JPH11323223A - Ink-jet ink and its production - Google Patents
Ink-jet ink and its productionInfo
- Publication number
- JPH11323223A JPH11323223A JP14844098A JP14844098A JPH11323223A JP H11323223 A JPH11323223 A JP H11323223A JP 14844098 A JP14844098 A JP 14844098A JP 14844098 A JP14844098 A JP 14844098A JP H11323223 A JPH11323223 A JP H11323223A
- Authority
- JP
- Japan
- Prior art keywords
- ink
- film
- inorganic vapor
- deposited film
- deposited
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、少なくとも無機蒸
着膜の非定型偏平片を含有してなるインクジェットイン
クに関するものであり、インクジェットインクによって
対象物に表出された印字や描画に金属光沢等を付与し得
る又は無機膜の有する機能性を付与しうるインクジェッ
トインクとその製法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an ink-jet ink containing at least an atypical flat piece of an inorganic vapor-deposited film. The present invention relates to an ink-jet ink that can be imparted or can impart the functionality of an inorganic film and a method for producing the same.
【０００２】[0002]
【従来の技術】インクジェットインクとして、水溶性染
料、グリコール系等の溶液安定剤等、アルコール等の粘
度調節剤等を水に溶解又は分散せしめたものが知られて
いる。インクジェットインクを用いたインクジェットプ
リンターは、インクジェットインクをノズルから噴射し
て対象物に印字、描画するものであり、ノズルからイン
クジェットインクが噴射される時にノズルに詰まること
が嫌われ、インクジェットインクに固形物を含有せしめ
ることはほとんど採用されていない。2. Description of the Related Art Ink jet inks are known in which water-soluble dyes, glycol-based solution stabilizers and the like, and viscosity modifiers such as alcohols and the like are dissolved or dispersed in water. Inkjet printers that use inkjet ink print and draw on the target object by ejecting the inkjet ink from the nozzles.I hate clogging the nozzles when the inkjet ink is ejected from the nozzles. Is hardly adopted.
【０００３】[0003]
【発明が解決しようとする課題】本発明は、従来のイン
クジェットインクに見られない、インクジェットインク
により、印字、描画に金属光沢を付与する、又は印字、
描画に透明導電性等の無機膜の有する機能を付与するこ
とを目的とするものである。SUMMARY OF THE INVENTION The present invention relates to a method for imparting metallic luster to printing and drawing, or printing, using an inkjet ink, which is not found in conventional inkjet inks.
An object of the present invention is to provide a drawing with a function of an inorganic film such as transparent conductivity.
【０００４】[0004]
【課題を解決するための手段】すなわち本発明は、厚さ
が０．２ミクロンメーター以下の無機蒸着膜の非定型偏
平片を含有してなることを特徴とするインクジェットイ
ンクであり、無機蒸着膜がアルミニウム、銀、金、ニッ
ケル、クロム、錫、亜鉛、インジウムの単体金属又はこ
れらの合金および単体酸化物又はそれら混合物の少なく
とも一種である前記のインクジェットインクであり、非
定型偏平片の最大長さが５ミクロンメーター以下である
前記のインクジェットインクであり、水性樹脂薄膜層を
無機蒸着膜の非定型偏平片の少なくとも片面に有する前
記のインクジェットインクであります。That is, the present invention relates to an ink-jet ink comprising an irregular flat piece of an inorganic vapor-deposited film having a thickness of 0.2 μm or less. Is the above-mentioned ink-jet ink, which is at least one of a single metal of aluminum, silver, gold, nickel, chromium, tin, zinc, indium or an alloy and a single oxide or a mixture thereof, and the maximum length of the atypical flat piece Is an ink-jet ink having a thickness of 5 μm or less, wherein the ink-jet ink has an aqueous resin thin film layer on at least one surface of an irregular flat piece of an inorganic vapor-deposited film.
【０００５】また離型性フイルムに無機蒸着膜を形成
し、離型性フイルムを剥離し、無機蒸着膜を粉砕し、粘
度調節剤等と共に水中に分散せしめることを特徴とする
インクジェットインクの製法であり、離型性フイルムに
水性樹脂薄膜層を形成し、該水性樹脂薄膜層上に無機蒸
着膜を形成し、離型性フイルムを剥離し、少なくとも無
機蒸着膜と水性樹脂薄膜層からなる複合体を粉砕する前
記のインクジェットインクの製法であります。[0005] An ink-jet ink manufacturing method characterized in that an inorganic vapor-deposited film is formed on a release film, the release film is peeled off, the inorganic vapor-deposited film is ground, and dispersed in water together with a viscosity modifier and the like. Yes, an aqueous resin thin film layer is formed on a release film, an inorganic vapor-deposited film is formed on the aqueous resin thin film layer, the release film is peeled off, and a composite comprising at least an inorganic vapor-deposited film and an aqueous resin thin film layer This is the method of manufacturing the inkjet ink described above.
【０００６】[0006]
【発明の実施の形態】本発明における、無機蒸着膜の偏
平片であって厚さが０．２ミクロンメーター以下の非定
型偏平片は、厚さが０．０３から０．２ミクロンメータ
ー程度の無機薄膜層であり、無機薄膜形成のための金属
としては、金属光沢を有する等の機能を有するものであ
れば特に限定されるものではないが、アルミニウム、
銀、金、ニッケル、クロム、錫、亜鉛、インジウム等が
使用され、これらの単体金属又はこれらの合金および単
体酸化物又はそれら混合物の少なくとも一種が使用され
る。また、前記例示のものの中から一種または二種以上
を適宜選定し一層または二層以上にして使用すればよ
い。これらの無機蒸着薄膜層の厚さは、０．０３から
０．２ミクロンメーターの範囲が好ましく、０．０３ミ
クロンメーターに満たないときは、光輝性においてまた
機能性においてその性能は乏しく、０．２ミクロンメー
ターを超えるときは、これ以上厚さを大きくしても反射
性、光輝性等の増大に影響が少ない上に経済的にも得策
ではない。BEST MODE FOR CARRYING OUT THE INVENTION In the present invention, a flat piece of an inorganic vapor-deposited film having a thickness of 0.2 μm or less has a thickness of about 0.03 to 0.2 μm. The inorganic thin film layer, the metal for forming the inorganic thin film is not particularly limited as long as it has a function such as having a metallic luster, aluminum,
Silver, gold, nickel, chromium, tin, zinc, indium, and the like are used, and at least one of these simple metals, their alloys, simple oxides, and mixtures thereof is used. In addition, one or two or more of the above examples may be appropriately selected and used in one or more layers. The thickness of these inorganic vapor-deposited thin film layers is preferably in the range of 0.03 to 0.2 μm, and when less than 0.03 μm, their performance in terms of glitter and functionality is poor. When the thickness exceeds 2 μm, even if the thickness is further increased, there is little influence on the increase in the reflectivity and the brilliancy, and it is not economically advantageous.
【０００７】本発明において、上記無機蒸着膜の非定型
偏平片を得るためには、離型性フイルムに水性樹脂薄膜
層を形成し、該水性樹脂薄膜層上に無機蒸着膜を形成
し、離型性フイルムを剥離し、少なくとも水性樹脂薄膜
層と無機蒸着膜とを有する複合膜を粉砕する製法が好ま
しく採用される。水性樹脂薄膜層は必ずしも必要ではな
いが、無機蒸着膜を形成した離型性フイルムから、離型
フイルムを剥離し、無機蒸着膜を粉砕し、無機蒸着膜の
非定型偏平片を得る時、取り扱い性から水性樹脂薄膜層
があった方が好ましい。該水性樹脂層中にはあらかじめ
色材等インクジェットインクとしての構成成分を含有さ
せておいてもよい。無機蒸着（薄膜）層の剥離性フイル
ム上（又は水性樹脂層上）への形成は、その方法におい
て特に限定されるものではなく、蒸着、スパッタリン
グ、イオンプレーテイングなど乾式薄膜形成法が好まし
い。この無機蒸着層薄膜形成後、該層上に、必要に応じ
てさらに前記の水性樹脂層を形成してもよく、また他の
樹脂性保護層を形成してもよい。この無機蒸着（薄膜）
層の剥離性フイルム上（又は水性樹脂層上）への形成は
目的とする無機蒸着層を一層設けてもよく、二層以上設
けてもよく、二層以上設けるに際しては、層間に水性樹
脂層を介在させてもよく、介在なしに直接層を積層して
もよい。この多層形成の場合においては、剥離性フイル
ムからの剥離が容易となり好適となる場合が多い。In the present invention, in order to obtain an atypical flat piece of the inorganic vapor-deposited film, an aqueous resin thin film layer is formed on a releasable film, and an inorganic vapor-deposited film is formed on the aqueous resin thin film layer. A production method in which the mold film is peeled off and a composite film having at least an aqueous resin thin film layer and an inorganic vapor deposition film is pulverized is preferably employed. Although the aqueous resin thin film layer is not always necessary, when the release film is peeled from the release film on which the inorganic vapor-deposited film is formed, the inorganic vapor-deposited film is crushed, and when the amorphous flat film of the inorganic vapor-deposited film is obtained, handling is performed. It is preferable to have an aqueous resin thin film layer from the viewpoint of the properties. The aqueous resin layer may contain a component such as a coloring material as an inkjet ink in advance. The method of forming the inorganic vapor-deposited (thin film) layer on the peelable film (or the aqueous resin layer) is not particularly limited in the method, and a dry thin film forming method such as vapor deposition, sputtering, and ion plating is preferable. After forming the inorganic vapor-deposited layer thin film, the above-mentioned aqueous resin layer may be further formed on the layer if necessary, or another resinous protective layer may be formed. This inorganic vapor deposition (thin film)
The formation of the layer on the releasable film (or on the aqueous resin layer) may be carried out by providing one layer of the intended inorganic vapor-deposited layer, or by providing two or more layers. May be interposed, or the layers may be directly laminated without any intervention. In the case of this multi-layer formation, peeling from the peelable film is facilitated and often preferred.
【０００８】剥離性フイルム上に形成され剥離性フイル
ムを剥離した、薄膜層状物として得られた非定型偏平片
の前駆体（複合体）を粉砕して本発明の非定型偏平片を
得るが、粉砕方法としては、特に限定されないが、ジェ
ットミル、ボールミル、リングロールミル、ハンマーミ
ル、チューブミル等が挙げられる。この粉砕を水中で行
ってもよくその際、染料等の色材、アルコール等の粘度
調節材、乾燥促進材、沈降安定剤、界面活性剤等を同時
に使用して粉砕してもよい。さらに特に粉砕を積極的に
実施しなくても、剥離性フイルムから剥離することだけ
で、前駆体（複合体）が微細な非定型偏平片となる場合
もある。The precursor (composite) of the atypical flat piece obtained as a thin film layered product formed on the peelable film and from which the peelable film has been peeled is crushed to obtain the atypical flat piece of the present invention. The pulverizing method is not particularly limited, and examples thereof include a jet mill, a ball mill, a ring roll mill, a hammer mill, and a tube mill. This pulverization may be carried out in water, and in that case, pulverization may be carried out simultaneously using a coloring material such as a dye, a viscosity controlling material such as alcohol, a drying accelerator, a sedimentation stabilizer, and a surfactant. Further, even if the pulverization is not actively performed, the precursor (composite) may become a fine irregular flat piece simply by peeling from the peelable film.
【０００９】上記水性樹脂はインクジェットインクに該
無機蒸着膜の非定型偏平片が分散される時に分散剤とし
てまた沈降を防ぐ安定剤としても作用する。水性樹脂と
しては製膜性があり、かつ水溶解性、ないしは易水分散
性のものが好ましく、エチレン・ビニルアルコール共重
合体、酢酸ビニル部分加水分解物、ポリビニルアルコー
ル、ポリエチレングリコール等のエチレンオキサイド付
加物、アラビヤゴム、ＣＭＣ（カルボキシメチルセルロ
ーズ）等のセルローズ誘導体等が挙げられるが、なかで
もポリエチレングリコール等のエチレンオキサイド付加
物が好ましく使用できる。該樹脂層の厚さは、０．３−
２ミクロン程度のものが好ましい。The aqueous resin functions as a dispersant when the atypical flat pieces of the inorganic vapor-deposited film are dispersed in the ink-jet ink and also as a stabilizer for preventing sedimentation. The aqueous resin is preferably a film-forming and water-soluble or easily dispersible in water, and ethylene oxide addition such as ethylene-vinyl alcohol copolymer, vinyl acetate partial hydrolyzate, polyvinyl alcohol and polyethylene glycol is preferred. , Arabic gum, cellulose derivatives such as CMC (carboxymethylcellulose), and among them, ethylene oxide adducts such as polyethylene glycol can be preferably used. The thickness of the resin layer is 0.3-
Those of about 2 microns are preferred.
【００１０】本発明で使用される離型性フイルムとして
は、ポリテトラフルオロエチレン、ポリエチレン、ポリ
プロピレン、ポリエチレンテレフタレート，ポリエチレ
ンナフタレート等のポリエステルフイルム、66ナイロ
ン、６ナイロン等のポリアミドフイルム、ポリカーボネ
ートフイルム、トリアセテートフイルム、ポリイミドフ
イルム等が挙げられるが特に限定されるものではない。
これらのフイルムの厚さは４ミクロンから４０ミクロン
であり、４ミクロンに満たないものは、工程等で取り扱
い性に問題が多く、４０ミクロンを超えると、柔軟性に
乏しくなり、剥離等に問題が多くなる。本発明において
は、厚さが０．２ミクロンメーター以下の無機蒸着膜の
非定型偏平片を使用しインクジェットインクの構成成分
とすることを骨子とするものであり、インクジェットイ
ンクに使用されるその他の構成成分、たとえば、染料等
の色材、グリセリンやジエチレングリコール等の粘度調
節剤、エタノール等の乾燥促進剤、界面活性材、消泡剤
等については従来公知の種々成分を適宜選択してもよい
ものである。The releasable films used in the present invention include polyester films such as polytetrafluoroethylene, polyethylene, polypropylene, polyethylene terephthalate and polyethylene naphthalate, polyamide films such as 66 nylon and 6 nylon, polycarbonate films and triacetate. Films, polyimide films and the like can be mentioned, but they are not particularly limited.
The thickness of these films is from 4 microns to 40 microns. If the thickness is less than 4 microns, there are many problems in handling properties in the process and the like. More. In the present invention, the outline is to use a non-standard flat piece of an inorganic vapor-deposited film having a thickness of 0.2 μm or less as a component of the inkjet ink, and other components used in the inkjet ink Constituents, for example, coloring materials such as dyes, viscosity modifiers such as glycerin and diethylene glycol, drying accelerators such as ethanol, surfactants, defoamers, and the like may be appropriately selected from conventionally known various components. It is.
【００１１】[0011]
【実施例】＊＊実施例１ 厚さ２０ミクロンの未延伸ポリプロピレンフイルムに、
フェノール末端エチレンオキサイド付加物（分子量８０
０）１５部（重量部、以下同じ）、スルフォン酸末端エ
チレンオキサイド付加物（分子量６００）２部、シアニ
ン系顔料５部を分散した液をグラビヤ方式で塗布・乾燥
し、厚さ１．０ミクロンメーターの水性樹脂層を形成し
た。該水性樹脂層上に、真空蒸着機において銀を０．０
８ミクロンメーターの厚さになるように、無機薄膜層と
して蒸着形成した。得られたこの銀金属薄膜層上に、ト
ップコート層として前記の水性樹脂層を０．５ミクロン
メーター厚さの樹脂層を形成した。。EXAMPLES ** Example 1 An unstretched polypropylene film having a thickness of 20 microns was applied to
Phenol-terminated ethylene oxide adduct (molecular weight 80
0) A solution in which 15 parts (parts by weight, hereinafter the same), 2 parts of a sulfonic acid-terminated ethylene oxide adduct (molecular weight: 600), and 5 parts of a cyanine pigment were dispersed and coated by a gravure method and dried, and the thickness was 1.0 μm. An aqueous resin layer of the meter was formed. On the aqueous resin layer, silver was added in a vacuum evaporator at 0.0%.
An inorganic thin film layer was formed by vapor deposition so as to have a thickness of 8 μm. On the obtained silver metal thin film layer, a water-based resin layer having a thickness of 0.5 μm was formed as a top coat layer. .
【００１２】こうして青色の特殊光輝性の長尺ロール積
層体を得、トップコート層側を下にして該長尺ロール積
層体を、巻き戻し方向に直交して配されたガイドバーの
下側を通過させながら巻き戻し、フイルムのみをこのガ
イドバーを挟み込むようにし１０％延伸を施しながら上
向きに巻き戻し、他の水性樹脂層・銀金属薄膜層・トッ
プコート層からなる積層体をフイルムと反対側に剥離し
振り落とし集積した。得られた積層体を水中で粉砕し、
グリセリンを添加し、篩い分け、銀金属薄膜層の最長片
長さで０．８ミクロンメーターの、厚さ０．０８ミクロ
ンメーターの特殊光輝性の美麗な偏平片を含むインクジ
ェットインクを得た。In this way, a blue special glittering long roll laminate is obtained, and the long roll laminate is placed with the top coat layer side down, with the lower side of the guide bar arranged perpendicular to the rewinding direction. The film is rewound while passing it, and only the film is sandwiched between the guide bars and rewound upward while being stretched by 10%, and the laminate including the other aqueous resin layer, the silver metal thin film layer, and the top coat layer is opposite to the film. And was shaken off and collected. The obtained laminate is pulverized in water,
Glycerin was added, and the mixture was sieved to obtain an ink-jet ink containing a specially bright and beautiful flat piece having a maximum length of 0.8 μm and a thickness of 0.08 μm of a silver metal thin film layer.
【００１３】＊＊実施例２ 厚さ２０ミクロンの未延伸ポリプロピレンフイルムに、
フェノール末端エチレンオキサイド付加物（分子量１２
００）１５部（重量部、以下同じ）、スルフォン酸末端
エチレンオキサイド付加物（分子量６００）２部、ナフ
トールレッド系顔料２部を分散した液をグラビヤ方式で
塗布・乾燥し、厚さ１．０ミクロンメーターの水性樹脂
層を形成した。該水性樹脂層上に、真空蒸着機において
アルミニウムを０．１２ミクロンメーターの厚さになる
ように、無機薄膜層として蒸着形成した。得られたこの
アルミニウム金属薄膜層上に、トップコート層として前
記の水性樹脂層を０．５ミクロンメーター厚さの樹脂層
を形成した。。こうして赤色の特殊光輝性の長尺ロール
積層体を得、トップコート層側を下にして該長尺ロール
積層体を、巻き戻し方向に直交して配されたガイドバー
の下側を通過させながら巻き戻し、フイルムのみをこの
ガイドバーを挟み込むようにし１０％延伸を施しながら
上向きに巻き戻し、他の水性樹脂層・アルミニウム金属
薄膜層・トップコート層からなる積層体をフイルムと反
対側に剥離し振り落とし集積した。得られた積層体を水
中で粉砕し、ジエチレングリコールトエタノールとを添
加し、篩い分け、アルミニウム金属薄膜層の最長片長さ
で２．０ミクロンメーターの、厚さ０．１２ミクロンメ
ーターの特殊光輝性の美麗な偏平片を含むインクジェッ
トインクを得た。** Example 2 A 20 micron thick unstretched polypropylene film was
Phenol-terminated ethylene oxide adduct (molecular weight 12
00) A solution in which 15 parts (parts by weight, the same applies hereinafter), 2 parts of a sulfonic acid-terminated ethylene oxide adduct (molecular weight: 600), and 2 parts of a naphthol red pigment are dispersed and coated by a gravure method and dried to a thickness of 1.0 An aqueous resin layer of a micrometer was formed. Aluminum was vapor-deposited and formed on the aqueous resin layer as an inorganic thin film layer in a vacuum vapor deposition machine so as to have a thickness of 0.12 μm. On the obtained aluminum metal thin film layer, a water-based resin layer having a thickness of 0.5 μm was formed as a top coat layer. . Thus, a long roll laminate having a special brilliant red color is obtained, while passing the top roll layer side down, passing the long roll laminate below the guide bar arranged perpendicular to the rewinding direction. Unwinding, rewinding upward only while holding the guide bar between the guide bars and stretching it by 10%, peeling off the laminate consisting of the other aqueous resin layer, aluminum metal thin film layer and top coat layer on the side opposite to the film. It was shaken off and accumulated. The obtained laminate is pulverized in water, added with diethylene glycol triethanol, and sieved. An inkjet ink containing a beautiful flat piece was obtained.
【００１４】[0014]
【発明の効果】本発明により、極めて薄い無機蒸着薄膜
を用いることによって、その優れた隠蔽力により、少量
で金属光沢を印字や描画に付与し得るインクジェットイ
ンクが得られ、また、印字や描画に透明導電性等の機能
を付与することもできるインクジェットインクが提供で
きる。According to the present invention, by using an extremely thin inorganic vapor-deposited thin film, an ink-jet ink capable of imparting metallic luster to printing or drawing with a small amount due to its excellent hiding power can be obtained. An inkjet ink that can also impart functions such as transparent conductivity can be provided.
Claims (6)
蒸着膜の非定型偏平片を含有してなることを特徴とする
インクジェットインク。1. An ink-jet ink comprising an irregular flat piece of an inorganic vapor-deposited film having a thickness of 0.2 μm or less.
ケル、クロム、錫、亜鉛、インジウムの単体金属又はこ
れらの合金および単体酸化物又はそれら混合物の少なく
とも一種である請求項１記載のインクジェットインク。2. The ink-jet ink according to claim 1, wherein the inorganic vapor-deposited film is at least one of a simple metal of aluminum, silver, gold, nickel, chromium, tin, zinc, and indium, an alloy thereof, a simple oxide and a mixture thereof. .
ター以下である請求項１記載のインクジェットインク。3. The ink-jet ink according to claim 1, wherein the maximum length of the atypical flat piece is 5 micrometers or less.
片の少なくとも片面に有する請求項１記載のインクジェ
ットインク。4. The ink-jet ink according to claim 1, wherein an aqueous resin thin film layer is provided on at least one side of the atypical flat piece of the inorganic vapor-deposited film.
型性フイルムを剥離し、無機蒸着膜を粉砕し、粘度調節
剤等と共に水中に分散せしめることを特徴とするインク
ジェットインクの製法。5. A method for producing an ink-jet ink, comprising: forming an inorganic vapor-deposited film on a releasable film, peeling the releasable film, pulverizing the inorganic vapor-deposited film, and dispersing the inorganic vapor-deposited film together with a viscosity modifier and the like. .
し、該水性樹脂薄膜層上に無機蒸着膜を形成し、離型性
フイルムを剥離し、少なくとも無機蒸着膜と水性樹脂薄
膜層からなる複合体を粉砕する請求項５記載のインクジ
ェットインクの製法。6. An aqueous resin thin film layer is formed on a releasable film, an inorganic vapor-deposited film is formed on the aqueous resin thin film layer, and the releasable film is peeled off at least from the inorganic vapor-deposited film and the aqueous resin thin film layer. The method for producing an ink-jet ink according to claim 5, wherein the composite is crushed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14844098A JPH11323223A (en) | 1998-05-13 | 1998-05-13 | Ink-jet ink and its production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14844098A JPH11323223A (en) | 1998-05-13 | 1998-05-13 | Ink-jet ink and its production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH11323223A true JPH11323223A (en) | 1999-11-26 |
Family
ID=15452852
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14844098A Pending JPH11323223A (en) | 1998-05-13 | 1998-05-13 | Ink-jet ink and its production |
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| Country | Link |
|---|---|
| JP (1) | JPH11323223A (en) |
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