JPS60212394A - Image-receiving body - Google Patents

Image-receiving body

Info

Publication number
JPS60212394A
JPS60212394A JP59070548A JP7054884A JPS60212394A JP S60212394 A JPS60212394 A JP S60212394A JP 59070548 A JP59070548 A JP 59070548A JP 7054884 A JP7054884 A JP 7054884A JP S60212394 A JPS60212394 A JP S60212394A
Authority
JP
Japan
Prior art keywords
image
image receptor
resin
transfer recording
color
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP59070548A
Other languages
Japanese (ja)
Other versions
JPH0671834B2 (en
Inventor
Toshio Niwa
俊夫 丹羽
Yukichi Murata
勇吉 村田
Takao Hirota
広田　隆男
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Kasei Corp
Original Assignee
Mitsubishi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Kasei Corp filed Critical Mitsubishi Kasei Corp
Priority to JP59070548A priority Critical patent/JPH0671834B2/en
Publication of JPS60212394A publication Critical patent/JPS60212394A/en
Publication of JPH0671834B2 publication Critical patent/JPH0671834B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/529—Macromolecular coatings characterised by the use of fluorine- or silicon-containing organic compounds

Abstract

PURPOSE:To provide an image-receiving body capable of being favorably released from a color sheet after transfer recording, wherein a releasing agent is incorporated in an image-receiving layer comprising a thermoplastic resin as a main constituent and formed on the surface of a base for an image-receiving body for sublimation thermal transfer recording. CONSTITUTION:A resin solution obtained by using a thermoplastic resin (preferably, an acrylic resin) as a main constituent and mixing a releasing agent (preferably, a silicon compound such as polysiloxane) therewith, ordinarily followed by adding particulate silica or the like for improving fixability, is applied to the surface of a base for the image-receiving body for sublimation thermal transfer recording to provide an image-receiving layer comprising the resin and the releasing agent, thereby obtaining the image-receiving body. The releasing agent is preferably used in an amount of 1-80wt% to the resin.

Description

【発明の詳細な説明】 本発明は昇華感熱転写記録用受像体に関ｊる。[Detailed description of the invention] The present invention relates to an image receptor for sublimation thermal transfer recording.

近年急速に普及しつつあるファクシミリ、プリンタ、複
写機等のＯＡ端末機は、視覚的に見易いカラー記録の要
望が高まり七おり、さらにテレビ画像をカラー記録する
技術の開発が望まれている。OA terminals such as facsimile machines, printers, and copiers, which have become rapidly popular in recent years, are in high demand for visually easy-to-read color recording, and there is also a desire for the development of technology for recording television images in color.

現在これらの目的のために亀子写真、インキジェット、
感熱転写記録方式などによるカラー記録技術が検討され
ている。Currently for these purposes Kameko Photo, Inkjet,
Color recording technology using a thermal transfer recording method is being considered.

これらの中にあって感熱転写記録方式は装置の保守、操
作性が容易で、装置及び消耗品が女価であるため他の方
式に比べて有利と考えられる。Among these, the thermal transfer recording method is considered to be advantageous over other methods because the device is easy to maintain and operate, and the device and consumables are inexpensive.

感熱転写記録方式は、シート状基体上に色素結着剤（バ
インダー）等ン含むインキ塗布面ス１５部シートのイン
キ塗布面を受像体に電ね合せ、カラーシートの背面を感
熱ヘッドで加熱して、カラーシート中の色素を受像体に
転写させることにより記録が行なわれる。In the thermal transfer recording method, the ink-coated surface of the 15-part sheet containing a dye binder is placed on a sheet-like substrate, and the ink-coated surface of the sheet is electrically connected to the image receptor, and the back side of the color sheet is heated with a thermal head. Recording is performed by transferring the dye in the color sheet to the image receptor.

感熱転写方式には熱溶融性インキを塗布したカラーシー
トな用いる溶融転写方式と昇華性色素ｖ含むインキを塗
布したカラーシートを用いる昇華転写方式があるが、昇
華転写方式は感熱ヘッドに与えるエネルギーな調整する
ことにまり色素の昇華転写ｔを制御することができるた
め、階調表現が容易でフルカラー記録に特に有利である
。Thermal transfer methods include the melt transfer method, which uses a color sheet coated with heat-melting ink, and the sublimation transfer method, which uses a color sheet coated with ink containing a sublimable dye, but the sublimation transfer method uses less energy given to the thermal head. Since the sublimation transfer t of the dye can be controlled through adjustment, gradation expression is easy and it is particularly advantageous for full-color recording.

昇華転写記録方式において、受像体は、カラーシートか
ら昇華した色素を受像体に染着させる必要がある定め、
受像体表面には、使用する色素と親和性の高い熱可塑性
の樹脂な主成分にした７７　（以後、受像層と呼ぶ）を
有するが、一般に感熱ヘッドの温度は一〇Ｏ′Ｃ以上に
もなるため、カラーシートのインキバインター−および
受像層の熱可塑性樹脂が熱により軟化あるいは融解し、
カラーシートと受像体が融着し、記録後剥離が困離とな
る問題を有している。In the sublimation transfer recording method, the image receptor is required to be dyed with the dye sublimated from the color sheet.
The surface of the image receptor has a layer 77 (hereinafter referred to as the image-receiving layer) made of a thermoplastic resin that has a high affinity with the dye used, but the temperature of the thermal head generally exceeds 10 O'C. As a result, the ink binder of the color sheet and the thermoplastic resin of the image-receiving layer soften or melt due to heat.
There is a problem in that the color sheet and the image receptor are fused together, making it difficult to peel them off after recording.

このカラーシートと受像体との融着な防止する方法とし
て、受像層に、架橋性の樹脂を用いることにより耐熱性
を向上させる方法（特開昭５ｔｒ−コ／３．）りｇ、特
開昭５ｇ−コｔ２ｑｑａ　）あるいは受像ノーの樹脂中
に顔料を加えることにより受像層表面ン粗面化する方法
（特開昭５７−１０７ざｇｓ）などが提案されている。As a method for preventing the color sheet from fusing with the image receptor, a method of improving heat resistance by using a crosslinking resin in the image receiving layer (Japanese Patent Application Laid-open No. 5 TR-CO/3.) A method has been proposed in which the surface of the image-receiving layer is roughened by adding a pigment to the image-receiving resin (Japanese Patent Application Laid-Open No. 107-1989).

本発明は、上述の昇華感熱転写記録において、受像体と
カラーシートとの、転写記録後の剥離性の良好な受像体
の提供を目的とするものである。An object of the present invention is to provide an image receptor with good releasability after transfer recording between the image receptor and a color sheet in the above-mentioned sublimation thermal transfer recording.

すなわち、本発明は、昇華感熱転写記録用受像体の基体
の表面に形成された熱可塑性樹脂を主成分とする受像層
が、離型剤を含むことを特徴とする受像体なその要旨と
するものである。That is, the gist of the present invention is an image receptor for sublimation thermal transfer recording, characterized in that an image receptor layer mainly composed of a thermoplastic resin formed on the surface of the base of the image receptor contains a release agent. It is something.

本発明の受像体は、受像体の基体上に、昇華性色素と親
和性の良好な熱可塑性樹脂を塗布し、受像層を形成する
ことにより作製されるが、受像層中に離型剤を含有させ
るためには、偏脂液中に離型剤を添加し、塗布する方法
又は、樹りぼ液塗布後、その上に離型剤を含む液を塗布
することにより実施される◎ 本発明に使用される離型剤としては、通常、離型剤、滑
剤などとして使用されているもので脂肪酸、高級脂肪酸
の金属塩、高級脂肪酸エステル、高級脂肪酸アミドまた
は高級アルコールなどから選ばれる物質があげられ、そ
れらは単独あるいは混合物の形で使用することができる
。The image receptor of the present invention is produced by coating a thermoplastic resin having good affinity with sublimable dyes on the substrate of the image receptor to form an image receiving layer. In order to contain the mold release agent, it is carried out by adding a mold release agent to the polarized fat liquid and applying it, or by applying a liquid containing the mold release agent thereon after applying the tree liquid.◎ This invention The mold release agent used for mold release is normally used as a mold release agent or lubricant, and includes substances selected from fatty acids, metal salts of higher fatty acids, higher fatty acid esters, higher fatty acid amides, higher alcohols, etc. They can be used alone or in mixtures.

具体例としてケイ素系化合物としては、液状、半固体状
又は固体状のシリコン系化合物があげられ、具体的には
ポリシロキサン、ケイ酸エステル構造な基本構過として
持つ化合物があげられ、これらは置換基としてカルボキ
シル基、アミノ基、ダ級化アミノ基、フッ素原子などを
有することもでき、更に三次元的網状構造をもつけ固体
状のフルオロカーボン系化合物があげらアルキル基を有
する炭化水素類、アルコール類、カルボン酸類、スルホ
ン酸頑、スルホン酸塩類、スルホンアミド類などがあげ
られる。Specific examples of silicon-based compounds include liquid, semi-solid, or solid silicon-based compounds, and specific examples include polysiloxane and compounds with a silicate ester structure as their basic structure, and these are substituted. Hydrocarbons having an alkyl group, alcohols, etc. can have a carboxyl group, an amino group, a d-classified amino group, a fluorine atom, etc. as a group, and can also have a three-dimensional network structure and are solid fluorocarbon compounds. Examples include carboxylic acids, sulfonic acids, sulfonate salts, and sulfonamides.

ワックス類としては、パラフィンワックス、塩素化パラ
フィンワックス、マイクロクリスタリンワックス、ポリ
エチレンワックス、セレシンワックス、モンタンワック
ス、カルナバワックス、キャンデリラワックス、木ろう
、密ろうなどの合成及び天然のワックスがあげられる。Examples of waxes include synthetic and natural waxes such as paraffin wax, chlorinated paraffin wax, microcrystalline wax, polyethylene wax, ceresin wax, montan wax, carnauba wax, candelilla wax, wood wax, and beeswax.

高級脂肪酸としては、ステアリン酸、オレイン酸、パル
ミチン酸、ラウリン酸、ミリスチン酸、セバシン酸など
があけられる。Examples of higher fatty acids include stearic acid, oleic acid, palmitic acid, lauric acid, myristic acid, and sebacic acid.

高級脂肪酸の金属塩としＣは、上記高級脂肪酸のＢａ、
　Ｃａ、　Ｚｎ、　ＡＩ、　Ｍｇ　などの塩があけられ
る。The metal salt of higher fatty acid C is Ba of the above-mentioned higher fatty acid,
Salts such as Ca, Zn, AI, Mg, etc. can be extracted.

高級脂肪酸エステルとしては、上記高級脂肪酸のアルコ
ール類、グリコール−などとのエステル類があげられる
。Examples of higher fatty acid esters include esters of the above-mentioned higher fatty acids with alcohols, glycols, and the like.

高級脂肪酸アミドとしては、上記Ｊｊｄ肪酸とアンモニ
ア、アルキルアミン−、アルキレンジアミン類などとの
アミド類があげられ、具体的にはステアリン酸アミド、
パルミチン酸アミド、メチレンビスステアリルアミド、
エチレンビスステアリルアミドなどがあげられる・ 高級アルコールとしてはラウリルアルコール、ミリスチ
ルアルコール、セチルアルコール、ステアリルアルコー
ル、ベヘニルアルコールなどがあけられる。Examples of higher fatty acid amides include amides of the above-mentioned Jjd fatty acids and ammonia, alkylamines, alkylene diamines, etc., and specifically stearic acid amides,
palmitic acid amide, methylene bisstearylamide,
Examples include ethylene bisstearylamide. Examples of higher alcohols include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, and behenyl alcohol.

上記離型剤は使用に際して、そのままの形で樹脂液に添
〃口して使用することもできるが、有機溶剤あるいは水
の溶液、あるいは水に対するエマルジョン、サスペンシ
ョンの形テ使用’ｆ　ルこともできる。When using the above mold release agent, it can be used as it is by adding it to the resin liquid, but it can also be used in the form of an organic solvent or water solution, or an emulsion or suspension in water. .

離型剤の添加量としては受像層形成のために使用される
熱可塑性樹脂に対して、θ／　−／　！；　０重量％の
間で使用することができるが、添加量が少ない場合には
効果が小さく、又添加量が多いと染料の発色性及び記録
の保存安定性が低下するなどの問題が生じるためｔｚｉ
ｒｏ重量％、の添加量が適当である。The amount of release agent added is θ/-/! with respect to the thermoplastic resin used for forming the image-receiving layer. ; It can be used at between 0% by weight, but if the amount added is small, the effect will be small, and if the amount added is too large, problems will occur, such as a decline in the color development of the dye and the storage stability of records. tzi
An appropriate addition amount is ro% by weight.

受像層形成のために使用される熱可塑性樹脂としては、
昇華性色素は、一般に分散染料が使用されるため、それ
ら色素と親和性の高い熱可ｍｌ性樹脂が選ばれ、具体的
には、ポリエチレンテレフタレート、ポリブチレンテレ
フタレートなどを主成分とする飽和線状ポリエステル樹
脂、ポリメチルメタアクリレート、ポリブチルメタクリ
レート、ポリメチルアクリレート、ポリブチルアクリレ
ートなどのアクリル系樹脂、ポリスチレン樹脂、ｈｓ衝
脂、ボリカーボネー・ト樹脂、ボリアリレート樹脂、ポ
リスルホン樹脂、ポリビニルピロリドン、エチルセルロ
ース、フセチルセルロースなどがあげられるが、飽和線
状ポリエステル樹脂及びアクリル系樹脂上分散染料（色
素）との親和力が良好である。Thermoplastic resins used for forming the image-receiving layer include:
As disperse dyes are generally used as sublimable dyes, thermoplastic resins with high affinity for these dyes are selected. Specifically, saturated linear resins containing polyethylene terephthalate, polybutylene terephthalate, etc. as main components Acrylic resins such as polyester resins, polymethyl methacrylate, polybutyl methacrylate, polymethyl acrylate, polybutyl acrylate, polystyrene resins, HS resins, polycarbonate resins, polyarylate resins, polysulfone resins, polyvinylpyrrolidone, ethyl cellulose, Examples include cetyl cellulose, which has good affinity with dispersed dyes (pigments) on saturated linear polyester resins and acrylic resins.

上記熱可塑性樹脂を受像体上に塗布する際には、該樹脂
が固形物あるいは粘度の高い液体等の場合は、たとえば
、適当な溶剤に該樹脂な適当な饋度に溶解し、得られた
溶液を受像体上に塗布し、次いで溶剤を除去する方法ン
採用することができる。When applying the above thermoplastic resin onto an image receptor, if the resin is a solid or a liquid with high viscosity, the resin is dissolved in an appropriate solvent to an appropriate degree of fragility. A method can be employed in which the solution is applied onto the image receptor and then the solvent is removed.

溶剤としては、メタノール、エタノール、プロパツール
等のアルコール類、メチルセロソルブ、メチルセロソル
ブ等のセロソルブ−、ベンゼン、トルエン、キシレン、
クロルベンゼン等の芳香族溶剤、酢酸エチル、酢酸ブチ
ル等のエステル類、アセトン、メチルエテルケトン、メ
チルイソブチルケトン、シクロヘキサノン等のケトン類
、クロロホルム、塩化メチレン、トリクロロエチレン等
の塩素溶剤、セしてジメチルホルムアミド、Ｎ−メチル
ピロリドン等の各種溶剤ン適宜使用すればよい。Examples of solvents include alcohols such as methanol, ethanol, propatool, cellosolves such as methyl cellosolve, methyl cellosolve, benzene, toluene, xylene,
Aromatic solvents such as chlorobenzene, esters such as ethyl acetate and butyl acetate, ketones such as acetone, methyl ether ketone, methyl isobutyl ketone, and cyclohexanone, chlorinated solvents such as chloroform, methylene chloride, and trichloroethylene, and dimethylformamide , N-methylpyrrolidone and the like may be used as appropriate.

受像層中には上記熱可塑性樹脂及び離型剤の他に色素の
発色性及び定着性を改良するために通常微粒子状のシリ
カが添加されるが、更に必要に応じて、紫外線吸収剤、
酸化防止剤、螢光増白剤などを添加しても良ｂ６ 受像層を形成するため［に受像体基体上に樹脂液に離型
剤及び前記の添加剤を配合し、塗布するか、離型剤を含
まない樹脂液を塗布、乾保後更に、離型剤液をその上に
塗布することにより実施できる０塗布の方法としては、
リノ（−スロールコータ、グラビアコータ、ロッドコー
タ、エアドクタコータなどを使用して実施することがで
きる（原崎勇次著、槙書店、１９７７年発行「コーティ
ング方式」）。In addition to the above-mentioned thermoplastic resin and release agent, fine particulate silica is usually added to the image-receiving layer in order to improve the color development and fixing properties of the dye, and if necessary, an ultraviolet absorber,
Antioxidants, fluorescent brighteners, etc. may be added.b6 To form an image-receiving layer, mix a mold release agent and the above additives with a resin liquid and apply or release onto the image-receptor substrate. A 0-coating method that can be carried out by applying a resin liquid that does not contain a mold agent, keeping it dry, and then applying a mold release agent liquid on top of it is as follows:
It can be carried out using a roller coater, gravure coater, rod coater, air doctor coater, etc. ("Coating Method" by Yuji Harasaki, published by Maki Shoten, 1977).

基体上に形成される受像ノーの厚さは乾煉後、＆／−／
１７ｐｍの範囲、特に好ましく　ｕ　／＝３　ｐｍの範
囲が適当である。The thickness of the image receiving layer formed on the substrate is &/-/ after drying.
A range of 17 pm, particularly preferably a range of u/=3 pm, is suitable.

受像体の基体としては、セルロース繊維ヨリ形成される
普通紙、曾成樹脂より形成されろ会成紙あるいにプラス
チックのフィルムなどが使用される。As the substrate of the image receptor, plain paper made of cellulose fibers, laminated paper made of synthetic resin, plastic film, etc. are used.

以下実施例により本発明を具体的に説明するが本実施例
は本発明を限定するものではない。EXAMPLES The present invention will be specifically explained below with reference to Examples, but these Examples are not intended to limit the present invention.

実施例１ ａ）カラーシートの製造 ＣＩディスパースブブルｌ弘染料　コｔエテルセルロー
ス　ＩｆＦ インプロパノ−Ａ／　９０７ 合計　１００ｆ 上記組成の混合物なガラスピーズな使用するペイントコ
ンディショナーで約３０分間処理することによりｗ４Ｍ
したインキｔグラビア校正機（版深ＪＯｐｍ）を用いコ
ンデンサー紙（／（７／ｊｍ）に塗布、乾燥し、カラー
シートを製造した。Example 1 a) Manufacture of color sheet CI Disperse Bubble L Hong Dyes Cot Ether Cellulose IfF Impropano-A/907 Total 100f W4M was treated for about 30 minutes with a paint conditioner using glass beads, which is a mixture of the above composition.
The ink was applied onto condenser paper (/(7/jm)) using a gravure proofing machine (Hanshin JOpm) and dried to produce a color sheet.

ｂ）受像体の製造 ポリエステル樹脂水分散液（商品名二ノクイロナールＭ
Ｄ−／２０θ、東洋紡株式会社製、固形分３＊％）１０
ｆｉ’、コロイダルシリカ（商品名：スノーテツクスダ
θ、日産化学株式会社製造、シリカ含有１ｔｌＩｏ％）
ｌＯｙ−、エマルショアタイプシリコン系離型剤（商品
名：ＫＭ−？ダ０１信越化学工業株式会社製造、シリコ
ン化合物含有ｆｎ、？Ｊ３ｇ％）　！ｒ　ｆ’−Ｙ配合
し、調整した液を坪量ｉｏ弘７ｖ曾のアート紙にバーコ
ーターノｈ３（ウェット膜厚コ亭μｍ）で塗布後、ドラ
イヤーで熱風乾燥し、受像体を製造したＯ Ｃ）転写記録結果 上記カラーシートのインキ塗布面を上記受像体の受像層
に重ねダドット／順の発熱抵抗体密度を持つ感熱ヘッド
を使用して０．４　Ｗ　／ドツトの電力′？：コ、ダ、
６、ざおよび１０ミリ秒印加して記録を行なった。記録
の除、カラーシートと受像体が融着することなく記録後
、カラーシートと受像体を簡単に剥離することができた
。又得られた記録は上記の印加時間に応じて各々ａｉ、
ｏ、コ、０．ダ、Ｑ６およびＱ９の色濃度を持つ鮮明な
シアン色を示し、各ドツトの−ターＲＤ−ｖｉｑｆＪｌ
　（フィルター：ラツテン應コ１）を用いて測定した。b) Production of image receptor Polyester resin aqueous dispersion (trade name Ninoquilonal M
D-/20θ, manufactured by Toyobo Co., Ltd., solid content 3*%) 10
fi', colloidal silica (product name: Snowtexuda θ, manufactured by Nissan Chemical Co., Ltd., silica content 1tlIo%)
lOy-, emulsion type silicone mold release agent (product name: KM-?da01 manufactured by Shin-Etsu Chemical Co., Ltd., silicon compound content fn,?J3g%)! The prepared solution was applied to art paper with a basis weight of 7 mm using a bar coater H3 (wet film thickness: μm), and then dried with hot air using a dryer to produce an image receptor (OC). Transfer Recording Results The ink-coated surface of the color sheet was superimposed on the image receiving layer of the image receptor, and a thermal head having a heating resistor density of 0.4 W/dot was used to generate a power of 0.4 W/dot. :Ko, da,
Recording was performed by applying 6 seconds and 10 milliseconds. After recording, the color sheet and image receptor could be easily peeled off without any fusion between the color sheet and the image receptor. In addition, the obtained records are ai, respectively, depending on the above application time.
o, ko, 0. It shows a clear cyan color with color densities of Da, Q6 and Q9, and each dot's -tarRD-viqfJl
(Filter: RATSUTENKO 1).

色濃度は下記式により計算される。Color density is calculated using the following formula.

色濃Ｆｉｌ　−ｌｏｇｌＯ（Ｉｏ／　Ｉ　）Ｉｏ−標準
白色反射板からの反射光の強さＩ−試験物体からの反射
光の強さ 比較例１ ａ）受像体の製造 離型剤を添加することなく他は実施例１と同様の方法に
より製造した口 ｂ）転写記録結果 上記受像体と前記のカラーシートな用いて実施例１と同
様の方法により転写記録な行なった結果印加時間６、ｇ
およびｉｏ秒に於てはカラーシートと受像体とが融着し
、記録後剥離することが困難であった。Color intensity Fil -loglO(Io/I)Io - Intensity of reflected light from standard white reflector I - Intensity of reflected light from test object Comparative example 1 a) Production of image receptor Adding a release agent b) Result of transfer recording Transfer recording was carried out in the same manner as in Example 1 using the above-mentioned image receptor and the above-mentioned color sheet.
At io seconds, the color sheet and image receptor were fused and it was difficult to separate them after recording.

実施例コ 実施１ｄＪ　／で使用したシリコン系離屋剤のかわりに
酸化パラフィンのエマルジョン（商品名：Ｄｌａｐｒｏ
ｏｆ　Ｇ　、三菱化成工業株式会社製造、固形分ｐｙ％
）５？な加えて実施例１と同じ方法で受像体を製造し、
前記のカラーシートな用いて実施例１と同様の方法によ
り転写記録な行なった結果、記録後カラーシートと受像
体ｙ！′簡単に剥離することができ、得られた記録は階
調性、解像性が良好で鮮明なシアン色す示した。In place of the silicone-based building release agent used in Example 1dJ/, an emulsion of paraffin oxide (trade name: Dlapro) was used.
of G, manufactured by Mitsubishi Chemical Industries, Ltd., solid content py%
)5? In addition, an image receptor was manufactured by the same method as in Example 1,
Transfer recording was performed using the color sheet described above in the same manner as in Example 1. After recording, the color sheet and the image receptor y! 'It could be easily peeled off, and the resulting record showed a clear cyan color with good gradation and resolution.

実施例３〜ｇ ポリエステル樹脂（商品名：バイロンａＯＯ。Examples 3-g Polyester resin (product name: Byron aOO.

東洋紡株式会社製造）コＯ？をメチルエチルクトン１０
０−に溶解し、表７に示す離厘剤ｙｒ？添加した液を使
用して実差例１と同様の方法により受像体を製造し、前
記のカラーシートを用いて、実施例１と同様の方法によ
り転写記録を行なった結果、各々の場合記録後カラーシ
ートと受像体な簡単に剥離することかでき、得られた記
録は階調性、解像性が良好で鮮明なシアン色な示した・ 表　ｌ ＊　商品名エフトップＥＦ−／コ／（Ｉｉ秋田化成株式
） 比較例コ 離戴剤を添加することなく他は、実施例３〜ざと同様の
方法で製造した受像体と前記カラーシートラ用い実施例
１と同様の方法により転写記録を行なった結果、カラー
シートと受像体が融着し、ｄ己録後剥離することが困雌
であった。Manufactured by Toyobo Co., Ltd.) KoO? Methyl ethyl lactone 10
The release agent yr? dissolved in 0- and shown in Table 7. An image receptor was manufactured in the same manner as in Example 1 using the added liquid, and transfer recording was performed in the same manner as in Example 1 using the color sheet. The color sheet and image receptor can be easily separated, and the resulting record shows a clear cyan color with good gradation and resolution. (Ii Akita Kasei Co., Ltd.) Comparative Example Transfer recording was carried out in the same manner as in Example 1 using an image receptor manufactured in the same manner as in Examples 3 to 3 and the color sheeter, except that no release agent was added. As a result, the color sheet and the image receptor were fused together, causing them to peel off after recording, which was a problem.

実施例？ 希釈しバーコーターＡ／（ウェット膜厚６μｍ）で塗布
、乾燥し製造した受像体と前記カラージ−トン用い実施
例１と同様の方法により転写記録を行なった結果、記録
後カラーシートと受像体を簡単に剥離することができ、
得られた配録は階調性、解像性が良好で鮮明なシアン色
を示した。Example? Transfer recording was performed in the same manner as in Example 1 using the image receptor manufactured by diluting and coating with Bar Coater A (wet film thickness 6 μm) and drying. As a result, after recording, the color sheet and image receptor were can be easily peeled off,
The resulting recording had good gradation and resolution, and exhibited a clear cyan color.

出願人　三菱化成工業株式会社 代理人　弁理士　長谷用　− はか１名Applicant: Mitsubishi Chemical Industries, Ltd. Agent Patent Attorney Hase - 1 person

Claims (1)

【特許請求の範囲】 口）　昇華感熱転写記録用受像体の基体の表面に形成さ
れた熱可塑性樹脂を主成分とする受像層が、離製剤を含
むことを特徴とする受像体。 金物、ワックス類、高級脂肪酸、高級脂肪酸の金″属塩
、高級脂肪ばエステル、高級脂肪酸アミド、または縄級
アルコールであることを特徴とする受像体。[Scope of Claims] An image receptor for sublimation thermal transfer recording, characterized in that an image receptor layer containing a thermoplastic resin as a main component and formed on the surface of a base of the image receptor contains a release agent. An image receptor characterized by being a metal, a wax, a higher fatty acid, a metal salt of a higher fatty acid, a higher fatty acid ester, a higher fatty acid amide, or a rope-grade alcohol.
JP59070548A 1984-04-09 1984-04-09 Image receptor Expired - Lifetime JPH0671834B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP59070548A JPH0671834B2 (en) 1984-04-09 1984-04-09 Image receptor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP59070548A JPH0671834B2 (en) 1984-04-09 1984-04-09 Image receptor

Related Child Applications (2)

Application Number Title Priority Date Filing Date
JP3076349A Division JP2605963B2 (en) 1991-04-09 1991-04-09 Receiver
JP4313654A Division JPH05193275A (en) 1992-11-24 1992-11-24 Manufacture of image-receiving medium

Publications (2)

Publication Number Publication Date
JPS60212394A true JPS60212394A (en) 1985-10-24
JPH0671834B2 JPH0671834B2 (en) 1994-09-14

Family

ID=13434679

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59070548A Expired - Lifetime JPH0671834B2 (en) 1984-04-09 1984-04-09 Image receptor

Country Status (1)

Country Link
JP (1) JPH0671834B2 (en)

Cited By (52)

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JPS6127290A (en) * 1984-07-17 1986-02-06 Dainippon Printing Co Ltd Thermal transfer sheet
JPS6127282A (en) * 1984-07-17 1986-02-06 Dainippon Printing Co Ltd Production of thermal transfer recording sheet
JPS61177289A (en) * 1985-02-01 1986-08-08 Matsushita Electric Ind Co Ltd Image-receiving material for transfer-type thermal recording
JPS61211092A (en) * 1985-03-15 1986-09-19 Matsushita Electric Ind Co Ltd Image-receiving material for transfer-type thermal recording
JPS6216191A (en) * 1985-07-15 1987-01-24 Sony Chem Kk Thermal transfer method
JPS6237193A (en) * 1985-08-12 1987-02-18 Mitsubishi Paper Mills Ltd Image-receiving paper for sublimation-type thermal transfer
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EP0227092A2 (en) * 1985-12-24 1987-07-01 EASTMAN KODAK COMPANY (a New Jersey corporation) Release agent for thermal dye transfer
JPS62201290A (en) * 1986-02-28 1987-09-04 Nippon Telegr & Teleph Corp <Ntt> Sublimation type thermal transfer image receiving member
JPS62238791A (en) * 1986-04-11 1987-10-19 Dainippon Printing Co Ltd Transfer printing sheet and decorating method therefor
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JPS62282982A (en) * 1986-06-02 1987-12-08 Nippon Telegr & Teleph Corp <Ntt> Image receiving sheet
JPS62294596A (en) * 1986-06-16 1987-12-22 Mitsubishi Chem Ind Ltd Image receiving medium for thermal transfer recording using sublimable dye
JPS6367188A (en) * 1986-09-10 1988-03-25 Mitsubishi Rayon Co Ltd Resin composition easily dyeable with sublimation dispersion dye
JPS6367189A (en) * 1986-09-10 1988-03-25 Mitsubishi Rayon Co Ltd Recording material in sublimation thermal transfer recording system
JPS6374693A (en) * 1986-09-18 1988-04-05 Mitsubishi Rayon Co Ltd Body to be recorded in sublimation-type thermal transfer recording method
JPS6374692A (en) * 1986-09-18 1988-04-05 Mitsubishi Rayon Co Ltd Sublimating dispersion-dye easily dyeable resin composition
JPS6374691A (en) * 1986-09-18 1988-04-05 Mitsubishi Rayon Co Ltd Sublimating dispersion-dye easily dyeable resin composition
JPS6374694A (en) * 1986-09-18 1988-04-05 Mitsubishi Rayon Co Ltd Body to be recorded in sublimation-type thermal transfer recording method
JPS6382791A (en) * 1986-09-26 1988-04-13 Matsushita Electric Ind Co Ltd Image-receiving material for sublimation transfer type thermal recording
JPS63319188A (en) * 1987-06-23 1988-12-27 Mitsubishi Kasei Corp Image-receiving material for thermal transfer recording
JPS641590A (en) * 1986-08-27 1989-01-05 Hitachi Ltd Thermal transfer printer, method and ink sheet used therefor
JPS644391A (en) * 1987-06-26 1989-01-09 Matsushita Electric Ind Co Ltd Image-receiving material for sublimation transfer type thermal recording
JPS645886A (en) * 1987-06-29 1989-01-10 Dainippon Printing Co Ltd Sheet to be thermally transferred
JPS6430792A (en) * 1987-07-27 1989-02-01 Toppan Printing Co Ltd Image receiving body for thermal transfer
JPS6430793A (en) * 1987-07-27 1989-02-01 Toppan Printing Co Ltd Image receiving body for thermal transfer
JPS6442284A (en) * 1987-08-11 1989-02-14 Mitsubishi Rayon Co Recording material for sublimation-type thermal transfer recording system
JPS6444781A (en) * 1987-08-13 1989-02-17 Dainippon Printing Co Ltd Sheet to be thermally transferred
JPS6487390A (en) * 1987-09-30 1989-03-31 Dainippon Printing Co Ltd Image receiving layer transfer sheet and image forming method employing the same
US4820687A (en) * 1983-07-25 1989-04-11 Dai Nippon Insatsu Kabushiki Kaisha Image receiving sheet and process for producing the same
JPH0196650A (en) * 1987-10-08 1989-04-14 Fuji Photo Film Co Ltd Image forming sheet
JPH01160682A (en) * 1987-12-18 1989-06-23 Dainippon Printing Co Ltd Image receiving layer transfer sheet
JPH01166991A (en) * 1987-12-23 1989-06-30 Nisshinbo Ind Inc Paper base sublimation type thermal transfer image receiving paper
JPH01176588A (en) * 1988-01-05 1989-07-12 Kanzaki Paper Mfg Co Ltd Sheet subjected to thermal transfer
JPH01202494A (en) * 1988-02-09 1989-08-15 Matsushita Electric Ind Co Ltd Image-receiving material for thermal transfer recording
EP0332204A2 (en) * 1988-03-11 1989-09-13 Dai Nippon Insatsu Kabushiki Kaisha Image-receiving sheet
JPH01232096A (en) * 1988-03-14 1989-09-18 Nisshinbo Ind Inc Production of sublimation-type thermal transfer image-receiving paper
EP0349141A2 (en) * 1988-06-29 1990-01-03 Imperial Chemical Industries Plc Receiver sheet
JPH024592A (en) * 1988-06-23 1990-01-09 Sanyo Chem Ind Ltd Image-receiving material for thermal transfer recording
EP0368550A2 (en) * 1988-11-11 1990-05-16 Imperial Chemical Industries Plc Thermal transfer receiver
US4927666A (en) * 1983-07-25 1990-05-22 Dai Nippon Insatsu Kabushiki Kaisha Image-receiving sheet
US4962080A (en) * 1988-03-08 1990-10-09 Kanzaki Paper Mfg. Co., Ltd. Image-receiving sheet for thermal dye-transfer recording
JPH0319892A (en) * 1989-06-16 1991-01-29 Dainippon Printing Co Ltd Thermal transfer image receiving sheet
US4997807A (en) * 1988-10-31 1991-03-05 Kanzaki Paper Mfg. Co., Ltd. Image-receiving sheet for thermal dye-transfer recording
JPH03275386A (en) * 1990-03-27 1991-12-06 Tomoegawa Paper Co Ltd Thermal transfer image receiving medium
US5095000A (en) * 1983-07-25 1992-03-10 Dai Nippon Insatsu Kabushiki Kaisha Image-receiving sheet
US5166127A (en) * 1988-03-11 1992-11-24 Dai Nippon Insatsu Kabushiki Kaisha Image-receiving sheet
US5232893A (en) * 1983-07-25 1993-08-03 Dai Nippon Insatsu Kabushiki Kaisha Heat transferable image-receiving sheet, heat transfer assembly and heat transfer process
JPH068661A (en) * 1984-07-04 1994-01-18 Dainippon Printing Co Ltd Thermal transfer image receiving sheet
JPH0648056A (en) * 1984-07-17 1994-02-22 Dainippon Printing Co Ltd Thermally transferred sheet
JP2007237643A (en) * 2006-03-10 2007-09-20 Fujifilm Corp Thermal transfer image-receiving sheet and method for forming image
US7799736B2 (en) 2006-03-09 2010-09-21 Fujifilm Corporation Heat-sensitive transfer image-receiving sheet and method of forming image

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JPS59165688A (en) * 1983-03-11 1984-09-18 Shin Nisso Kako Co Ltd Thermal transfer recording material
JPS6025793A (en) * 1983-07-25 1985-02-08 Dainippon Printing Co Ltd Sheet for heat transfer printing

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US5362703A (en) * 1983-07-25 1994-11-08 Dai Nippon Insatsu Kabushiki Kaisha Heat transferable sheet
US5281573A (en) * 1983-07-25 1994-01-25 Dai Nippon Insatsu Kabushiki Kaisha Heat transferable sheet
US4820687A (en) * 1983-07-25 1989-04-11 Dai Nippon Insatsu Kabushiki Kaisha Image receiving sheet and process for producing the same
US4927666A (en) * 1983-07-25 1990-05-22 Dai Nippon Insatsu Kabushiki Kaisha Image-receiving sheet
US5095000A (en) * 1983-07-25 1992-03-10 Dai Nippon Insatsu Kabushiki Kaisha Image-receiving sheet
US5232893A (en) * 1983-07-25 1993-08-03 Dai Nippon Insatsu Kabushiki Kaisha Heat transferable image-receiving sheet, heat transfer assembly and heat transfer process
JPH068661A (en) * 1984-07-04 1994-01-18 Dainippon Printing Co Ltd Thermal transfer image receiving sheet
JPS6127290A (en) * 1984-07-17 1986-02-06 Dainippon Printing Co Ltd Thermal transfer sheet
JPS6127282A (en) * 1984-07-17 1986-02-06 Dainippon Printing Co Ltd Production of thermal transfer recording sheet
JPH0648056A (en) * 1984-07-17 1994-02-22 Dainippon Printing Co Ltd Thermally transferred sheet
JPS61177289A (en) * 1985-02-01 1986-08-08 Matsushita Electric Ind Co Ltd Image-receiving material for transfer-type thermal recording
JPS61211092A (en) * 1985-03-15 1986-09-19 Matsushita Electric Ind Co Ltd Image-receiving material for transfer-type thermal recording
JPH0566273B2 (en) * 1985-07-15 1993-09-21 Sony Chemicals
JPS6216191A (en) * 1985-07-15 1987-01-24 Sony Chem Kk Thermal transfer method
JPH0465798B2 (en) * 1985-08-12 1992-10-21 Mitsubishi Paper Mills Ltd
US4757047A (en) * 1985-08-12 1988-07-12 Mitsubishi Paper Mills, Ltd. Sublimation-type thermal transfer image receiving paper
JPS6237193A (en) * 1985-08-12 1987-02-18 Mitsubishi Paper Mills Ltd Image-receiving paper for sublimation-type thermal transfer
JPS62116189A (en) * 1985-11-15 1987-05-27 Mitsubishi Chem Ind Ltd Image acceptor for thermal transfer recording using subliming dyestuff
EP0227092A2 (en) * 1985-12-24 1987-07-01 EASTMAN KODAK COMPANY (a New Jersey corporation) Release agent for thermal dye transfer
US4740496A (en) * 1985-12-24 1988-04-26 Eastman Kodak Company Release agent for thermal dye transfer
JPS62201290A (en) * 1986-02-28 1987-09-04 Nippon Telegr & Teleph Corp <Ntt> Sublimation type thermal transfer image receiving member
JPS62238791A (en) * 1986-04-11 1987-10-19 Dainippon Printing Co Ltd Transfer printing sheet and decorating method therefor
JPS62180558U (en) * 1986-05-06 1987-11-16
JPS62282982A (en) * 1986-06-02 1987-12-08 Nippon Telegr & Teleph Corp <Ntt> Image receiving sheet
JPS62294596A (en) * 1986-06-16 1987-12-22 Mitsubishi Chem Ind Ltd Image receiving medium for thermal transfer recording using sublimable dye
JPS641590A (en) * 1986-08-27 1989-01-05 Hitachi Ltd Thermal transfer printer, method and ink sheet used therefor
JPS6367189A (en) * 1986-09-10 1988-03-25 Mitsubishi Rayon Co Ltd Recording material in sublimation thermal transfer recording system
JPS6367188A (en) * 1986-09-10 1988-03-25 Mitsubishi Rayon Co Ltd Resin composition easily dyeable with sublimation dispersion dye
JPS6374691A (en) * 1986-09-18 1988-04-05 Mitsubishi Rayon Co Ltd Sublimating dispersion-dye easily dyeable resin composition
JPS6374692A (en) * 1986-09-18 1988-04-05 Mitsubishi Rayon Co Ltd Sublimating dispersion-dye easily dyeable resin composition
JPS6374693A (en) * 1986-09-18 1988-04-05 Mitsubishi Rayon Co Ltd Body to be recorded in sublimation-type thermal transfer recording method
JPS6374694A (en) * 1986-09-18 1988-04-05 Mitsubishi Rayon Co Ltd Body to be recorded in sublimation-type thermal transfer recording method
JPH0533916B2 (en) * 1986-09-26 1993-05-20 Matsushita Electric Ind Co Ltd
JPS6382791A (en) * 1986-09-26 1988-04-13 Matsushita Electric Ind Co Ltd Image-receiving material for sublimation transfer type thermal recording
JPS63319188A (en) * 1987-06-23 1988-12-27 Mitsubishi Kasei Corp Image-receiving material for thermal transfer recording
JPS644391A (en) * 1987-06-26 1989-01-09 Matsushita Electric Ind Co Ltd Image-receiving material for sublimation transfer type thermal recording
JPS645886A (en) * 1987-06-29 1989-01-10 Dainippon Printing Co Ltd Sheet to be thermally transferred
JPH0523600B2 (en) * 1987-07-27 1993-04-05 Toppan Printing Co Ltd
JPH0523599B2 (en) * 1987-07-27 1993-04-05 Toppan Printing Co Ltd
JPS6430792A (en) * 1987-07-27 1989-02-01 Toppan Printing Co Ltd Image receiving body for thermal transfer
JPS6430793A (en) * 1987-07-27 1989-02-01 Toppan Printing Co Ltd Image receiving body for thermal transfer
JPS6442284A (en) * 1987-08-11 1989-02-14 Mitsubishi Rayon Co Recording material for sublimation-type thermal transfer recording system
JPS6444781A (en) * 1987-08-13 1989-02-17 Dainippon Printing Co Ltd Sheet to be thermally transferred
JPS6487390A (en) * 1987-09-30 1989-03-31 Dainippon Printing Co Ltd Image receiving layer transfer sheet and image forming method employing the same
JPH0196650A (en) * 1987-10-08 1989-04-14 Fuji Photo Film Co Ltd Image forming sheet
JPH01160682A (en) * 1987-12-18 1989-06-23 Dainippon Printing Co Ltd Image receiving layer transfer sheet
JPH01166991A (en) * 1987-12-23 1989-06-30 Nisshinbo Ind Inc Paper base sublimation type thermal transfer image receiving paper
JPH01176588A (en) * 1988-01-05 1989-07-12 Kanzaki Paper Mfg Co Ltd Sheet subjected to thermal transfer
JPH01202494A (en) * 1988-02-09 1989-08-15 Matsushita Electric Ind Co Ltd Image-receiving material for thermal transfer recording
US4962080A (en) * 1988-03-08 1990-10-09 Kanzaki Paper Mfg. Co., Ltd. Image-receiving sheet for thermal dye-transfer recording
US5362701A (en) * 1988-03-11 1994-11-08 Dai Nippon Insatsu Kabushiki Kaisha Image-receiving sheet
US5166127A (en) * 1988-03-11 1992-11-24 Dai Nippon Insatsu Kabushiki Kaisha Image-receiving sheet
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US5407895A (en) * 1988-03-11 1995-04-18 Dai Nippon Insatsu Kabushiki Kaisha Image receiving sheet
EP0715963A3 (en) * 1988-03-11 1996-07-24 Dainippon Printing Co Ltd
EP0332204A2 (en) * 1988-03-11 1989-09-13 Dai Nippon Insatsu Kabushiki Kaisha Image-receiving sheet
JPH01232096A (en) * 1988-03-14 1989-09-18 Nisshinbo Ind Inc Production of sublimation-type thermal transfer image-receiving paper
JP2618676B2 (en) * 1988-03-14 1997-06-11 日清紡績株式会社 Manufacturing method of sublimation type thermal transfer image receiving paper
JPH024592A (en) * 1988-06-23 1990-01-09 Sanyo Chem Ind Ltd Image-receiving material for thermal transfer recording
EP0349141A2 (en) * 1988-06-29 1990-01-03 Imperial Chemical Industries Plc Receiver sheet
US4997807A (en) * 1988-10-31 1991-03-05 Kanzaki Paper Mfg. Co., Ltd. Image-receiving sheet for thermal dye-transfer recording
EP0368550A2 (en) * 1988-11-11 1990-05-16 Imperial Chemical Industries Plc Thermal transfer receiver
JPH0319892A (en) * 1989-06-16 1991-01-29 Dainippon Printing Co Ltd Thermal transfer image receiving sheet
JPH0530636B2 (en) * 1990-03-27 1993-05-10 Tomoegawa Paper Co Ltd
JPH03275386A (en) * 1990-03-27 1991-12-06 Tomoegawa Paper Co Ltd Thermal transfer image receiving medium
US7799736B2 (en) 2006-03-09 2010-09-21 Fujifilm Corporation Heat-sensitive transfer image-receiving sheet and method of forming image
JP2007237643A (en) * 2006-03-10 2007-09-20 Fujifilm Corp Thermal transfer image-receiving sheet and method for forming image
US7960309B2 (en) 2006-03-10 2011-06-14 Fujifilm Corporation Heat-sensitive transfer image-receiving sheet and method of forming image

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