JPS54131584A - Manufacture of cation exchange membrane - Google Patents
Manufacture of cation exchange membraneInfo
- Publication number
- JPS54131584A JPS54131584A JP3925978A JP3925978A JPS54131584A JP S54131584 A JPS54131584 A JP S54131584A JP 3925978 A JP3925978 A JP 3925978A JP 3925978 A JP3925978 A JP 3925978A JP S54131584 A JPS54131584 A JP S54131584A
- Authority
- JP
- Japan
- Prior art keywords
- groups
- membrane
- dipped
- treated
- cation exchange
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
PURPOSE: To manufacture cation exchange membrane of excellent OH- permeation inhibiting property by the procedure in which an amine is reacted to the one side of a fluoro-polymer membrane with sulfonylhalide groups followed by a high temperature heat treatment and hydrolysis, and then the membrane so treated is dipped in an organic solvent, then heat treated and impregnated with a diene derivative for polymerization, and lastly dipped in an organic solvent.
CONSTITUTION: A di- or polyamine is reacted to the one side of a fluoro-polymer membrane with sulfonylhalide groups on its side chains, then heat treated at a temperature between 170°C and the deterioration temperature of the polymer membrane, proferably 190 to 300°C, and lastly hydrolized to obtain cation exchange membrane. The membrane thus obtained is dipped in an organic solvent, having a water solubility of 0.1 g/100 g of H2O at room temperature and a boiling point of more than 120°C at 760 mm Hg, and then put between flat plates to subject it to a heat treatment at 40 to 180°C. Then, the membrane so treated is impregnated with a diene derivative with CO2H groups or groups convertible into CO2H groups, then put between flat plates to subject it to a heat treatment at 80 to 180°C to remove the solvent and also to convert groups convertible into CO2H groups into CO2H groups, and lastly dipped in a NaOH aqueous solution.
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3925978A JPS54131584A (en) | 1978-04-05 | 1978-04-05 | Manufacture of cation exchange membrane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3925978A JPS54131584A (en) | 1978-04-05 | 1978-04-05 | Manufacture of cation exchange membrane |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS54131584A true JPS54131584A (en) | 1979-10-12 |
Family
ID=12548138
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3925978A Pending JPS54131584A (en) | 1978-04-05 | 1978-04-05 | Manufacture of cation exchange membrane |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS54131584A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002516348A (en) * | 1998-05-22 | 2002-06-04 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | Crosslinked ion conductive membrane |
-
1978
- 1978-04-05 JP JP3925978A patent/JPS54131584A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002516348A (en) * | 1998-05-22 | 2002-06-04 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | Crosslinked ion conductive membrane |
| JP4718010B2 (en) * | 1998-05-22 | 2011-07-06 | スリーエム カンパニー | Cross-linked ion conductive membrane |
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