JPS63106917A - Magnetic recording medium - Google Patents

Magnetic recording medium

Info

Publication number
JPS63106917A
JPS63106917A JP13305087A JP13305087A JPS63106917A JP S63106917 A JPS63106917 A JP S63106917A JP 13305087 A JP13305087 A JP 13305087A JP 13305087 A JP13305087 A JP 13305087A JP S63106917 A JPS63106917 A JP S63106917A
Authority
JP
Japan
Prior art keywords
magnetic
magnetic layer
layer
recording medium
magnetic recording
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP13305087A
Other languages
Japanese (ja)
Other versions
JPH0758540B2 (en
Inventor
Akinori Kurikawa
栗川 明典
Takao Matsudaira
松平 他家夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoya Corp
Original Assignee
Hoya Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoya Corp filed Critical Hoya Corp
Priority to JP62133050A priority Critical patent/JPH0758540B2/en
Publication of JPS63106917A publication Critical patent/JPS63106917A/en
Publication of JPH0758540B2 publication Critical patent/JPH0758540B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Abstract

PURPOSE:To permit formation of a magnetic recording medium having good coercive force and MrT by providing an underlying layer between a nonmagnetic base and magnetic layer and forming the magnetic layer of cobalt, nickel, chromium, and platinum. CONSTITUTION:The magnetic layer 3 is provided on the nonmagnetic base 1 and the underlying layer 2 is provided between the nonmagnetic base 1 and the magnetic layer 3. The magnetic layer 3 consists of the cobalt, nickel, chromium, and platinum and contains 1-43atom% platinum. For example, the film thickness of the underlying layer 2 is >=500Angstrom and the film thickness of the magnetic layer 3 is 400-1,000Angstrom . The underlying layer 2 is constituted of a nonmagnetic material such as chromium, molybdenum, titanium or tantalum. The medium having the good coercive force (Hc) and the product MrT of the residual magnetization (Mr) and the film thickness T of the magnetic layer is thereby obtd.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、磁気記録に用いられる磁気ディスク、磁気ド
ラム、磁気テープ、磁気カード等の磁気記録媒体に関づ
るものである。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to magnetic recording media used for magnetic recording, such as magnetic disks, magnetic drums, magnetic tapes, and magnetic cards.

〔従来の技術〕[Conventional technology]

従来、この種の磁気記録媒体としては、非磁性支持体上
に、Crからなる下地層(膜厚: 2500人)及びC
o−Ni−Crからなる磁性層(膜厚:600人)を順
次積層したものや、非磁性支持体ヒに、N1−P合金か
らなるメッキ膜、ptとN1を含有するCO合金からな
る磁性層及びSiO2膜を順次積層したもの(特開昭5
9−61106号公報)があった。
Conventionally, this type of magnetic recording medium consists of an underlayer made of Cr (thickness: 2,500 yen) and Cr on a non-magnetic support.
Magnetic layers (thickness: 600 layers) made of o-Ni-Cr are sequentially laminated, plated films made of N1-P alloy on a non-magnetic support, magnetic layers made of CO alloy containing PT and N1. layer and SiO2 film are sequentially laminated (Japanese Unexamined Patent Publication No. 5
9-61106).

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

しかしながら、従来の磁気記録媒体は、次のような問題
点があった。すなわち、Crからなる下地層とCo−旧
−Crからなる磁性層とを有する磁気記録媒体では、保
磁力(Hc)を向上ざVるためには、Cr下地層の膜厚
を厚くするか、または磁性層の膜厚を薄くする必要があ
る。しかし、Cr下地層は膜厚5000人程度でtlc
の増加は飽和してしまい、単に膜厚を厚くしてもHcは
向上しない。・一方、磁気記録媒体に記録された情報の
再生時の出力が、残留磁化(14r)と磁性層の膜厚(
T)との積(以下、[HrrJという。)に比例するこ
とから、Co−Ni−Crからなる磁性層の膜厚を薄く
してticを高める場合、この磁性層の膜厚を蒲クシす
ぎると前述した再生時の出力に支障が生じる。したがっ
て、磁性層の膜厚(T)を薄クシてHcを高めることに
も限界がある。
However, conventional magnetic recording media have the following problems. That is, in a magnetic recording medium having an underlayer made of Cr and a magnetic layer made of Co-old-Cr, in order to improve the coercive force (Hc), it is necessary to increase the thickness of the Cr underlayer or to increase the thickness of the Cr underlayer. Alternatively, it is necessary to reduce the thickness of the magnetic layer. However, the Cr underlayer has a film thickness of about 5,000 tlc.
The increase in Hc reaches saturation, and simply increasing the film thickness does not improve Hc.・On the other hand, the output when reproducing information recorded on a magnetic recording medium depends on the residual magnetization (14r) and the thickness of the magnetic layer (
T) (hereinafter referred to as [HrrJ)]. Therefore, if the thickness of the magnetic layer made of Co-Ni-Cr is made thinner to increase the tic, the thickness of the magnetic layer may be too large. This causes the aforementioned problem with the output during playback. Therefore, there is a limit to increasing Hc by reducing the thickness (T) of the magnetic layer.

例えば、近年要求されている3、 7x 10’ (e
a+u /ci )以上のHrTを得ようとすると、H
rTと同様に要求されている900(Oe)以上のII
cを得ることは困難であった。
For example, 3, 7x 10' (e
When trying to obtain HrT greater than a+u/ci), H
II of 900 (Oe) or higher, which is required similarly to rT.
It was difficult to obtain c.

また、co−Nt−ptからなる磁性層は、前述したC
Further, the magnetic layer made of co-Nt-pt is made of the above-mentioned C
.

−Ni−Crからなる磁性層よりも耐湿性が劣ることか
ら、良好な磁気記録媒体を得ることができなかった。ま
た、前述した値のllc及びHrTを得るためには、p
tの含有率を10〜25原子%の範囲しか選択できず製
造コストの低減を行なうことができなかった。
Since the moisture resistance was inferior to that of a magnetic layer made of -Ni-Cr, a good magnetic recording medium could not be obtained. In addition, in order to obtain the above-mentioned values of llc and HrT, p
The content of t could only be selected within the range of 10 to 25 atom %, making it impossible to reduce manufacturing costs.

〔問題点を解決するための手段〕[Means for solving problems]

本発明は前述した問題点を除去するためになされたもの
で、その特徴は、非磁性支持体上に磁性層を設けた磁気
記録媒体において、前記非磁性支持体と前記磁性層との
間に下地層を設け、前記磁性層が、コバルト(CO)、
ニッケル(Ni)、クロム(Cr)及び白金(pt)か
らなり、かつ前記白金が1〜43原子%含有している磁
気記録媒体である。
The present invention has been made to eliminate the above-mentioned problems, and is characterized in that in a magnetic recording medium in which a magnetic layer is provided on a non-magnetic support, there is a gap between the non-magnetic support and the magnetic layer. An underlayer is provided, and the magnetic layer is made of cobalt (CO),
This magnetic recording medium is made of nickel (Ni), chromium (Cr), and platinum (pt), and contains 1 to 43 atomic percent of the platinum.

本発明の実施態様は、下地層の膜厚が500Å以上であ
り、かつ磁性層の膜厚が400〜1000人であること
、また下地層がクロム(Cr)、モリブデン(No)、
チタン(Ti)、タンタル(Ta)等の非磁性材料から
なることである。
In an embodiment of the present invention, the thickness of the underlayer is 500 Å or more, and the thickness of the magnetic layer is 400 to 1000 Å, and the underlayer is made of chromium (Cr), molybdenum (No),
It is made of a non-magnetic material such as titanium (Ti) or tantalum (Ta).

〔実施例〕〔Example〕

本発明の一実施例を第1図に基づき詳細に説明する。 An embodiment of the present invention will be described in detail based on FIG.

先ず、ソーダライムガラスからなる非磁性支持体1の一
主表面上に、Crをターゲットとして、非磁性支持体1
の温度を室温とし、Arガス雰囲気(Arガス圧: 6
 X 10−’Pa)中でマグネトロンスパッタリング
法で、Crからなる非磁性の下地層2(膜厚: 300
0人)を成膜する。次にCo、Ni、Cr、及びptか
らなる合金をターゲットとし、下地層2を成膜したとき
と同様にマグネトロンスパッタリング法でCo、Ni、
Cr及びptからなる磁性層3(膜厚は600人で、C
o、Ni、Cr及びptのそれぞれの含有率(原子%)
は、69.0.24.3.4.9及び1.8である。
First, on one main surface of the non-magnetic support 1 made of soda lime glass, the non-magnetic support 1 is coated with Cr as a target.
temperature is room temperature, Ar gas atmosphere (Ar gas pressure: 6
A nonmagnetic underlayer 2 made of Cr (thickness: 300
0 people) to form a film. Next, using an alloy consisting of Co, Ni, Cr, and pt as a target, Co, Ni, and
Magnetic layer 3 made of Cr and pt (thickness is 600 mm, C
o, Ni, Cr and pt content (atomic %)
are 69.0.24.3.4.9 and 1.8.

)を下地層2上に積層する。なお、この下地層2は、こ
の上に積層する磁性層3の結晶構造を制御する作用をす
る。次に、この磁性via上に、炭素(C)をターゲッ
トとし、前述したマグネトロンスパッタリング法で、C
からなる保護膜4(膜厚:300人)を積層し、磁気記
録媒体5を製作する。
) is laminated on the base layer 2. Note that this underlayer 2 functions to control the crystal structure of the magnetic layer 3 laminated thereon. Next, using carbon (C) as a target on this magnetic via, carbon
A magnetic recording medium 5 is manufactured by laminating a protective film 4 (thickness: 300 layers) consisting of:

次に、前述した磁気記録媒体5の保磁力(Hc)及びM
rTを次の表に示す。なお、Co、Ni、Cr及びpt
の含有率の異なる他の実施例についてもシ1様に示す。
Next, the coercive force (Hc) and M of the magnetic recording medium 5 described above are
rT is shown in the table below. In addition, Co, Ni, Cr and pt
Other examples with different content rates are also shown in Figure 1.

なお、比較例として、磁性層がCo、Ni及びptから
なるものであるとき(他の構成は本例と同様である。)
の保磁力11cも示寸。
Note that as a comparative example, the magnetic layer is made of Co, Ni, and pt (other configurations are the same as in this example).
The coercive force 11c of is also indicated.

また、前述した下地層2の膜厚を3000人とし、磁性
fI3のpt会右率を1〜45原子%の範囲で変化させ
、残りのCo、Ni、Crの含有率を原子比70:25
: 5で配分して含有さけた磁気記録媒体(保護膜も前
述したと同様に積層されている。)の保磁力とHrTを
第2図に示す。なお、同図の線Aは保磁力を示し、同図
の線BはHrTを示ず。この図及び前述した表によれば
、ptが1〜43原子%の範囲でかつ下地層2を有して
いることから、保磁力は90000以上が保たれ、か”
) MrTも3.7X 1O−381tJ/ci以Fと
なる。したがって、従来のCo−Ni−Crからなる磁
性膜のときのように、保磁力を向上させる場合、磁性層
を助くする必要もなく、また薄くしても)1rT ハ3
.7xlO−3emu/ci以上を維持スルコトができ
る。なお、第2図においては、P【の含有間1原子%未
満の保磁力を示していないが、1原子%未満であると急
激に低下する。また、ptの範囲を広くとることができ
ることから、製造条件の管理を緩和することができ、か
つ従来のCo−Ni−Ptからなる磁性層よりもptの
含有率を下げても(例えば1〜10原子%)、所望する
保磁力及びHrTが得られることから製造コストの低減
になる。さらに、この磁性層は、従来のCo−Ni−C
rからなる磁性層よりも耐湿性が優れていた。
Further, the thickness of the underlayer 2 mentioned above was set to 3000, the PT ratio of the magnetic fI3 was varied in the range of 1 to 45 at%, and the content of the remaining Co, Ni, and Cr was adjusted to an atomic ratio of 70:25.
FIG. 2 shows the coercive force and HrT of the magnetic recording medium (the protective film is also laminated in the same manner as described above) in which the content was avoided by distributing the amount of 5:5. Note that line A in the same figure indicates coercive force, and line B in the same figure does not indicate HrT. According to this figure and the table mentioned above, since the pt is in the range of 1 to 43 atomic % and the underlayer 2 is present, the coercive force is maintained at 90,000 or more.
) MrT is also 3.7X 1O-381tJ/ci or more F. Therefore, when improving the coercive force as in the case of a conventional magnetic film made of Co-Ni-Cr, there is no need to improve the magnetic layer, and even if it is thinned (1rT)
.. It is possible to maintain 7xlO-3 emu/ci or higher. Although FIG. 2 does not show a coercive force of less than 1 atomic % when P is contained, the coercive force decreases rapidly when the content is less than 1 atomic %. In addition, since the range of pt can be widened, the control of manufacturing conditions can be relaxed, and even if the pt content is lower than that of the conventional magnetic layer made of Co-Ni-Pt (for example, 1 to 10 at. Furthermore, this magnetic layer is similar to the conventional Co-Ni-C
It had better moisture resistance than a magnetic layer made of r.

本発明は前記実施例に限らず、下記のものであってもよ
い。先ず、非磁性支持体は、ソーダライムガラスからな
るものに限らず、アルミノシリケートガラス、石英ガラ
ス等の他のガラスや、A1合金やセラミックであっても
よい。また、下地層はcrに限らず他の非磁性材料、例
えばMo、Ti、■aであってもよい。また、磁性層及
び下地層の膜厚は、ぞれぞれ600人及び3000人に
限るものではないが、望ましくは磁性層は400人〜1
000人で、かつ下地層は500Å以上がよい。すなわ
ち、下地層が500人未満であると、前述した保磁力が
9000層未満及びMrTが3.7x 10−3 em
u/cd未満となる場合があり、一方、磁性層が400
人〜1000人の範囲外であると、前記した下地層と同
様な場合がある。なお、下地層の膜厚は5000人を上
限とすると、さらに磁気記録媒体の製造コスト等の実用
性が向上する。
The present invention is not limited to the above-described embodiments, but may include the following embodiments. First, the nonmagnetic support is not limited to soda lime glass, but may be other glasses such as aluminosilicate glass or quartz glass, A1 alloy, or ceramic. Further, the underlayer is not limited to Cr, but may be made of other non-magnetic materials, such as Mo, Ti, and (a). The thickness of the magnetic layer and the underlayer are not limited to 600 and 3000, respectively, but preferably the magnetic layer has a thickness of 400 to 1.
000 people, and the base layer preferably has a thickness of 500 Å or more. That is, when the underlayer is less than 500 layers, the above-mentioned coercive force is less than 9000 layers and MrT is 3.7x 10-3 em.
The magnetic layer may be less than 400 u/cd.
If the number is outside the range of 1,000 to 1,000 people, there may be cases similar to those of the base layer described above. Note that if the thickness of the underlayer is set at 5,000 layers as an upper limit, practicality such as manufacturing cost of the magnetic recording medium will be further improved.

また、前記実施例ではptを除く、残りのCo、Xi、
Crの含有率を原子比70:25:5で配分したが、他
の配分、例えば76:18:6であってもよい。また、
前記実施例では、保護膜を積層したがこれはなくてもよ
い。また保護膜を積層したとき、前記実施例ではCから
なる保護膜であったが、これに限らずSi02やCi機
重重合体らなる保護膜、さらに複合層、例えば、cr層
と0層とを当接して積層したもの、cr層とSi02層
とを当接して積層したもの、CrJfflとclとSi
02層とからなりこれらを退官当接して積層したもの、
又前記複合層の材料を混合した混合層であってもよい。
In addition, in the above embodiment, the remaining Co, Xi,
Although the Cr content was distributed at an atomic ratio of 70:25:5, other distributions may be used, for example, 76:18:6. Also,
In the above embodiment, a protective film is laminated, but this may be omitted. In addition, when the protective film is laminated, the protective film is made of C in the above embodiment, but the protective film is not limited to this, and the protective film is not limited to this, but may be made of Si02 or a Ci polymer, or a composite layer, for example, a CR layer and a 0 layer. Laminated in contact with each other, Cr layer and Si02 layer in contact with each other, CrJffl, cl and Si
It consists of 02 layers and is laminated with these layers in contact with each other.
Alternatively, it may be a mixed layer in which the materials of the composite layer are mixed.

また、前記実施例では、非磁性支持体上に下地層、磁性
層及び保護膜を順次積層したが、例えば、円板状の磁気
記録媒体(磁気ディスク)のとき、磁気ヘッドによる情
報の書き込み又は読み取り終了後、磁気ヘッドが配置さ
れるランディングゾーンを含む領域の、非磁性支持体と
下地層との間又は下地層と磁性層との間に磁性層や保護
膜層に凹凸を形成する層(例えばへ克薄膜)を設けても
よい。
In the above embodiments, the underlayer, magnetic layer, and protective film were sequentially laminated on the nonmagnetic support. After reading is completed, a layer that forms irregularities on the magnetic layer or protective film layer ( For example, a thin film) may be provided.

〔発明の効果〕〔Effect of the invention〕

本発明は前述したように1、非磁性支持体と磁性層との
間に下地層を設け、磁性層がCo、Hi、Cr及びpt
からなり、かつptの含有率を1〜43原子%であるこ
とから、良好な保磁力とHrTを右する磁気記録媒体が
可能となった。
As described above, the present invention provides 1. an underlayer between the nonmagnetic support and the magnetic layer, and the magnetic layer is made of Co, Hi, Cr, and pt.
and a pt content of 1 to 43 at. %, it has become possible to create a magnetic recording medium with good coercive force and good HrT.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の磁気記録媒体の一実施例を示す断面図
であり、第2図は本発明の一実施例において磁性層のp
t含有率を変化させたときの保磁力及びHrTを示す特
性図である。
FIG. 1 is a sectional view showing one embodiment of the magnetic recording medium of the present invention, and FIG. 2 is a cross-sectional view showing one embodiment of the magnetic recording medium of the present invention.
FIG. 3 is a characteristic diagram showing coercive force and HrT when the t content is changed.

Claims (3)

【特許請求の範囲】[Claims] (1)非磁性支持体上に磁性層を設けた磁気記録媒体に
おいて、前記非磁性支持体と前記磁性層との間に下地層
を設け、前記磁性層が、コバルト、ニッケル、クロム及
び白金からなり、かつ前記白金が1〜43原子%含有し
ていることを特徴とする磁気記録媒体。
(1) In a magnetic recording medium in which a magnetic layer is provided on a non-magnetic support, an underlayer is provided between the non-magnetic support and the magnetic layer, and the magnetic layer is made of cobalt, nickel, chromium, and platinum. A magnetic recording medium characterized in that the platinum is contained in an amount of 1 to 43 atomic %.
(2)下地層の膜厚が500Å以上であり、かつ磁性層
の膜厚が400〜1000Åであることを特徴とする特
許請求の範囲第(1)項記載の磁気記録媒体。
(2) The magnetic recording medium according to claim (1), wherein the underlayer has a thickness of 500 Å or more, and the magnetic layer has a thickness of 400 to 1000 Å.
(3)下地層がCr、Mo、Ti、Ta等の非磁性材料
からなることを特徴とする特許請求の範囲第(1)項又
は第(2)項記載の磁気記録媒体。
(3) The magnetic recording medium according to claim (1) or (2), wherein the underlayer is made of a nonmagnetic material such as Cr, Mo, Ti, or Ta.
JP62133050A 1986-06-27 1987-05-28 Magnetic recording medium Expired - Lifetime JPH0758540B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62133050A JPH0758540B2 (en) 1986-06-27 1987-05-28 Magnetic recording medium

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP15114886 1986-06-27
JP61-151148 1986-06-27
JP62133050A JPH0758540B2 (en) 1986-06-27 1987-05-28 Magnetic recording medium

Publications (2)

Publication Number Publication Date
JPS63106917A true JPS63106917A (en) 1988-05-12
JPH0758540B2 JPH0758540B2 (en) 1995-06-21

Family

ID=26467487

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62133050A Expired - Lifetime JPH0758540B2 (en) 1986-06-27 1987-05-28 Magnetic recording medium

Country Status (1)

Country Link
JP (1) JPH0758540B2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5180640A (en) * 1990-10-01 1993-01-19 Komag, Inc. Magnetic recording medium comprising a magnetic alloy layer of cobalt nickel, platinum and chromium formed directly on a nickel alloy amorphous underlayer
US5536585A (en) * 1993-03-10 1996-07-16 Hitachi, Ltd. Magnetic recording medium and fabrication method therefor
JP2007247741A (en) * 2006-03-15 2007-09-27 Ogino Kogyo Kk Rocking gear device
US7927022B2 (en) 2005-04-05 2011-04-19 Nsk Ltd. Thrust roller bearing

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5911605A (en) * 1982-06-28 1984-01-21 エヌ・ベ−・フイリツプス・フル−イランペンフアブリケン Magnetic recording element
JPS62223813A (en) * 1986-03-25 1987-10-01 Hitachi Metals Ltd Magnetic recording medium

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5911605A (en) * 1982-06-28 1984-01-21 エヌ・ベ−・フイリツプス・フル−イランペンフアブリケン Magnetic recording element
JPS62223813A (en) * 1986-03-25 1987-10-01 Hitachi Metals Ltd Magnetic recording medium

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5180640A (en) * 1990-10-01 1993-01-19 Komag, Inc. Magnetic recording medium comprising a magnetic alloy layer of cobalt nickel, platinum and chromium formed directly on a nickel alloy amorphous underlayer
US5536585A (en) * 1993-03-10 1996-07-16 Hitachi, Ltd. Magnetic recording medium and fabrication method therefor
US7927022B2 (en) 2005-04-05 2011-04-19 Nsk Ltd. Thrust roller bearing
JP2007247741A (en) * 2006-03-15 2007-09-27 Ogino Kogyo Kk Rocking gear device

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