JPS6143394B2 - - Google Patents

Info

Publication number: JPS6143394B2
Authority: JP; Japan
Prior art keywords: weight; parts; aqueous suspension; particle size; microspheres
Prior art date: 1983-03-03
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP58033843A

Other languages

English (en)

Japanese (ja)

Other versions

JPS59159869A (ja

Inventor

Tooru Kinoshita

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Individual

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-03-03

Filing date

1983-03-03

Publication date

1986-09-27

1983-03-03 Application filed by Individual filed Critical Individual

1983-03-03 Priority to JP3384383A priority Critical patent/JPS59159869A/ja

1984-09-10 Publication of JPS59159869A publication Critical patent/JPS59159869A/ja

1986-09-27 Publication of JPS6143394B2 publication Critical patent/JPS6143394B2/ja

Status Granted legal-status Critical Current

Links

239000002245 particle Substances 0.000 claims description 42
239000004005 microsphere Substances 0.000 claims description 31
239000007900 aqueous suspension Substances 0.000 claims description 29
239000000178 monomer Substances 0.000 claims description 24
238000010557 suspension polymerization reaction Methods 0.000 claims description 14
229920000642 polymer Polymers 0.000 claims description 13
238000006243 chemical reaction Methods 0.000 claims description 10
239000000203 mixture Substances 0.000 claims description 10
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 10
238000004519 manufacturing process Methods 0.000 claims description 9
239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 8
239000002998 adhesive polymer Substances 0.000 claims description 8
229920002554 vinyl polymer Polymers 0.000 claims description 8
239000000084 colloidal system Substances 0.000 claims description 6
230000001681 protective effect Effects 0.000 claims description 6
239000002253 acid Substances 0.000 claims description 5
239000005018 casein Substances 0.000 claims description 5
BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims description 5
235000021240 caseins Nutrition 0.000 claims description 5
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
125000005907 alkyl ester group Chemical group 0.000 claims description 3
125000000217 alkyl group Chemical group 0.000 claims description 3
239000012736 aqueous medium Substances 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 3
230000000379 polymerizing effect Effects 0.000 claims description 2
239000000853 adhesive Substances 0.000 description 28
230000001070 adhesive effect Effects 0.000 description 28
238000006116 polymerization reaction Methods 0.000 description 15
239000000725 suspension Substances 0.000 description 8
239000010419 fine particle Substances 0.000 description 7
238000000034 method Methods 0.000 description 7
239000011248 coating agent Substances 0.000 description 6
238000000576 coating method Methods 0.000 description 6
238000001704 evaporation Methods 0.000 description 6
230000008020 evaporation Effects 0.000 description 6
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 5
238000004873 anchoring Methods 0.000 description 5
229920001577 copolymer Polymers 0.000 description 5
239000000839 emulsion Substances 0.000 description 5
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
239000003945 anionic surfactant Substances 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 4
230000000704 physical effect Effects 0.000 description 4
239000003381 stabilizer Substances 0.000 description 4
238000003860 storage Methods 0.000 description 4
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 3
239000000123 paper Substances 0.000 description 3
238000003756 stirring Methods 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 2
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
239000004342 Benzoyl peroxide Substances 0.000 description 2
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
235000019400 benzoyl peroxide Nutrition 0.000 description 2
239000001913 cellulose Substances 0.000 description 2
LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 2
238000001035 drying Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000009775 high-speed stirring Methods 0.000 description 2
239000011259 mixed solution Substances 0.000 description 2
239000002736 nonionic surfactant Substances 0.000 description 2
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
229920002401 polyacrylamide Polymers 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
238000004062 sedimentation Methods 0.000 description 2
229910052709 silver Inorganic materials 0.000 description 2
239000004332 silver Substances 0.000 description 2
239000002904 solvent Substances 0.000 description 2
239000000758 substrate Substances 0.000 description 2
239000004094 surface-active agent Substances 0.000 description 2
LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 2
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 description 1
CUXGDKOCSSIRKK-UHFFFAOYSA-N 7-methyloctyl prop-2-enoate Chemical compound CC(C)CCCCCCOC(=O)C=C CUXGDKOCSSIRKK-UHFFFAOYSA-N 0.000 description 1
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
230000005653 Brownian motion process Effects 0.000 description 1
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
239000002202 Polyethylene glycol Chemical class 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
239000004480 active ingredient Substances 0.000 description 1
239000002390 adhesive tape Substances 0.000 description 1
230000002411 adverse Effects 0.000 description 1
239000000443 aerosol Substances 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000002280 amphoteric surfactant Substances 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
238000005537 brownian motion Methods 0.000 description 1
239000001768 carboxy methyl cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
229920006184 cellulose methylcellulose Polymers 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000007547 defect Effects 0.000 description 1
229940061607 dibasic sodium phosphate Drugs 0.000 description 1
BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000009826 distribution Methods 0.000 description 1
GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
238000010556 emulsion polymerization method Methods 0.000 description 1
UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000011521 glass Substances 0.000 description 1
150000002334 glycols Chemical class 0.000 description 1
-1 hydroxypropyl Chemical group 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229920000831 ionic polymer Polymers 0.000 description 1
PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
230000007774 longterm Effects 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
239000000463 material Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
238000002156 mixing Methods 0.000 description 1
OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 1
UTSYWKJYFPPRAP-UHFFFAOYSA-N n-(butoxymethyl)prop-2-enamide Chemical compound CCCCOCNC(=O)C=C UTSYWKJYFPPRAP-UHFFFAOYSA-N 0.000 description 1
ULYOZOPEFCQZHH-UHFFFAOYSA-N n-(methoxymethyl)prop-2-enamide Chemical compound COCNC(=O)C=C ULYOZOPEFCQZHH-UHFFFAOYSA-N 0.000 description 1
238000005580 one pot reaction Methods 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920001223 polyethylene glycol Chemical class 0.000 description 1
239000003505 polymerization initiator Substances 0.000 description 1
239000001267 polyvinylpyrrolidone Substances 0.000 description 1
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
238000010926 purge Methods 0.000 description 1
238000010992 reflux Methods 0.000 description 1
239000013049 sediment Substances 0.000 description 1
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000004834 spray adhesive Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
238000005406 washing Methods 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)
Adhesives Or Adhesive Processes (AREA)

JP3384383A 1983-03-03 1983-03-03 再剥離性粘着剤組成物およびその製造法 Granted JPS59159869A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP3384383A JPS59159869A (ja)	1983-03-03	1983-03-03	再剥離性粘着剤組成物およびその製造法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP3384383A JPS59159869A (ja)	1983-03-03	1983-03-03	再剥離性粘着剤組成物およびその製造法

Publications (2)

Publication Number	Publication Date
JPS59159869A JPS59159869A (ja)	1984-09-10
JPS6143394B2 true JPS6143394B2 (zh)	1986-09-27

Family

ID=12397771

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP3384383A Granted JPS59159869A (ja)	1983-03-03	1983-03-03	再剥離性粘着剤組成物およびその製造法

Country Status (1)

Country	Link
JP (1)	JPS59159869A (zh)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS61152779A (ja) *	1984-12-27	1986-07-11	Toyo Ink Mfg Co Ltd	再剥離型粘着剤組成物
JPH0684491B2 (ja) *	1985-05-15	1994-10-26	ニチバン株式会社	再剥離性粘着剤組成物
JPH0684490B2 (ja) *	1985-05-15	1994-10-26	ニチバン株式会社	再剥離性粘着剤組成物

Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS502736A (zh) *	1973-04-06	1975-01-13

1983
- 1983-03-03 JP JP3384383A patent/JPS59159869A/ja active Granted

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS502736A (zh) *	1973-04-06	1975-01-13

Also Published As

Publication number	Publication date
JPS59159869A (ja)	1984-09-10

Publication	Publication Date	Title
US4656218A (en)	1987-04-07	Adhesive copolymer microspheres-containing aqueous suspension and method for producing the same
US4645783A (en)	1987-02-24	Adhesive copolymer microspheres-containing aqueous suspension and method for producing the same
TW416963B (en)	2001-01-01	Stabilized adhesive microspheres
EP0419020B1 (en)	1995-01-25	Pressure-sensitive adhesive comprising hollow tacky microspheres and macromonomer-containing binder copolymer
JP5346048B2 (ja)	2013-11-20	複合感圧接着性微小球
JP4130993B2 (ja)	2008-08-13	部分的に架橋された微小球
US4988567A (en)	1991-01-29	Hollow acid-free acrylate polymeric microspheres having multiple small voids
JPH04216888A (ja)	1992-08-06	中空多孔性アシッドフリーアクリレート系高分子量微小球
JPH02194079A (ja)	1990-07-31	中空のアクリレートポリマー微小球およびその製造方法
JPH04227672A (ja)	1992-08-17	粘着性固体微小球とマクロモノマー含有バインダーコポリマーを含有する感圧接着剤
EP0797644A1 (en)	1997-10-01	Removable pressure sensitive adhesive and article
JPS61261382A (ja)	1986-11-19	再剥離性粘着剤組成物
JPH0339521B2 (zh)	1991-06-14
JP2000281999A (ja)	2000-10-10	再剥離型感圧接着剤組成物
JP2610616B2 (ja)	1997-05-14	水分散型感圧性接着剤組成物
JPS6143394B2 (zh)	1986-09-27
JPH0527669B2 (zh)	1993-04-21
JP2924695B2 (ja)	1999-07-26	水分散型アクリル系粘着剤組成物を塗工する粘着製品の製造方法
JPS6011569A (ja)	1985-01-21	再剥離性粘着剤組成物およびその製造法
JPS5822492B2 (ja)	1983-05-09	感圧接着剤
JPS63260973A (ja)	1988-10-27	微球状感圧性接着剤の製造方法
JPS6149350B2 (zh)	1986-10-29
JPH0623364B2 (ja)	1994-03-30	水分散型感圧性接着剤組成物
JPH0352981A (ja)	1991-03-07	接着剤組成物
JPH0579272B2 (zh)	1993-11-01