JPS6051798A - Abrasive-containing colored liquid detergent composition - Google Patents
Abrasive-containing colored liquid detergent compositionInfo
- Publication number
- JPS6051798A JPS6051798A JP15998283A JP15998283A JPS6051798A JP S6051798 A JPS6051798 A JP S6051798A JP 15998283 A JP15998283 A JP 15998283A JP 15998283 A JP15998283 A JP 15998283A JP S6051798 A JPS6051798 A JP S6051798A
- Authority
- JP
- Japan
- Prior art keywords
- abrasive
- weight
- composition
- colored liquid
- containing colored
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0013—Liquid compositions with insoluble particles in suspension
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
本発明は研磨材含有着色液体洗浄剤組成物、さらに詳し
くいえば、該組成物をスポンジなどの洗浄補助具へ直接
採取しても、該洗浄補助具に整色することのない、研磨
材を含有した着色液体洗浄剤組成物に関するものである
。DETAILED DESCRIPTION OF THE INVENTION The present invention provides an abrasive-containing colored liquid cleaning composition, and more specifically, the present invention provides an abrasive-containing colored liquid cleaning composition, and more specifically, the present invention provides an abrasive-containing colored liquid cleaning composition. The present invention relates to a colored liquid cleaning composition containing an abrasive.
従来、野菜や食器洗い用洗剤としては、主として界面活
性剤のみを含有した組成物が用いられてきたが、このも
のは固体油や焼成油などに対する洗浄力が比較的弱いた
めに、近年界面活性剤を含む組成物に研磨材を含有させ
る試みが種々なされている。Conventionally, compositions containing only surfactants have been used as vegetable and dishwashing detergents, but since these detergents have relatively weak cleaning power against solid oils and baking oils, surfactants have recently been used. Various attempts have been made to incorporate an abrasive into a composition containing.
一方、台所用、衣類用、住居用あるいは毛髪用液体洗浄
剤などにおいては、これらに微量の色素を加えて美観を
与え、商品のイメージ・アンプを図ることが一般に行わ
れている。On the other hand, in the case of liquid detergents for kitchen use, clothing, home use, or hair, it is common practice to add a small amount of pigment to these products to give them a beautiful appearance and to enhance the image of the product.
ところで、研磨材を含有する洗浄剤組成物においては、
研磨材に色調遮へい効果があるために、研磨材を含有し
ない組成物と同じ外観を与えるには、研磨材を含有しな
い組成物の場合より３〜６倍量の色素を添加しなければ
ならず、また、研磨材含有洗浄剤組成物を使用する場合
、その研磨力を発揮させるために、スポンジなどの洗浄
補助具に該組成物を直接採取して洗浄する必要がある。By the way, in a cleaning composition containing an abrasive,
Because of the color-blocking effect of abrasives, 3 to 6 times more pigment must be added than in a non-abrasive composition to give the same appearance as a non-abrasive composition. Furthermore, when using a cleaning agent composition containing an abrasive material, in order to exert its abrasive power, it is necessary to directly collect the composition onto a cleaning aid such as a sponge for cleaning.
したがって、研磨材を含有した着色洗浄剤組成物を用い
る際に、スポンジなどの洗浄補助具への色素の染着が問
題となる。Therefore, when using a colored cleaning composition containing an abrasive, dyeing of cleaning aids such as sponges becomes a problem.
本発明者らは、このような問題を解決した研磨材含有着
色液体洗浄剤組成物を提供すべく鋭意研究を重ねた結果
、所定量の界面活性剤、水不溶性研磨材及び特定の増粘
剤を含有した組成物に、ＳＯ３基を有する色素を所定量
配合することにより、その目的を達成しうろことを見出
し、この知見に基づいて本発明を完成するに至った。The present inventors have conducted extensive research to provide a colored liquid cleaning composition containing an abrasive that solves these problems. It was discovered that the objective could be achieved by blending a predetermined amount of a dye having an SO3 group into a composition containing SO3, and based on this knowledge, the present invention was completed.
すなわち、本発明は、（Ａ）界面活性剤１０〜３０重量
％、（Ｂ）非水溶性研磨材３〜３０重量％、（Ｃ）水溶
性高分子物質及び粘土鉱物の中から選ばれた少なくとも
１種の増粘剤０．１〜１０重量％、及び（Ｄ）分子内に
少なくとも１個のＳ０３基を有する色素０．００１〜０
．０５重量％を含有することを特徴とする研磨材含有着
色液体洗浄剤組成物を提供するものである。That is, the present invention provides at least one of (A) 10 to 30% by weight of a surfactant, (B) 3 to 30% by weight of a water-insoluble abrasive, and (C) a water-soluble polymeric substance and a clay mineral. 0.1 to 10% by weight of one kind of thickener, and (D) 0.001 to 0 of a dye having at least one S03 group in the molecule.
．． The present invention provides an abrasive-containing colored liquid cleaning composition characterized by containing 0.05% by weight.
本発明組成物において、（Ｎ成分として用いる界面活性
剤はアニオン性界面活性剤、ノニオン性界面活性剤、カ
チオン性界面活性剤、両性界面活性剤又は双性イオン界
面活性剤などであって、アニオン性界面活性剤としては
、通常のスルホネート系、サルフェート系、ホスフェー
ト系のアニオン性界面活性剤が使用される。これらのア
ニオン性界面活性剤の中でスルホネ−１・系アニオン性
界面活性剤としては、例えば直鎖又は分枝鎖アルキル（
０８〜Ｃ２３）ベンゼンスルホン酸塩、長鎖アルキル（
０８〜Ｃ２□）スルホン酸塩、長鎖オレフィン（０８〜
Ｃ２２）スルホン酸塩などが挙げられる。またサルフェ
ート系アニオン性界面活性剤としては、例えば長鎖モノ
アルキル（０８〜Ｃｚｚ）硫酸エステル塩、ポリオキ７
エチレン（１〜６モル）長鎖アルキル（０８〜Ｇ２２）
エーテル硫酸エステル塩、ポリオキシエチレン（１〜６
モル）アルキル（０８〜０１ｓ ）フェニルエーテル硫
酸エステル塩ナトカ挙げられ、またホスフェート系アニ
オン性界面活性剤としては、例えば長鎖モノアルキル、
ジアルキル又はセスキ（各アルキル基の炭素数は８〜２
２である）リン酸塩、ポリオキシエチレン（１〜６モル
）モノアルキル、ジアルキル又はセスキ（各アルキル基
の炭素数が８〜２２である）リン酸塩々どが挙けられる
。これらのアニオン性界面活性剤の対イオンとしての陽
イオンは、例えばナトリウム、カリウム、マグネシウム
などのアルカリ金属イオン、モノエタノールアミン、ジ
ェタノールアミン、トリエタノールアミンなどのアルカ
ノールアミンイオンなどである。In the composition of the present invention, the surfactant used as the N component is an anionic surfactant, a nonionic surfactant, a cationic surfactant, an amphoteric surfactant, a zwitterionic surfactant, etc. As the surfactant, ordinary sulfonate-based, sulfate-based, and phosphate-based anionic surfactants are used. Among these anionic surfactants, sulfone-1-based anionic surfactants include , for example straight-chain or branched alkyl (
08-C23) Benzene sulfonate, long chain alkyl (
08~C2□) Sulfonate, long chain olefin (08~
C22) sulfonate salts and the like. Examples of sulfate-based anionic surfactants include long-chain monoalkyl (08-Czz) sulfate salts, polyoxy7
Ethylene (1-6 mol) long chain alkyl (08-G22)
Ether sulfate ester salt, polyoxyethylene (1 to 6
Examples of phosphate anionic surfactants include long chain monoalkyl,
Dialkyl or sesqui (each alkyl group has 8 to 2 carbon atoms)
2), polyoxyethylene (1 to 6 mol) monoalkyl, dialkyl or sesqui(each alkyl group has 8 to 22 carbon atoms) phosphates, and the like. Cations as counter ions of these anionic surfactants include, for example, alkali metal ions such as sodium, potassium, and magnesium, and alkanolamine ions such as monoethanolamine, jetanolamine, and triethanolamine.
ノニオン性界面活性剤としては、例えばポリオキシエチ
レン（１〜２０モル）長鎖アルキル（第−級又は第二級
０８〜０２２）エーテル、ポリオキシエチレン（１〜２
０モル）アルキル（Ｃ，〜Ｃ１ｌ＋ ）フェニルエーテ
ル、−ポリオキシエチレンポリオキシプロピレンブロッ
クコポリマーなどのオキシアルキレン付加化合物、高級
脂肪酸アルカノールアミド又はそのアルキレンオキサイ
ド付加物、長鎖型第三級アミンオキシド（０１２〜＋４
．）などが挙げられる。Examples of nonionic surfactants include polyoxyethylene (1 to 20 moles) long chain alkyl (primary or secondary 08 to 022) ether, polyoxyethylene (1 to 2 moles),
0 mol) alkyl (C, ~C1l+) phenyl ether, oxyalkylene addition compounds such as -polyoxyethylene polyoxypropylene block copolymer, higher fatty acid alkanolamide or its alkylene oxide adduct, long chain tertiary amine oxide (012 ~+4
．． ), etc.
カチオン性界面活性剤としては、例えば長鎖アルキルト
リメチルアンモニウム塩、長鎖アルキルジメチルベンジ
ルアンモニウム塩、長鎖アルキルピリジニウム塩などの
第四級アンモニウム塩などが挙げられる。Examples of the cationic surfactant include quaternary ammonium salts such as long-chain alkyltrimethylammonium salts, long-chain alkyldimethylbenzylammonium salts, and long-chain alkylpyridinium salts.
両性界面活性剤としては例えば、ジメチル長鎖（０８〜
０１ｇ）アルキル−カルボキシメチルアンモニウムベタ
イン、ジ長鎖（０８〜Ｃｌ８）アルキルアミノアルキレ
ンカルボン酸塩、２−アルキル−１−カルボキノメチル
−１−ヒドロキシエチルイミダゾリニウムベタインなど
が挙げられる。Examples of amphoteric surfactants include dimethyl long chain (08-
01g) Alkyl-carboxymethylammonium betaine, di-long chain (08-Cl8) alkylaminoalkylene carboxylate, 2-alkyl-1-carboquinomethyl-1-hydroxyethylimidazolinium betaine, and the like.
これらの界面活性剤はそれぞれ単独で用いてもよいし、
２種以上混合して用いてもよく、その配合量は組成物全
足に対し、１０〜３０重量％、好ましくは１５〜２５重
量％の範囲である。この量が１０重量％未満では起泡力
や洗浄力が不足し、また３０重量％を超えると被洗物が
ぬるついたり、すすぎ性が劣化したりするため好ましく
ない。These surfactants may be used alone or
Two or more kinds may be used as a mixture, and the blending amount thereof is in the range of 10 to 30% by weight, preferably 15 to 25% by weight, based on the total weight of the composition. If this amount is less than 10% by weight, the foaming power and cleaning power will be insufficient, and if it exceeds 30% by weight, the laundry will become slimy and the rinsing performance will deteriorate, which is not preferable.
本発明組成物において（Ｂ）成分として用いる非水溶性
研磨材としては、例えば石英、シリカ、方解石、長石、
アルミナ、ケインウ土、パーライト、アルミノケイ酸塩
、リン酸カルシウム、炭酸カルシウム、合成樹脂などが
挙げられる。これらは単独で用いてもよいし、２種以上
組合わせて用いてもよい。またその平均粒径としては、
通常１〜１５０μ、好ましくは５〜４０μ程度のものが
用いられる。Examples of water-insoluble abrasives used as component (B) in the composition of the present invention include quartz, silica, calcite, feldspar,
Examples include alumina, cinnabar earth, perlite, aluminosilicate, calcium phosphate, calcium carbonate, and synthetic resin. These may be used alone or in combination of two or more. In addition, the average particle size is
Usually, the thickness is about 1 to 150 microns, preferably about 5 to 40 microns.
本発明組成物における前記研磨材の含有量は３〜３０重
量％、好ましくは５〜１５重量％の範囲である。この量
が３重量％未満では研磨力が不足し、一方３０重量％を
超えるとその遮へい効果のため、色素配合量を増やさね
ばならず、本発明の色素を用いてもスポンジなどの洗浄
補助具に染着しやすくなる。The content of the abrasive in the composition of the present invention is in the range of 3 to 30% by weight, preferably 5 to 15% by weight. If this amount is less than 3% by weight, the polishing power will be insufficient, while if it exceeds 30% by weight, the amount of the pigment must be increased due to its shielding effect, and even if the pigment of the present invention is used, cleaning aids such as sponges etc. becomes easily stained.
本発明組成物において（Ｃ）成分として用いる増粘剤は
水溶性高分子物質及び粘土鉱物の中から選ばれたもので
ある。水溶性高分子としては、例えばカルボキンセルロ
ース、ポリアクリル酸及びその塩、ポリビニルアルコー
ル、ヒドロキシエチルセルロース、ポリヒニルビロリド
ン、無水マレイン酸ポリマー及びその塩などが挙げられ
る。寸だ粘土鉱物としては、例えばモンモリロナイト、
ノントロナイト、ヘクトライト、バーミキュライト、ア
クパルジャイト、セピオライト及びこれらの混合物を主
成分とする粘土などを挙げることができる。The thickener used as component (C) in the composition of the present invention is selected from water-soluble polymeric substances and clay minerals. Examples of water-soluble polymers include carboxyl cellulose, polyacrylic acid and its salts, polyvinyl alcohol, hydroxyethyl cellulose, polyhinylpyrrolidone, maleic anhydride polymer and its salts, and the like. Examples of clay minerals include montmorillonite,
Examples include clays whose main components are nontronite, hectorite, vermiculite, acpulgite, sepiolite, and mixtures thereof.
これらの増粘剤はそれぞれ単独で用いてもよいし、２種
以上混合して用いてもよく、その配合量は組成物全量に
対し０．１〜１０重量％、好捷しくは０，５〜３重量％
の範囲である。この量が０．１重量％未満では安定化に
必要な粘度が得られず、また１０重量％を超えると粘度
が高くなりすぎて使用上好ましくない。Each of these thickeners may be used alone or in combination of two or more, and the amount thereof is 0.1 to 10% by weight based on the total amount of the composition, preferably 0.5% by weight. ~3% by weight
is within the range of If this amount is less than 0.1% by weight, the viscosity necessary for stabilization cannot be obtained, and if it exceeds 10% by weight, the viscosity becomes too high, which is undesirable for use.
本発明組成物において（Ｄ）成分として用いる色素は、
少なくとも１個のＳ０３基を有するものであり、このよ
うなものとしては、カラーインデックスナンバーに従っ
て記載すると、例えばアシッドレッド２７、アシッドレ
ッド５２、アシッドレッド１０５、アシッドレッド１０
６、アシッドイエロー３、アシッドイエロー２３、アン
ラドブル−９、アンラドブルー６２、アシッドブルーフ
４などの酸性染料、ダイレフトレンド３１などの直接染
料、フッドグリーン２、フンドグリーン３、フッドイエ
ロー３などの食品用色素、ピグメントレッド４９、ピグ
メントレッド５３などの有機顔料が挙げられる。The pigment used as component (D) in the composition of the present invention is:
It has at least one S03 group, and when described according to the color index number, for example, Acid Red 27, Acid Red 52, Acid Red 105, Acid Red 10.
6. Acidic dyes such as Acid Yellow 3, Acid Yellow 23, Anrad Blue-9, Anrad Blue 62, Acid Bluff 4, direct dyes such as Dyref Trend 31, food colorants such as Hood Green 2, Fund Green 3, Hood Yellow 3, etc. , Pigment Red 49, and Pigment Red 53.
これらの色素の配合量は、組成物全量に対して０．００
１〜０．０５重量％の範囲である。この量が０．００１
重量％未満では発色性が悪く、また０、０５重量％を超
えるとスポンジなどの洗浄補助具に染着するため好まし
くない。The blending amount of these pigments is 0.00 based on the total amount of the composition.
It ranges from 1 to 0.05% by weight. This amount is 0.001
If it is less than 0.05% by weight, the coloring property is poor, and if it exceeds 0.05% by weight, cleaning aids such as sponges will be dyed, which is not preferable.
本発明の研磨材含有着色液体洗浄剤組成物は、界面活性
剤、水不溶性研磨材及び増粘剤に、特定の色素を配合し
たものであって、スポンジなどの洗浄補助具への色素の
転移が起らない組成物である。The abrasive-containing colored liquid cleaning composition of the present invention is a composition in which a specific pigment is blended with a surfactant, a water-insoluble abrasive, and a thickener, and the pigment is transferred to cleaning aids such as sponges. This is a composition that does not cause
次に実施例によって本発明をさらに詳細に説明する。Next, the present invention will be explained in more detail with reference to Examples.
なお、組成物の着色度及びスポンジへの染着性は次のよ
うにして評価した。In addition, the degree of coloring of the composition and the dyeability to sponge were evaluated as follows.
組成物の着色度
組成物を１００−容ガラスびんに充てんし、着色度合を
目視で評価し、薄すぎる場合を１１やや薄い場合を２、
良い場合を３、とすぎる場合を４とし、２及び３を合格
としだ。Coloring degree of the composition The composition was filled into a 100-capacity glass bottle, and the degree of coloring was visually evaluated.If it was too light, it would be rated 11, if it was a little thin, it would be 2,
A good score is rated 3, a poor score is 4, and 2 and 3 are considered passing.
白色のウレタンスポンジを２×５ｃｒｎに切断し、１０
〇−容ビーカーに入れた組成物中で３分間かきまぜ、取
り出す。次いで水道水で洗剤のぬるつきがなくなるまで
洗ったのち、目視により着色度を元の白色スポンジと比
較して評価した。Cut white urethane sponge into 2 x 5 crn pieces, 10
Stir the composition in a 〇-sized beaker for 3 minutes and remove it. After washing with tap water until the detergent was no longer sticky, the degree of coloring was visually evaluated by comparing it with the original white sponge.
判定基準は スポンジに着色が認められない ：○ やや着色が認められる ：△ 明らかに着色が認められる ：× とし、○及び△を合格とした。The criteria are No coloring is observed on the sponge:○ Slight discoloration is observed: △ Coloring is clearly observed: × ○ and △ were considered to be passed.
また、実施例及び比較例で用いた色素の構造式％式％
アシッドレッド２７
ＳＯ３Ｎａ
ＳＯ３Ｎａ
アシッドイエロー３
２部 １部
アシッドイエロー２３
０ＯＮａ
フッドイエロー３
Ｏ
フッドグリーン３
アシッドブルー９
０３Ｎａ
ピグメントレッド５３
ピグメントレッド４９
ダイレクトレッド３１
アシッドレッド５１
ペイシックバイオレット１゜
ピグメントレッド３
Ｈ
ンルベントレッド４９
実施例
第１表に示すような組成を有する研磨材含有着色液体洗
浄剤組成物を調製し、該組成物の着色度及びスポンジへ
の染着性を評価した。その結果を第１表に示す。In addition, the structural formulas of the pigments used in Examples and Comparative Examples % Formula % Acid Red 27 SO3Na SO3Na Acid Yellow 3 2 parts 1 part Acid Yellow 23 0ONa Hood Yellow 3 O Hood Green 3 Acid Blue 9 03Na Pigment Red 53 Pigment Red 49 Direct Red 31 Acid Red 51 Pacific Violet 1゜Pigment Red 3 H Nruvent Red 49 Example An abrasive-containing colored liquid cleaning composition having the composition shown in Table 1 was prepared, and the degree of coloration of the composition was determined. And the dyeability to sponge was evaluated. The results are shown in Table 1.
比較例
第２表に示すような組成を有する研磨材含有着色液体洗
浄剤組成物を調製し、該組成物の着色度及びスポンジへ
の染着性を評価した。その結果を第２表に示す。Comparative Example An abrasive-containing colored liquid cleaning composition having the composition shown in Table 2 was prepared, and the degree of coloring and stainability of the composition to a sponge were evaluated. The results are shown in Table 2.
Claims (1)
研磨材３〜３０重量％、（Ｃ）水溶性高分子物質及び粘
土鉱物の中から選ばれた少なくとも１種の増粘剤０．１
〜１０重量％、及び（Ｄ）分子内に少なくとも１個の８
０３基を有する色素０．００１〜０．０５重量％を含有
することを特徴とする研磨材含有着色液体洗浄剤組成物
。 ２ 色素が少なくとも１個のＳ０３基を含む酸性染料、
直接染料、食品用色素及び有機顔料の中から選ばれたも
のである特許請求の範囲第１項記載の組成物。[Scope of Claims] 1 (A) 10 to 30% by weight of a surfactant, (B) 3 to 30% by weight of a water-insoluble abrasive, (C) selected from water-soluble polymeric substances and clay minerals. At least one thickener 0.1
~10% by weight, and (D) at least one 8 in the molecule
An abrasive-containing colored liquid cleaning composition characterized by containing 0.001 to 0.05% by weight of a dye having 03 groups. 2. Acidic dye whose pigment contains at least one S03 group,
A composition according to claim 1, which is selected from direct dyes, food colorings and organic pigments.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15998283A JPS6051798A (en) | 1983-08-31 | 1983-08-31 | Abrasive-containing colored liquid detergent composition |
| GB08420520A GB2145729B (en) | 1983-08-31 | 1984-08-13 | Abrasive colored liquid detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15998283A JPS6051798A (en) | 1983-08-31 | 1983-08-31 | Abrasive-containing colored liquid detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6051798A true JPS6051798A (en) | 1985-03-23 |
| JPS6111995B2 JPS6111995B2 (en) | 1986-04-05 |
Family
ID=15705412
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15998283A Granted JPS6051798A (en) | 1983-08-31 | 1983-08-31 | Abrasive-containing colored liquid detergent composition |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPS6051798A (en) |
| GB (1) | GB2145729B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015010188A (en) * | 2013-06-28 | 2015-01-19 | ライオン株式会社 | Detergent for dishwasher |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4772425A (en) * | 1985-12-23 | 1988-09-20 | Colgate-Palmolive Company | Light duty liquid dishwashing composition containing abrasive |
| NZ226289A (en) * | 1987-09-29 | 1990-09-26 | Colgate Palmolive Co | Gel-like aqueous dishwashing composition with sodium silicate and silica anti-filming agent |
| AU616206B2 (en) * | 1987-09-29 | 1991-10-24 | Colgate-Palmolive Company, The | Thixotropic aqueous liquid automatic dishwashing detergent composition |
| JPH01288391A (en) * | 1988-05-17 | 1989-11-20 | Agency Of Ind Science & Technol | Method and apparatus for treatment of waste water |
| GB0506558D0 (en) * | 2005-03-31 | 2005-05-04 | Unilever Plc | Shading dyes |
| WO2010039574A1 (en) | 2008-09-30 | 2010-04-08 | The Procter & Gamble Company | Liquid hard surface cleaning composition |
| EP2328998A1 (en) | 2008-09-30 | 2011-06-08 | The Procter & Gamble Company | Liquid hard surface cleaning composition |
| ES2582573T3 (en) | 2008-09-30 | 2016-09-13 | The Procter & Gamble Company | Hard surface liquid cleaning compositions |
| JP5658277B2 (en) | 2009-12-22 | 2015-01-21 | ザ プロクター アンド ギャンブルカンパニー | Liquid cleaning and / or cleansing composition |
| US8440602B2 (en) | 2009-12-22 | 2013-05-14 | The Procter & Gamble Company | Liquid cleaning and/or cleansing composition comprising a divinyl benzene cross-linked styrene polymer |
| MX336922B (en) | 2010-04-21 | 2016-02-05 | Procter & Gamble | Liquid cleaning and/or cleansing composition. |
| EP2431453B1 (en) | 2010-09-21 | 2019-06-19 | The Procter & Gamble Company | Liquid cleaning and/or cleansing composition |
| EP2431452B1 (en) * | 2010-09-21 | 2015-07-08 | The Procter & Gamble Company | Liquid cleaning composition |
| EP2431451A1 (en) | 2010-09-21 | 2012-03-21 | The Procter & Gamble Company | Liquid detergent composition with abrasive particles |
| EP2537917A1 (en) | 2011-06-20 | 2012-12-26 | The Procter & Gamble Company | Liquid detergent composition with abrasive particles |
| US8852643B2 (en) | 2011-06-20 | 2014-10-07 | The Procter & Gamble Company | Liquid cleaning and/or cleansing composition |
| WO2012177615A1 (en) | 2011-06-20 | 2012-12-27 | The Procter & Gamble Company | Liquid cleaning and/or cleansing composition |
| EP2721136A1 (en) | 2011-06-20 | 2014-04-23 | The Procter and Gamble Company | Liquid cleaning and/or cleansing composition |
| ES2577147T3 (en) | 2012-10-15 | 2016-07-13 | The Procter & Gamble Company | Liquid detergent composition with abrasive particles |
-
1983
- 1983-08-31 JP JP15998283A patent/JPS6051798A/en active Granted
-
1984
- 1984-08-13 GB GB08420520A patent/GB2145729B/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015010188A (en) * | 2013-06-28 | 2015-01-19 | ライオン株式会社 | Detergent for dishwasher |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2145729A (en) | 1985-04-03 |
| GB8420520D0 (en) | 1984-09-19 |
| GB2145729B (en) | 1987-03-11 |
| JPS6111995B2 (en) | 1986-04-05 |
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