JPS5659718A - Preparation of substituted phenoxycarboxylic acid derivative - Google Patents
Preparation of substituted phenoxycarboxylic acid derivativeInfo
- Publication number
- JPS5659718A JPS5659718A JP13501079A JP13501079A JPS5659718A JP S5659718 A JPS5659718 A JP S5659718A JP 13501079 A JP13501079 A JP 13501079A JP 13501079 A JP13501079 A JP 13501079A JP S5659718 A JPS5659718 A JP S5659718A
- Authority
- JP
- Japan
- Prior art keywords
- acid derivative
- substituted
- phenoxycarboxylic acid
- preparation
- expressed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE: To prepare a substituted phenoxycarboxylic acid derivative useful as a raw material for agricultural chemicals effectively, by reacting a specific substituted phenol with an alkyl halide in the presence of a base and a phase transfer catalyst.
CONSTITUTION: A substituted phenol, e.g. 2,4-dichlorophenol or hydroquinone, expressed by formula I (R1 is OH; R2 is H, halogen, nitro, cyano, lower alkyl or trifluoromethyl) is reacted with an alkyl halide, e.g. 2-bromopropionic acid, expressed by the formual R3-X [R3 is formulas II, III, IV and V (R4 and R5 are Hs or lower alkyls)] in the presence of a base, e.g. potassium carbonate, and a phase transfer catalyst, e.g. benzyltriethylammonium chloride, to give a substituted phenoxycarboxylic acid derivative of formula VI.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13501079A JPS5659718A (en) | 1979-10-19 | 1979-10-19 | Preparation of substituted phenoxycarboxylic acid derivative |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13501079A JPS5659718A (en) | 1979-10-19 | 1979-10-19 | Preparation of substituted phenoxycarboxylic acid derivative |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5659718A true JPS5659718A (en) | 1981-05-23 |
Family
ID=15141813
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP13501079A Pending JPS5659718A (en) | 1979-10-19 | 1979-10-19 | Preparation of substituted phenoxycarboxylic acid derivative |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5659718A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5789653U (en) * | 1981-09-02 | 1982-06-02 | ||
JPS60204745A (en) * | 1984-03-30 | 1985-10-16 | Nissan Chem Ind Ltd | Preparation of 2-(4-hydroxyphenoxy)alkanoic acid ester |
FR2800067A1 (en) * | 1999-10-21 | 2001-04-27 | Rhodia Chimie Sa | Preparation of new and known 2-(2-formyl-4-nitro-phenoxy or -phenylthio)-alkanoic acid derivatives by selective nitration, for use as intermediates for pharmaceutically useful nitro-benzofurans or -benzothiophenes |
-
1979
- 1979-10-19 JP JP13501079A patent/JPS5659718A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5789653U (en) * | 1981-09-02 | 1982-06-02 | ||
JPS60204745A (en) * | 1984-03-30 | 1985-10-16 | Nissan Chem Ind Ltd | Preparation of 2-(4-hydroxyphenoxy)alkanoic acid ester |
FR2800067A1 (en) * | 1999-10-21 | 2001-04-27 | Rhodia Chimie Sa | Preparation of new and known 2-(2-formyl-4-nitro-phenoxy or -phenylthio)-alkanoic acid derivatives by selective nitration, for use as intermediates for pharmaceutically useful nitro-benzofurans or -benzothiophenes |
WO2001028974A3 (en) * | 1999-10-21 | 2001-12-06 | Rhodia Chimie Sa | Intermediates for making a benzofuran or benzothiophene derivative nitrated in position 5 and uses thereof |
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