JPS62260034A - Permanent magnet - Google Patents
Permanent magnetInfo
- Publication number
- JPS62260034A JPS62260034A JP61084899A JP8489986A JPS62260034A JP S62260034 A JPS62260034 A JP S62260034A JP 61084899 A JP61084899 A JP 61084899A JP 8489986 A JP8489986 A JP 8489986A JP S62260034 A JPS62260034 A JP S62260034A
- Authority
- JP
- Japan
- Prior art keywords
- alloy
- permanent magnet
- magnetic field
- subjected
- point
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 7
- 239000000956 alloy Substances 0.000 claims abstract description 7
- 229910017985 Cu—Zr Inorganic materials 0.000 claims abstract description 4
- 229910000765 intermetallic Inorganic materials 0.000 claims abstract description 3
- 229910001004 magnetic alloy Inorganic materials 0.000 claims abstract description 3
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 3
- 150000002910 rare earth metals Chemical group 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 5
- 229910052802 copper Inorganic materials 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 230000032683 aging Effects 0.000 description 4
- 230000005347 demagnetization Effects 0.000 description 4
- 230000005415 magnetization Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 230000001914 calming effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000008774 maternal effect Effects 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Landscapes
- Hard Magnetic Materials (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、RCo 系金属間化合物の組成に関するも
のである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to the composition of RCo 2 -based intermetallic compounds.
従来からR−Co −Fe −Cu −Zrからなる合
金系は。Conventionally, the alloy system consists of R-Co-Fe-Cu-Zr.
優れた出気特性が得られていることが知られている。こ
こでRは希土類金属元素であるが減磁曲線の第2象限に
゛くに〈点”を持つために、低い動作点での使用が出来
ない欠点があった。又、従来組成においても、熱処理条
件を選ぶことによフ。It is known that excellent air output characteristics are obtained. Here, R is a rare earth metal element, but because it has a "point" in the second quadrant of the demagnetization curve, it has the disadvantage that it cannot be used at a low operating point.Also, even in the conventional composition, heat treatment By choosing the conditions.
“〈に〈点”を下げ、低い動作点で使用することは出来
るが、減磁特性のiHcが大きくなシ1着磁がしにくく
なる欠点があった。Although it is possible to lower the "point" and use it at a lower operating point, it has the disadvantage that the iHc of the demagnetizing characteristic is large, making it difficult to magnetize.
不発明は、これらの欠点を除去し減磁曲線第2象限の°
くにぐ点″を下げて、低い動作点で使用できる様にし、
又、減磁特性iHcを小さくシ2着磁しやすい永久磁石
を提供する事を目的とする。The invention is to eliminate these drawbacks and reduce the demagnetization curve to the second quadrant.
By lowering the "kunigu point", it can be used at a lower operating point,
Another object of the present invention is to provide a permanent magnet that has a small demagnetization characteristic iHc and is easy to magnetize.
本発明は+ RCo17系金属化合物を主体とするR−
Co−Fe −Cu−Zrからなる合金において、 C
oの一部をO,]乃至0.5 wt%のTiで置換した
永久磁石である。The present invention is directed to + RCo17 based metal compounds.
In an alloy consisting of Co-Fe-Cu-Zr, C
This is a permanent magnet in which a part of o is replaced with O,] to 0.5 wt% of Ti.
着磁性を良好KL、且つ低い動作点でも使用できる。 It has good magnetization KL and can be used even at a low operating point.
〈実施例1〉
組成26wt%Sm 、 15wt%Fe l 5 w
t%Cu 。<Example 1> Composition 26wt%Sm, 15wt%FeI5w
t%Cu.
2、5 wt% Zr 、残部Coの合金と、coの0
.1 、0.3゜0.5 、0.7 wt%をTiで置
換した合金を溶解し、得られた磁石合金を平均粒径4μ
mに微粉砕し、10KOeの磁場中で千行砒場ゾレス成
形を行い、 1215℃で2時間焼結後、1200℃で
5時間溶体化処理を行った。2.5 wt% Zr, balance Co alloy and 0 co
.. An alloy in which 1,0.3°0.5,0.7 wt% was replaced with Ti was melted, and the resulting magnetic alloy had an average grain size of 4μ.
The material was pulverized to 500 ml of powder, subjected to Soles molding in a 10 KOe magnetic field, sintered at 1215°C for 2 hours, and then solution treated at 1200°C for 5 hours.
次いで時効処理として780℃×10H後10’C/m
inで40℃まで徐冷後、急冷を行った。得ら九た磁石
の磁気特性を第1図に示す。Then, as aging treatment, after 780°C x 10H, 10'C/m
After slow cooling to 40° C., rapid cooling was performed. The magnetic properties of the obtained magnet are shown in Figure 1.
第1図かられかる通p 、 Coの一部をTiで置換す
る事によシ、ある量まで減磁特性gHcが上昇し。As shown in Figure 1, by substituting a part of Co with Ti, the demagnetization characteristic gHc increases up to a certain amount.
0、6%以上ではTi置換の効果がなく逆に低下してい
る。At 0.6% or more, the Ti substitution has no effect and on the contrary decreases.
第2図にB−H曲線の例を書いたが、′〈にく点”の評
価は、 BHcが大きい方が良い事を示している。従っ
てTiの含有量が0.3wt%の時がもっともBHcが
高く、“′くにく点”を低くしている事が分かる。An example of the B-H curve is shown in Fig. 2, and the evaluation of the ``nikk point'' indicates that the larger the BHc, the better.Therefore, when the Ti content is 0.3 wt%, However, it can be seen that the BHc is the highest and the ``kuniku point'' is low.
〈実施例2〉
実施例1で得られた溶体化処理後の磁石について1時効
処理条件を変えて行った。時効処理として、820℃×
10H後、10℃/m i nで400℃まで徐冷後、
急冷を行った。得られた磁石の母性特性を第3図に示す
。第3図かられかる通り、実施例1より、全体的にBH
c値が高く得られ、Ti置換によって、 BHcを大き
くしてもiHcの値は低く押える事ができる。このiH
cが重要な事を第4図で説明すると、100%着礎する
のに、 iHcが小さいものは低い着磁磁場で良(、i
Hcの大きいものは高い着磁磁場が必要である。着凪母
場を大きくする事は1着磁の・ぐターン等で不可能な事
もあり。<Example 2> The solution-treated magnet obtained in Example 1 was subjected to aging treatment under different aging conditions. As aging treatment, 820℃×
After 10 hours, slowly cooled to 400°C at 10°C/min,
Rapid cooling was performed. Figure 3 shows the maternal characteristics of the obtained magnet. As can be seen from FIG. 3, from Example 1, overall BH
A high c value can be obtained, and by replacing Ti, the iHc value can be kept low even if the BHc is increased. This iH
The importance of c is explained in Figure 4. For 100% anchoring, a small iHc can be achieved with a low magnetizing field (, i
A material with a large Hc requires a high magnetizing magnetic field. It may be impossible to increase the calming base field in one turn of magnetization.
極力小さな着磁磁場で100%着磁出来る事が。It is possible to achieve 100% magnetization with the smallest possible magnetizing magnetic field.
良い3石が得らnることである。It is important to get a good 3 stones.
以上述べたごとく2本発明によれば、 Coの一部をT
iで置換する事により、”<にく点″を低クシ。As described above, according to the present invention, a part of Co is replaced by T
By replacing it with i, the "<nikku point" is lowered.
しかも着磁のしやすい低い動作点で使用の出きるR2C
017系永久磁石を得ることができる。Moreover, R2C can be used at a low operating point that is easy to magnetize.
A 017 series permanent magnet can be obtained.
以下余白Margin below
第1図は実施例1におけるTiの含有率に対するBHc
特性を、第2図は“くにく点”とBHcとの関係図を示
す。第3図は実施例2におけるTiの含有率に対する1
)(cとnHcの特性図を、第4図は同じく着磁磁場と
着磁率との関係図を示す。
第11Figure 1 shows BHc versus Ti content in Example 1.
Regarding the characteristics, FIG. 2 shows a relationship diagram between the "kuniku point" and BHc. Figure 3 shows 1 for the Ti content in Example 2.
) (A characteristic diagram of c and nHc, and Figure 4 also shows a diagram of the relationship between the magnetizing magnetic field and the magnetization rate. 11th
Claims (1)
化合物を主体とするR−Co−Fe−Cu−Zrからな
る合金においてCoを0.1乃至0.5wt%のTiで
置換することを特徴とする永久磁石合金。1. R_2 (R is a rare earth metal) An alloy consisting of R-Co-Fe-Cu-Zr mainly composed of Co_1_7 intermetallic compounds, characterized by replacing Co with 0.1 to 0.5 wt% of Ti. Permanent magnetic alloy.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61084899A JPS62260034A (en) | 1986-04-15 | 1986-04-15 | Permanent magnet |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61084899A JPS62260034A (en) | 1986-04-15 | 1986-04-15 | Permanent magnet |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS62260034A true JPS62260034A (en) | 1987-11-12 |
Family
ID=13843584
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61084899A Pending JPS62260034A (en) | 1986-04-15 | 1986-04-15 | Permanent magnet |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS62260034A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9087631B2 (en) | 2008-11-19 | 2015-07-21 | Kabushiki Kaisha Toshiba | Permanent magnet and method of manufacturing the same, and motor and power generator using the same |
US9774219B2 (en) | 2009-08-06 | 2017-09-26 | Kabushiki Kaisha Toshiba | Permanent magnet, motor and electric generator |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57196502A (en) * | 1981-05-29 | 1982-12-02 | Tohoku Metal Ind Ltd | Material for permanent magnet |
JPS5848650A (en) * | 1981-09-16 | 1983-03-22 | Namiki Precision Jewel Co Ltd | Permanent magnet alloy |
JPS59165402A (en) * | 1983-03-10 | 1984-09-18 | Seiko Epson Corp | Thermal resistance-improved composite permanent magnet |
-
1986
- 1986-04-15 JP JP61084899A patent/JPS62260034A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57196502A (en) * | 1981-05-29 | 1982-12-02 | Tohoku Metal Ind Ltd | Material for permanent magnet |
JPS5848650A (en) * | 1981-09-16 | 1983-03-22 | Namiki Precision Jewel Co Ltd | Permanent magnet alloy |
JPS59165402A (en) * | 1983-03-10 | 1984-09-18 | Seiko Epson Corp | Thermal resistance-improved composite permanent magnet |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9087631B2 (en) | 2008-11-19 | 2015-07-21 | Kabushiki Kaisha Toshiba | Permanent magnet and method of manufacturing the same, and motor and power generator using the same |
US9774219B2 (en) | 2009-08-06 | 2017-09-26 | Kabushiki Kaisha Toshiba | Permanent magnet, motor and electric generator |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPS5814865B2 (en) | permanent magnet material | |
JPS60243247A (en) | Permanent magnet alloy | |
JPS62260034A (en) | Permanent magnet | |
JP3296507B2 (en) | Rare earth permanent magnet | |
JPS60197843A (en) | Permanent magnet alloy | |
JPH0252412B2 (en) | ||
JPS61147503A (en) | Rare earth magnet | |
JPS62116756A (en) | Permanent magnet alloy | |
JPH0426525B2 (en) | ||
JPS619551A (en) | Rare earth element-iron type permanent magnet alloy | |
JPH05171323A (en) | Permanent magnet material | |
JPS62158852A (en) | Permanent magnet material | |
JP2632025B2 (en) | Rare earth permanent magnet material | |
JPS62158854A (en) | Permanaent magnet material | |
JPS6077952A (en) | Samarium-cobalt magnetic alloy containing praseodymium and neodymium | |
JPH0869907A (en) | Material for permanent magnet and material for bonded magnet using the same | |
JPH01179302A (en) | Permanent magnet | |
JPH063763B2 (en) | Rare earth permanent magnet manufacturing method | |
JPS61246347A (en) | Anisoptopic sintered permanent magnet alloy | |
JPS62291902A (en) | Manufacture of permanent magnet | |
JPS596350A (en) | Rare earth element cobalt material for magnet and preparation thereof | |
JPS62103346A (en) | Permanent magnet alloy | |
JPS58157938A (en) | Permanent magnet alloy | |
JPS62149828A (en) | Manufacture of rare earth magnet | |
JPH0441652A (en) | Rare earth magnetic alloy |