JPS5891130A - Cooling method for strip in successive annealing - Google Patents

Cooling method for strip in successive annealing

Info

Publication number
JPS5891130A
JPS5891130A JP18700681A JP18700681A JPS5891130A JP S5891130 A JPS5891130 A JP S5891130A JP 18700681 A JP18700681 A JP 18700681A JP 18700681 A JP18700681 A JP 18700681A JP S5891130 A JPS5891130 A JP S5891130A
Authority
JP
Japan
Prior art keywords
strip
heating
spraying
underwater
aqueous solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP18700681A
Other languages
Japanese (ja)
Other versions
JPH0118974B2 (en
Inventor
Shuzo Uchino
内野 周三
Teiji Nakayama
中山 悌二
Shigehiro Takushima
重宏 多久島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Engineering Corp
Original Assignee
NKK Corp
Nippon Kokan Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NKK Corp, Nippon Kokan Ltd filed Critical NKK Corp
Priority to JP18700681A priority Critical patent/JPS5891130A/en
Publication of JPS5891130A publication Critical patent/JPS5891130A/en
Publication of JPH0118974B2 publication Critical patent/JPH0118974B2/ja
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • C21D9/54Furnaces for treating strips or wire
    • C21D9/56Continuous furnaces for strip or wire
    • C21D9/573Continuous furnaces for strip or wire with cooling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)

Abstract

PURPOSE:To carry out proper scale removal by spraying a solution containing organic acids on a strip in the air and then dipping it in the solution, and performing underwater spraying in the solution while heating the strip by heating rolls which utilize the waste heat of a heating furnace during the dipping. CONSTITUTION:A strip S heated and soaked at above recrystallization temperature and carried from a soaking pit 18 is sprayed with a solution containing organic acids from an in-air spray nozzle 2 to be cooled rapidly. Then, the strip is dipped in a treating tank 1 containing said solution 15 and passes through heating rolls 5a, 5b, and 5c successively. In the heating rolls 5a, 5b, and 5c, a heat medium having recovered the heat of waste gas of a heating furnace circulates. During said dipping, underwater spraying is carried out by an underwater spray nozzle 7. Therefore, scale produced during the in-air spraying is reduced with the organic acids and the reaction is accelerated by the heating rolls to remove the scale through the underwater spraying.

Description

【発明の詳細な説明】 本発明は連続焼鈍におけるストリップの冷却方法に関す
る。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for cooling a strip during continuous annealing.

連続焼鈍によって軟質材を製造する場合、固溶Cの析出
を十分確保するため、ストリップを再結晶温度に加熱・
均熱後急冷し、次いで400 ’0程度の温度域で過時
効処理が行われる。従来このような処理における加熱後
の代表的な一急冷手段として浸水冷却が行われている。
When manufacturing soft materials by continuous annealing, the strip is heated to the recrystallization temperature to ensure sufficient precipitation of solid solution C.
After soaking, it is rapidly cooled and then over-aged in a temperature range of about 400'0. Conventionally, water immersion cooling has been performed as a typical rapid cooling means after heating in such processing.

この方法は第1図に示すように冷却速度が大きいため、
急冷後の過時効処理時間が短くて済むものの、その冷却
速度のため急冷後の温度コン)a−ルができず、板温が
ほぼ室温近くまで冷却されてしまう。このため、従来で
はかかる急冷後の過時効処理においてストリップti!
温状態から再加熱する必要があプ、第1図中斜線で示す
ような新たな熱エネルギーを必11.するという問題が
あった。また上記のような急冷を行った場合、ストリッ
プ表面にはスケールが生成してしまい、このため、急冷
直後又は過時効処理後に別途酸洗槽を設けてスケール除
去を行わなければならず、その分だけライン長さを増大
させる結果となっていた。
This method has a high cooling rate as shown in Figure 1, so
Although the overaging treatment time after quenching can be shortened, the temperature control after quenching is not possible due to the cooling rate, and the plate temperature is cooled to approximately room temperature. For this reason, in the conventional overaging treatment after rapid cooling, strip ti!
11. It is necessary to reheat from the warm state, so new thermal energy as shown by diagonal lines in Figure 1 is required. There was a problem. In addition, when the above-mentioned rapid cooling is performed, scale is generated on the strip surface, and therefore a separate pickling tank must be installed to remove scale immediately after the rapid cooling or after overaging treatment. This resulted in an increase in line length.

本発明は以上のような従来法の間賠を解消すべく創案さ
れたもので、所定の急冷速度を確保しつつ過冷却管防止
し、しかも生じ良スケールを適切に除去することができ
る方法の提案をその目的とする。
The present invention was devised in order to eliminate the drawbacks of the conventional methods as described above, and is a method that can secure a predetermined quenching rate, prevent supercooled pipes, and properly remove the formed scale. The purpose is to make a proposal.

本発8AFi再結晶温度以上に加熱・均熱されたストリ
ップを急冷するに当り、まずストリップに有機酸を含む
水溶液を空中スプレーし、次いで、直ぐにストリップを
前記水溶液中に浸漬せしめ、さらにこの浸漬中、加熱炉
の燃焼廃熱を利用した壷数の加熱ロールで加熱しつつ水
溶液の水中スプレーを行い、しかる後過時効処理を行う
ようにし喪ものであり、このように空中スプレー及び水
溶液中への浸漬により所定の急冷速度を確保しつつ、浸
漬中の複数の加熱ロールによる加熱によシストリップの
過冷却を防止しその温度を過時効処理温IAtの極〈近
い範囲まで留めることができ、しかも加熱ロールには加
熱炉の燃焼廃熱を利用するので新規なエネルギーを浪費
することもない。また空中スプレー及び浸漬を有機酸を
営む水溶液で行うので、急冷によって生じたスケールを
これで除去することができ、しかもこの際、加熱ロール
でス) Ilツブが加熱され且つ水中スプレーによりス
トリップ表面に生じ喪蒸気膜が除去されるので適切なス
ケーク除去が行、わむる。
To rapidly cool a strip that has been heated and soaked above the recrystallization temperature of the 8AFi of the present invention, first, an aqueous solution containing an organic acid is sprayed onto the strip in the air, and then the strip is immediately immersed in the aqueous solution. In this method, an aqueous solution was sprayed underwater while being heated with a heating roll using the combustion waste heat of a heating furnace, and then an over-aging treatment was performed. While ensuring a predetermined quenching rate through immersion, overcooling of the systrip can be prevented by heating with a plurality of heating rolls during immersion, and its temperature can be kept within a range extremely close to the overaging treatment temperature IAt. Since the heating roll uses combustion waste heat from the heating furnace, no new energy is wasted. In addition, since aerial spraying and dipping are carried out in an aqueous solution containing an organic acid, scale produced by rapid cooling can be removed. Appropriate descaling is performed as the vapor film formed is removed.

本発明で利用される有機酸としては、例えはマロン酸等
があり、またその#1度は通常0.5〜1嚢程度の範囲
、温度は60〜70°0の範囲で選択される。また加熱
ロールへの熱の供給は、ライン中の加熱炉の燃焼排ガス
の廃熱を例えば熱交換装置によシ高沸点熱媒に熱交換し
、この高沸点熱媒を加熱ロールに通すことにより行い、
これKより加熱ロールの表面は300〜350”0程度
となシ、かかるロール温度によ)ストリップの過冷却が
防止される。
The organic acid used in the present invention includes, for example, malonic acid, and its #1 degree is usually selected in the range of about 0.5 to 1 sachet, and the temperature is selected in the range of 60 to 70°0. In addition, heat is supplied to the heating rolls by heat-exchanging waste heat from combustion exhaust gas from a heating furnace in the line to a high-boiling heating medium using a heat exchanger, and passing this high-boiling heating medium through the heating rolls. conduct,
Since the surface of the heating roll is about 300 to 350"0, this roll temperature prevents the strip from being overcooled.

第2図は本発明の実施に供される設備を概略的に示すも
ので、(1)は処理タンク、(2)(2)は#処理タン
ク(1)上方に般けられ喪空中スプレーノズル、(3)
は水浴液の循環タンク、(4)は熱交換器、(Isa)
 ’(5b)及び(5c)は処理タンク0)内に連続的
に設けられた加熱口1−ル、(6)は水溶液温度管理用
のクーラー、(7)は水中スプレー/ スル、(8) 
(8) a水切9パージ用のノズルである。かかる設備
では循環タンク(3)から空中スフ’L/−ノズル(2
) (2)及び水中スプレーノズル(7)Kそれぞれ配
管(9)及び叫を介して水溶液が供給され、前記空中ス
プレーノズル(2バ2)からスプレーされ大水溶液は下
方の処理タンク(1)に落ちるようになっている。t+
処理タンク(1)には配管(ロ)により別途水溶液が供
給可能であり、ま九処理タンク(1)内の水溶液はオー
バー70−配管(2)によって循環タンク(3)に戻さ
れる。熱交換器(4)には、加熱炉からの燃焼排ガス用
配管(ロ)と、加熱レール(5m) (5b) llz
び(5c)をtil1次経て高沸点熱媒を循環させるよ
うに構成された配管(ロ)とがそれぞれ接続され、両流
体の熱変換を行うようになっている。なお前記各加熱ロ
ール(5)に熱媒を流通せしめるためにロールの一方の
軸端からロールシェル内側に熱媒を流通せしめ、他方の
軸端からロールタ1に排出させ、さらにその排出された
熱媒を次の加熱ロール(5)に供給するとい、うような
構成となっている。
Figure 2 schematically shows the equipment used for carrying out the present invention, in which (1) is a processing tank, (2) is an aerial spray nozzle that extends above #processing tank (1) ,(3)
is a water bath liquid circulation tank, (4) is a heat exchanger, (Isa)
'(5b) and (5c) are heating ports 1-1 continuously provided in the processing tank 0), (6) is a cooler for controlling the temperature of the aqueous solution, (7) is an underwater spray/through, (8)
(8) a Drainer 9 This is a purge nozzle. In such equipment, the air flow nozzle (2) is connected to the circulation tank (3).
) (2) and the underwater spray nozzle (7) K are supplied with an aqueous solution through the pipes (9) and pipes, respectively, and the large aqueous solution sprayed from the above-mentioned aerial spray nozzle (2 bar 2) is sent to the lower processing tank (1). It's starting to fall. t+
A separate aqueous solution can be supplied to the processing tank (1) through piping (b), and the aqueous solution in the processing tank (1) is returned to the circulation tank (3) through over-70 piping (2). The heat exchanger (4) includes piping for combustion exhaust gas from the heating furnace (b) and heating rail (5m) (5b).
and (5c) are connected to piping (b) configured to circulate a high boiling point heat medium through the first til, respectively, so as to perform heat conversion of both fluids. In order to circulate the heat medium through each of the heating rolls (5), the heat medium is caused to flow inside the roll shell from one shaft end of the roll, and is discharged from the other shaft end to the roll rotor 1, and the discharged heat is The medium is supplied to the next heating roll (5).

なお、前記水中スプレーノズル(7)は第3図に示すよ
うに加熱ロール(6)の軸方向で複数に分割され、スト
リップ幅に応じてノズルを使い分けるようになっている
。即ち、これによってロール表面にスプレーすることを
防止1、加熱ロール(5)から水溶液(2)への熱放置
を極力防止するようにしている。その他図面においてo
IJ(ロ)はポンプである。
The underwater spray nozzle (7) is divided into a plurality of parts in the axial direction of the heating roll (6), as shown in FIG. 3, and the nozzle is selectively used depending on the strip width. That is, this prevents spraying onto the roll surface (1) and prevents the heating roll (5) from leaving the aqueous solution (2) as much as possible. In other drawings o
IJ (b) is a pump.

以上のような設備によれば、均熱炉−からのストリップ
(8)を9中スプレーノズル(2) (2)間を通過せ
しめるとともに、処理タンク(1)の加熱ロール(sa
) (sb)及び(5c)4C通し、しかる後、過時効
処理炉四に導くものであるが、この際、ストリップ(S
)は空中スプレーノズル(2) (2)によシ有mi!
1g!を含む水溶液がスプレーされ、急冷が行われると
ともに、直ぐに処理タンク(1)の水S液(2)中に浸
漬され、ここで加熱ロール(5m) (5b)及び(5
c)に馴次通されることにより、それ以上の冷却が抑え
られる。即ち加熱o −ル(am) (5b)及び(5
c)には熱交換器(4)で加熱炉の燃焼排ガスの熱を回
収し喪高沸点熱媒が流通し、ロール表面は300〜35
 G ’0程度VCなっており、このため、これに接触
するス) IJツブ(S)はそれ以上の冷却が抑えられ
且つ最終の加燃ロール(5c)の出側では上記温度節H
v(保持されることになる。第4図はこのような本発明
の冷却工程管含む熱サイクルを示すもので、(A)は加
熱・均熱、(B)は空中スプレー及び一部水溶液浸漬に
よる急冷、(C)は加熱ロール(5)による加熱、(D
)は過時効処理のサイクルをそれぞれ示す。このように
本発明によればストリップ(S)の過冷却を防止するこ
とができる。
According to the above-mentioned equipment, the strip (8) from the soaking furnace is passed between the spray nozzles (2) (2) in 9, and the heating roll (sa) of the processing tank (1) is
) (sb) and (5c) 4C, and then led to the overaging treatment furnace 4. At this time, the strip (S
) is the same as the aerial spray nozzle (2) (2)!
1g! An aqueous solution containing S is sprayed, rapidly cooled, and immediately immersed in the water S solution (2) in the treatment tank (1), where heating rolls (5 m) (5b) and (5
By passing through c), further cooling is suppressed. That is, heating o-le (am) (5b) and (5
In c), the heat of the combustion exhaust gas of the heating furnace is recovered in the heat exchanger (4), and a high boiling point heat medium is circulated, and the roll surface has a temperature of 300 to 35
G '0 VC, therefore, the IJ tube (S) that comes into contact with it is prevented from further cooling and the above temperature node H is maintained on the exit side of the final combustion roll (5c).
v (will be maintained. Figure 4 shows a thermal cycle including such a cooling process tube of the present invention, (A) is heating and soaking, (B) is aerial spraying and partial immersion in aqueous solution. quenching, (C) heating with heating roll (5), (D
) indicate the cycles of overaging treatment, respectively. As described above, according to the present invention, overcooling of the strip (S) can be prevented.

また、以上の過程において、空中スプレ一時に生じたス
ケールは、そのスプレ一時におりる有機酸及びスプレー
直後に浸漬される水浴液中の有機酸により還元され、そ
の除去が行われる。そして特に処理タンク(1)内では
加熱ロール(5)の加熱によ)その除去反応が促進され
るとともに、水中スプレーノズル(7)Kよるスプレー
により、ストリップ(8)表面に付着して前記除去反応
を阻害する蒸気膜が払拭され、これらによってスケール
除去が適切に行わねる。
Further, in the above process, the scale generated during the aerial spraying is reduced and removed by the organic acid that falls during the spraying and the organic acid in the water bath liquid that is immersed immediately after the spraying. Particularly in the processing tank (1), the removal reaction is accelerated by the heating of the heating roll (5), and at the same time, by spraying from the underwater spray nozzle (7) K, it adheres to the surface of the strip (8) and is removed. Steam films that inhibit the reaction are wiped away, and scale removal cannot be performed properly due to these.

is、P:の加熱ロール(5c)を抜けたストリップは
ノズル(lit) (8)により水切シパージがなされ
、過時効処理炉(至)に導かれる。
The strip that has passed through the heating roll (5c) of is, P: is drained and sipped by a nozzle (lit) (8), and is led to an overaging treatment furnace (to).

以上述べた本発明によれば、ストリップVこ有機酸を含
む水溶液を空中スプレーし、次いで直ぐにストリップを
前記水f6液中に浸漬せしめるとともに、この浸漬中、
加熱炉の燃焼廃熱を利用した複数の加熱ロールで加熱し
つつ水溶液の水中スプレーを行うようにしたので、空中
スプレー及び水溶液中への浸漬により所定の急冷速度を
確保しつつ、加熱炉の燃焼廃熱を利用した加熱ロールに
よる加熱により、ストリップの過冷却を防止することが
でき、もって従来の浸水冷却と同様に過時効処理時間が
短くて請むたけでなく、過時効処理炉においてストリッ
プ加熱のための新規な熱エネルギーの供給を大幅に低減
することができ、加えて空中スプレー及び浸漬を有mm
t−含む水溶液で行い、さらに加熱ロール及び水中スプ
レーに反応促、進作用をなさしめることにより、急冷に
よって生じたスケールを適切に除去することができる尋
、−々の優れた効果を有するものである。
According to the present invention described above, an aqueous solution containing an organic acid is sprayed on the strip V in the air, and then the strip is immediately immersed in the water F6 liquid, and during this immersion,
Since the aqueous solution is sprayed underwater while being heated with multiple heating rolls that utilize the combustion waste heat of the heating furnace, the combustion of the heating furnace is maintained while ensuring a predetermined quenching rate by aerial spraying and immersion in the aqueous solution. Heating with heating rolls using waste heat can prevent overcooling of the strip, which not only shortens the overaging treatment time like conventional water immersion cooling, but also allows strip heating in the overaging treatment furnace. can significantly reduce the supply of new thermal energy for, in addition to aerial spraying and dipping.
By using an aqueous solution containing T-T and further promoting the reaction by using a heating roll and underwater spray, it has the following excellent effects: it is possible to appropriately remove scale generated by rapid cooling. be.

【図面の簡単な説明】[Brief explanation of the drawing]

g1図は従来の連続焼鈍の熱サイクルをノ」りすもので
ある。第2図及び第3図は本発明の実施に供される急冷
設備を概略的に示すもので、第2図は全体吐明図、第3
図は水中スプレーノズルを部分的に示す説明図である。 第4図は本発明の冷却方法を実施した連続焼鈍の熱サイ
クルを示すものである。 図において、(1)は処理タンク、(2)は空中スプレ
ーノズル、(sa) (5b) (sc)は加熱ロール
、(7)は水中スプレーノズルを各示す。 第1図 時間 第2図
Diagram g1 shows the thermal cycle of conventional continuous annealing. 2 and 3 schematically show the quenching equipment used for carrying out the present invention.
The figure is an explanatory diagram partially showing an underwater spray nozzle. FIG. 4 shows a thermal cycle of continuous annealing using the cooling method of the present invention. In the figure, (1) indicates a processing tank, (2) an aerial spray nozzle, (sa), (5b), (sc) a heating roll, and (7) an underwater spray nozzle. Figure 1 Time Figure 2

Claims (1)

【特許請求の範囲】[Claims] 軟質冷延鋼板製造に際して、再結晶温度以上に加熱・均
熱されたストリップを急冷するに当り、ストリップに有
機酸を食も水溶液を空中スプレーし、次いで直ぐにスト
リップを前記水溶液中に浸漬せしめるとともに、この浸
漬中、加熱炉の燃焼廃熱を利用した複数の加熱ロールで
加熱しつつ水溶液の水中スプレーを行うことを特徴とす
る連続焼鈍におけるストリップの冷却方法。
During the production of soft cold-rolled steel sheets, when rapidly cooling a strip that has been heated and soaked above the recrystallization temperature, an aqueous solution containing an organic acid is sprayed onto the strip in the air, and then the strip is immediately immersed in the aqueous solution. A method for cooling a strip in continuous annealing, characterized in that during this immersion, an aqueous solution is sprayed underwater while heating with a plurality of heating rolls utilizing combustion waste heat of a heating furnace.
JP18700681A 1981-11-24 1981-11-24 Cooling method for strip in successive annealing Granted JPS5891130A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP18700681A JPS5891130A (en) 1981-11-24 1981-11-24 Cooling method for strip in successive annealing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP18700681A JPS5891130A (en) 1981-11-24 1981-11-24 Cooling method for strip in successive annealing

Publications (2)

Publication Number Publication Date
JPS5891130A true JPS5891130A (en) 1983-05-31
JPH0118974B2 JPH0118974B2 (en) 1989-04-10

Family

ID=16198548

Family Applications (1)

Application Number Title Priority Date Filing Date
JP18700681A Granted JPS5891130A (en) 1981-11-24 1981-11-24 Cooling method for strip in successive annealing

Country Status (1)

Country Link
JP (1) JPS5891130A (en)

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* Cited by examiner, † Cited by third party
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BE1012753A3 (en) * 1998-10-01 2001-03-06 Centre Rech Metallurgique Non-oxidising cooling method for a rolled steel strip
JP2008256481A (en) * 2007-04-04 2008-10-23 Kubota Corp Correction method for weighing device
JP2013185182A (en) * 2012-03-06 2013-09-19 Jfe Steel Corp Apparatus and method for manufacturing steel strip
JP2015038233A (en) * 2013-08-19 2015-02-26 Jfeスチール株式会社 Method and installation for production of steel strip
JP2015038234A (en) * 2013-08-19 2015-02-26 Jfeスチール株式会社 Method and installation for production of steel strip
WO2015083047A1 (en) * 2013-12-05 2015-06-11 Fives Stein Method and apparatus for continuous thermal treatment of a steel strip
US10385419B2 (en) 2016-05-10 2019-08-20 United States Steel Corporation High strength steel products and annealing processes for making the same
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