JPS60241658A - Manufacture of fuel cell separator - Google Patents
Manufacture of fuel cell separatorInfo
- Publication number
- JPS60241658A JPS60241658A JP59096607A JP9660784A JPS60241658A JP S60241658 A JPS60241658 A JP S60241658A JP 59096607 A JP59096607 A JP 59096607A JP 9660784 A JP9660784 A JP 9660784A JP S60241658 A JPS60241658 A JP S60241658A
- Authority
- JP
- Japan
- Prior art keywords
- separator
- etching
- fuel
- chamber
- manufacturing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0204—Non-porous and characterised by the material
- H01M8/0206—Metals or alloys
- H01M8/0208—Alloys
- H01M8/021—Alloys based on iron
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0247—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/14—Fuel cells with fused electrolytes
- H01M2008/147—Fuel cells with molten carbonates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0048—Molten electrolytes used at high temperature
- H01M2300/0051—Carbonates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Abstract
Description
【発明の詳細な説明】
〔発明の利用分野〕
本発明は燃料電池のセパレータの製造方法に係シ、特に
、隔壁を介してその両面に設けられる燃料室及び酸化剤
室と、これら室内に設けられた集電用突起部とをエツチ
ングで形成する燃料電池のセパレータの製造方法に関す
る。[Detailed Description of the Invention] [Field of Application of the Invention] The present invention relates to a method for manufacturing a separator for a fuel cell, and in particular, to a method for manufacturing a separator for a fuel cell, and in particular, to a method for manufacturing a separator for a fuel cell. The present invention relates to a method for manufacturing a fuel cell separator, in which a current collecting protrusion is formed by etching.
溶解塩型燃料電池は、その構成部材のうち、セパレータ
として導電性を有する金属を用いると共に、電解質板と
してセラミックスを用いている。Among its constituent members, a molten salt fuel cell uses conductive metal as a separator and ceramics as an electrolyte plate.
大容量の電池出力を得るために、この燃料電池は、電解
質板の一方の面にアノードを、その電解質板の他方の面
にカソードを配設し、かつその両面にセパレータを配設
することによυ単位電池を構成し、しかもこの単位電池
を極性をそろえて順次積み重ねて構成されている。In order to obtain a large capacity battery output, this fuel cell has an anode on one side of an electrolyte plate, a cathode on the other side of the electrolyte plate, and a separator on both sides. It consists of unit batteries, and these unit batteries are stacked one after another with the polarities aligned.
かかる溶融塩型燃料電池は、その運転温度が650〜7
00’Cの如く高温であるため、セパレータに用いられ
る材料は耐熱の面から金属材料に限られている。また、
電解質にはアルカリ溶融炭酸塩が用いられていることか
ら、セパレータに用いられる材料は耐食性にも富むステ
ンレス材を用いている。ところで、かかるステンレス材
を用いたセパレータに、燃料室及び酸化剤室と、両室に
設けられる集電部の突起とを形成する方法としては、従
来は機械加工によっていた。Such a molten salt fuel cell has an operating temperature of 650 to 7
Since the temperature is as high as 00'C, the materials used for the separator are limited to metal materials from the viewpoint of heat resistance. Also,
Since alkaline molten carbonate is used as the electrolyte, the material used for the separator is stainless steel, which is highly corrosion resistant. By the way, machining has conventionally been used as a method for forming the fuel chamber, the oxidizer chamber, and the protrusions of the current collector provided in both chambers in a separator made of such a stainless steel material.
機械加工によシセバレータを形成する方法は、セパレー
タの仕上がシ精度を高く維持できることから適している
と言える。しかしながら、かかる従来の製造方法によれ
ば、セパレータは切削加工時に生ずる熱歪の影響を受け
やすい。また、かかる従来の製造方法によると、セパレ
ータの材料の厚さが5〜6〔關〕以下の肉薄のものであ
ると加工が困難であるため、7〜8〔關〕以上の肉厚の
材料を使用せざるを得ない。このため、燃料電池の小型
軽量化が図れないという大きな欠点がある。The method of forming the separator by machining is suitable because the finish of the separator can maintain high precision. However, according to such conventional manufacturing methods, the separator is easily affected by thermal distortion that occurs during cutting. Furthermore, according to such conventional manufacturing methods, if the thickness of the separator material is less than 5 to 6 [m], it is difficult to process. I have no choice but to use . For this reason, there is a major drawback in that the fuel cell cannot be made smaller and lighter.
もちろん、セパレータの材料費は高価になシ、さらにそ
のセパレータの製造方法は機械加工法であるため、その
製作時間がかがシ製作費も非常に高価なものとなるとい
う欠点がある。Of course, the materials for the separator are expensive, and since the separator is manufactured by machining, the manufacturing time is long and the manufacturing cost is also very high.
また、その製作方法が機械加工である場合、燃料や酸化
剤などのガスの流れ及び集電に効果的な構造に加工する
ことにも限界がある。Furthermore, when the manufacturing method is machining, there is a limit to the ability to process the structure into a structure that is effective for the flow of gases such as fuel and oxidizer, and for current collection.
本発明は上記従来技術に鑑みてなされたものであり、そ
の目的はガスの流れが良く、集電効果の大きい、かつ小
型軽量のセパレータを製造するセパレータの製造方法を
提供することにある。The present invention has been made in view of the above-mentioned prior art, and its object is to provide a method for manufacturing a separator that has good gas flow, a large current collection effect, and is small and lightweight.
上記目的を達成するため、本発明は、隔壁の一方の面に
燃料室及び集電部、該隔壁の他方の面に酸化剤室及び集
電部を有するセパレータを製造する製造方法において、
素材をセパレータ寸法に加工し、両面を平滑に仕上げた
金属材料に、電極の厚さに合せて、その寸法をまず堀込
むようなエツチングマスクをかぶせ、エツチング液に所
定の時間浸漬して第1段堀シの処理をし、ついで燃料ま
たは酸化剤となるガスが室内全域に高分散しかつ集電が
高率で行なえるような形状のマスクをかぶせ、再びエツ
チング液に所定時間浸漬して第2段堀りの処理をするこ
とによシ、燃料室、酸化剤室及び集電突起部が形成され
たセパレータを得るものである。In order to achieve the above object, the present invention provides a manufacturing method for manufacturing a separator having a fuel chamber and a current collector on one side of the partition, and an oxidizer chamber and a current collector on the other side of the partition.
A metal material that has been processed to have the dimensions of a separator and smoothed on both sides is covered with an etching mask that first etches the dimensions to match the thickness of the electrode, and is immersed in an etching solution for a predetermined period of time. After processing the step trench, the mask is covered with a mask shaped so that the fuel or oxidizing gas is highly dispersed throughout the room and current collection can be carried out at a high rate. By carrying out the two-stage drilling process, a separator in which a fuel chamber, an oxidizing agent chamber, and a current collecting protrusion are formed is obtained.
本発明によるセパレータの製造方法によれば突起部の形
状を従来の機械加工による製造方法では困難であった形
状のセパレータの製作が可能となる。According to the method of manufacturing a separator according to the present invention, it is possible to manufacture a separator with a protrusion shape that is difficult to produce using a conventional manufacturing method using machining.
以下、本発明の実施例を図面に基づいて説明する。 Embodiments of the present invention will be described below based on the drawings.
第1図は本発明に係る製造方法で製造されたセパレータ
の設置例を示す原理的構成図である。FIG. 1 is a theoretical configuration diagram showing an example of installing a separator manufactured by the manufacturing method according to the present invention.
第1図において、符号1はセパレータであシ、セパレー
タ1には、酸化剤室2及びこの室2に設けた集電用突起
3と、燃料室4及びこの室4に設は九集電用突起5とが
設けられている。このセ・ゝレータ1,1の間にはアノ
ード6、電解質7及びカソード8が設けられて単位電池
が構成されている。通常、この単位電池が複数個重ね合
せて燃料電池が構成されている。In FIG. 1, reference numeral 1 indicates a separator, and the separator 1 has an oxidizer chamber 2 and a current collecting protrusion 3 provided in this chamber 2, a fuel chamber 4, and a current collecting protrusion 3 provided in this chamber 4. A projection 5 is provided. An anode 6, an electrolyte 7, and a cathode 8 are provided between the separators 1, 1 to constitute a unit battery. Usually, a fuel cell is constructed by stacking a plurality of these unit cells.
このようにセパレータは用いられている。ところで、か
かるセパレータは、次のように構成されている。Separators are used in this way. By the way, such a separator is configured as follows.
まず、セパレータの材料としてはステンレス板を用いて
いる。その大きさは一辺が360[ml)の正方形であ
り、その板厚は5〔閣〕である。この平板10に第2図
及び第3図に示すように、電極セット部11を、電極の
厚さ0.6(w)に対して0.4〔闘〕の深さに、また
電極面積900C−〕(a o (m)角)がセットで
きるよう301〔■〕角の大きさのにエツチングマスク
をかぶせて所定の時間エツチング液に浸漬してエツチン
グをする。First, a stainless steel plate is used as the material for the separator. Its size is a square with each side measuring 360 [ml], and its thickness is 5 [kaku]. As shown in FIGS. 2 and 3, the electrode set part 11 is placed on this flat plate 10 at a depth of 0.4 (w) for the electrode thickness of 0.6 (w), and with an electrode area of 900 cm. -] (a o (m) angle) is set by covering the etching mask with the size of the 301 [■] corner and etching it by immersing it in an etching solution for a predetermined time.
つぎに、第2段堀)として、第4図のように、実際には
第5図に示すように燃料室12を深さ1.5〔關〕、面
積290〔簡〕、集電突起部13は幅が2(ma〕、燃
料室12すなわち凹部の幅が3〔■〕になるようにエツ
チングする。また燃料通路14は外周辺部15に直径6
〔關〕で一辺に4個を、さらに裏面にも酸化剤室16.
集電突起部17及び酸化剤通路18を、燃料室12の集
電突起部13と全く同じ形状で直交するように、同時に
エツチングする。Next, as a second stage moat, the fuel chamber 12 is constructed with a depth of 1.5 [degrees], an area of 290 [simplified], and a current collecting protrusion as shown in Fig. 4, but actually as shown in Fig. 5. 13 is etched so that the width is 2 (ma) and the width of the fuel chamber 12, that is, the recess is 3 [■].Furthermore, the fuel passage 14 is etched so that the width of the fuel chamber 12, that is, the recess is 3 [■].
There are 4 oxidizer chambers on one side with 16 oxidizer chambers on the back side.
The current collector protrusion 17 and the oxidizer passage 18 are etched at the same time so that they have exactly the same shape as the current collector protrusion 13 of the fuel chamber 12 and are orthogonal to each other.
さらに、燃料通路14と酸化剤通路が第2段堀りのエツ
チングで深さ1.5[a+:]まで堀シ込まれているの
で、寸法とりの作業をすることなく、その位置をドリル
で貫通させ通気孔を設け、七ノくレータ10を完成させ
る。Furthermore, since the fuel passage 14 and oxidizer passage are etched to a depth of 1.5 [a+:] in the second stage of drilling, their positions can be drilled without having to take measurements. A ventilation hole is provided through the hole to complete the seven cutter 10.
同、本実施例はエツチング法によシセ/くレータを製造
するものであシ、集電用突起13を前記実施例と同様の
作業手順で、第6図に示すように三角形状とし、第7図
に示すように四角形状とし、また第8図に示すように丸
形などの形状とすることもできる。エツチング後は第9
図に示すように、例えば丸型の上面を直径4〔鴎〕に設
計すると、仕上りは3.8(sm)程度になシ堀シ込み
が1〜1.5〔聰〕の間では5〜5.5〔聴〕と直径が
太くなり集電に好ましい形状が得られた。Similarly, in this embodiment, the cutter/cutter is manufactured by the etching method, and the current collecting protrusion 13 is formed into a triangular shape as shown in FIG. It may be square as shown in FIG. 7, or round as shown in FIG. 8. 9th after etching
As shown in the figure, for example, if the top surface of a round shape is designed to have a diameter of 4 [sm], the finish will be about 3.8 (sm), and if the depth of the hole is between 1 and 1.5 [s. The diameter was increased to 5.5 [audible], and a shape suitable for current collection was obtained.
セパレータをエツチングで形成すると、第1に燃料室と
隔壁を介したもう一方の面の酸化剤室の堀シ込み深さが
同じであれば、両面同時作業が可能で製作時間もその2
分の1に短縮されることになる。また、機械加工による
従来の製造方法がセパレータ1枚片面を形成するのに要
する時間が約40時間要するのに対して、本発明に係る
製造方法によれば両面同時作業で約3時間という短時間
で完成させることができた。If the separator is formed by etching, firstly, if the trench depth of the fuel chamber and the oxidizer chamber on the other side through the partition are the same, it is possible to work on both sides at the same time, which reduces the manufacturing time.
It will be shortened to one-fold. In addition, while it takes about 40 hours to form one separator on one side using the conventional manufacturing method using machining, the manufacturing method according to the present invention takes only about 3 hours to form both sides at the same time. I was able to complete it.
第2に、機械加工による従来の製造方法においては、セ
パレータの材料がステンレスの場合、厚さが7〜8〔闘
〕以下のものを使用すると、切削作業時に摩擦熱による
歪が大きく、連続加工作業が不可能であるのに対して、
エツチング加工による本発明の製造方法によればこれら
の問題がなく、4〜5〔閣〕の薄い材料でも容易に加工
でき、セパレータの軽量化と材料費の低減に大きな効果
がある。Second, in the conventional manufacturing method by machining, if the separator material is stainless steel and the thickness is less than 7 to 8 mm, there will be large distortion due to frictional heat during cutting, and continuous processing While it is impossible to work
The manufacturing method of the present invention by etching does not have these problems, and even materials as thin as 4 to 5 mm can be easily processed, which is highly effective in reducing the weight of the separator and material costs.
第3には、エツチング加工による本発明の製造方法は1
個のマスクパターンで処理するため、その仕上シに精度
誤差が全くなく、電池組立が容易になシ作業性が向上す
る。Thirdly, the manufacturing method of the present invention by etching is 1
Since processing is performed using individual mask patterns, there is no precision error in the finishing process, making battery assembly easier and improving work efficiency.
第4に、本発明製造方法によれば、果電部の突起形状及
び配列が導入する反応ガスの燃料室や酸化剤室での高分
散性と流れ性を最重視した構造に加工でき、それが複雑
で機械加工では不可能な形状でも容易にできることであ
る。Fourthly, according to the manufacturing method of the present invention, the shape and arrangement of the protrusions of the power generating part can be processed into a structure that emphasizes the high dispersibility and flowability of the introduced reactant gas in the fuel chamber and oxidizer chamber. It is possible to easily create shapes that are complex and impossible to machine.
以上述べたように本発明によれば、小型軽量化を図るこ
とができるセパレータを得ることができるという効果が
ある。さらに、また本発明によれば、ガスの流れに適し
た形状の集電用矢起を備えたセパレータを得ることがで
きるという効果もある。As described above, according to the present invention, it is possible to obtain a separator that can be made smaller and lighter. Furthermore, according to the present invention, it is possible to obtain a separator equipped with a current collection arrowhead having a shape suitable for the flow of gas.
第1図は燃料電池のセパレータの設置状態を示す原理的
構成図、第2図及び第3図は本発明の詳細な説明するた
めのものであって、1段堀りのエツチング後のセパレー
タを示す正面図及び断面図、第4図及び第5図は本発明
の詳細な説明するためのものであって、2段堀シのエツ
チング後のセパレータを示す原理図及び正面図、第6図
乃至第8図は集電用突起の形状をそれぞれ示す正面図、
第9図は第6図乃至第8図の集電用突起の形状を示す断
面図である。
11・・・電極セット部、12・・・燃料室、13・・
・集電用突起、14・・・燃料通路。
特許出願人 工業技術院長 川田裕部
第3図
第1I−図
第5図
1?−
第C図 第7図
/lFig. 1 is a basic configuration diagram showing the installation state of a separator in a fuel cell, and Figs. 2 and 3 are for explaining the present invention in detail, and show the separator after etching in the first stage. The front view and sectional view shown, FIGS. 4 and 5 are for explaining the present invention in detail, and the principle view and front view showing the separator after etching of the two-stage trench, and FIGS. Figure 8 is a front view showing the shape of the current collecting protrusions;
FIG. 9 is a sectional view showing the shape of the current collecting protrusion shown in FIGS. 6 to 8. FIG. 11... Electrode set part, 12... Fuel chamber, 13...
- Current collection protrusion, 14... fuel passage. Patent applicant: Director of the Agency of Industrial Science and Technology Hirobe Kawada Figure 3 Figure 1I - Figure 5 Figure 1? - Figure C Figure 7/l
Claims (1)
において、セパレータ材に7ノード・カソード用の電極
の面積と厚さに応じたエツチングマスクを被覆してエツ
チング液に所定時間浸漬する工程と、セパレータ材に燃
料・酸化剤のガスが分散する形状のエツチングマスクを
かぶせてエツチング液に所定時間浸漬する工程とを有す
ることを゛骨徴とする燃料電池のセパレータの製造方法
。1. In a manufacturing method for manufacturing a separator for a molten salt fuel cell, the step of covering the separator material with an etching mask corresponding to the area and thickness of the 7-node cathode electrode and immersing it in an etching solution for a predetermined time; A method for manufacturing a fuel cell separator, the main feature of which is to cover the separator material with an etching mask shaped to disperse fuel/oxidant gas and immerse it in an etching solution for a predetermined time.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59096607A JPS60241658A (en) | 1984-05-16 | 1984-05-16 | Manufacture of fuel cell separator |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59096607A JPS60241658A (en) | 1984-05-16 | 1984-05-16 | Manufacture of fuel cell separator |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS60241658A true JPS60241658A (en) | 1985-11-30 |
Family
ID=14169551
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59096607A Pending JPS60241658A (en) | 1984-05-16 | 1984-05-16 | Manufacture of fuel cell separator |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60241658A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2811140A1 (en) * | 2000-06-30 | 2002-01-04 | Aisin Takaoka Ltd | Method for manufacturing fuel cell separators, comprises placing mask on material to be treated, injecting electrolyte perpendicularly on to material face through an electrode and removing mask |
KR100429685B1 (en) * | 2001-12-17 | 2004-05-03 | 한국과학기술연구원 | Gas- distributing plate for compact polymer electrolyte membrane fuel cell and separator plate using the said gas-distributing plate |
EP1282183A3 (en) * | 2001-07-27 | 2005-10-05 | Hewlett-Packard Company | Bipolar plates and end plates for fuel cells and methods for making the same |
JP2006134866A (en) * | 2004-11-02 | 2006-05-25 | General Electric Co <Ge> | Flow field structure of fuel cell of high fuel utilization rate |
KR100737551B1 (en) * | 2006-07-04 | 2007-07-10 | 현대자동차주식회사 | Fuel cell vehicle separator structure and the manufacturing method |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58131664A (en) * | 1982-01-29 | 1983-08-05 | Hitachi Ltd | Fuel cell |
-
1984
- 1984-05-16 JP JP59096607A patent/JPS60241658A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58131664A (en) * | 1982-01-29 | 1983-08-05 | Hitachi Ltd | Fuel cell |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2811140A1 (en) * | 2000-06-30 | 2002-01-04 | Aisin Takaoka Ltd | Method for manufacturing fuel cell separators, comprises placing mask on material to be treated, injecting electrolyte perpendicularly on to material face through an electrode and removing mask |
EP1282183A3 (en) * | 2001-07-27 | 2005-10-05 | Hewlett-Packard Company | Bipolar plates and end plates for fuel cells and methods for making the same |
US8263259B2 (en) | 2001-07-27 | 2012-09-11 | Eveready Battery Company, Inc. | Bipolar plates and end plates for fuel cells and methods for making the same |
KR100429685B1 (en) * | 2001-12-17 | 2004-05-03 | 한국과학기술연구원 | Gas- distributing plate for compact polymer electrolyte membrane fuel cell and separator plate using the said gas-distributing plate |
JP2006134866A (en) * | 2004-11-02 | 2006-05-25 | General Electric Co <Ge> | Flow field structure of fuel cell of high fuel utilization rate |
KR100737551B1 (en) * | 2006-07-04 | 2007-07-10 | 현대자동차주식회사 | Fuel cell vehicle separator structure and the manufacturing method |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0068508B1 (en) | Methanol fuel cell | |
JPH11510637A (en) | Plastic platelet fuel cell with centralized fluid treatment | |
JP3064023B2 (en) | Gas separator for fuel cells | |
JPH05109415A (en) | Gas separator for fuel cell | |
JPS61216257A (en) | Separator for fuel cell | |
KR101628653B1 (en) | Saperator for solid oxide fuel cell and fuel cell having thereof and method for manufacturing the same | |
JPS60241658A (en) | Manufacture of fuel cell separator | |
US3471338A (en) | Method of making a fuel cell electrode | |
JP2000100452A (en) | Solid high polymer electrolyte fuel cell and manufacture therefor | |
JP3057342B2 (en) | Solid electrolyte fuel cell | |
JPH07166301A (en) | Separator for solid electrolyte fuel cell | |
JPH0462757A (en) | Solid electrolyte type fuel cell | |
JPH0282456A (en) | Fuel cell | |
JPS5996668A (en) | Bipolar separator for fuel cell | |
JPS62147664A (en) | Reaction gas supply method in fuel cell | |
JPH03238758A (en) | Fuel cell of solid electrolyte type | |
JPH1032012A (en) | Phosphoric acid fuel cell and manufacture thereof | |
JPS6012670A (en) | Molten carbonate fuel cell | |
JPS58129787A (en) | Fused carbonate fuel cell layer body | |
JPS6124165A (en) | Electrolyte supporter of fused carbonate type fuel cell | |
JPH04138670A (en) | Solid electrolyte type fuel cell | |
JPS60207252A (en) | Method of fusing electrode for molten carbonate fuel cell | |
JP2972925B2 (en) | Water electrolyzer using solid polymer electrolyte membrane | |
JPH10241715A (en) | Fused carbonate type fuel cell | |
JPS62252074A (en) | Matrix for fuel cell |