JPS62145664A - Manufacture of sealed lead storage battery - Google Patents
Manufacture of sealed lead storage batteryInfo
- Publication number
- JPS62145664A JPS62145664A JP60284981A JP28498185A JPS62145664A JP S62145664 A JPS62145664 A JP S62145664A JP 60284981 A JP60284981 A JP 60284981A JP 28498185 A JP28498185 A JP 28498185A JP S62145664 A JPS62145664 A JP S62145664A
- Authority
- JP
- Japan
- Prior art keywords
- electrode plate
- battery
- electrochemically
- unformed
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/06—Lead-acid accumulators
- H01M10/12—Construction or manufacture
- H01M10/128—Processes for forming or storing electrodes in the battery container
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
すを使っ°Ｃ組立てた極板群を電槽内に挿入し、該極板
群に電解液を含浸せしめて、電槽化成を行なう密閉型鉛
蓄電池の製造法の改良に関する従来の技術
従来この種密閉型鉛蓄電池の製造法は、格子にペースト
を充填した後、希硫酸により浸漬を行なって、その後熟
成乾燥し、そのまま極板の状態で化成した既化成極板を
使うか、まグこは、未化成極板を使って組立゛Ｃた極板
群を電槽内に収納した後、該極板群に電解液を含浸して
電相化成を行なっていた。[Detailed Description of the Invention] Industrial Field of Application A closed type lead battery that performs battery cell formation by inserting a group of electrode plates assembled at °C into a battery case and impregnating the electrode plate group with an electrolyte. Conventional technology for improving the manufacturing method of storage batteries The conventional manufacturing method for this type of sealed lead-acid battery is to fill a grid with paste, immerse it in dilute sulfuric acid, then age and dry it, and then chemically process it in the form of electrode plates. Alternatively, magko can use unformed electrode plates to assemble the electrode plates, store them in a battery case, and then impregnate the electrode plates with an electrolyte and apply the electrolytic phase. I was doing chemical conversion.
発明が解決しようとする問題点
上記の製造法において、未化成正極板は、電槽化成中に
極板表面とリテーナとの間に、ガツシングによる気泡が
ｔこまり、そのため液拡散を妨げる。その結果、化成終
了後においても、正極板表面にＰｂ５Ｏ，の自戒（白い
色のＰｂ８０゜か化成されずに残っ〔いること）を生じ
て化成仕上りか悪くなったり、Ｐｂｏｔ組成にバラツキ
を生じた。Problems to be Solved by the Invention In the above manufacturing method, air bubbles are trapped in the unformed positive electrode plate between the surface of the electrode plate and the retainer during formation of the battery case due to gassing, which impedes liquid diffusion. As a result, even after completion of chemical formation, Pb5O (white-colored Pb80° remained unformed) was produced on the surface of the positive electrode plate, resulting in poor chemical formation finish and variations in Pbot composition. .
問題点を解決するための手段
本発明は、上記の問題点を解決するために、上ＩＩ＋ｒ
＋ 〒４ｅ七−ｍ ｋ ｆ ｒｆ：＋ｌＧ／６；’！１
ｍレバ昌ルｔ＋Ｉ ／？％硫酸溶液例えばペルオキソ
硫酸アンモニウム硫酸溶液（Ｎｌ（４） ｔ ｓｔ Ｏ
ｓを用いてこの中に浸漬することにより未化成正極板表
面を前もっＣ１化学的にＰ ｂＯ，化し、熟成乾燥後の
未化成正極板を使って未化成正極板およびリテーナと共
に組立てた極板群を７１２！内に収納し、該極板群中に
遊離液を生じない程度に電解液を含浸させた状態で、電
槽化成を行なって密閉型鉛蓄電池を製造することを特徴
とするものである。Means for Solving the Problems In order to solve the above problems, the present invention provides
+〒4e7-mk f rf:+lG/6;'! 1
m lever t + I /? % sulfuric acid solution such as ammonium peroxosulfate sulfuric acid solution (Nl(4) t st O
The surface of the unformed positive electrode plate was previously converted to P bO by C1 chemical treatment by immersing it in this solution using S, and the unformed positive electrode plate after aging and drying was used to assemble the unformed positive electrode plate and the retainer. 712 groups! The method is characterized in that a sealed lead-acid battery is manufactured by carrying out cell formation in a state in which the electrode plate group is impregnated with an electrolytic solution to an extent that free liquid is not generated.
作用
本発明は、上記の手段を用いることにより正郷板組成の
バラツキがなくなり、したがってモノブロック電池の場
合、各セル間で電池容量の；奄うツキを生ずることがな
い。また、未化成正極板表面のｐ ｂｏ、化により、た
とえ極板とリテーナＷの間に気泡かたまっても、正極板
表面にＰｂ５Ｏ，の自戒はなくなる。さらに未化成正極
板の酸化剤の硫酸溶液中での浸漬にょるＰｂｕ、化によ
っＣ多孔度か増加し、電池特性、特に高率放電性能の向
上にもつながる。Effect of the present invention By using the above-mentioned means, variations in the composition of the solar cells are eliminated, and therefore, in the case of a monoblock battery, variations in battery capacity between cells do not occur. Furthermore, due to the p-bo conversion on the surface of the unformed positive electrode plate, even if air bubbles form between the electrode plate and the retainer W, there is no need to worry about Pb5O on the surface of the positive electrode plate. Furthermore, the Pbu and C porosity increases when the unformed positive electrode plate is immersed in a sulfuric acid solution of an oxidizing agent, thereby increasing the C porosity, which also leads to improvement in battery characteristics, particularly high rate discharge performance.
実施例 本発明の一実施例を説明する。Example An embodiment of the present invention will be described.
まず鉛合金格子に鉛酸化物のペーストを充填し、２〜↓
ｍ ｆｆｔ ＪＧペルオキソ硫酸アンモニウム塩を比重
１．０２０〜１．０５０の硫酸溶液で溶解した液に３０
分浸漬させ、次のｆｉｌ、（２）式の反応を起こさせる
。First, the lead alloy grid is filled with lead oxide paste, and 2~↓
m fft JG Ammonium peroxosulfate is dissolved in a sulfuric acid solution with a specific gravity of 1.020 to 1.050.
Then, the next fil, the reaction of formula (2) is caused.
（ＮＨ，） 、 Ｓ、 Ｏ＋ 十Ｐ ｂｏ十Ｈ，０→（
ＮＨ，）、ＳＯ，＋Ｈ１Ｏ，＋ＰｂＯ，１ｔｌ）−１！
ＳＯ，＋ＰｂＯ−＋Ｐｂ５Ｏ，＋）（１０ｆ２１その後
水洗し、熟成乾燥後の未化成正極板を使っＣ未化成負極
板およびリテーナと共に組立でた極板群を電槽内に収納
し、該極板群中に、遊離液を生じない程度に電解液を含
浸させた状態で電槽化を行なって密閉型鉛蓄電池を得る
。(NH,) , S, O+ 10P bo1H, 0→(
NH,), SO, +H1O, +PbO, 1tl)-1!
SO, +PbO-+Pb5O, +) (10f21) After that, the electrode plate group assembled with the C unformed negative electrode plate and the retainer using the unformed positive electrode plate washed with water after aging and drying is stored in a battery case, and the electrode plate group is assembled. A sealed lead-acid battery is obtained by impregnating the battery with an electrolytic solution to an extent that no free liquid is produced and forming the battery into a container.
本発明の製造法によって得ｔこ密閉型鉛蓄電池Ｃ本発明
品）と従来の製造法によって得た密閉型鉛蓄電池（従来
品）との電池特性の比較を第１図、第２図に示す。電池
はいずれも４Ｖ−４Ａｈで、第１図は雰囲気温度２０’
Ｃ＋ｌ’ＣｉＣおける各放電電流での終止電圧２．８Ｖ
までの放電持続時間の関係を示ｔ０
第１図から明らかなように本発明品が従来品より放電持
続時間が長い。第２図は雰囲気温度２０″Ｃ±１°Ｃに
おける充放電サイクル寿命特性を示すもので、充電条件
は４．９Ｖの定電圧充電で、カット電流が０３０．充電
時間が１５時間である。また放電条件はＩＣの定電流放
電で、終止電圧２．８Ｖまで放電する。第２図からも明
らかなように本発明品が従来品より寿命が長い。Figures 1 and 2 show a comparison of battery characteristics between a sealed lead-acid battery (product of the present invention) obtained by the manufacturing method of the present invention and a sealed lead-acid battery (conventional product) obtained by the conventional manufacturing method. . All batteries are 4V-4Ah, and the ambient temperature in Figure 1 is 20'.
Final voltage 2.8V at each discharge current in C+l'CiC
As is clear from FIG. 1, the discharge duration of the product of the present invention is longer than that of the conventional product. Figure 2 shows the charge/discharge cycle life characteristics at an ambient temperature of 20''C±1°C, and the charging conditions are constant voltage charging at 4.9V, cut current at 030V, and charging time at 15 hours. The discharge condition is constant current discharge of the IC, and the discharge reaches a final voltage of 2.8 V.As is clear from FIG. 2, the product of the present invention has a longer lifespan than the conventional product.
発明の効果
以上のように本発明によれば、密閉型鉛蓄電池の電槽化
成におい〔、正極板表面にｐｂｓｏ。Effects of the Invention As described above, according to the present invention, in the case formation of a sealed lead-acid battery, PBSO is applied to the surface of the positive electrode plate.
の自戒を生じることなく化成され、従っＣ正極板表面の
ｐｂｓｏ、の自戒をなくすための過充電の必要も少ない
ので、充電費の節減が可能となる。また放電持続時間も
従来品より長くなり、寿命特性も向上する等工業的価値
様めて大なるものである。It is chemically formed without causing any self-discipline, and therefore there is little need for overcharging to eliminate the self-discipline of PBSO on the surface of the C positive electrode plate, making it possible to reduce charging costs. Furthermore, the discharge duration is longer than that of conventional products, and the life characteristics are also improved, so it has great industrial value.
第１図は本発明品と従来品との各放を電流での持続時間
の比較特性曲線図、第２図は同じく充放電サイクル寿命
の比較特性曲線図である。FIG. 1 is a comparative characteristic curve diagram of the duration of each discharge at current between the product of the present invention and a conventional product, and FIG. 2 is a comparative characteristic curve diagram of the charge/discharge cycle life.
Claims (1)
製造法において、ペーストを充填した後で酸化剤の硫酸
溶液により浸漬あるいは塗布処理し熟成乾燥した未化成
正極板と、未化成負極板とを用いて極板群を組立て、該
極板群を電槽内に収納した後、該極板群に電解液を含浸
せしめて電槽化成を行なうことを特徴とする密閉型鉛蓄
電池の製造法。In a method for manufacturing a sealed lead-acid battery consisting of a positive electrode plate, a negative electrode plate, and a retainer, an unformed positive electrode plate, which is filled with a paste, dipped or coated in a sulfuric acid solution containing an oxidizing agent, and then aged and dried, and an unformed negative electrode plate are used. 1. A method for manufacturing a sealed lead-acid battery, which comprises: assembling a group of electrode plates using a battery, storing the group of electrode plates in a battery case, and then impregnating the group of electrode plates with an electrolyte to form a battery case.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60284981A JPS62145664A (en) | 1985-12-18 | 1985-12-18 | Manufacture of sealed lead storage battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60284981A JPS62145664A (en) | 1985-12-18 | 1985-12-18 | Manufacture of sealed lead storage battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62145664A true JPS62145664A (en) | 1987-06-29 |
Family
ID=17685583
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60284981A Pending JPS62145664A (en) | 1985-12-18 | 1985-12-18 | Manufacture of sealed lead storage battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62145664A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01167952A (en) * | 1987-12-24 | 1989-07-03 | Shin Kobe Electric Mach Co Ltd | Manufacture of lead-acid battery |
| US5149606A (en) * | 1991-03-12 | 1992-09-22 | Globe-Union Inc. | Method of treating a battery electrode with persulfate |
| RU2693047C1 (en) * | 2018-02-08 | 2019-07-01 | Общество с ограниченной ответственностью "Аккумулятор инноваций" | Method for manufacturing sealed lead accumulator |
-
1985
- 1985-12-18 JP JP60284981A patent/JPS62145664A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01167952A (en) * | 1987-12-24 | 1989-07-03 | Shin Kobe Electric Mach Co Ltd | Manufacture of lead-acid battery |
| US5149606A (en) * | 1991-03-12 | 1992-09-22 | Globe-Union Inc. | Method of treating a battery electrode with persulfate |
| RU2693047C1 (en) * | 2018-02-08 | 2019-07-01 | Общество с ограниченной ответственностью "Аккумулятор инноваций" | Method for manufacturing sealed lead accumulator |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI459610B (en) | Flooded lead-acid battery and method of making the same | |
| US3870563A (en) | Hermetically sealed storage battery | |
| Hullmeine et al. | Effect of previous charge/discharge history on the capacity of the PbO2/PbSO4 electrode: the hysteresis or memory effect | |
| JPS62145664A (en) | Manufacture of sealed lead storage battery | |
| US4131515A (en) | Method for making positive electrode for lead-sulfuric acid storage battery | |
| US4230779A (en) | Battery plate | |
| JP2002008644A (en) | Production method of positive electrode plate for lead storage battery | |
| JPS6216506B2 (en) | ||
| JPH0793135B2 (en) | Lead acid battery and manufacturing method thereof | |
| JPS58115775A (en) | Lead-acid battery | |
| JPS61142668A (en) | Manufacture of lead storage battery | |
| CS214885B2 (en) | Lead accumulator cell and method of making the said | |
| JPS59138062A (en) | Lead storage battery | |
| JP2773311B2 (en) | Manufacturing method of sealed lead-acid battery | |
| US4295940A (en) | Method for battery plate | |
| JPS6386258A (en) | Manufacture of lead acid battery | |
| JPS607069A (en) | Manufacture of sealed lead-acid battery | |
| JPH05151987A (en) | Manufacture of sealed type lead acid battery | |
| JPS607059A (en) | Manufacture of positive plate for sealed lead storage battery | |
| JP2541355B2 (en) | Method for manufacturing electrode plate for lead acid battery | |
| JPH04345756A (en) | Manufacture of lead storage battery electrode | |
| JPS6050861A (en) | Positive plate for quick use type lead storage battery | |
| JPH053709B2 (en) | ||
| JPS61198574A (en) | Lead storage battery | |
| JPH01117270A (en) | Manufacture of anode plate of lead-acid battery |