIZ-UHFFFAOYSA-N 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- CYHOWEBNQPOWEI-UHFFFAOYSA-L calcium 3-carboxy-1-phenyldiazenylnaphthalen-2-olate Chemical compound OC=1C(=CC2=CC=CC=C2C1N=NC1=CC=CC=C1)C(=O)[O-].OC=1C(=CC2=CC=CC=C2C1N=NC1=CC=CC=C1)C(=O)[O-].[Ca+2] CYHOWEBNQPOWEI-UHFFFAOYSA-L 0.000 description 1
- QRTXZGIQTYDABO-UHFFFAOYSA-N carbanolate Chemical compound CNC(=O)OC1=CC(C)=C(C)C=C1Cl QRTXZGIQTYDABO-UHFFFAOYSA-N 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 235000021466 carotenoid Nutrition 0.000 description 1
- 150000001747 carotenoids Chemical class 0.000 description 1
- 150000005827 chlorofluoro hydrocarbons Chemical class 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 229960002380 dibutyl phthalate Drugs 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 235000012732 erythrosine Nutrition 0.000 description 1
- IPQYBTMOVNTKGM-UHFFFAOYSA-M ethenyl-dimethyl-(13-phenyltridecyl)azanium;chloride Chemical compound [Cl-].C=C[N+](C)(C)CCCCCCCCCCCCCC1=CC=CC=C1 IPQYBTMOVNTKGM-UHFFFAOYSA-M 0.000 description 1
- 125000005448 ethoxyethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- NXMXPVQZFYYPGD-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;methyl prop-2-enoate Chemical compound COC(=O)C=C.COC(=O)C(C)=C NXMXPVQZFYYPGD-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 229940105132 myristate Drugs 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- AZJPTIGZZTZIDR-UHFFFAOYSA-L rose bengal Chemical compound [K+].[K+].[O-]C(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 AZJPTIGZZTZIDR-UHFFFAOYSA-L 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical group S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、顔料を着色料として、樹脂を固層剤として使
用する毛髪用一時染毛剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a temporary hair dye composition using a pigment as a coloring agent and a resin as a solidifying agent.
本発明の組成物は毛髪に塗布する時点に於ては、含水系
の親水溶媒系とすることも可能で、塗布乾燥後は耐摩耗
性に優れ、さらに耐水性を有する樹脂を形成し、この樹
脂は水分（例えば、汗や雨など）で洗い落されることが
なく、洗い落したい時には通常の界面活性剤を含有する
洗浄剤（シャンプー〕で、洗髪することにより容易に洗
い落すことができる。The composition of the present invention can also be made into a water-containing hydrophilic solvent system at the time of application to the hair, and after application and drying, it forms a resin with excellent abrasion resistance and water resistance. The resin will not be washed off by moisture (e.g. sweat or rain), and when you want to wash it off, you can easily wash it off by washing your hair with a detergent (shampoo) containing a normal surfactant. .
従来技術
従来、顔料′ｊ＆：清色料として使用し、毛髪を一時染
毛する場合、顔料を樹脂の溶液に分散させたものを毛髪
に塗布し、乾燥させることにより顔料を毛髪に樹脂で固
着させ一時染毛する手法がとられている。Prior Art Conventionally, pigments are used as colorants to temporarily dye hair, and when the pigment is dispersed in a resin solution and applied to the hair, the pigment is fixed to the hair with the resin by drying. A method of temporarily dyeing the hair is used.
この場合、使用される樹脂としては、アニオン系のアク
リル樹脂のフルカノールアミン中和物、および両性イオ
ン系樹脂等が一般的である。In this case, the resin used is generally a flukanolamine neutralized product of an anionic acrylic resin, an amphoteric resin, or the like.
これらの樹脂を使用した一時染毛剤組成物は、耐摩耗性
が十分でない為、服や布などで強くこすられた場合、顔
料が移行し服や布をよごすという問題があつ次。Temporary hair dye compositions using these resins do not have sufficient abrasion resistance, so when they are rubbed strongly with clothes or cloth, there is a problem that the pigment transfers and stains the clothes or cloth.
また、これらの樹脂は毛髪に塗布する時点（処方時点）
と、毛髪上で乾燥した時点との間に、親水性／疎水性の
変化が殆んどない。In addition, these resins are used at the time of application to the hair (at the time of prescription).
There is almost no change in hydrophilicity/hydrophobicity between the time of drying on the hair and the time of drying on the hair.
従って、毛髪上で一時染毛剤を乾燥した時点での耐水性
を考慮した場合、処方時点でも樹脂を耐水性としておく
必要があり、含水溶媒系では樹脂が不溶であるとの問題
があった。また逆に、処方時点で、含水溶媒系ＩＩｃ樹
脂を可溶となるようにした場合、毛髪上で乾燥した時点
に於て、耐水性が不十分で、雨や汗により着色物が毛髪
より流れ落ちたり、服や布などに付着し、汚染する問題
があった。Therefore, when considering the water resistance of the temporary hair dye when it dries on the hair, the resin needs to be water resistant even at the time of formulation, and there is a problem that the resin is insoluble in water-containing solvent systems. . Conversely, if the water-containing solvent type IIc resin is made soluble at the time of formulation, the water resistance will be insufficient when it dries on the hair, and the colored material will run off from the hair due to rain or sweat. There was a problem that it could adhere to clothing, cloth, etc. and contaminate it.
更に、乾燥速度の制御、および一時染毛後の毛髪の補助
染色を目的として酸性染料等を添加する等、種々の冷加
剤を配合する場合、処方時点て於て含水溶媒系としなけ
ればならないことがあるが、従来技術では上に述べた様
に、含水溶媒系で毛髪に塗布し、毛髪上で乾燥後、耐水
性をもたせることは不可能であった。Furthermore, when adding various cooling agents, such as adding acid dyes for the purpose of controlling drying speed and auxiliary dyeing of hair after temporary hair dyeing, it is necessary to use a water-containing solvent system at the time of formulation. However, in the prior art, as mentioned above, it has been impossible to apply a water-containing solvent system to hair and provide water resistance after drying on the hair.
〔問題点を解決するための具体的な手段〕本発明者らは
、上記問題を解決する為鋭意研究を重ね念結果、酸基を
有する樹脂を使用し、必要く応じてアンモニアまたは揮
発性アミンで中和することにより、耐摩耗性に優れ、処
方時点では含水溶媒系とすることもでき、毛髪上で乾燥
後は良好な耐水性を示し、さらに洗い落したい時には、
界面活性剤を含む洗浄剤〔シャンプー〕を用いれば洗い
落すことができる一時染毛剤組成物を提供できることを
見出した。[Specific Means for Solving the Problems] In order to solve the above problems, the present inventors have conducted intensive research and have found that they use resins with acid groups and, if necessary, add ammonia or volatile amines. It has excellent abrasion resistance by neutralizing it with water, and can be made into a water-containing solvent system at the time of formulation, and shows good water resistance after drying on the hair.
It has been found that it is possible to provide a temporary hair dye composition that can be washed off by using a detergent (shampoo) containing a surfactant.
発明の構成
本発明は、
（Ａ）ポリマー構成成分として酸基を有する酸性Ｓ量体
を少なくとも５重量係含有する数平均分子量がｓ、ｏ
ｏ ｏ〜３００，０００のポリマー＝０．５〜１５重量
％
（Ｗ顔料 ：０．１〜５重１俤（転）
水および／または親水性溶媒
二８０〜９９．４重を釜
よりなる一時染毛剤組成物を提供するものである。Structure of the Invention The present invention provides (A) a polymer having a number average molecular weight of s, o containing at least 5 weight percent of an acidic S-mer having an acid group as a polymer constituent component;
o o ~ 300,000 polymer = 0.5 ~ 15% by weight (W pigment: 0.1 ~ 5 weight 1 yen (roll)
The present invention provides a temporary hair dye composition comprising 280 to 99.4 parts of water and/or a hydrophilic solvent in a kettle.
発明の詳細な説明
本発明に用いる囚成分の酸基（−ＣＯＯＨ，１７ン酸基
、硫酸基等）ポリマーは、ポリマー構成成分として、カ
ルボキシル基、リン酸基等を有する酸性単量体を少なく
とも５ｆｆｉｔ＊用い、これと他の単量体金共重せして
得られる数平均分子量が５，０００〜３００，０００の
ポリマーである。DETAILED DESCRIPTION OF THE INVENTION The acidic group (-COOH, 17-acid group, sulfuric acid group, etc.) polymer used in the present invention as a carrier component contains at least an acidic monomer having a carboxyl group, a phosphoric acid group, etc. as a polymer component. This is a polymer having a number average molecular weight of 5,000 to 300,000 obtained by using 5ffit* and copolymerizing it with other gold monomers.
酸性単量体としては、酸性基を有するエチレン性不飽和
単を億で具体例を挙げれば、たとえばメタクリル酸、ア
クリル酸、マレイン酸、イタコン酸、７マル酸、ビニル
酢酸、クロトン酸、アシッドホスホオキシエチルメタク
リレート、アシッドホスホオキシアクリレート、アシッ
ドホスホオキシメタクリレート、又はこれらの酸無水物
等があり、それぞれ一種または二種以上を選択して用い
ることができる。Specific examples of acidic monomers include ethylenically unsaturated monomers having an acidic group, such as methacrylic acid, acrylic acid, maleic acid, itaconic acid, hexamaric acid, vinyl acetic acid, crotonic acid, and acid phosphoric acid. Examples include oxyethyl methacrylate, acid phosphooxy acrylate, acid phosphooxy methacrylate, and acid anhydrides thereof, and one or more of these can be selected and used.
これら酸性単量体は、ポリマー成分中の５〜６０！童係
の割合で好ましく用いられる。These acidic monomers are present in 5 to 60% of the polymer components. Preferably used in the proportion of children's attendants.
この酸性単量体と共重合させる単量体としては、共冨合
可能なエチレン性不飽和単量体であれば任意に選択でき
、具体例を挙げれば、たとえばメチルメタクリレートメ
チルアクリレート（以下メチル（メタ）アクリレートと
略す。）、エテル°（メタ）アクリレート、インブチル
（メタ）アクリレート、１ シクロヘキシル（メタ）ア
クリレート、ラウリル（メタ〕アクリレート、オレイル
（メタ）アクリレート、ステアリル（メタ）アクリレー
ト、スチレン、ビニルトルエン、アクリロニトリル、（
メタ）アクリロキシプロピルトリメトキシシラン、ヒド
ロキシプロピル（メタ）アクリレート、ポリプロピレン
グリコール（メタ）アクリレート、ジメチルアミノエチ
ル（メタノアクリレート、エトキシエチル（メタ）アク
リレート、ダイア七トン（メタ）アクリルアミド等があ
り、さらに必要に応じてＮ−（メタ）アクリロイル−Ｎ
、Ｎ、Ｎ−）リメチルアンモニウムクロライド、Ｎ−（
メタ）アクリロイルプロピル−Ｎ、Ｎ−ジメチルＮ−ベ
ンジルアンモニウムクロ２イド、Ｎ−ビニルベンジル−
Ｎ、Ｎ−ジメチル−Ｎ−ラウリルアンモニウムクロライ
ド、Ｎ−（メタ）アクリロイルエチル−Ｎ。The monomer to be copolymerized with this acidic monomer can be arbitrarily selected as long as it is an ethylenically unsaturated monomer that can be copolymerized. Specific examples include methyl methacrylate methyl acrylate (hereinafter referred to as methyl ), ether (meth)acrylate, inbutyl (meth)acrylate, 1 cyclohexyl (meth)acrylate, lauryl (meth)acrylate, oleyl (meth)acrylate, stearyl (meth)acrylate, styrene, vinyltoluene , acrylonitrile, (
meth)acryloxypropyltrimethoxysilane, hydroxypropyl (meth)acrylate, polypropylene glycol (meth)acrylate, dimethylaminoethyl (meth)acrylate, ethoxyethyl (meth)acrylate, diaseptone (meth)acrylamide, etc., and more are required. Depending on N-(meth)acryloyl-N
, N, N-)limethylammonium chloride, N-(
meth)acryloylpropyl-N, N-dimethyl N-benzylammonium chloride, N-vinylbenzyl-
N,N-dimethyl-N-lauryl ammonium chloride, N-(meth)acryloylethyl-N.
Ｎ−ジメチルアンモニウム−Ｎ−メチルカルボキシベタ
イン、ポリエチレングリコール（メタ）アクリレート、
Ｎ−ビニルピロリドン等の親水性単量体（親水性単量体
とは、単量体単独重合体ｌＯ？ｆ９０ｔの水に溶かした
時に、完全溶解するものをいう。）を塗布乾燥後の耐水
性を低下させない範囲で使用することができる。N-dimethylammonium-N-methylcarboxybetaine, polyethylene glycol (meth)acrylate,
Water resistance after coating with a hydrophilic monomer such as N-vinylpyrrolidone (a hydrophilic monomer is one that completely dissolves when the monomer homopolymer lO?f90t is dissolved in water). It can be used as long as it does not reduce its properties.
酸性単量体の使用量は、全単量体に対して少なくとも５
重量％以上、好ましくは１０〜６０重量係であシ、それ
ぞれ一種または二種以上選択して用いることができるが
、５重量係未満では、洗髪時の除去が不可能であり、含
水溶媒系とすることができない。また６０ｉｉ４’ｉ越
えると、塗布乾燥後の耐水性が不十分である。The amount of acidic monomer used is at least 5% based on the total monomers.
If the proportion is more than 5% by weight, preferably 10 to 60% by weight, one or more types can be selected and used, but if the proportion is less than 5% by weight, it will be impossible to remove when washing the hair, and it will not be possible to use a water-containing solvent system. Can not do it. If it exceeds 60ii4'i, the water resistance after coating and drying will be insufficient.
その他の共重合可能なエチレン性不飽和単量体の使用量
は、全単量体に対して５〜９５重量僑であ夛、それぞれ
−撞または二種以上を選択して用いることができるが、
９５重量％を越えては、処方時点で含水溶媒系とするこ
とが出来す、また洗髪時の樹脂の除去が困難となる。The amount of other copolymerizable ethylenically unsaturated monomers to be used is 5 to 95% by weight based on the total monomers, and each or two or more types can be selected and used. ,
If it exceeds 95% by weight, a water-containing solvent system may be formed at the time of formulation, and removal of the resin during hair washing becomes difficult.
上記単量体は、公知の溶液重合、塊状重合、または懸濁
重合等により重合させて（Ａ）成分のポリマーを得るこ
とができる。The above monomers can be polymerized by known solution polymerization, bulk polymerization, suspension polymerization, etc. to obtain the polymer of component (A).
好ましくは、（Ａ）成分のポリマーは、次の（ａ）〜（
Ｃ）のビニル単量体を共重合させて得られるものである
。Preferably, the polymer of component (A) comprises the following (a) to (
It is obtained by copolymerizing the vinyl monomer of C).
（ａ）不飽和カルボン酸 ５〜６０重量係（ｂ）
次式で示されるアクリレート
４０〜９５重量係
Ｈ２Ｃ＝Ｃ−Ｃ０ＯＲ” ・
（Ｃ）上記（ａ）、Φ）以外の重合性単量体０〜３０重
量優
重量中、Ｒ１はＨまたＦｉｃＨｌであシ；Ｒ″は炭素数
１〜２２の飽和もしくは不飽和の炭化水素基を示す。〕
この（Ａ）成分のポリマーの酸基をアンモニアまたは揮
発性アミンにより中和し、耐水性と洗髪性を向上させる
ことができる。(a) Unsaturated carboxylic acid 5-60 weight ratio (b)
Acrylate represented by the following formula with a weight ratio of 40 to 95 H2C=C-C0OR" (C) Among 0 to 30 polymerizable monomers other than (a) and Φ) above, R1 is H or FicHl. R'' represents a saturated or unsaturated hydrocarbon group having 1 to 22 carbon atoms. ] The acid groups of the polymer of component (A) can be neutralized with ammonia or volatile amine to improve water resistance and hair washability.
かかる中和剤として用いる揮発性アミンとは、常圧に於
ける沸点が１３０℃以下のものがよく、具体例を挙げれ
ば、例えば、アンモニア、メチルアミン、ジメチルアミ
ン、トリメチルアミン、エテルアミン、ジエチルアミン
、トリエチルアミン、ｎ−プロピルアミン、ｎ−ブチル
アミン、アリルアミン、エチレンジアミン、モルホリン
、ピリジン等があり、それぞれ−棟または二種以上を選
択して用することかできる。また、これらは水溶液の形
態で用いてもよい。The volatile amine used as such a neutralizing agent preferably has a boiling point of 130°C or lower at normal pressure, and specific examples include ammonia, methylamine, dimethylamine, trimethylamine, etheramine, diethylamine, and triethylamine. , n-propylamine, n-butylamine, allylamine, ethylenediamine, morpholine, pyridine, etc., and each type or two or more types can be selected and used. Moreover, these may be used in the form of an aqueous solution.
このアンモニアまたは揮発性アミンの使用量は、親水溶
媒系で使用する場合は使用しなくても可能であるが、含
水溶媒系で使用する場合は、■成分のポリマーを構成す
る酸性単量体の酸基を中和するに必要な量の１０〜２０
０モル％までの範囲であり、２００モル％を越えると乾
燥時点におけるポリマー（樹脂）フィルムの耐水性が十
分発揮さｆｉない。When using a hydrophilic solvent system, it is possible to use no ammonia or volatile amine, but when using a water-containing solvent system, 10 to 20 of the amount necessary to neutralize acid groups
The range is up to 0 mol %, and if it exceeds 200 mol %, the polymer (resin) film will not exhibit sufficient water resistance at the time of drying.
アンモニアまた＃ｉ揮発性アミンによる中和は、酸性単
量体を予め中和した後、単量体の共重合を行なっても良
いし、酸性基を含む共重合ポリマーを中和しても良いし
、酸基を含む共重合ポリマー、顔料、水および／または
親水性溶媒を混合後中和を行なっても良い。Neutralization with ammonia or #i volatile amine may be performed by neutralizing the acidic monomer in advance and then copolymerizing the monomer, or by neutralizing the copolymer containing acidic groups. However, neutralization may be performed after mixing the copolymer containing acid groups, the pigment, water and/or the hydrophilic solvent.
非揮発性アミン、たとえばエタノールアミン、ジェタノ
ールアミン、トリエタノールアミン、２−アミノ−２−
メチル−１−グロバノール、２−アミノ−２−エチル−
１，３−プロパンジオール等でポリマーの酸基を部分中
和することは可能であるが、共重合可能な親水性単量体
と同様、塗布乾燥後の耐水性を低下させない範囲で使用
することができる。Non-volatile amines such as ethanolamine, jetanolamine, triethanolamine, 2-amino-2-
Methyl-1-globanol, 2-amino-2-ethyl-
It is possible to partially neutralize the acid groups of the polymer with 1,3-propanediol, etc., but as with copolymerizable hydrophilic monomers, use within the range that does not reduce the water resistance after coating and drying. Can be done.
本発明に用−る（匂成分の顔料は具体例をあげれば、カ
ーボンブラック、タルク、カオリン、マイカ、酸化チタ
ン、等の無機顔料、赤色２０２号、赤色２０４号、赤色
２０５号、赤色２０６号、赤色２１９号、赤色２２８号
、黄色２０５号、赤色４０４号、だｂだい４０１号、黄
色４０１号、青色４０４号等の有機顔料等があり、一種
または二株以上を選択して用いることができる。Specific examples of the pigments used in the present invention (smell component) include inorganic pigments such as carbon black, talc, kaolin, mica, titanium oxide, Red No. 202, Red No. 204, Red No. 205, and Red No. 206. , Red No. 219, Red No. 228, Yellow No. 205, Red No. 404, Dab Dai No. 401, Yellow No. 401, Blue No. 404, etc., and one or more of them can be selected and used. can.
この顔料の使用量は一時染毛剤組成物中の０．１〜５ｍ
！１％好ましくは０．５〜３重量ｓｒ、０．１重量傷未
満では、毛髪を一時染毛することができなくなり、５重
量ｔｌＩを越えると毛髪上での光沢がなくなシ、手で触
れた時の異和感が大で、顔料が毛髪より脱離しやすくな
る。The amount of this pigment used is 0.1 to 5 m in the temporary hair dye composition.
! 1% preferably 0.5 to 3 weight sr, less than 0.1 weight sr, hair cannot be temporarily dyed, and more than 5 weight tlI, the hair loses its luster and cannot be touched by hand. It gives a very strange feeling when it is applied, and the pigment comes off more easily than the hair.
本発明で使用する（Ｃ）成分の親水性溶媒は、水に対す
る溶解度が（１０ｆ ／ １００ を水／２５℃〕以上
である有機溶媒を意味し、具体例をあげれば例えば、メ
タノール、エタノール、イングロバノール、エチレング
リコール、エチルセロソルブ、ジオキサン、酢酸メチル
等である。The hydrophilic solvent of component (C) used in the present invention means an organic solvent having a solubility in water of (10f/100 in water/25°C) or more, and specific examples include methanol, ethanol, and inglobin. Banol, ethylene glycol, ethyl cellosolve, dioxane, methyl acetate, etc.
０成分の溶媒は、親水性溶媒の一種または二種以上を選
択して用いることができ、さらに必要に厄じて水と混合
して使用することが可能である。As the solvent of component 0, one or more hydrophilic solvents can be selected and used, and if necessary, it can be used in combination with water.
本発明の組成物には、一時染毛剤組成物を塗布した時点
で毛髪を染色しておき、一時染毛剤を洗浄除去した後で
も毛髪が染色されている状態とする為に、必要に応じて
赤色３号、赤色１０４号、赤色１０５号、黄色４号、黄
色５号、緑色３号、青色１号、青色２号、赤色２０１号
、赤色２２５号、だいだい２０７号、黄色２０２号、緑
色２０５号、青色２０３号、赤色５０２号、だいだい４
０２号、黒色４０１号等の酸性染料を添加することが可
能である。The composition of the present invention has the necessary ingredients to dye the hair at the time the temporary hair dye composition is applied and to keep the hair dyed even after the temporary hair dye is washed away. Red No. 3, Red No. 104, Red No. 105, Yellow No. 4, Yellow No. 5, Green No. 3, Blue No. 1, Blue No. 2, Red No. 201, Red No. 225, Daidai No. 207, Yellow No. 202, Green No. 205, Blue No. 203, Red No. 502, Daidai 4
It is possible to add acidic dyes such as No. 02 and Black No. 401.
さらに必要に応じて、カロチノイド系色素、フラビン系
色素、キノン系色素等の天然系色素、２ノリン、２ノリ
ン誘導体、グリセリン、グリセリン誘導体、イングロビ
ルミリステート、オレイルアルコール、ジブチルフタレ
ート、ジメチルポリシロキサン、シリコーン類およびバ
ントテニルアルコール等の軟化剤、潤滑剤及び、香料そ
の他の添加剤を添加することができる。Furthermore, if necessary, natural pigments such as carotenoid pigments, flavin pigments, and quinone pigments, 2-noline, 2-noline derivatives, glycerin, glycerin derivatives, inglobil myristate, oleyl alcohol, dibutyl phthalate, dimethylpolysiloxane, Softeners such as silicones and vanthothenyl alcohol, lubricants, fragrances and other additives can be added.
さらに、アルミ箔又はこれを着色及び／又はエポキシ樹
脂、アクリル樹脂等で被覆したものを細かく切断したも
の、ポリエステルフィルム、ポリプロピレンフィルム等
の樹脂フィルムにアルミ蒸着したもの又はこれらを着色
及び／又はエポキシ樹脂、アクリル樹脂等で被覆積層し
たものを細かく切断し念もの、アルミ粉末或いは寓母片
にアルミ、酸化チタン、酸化鉄等の金属類を蒸着したも
の等の光輝性を有する物質を添加することが出来る。Furthermore, finely cut aluminum foil or colored and/or coated with epoxy resin, acrylic resin, etc., aluminum vapor-deposited on resin film such as polyester film or polypropylene film, or colored and/or epoxy resin coated with aluminum foil, etc. It is possible to add glittering substances such as aluminum, titanium oxide, iron oxide, and other metals deposited on aluminum powder or aluminum oxide by cutting the laminated layer coated with acrylic resin into small pieces. I can do it.
本発明の一時染毛剤組成物全使用する形態としては、ク
ロロフルオロ炭化水素、プロパン、ブタン、窒素、二酸
化炭素等の公知の噴射剤を添加して使用する加圧エアゾ
ール、ポンプスプレー、または溶液を刷毛塗布する方式
等の方法があシ、公知の技術により各形態として使用す
ることができる。The temporary hair dye composition of the present invention can be used in any form such as pressurized aerosol, pump spray, or solution using a known propellant such as chlorofluorohydrocarbon, propane, butane, nitrogen, or carbon dioxide. There are various methods, such as brush application, and it can be used in various forms using known techniques.
本発明の一時染毛剤組成物を使用する場合、ポリマー、
顔料、水および／または親水性溶媒を予めマスターバッ
チとして高濃度で準備し、必要に厄じ使用形態まで、ア
ンモニアまたは揮発性アミンを添加後、水および／また
は親水性溶媒、および噴射剤で希釈するか、使用形態の
配合比に配合し、使用形態に供しても良い。いずれの場
合も、これらの混合は通常の攪拌によるか、必要に応じ
て、ホモジナイザー、ボールミル、サンドミル、ロール
ミル、ディスパーミル等で粉砕混合してもよい。When using the temporary hair dye composition of the present invention, polymers,
Pigments, water and/or hydrophilic solvents are prepared in advance as a masterbatch at high concentrations and diluted with water and/or hydrophilic solvents and propellant after addition of ammonia or volatile amines to the required usage form. Alternatively, it may be blended in the mixing ratio of the usage form and provided for the usage form. In either case, these may be mixed by normal stirring or, if necessary, by pulverization using a homogenizer, ball mill, sand mill, roll mill, disper mill, or the like.
本発明の一時染毛剤組成物は、毛髪の一時染毛の為にｍ
−るが、その他窓ガラス、衣類、家具等の装飾用などに
用いることができる。The temporary hair dye composition of the present invention can be used for temporary hair dyeing.
However, it can also be used to decorate window glass, clothing, furniture, etc.
実験例
以下の例中に用いる部および係はそれぞれ重量基準であ
る。EXPERIMENTAL EXAMPLES All parts and units used in the following examples are by weight.
メチルメタクリレート １０部ブチル
メタクリレート ２０部トリデシルメ
タクリレート ２０部ブチルアクリレート
２０部ダイア七トンアクリルアミ
ド ５部メタクリル酸
２０部アクリル酸
５部エタノール ８０部過
酸化ベンゾイル １部上記の試料
を攪拌器、還流冷却器、温度計および窒素導入管を付設
した四つロフラスコ内に入れ、窒素気流下８０℃で６時
間共重合を行わせ念。Methyl methacrylate 10 parts Butyl methacrylate 20 parts Tridecyl methacrylate 20 parts Butyl acrylate 20 parts Diaseptone acrylamide 5 parts Methacrylic acid
20 parts acrylic acid
5 parts ethanol 80 parts benzoyl peroxide 1 part The above sample was placed in a four-loaf flask equipped with a stirrer, reflux condenser, thermometer and nitrogen inlet tube, and copolymerization was carried out at 80°C for 6 hours under a nitrogen stream. Just in case.
次いで、冷却後、エタノールを加え共重合ポリマー含：
１３０重量％の「ポリマーＡ溶液」を得た。Next, after cooling, ethanol was added to contain the copolymer:
A 130% by weight "Polymer A solution" was obtained.
このポリマーの数平均分子量は、ＧＰＣで測定した結果
、９８，０００であった。The number average molecular weight of this polymer was 98,000 as measured by GPC.
ポリマーＢ製造例
エチルメタクリレート １０部ブチル
メタクリレート ３５部２ウリルメタ
クリレート ２０部２−エチルへキシル
アクリレート １５部メタクリル酸
１０部イタコン酸
１０部インプロパツール １５０部
アゾビスイソブチロニトリル １部上記の試
料をポリマーＡの製造例と同様に共重合させ念。Polymer B Production Example Ethyl methacrylate 10 parts Butyl methacrylate 35 parts 2-uryl methacrylate 20 parts 2-ethylhexyl acrylate 15 parts Methacrylic acid
10 parts itaconic acid
10 parts Improper tool 150 parts Azobisisobutyronitrile 1 part The above sample was copolymerized in the same manner as in the production example of Polymer A.
冷却後イングロパノールを加え、共重合ポリマー含［３
（ｌの「ポリマーＢ溶液」を得た。このポリマーの数平
均分子量は、ＧＰＣで測定したところ、２５，０００で
あった。After cooling, ingropanol was added and the copolymer-containing [3
A "polymer B solution" of 1 was obtained. The number average molecular weight of this polymer was measured by GPC and was 25,000.
ポリマーＣの製造例
エチルメタクリレート ２０部ラウリ
ルメタクリレート ３０部エトキシエチ
ルメタクリレート ２０部ラウリルアクリレー
ト １５部Ｎ−ビニルピロリドン
５都メタクリル酸
１０部エタノール
７０部過酸化ベンゾイル ０．２
部上記の試料を攪拌器、還流冷却器、温度計、窒素導入
管および滴下ロートを付設した四つロフラスコ内に入れ
、窒素気流下８０℃で１時間加熱し、引きつづき過酸化
ラウロイル０．４部をエタノール３０部に溶かした溶液
を３時間かけて、８０℃に保ったフラスコに滴下し、さ
らに８０℃で３ｆｌ？？間保って共重合を行なわせた。Production example of polymer C Ethyl methacrylate 20 parts Lauryl methacrylate 30 parts Ethoxyethyl methacrylate 20 parts Lauryl acrylate 15 parts N-vinylpyrrolidone
5 cities methacrylic acid
10 parts ethanol
70 parts Benzoyl peroxide 0.2
The above sample was placed in a four-hole flask equipped with a stirrer, reflux condenser, thermometer, nitrogen inlet tube, and dropping funnel, heated at 80°C for 1 hour under a nitrogen stream, and then heated with 0.4 lauroyl peroxide. A solution of 30 parts of ethanol dissolved in 30 parts of ethanol was added dropwise over 3 hours to a flask kept at 80°C, and then 3 fl? ? Copolymerization was carried out at intervals.
次いで、冷却後エタノールを加え、共重合ポリマー含！
３０重量傷の「ポリマーＣ溶液」を得た。Next, after cooling, ethanol is added to contain the copolymer!
A "polymer C solution" with a 30 weight scratch was obtained.
このポリマーの数平均分子量は、ＧＰＣで測定したとこ
ろ１３５，０００であった。The number average molecular weight of this polymer was determined by GPC to be 135,000.
ポリマーＤの製造例
メチルメタクリレート ２０部イソブ
チルメタクリレート ４２部トリデシルメ
タクリレート ２０部２−エチルへキシル
アクリレート １５部メタクリル酸
３部エタノール
８０部アゾビスイソブチロニトリル １
部上記試料を「ポリマーＡ製造例」と同様に共重合し、
冷却後エタノールを加え、共重合ポリマー含量３０％の
「ポリマーＤ溶液」を得た。このポリマーの数平均分子
量は、ＧＰＣで測定し念ところ、８５，０００であった
。Production example of Polymer D Methyl methacrylate 20 parts Isobutyl methacrylate 42 parts Tridecyl methacrylate 20 parts 2-ethylhexyl acrylate 15 parts Methacrylic acid
3 parts ethanol
80 parts azobisisobutyronitrile 1
Part The above sample was copolymerized in the same manner as in "Polymer A Production Example",
After cooling, ethanol was added to obtain a "Polymer D solution" having a copolymer content of 30%. The number average molecular weight of this polymer was determined to be 85,000 as determined by GPC.
実施例１、比較例１
ポリマー溶液Ａ４０部、カーボンブラック１０部、エタ
ノール５０ｓを常法に従って３０分間循環混合処理し、
マスターパッチを得た。Example 1, Comparative Example 1 40 parts of polymer solution A, 10 parts of carbon black, and 50 seconds of ethanol were circulated and mixed for 30 minutes according to a conventional method,
Obtained master patch.
このマスターパッチを使用し、表１に記載した配付割合
で、エアゾールを作成した。評価方法は次のとおりであ
り、谷配せ例での計画結果を表１に示した。Using this master patch, aerosols were prepared at the distribution ratios listed in Table 1. The evaluation method was as follows, and the planning results for the valley layout example are shown in Table 1.
く評価方法〉
ｌ）耐水性
ガラス板上にエアゾール内液を、約１５備の距離より約
３秒間霧状に噴出させた。ついで、ヘヤードライヤーを
使用し約１分間乾燥させた後、２３℃、６０％ＲＨΩ恒
温恒室内に一昼夜放置した。Evaluation method> l) The aerosol liquid was sprayed in the form of a mist for about 3 seconds onto a water-resistant glass plate from a distance of about 15 mm. Then, after drying for about 1 minute using a hair dryer, it was left in a constant temperature room at 23° C. and 60% RHΩ all day and night.
次に同じ恒温恒湿室内でガラス板上に２３℃の純水全落
し、５分後に指で軽くこすシ、フィルムの溶解有無を確
認した。Next, in the same constant temperature and humidity room, pure water at 23°C was poured onto a glass plate, and after 5 minutes, the glass plate was rubbed lightly with a finger to check whether the film had dissolved or not.
○：フイルム溶膚せず
Ｘ：フィルム溶解開始または完全溶解
２）洗浄性
ポリオキシエチレン（付加モル数約３モル）ラウリルエ
ーテル硫酸ナトリウム（商品名・エマール２０ ：花王
）の有効取分２係水溶液を用意した。次に、この水溶液
を４０℃に保ち、ｌ）耐水性評価と同様に作成し次ガラ
ス板金約１０分間浸漬後、軽くこすシフイルムの溶解の
有無を確認した。○: Film does not melt. prepared. Next, this aqueous solution was maintained at 40° C., and a glass sheet metal prepared in the same manner as in 1) Evaluation of Water Resistance was immersed for about 10 minutes, and then lightly rubbed to check for dissolution of the film.
○：フイルムが完全に溶解した。または溶解全開始した
。○: The film was completely dissolved. Or the whole melt started.
×：フィルムは溶解せず。×: The film did not dissolve.
３）耐摩耗性
重量１９．長さ２０百の毛束−６ａ ｏ ｒｐｍ で
回転させながら、１５ｃ！Ｒの距離より約５秒間スプレ
ーシ、毛髪全体を指でならした。3) Wear resistance weight 19. A bundle of hair 2000 long long - 15c while rotating at 6a o rpm! Spray from distance R for about 5 seconds and smooth the entire hair with your fingers.
その後、ヘヤードライヤーを使用し約１分間乾燥させた
後、２３℃、６０％ＲＨの恒温恒湿室に一昼夜放置し友
。After that, I used a hair dryer to dry it for about 1 minute, and then left it in a constant temperature and humidity room at 23°C and 60% RH all day and night.
次に、この毛髪に木綿の布をこすりつけ、布に付着し念
顔料の量を目視九よｐ判断した。Next, a cotton cloth was rubbed on the hair, and the amount of pigment attached to the cloth was visually judged.
○：転看なし、またはほとんどなし。○: No or almost no change of care.
×：転着量大。×: Large amount of transfer.
（以下余白）
表２
実施例２、比較例２
ポリマー溶液８ ４０部カーボンブ
ラック １部黒色４０１号
１部エタノール
１０部イオン交換水 ４６
．５部アンモニア水（２８憾）１．５部
ポリマー溶液Ｄ ４０部カーボン
ブラック １部黒色４０１号
１部エタノール
１部部イオン変換水 ４７
．７部アンモニア水（２８優）ｏ、３部
配合例３（比較例）
ポリマー溶液Ｄ ４０部カーボン
ブラック １部黒色４０１号
１部エタノール
５７．６部２−アミノ２−メチルｌ−プロパノ
ール０．４部
上記の各配合物全ディスパーミルで各１時間処理し、混
合分散液とした。「配合例２Ｊはポリマーが析出し液状
態が不良であった。(Margin below) Table 2 Example 2, Comparative Example 2 Polymer solution 8 40 parts Carbon black 1 part Black No. 401
1 part ethanol
10 parts ion exchange water 46
．． 5 parts Ammonia water (28 ml) 1.5 parts Polymer solution D 40 parts Carbon black 1 part Black No. 401
1 part ethanol
1 part ionized water 47
．． 7 parts Ammonia water (28%) o, 3 parts Blend example 3 (comparative example) Polymer solution D 40 parts Carbon black 1 part Black No. 401
1 part ethanol
57.6 parts 2-amino 2-methyl l-propanol 0.4 parts Each of the above formulations was treated in a Dispermill for 1 hour each to form a mixed dispersion. “In Formulation Example 2J, the polymer precipitated and the liquid condition was poor.
液状態が良好であった「配合例１」および「配合例３」
の分散液に、漂白した毛髪を浸は引き出した後、過剰の
液を指でしぼシヘヤードライヤーで約１分間乾燥させた
。“Formulation Example 1” and “Formulation Example 3” with good liquid condition
After dipping the bleached hair into the dispersion and pulling it out, the excess solution was squeezed with fingers and dried with a hair dryer for about 1 minute.
得られ九毛髪は、両者とも黒色の外観を呈してＩＡ比。Both of the nine hairs obtained had a black appearance and had an IA ratio.
これらの毛髪をそれぞれ、シャンプーで良く洗浄し、水
ですすぎ風乾して得られた毛髪の染毛状態を観察したと
ころ「配合例１」で処理し九毛髪は黒色に染毛されて込
たが、「配合例３」で処理し六毛髪は染毛されていなか
った。Each of these hairs was thoroughly washed with shampoo, rinsed with water, and air-dried to observe the dyed state of the hair. Nine hairs treated with "Formulation Example 1" were dyed black. , six hairs treated with "Formulation Example 3" were not dyed.
なお、配合例１の染毛剤で処理された毛髪は、２０℃で
は汗や雨では染料はにじみでることなく、衣服を汚すこ
とはなかった。In addition, in the hair treated with the hair dye of Formulation Example 1, the dye did not bleed through sweat or rain at 20° C., and did not stain clothes.
実施例３
ポリマー溶液０ ４０部カーボンブ
ラック １部赤色４０４号
７部赤色２０５号
３部エタノール ５０
部全常法に従って３０分間循環処処理台し、マスターバ
ッチ金得た。Example 3 Polymer solution 0 40 parts Carbon black 1 part Red No. 404
7th part red No. 205
3 parts ethanol 50
The mixture was subjected to circulation treatment for 30 minutes according to a conventional method to obtain a masterbatch.
このマスターバッチを使用し、く表２〉中の実施例４中
の配合例Ａ１および配合例４３（ただしアンモニア水（
２８％）の使用ｉ１：ｏ、ｚ部）と同様に配合して得ら
れ九エアゾールを、実施例１の評価方法に準じて評価を
行なったところ、両者とも良好な耐水性、洗浄性、耐摩
耗性を示した。Using this masterbatch, Formulation Example A1 and Formulation Example 43 in Example 4 in Table 2 (with the exception of ammonia water)
When 9 aerosols obtained by blending in the same manner as i1:o, z parts) were evaluated according to the evaluation method of Example 1, both had good water resistance, washability, and resistance. It showed abrasive properties.
Claims (1)
単量体を少なくとも５重量％含有する数平均分子量が５
，０００〜３００，０００のポリマー ０．５〜１５重
量％ （Ｂ）顔料 ０．１〜５重量％ （Ｃ）水および／または親水性溶媒 ８０〜９９．４重
量％ 上記（Ａ）、（Ｂ）および（Ｃ）成分を含有する一時染
毛剤組成物。 ２）、（Ａ）成分のポリマーが、次の（ａ）〜（ｃ）の
ビニル単量体を共重合させて得られるものであることを
特徴とする特許請求の範囲第１項記載の組成物。 （ａ）不飽和カルボン酸 ５〜６０重量％ （ｂ）次式で示されるアクリレート ４０〜９５重量％ ▲数式、化学式、表等があります▼ （ｃ）上記（ａ）、（ｂ）以外の重合性単量体 ０〜３
０重量％ 〔式中、Ｒ＾１またはＣＨ＿３であり；Ｒ＾２は炭素数
１〜２２の飽和もしくは不飽和の炭化水素基を示す。〕[Claims] 1), (A) A polymer having a number average molecular weight of 5 and containing at least 5% by weight of an acidic monomer having an acid group as a polymer constituent component.
,000-300,000 polymer 0.5-15% by weight (B) Pigment 0.1-5% by weight (C) Water and/or hydrophilic solvent 80-99.4% by weight Above (A), (B) ) and (C) A temporary hair dye composition containing components. 2) The composition according to claim 1, wherein the polymer of component (A) is obtained by copolymerizing the following vinyl monomers (a) to (c). thing. (a) Unsaturated carboxylic acid 5-60% by weight (b) Acrylate represented by the following formula 40-95% by weight ▲ Numerical formulas, chemical formulas, tables, etc. are available ▼ (c) Polymerization other than (a) and (b) above Sexual monomer 0-3
0% by weight [In the formula, R^1 or CH_3; R^2 represents a saturated or unsaturated hydrocarbon group having 1 to 22 carbon atoms. ]
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5173487A JPS63218613A (en) | 1987-03-06 | 1987-03-06 | Temporary hair-dye composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5173487A JPS63218613A (en) | 1987-03-06 | 1987-03-06 | Temporary hair-dye composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63218613A true JPS63218613A (en) | 1988-09-12 |
Family
ID=12895125
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5173487A Pending JPS63218613A (en) | 1987-03-06 | 1987-03-06 | Temporary hair-dye composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63218613A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2709418A1 (en) * | 1993-09-01 | 1995-03-10 | Mitsubishi Pencil Co | Hair dye |
| JP3012332B2 (en) * | 1993-05-07 | 2000-02-21 | ロレアル | Use of terpolymers derived from vinyl lactams as blowing agents in aerosol mousse-forming compositions, and compositions obtained thereby |
| US6106577A (en) * | 1995-11-23 | 2000-08-22 | L'oreal | Use of a composition containing a film-forming polymer dispersion and non-melanic pigment for temporarily dyeing human or animal hair |
| WO2005120443A1 (en) * | 2004-06-14 | 2005-12-22 | Yoshikazu Shimizu | Method of hair restoration, method of fixation and stabilization of hair foundation agent, and hair restoration setting agent used in the methods |
| JP2006063059A (en) * | 2004-08-29 | 2006-03-09 | Kiichi Shimizu | Color hairdye, remover of color hairdye, agent for color hair-dyed part, and method for treating film of color hairdye |
| JP2010163390A (en) * | 2009-01-16 | 2010-07-29 | Kao Corp | Temporarily hair-dyeing agent composition |
| JP2010229106A (en) * | 2009-03-27 | 2010-10-14 | Milbon Co Ltd | Hair coloring agent and hair bleach |
| WO2012081510A1 (en) * | 2010-12-15 | 2012-06-21 | 株式会社マンダム | Mist cosmetic for hair styling agents, and hair styling agent |
| JP2017066158A (en) * | 2007-12-13 | 2017-04-06 | ロレアル | Process for dyeing hair using composition comprising hydrophobic film-forming polymer, pigment, and volatile solvent |
| JP2020527142A (en) * | 2017-07-11 | 2020-09-03 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェンＨｅｎｋｅｌ ＡＧ ＆ Ｃｏ． ＫＧａＡ | Water resistant cosmetic for temporary color change of keratin substance I |
-
1987
- 1987-03-06 JP JP5173487A patent/JPS63218613A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3012332B2 (en) * | 1993-05-07 | 2000-02-21 | ロレアル | Use of terpolymers derived from vinyl lactams as blowing agents in aerosol mousse-forming compositions, and compositions obtained thereby |
| FR2709418A1 (en) * | 1993-09-01 | 1995-03-10 | Mitsubishi Pencil Co | Hair dye |
| US6106577A (en) * | 1995-11-23 | 2000-08-22 | L'oreal | Use of a composition containing a film-forming polymer dispersion and non-melanic pigment for temporarily dyeing human or animal hair |
| WO2005120443A1 (en) * | 2004-06-14 | 2005-12-22 | Yoshikazu Shimizu | Method of hair restoration, method of fixation and stabilization of hair foundation agent, and hair restoration setting agent used in the methods |
| JP2006063059A (en) * | 2004-08-29 | 2006-03-09 | Kiichi Shimizu | Color hairdye, remover of color hairdye, agent for color hair-dyed part, and method for treating film of color hairdye |
| JP2017066158A (en) * | 2007-12-13 | 2017-04-06 | ロレアル | Process for dyeing hair using composition comprising hydrophobic film-forming polymer, pigment, and volatile solvent |
| JP2010163390A (en) * | 2009-01-16 | 2010-07-29 | Kao Corp | Temporarily hair-dyeing agent composition |
| JP2010229106A (en) * | 2009-03-27 | 2010-10-14 | Milbon Co Ltd | Hair coloring agent and hair bleach |
| WO2012081510A1 (en) * | 2010-12-15 | 2012-06-21 | 株式会社マンダム | Mist cosmetic for hair styling agents, and hair styling agent |
| JP2020527142A (en) * | 2017-07-11 | 2020-09-03 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェンＨｅｎｋｅｌ ＡＧ ＆ Ｃｏ． ＫＧａＡ | Water resistant cosmetic for temporary color change of keratin substance I |
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