JPS58152372A - Manufacturing method for positive plate of alkaline battery - Google Patents
Manufacturing method for positive plate of alkaline batteryInfo
- Publication number
- JPS58152372A JPS58152372A JP57035439A JP3543982A JPS58152372A JP S58152372 A JPS58152372 A JP S58152372A JP 57035439 A JP57035439 A JP 57035439A JP 3543982 A JP3543982 A JP 3543982A JP S58152372 A JPS58152372 A JP S58152372A
- Authority
- JP
- Japan
- Prior art keywords
- positive plate
- hydroxide
- cobalt
- cobalt hydroxide
- alkaline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/24—Electrodes for alkaline accumulators
- H01M4/26—Processes of manufacture
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、水酸化ニッケルを活物質とするアルカリ電油
用＋Ｅ囁仮の＃盾法に関するもので、水酸化コバルト、
あるいは四三酸化コバルトを活物′Ｒと見合しＴこ後、
三次元的に連続１，１こ構造を何する支持体に塗布して
形成し１こ自板をアルカリ水Ｍｌｆ中でカノード分晩し
、つづいてアノー分−１シｆこのら乾燥中ることにより
、金属コバル）−を添ＺＩｌシｊこ場合よりすぐれ１こ
性能を有する正鑞板を提供することを目ト０と−むろも
のである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a +E whisper #shield method for alkaline electric oil using nickel hydroxide as an active material, cobalt hydroxide,
Alternatively, after matching tricobalt tetroxide with the active material 'R',
Form a three-dimensionally continuous 1, 1 structure by coating it on a support of some kind, soak the plate in alkaline water Mlf overnight, and then dry the anode layer. Accordingly, it is our aim to provide a solder plate having superior performance than that obtained by adding metal cobal.
従来、アルカリ４池のｌＦ鴎仮の硫仮と（７ては、ニッ
ケル粉末の焼結体が［１１いらｔｌてもするが、その多
孔１（は７１）へ・８０％程度であり、こオ′１以口こ
多孔ＩＷをヒげると、その機械的嶺邸が麿しく誠少し、
し１こがってその空国内にｔＥｔｄｋｒ占Ｐｌ丙を充填
１−Ｔこ場的こ、基板の安形、亀裂や活物べの刹嶋ヰを
招米する欠点があつｆこ。よ１：、宿ｖＩＡ丙を充填す
る用台、１１ＩＩ常鍼王含浸法とよばオ］る方法、すな
わち硝酸ニッケルや硫酸二ツノｒル咎のニノノｒル塩の
水浴液を基板に減千含浸しｒコのら、アルカリ水浴液で
処理し、さらに場洗、乾燥するという操作を操り返す方
法がとられている。しかしながら、−回の（１作によっ
て充填される喰は少なく、しかも２回目力）ら充填され
る嘘は次第に減少１７てくるので通常４〜１０回の操作
をくり返す必要がある。そのＴこめに製造工程が複雑で
経済的コストが高くなるとし１う欠点があつｆこ。Conventionally, a sintered body of nickel powder was mixed with 1F sulfur in an alkali 4 pond (7), but the sintered body of nickel powder was about 80% of the pores 1 (71). When I opened the porous IW from the beginning, the mechanical structure was slow and sincere.
However, filling the empty space with tEtdkr PL 2 has the drawbacks of cheap substrates, cracks, and the formation of live objects. 1: The table for filling the ink is filled with a method called the 11II regular acupuncture impregnation method, that is, a water bath solution of nickel nitrate or ninonol salt such as sulfuric acid is applied to the substrate. The method used is to repeat the steps of impregnating, treating with an alkaline water bath, washing in place, and drying. However, since the number of lies charged gradually decreases from the -th time (the amount of food charged by one operation is small, and moreover, the second power), it is usually necessary to repeat the operation 4 to 10 times. Another drawback is that the manufacturing process is complicated and the economic cost is high.
そこで遅生、三次元的に連続ＩＪこ嘴造を何するニッケ
ル舎属よりなるスポノジ状多孔体に、ぺ一スト伏にしｒ
ニー ＩＥ ｌ＋ｉ１１活物質を１１１）にイＩゞ檀−
ＣるＵ法が注目さ′ＩＩＣき−Ｃいる。Therefore, a late-growing, three-dimensionally continuous IJ beak structure was placed in a sponge-like porous material made of nickel-like material.
IE l+i11 active material to 111)
The CruU method is attracting attention.
三大元的に連続［７ｆこ構造をｆ−ｒ ４−る番孔体は
、その多孔呟が９０〜９８％と簡く、しかも機械的強１
￥が大とい。そのうえ孔径か大きいのでこの多孔体に活
物′冴を充積−（５とＩＦ山板の確谷［４化をはかるこ
とかで入るとともに充嘘方法が鵠めて；覇便に／ｆすＩ
！Ｉ！続工程加工程能で経済面にも利用と４ｆる。The porous body with a three-dimensional continuous [7f] structure has a simple porosity of 90 to 98%, and has mechanical strength of 1.
It costs a lot of ¥. Moreover, since the pore size is large, this porous body is filled with living matter. I
! I! It can also be used economically due to the continuous process processing capacity.
しかしながら、多孔体の孔径が大きいｆコめに集゛亀体
でｊ）るニッケル番孔体と活物質粉本との間および活物
百粒子間の市電的な接部性が充分に得られず、利用率が
低いという欠点がある。そのｆ： ）／ｒにニッケル粉
末等のｓ電材や種々の添叩剤を加えることに、１つて、
利用率を同上−する拭みがおこｒ（われている。この添
Ｉｌｌ ｉｌｌと（７ては、王として金属コバルト粉末
が考古−られでいるが、その効果は・必ずしも充分では
なく、まｆこ高価であるという欠点がある。−万、水酸
化コバルトや酸化コバルト等も添＋１１Ｉ 制として用
いられるが、その効果は金１５ｉコバルＩ・よりも劣っ
ている。However, sufficient tram-like contact properties between the nickel hole body and the active material powder and between the 100 particles of the active material, which are concentrated in the body where the pores of the porous body are large, cannot be obtained. However, it has the disadvantage of low utilization rate. One thing about adding electrical materials such as nickel powder and various additives to f: )/r is,
There has been some effort to reduce the utilization rate.Although metallic cobalt powder has been used as a metal, its effectiveness is not necessarily sufficient and may be insufficient. However, cobalt hydroxide, cobalt oxide, etc. are also used as additives, but their effectiveness is inferior to that of gold-15i cobalt I.
本宅明は水すｆｌＳ１ハル）・あろい１才・’１１三ｍ
化コバルト６７添１１１１ Ｍ トｌ−テ’ｌｌ イｆ
： ｔｌｌｌｎＪ Ｏｉを７ ルｌＪ’Ｊ ’Ｋ ＃４
孜中でカラード分ｊＩ＋ １．、、〜）づいてアノード
分１執１゜ｆこのち・吃Ｉψｒる（−Ｊに１０、后イ勿
直！１」由来を＆ Ｌ−く向ヒフ・缶る（とをノドいｆ
でしｆこことに〜（づくもので売る。Akira Motoya is a water flS1 hull), Aoi 1 year old, '113m
Cobalt chloride 67 addition 1111 M Torte'll If
: tlllnJ Oi 7 LulJ'J 'K #4
Keinaka colored part jI+ 1. ,, ~), then the anode part 1 1゜f Kochi・吃Iψrru (-J ni 10, wa ii nadunao!
Deshif Kokoto ~ (Sold at Zukumono.
以−ド木宅明の゛央ｈｉｕ例４Ｌ ’ｌびにその効栄を
、祥！［する。Here's Akira Kidaku's ``Ohiu Example 4L'' and its effectiveness! [do.
本発明に用い１ｊ禰はつざの、ｔうに°ＩＷ ｌ’ｌ＋
Ｌ ｒこ。Sea urchin used in the present invention
L rko.
１５０メツツユ１ｉＴｌ堝の７Ｋ ４１２ 化二）′ｒ
ルＮ）ｆｌ’！５ 部。150 Metsutsuyu 1iTl 7K 412 Chemical 2)'r
LeN)fl'! 5 parts.
カーボー・ニッケル粉末１０ 部との４６舎扮木に、＋
５０メツツユｉｉｌ＋渦の水酸化コバル！・粉末８部、
あるいは四三酸化コバルト粉末７部を混合しｆこものに
０．６ｗｔ％の力―レボキソメチルセルロース水（／ｌ
ｇを加えＣペースト・状にしｔこ。このペーストを五
欠元的に連続しｔこ構造を汀する二ノゲル矛孔体に充積
１． ｒ二のら、乾燥しフッ累樹脂の分散液に浸漬し、
さらに乾燥してから５ｆｌＯｋｇ／ｄの子方でブ１／ス
じて正嘩仮とじｆこ。46 pieces of wood with 10 parts of carbo-nickel powder, +
50 Metutsuyu Iil + Whirlpool Hydroxide Kobal!・8 parts of powder,
Alternatively, mix 7 parts of tricobalt tetroxide powder and add 0.6 wt% of the powder to levoxomethylcellulose water (/l).
Add g and make it into a paste. This paste is filled into a two-gel hole body that has a five-dimensional continuous structure and a t-shaped structure.1. R Nira, dried and immersed in a fluorocarbon resin dispersion,
After further drying, I temporarily stapled the paper at 5flOkg/d.
Ｃの正自板を、対１ｍ ％−−−）γル仮として、８．
Ｇ。Assuming that the normal plate of C is 1 m%---)γ, 8.
G.
１．２５０ （２＋１’ＯＪ ＫＬ用水４欣中でｌ Ｏ
ｍＡ／Ｃｊ の電流酒１頼で−ｔｉ １１．ｊ間カノー
ド分階しｆこ。そののら同じ電流、ぞＷで−ｉｆ： ｌ
ｌ：ｊ間アノード分廓［７、揚洗をわこなＬ％８（１’
Ｃで１時間乾燥しｒ：、 、、汁崗時１１の助層を、凋
へるＴこめに、この＋Ｅｌ佃仮１枚と従来から公知のべ
一゛スｌ一式カドミウム負崗奴２枚と″邂解枚に８．
（１，１，２５０（２０℃）Ｋ（月１水ｍ孜とを用いｆ
こ公弥谷献か２４Δ１鳥のフラデノドタイプのｔａを賀
ｒｉ’ Ｌ、で、 ｇ、ＩＯＡテ２０時間光１シ１こ
のら、］ Ｃ０で０．ＩＶよで放電しｆこ。アノード分
画の時間を３０分とし−Ｃ、カノード分階の時間をかえ
ｔこ揚台、およびカノード分醜の時間を３０分としてア
ノード分篩の時間をかえｔこ場合の活物ｉ［ｉ１１用率
と分崗時間とのＡ係をそれぞれ第１囲繞び市２１図にボ
す。第１１図から水酸化コバルトを用い１こ場合は２０
分級上、土ｆこ四三噴化コバルＩ・を…い１こ場合は
１０ 分級上のカソード分隔時間で利用率か９５％を越
え良好であることかわかる。第２図からカノード分醜の
のちアノード分１醜をおこなうことにより、利用率の向
上がはか才するＣとがわかる。1.250 (2+1'OJ KL water in 4 liters)
-ti with one order of mA/Cj 11. Between the canode and the floor. Then the same current, W, -if: l
l:j anode branch [7, lift washing wakona L%8 (1'
Dry at C for 1 hour, then add 11 auxiliary layers to the cooling T, add 1 piece of this + El Tsukuda and 2 pieces of the conventionally known Base 1 set cadmium granite. 8.
(1,1,250 (20℃) K (1, 1, 250 (20℃)
24 Δ 1 bird's fladenod type ta, g, IOA te 20 hours light 1 si 1 these,] C0 0. Discharge it with the IV. Change the anode fractionation time to 30 minutes, change the time to the canode separation stage, set the time to the canode separation stage to 30 minutes, and change the anode separation time to 30 minutes. Section A for utilization rate and breaking time are shown in Figure 21 of the First Encircled City, respectively. From Figure 11, using cobalt hydroxide, 1 in this case 20
In terms of classification, if soil f is 43 erupted Kobal I...1, it can be seen that the utilization rate is good and exceeds 95% at the cathode interval time of 10 minutes. From FIG. 2, it can be seen that the utilization rate can be dramatically improved by carrying out the anode removal after the canode removal.
一つぎにカノード分１亜ＰＪ 、ｔ＜Ｆアノード分画を
２０分間おこｆ（つて製作しｆ：本′１６明１こよるｉ
Ｅｔ＆仮とペースト式カドミウム鉤商仮とをナイロン不
繊布のセハレータを介１．て渦巻状にａき、ｔｉｔ眸故
に８．ｆＪ。Next, carry out the anode fractionation for 20 minutes, t<F, for 20 minutes.
1. Connect Et&temporary and paste type cadmium hook commercial temporary through a sehalator made of nylon nonwoven fabric. 8. fJ.
１．８００（２０−ＣＩ Ｋ（ＩＨｔｇ箭液を用いて公
亦谷破２４Ａｈ の円筒形密閉ニッケル・カドミウム屈
曲を製作し１こ。柚頌としては添ｎｌＩ剤に水酸化コバ
ルトを用いｔこ不発明による＋［池ＩＡｌおよび四三酸
１２コバルトを用いｔこ不軍明によるＦ１イ也（ＩＳ）
を製作しｆこ。ま１こ比較の１コめに、ｆｓ ’ＩＩ削
に缶１１コバルト、水庸化コバル；・、および１傷三酸
化コバルトを；口いて力゛ノード分ｔ＋ＭＯ畦をおこｒ
ｆ才つないＩＦ陽数を用いｆこ従来の電池、それぞれ（
Ｃ１（１）ｌおよび（Ｅ＋を製作Ｌｒこ。1.800 (20-CI K (IHtg) was used to fabricate a cylindrical sealed nickel-cadmium bend of 24Ah. According to the invention + [F1 Iya (IS) by Fugunmei using Ike IAl and 12 cobalt tetraoxide
I made it. For the first comparison, add 11 cans of cobalt, hydrated cobal, and 1 scratch cobalt trioxide to the fs 'II cut, and make a force node t + MO ridge.
Using an IF positive number that connects f years, f conventional batteries, respectively (
Create C1(1)l and (E+).
これらの電池を２０“Ｃ１Ｑ、 ｌ ＯＡで１６時間充
電し１このらＩＯＡで放電しＴコときの放゛イ特性を第
３図に示−む。図より不発明による「Ｅ山板を用いＴこ
１Ｊ１曲（Ａ）。Figure 3 shows the radiation characteristics when these batteries were charged for 16 hours at 20C1Q, lOA and discharged at 1IOA. Tko1J1 song (A).
（８１は従来の電池ｔ１）＋、ｔＥ＋と比較［７て利用
率か婿しく向Ｉ：］７ており、金属コバルトを用いｆこ
４ ａ （Ｑよりもすぐれｔ、：性能を何していること
かわかる、何故、添ＩＪ口剤に水酸化コバルトあるいは
四三酸 ６−
化コバル１−を用い１こ―仮をカノード分自しｆこのら
アノード分１ヘ−「ると利用率が著しく１１１ヒするの
か１、ｔ ％かでｌ【いが、つぎの１うな＠宋によるｔ
）のでｊ）ると４＋ら１する。ｆなわら、水酸１ｂコバ
ルトＢよび四三酸ｆｋＺコバルトは電気（ＩＺ学旧な活
性１すか小さし）ｆこうに、その十王の状１麿では利用
率を向にさせる効果か乏しい。しか（２ζ（からカノー
ド分鴎をおこ４ｆうと水酸化コハルＩ−は合礪コバルト
に、ま１こ四三酸化コバルトは１ば接」ハルトイオノに
趨元さイ１ろと４左らオ″する。にで水酸化コバルトす
り生成Ｌ ｆ：金喘コバルトは、一般に市販されている
カー１ｔニルコバルトを熱分解して・四重しｆこ金属コ
バル１−よりも活性でｂるので、つづくアノーＶ分晩で
従ｆ、法と同様に１ａ接水酸化コバル］・に変化するか
、一部は欠の０式に従って一度イオンと１．て溶解］７
、さらに０代に従って水酸化コバルトに変化′４−ると
鱈えられる。(81 is a comparison with conventional batteries t1)+ and tE+ [7] The utilization rate is significantly higher than that of tE+. I understand why, if you use cobalt hydroxide or cobalt tetratriate 6-hydride as an added IJ filler and divide one part into the canode part, and then add this part to the anode part, the utilization rate will increase. Is it going to be 111% or less?
), so j) then 4+1. However, cobalt hydroxide 1b and cobalt tetanic acid fkZ are electrically active (IZ science's old activity is slightly less than 1), so their effectiveness in improving the utilization rate is poor. However, when the canode is separated from 2ζ (4f), the hydroxide cohal I- is combined with the cobalt, and the 1 and the tricobalt tetroxide are connected to 1. Cobalt hydroxide is produced by scouring Lf: Cobalt is produced by thermally decomposing the generally commercially available carbonyl cobalt. After a few minutes, it changes to 1a hydrated cobal oxide as in the method, or it dissolves once with ions according to the formula 1).7
, and further changes to cobalt hydroxide in the 0th generation.
Ｃｏ ＋３（Ｊ［−→Ｈｅｏ（Ｊｇ−＋Ｈ２Ｕ＋２ｅ
−−■１（００（Ｊ２−−１−１１（Ｊ −＋ Ｇｏ
（（川） ２ ＋ Ｕ ｔｌ −−■この場合生成する
水酸化コバルトは、同じ六万晶杉の結晶形を有する水酸
化ニッケルの拉ｒの表面に選別用に析出イると考えられ
ろｆこめ、その結束水＋４ イ：’、 ＝ノケル拉ト問
および水酸化ニッケル粒子とニッケル４孔体あるいは二
ノ′１ル扮木との間が水酸１３コバル１−によって結合
さｆ’Ｌ ｒコＩしとなぜ）、１仮の内部低光が繊′し
し、活物冴Ｉ」用事が同モするものと思われる。四三酸
化コバルトを用いｔこ場合も１４様の効果によって利用
率か同ｌ：：−ｊるものと４Ａ−らｌるが、この場合は
リノード分晦のみによりＩＢ接コバルトイオノに変化′
Ｃるので水酸化コバルトを＋Ｈいｆこ場合Ｉ ＩＩも効
果が大きい１こめに、第１図、第２図および＠３図に賦
ら１するようにすくオ′１ｆこ性能が得られるものと考
えらｔする。Co +3(J[-→Heo(Jg-+H2U+2e
--■1(00(J2--1-11(J-+ Go
((river) 2 + U tl --■ The cobalt hydroxide produced in this case is thought to be precipitated for sorting on the surface of the nickel hydroxide ladle, which has the same crystal form as Rokumansho Sugi. The bond between the nickel hydroxide particles and the 4-pore nickel body or the 2-hole wood is bonded by 13 cobal 1- of hydroxide. However, it is thought that the temporary internal low light is weak and that the living matter is the same. Tricobalt tetroxide is used, and in this case, the utilization rate is the same due to the same effect as in 14. However, in this case, it changes to IB contact cobalt ion due to linode separation only.
Since the cobalt hydroxide is added to +Hf in this case, I II also has a large effect. I thought about it.
以上述へｆコように、本発明は、水酸化コバルト ゛あ
るいは四三酸化コバル１〜を添ＩＪ口剤に用いｆこＩＥ
ｌ極板をカノード分囁し、つづいてアノード分画−（
ることに上り、添加剤に金属コバル１−を用いｊこ＋Ｅ
ｔｂ板よりすぐ１１Ｔこ性能を仔する正囁仮を提供する
ことができる。ｆ、〔お、本発明に、［るＩＥＩＭＮは
曲沿。As mentioned above, the present invention uses cobalt hydroxide or tricobal tetroxide 1 to 1 to IJ mouthpiece additives.
The l electrode plate is divided into the cathode section, and then the anode section - (
Particularly, using metal cobal 1- as an additive,
It is possible to provide a model with a performance of 11T faster than the tb board. f, [Oh, in the present invention, [IEIMN is a song list.
鉄等を負比仮とｆる他のアルカリＩ４ｃ油にもＬ内用Ｃ
きることは馬うまでもない。For other alkaline I4C oils that have a negative ratio of iron, etc.
It goes without saying that you can't do it.
第１（２）はカノード分自時間をかえｆコ場合の活物質
利用率の変化、−君２図はアノード分陰時間をかえｆコ
場合の活物′ｆｉ利用率の変化、第３図は６種の袈竹広
によるＩＥ商仮を用いＴコミ池のＩＯＡ ＠電特性の比
較を・もし１こ図である。
Ａ、Ｈ−本ｆ？ｌｉ明によるｒｆＬ Ｍｕ 。
０ 、 ＩＪ 、 Ｅ・・−・−従永の畦池。
９ −
寿 １ 回
θ ／ρ ２θ ３６４θガ
ソ一ド分脳ｌ即園（償ｔｎ）
大 ７ 区
θ ｔｏ ２θ ３θ
Ｕアノード介層１オｒＦＩ（−ｎｉｎ）Figure 1 (2) shows the change in the active material utilization rate when the anode distribution time is changed, Figure 2 shows the change in the active material utilization rate when the anode distribution time is changed, and Figure 3 shows the change in the active material utilization rate when the anode distribution time is changed. Here is a comparison of the IOA @ electric characteristics of T Komiike using 6 types of IE commercial provision by Takehiro Kema. A, H-book f? rfL Mu by Li Ming. 0, IJ, E...--Tonaga's Aneike. 9 - Kotobuki 1 time θ / ρ 2θ 364 θ gaso one brain brain l sokuen (compensation tn) large 7 ku θ to 2θ 3θ
U anode interlayer 1 or FI (-nin)
Claims (1)
ッケルを上体とする活物丙粉末を保持し１こ三次元的に
連続＋−ｒこｆＩＩｔ造をりする基板をアルカリ水浴液
、例えばに、０１（水浴液、 Ｎａ（Ｊｌｌ水浴故等の
中でカノード分１瓶させ、つりいてアノード外廓させ１
このち乾燥することを特徴とするアルカリ″臂油用正晩
仮０ＩＩＩ造法。A substrate on which active material C powder containing cobalt hydroxide or tricobalt tetroxide and nickel hydroxide is held and a three-dimensional continuous structure is prepared is heated in an alkaline water bath, for example. 01 (water bath solution, Na
A method for making alkaline ``armpit oil'' characterized by subsequent drying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57035439A JPS58152372A (en) | 1982-03-05 | 1982-03-05 | Manufacturing method for positive plate of alkaline battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57035439A JPS58152372A (en) | 1982-03-05 | 1982-03-05 | Manufacturing method for positive plate of alkaline battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS58152372A true JPS58152372A (en) | 1983-09-09 |
Family
ID=12441876
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57035439A Pending JPS58152372A (en) | 1982-03-05 | 1982-03-05 | Manufacturing method for positive plate of alkaline battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58152372A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6174261A (en) * | 1984-09-19 | 1986-04-16 | Yuasa Battery Co Ltd | Nickel positive pole for alkaline strage battery |
| JPS61104565A (en) * | 1984-10-25 | 1986-05-22 | Matsushita Electric Ind Co Ltd | Preparation of powdered active material for nickel positive electrode of cell |
| JPS61124061A (en) * | 1984-11-20 | 1986-06-11 | Yuasa Battery Co Ltd | Nickel positive pole plate for alkaline storage battery |
| JPS61124060A (en) * | 1984-11-20 | 1986-06-11 | Yuasa Battery Co Ltd | Paste type positive pole plate for alkaline storage battery |
| JPS61124068A (en) * | 1984-11-20 | 1986-06-11 | Yuasa Battery Co Ltd | Nickel cadmium alkaline battery |
| JPS61138458A (en) * | 1984-12-07 | 1986-06-25 | Yuasa Battery Co Ltd | Alkaline battery |
| JPS61183868A (en) * | 1985-02-08 | 1986-08-16 | Yuasa Battery Co Ltd | Paste type positive electrode for alkaline storage battery |
| JPS62222566A (en) * | 1986-03-24 | 1987-09-30 | Yuasa Battery Co Ltd | Nickel electrode for alkaline battery |
| JPS62234867A (en) * | 1986-04-03 | 1987-10-15 | Yuasa Battery Co Ltd | Nickel electrode for alkaline cell |
| JPS62237667A (en) * | 1986-04-08 | 1987-10-17 | Yuasa Battery Co Ltd | Nickel positive electrode for alkaline storage battery |
| JPH01187768A (en) * | 1988-01-19 | 1989-07-27 | Yuasa Battery Co Ltd | Nickel electrode for alkali battery |
| US10547046B2 (en) | 2011-11-30 | 2020-01-28 | Lawrence Livermore National Security, Llc | High energy/power density nickel oxide/hydroxide materials and nickel cobalt oxide/hydroxide materials and production thereof |
-
1982
- 1982-03-05 JP JP57035439A patent/JPS58152372A/en active Pending
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0430713B2 (en) * | 1984-09-19 | 1992-05-22 | ||
| JPS6174261A (en) * | 1984-09-19 | 1986-04-16 | Yuasa Battery Co Ltd | Nickel positive pole for alkaline strage battery |
| JPH0350384B2 (en) * | 1984-10-25 | 1991-08-01 | Matsushita Electric Ind Co Ltd | |
| JPS61104565A (en) * | 1984-10-25 | 1986-05-22 | Matsushita Electric Ind Co Ltd | Preparation of powdered active material for nickel positive electrode of cell |
| JPS61124061A (en) * | 1984-11-20 | 1986-06-11 | Yuasa Battery Co Ltd | Nickel positive pole plate for alkaline storage battery |
| JPS61124060A (en) * | 1984-11-20 | 1986-06-11 | Yuasa Battery Co Ltd | Paste type positive pole plate for alkaline storage battery |
| JPS61124068A (en) * | 1984-11-20 | 1986-06-11 | Yuasa Battery Co Ltd | Nickel cadmium alkaline battery |
| JPS61138458A (en) * | 1984-12-07 | 1986-06-25 | Yuasa Battery Co Ltd | Alkaline battery |
| JPH0526304B2 (en) * | 1984-12-07 | 1993-04-15 | Yuasa Koohoreeshon Kk | |
| JPH041992B2 (en) * | 1985-02-08 | 1992-01-16 | ||
| JPS61183868A (en) * | 1985-02-08 | 1986-08-16 | Yuasa Battery Co Ltd | Paste type positive electrode for alkaline storage battery |
| JPH0415984B2 (en) * | 1986-03-24 | 1992-03-19 | Yuasa Battery Co Ltd | |
| JPS62222566A (en) * | 1986-03-24 | 1987-09-30 | Yuasa Battery Co Ltd | Nickel electrode for alkaline battery |
| JPS62234867A (en) * | 1986-04-03 | 1987-10-15 | Yuasa Battery Co Ltd | Nickel electrode for alkaline cell |
| JPH044698B2 (en) * | 1986-04-03 | 1992-01-29 | ||
| JPS62237667A (en) * | 1986-04-08 | 1987-10-17 | Yuasa Battery Co Ltd | Nickel positive electrode for alkaline storage battery |
| JPH01187768A (en) * | 1988-01-19 | 1989-07-27 | Yuasa Battery Co Ltd | Nickel electrode for alkali battery |
| JPH0568068B2 (en) * | 1988-01-19 | 1993-09-28 | Yuasa Battery Co Ltd | |
| US10547046B2 (en) | 2011-11-30 | 2020-01-28 | Lawrence Livermore National Security, Llc | High energy/power density nickel oxide/hydroxide materials and nickel cobalt oxide/hydroxide materials and production thereof |
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