JPH0554868B2 - - Google Patents
Info
- Publication number
- JPH0554868B2 JPH0554868B2 JP60184775A JP18477585A JPH0554868B2 JP H0554868 B2 JPH0554868 B2 JP H0554868B2 JP 60184775 A JP60184775 A JP 60184775A JP 18477585 A JP18477585 A JP 18477585A JP H0554868 B2 JPH0554868 B2 JP H0554868B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- polyoxyalkylene
- silicone oil
- modified
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920002545 silicone oil Polymers 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 13
- 229920001296 polysiloxane Polymers 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000002734 clay mineral Substances 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 125000005375 organosiloxane group Polymers 0.000 claims 1
- 230000008719 thickening Effects 0.000 description 11
- 239000002537 cosmetic Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000001993 wax Substances 0.000 description 5
- 239000006071 cream Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- -1 octadecyldimethylbenzylammonium salt-modified montmorillonite Chemical class 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- 206010042496 Sunburn Diseases 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000003676 hair preparation Substances 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 150000002892 organic cations Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/042—Gels
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Dermatology (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Medicinal Preparation (AREA)
Description
［産業上の利用分野］
本発明は安定性、使用性に優れるシリコンオイ
ルを含むゲル組成物に関する。
［従来の技術］
従来、シリコンオイルはさまざまな製品に使用
されている。特に化粧料においては、シリコンオ
イルがなめらかな使用性を持ち揆水性に優れてお
り、また揮散性シリコンオイルを配合とすると当
初のびがよく且つ塗布にともなつてシリコンオイ
ルが揮散してしまうので塗布後の化粧くずれが少
ないメーキヤツプ化粧料を製造することができる
ことから、のびのよい使用感を求められるフエー
シヤル化粧料や水はじきの性能を要求されるハン
ドクリームや頭髪化粧料あるいはまたメーキヤツ
プ化粧料などに配合が期待されてきた。また、シ
リコンオイルは皮膚安全性が高いという化粧料原
料としての条件も備えている。
［発明が解決しようとする問題点］
しかしながら、シリコンオイルは安定な増粘系
を得るのが非常に困難であるという欠点を有して
おり、強く要望されているにもかかわらず、この
ものを多量に配合し且つ適当な粘度を有する組成
物は得られていない。
これまで、安全性良好なシリコンオイルの増粘
系を得るためにはシリコンオイルをワツクス類と
ともに固化する方法や、シリカあるいは親油化処
理したシリカで増粘するなどの方法がとられてき
た。しかしながら、ワツクス類とともに固化する
方法はのびが重くべたつくといつた使用性上の欠
点や、流動性がないため応用できる範囲が限られ
ている。また、シリカで増粘する方法は経時での
安定性が悪く、使用前によく振ることが必須であ
り好ましくない。
［問題点を解決するための手段］
本発明者らは、こうした事情にかんがみ、シリ
コンオイルの増粘法について鋭意研究を重ねた結
果、シリコンオイルに特定のシリコン化合物と有
機変性粘土鉱物と水とを特定量配合することによ
り、任意の粘度を有する経時安定性及び使用性が
良好なゲル組成物が得られることを見出し、この
知見に基づいて本発明を完成するに至つた。
すなわち、本発明は、シリコンオイル、一般式
（）、（）または（）で示されるポリオキシ
アルキレン変性オルガノポリシロキサンの一種ま
たは二種以上、有機変性粘土鉱物ならびに水を配
合することを特徴とするシリコンオイルを含むゲ
ル組成物を提供するものである。
｛一般式（）、（）、（）中、Ｒはメチル基ま
たは一部がフエニル基、R′は水素または炭素数
１〜12のアルキル基、ｐは１〜５の数、ｑは２〜
３の数、ｘ、ｍ、ｎは平均数でポリオキシアルキ
レン変性オルガノポリシロキサンが分子中にポリ
オキシアルキレン基を20重量％を超えてかつ40重
量％以下含有し且つ該ポリオキシアルキレン変性
オルガノポリシロキサンの粘度が25℃において５
〜3000センチトークスになるような数値を表す。｝
以下、本発明の構成について詳述する。
本発明で用いられるシリコンオイルは従来用い
られている周知のものを使用することができる。
たとえば、ジメチルポリシロキサン、メチルフエ
ニルポリシロキサン、オクタメチルシクロテトラ
シロキサン、デカメチルシクロペンタシロキサン
などが挙げられる。これらの中から一種又は二種
以上が任意に選択される。
配合量は通常本発明の組成物全量中の20〜90重
量％である。
本発明で用いられるポリオキシアルキレン変性
オルガノポリシロキサン（以下、ポリエーテル変
性シリコンと略記する）は前記一般式（）、
（）または（）で表されるものであり、これ
らのうちの任意の一種又は二種以上が選ばれて用
いられる。
本発明の目的に合致した効果、すなわち経時安
定性及び使用性の良好なシリコン増粘効果を満足
せしめるためには、ポリエーテル変性シリコンは
ポリオキシアルキレン基をその分子量に対して20
〜40重量％（20重量％含まず）の割合で含有し且
つ25℃においてそのもの自体の粘土が５〜3000セ
ンチトークスの範囲に存するとよい。ポリエーテ
ル変性シリコンの粘土が５センチストークス未満
では増粘効果が十分でなく、3000センチストーク
スを越えると使用感がべたつき好ましくない。
本発明のゲル組成物に対するポリエーテル変性
シリコンの配合量は全量中の0.1から30重量％の
範囲で選択されるが、好ましくは0.2〜25重量％
である。0.1重量％未満では増粘効果が十分でな
く経時安定性も流い、30重量％を越えるとべたつ
きが感じられ、また化粧もちも悪くなる。
本発明で用いられる有機変性粘土鉱物は粘土鉱
物の結晶層間に介在する変換性カチオンを有機極
性化合物や有機カチオンで置換したものであり、
たとえば、ジオクタデシルジメチルアンモニウム
変換性モンモリロナイト、オクタデシルジメチル
ベンジルアンモニウム塩変性モンモリロナイト、
ジヘキサデシルジメチルアンモニウム塩変性モン
モリロナイトなどが挙げられる。これらの中から
一種または二種以上が任意に選択される。
配合量は本発明のゲル組成物全量中の0.1〜15
重量％の範囲で選択されるが、好ましくは0.2〜
10重量％である。0.1重量％未満では増粘効果が
十分でなく経時安定性も悪い。15重量％を越える
とのびが重くなり使用性が悪くなる。
本発明における水の配合量はゲル組成物全量中
の0.2〜80重量％の範囲で選択されるが、好まし
くは0.5〜60重量％である。0.2重量％未満では増
粘効果が十分でなく経時安定性も悪い。80重量％
を越えるとのびが重くなり好ましくない。
本発明のシリコン増粘組成物を応用した化粧料
は、上記の必須成分に加えて、必要に応じてワツ
クス、油脂、保湿剤、顔料、粉末、樹脂、香料、
防腐剤等が配合される。
なお、さらにエタノール、イソプロピルアルコ
ール等の低級アルコールやプロピレングリコー
ル、ジプロピレングリコール、１，３−ブチレン
グリコール等のグリコール類を組成物全量に対し
て0.1〜10重量％加えるとさらに増粘し安定性を
向上させることができる。
［発明の効果］
本発明のシリコンオイルを含むゲル組成物は経
時安定性が良好で且つ使用に際してはのびがよく
てべたつきがない良好な使用感触を有し、耐水性
や経時の持ちにも優れたゲル組成物である。
また、粘度すなわち流動性を自由にコントロー
ルできるため、化粧料をはじめ、医薬品の基剤や
自動車ワツクス、家具ワツクスなど広い範囲にわ
たつて使用することができる。
［実施例］
次に実施例によつて本発明をさらに詳細に説明
する。本発明はこれにより限定されるものではな
い。配合量は重量％である。
なお、実施例および比較例の諸特製についての
試験法は次の通り行なつたものである。
(1) 安定性
サンプル管に試料を取り各温度条件に放置
し、分離度で評価（１週間後判定）。
評価基準
○：分離なし
△：1/5程度分離
×：2/3以上分離
(2) 粘度
ブルツクフイールド型粘度計にて測定（30
℃、１日後）。
(3) べたつきおよびのび
実使用試験による官能評価（パネル20名）。
評価基準
○：べたつきなし、のびが軽い。
△：ややべたつく、のびが普通。
×：べたつく、のびが重い。
[Industrial Application Field] The present invention relates to a gel composition containing silicone oil that is excellent in stability and usability. [Prior Art] Silicone oil has conventionally been used in various products. Particularly in cosmetics, silicone oil is smooth to use and has excellent water-repellent properties, and when volatile silicone oil is added, it spreads well at first, but the silicone oil evaporates as it is applied, so it is difficult to apply. Since it is possible to produce make-up cosmetics with less makeup smearing after application, it can be used in facial cosmetics that require a long-wearing feel, hand creams and hair cosmetics that require water-repellent performance, and make-up cosmetics. A combination has been expected. Silicone oil also has the requirements for being a cosmetic raw material, as it is highly safe for the skin. [Problems to be Solved by the Invention] However, silicone oil has the disadvantage that it is very difficult to obtain a stable thickening system, and despite strong demands, this oil has not been used. A composition containing a large amount and having an appropriate viscosity has not been obtained. Up to now, in order to obtain a safe silicone oil thickening system, methods have been used, such as solidifying silicone oil with waxes, or thickening it with silica or silica treated to make it lipophilic. However, the method of solidifying with waxes has disadvantages in usability, such as being difficult to spread and is sticky, and has no fluidity, which limits its applicability. Further, the method of thickening with silica is not preferred because it has poor stability over time and requires shaking well before use. [Means for Solving the Problems] In view of these circumstances, the present inventors have conducted extensive research on methods of thickening silicone oil, and have found that silicone oil contains a specific silicon compound, an organically modified clay mineral, and water. It was discovered that a gel composition having a desired viscosity and good stability over time and ease of use can be obtained by blending a specific amount of the following, and based on this knowledge, the present invention was completed. That is, the present invention is characterized by blending silicone oil, one or more polyoxyalkylene-modified organopolysiloxanes represented by the general formula (), (), or (), an organically modified clay mineral, and water. A gel composition containing silicone oil is provided. {In the general formulas (), (), (), R is a methyl group or partially a phenyl group, R' is hydrogen or an alkyl group having 1 to 12 carbon atoms, p is a number from 1 to 5, and q is a number from 2 to
The numbers 3, x, m, and n are average numbers, and the polyoxyalkylene-modified organopolysiloxane contains more than 20% by weight and 40% by weight or less of polyoxyalkylene groups in the molecule, and the polyoxyalkylene-modified organopolysiloxane The viscosity of siloxane is 5 at 25℃.
Represents a number that is ~3000 centitokes. } Hereinafter, the configuration of the present invention will be explained in detail. As the silicone oil used in the present invention, conventionally known silicone oils can be used.
Examples include dimethylpolysiloxane, methylphenylpolysiloxane, octamethylcyclotetrasiloxane, and decamethylcyclopentasiloxane. One or more types are arbitrarily selected from these. The blending amount is usually 20 to 90% by weight based on the total amount of the composition of the present invention. The polyoxyalkylene-modified organopolysiloxane (hereinafter abbreviated as polyether-modified silicone) used in the present invention has the general formula (),
It is represented by () or (), and one or more of these may be selected and used. In order to satisfy the effect consistent with the purpose of the present invention, that is, the silicone thickening effect with good stability over time and ease of use, the polyether-modified silicone must have a polyoxyalkylene group of 20% relative to its molecular weight.
It is preferable that the clay is contained in a proportion of ~40% by weight (excluding 20% by weight) and that the clay itself is in the range of 5 to 3000 centistokes at 25°C. If the polyether-modified silicone clay is less than 5 centistokes, the thickening effect will not be sufficient, and if it exceeds 3,000 centistokes, the feel will be sticky and undesirable. The amount of polyether-modified silicone added to the gel composition of the present invention is selected in the range of 0.1 to 30% by weight based on the total amount, preferably 0.2 to 25% by weight.
It is. If it is less than 0.1% by weight, the thickening effect will not be sufficient and the stability over time will be poor, and if it exceeds 30% by weight, it will feel sticky and the makeup will not last long. The organically modified clay mineral used in the present invention is one in which the convertible cations present between the crystal layers of the clay mineral are replaced with an organic polar compound or an organic cation,
For example, dioctadecyldimethylammonium-converted montmorillonite, octadecyldimethylbenzylammonium salt-modified montmorillonite,
Examples include dihexadecyldimethylammonium salt-modified montmorillonite. One or more types are arbitrarily selected from these. The blending amount is 0.1 to 15% of the total amount of the gel composition of the present invention.
It is selected in the range of weight%, preferably 0.2~
It is 10% by weight. If it is less than 0.1% by weight, the thickening effect will not be sufficient and the stability over time will be poor. If it exceeds 15% by weight, it becomes difficult to spread and usability deteriorates. The amount of water in the present invention is selected within the range of 0.2 to 80% by weight based on the total amount of the gel composition, preferably 0.5 to 60% by weight. If it is less than 0.2% by weight, the thickening effect will not be sufficient and the stability over time will be poor. 80% by weight
Exceeding this is not desirable as it becomes difficult to spread. Cosmetics to which the silicone thickening composition of the present invention is applied include, in addition to the above-mentioned essential ingredients, waxes, oils and fats, humectants, pigments, powders, resins, fragrances,
Preservatives etc. are added. Furthermore, if 0.1 to 10% by weight of lower alcohols such as ethanol and isopropyl alcohol, and glycols such as propylene glycol, dipropylene glycol, and 1,3-butylene glycol are added to the total amount of the composition, the viscosity will further increase and the stability will be improved. can be improved. [Effects of the Invention] The gel composition containing the silicone oil of the present invention has good stability over time, and when used, it spreads well and has a good feel without stickiness, and has excellent water resistance and durability over time. It is a gel composition. In addition, since the viscosity, or fluidity, can be freely controlled, it can be used in a wide range of applications, including cosmetics, pharmaceutical bases, automobile waxes, and furniture waxes. [Example] Next, the present invention will be explained in more detail with reference to Examples. The present invention is not limited thereby. The blending amount is in weight%. The test methods for the special products of Examples and Comparative Examples were as follows. (1) Stability A sample is taken in a sample tube and left at each temperature condition, and evaluated by degree of separation (determined after 1 week). Evaluation criteria ○: No separation △: Approximately 1/5 separation ×: 2/3 or more separation (2) Viscosity Measured with a Burckfield viscometer (30
°C, after 1 day). (3) Stickiness and spread Sensory evaluation based on practical use test (20 panelists). Evaluation criteria: ○: No stickiness, easy spreading. △: Slightly sticky, spreads normally. ×: Sticky, hard to spread.
【表】
（製法）
〜をホモデイスパーにて撹拌し、日やけ用
乳液を得た。
表中に示した特性から、実施例１、２、３は経
時安定性及び使用性に優れていることが判る。[Table] (Production method) ~ was stirred in a homodisper to obtain a sunburn emulsion. From the characteristics shown in the table, it can be seen that Examples 1, 2, and 3 are excellent in stability over time and usability.
【表】【table】
【表】
（製法）
〜をホモデイスパーにて撹拌し、クリーム
を得た。
表中に示した特性から実施例４、５、６、７、
８、９は経時安定性および使用性に優れているこ
とが判る。[Table] (Production method) ~ was stirred in a homodisper to obtain cream. From the characteristics shown in the table, Examples 4, 5, 6, 7,
It can be seen that Samples Nos. 8 and 9 are excellent in stability over time and usability.
【表】【table】
【表】
（製法）
〜をホモデイスパーにて撹拌し、耐水性フ
アンデーシヨンを得た。
表中に示した特性から実施例10、11、12は経時
安定性および使用性に優れていることが判る。
また、海浜における実使用テスト（パネル20
名）により耐水性フアンデーシヨンとして十分な
機能を有しており、化粧もちも良いことが確認さ
れた。[Table] (Manufacturing method) - was stirred in a homodisper to obtain a water-resistant foundation. From the properties shown in the table, it can be seen that Examples 10, 11, and 12 are excellent in stability over time and usability. In addition, actual use tests on the beach (Panel 20
It was confirmed that it has sufficient functionality as a water-resistant foundation and has good makeup retention.
【表】
（製法）
〜をホモデイスパーで撹拌し、耐水性アイ
ライナーを得た。
表中に示した特性から実施例13、14、15、16は
経時安定性および使用性に優れていることが判
る。
また、海浜における実使用テスト（パネル20
名）により耐水性アイライナーとして十分な機能
を有しており、塗布後の乾燥が早く化粧もちも良
いことが確認された。[Table] (Production method) ~ was stirred with a homodisper to obtain a water-resistant eyeliner. From the properties shown in the table, it can be seen that Examples 13, 14, 15, and 16 are excellent in stability over time and usability. In addition, we conducted actual use tests on the beach (panel 20).
It was confirmed that it has sufficient functionality as a water-resistant eyeliner, and that it dries quickly after application and has good makeup retention.
【表】
（製法）
〜をホモデイスパーで撹拌し、つや出しク
リームを得た。
実施例17、18は化粧品だけでなく、家具のつや
出しクリームなどにも使用できることを実使用テ
ストにて確認した。[Table] (Production method) ~ was stirred with a homodisper to obtain a glossy cream. It was confirmed through actual use tests that Examples 17 and 18 can be used not only for cosmetics but also for furniture polishing creams.
Claims (1)
（）で示されるポリオキシアルキレン変性オル
ガノポリシロキサンの一種または二種以上、有機
変性粘土鉱物ならびに水を配合することを特徴と
するシリコンオイルを含む水含有ゲル組成物。 ｛一般式（）、（）、（）中、Ｒはメチル基ま
たは一部がフエニル基、R′は水素または炭素数
１〜12のアルキル基、ｐは１〜５の数、ｑは２〜
３の数、ｘ、ｍ、ｎは平均数でポリオキシアルキ
レン変性オルガノポリシロキサンが分子中にポリ
オキシアルキレン基を20重量％を超えてかつ40重
量％以下含有し且つ該ポリオキシアルキレン変性
オルガノシロキサンの粘度が25℃において５〜
3000センチトークスになるような数値を表す。｝ [Claims] 1. It is characterized by containing silicone oil, one or more polyoxyalkylene-modified organopolysiloxanes represented by the general formula (), (), or (), an organically modified clay mineral, and water. A water-containing gel composition containing silicone oil. {In the general formulas (), (), (), R is a methyl group or partially a phenyl group, R' is hydrogen or an alkyl group having 1 to 12 carbon atoms, p is a number from 1 to 5, and q is a number from 2 to
The numbers 3, x, m, and n are average numbers, and the polyoxyalkylene-modified organopolysiloxane contains more than 20% by weight and 40% by weight or less of polyoxyalkylene groups in the molecule, and the polyoxyalkylene-modified organosiloxane The viscosity of is 5~ at 25℃
Represents a number that equals 3000 centitokes. }
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18477585A JPS6245656A (en) | 1985-08-22 | 1985-08-22 | Gel composition containing silicone oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18477585A JPS6245656A (en) | 1985-08-22 | 1985-08-22 | Gel composition containing silicone oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6245656A JPS6245656A (en) | 1987-02-27 |
| JPH0554868B2 true JPH0554868B2 (en) | 1993-08-13 |
Family
ID=16159091
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18477585A Granted JPS6245656A (en) | 1985-08-22 | 1985-08-22 | Gel composition containing silicone oil |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6245656A (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01252664A (en) * | 1988-04-01 | 1989-10-09 | Nippon Unicar Co Ltd | Transparent gel composition containing organopolysiloxane |
| GB8914905D0 (en) * | 1989-06-29 | 1989-08-23 | Unilever Plc | Cosmetic composition |
| JP2631772B2 (en) * | 1991-02-27 | 1997-07-16 | 信越化学工業株式会社 | Novel silicone polymer and paste-like silicone composition having water dispersibility using the same |
| JP2544045B2 (en) * | 1991-10-01 | 1996-10-16 | 信越化学工業株式会社 | Water-in-oil type silicone emulsion composition |
| JP3333782B2 (en) * | 1992-05-01 | 2002-10-15 | 東レ・ダウコーニング・シリコーン株式会社 | Gel silicone composition |
| FR2737112B1 (en) | 1995-07-28 | 1997-09-05 | Oreal | USE OF THE ASSOCIATION OF TWO PARTICULAR OILS IN A COMPOSITION, ESPECIALLY COSMETIC, AND COMPOSITION OBTAINED |
| JP3550501B2 (en) * | 1998-09-08 | 2004-08-04 | 株式会社資生堂 | Gel composition |
| JP4490817B2 (en) | 2002-09-12 | 2010-06-30 | 信越化学工業株式会社 | Novel organopolysiloxane polymer and paste-like composition, and cosmetics using the composition |
| JP5349831B2 (en) * | 2008-04-16 | 2013-11-20 | 花王株式会社 | Gel cosmetic |
| JP6215719B2 (en) | 2014-01-23 | 2017-10-18 | 信越化学工業株式会社 | Cosmetics |
| JP6285381B2 (en) | 2015-03-13 | 2018-02-28 | 信越化学工業株式会社 | Gel paste composition and cosmetics using the gel paste composition |
| JP2023057598A (en) | 2021-10-12 | 2023-04-24 | 信越化学工業株式会社 | Organoalkoxysilane-containing composition and production method of the same, and water absorption-preventive agent |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1127592A (en) * | 1964-12-17 | 1968-09-18 | Midland Silicones Ltd | Organosiloxane compositions |
| JPS5679614A (en) * | 1979-12-03 | 1981-06-30 | Dow Corning | Personal care emulsion composition |
| JPS606607A (en) * | 1983-06-24 | 1985-01-14 | Pola Chem Ind Inc | Point makeup cosmetic |
| JPS6166752A (en) * | 1984-09-11 | 1986-04-05 | Shiseido Co Ltd | Gel composition containing silicone oil |
| JPS61113646A (en) * | 1984-11-08 | 1986-05-31 | Shiseido Co Ltd | Gel composition containing silicone oil |
| JPS61212324A (en) * | 1985-03-15 | 1986-09-20 | Shiseido Co Ltd | Gel composition containing silicone oil |
| JPS61271030A (en) * | 1985-05-28 | 1986-12-01 | Shiseido Co Ltd | Oily gel composition |
-
1985
- 1985-08-22 JP JP18477585A patent/JPS6245656A/en active Granted
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1127592A (en) * | 1964-12-17 | 1968-09-18 | Midland Silicones Ltd | Organosiloxane compositions |
| JPS5679614A (en) * | 1979-12-03 | 1981-06-30 | Dow Corning | Personal care emulsion composition |
| JPS606607A (en) * | 1983-06-24 | 1985-01-14 | Pola Chem Ind Inc | Point makeup cosmetic |
| JPS6166752A (en) * | 1984-09-11 | 1986-04-05 | Shiseido Co Ltd | Gel composition containing silicone oil |
| JPS61113646A (en) * | 1984-11-08 | 1986-05-31 | Shiseido Co Ltd | Gel composition containing silicone oil |
| JPS61212324A (en) * | 1985-03-15 | 1986-09-20 | Shiseido Co Ltd | Gel composition containing silicone oil |
| JPS61271030A (en) * | 1985-05-28 | 1986-12-01 | Shiseido Co Ltd | Oily gel composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6245656A (en) | 1987-02-27 |
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| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
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| LAPS | Cancellation because of no payment of annual fees |