JPS5586A - Preparation of d-n-carbamyl(p-hydroxyphenyl)glycine - Google Patents

Preparation of d-n-carbamyl(p-hydroxyphenyl)glycine

Info

Publication number
JPS5586A
JPS5586A JP3158079A JP3158079A JPS5586A JP S5586 A JPS5586 A JP S5586A JP 3158079 A JP3158079 A JP 3158079A JP 3158079 A JP3158079 A JP 3158079A JP S5586 A JPS5586 A JP S5586A
Authority
JP
Japan
Prior art keywords
hydroxyphenyl
hydantoin
carbamyl
glycine
semi
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP3158079A
Other languages
Japanese (ja)
Other versions
JPS5918994B2 (en
Inventor
Hideaki Yamada
Satomi Takahashi
Koji Yoneda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kanegafuchi Chemical Industry Co Ltd
Original Assignee
Kanegafuchi Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kanegafuchi Chemical Industry Co Ltd filed Critical Kanegafuchi Chemical Industry Co Ltd
Priority to JP3158079A priority Critical patent/JPS5918994B2/en
Publication of JPS5586A publication Critical patent/JPS5586A/en
Publication of JPS5918994B2 publication Critical patent/JPS5918994B2/en
Expired legal-status Critical Current

Links

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  • Preparation Of Compounds By Using Micro-Organisms (AREA)

Abstract

PURPOSE: To prepare D-N-carbamyl(p-hydroxyphenyl)glycine in high yield, by contacting 5-(p-hydroxyphenyl)hydantoin with bacteria belonging to Pseudomonas genus.
CONSTITUTION: Cultured liquid, cells or treated cells, prepared by culturing bacteria belonging to Pseudomonas genus and capable of assymmetrically hydrolyzing a hydantoin ring, are mixed or inoculated to 5-(p-hydroxyphenyl)hydantoin, and made to react in an aqueous medium at pH6W11 to perform the assymmetric hydrolysis of the hydantoin ring. The racemization reaction of the hydantoin ring is accelerated by this process, and the D-N-carbamyl(p-hydroxyphenyl)glycine can be obtained in high yield. The product is useful as an intermediate of semi-synthetic penicillin, semi-synthetic cephalosporin, etc.
COPYRIGHT: (C)1980,JPO&Japio
JP3158079A 1979-03-16 1979-03-16 Method for producing D-N-carbamyl (p-hydroxyphenyl) glycine Expired JPS5918994B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3158079A JPS5918994B2 (en) 1979-03-16 1979-03-16 Method for producing D-N-carbamyl (p-hydroxyphenyl) glycine

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3158079A JPS5918994B2 (en) 1979-03-16 1979-03-16 Method for producing D-N-carbamyl (p-hydroxyphenyl) glycine

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP1157576A Division JPS5344690A (en) 1976-02-04 1976-02-04 Preparation of d-n-carbamylphenylglycine and its substituted derivatives

Publications (2)

Publication Number Publication Date
JPS5586A true JPS5586A (en) 1980-01-05
JPS5918994B2 JPS5918994B2 (en) 1984-05-01

Family

ID=12335114

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3158079A Expired JPS5918994B2 (en) 1979-03-16 1979-03-16 Method for producing D-N-carbamyl (p-hydroxyphenyl) glycine

Country Status (1)

Country Link
JP (1) JPS5918994B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02174684A (en) * 1988-12-26 1990-07-06 Mitsui Toatsu Chem Inc Production of n-carbamoyl-d-phenylglycine

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02174684A (en) * 1988-12-26 1990-07-06 Mitsui Toatsu Chem Inc Production of n-carbamoyl-d-phenylglycine

Also Published As

Publication number Publication date
JPS5918994B2 (en) 1984-05-01

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