JPS62130874A - Copying sheet for prevention of unjust act - Google Patents

Copying sheet for prevention of unjust act

Info

Publication number
JPS62130874A
JPS62130874A JP27233585A JP27233585A JPS62130874A JP S62130874 A JPS62130874 A JP S62130874A JP 27233585 A JP27233585 A JP 27233585A JP 27233585 A JP27233585 A JP 27233585A JP S62130874 A JPS62130874 A JP S62130874A
Authority
JP
Japan
Prior art keywords
carbon
sheet
ink
read
rays
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP27233585A
Other languages
Japanese (ja)
Inventor
Naoyasu Nagai
永井 直保
Tsutomu Matsuda
努 松田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NAGAI INSATSU KOGYO KK
Naigai Carbon Ink Co Ltd
Original Assignee
NAGAI INSATSU KOGYO KK
Naigai Carbon Ink Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NAGAI INSATSU KOGYO KK, Naigai Carbon Ink Co Ltd filed Critical NAGAI INSATSU KOGYO KK
Priority to JP27233585A priority Critical patent/JPS62130874A/en
Publication of JPS62130874A publication Critical patent/JPS62130874A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/14Security printing

Landscapes

  • Printing Methods (AREA)
  • Duplication Or Marking (AREA)

Abstract

PURPOSE:To enable a confidential text or an ID number to be read only when X rays or the like are used, by providing a copying sheet comprising a carbon transfer sheet having a carbon ink layer and a carbon receiving sheet for forming ink images which can be read only on a video system using soft X rays or supersoft X rays. CONSTITUTION:A mixture of 40 parts of calcium tungstate and 10 parts of liquid paraffin is kneaded by a triple roll mill, and then 5 parts of paraffin wax and 1 part of carnauba wax are added to the kneaded mixture, followed by agitating sufficiently while heating to 100 deg.C to prepare a carbon ink. While heating the carbon ink to 90 deg.C, the ink is applied to a copying paper by a carbon printing press to obtain a carbon transfer sheet. On the other hand, a carbon receiving sheet is obtained by subjecting a woodfree paper to printing and embossing. When the surface of the carbon receiving sheet printed with concealed characters which can not be read at all by the naked dyes is set on a SOFTEX video system, the characters can be clearly read.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は軟X線、又は超軟X線ににる映像システムにお
いてのみ判読可能な、潜在的に隠蔽された文字や記号等
を複写する複写ノートに関する。
[Detailed Description of the Invention] (Industrial Application Field) The present invention reproduces potentially hidden characters, symbols, etc. that are readable only with an imaging system using soft or ultra-soft X-rays. Concerning photocopy notes.

(従来技術およびその問題点) 多様化された現在社会の種々の分野においては、極秘文
、暗号、キャッンユカード登録番号等、他人や特定の関
係者以外に判読知得されては困るような秘密情報を特に
複写して伝達する必要に迫られる場合が非常に多い。特
に、暗証番号に基づいて金銭の移動が容易になされる昨
今、暗証番号知得による犯罪を防止するために極めて少
数の人間のみが前記暗証番号を管理することができる警
防を整えることが要請されている。
(Prior art and its problems) In various fields of today's diversified society, there are documents that cannot be read and obtained by others or other than specific parties, such as confidential texts, codes, and Can-U card registration numbers. Very often there is a need to transmit confidential information, especially by copying it. In particular, in these days when money is easily transferred based on PIN numbers, there is a need for a security system that allows only a very small number of people to manage the PIN numbers in order to prevent crimes caused by the acquisition of PIN numbers. ing.

そのために、例えばX線等を用いた場合にのみ前記秘密
文章、あるいは暗証番号が判読できるシステムが煮えら
れるが、実際にこれを実施するには解決すべき困難点、
例えばX線による破曝を避けること等の問題が存在する
For this purpose, a system is being developed that allows the secret text or password to be read only by using X-rays, etc., but there are some difficulties that need to be resolved in order to actually implement this system.
For example, there are problems such as avoiding radiation exposure due to X-rays.

(発明の目的) 本発明はこのような要請に簡便かつ的確に応えるために
なされたものであって、その要旨は軟X線又は超軟X線
による映像システムにおいてのみ判読可能となるカーボ
ンインキ層を有するカーボン転写シートおよびカーボン
受理ノートから成る不正防止用複写ソートに存する。
(Object of the Invention) The present invention has been made to easily and accurately meet such demands, and its gist is to provide a carbon ink layer that can be read only in an imaging system using soft X-rays or ultra-soft X-rays. A tamper-evident copying sort consisting of a carbon transfer sheet and a carbon acceptance note with a

(発明の内容) 本発明にいう炊X線、超軟X線とは紫外線とγ線の間に
波長域を持つX線のうち紫外線に近い波長域を持つもの
を云う。
(Contents of the Invention) The hot X-rays and ultra-soft X-rays used in the present invention refer to X-rays that have a wavelength range close to ultraviolet rays among the X-rays that have a wavelength range between ultraviolet rays and gamma rays.

この2つのX線は被曝の危険が全く無く、容易かつ簡便
に扱え、しかも装置も簡単であるため、非常に優れたも
のである。
These two X-rays are extremely excellent because they have no risk of exposure, are easy and convenient to use, and have simple equipment.

しかしながら、この種のX線を用いた場合、通常考えら
れるバリウム化合物、鉄微粉末等では、通常のカーボン
インキ層への添加量で判読が難しい事が判明した。従っ
て、種々の化合物から、本発明者等は種々の金属および
金属化合物を検討した結果、密度が10以上、特に11
〜20の金属の化合物が極めて上記2種のX線に感度が
高く、しかも毒性も無く、インキ化容易である事が判っ
た。このような金属化合物の例としては、タングステン
酸カルンウム、タングステン酸マグネノウム、タングス
テン酸カリウム、タングステン酸銀−酸化マグネシウム
、タングステン酸等がまたはこれらの混合物が例示され
る。
However, when this type of X-ray is used, it has been found that it is difficult to read barium compounds, iron fine powder, etc., which are usually considered, at the amount added to a normal carbon ink layer. Therefore, as a result of examining various metals and metal compounds among various compounds, the present inventors found that the density is 10 or more, especially 11.
It was found that compounds of ~20 metals have extremely high sensitivity to the above two types of X-rays, are not toxic, and can be easily made into inks. Examples of such metal compounds include carunium tungstate, magnesium tungstate, potassium tungstate, silver tungstate-magnesium oxide, tungstic acid, and mixtures thereof.

上記化合物のカーボンインキ中での含有量は40〜80
%が適正であり、含有量が40%より少なくなると軟X
線、超軟X線による映像システムの判読が不鮮明となり
、80%より多くなるとカーボンインキのインキ流動性
が悪くなり実用上問題がある。
The content of the above compound in the carbon ink is 40 to 80
% is appropriate, and if the content is less than 40%, it will be soft
If the amount exceeds 80%, the ink fluidity of the carbon ink deteriorates, which poses a practical problem.

上記化合物は通常融点的30−120℃のワックスまた
はワックス物質と配合してワックス型のカーボンインキ
として使用する。このようなワックスまたはワックス状
物質としてはカルナバワックス、モンタンワックス、オ
ーリキュリーワックス、ココナツツワックス、シュガケ
ーンワックス、キャンデリラワックス、ヘキストワック
ス(o :op、s等)、バリコワックス(WBポリワ
ックス等)、ポリエチレンワックス、酸化マイクロワッ
クス、パラフィンワックス等が例示される。
The above compound is usually blended with a wax or wax substance having a melting point of 30-120 DEG C. and used as a wax-type carbon ink. Such waxes or waxy substances include carnauba wax, montan wax, auriculie wax, coconut wax, sugar cane wax, candelilla wax, Hoechst wax (o: op, s, etc.), Varico wax (WB polywax, etc.) ), polyethylene wax, oxidized microwax, paraffin wax, etc.

以上のワックスと混合して得られるワックス型のカーボ
ンインキには油を適宜配合して可塑化させ転移性を向上
させることもできる添加油としては鉱物油、不乾性植物
油が有用である油の配合量は通常カーボンインキ全量の
約5〜50%にする。
The wax-type carbon ink obtained by mixing with the above wax can be appropriately blended with oil to plasticize it and improve transferability. Mineral oil and non-drying vegetable oil are useful as additive oils. The amount is usually about 5 to 50% of the total amount of carbon ink.

また、上記化合物の外に通常の着色顔料、例えばミロリ
ブルー、ンアニンブルー、レーキレッド、ペンヂノンエ
ロー、シアニングリーン等を添加してインキの隠蔽性を
高める事もできるが、この場合にはカーボン受理ソート
のカーボン受理部分に同色の迷彩模様を刷して文字等が
判読できないようにずろ必要がある。
Furthermore, in addition to the above compounds, it is also possible to add ordinary colored pigments such as Milori Blue, N'Anin Blue, Lake Red, Pendinone Yellow, Cyanine Green, etc. to improve the hiding properties of the ink. It is necessary to print a camouflage pattern of the same color on the part and offset it so that the letters etc. cannot be read.

本発明の転写シートは上記のカーボンインキをその融点
以下の温度、好ましくは融点よりも約LO°C高い温度
で溶融させて基材シート、例えば、紙、セロファン、プ
ラスチックフィルム等の片面に塗布またはスボゾト印刷
し直ちに冷却させて固化セットする所謂コールドセント のか一般的である。
The transfer sheet of the present invention can be prepared by melting the above-mentioned carbon ink at a temperature below its melting point, preferably at a temperature about LO°C higher than its melting point, and coating it on one side of a base sheet, such as paper, cellophane, plastic film, etc. It is common to use so-called cold cent printing, in which the material is printed in a vacuum and then immediately cooled to solidify and set.

このよう、にして得られるカーボン転写シートはカーボ
ン受理シートと組み合わせて使用される。
The carbon transfer sheet thus obtained is used in combination with a carbon receiving sheet.

本発明に用いるカーホン受理シートは、カーホン転写ソ
ートに加わる圧力によって転移するカーボンインキを潜
在的に隠蔽性を向上する等の利点が得られる。カーボン
受理シートの隠蔽部分はエンボス加工を施して、平圧に
よる筆記文字の判読を不可能にするのが好ましい。
The carphone receiving sheet used in the present invention has advantages such as potentially improving the ability to hide carbon ink transferred by pressure applied to carphone transfer sorting. Preferably, the concealed portion of the carbon receiving sheet is embossed to make it impossible to read the written characters under flat pressure.

前記のカーボン転写シートのカーボンインキ層にカーボ
ン受理シートを重ね、転写シート側から筆記圧やタイプ
ライタ−打圧等の圧力を加えることによって加圧部に対
応するカーボンインキ層はカーボン受理シート上に潜在
的に隠蔽された状態(肉眼では判読不可能な状@)で転
写され、この受理シートを軟X線、超軟X線映像システ
ム(例えばソフテックス株式会社製の50FT映像シス
テム)により判読する事ができる。
A carbon receiving sheet is placed on the carbon ink layer of the carbon transfer sheet, and by applying pressure such as writing pressure or typewriter pressure from the transfer sheet side, the carbon ink layer corresponding to the pressure area is placed on the carbon receiving sheet. It is transferred in a potentially hidden state (unreadable to the naked eye), and this receipt sheet is read using a soft X-ray or ultra-soft X-ray imaging system (for example, the 50FT imaging system manufactured by Softex Co., Ltd.). I can do things.

(発明の効果) 本発明による複写シートは秘密情報を簡便にしから適確
に伝達できるので各種分野において非常に有用なものと
なる。
(Effects of the Invention) The copy sheet according to the present invention is extremely useful in various fields because confidential information can be transmitted easily and accurately.

(実施例) 以下、本発明を実施例によって説明する。実施例中、「
部」とあるのは重量部を表す。
(Examples) Hereinafter, the present invention will be explained by examples. In the examples, “
"Parts" means parts by weight.

実施例1 タングステン酸カルシウム40部と流動パラフィン10
部を3本ロールを用いて練肉し、これにパラフィンワッ
クス5部とカルナウバワックス1部を加え+00°Cで
充分加熱攪拌してカーボンインキを調整した。
Example 1 40 parts of calcium tungstate and 10 parts of liquid paraffin
5 parts of paraffin wax and 1 part of carnauba wax were added to the mixture and thoroughly heated and stirred at +00°C to prepare a carbon ink.

このカーボンインキを90°Cに加熱しながらカーボン
印刷機を用いて複写用紙上に印刷しカーボン転写ソート
を得た。
This carbon ink was heated to 90° C. and printed on copy paper using a carbon printing machine to obtain a carbon transfer sort.

一方、上質紙(I 05 g/m”)に常套手段により
、印刷エンボス加工されたカーボン受理ソートを得た。
On the other hand, a printed embossed carbon receiving sort was obtained on high-quality paper (I 05 g/m'') by conventional means.

前記のカーボン転写シートのカーボンインキ印刷面にカ
ーボン受理シートを重ねカーボン転写シート上からボー
ルペンで筆記してカーボン受理シート上に肉眼では全く
判読できない文字を印字した。隠蔽文字を印字した紙面
を5OFTEX映像ンステム(ソフテノクス(朱式会社
製)にかけると明確に1′11読てきた。
A carbon receiving sheet was placed on the carbon ink printed surface of the carbon transfer sheet, and characters were written on the carbon transfer sheet with a ballpoint pen to print characters that were completely indecipherable to the naked eye on the carbon receiving sheet. When I ran the paper with hidden characters printed on the 5OFTEX video system (Softenox (manufactured by Shushiki Company)), it read clearly 1'11.

実施例2 タングステン酸40部、ノアエンプル−1部、ヒマi+
I+ I O部、カルナウバワックス3部、モノクンワ
ックス3部と共にアトライターにて100°Cで加熱攪
拌してカーホンインキを調整した。
Example 2 40 parts of tungstic acid, 1 part of Noah Empuru, castor i+
A carphone ink was prepared by heating and stirring at 100°C in an attritor with parts I+IO, 3 parts of carnauba wax, and 3 parts of Monokun wax.

このカーボンインキを実施例1と同様に印刷してカーボ
ン転写ノートを得た。
This carbon ink was printed in the same manner as in Example 1 to obtain a carbon transfer note.

一方、上質紙についても実施例1と同様にしてカーボン
受理シートを得た。
On the other hand, a carbon-receiving sheet was also obtained using high-quality paper in the same manner as in Example 1.

但し、迷彩模様の印刷についてはカーホンインキの色相
と同色のインキを使用した。
However, for printing the camouflage pattern, ink of the same color as the carphone ink was used.

実施例1と同様にして筆記したところ、カーボンインキ
、迷彩模様共に同色のため肉眼にては全く判読できなか
っfこが、5oFTEX映象ノステムにかけろと明確に
判読できた。
When written in the same manner as in Example 1, the carbon ink and camouflage pattern were both the same color, so it was completely unreadable to the naked eye, but it was clearly legible when applied to the 5oFTEX image system.

比較例1 ケイ酸バリウム40部とをシアーシブルー1部、流動パ
ラフィンIO部パラフィンワックス5部バリコワックス
(WB−15)I!’I!と共にアトライターにて10
0°Cで充分加熱攪拌してカーボンインキを調整した。
Comparative Example 1 40 parts of barium silicate, 1 part of Shear Si Blue, 1 part of liquid paraffin, 5 parts of paraffin wax, Varicowax (WB-15) I! 'I! At Atlighter with 10
Carbon ink was prepared by thoroughly heating and stirring at 0°C.

このカーボンインキを実施例Iと同様に印11i11 
Lでカーボン転写シートを得た。
This carbon ink was applied to marks 11i11 in the same manner as in Example I.
A carbon transfer sheet was obtained using L.

一方、上質紙についてら実施例Iと同様にしてカーボン
受理ソートを得た。但し迷彩模様の印刷についてはカー
ホンインキの色相と同色のインキを使用した。
On the other hand, carbon-receiving sorting was obtained for high-quality paper in the same manner as in Example I. However, for printing the camouflage pattern, ink of the same color as the carphone ink was used.

実施例1と同様にして筆記したところ、カーボンインキ
、迷彩模様共に同色のため肉眼にては、全く′lJI読
できなかった。また、SOF’TEX映像ノステムにか
けて乙明確に判読できなかった。
When written in the same manner as in Example 1, the carbon ink and the camouflage pattern were both the same color, so the 'lJI could not be read with the naked eye. Also, the SOF'TEX video system was not clearly readable.

Claims (1)

【特許請求の範囲】 1、軟X線、超軟X線による映像システムにおいてのみ
判読可能となるカーボンインキ層を有するカーボン転写
シートおよびカーボン受理シートからなる不正防止用複
写シート。 2、カーボンインキ層に密度10以上を有する金属の化
合物を40〜80%含有することを特徴とする第1項記
載の不正防止用複写シート。 3、密度10以上を有する金属の化合物がタングステン
化合物である第2項記載の不正防止用複合シート。 4、カーボン受理シートのカーボン受理部分に迷彩模様
を印刷し、エンボス加工を施した第1項記載の不正防止
用複写シート。
[Claims] 1. A tamper-proof copying sheet comprising a carbon transfer sheet and a carbon receiving sheet, each having a carbon ink layer that is readable only in a soft X-ray or ultra-soft X-ray imaging system. 2. The anti-tamper copying sheet according to item 1, wherein the carbon ink layer contains 40 to 80% of a metal compound having a density of 10 or more. 3. The composite sheet for fraud prevention according to item 2, wherein the metal compound having a density of 10 or more is a tungsten compound. 4. The copying sheet for fraud prevention according to item 1, wherein a camouflage pattern is printed and embossed on the carbon receiving portion of the carbon receiving sheet.
JP27233585A 1985-12-02 1985-12-02 Copying sheet for prevention of unjust act Pending JPS62130874A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP27233585A JPS62130874A (en) 1985-12-02 1985-12-02 Copying sheet for prevention of unjust act

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP27233585A JPS62130874A (en) 1985-12-02 1985-12-02 Copying sheet for prevention of unjust act

Publications (1)

Publication Number Publication Date
JPS62130874A true JPS62130874A (en) 1987-06-13

Family

ID=17512456

Family Applications (1)

Application Number Title Priority Date Filing Date
JP27233585A Pending JPS62130874A (en) 1985-12-02 1985-12-02 Copying sheet for prevention of unjust act

Country Status (1)

Country Link
JP (1) JPS62130874A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002129076A (en) * 2000-10-30 2002-05-09 Toppan Forms Co Ltd Back carbon ink, and tamperproof pressure-sensitive copying sheet using the same
JP2002129077A (en) * 2000-10-30 2002-05-09 Toppan Forms Co Ltd Back carbon ink, and tamperproof pressure-sensitive copying sheet using the same
US7960022B2 (en) 2000-09-18 2011-06-14 Yupo Corporation Forgery-preventing film

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS491301U (en) * 1972-04-04 1974-01-08
JPS5815068A (en) * 1981-07-15 1983-01-28 本荘ケミカル株式会社 Manufacture of electroconductive zinc oxide
JPS58155991A (en) * 1982-03-12 1983-09-16 Nagai Insatsu Kogyo Kk Copy sheet
JPS597871B2 (en) * 1978-11-29 1984-02-21 オムニシエル・インコ−ポレ−テッド release valve device
JPS5998892A (en) * 1982-11-29 1984-06-07 Dainippon Printing Co Ltd Ink for pressure sensitive duplication

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS491301U (en) * 1972-04-04 1974-01-08
JPS597871B2 (en) * 1978-11-29 1984-02-21 オムニシエル・インコ−ポレ−テッド release valve device
JPS5815068A (en) * 1981-07-15 1983-01-28 本荘ケミカル株式会社 Manufacture of electroconductive zinc oxide
JPS58155991A (en) * 1982-03-12 1983-09-16 Nagai Insatsu Kogyo Kk Copy sheet
JPS5998892A (en) * 1982-11-29 1984-06-07 Dainippon Printing Co Ltd Ink for pressure sensitive duplication

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7960022B2 (en) 2000-09-18 2011-06-14 Yupo Corporation Forgery-preventing film
JP2002129076A (en) * 2000-10-30 2002-05-09 Toppan Forms Co Ltd Back carbon ink, and tamperproof pressure-sensitive copying sheet using the same
JP2002129077A (en) * 2000-10-30 2002-05-09 Toppan Forms Co Ltd Back carbon ink, and tamperproof pressure-sensitive copying sheet using the same
JP4714330B2 (en) * 2000-10-30 2011-06-29 トッパン・フォームズ株式会社 Pressure sensitive copy sheet for preventing tampering using back carbon ink
JP4714331B2 (en) * 2000-10-30 2011-06-29 トッパン・フォームズ株式会社 Pressure sensitive copy sheet for preventing tampering using back carbon ink

Similar Documents

Publication Publication Date Title
JPS62501346A (en) Thermal transfer ink formulations and media
US4592946A (en) Thermal ink transfer recording
JPH09142031A (en) Thermal transfer recording material
CA2638581C (en) Improved invisible ink and scratch pad
EP0326303B1 (en) Improved security for images formed by impact based systems
US4510206A (en) Thermal ink transfer recording
JPS62130874A (en) Copying sheet for prevention of unjust act
US3406137A (en) Imaging material
US3062676A (en) Smudge-resistant pressure-sensitive transfer element for placing smudgeresistant marks
US5888644A (en) Thermal transfer recording material
DE1671632B2 (en) TRANSFER SHEET
JP5556311B2 (en) Sublimation thermal transfer method and information leakage prevention system
JPS5924693A (en) Ink for transfer type heat sensitive sheet
US3436234A (en) Duplicating ink
JPH0530196B2 (en)
JPH05286272A (en) Thermal transfer ink
JPH06297889A (en) Securities and the like
US3389011A (en) Heat-sensitive transfer sheet for producing a thermographic facsimile copy
JPS62111800A (en) Heat-sensitive transfer sheet
JP2634050B2 (en) Thermal transfer material
JPS5971896A (en) Multi-gradation thermosensitive transfer recording medium
JPS63290789A (en) Thermal transfer material
JP3073198B1 (en) Counterfeit prevention method
JPH06191162A (en) Heat transfer material
JPS6270088A (en) Thermal transfer ink