JPH09119098A - Decorative paper - Google Patents
Decorative paperInfo
- Publication number
- JPH09119098A JPH09119098A JP7273860A JP27386095A JPH09119098A JP H09119098 A JPH09119098 A JP H09119098A JP 7273860 A JP7273860 A JP 7273860A JP 27386095 A JP27386095 A JP 27386095A JP H09119098 A JPH09119098 A JP H09119098A
- Authority
- JP
- Japan
- Prior art keywords
- plasticizer
- decorative paper
- layer
- heat
- decorative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paper (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は内装用化粧紙、特に
壁、天井等をカバーする壁紙、天井材としての化粧紙に
関し、貼り替えが考えられる用途の化粧紙に関するもの
である。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a decorative paper for interiors, and more particularly, to a wallpaper for covering walls, ceilings, etc., and a decorative paper as a ceiling material, and more particularly to a decorative paper for which replacement is possible.
【０００２】[0002]
【従来の技術】従来より、壁や天井に貼付する化粧紙と
しては、難燃紙等の基材上にポリ塩化ビニル（以下、Ｐ
ＶＣとする）樹脂層を設け、適宜な絵柄層やエンボス加
工を施したものが知られており、これらを施工の際には
でんぷん糊等の接着剤を基材裏面側に塗布して貼り付け
していた。又は、難燃裏打紙などの基材表面にＰＶＣ樹
脂層を設けた化粧紙において、基材裏面側に感熱型粘着
剤層を設けたことを特徴とする化粧紙も知られている。2. Description of the Related Art Conventionally, as a decorative paper to be attached to a wall or a ceiling, polyvinyl chloride (hereinafter, referred to as P
It is known that a resin layer (referred to as VC) is provided and an appropriate pattern layer or embossing is applied. When these are applied, an adhesive such as starch paste is applied to the back side of the base material and attached. Was. Alternatively, a decorative paper having a PVC resin layer provided on the surface of a base material such as a flame-retardant backing paper is also known, in which a heat-sensitive adhesive layer is provided on the back surface side of the base material.
【０００３】しかし、最近の住宅事情により再施工、リ
フォームなどが多く行われるようになり、前記化粧紙は
その際の貼り替えに問題があった。すなわち前者の場
合、貼り替えの際に基材である難燃紙等の紙間で剥が
れ、その約半分は壁や天井構造物の表面に残るため、下
地の処理が必要となり、しかも構造物本来の防火性能を
低下する事があった。また、後者の場合、ＰＶＣ層に含
まれるフタル酸系のフタル酸ジオクチル（以下、ＤＯＰ
とする）等の可塑剤が移動して感熱粘着剤層に進入し、
これを可塑化し施工した場合、常温で粘着剤層から剥が
れるという現象が起きている。However, due to recent housing circumstances, reworking, reforming, and the like are often performed, and there is a problem in replacement of the decorative paper at that time. That is, in the case of the former, when it is replaced, it peels off between the flame-retardant paper, which is the base material, and about half of it peels off on the surface of the wall or ceiling structure, so it is necessary to treat the groundwork. There was a case that the fire prevention performance of the. In the latter case, the dioctyl phthalate (hereinafter referred to as DOP) of the phthalic acid type contained in the PVC layer is used.
Plasticizer such as) moves and enters the heat-sensitive adhesive layer,
When this is plasticized and applied, there is a phenomenon that it peels off from the adhesive layer at room temperature.
【０００４】[0004]
【発明が解決しようとする課題】本発明は、これらの問
題点を解決するためになされたものであり、その課題と
するところは、施工後、貼り替えを容易に行うことがで
き、可塑剤の影響もなく、常温において剥離しない化粧
紙を提供することにある。SUMMARY OF THE INVENTION The present invention has been made to solve these problems, and the object of the present invention is to make it possible to easily replace the plasticizer after construction and to use a plasticizer. Another object of the present invention is to provide a decorative paper that is not affected by the above and does not peel off at room temperature.
【０００５】[0005]
【課題を解決するための手段】本発明は前記課題を解決
するため、基材表面に、可塑剤を使用しない水性エマル
ジョンからなる化粧層を設け、基材裏面側に感熱型粘着
剤層を設けてなることを特徴とする化粧紙を提供し、ま
た、前記感熱型粘着剤が、接着力を与える高分子材料
と、粘着付与剤と、固体可塑剤とからなることを特徴と
する化粧紙を提供する。In order to solve the above problems, the present invention provides a base material surface with a cosmetic layer made of an aqueous emulsion without using a plasticizer, and a heat-sensitive adhesive layer on the back surface side of the base material. And a thermosensitive adhesive, wherein the thermosensitive adhesive comprises a polymeric material that imparts adhesive force, a tackifier, and a solid plasticizer. provide.
【０００６】[0006]
【発明の実施の形態】以下本発明の実施の形態を図面に
基づき説明する。基材１としては、坪量８０〜１５０ｇ
／ｍ2 程度の化粧紙用原紙が使用可能であり、壁紙等に
用いる場合は特に難燃性の裏打紙が好適に使用できる。Embodiments of the present invention will be described below with reference to the drawings. The base material 1 has a basis weight of 80 to 150 g.
/ M 2 of base paper for decorative paper can be used, and when used as wallpaper, etc., flame-retardant backing paper can be preferably used.
【０００７】基材１の表面に設ける可塑剤を使用しない
水性エマルジョンからなる化粧層２としては、図示はし
ないが任意の絵柄層や凹凸模様を設けることができる。
また、この凹凸模様はエンボス板による凹凸模様、また
は合成樹脂層中に炭化水素を内包したカプセル発泡剤を
分散して、発泡盛り上げによる凹凸模様を形成すること
でもよい。The decorative layer 2 made of an aqueous emulsion which does not use a plasticizer and is provided on the surface of the base material 1 may be provided with an optional pattern layer or an uneven pattern although not shown.
In addition, this uneven pattern may be formed by an embossed plate or by dispersing a capsule foaming agent containing a hydrocarbon in a synthetic resin layer to form an uneven pattern by foaming.
【０００８】本発明においては前記のごとく、化粧層に
使用する樹脂として可塑剤を使用しない水性エマルジョ
ンを選定した。これは、従来の壁紙の主流であるＰＶＣ
を用いた壁紙では、それに柔軟性を与えるためのフタル
酸系のＤＯＰ等の可塑剤が感熱型粘着剤層に移動し、こ
れを可塑化し常温で剥離するという現象を引き起こす為
である。前記可塑剤を使用しない水性エマルジョンとし
ては、例えば水性のアクリル系樹脂、アクリル／エチレ
ン酢酸ビニル共重合体（以下、ＥＶＡとする）混合系樹
脂、アクリル酸エステル−ＥＶＡ系樹脂等からなる水性
エマルジョンが使用可能である。In the present invention, as described above, an aqueous emulsion containing no plasticizer was selected as the resin used in the decorative layer. This is the mainstream PVC for conventional wallpaper
This is because, in the wallpaper using, the plasticizer such as phthalic acid-based DOP for giving flexibility to it moves to the heat-sensitive adhesive layer, plasticizes it, and peels at room temperature. Examples of the aqueous emulsion that does not use the plasticizer include aqueous acrylic resins, acrylic / ethylene vinyl acetate copolymer (hereinafter referred to as EVA) mixed resins, and acrylic acid ester-EVA resins. It can be used.
【０００９】さらに、前記化粧層となる水性エマルジョ
ンを塗布する際、裏打紙が水分を吸収して伸び等の不具
合、いわゆる波打ち現象を防ぐため、水性エマルジョン
中に水酸化アルミニウムなどの無機質粉体を分散するこ
とも好適に行われる。Further, when applying the aqueous emulsion to be the decorative layer, an inorganic powder such as aluminum hydroxide is added to the aqueous emulsion in order to prevent the backing paper from absorbing the moisture and causing a defect such as stretching, that is, a so-called waviness phenomenon. Dispersion is also suitably performed.
【００１０】基材１裏面に設けられる感熱型粘着剤層３
は、主に接着力を与える高分子材料、粘着付与剤、固体
可塑剤からなるものであり、常温では粘着性はないが加
熱によって粘着性が生じて、再び室温に戻すと３０分程
で粘着力は消える。故に、通常においてこの粘着剤の乾
燥塗膜には粘着性はなく、製造行程において問題はな
い。Thermosensitive adhesive layer 3 provided on the back surface of the substrate 1
Is mainly composed of a polymer material that gives an adhesive force, a tackifier, and a solid plasticizer. It does not have tackiness at room temperature, but when heated to room temperature, it becomes tacky and sticks in about 30 minutes. The power disappears. Therefore, the dry coating film of this pressure-sensitive adhesive is usually not tacky, and there is no problem in the production process.
【００１１】ここで接着力を与える高分子材料として
は、例えば、ポリ酢酸ビニル、コポリエチレン−酢酸ビ
ニル、ポリアクリル酸エステル系、ポリ塩化ビニル系、
天然ゴム、合成ゴム、ポリエステル系、ポリウレタン系
などの高分子化合物類を適宜選択し使用することができ
る。Examples of the polymer material which gives an adhesive force include polyvinyl acetate, copolyethylene-vinyl acetate, polyacrylic acid ester type, polyvinyl chloride type,
Polymer compounds such as natural rubber, synthetic rubber, polyester-based and polyurethane-based can be appropriately selected and used.
【００１２】粘着付与剤としては、加熱により活性化さ
れた際に粘着性を増強するための成分で、例えばロンジ
ン誘導体、テルペン樹脂系、石油樹脂系、フェノール樹
脂系、キシレン樹脂系などの樹脂類が使用可能である。The tackifier is a component for enhancing the tackiness when activated by heating, for example, resins such as longines derivatives, terpene resins, petroleum resins, phenol resins and xylene resins. Can be used.
【００１３】本発明における固体可塑剤とは、常温では
固体であって、その融点以上に加熱されると溶解し、前
記高分子材料や粘着付与剤を膨潤・溶解して、粘着性を
発現させ、溶解後、室温において３０分ほどで粘着性は
完全に消えるものである。例えば、フタル酸ジフェニ
ル、フタル酸ジヘキシル、フタル酸ジシクロヘキシル、
フタル酸ジヒドロアビエチル、安息香酸スクロース、ク
エン酸トリシクロヘキシル、Ｎ−シクロヘキシル−Ｐ−
トルエンスルホンアミドなどの常温で固体の有機化合物
が使用可能である。The solid plasticizer in the present invention is a solid at room temperature and dissolves when heated above its melting point to swell and dissolve the polymer material and the tackifier to develop tackiness. After the dissolution, the tackiness disappears completely in about 30 minutes at room temperature. For example, diphenyl phthalate, dihexyl phthalate, dicyclohexyl phthalate,
Dihydroabietyl phthalate, sucrose benzoate, tricyclohexyl citrate, N-cyclohexyl-P-
Organic compounds that are solid at room temperature such as toluene sulfonamide can be used.
【００１４】前記感熱型接着剤の各材料の配合比は、接
着力を与える高分子材料１００部に対して、粘着付与剤
０〜１００部、固体可塑剤５０〜１００部で感熱型粘着
剤を調製する。この組成物を化粧紙の裏面側に塗布、乾
燥させて感熱型粘着剤層３を形成する。感熱型粘着剤層
３の厚さは５〜３０μｍが好ましい。また、この感熱型
粘着剤の塗布方法は、グラビアコーティング、ナイフコ
ーティング、リップコーティング、ロールコーティング
など、公知のコーティング装置で塗布することができ
る。The mixing ratio of each material of the heat-sensitive adhesive is 0 to 100 parts of the tackifier and 50 to 100 parts of the solid plasticizer to 100 parts of the polymer material which gives the adhesive force. Prepare. This composition is applied to the back side of the decorative paper and dried to form the heat-sensitive adhesive layer 3. The thickness of the heat-sensitive adhesive layer 3 is preferably 5 to 30 μm. The heat-sensitive adhesive can be applied by a known coating device such as gravure coating, knife coating, lip coating and roll coating.
【００１５】この感熱型粘着剤層３を設けた壁紙等は、
貼り替えの際に壁紙表面からアイロンやジェットドライ
ヤー等の加熱器具を用いて壁紙全体を加熱することによ
り、感熱型粘着剤層の固体可塑剤を活性化させ、この粘
着剤層が接着剤として作用する。すなわち、接着剤とは
固形化した際には２つの物体を接着するが、完全に固形
化する以前、すなわち、液体系では２つの物を剥がすこ
とも可能である。よって裏打紙を破壊することなく壁面
から壁紙を綺麗に粘着剤層から剥がすことが可能とな
る。The wallpaper provided with the heat-sensitive adhesive layer 3 is
By heating the entire wallpaper from the surface of the wallpaper with a heating device such as an iron or a jet drier when replacing, the solid plasticizer of the heat-sensitive adhesive layer is activated, and this adhesive layer acts as an adhesive. To do. That is, the adhesive bonds two objects when solidified, but it is also possible to peel the two objects before completely solidified, that is, in a liquid system. Therefore, the wallpaper can be neatly peeled from the adhesive layer from the wall surface without destroying the backing paper.
【００１６】[0016]
【実施例】以下実施例により本発明を詳細に説明する。
基材として坪量１２０ｇ／ｍ2 の難燃性壁紙（特種製紙
（株）製：「ＴＴ−１２０ＴＷ」）を用い、これに下記
の配合の水性エマルジョンをコンマコーターをもちいて
塗布し、厚さ１２０ｇ／ｍ2 （ｄｒｙ）の層とした。The present invention will be described in detail with reference to the following examples.
A flame-retardant wallpaper having a basis weight of 120 g / m 2 (“TT-120TW” manufactured by Tokushu Paper Co., Ltd.) was used as a base material, and an aqueous emulsion having the following composition was applied to this using a comma coater to obtain a thickness. It was a layer of 120 g / m 2 (dry).
【００１７】 ＜水性エマルジョンの配合＞ ポリアクリル酸エステル １００重量部 水酸化アルミニウム粉体（日本軽金属（株）製「Ｂ−703 」）１００重量部 カプセル発泡剤（大塚化学（株）製：「ＡＺ−Ｈ」 １０重量部 酸化チタン（顔料） １５重量部 分散剤（花王（株）製：「ポイズ５２０」） 適量 増粘剤（東亞合成（株）製：「アロンＡ−２０Ｌ」） 適量<Composition of Aqueous Emulsion> 100 parts by weight of polyacrylic acid ester Aluminum hydroxide powder (“B-703” manufactured by Nippon Light Metal Co., Ltd.) 100 parts by weight Capsule foaming agent (manufactured by Otsuka Chemical Co., Ltd .: “AZ”) -H "10 parts by weight Titanium oxide (pigment) 15 parts by weight Dispersant (Kao Co., Ltd .:" Poise 520 ") Proper amount Thickener (Toagosei Co., Ltd .:" Aron A-20L ") Proper amount
【００１８】この層上に、印刷による絵柄層を設け、つ
いで加熱発泡による凹凸模様を形成し化粧層とした。そ
の後、基材の裏面側に下記配合の感熱型粘着剤を２０μ
ｍ塗布し乾燥させ、本発明の化粧紙を得た。On this layer, a pattern layer was formed by printing, and then a concavo-convex pattern was formed by heat foaming to form a decorative layer. After that, a heat-sensitive adhesive of the following composition is applied to the back side of the base material at 20 μm.
m and then dried to obtain the decorative paper of the present invention.
【００１９】 ＜感熱型粘着剤の配合＞ ＥＶＡ樹脂（接着性を有する高分子材料） １００重量部 ロジンエステル（粘着付与剤） １０重量部 フタル酸ジシクロヘキシル（固体可塑剤） １００重量部<Blending of heat-sensitive adhesive> EVA resin (polymer material having adhesiveness) 100 parts by weight Rosin ester (tackifier) 10 parts by weight Dicyclohexyl phthalate (solid plasticizer) 100 parts by weight
【００２０】その後、この化粧紙にアミノールと水を
１：１に調節したでんぷん糊を、塗布量１５０ｇ／ｍ2
（ｗｅｔ）に塗布し石膏ボードに貼り付けた。それを常
温および４０℃９０％ＲＨの条件で２カ月間保存した
後、工業用ドライヤーを用い、表面より加熱した。この
加熱により感熱型粘着剤が活性化され、その層間で剥が
れ、石膏ボード表面はきれいなままであった。またこれ
に従う粘着によるべとつきも３０分以内になくなり、次
の施工に支障はなかった。Then, a starch paste prepared by adjusting aminol and water in a ratio of 1: 1 was applied to the decorative paper in an amount of 150 g / m 2.
It was applied to (wet) and attached to a plaster board. After it was stored at room temperature and 40 ° C. and 90% RH for 2 months, it was heated from the surface using an industrial dryer. This heating activated the heat-sensitive adhesive, peeled it off between the layers, and the gypsum board surface remained clean. In addition, stickiness according to this disappeared within 30 minutes, and there was no problem in the next construction.
【００２１】[0021]
【発明の効果】本発明は以上の構成であるから、下記に
示す如き効果がある。一般的な壁紙は裏打紙の紙間で剥
離する為、綺麗に剥離する為には基材自体にピーラブル
性が要求された。しかし、本発明においては、剥離する
層が粘着剤層のため、基材のピーラブル性を必要としな
い。これにより、基材に安価な紙を使用することも可能
となり、印刷以外の他の機能、例えば消臭や電波シール
ドといった機能を有する原紙も使用することが可能とな
った。As described above, the present invention has the following effects. In general, wallpaper is peeled between the backing papers, and therefore the base material itself is required to have peelability in order to peel it off neatly. However, in the present invention, since the layer to be peeled off is the pressure-sensitive adhesive layer, the peelability of the substrate is not required. This makes it possible to use inexpensive paper as the base material, and it is also possible to use base paper having a function other than printing, for example, a function such as deodorization or radio wave shielding.
【００２２】また、裏打紙の紙間で剥離せず、剥離後も
粘着剤によるべとつきがないので、リフォーム等の貼り
替えの際に石膏ボード等の下地処理が簡単であり、比較
的大きな面積でも壁面から綺麗に剥離させることができ
ることから、化粧紙の再利用も有効に行なうことが可能
である。Further, since the backing paper is not peeled between the sheets and there is no stickiness after the peeling due to the adhesive, the ground treatment of the gypsum board or the like can be easily performed when the reforming or the like is replaced, and even in a relatively large area. Since it can be neatly peeled off from the wall surface, it is possible to effectively reuse the decorative paper.
【００２３】かつ、壁面構成基材の防火性能を低下させ
ず、樹脂層からの可塑剤の移行を防ぐために、水性エマ
ルジョンを使用して化粧紙を製造しているので、製造時
に溶剤による大気汚染、爆発、火災、中毒等の心配がな
い。従って機械を防爆仕様にする必要がなく、また溶剤
回収施設もいらない。また、施工、室内環境は、可塑
剤、有機難燃剤等が揮発して室内を汚染するものがな
く、施工者、居住者にたいして安全性が保証できる。さ
らに、廃材処理時には、樹脂層がＣ、Ｈ、Ｏから成り立
っており、焼却処分をしても塩素ガス等は発生しない。Moreover, in order to prevent migration of the plasticizer from the resin layer without deteriorating the fireproof performance of the wall-constituting substrate, the decorative paper is manufactured using an aqueous emulsion, and therefore air pollution caused by the solvent during manufacturing. , No danger of explosion, fire, poisoning, etc. Therefore, there is no need to make the machine explosion-proof and no solvent recovery facility is required. In addition, in the construction and indoor environment, plasticizers, organic flame retardants, etc. are not volatilized to pollute the interior of the room, and the safety can be guaranteed to the installers and residents. Further, when the waste material is treated, the resin layer is composed of C, H, and O, and chlorine gas or the like does not occur even if it is incinerated.
【図１】本発明の化粧紙の一例を示す断面で表した説明
図である。FIG. 1 is an explanatory view showing a cross section showing an example of a decorative paper of the present invention.
１…基材 ２…化粧層 ３…感熱型粘着剤層 1 ... Substrate 2 ... Decorative layer 3 ... Thermosensitive adhesive layer
Claims (2)
ルジョンからなる化粧層を設け、基材裏面に感熱型粘着
剤層を設けてなることを特徴とする化粧紙。1. A decorative paper comprising a base material surface provided with a cosmetic layer made of an aqueous emulsion without using a plasticizer, and a base material back surface provided with a heat-sensitive adhesive layer.
子材料と、粘着付与剤と、固体可塑剤とからなることを
特徴とする請求項１記載の化粧紙。2. The decorative paper according to claim 1, wherein the heat-sensitive adhesive comprises a polymeric material that gives an adhesive force, a tackifier, and a solid plasticizer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27386095A JP4001644B2 (en) | 1995-10-23 | 1995-10-23 | Decorative paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27386095A JP4001644B2 (en) | 1995-10-23 | 1995-10-23 | Decorative paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH09119098A true JPH09119098A (en) | 1997-05-06 |
| JP4001644B2 JP4001644B2 (en) | 2007-10-31 |
Family
ID=17533569
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP27386095A Expired - Fee Related JP4001644B2 (en) | 1995-10-23 | 1995-10-23 | Decorative paper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4001644B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005120484A (en) * | 2003-10-14 | 2005-05-12 | Toppan Printing Co Ltd | Easily applicable decorative sheet |
| JP2009122648A (en) * | 2007-10-26 | 2009-06-04 | Fuji Seal International Inc | Heat-sensitive label and container with label |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5364282A (en) * | 1976-11-20 | 1978-06-08 | Eidai Co Ltd | Production of decorative sheet for surface covering |
| JPH05261880A (en) * | 1992-03-19 | 1993-10-12 | Toppan Printing Co Ltd | Manufacture of decorative laminate material |
| JPH0647875A (en) * | 1992-02-25 | 1994-02-22 | Achilles Corp | Decorative sheet and production thereof |
| JPH0780979A (en) * | 1993-09-16 | 1995-03-28 | Toppan Printing Co Ltd | Decorative material |
| JPH07121108A (en) * | 1992-05-01 | 1995-05-12 | Osaka Sealing Insatsu Kk | Non-separation type label raw paper |
| JPH0852846A (en) * | 1994-06-09 | 1996-02-27 | Toppan Printing Co Ltd | Decorating method and decorative paper for plate material |
| JPH0957909A (en) * | 1995-08-24 | 1997-03-04 | Toppan Printing Co Ltd | Decorative sheet and its preparation |
-
1995
- 1995-10-23 JP JP27386095A patent/JP4001644B2/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5364282A (en) * | 1976-11-20 | 1978-06-08 | Eidai Co Ltd | Production of decorative sheet for surface covering |
| JPH0647875A (en) * | 1992-02-25 | 1994-02-22 | Achilles Corp | Decorative sheet and production thereof |
| JPH05261880A (en) * | 1992-03-19 | 1993-10-12 | Toppan Printing Co Ltd | Manufacture of decorative laminate material |
| JPH07121108A (en) * | 1992-05-01 | 1995-05-12 | Osaka Sealing Insatsu Kk | Non-separation type label raw paper |
| JPH0780979A (en) * | 1993-09-16 | 1995-03-28 | Toppan Printing Co Ltd | Decorative material |
| JPH0852846A (en) * | 1994-06-09 | 1996-02-27 | Toppan Printing Co Ltd | Decorating method and decorative paper for plate material |
| JPH0957909A (en) * | 1995-08-24 | 1997-03-04 | Toppan Printing Co Ltd | Decorative sheet and its preparation |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005120484A (en) * | 2003-10-14 | 2005-05-12 | Toppan Printing Co Ltd | Easily applicable decorative sheet |
| JP2009122648A (en) * | 2007-10-26 | 2009-06-04 | Fuji Seal International Inc | Heat-sensitive label and container with label |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4001644B2 (en) | 2007-10-31 |
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