JPH0548198B2 - - Google Patents
Info
- Publication number
- JPH0548198B2 JPH0548198B2 JP59086532A JP8653284A JPH0548198B2 JP H0548198 B2 JPH0548198 B2 JP H0548198B2 JP 59086532 A JP59086532 A JP 59086532A JP 8653284 A JP8653284 A JP 8653284A JP H0548198 B2 JPH0548198 B2 JP H0548198B2
- Authority
- JP
- Japan
- Prior art keywords
- general formulas
- group
- methyl
- coloring material
- polymer composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000642 polymer Polymers 0.000 claims description 26
- 239000000463 material Substances 0.000 claims description 18
- 239000000975 dye Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 17
- 239000000126 substance Substances 0.000 claims description 13
- 238000004040 coloring Methods 0.000 claims description 9
- 239000010419 fine particle Substances 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 8
- 230000001050 lubricating effect Effects 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 238000000859 sublimation Methods 0.000 claims description 5
- 230000008022 sublimation Effects 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 239000006229 carbon black Substances 0.000 claims description 4
- 239000003086 colorant Substances 0.000 claims description 4
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 claims description 4
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 229920002545 silicone oil Polymers 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 22
- 229920005989 resin Polymers 0.000 description 17
- 239000011347 resin Substances 0.000 description 17
- -1 2,2-dicyanovinyl Chemical group 0.000 description 13
- 239000000976 ink Substances 0.000 description 8
- 239000000377 silicon dioxide Substances 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 239000002904 solvent Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 238000001454 recorded image Methods 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- 229910002012 Aerosil® Inorganic materials 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000004642 Polyimide Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- 229920001721 polyimide Polymers 0.000 description 3
- 229920006324 polyoxymethylene Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 229920002799 BoPET Polymers 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 229930182556 Polyacetal Natural products 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 229920013820 alkyl cellulose Polymers 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- LRCFXGAMWKDGLA-UHFFFAOYSA-N dioxosilane;hydrate Chemical compound O.O=[Si]=O LRCFXGAMWKDGLA-UHFFFAOYSA-N 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 150000003949 imides Chemical class 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920002492 poly(sulfone) Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229960004029 silicic acid Drugs 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 229910002029 synthetic silica gel Inorganic materials 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 239000011882 ultra-fine particle Substances 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- OOAQCESADLTRLQ-UHFFFAOYSA-N 2-[4-(diethylamino)phenyl]ethene-1,1,2-tricarbonitrile Chemical compound CCN(CC)C1=CC=C(C(C#N)=C(C#N)C#N)C=C1 OOAQCESADLTRLQ-UHFFFAOYSA-N 0.000 description 1
- FKCWUWJFGXKLNW-UHFFFAOYSA-N 2-[4-(dimethylamino)-2-methylphenyl]ethene-1,1,2-tricarbonitrile Chemical compound CN(C)C1=CC=C(C(C#N)=C(C#N)C#N)C(C)=C1 FKCWUWJFGXKLNW-UHFFFAOYSA-N 0.000 description 1
- KPVQHJLNKIZNIH-UHFFFAOYSA-N 2-[4-(dimethylamino)phenyl]ethene-1,1,2-tricarbonitrile Chemical compound CN(C)C1=CC=C(C(C#N)=C(C#N)C#N)C=C1 KPVQHJLNKIZNIH-UHFFFAOYSA-N 0.000 description 1
- GIXUEKGLQBMKGE-UHFFFAOYSA-N 2-[4-[ethyl(methyl)amino]-2-methylphenyl]ethene-1,1,2-tricarbonitrile Chemical compound CCN(C)C1=CC=C(C(C#N)=C(C#N)C#N)C(C)=C1 GIXUEKGLQBMKGE-UHFFFAOYSA-N 0.000 description 1
- MTNBMBHSBJKQQA-UHFFFAOYSA-N 2-[[4-(diethylamino)-2-methylphenyl]methylidene]propanedinitrile Chemical compound CCN(CC)C1=CC=C(C=C(C#N)C#N)C(C)=C1 MTNBMBHSBJKQQA-UHFFFAOYSA-N 0.000 description 1
- NESSTUFHMYIRKI-UHFFFAOYSA-N 2-[[4-(diethylamino)phenyl]methylidene]propanedinitrile Chemical compound CCN(CC)C1=CC=C(C=C(C#N)C#N)C=C1 NESSTUFHMYIRKI-UHFFFAOYSA-N 0.000 description 1
- WPJHTIRBHRFQKU-UHFFFAOYSA-N 2-[[4-(dimethylamino)-2-methylphenyl]methylidene]propanedinitrile Chemical compound CN(C)C1=CC=C(C=C(C#N)C#N)C(C)=C1 WPJHTIRBHRFQKU-UHFFFAOYSA-N 0.000 description 1
- IYNONQVNLZATDK-UHFFFAOYSA-N 2-[[4-(dimethylamino)phenyl]methylidene]propanedinitrile Chemical compound CN(C)C1=CC=C(C=C(C#N)C#N)C=C1 IYNONQVNLZATDK-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- JMMZCWZIJXAGKW-UHFFFAOYSA-N 2-methylpent-2-ene Chemical compound CCC=C(C)C JMMZCWZIJXAGKW-UHFFFAOYSA-N 0.000 description 1
- VJDYNCYNNXYJGU-UHFFFAOYSA-N 4,8-bis(ethylamino)naphthalene-1,5-dione Chemical compound O=C1C=CC(NCC)=C2C(=O)C=CC(NCC)=C21 VJDYNCYNNXYJGU-UHFFFAOYSA-N 0.000 description 1
- MGKZFFUHEGPTDR-UHFFFAOYSA-N 4,8-bis(methylamino)naphthalene-1,5-dione Chemical compound O=C1C=CC(NC)=C2C(=O)C=CC(NC)=C21 MGKZFFUHEGPTDR-UHFFFAOYSA-N 0.000 description 1
- BHIOPVBOXIVMKV-UHFFFAOYSA-N 4-(ethylamino)-8-(methylamino)naphthalene-1,5-dione Chemical compound O=C1C=CC(NC)=C2C(=O)C=CC(NCC)=C21 BHIOPVBOXIVMKV-UHFFFAOYSA-N 0.000 description 1
- OECTYKWYRCHAKR-UHFFFAOYSA-N 4-vinylcyclohexene dioxide Chemical compound C1OC1C1CC2OC2CC1 OECTYKWYRCHAKR-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000004697 Polyetherimide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 229940081735 acetylcellulose Drugs 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000011353 cycloaliphatic epoxy resin Substances 0.000 description 1
- NZNMSOFKMUBTKW-UHFFFAOYSA-M cyclohexanecarboxylate Chemical compound [O-]C(=O)C1CCCCC1 NZNMSOFKMUBTKW-UHFFFAOYSA-M 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000012954 diazonium Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- HDNHWROHHSBKJG-UHFFFAOYSA-N formaldehyde;furan-2-ylmethanol Chemical compound O=C.OCC1=CC=CO1 HDNHWROHHSBKJG-UHFFFAOYSA-N 0.000 description 1
- 239000007849 furan resin Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910001512 metal fluoride Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- MUTNCGKQJGXKEM-UHFFFAOYSA-N tamibarotene Chemical compound C=1C=C2C(C)(C)CCC(C)(C)C2=CC=1NC(=O)C1=CC=C(C(O)=O)C=C1 MUTNCGKQJGXKEM-UHFFFAOYSA-N 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 238000010023 transfer printing Methods 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/426—Intermediate, backcoat, or covering layers characterised by inorganic compounds, e.g. metals, metal salts, metal complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Description
産業上の利用分野
本発明は、熱転写による記録に用いられる感熱
記録用転写体に関し、とくにサーマルヘツドやレ
ーザービームなどの電子デバイスによる高速記録
に利用される。
従来例の構成とその問題点
従来この記録方法には、安定性に優れるポリエ
ステル繊維の転写捺染用染料を含有する転写体が
使用されていたが、かかる転写体は染料の昇華性
が低いため着色力が劣り、通常のサーマルヘツド
の熱エネルギーでは充分な色濃度を得ることは困
難であつた。
又、昇華性の高いカラーフオーマーを含むイオ
ン系染料は充分な色濃度を得ることはできるが、
保存安定性に問題があつた。
又、均質な画像を得るために用いる安価で均質
なフイルムからなる転写基体は、特に記録手段と
してサーマルヘツドを用いた場合、ヘツドの融着
防止のために基体に樹脂層を設けることが提案さ
れているが、上記樹脂層ではヘツドの発熱体付近
に数μmの微小な凹凸があるため、樹脂層の高分
子あるいは添加剤が削られてきて発熱体上にたま
り画像に白線を発生する記録ねけ(ドロツプアウ
ト)が生じる大きな欠点があつた。
発明の目的
本発明は、安定で昇華能力に優れている色素を
用いて十分な色濃度を得ると共に、画像に白線の
ない均一な記録画像を与える感熱記録用転写体を
得ることを目的とする。
発明の構成
本発明の転写体は、基体の一方の面に下器一般
式(),(),()で表わされる昇華性染料の
うち少なくとも1種類を含む色材層が設けられ、
他方の面にフツ化カーボン、カーボンブラツク、
黒鉛からなる群より選ばれる微粒子とシリコーン
オイルからなる液状潤滑性物質と高分子物質とか
らなる高分子組成物層が設けられ、かつ前記微粒
子により前記高分子組成物層の表面が粗面化され
ていることを特徴とする。
(式中、Xは水素原子またはメチル基を、R及
びR′はそれぞれメチル基、エチル基、直鎖状も
しくは分岐鎖状のプロピル基又はブチル基を表わ
す)
以上のような構成にすることにより、前記化学構
造の染料を含む色材層は保存安定性に優れ、充分
な色濃度と色相の優れた記録画像を与え、又、高
分子組成物層は画像に白線のない均一な画像の形
成に寄与する。
実施例の説明
以下、本発明の実施例について説明する。
本発明の実施例である転写体の概略断面図を図
に示す。基体1の上面に色材層2があり、下面に
高分子組成物層3がある。
前記一般式(),(),()で表わされる昇
華性染料の具体例としては、以下のものがあげら
れる。
()で表わされるシアン色を呈するもの
1,5−ビス(メチルアミノ)−4,8−ナフ
トキノン、1,5−ビス(エチルアミノ)−4,
8−ナフトキノン、1,5−ビス((n)−プロピル
アミノ)−4,8−ナフトキノン、1,5−ビス
((iso)−プロピルアミノ)−4,8−ナフトキノ
ン、1,5−ビス((n)−プチルアミノ)−4,8
−ナフトキノン、1,5−ビス((iso)−ブチル
アミノ)−4,8−ナフトキノン、1−メチルア
ミノ−5−エチルアミノ−4,8−ナフトキノ
ン、1−メチルアミノ−5−(n)−プロピルアミノ
−4,8−ナフトキノン、1−メチルアミノ−5
−(n)−ブチルアミノ−4,8−ナフトキノン、1
−メチルアミノ−5−(iso)−プロピルアミノ−
4,8−ナフトキノン、エチルアミノ−5−(n)−
プロピルアミノ−4,8−ナフトキノン、1−エ
チルアミノ−5−(n)−ブチルアミノ−4、8−ナ
フトキノン、1−(n)−プロピルアミノ−5−(n)−
ブチルアミノ−4,8−ナフトキノン。
()で表わされるイエロー色を呈するもの
4−(2,2−ジシアノビニル)−N,N−ジメ
チルアニリン、4−(2,2−ジシアノビニル)−
N,N−ジエチルアニリン、4−(2,2−ジシ
アノビニル)−N,N−ジ(n)−プロピルアニリン、
4−(2,2−ジシアノビニル)−N,N−ジ
{iso)−プロピルアニリン、4−(2,2−ジシア
ノビニル)−N,N−ジ(n)−ブチルアニリン、4
−(2,2−ジシアノビニル)−N,N−ジ{iso)
−ブチルアニリン、4−(2,2−ジシアノビニ
ル)−N,N−ジ(sec)−ブチルアニリン、3−
メチル−4−(2,2−ジシアノビニル)−N,N
−ジメチルアニリン、3−メチル−4−(2,2
−ジシアノビニル)−N,N−ジエチルアニリン、
3−メチル−4−(2,2−ジシアノビニル)−
N,N−ジ(n)−プロピルアニリン、3−メチル−
4−(2,2−ジシアノビニル)−N,N−ジ
{iso)−プロピルアニリン、3−メチル−4−
(2,2−ジシアノビニル)−N,N−ジ(n)−ブチ
ルアニリン、3−メチル−4−(2,2−ジシア
ノビニル)−N,N−ジ(iso)−ブチルアニリン、
3−メチル−4−(2,2−ジシアノビニル)−
N,N−ジ(sec)−ブチルアニリン、4−(2,
2−ジシアノビニル)−N−エチル−N−(n)−プ
ロピルアニリン、4−(2,2−ジシアノビニル)
−N−エチル−N−(n)−ブチルアニリン、4−
(2,2−ジシアノビニル)−N−メチル−N−(n)
−プロピルアニリン、4−(2,2−ジシアノビ
ニル)−N−メチル−N−(n)−ブチルアニリン、
3−メチル−4−(2,2−ジシアノビニル)−N
−メチル−N−(n)−プロピルアニリン、3−メチ
ル−4−(2,2−ジシアノビニル)−N−メチル
−N−(n)−ブチルアニリン、3−メチル−4−
(2,2−ジシアノビニル)−N−エチル−N−(n)
−プロピルアニリン、3−メチル−4−(2,2
−ジシアノビニル)−N−エチル−N−(n)−ブチ
ルアニリン、
()で表わされるマゼンタ色を呈するもの
4−トリシアノビニル−N,N−ジメチルアニ
リン、4−トリシアノビニル−N,N−ジエチル
アニリン、4−トリシアノビニル−N,N−ジ(n)
−プロピルアニリン、4−トリシアノビニル−
N,N−ジ(iso)−プロピルアニリン、4−トリ
シアノビニル−N,N−ジ(n)−ブチルアニリン、
4−トリシアノビニル−N,N−ジ(iso)−ブチ
ルアニリン、4−トリシアノビニル−N,N−ジ
(sec)−ブチルアニリン、3−メチル−4−トリ
シアノビニル−N,N−ジメチルアニリン、4−
トリシアノビニル−N−メチル−N−(n)−プロピ
ルアニリン、4−トリシアノビニル−N−メチル
−N−(n)−ブチルアニリン、4−トリシアノビニ
ル−N−エチル−N−(n)−プロピルアニリン、4
−トリシアノビニル−N−エチル−N−(n)−ブチ
ルアニリン、4−トリシアノビニル−N−エチル
−N−(iso)−ブチルアニリン、4−トリシアノ
ビニル−N−エチル−N−(sec)−ブチルアニリ
ン、4−トリシアノビニル−N−(n)−プロピル−
N−(n)−ブチルアニリン、3−メチル−4−トリ
シアノビニル−N−メチル−N−エチルアニリ
ン、
色材層を構成するためのインキは、前記一般式
()又は()又は()で表わされる色素を
融点又は軟化点の高い樹脂と溶剤又は水等の溶媒
と混合してつくることができる。又、色材層に非
昇華性粒子、界面活性剤等を添加して用いること
もできる。
上記のインキを調製するための樹脂としては、
通常の印刷インキに使用されるもので良く、ロジ
ン系、フエノール系、キシレン系、石油系、ビニ
ル系、ポリイミド系、アルキツド系、ニトロセル
ロース系、アルキルセルロース、アルキルセルロ
ース類、エーテル系、エステル系などの油性系の
樹脂あるいはマレイン酸系、アクリル酸系、カゼ
イン、シエラツク、ニカワ等の水性系樹脂が使用
できるがより具体的には融点又は軟化点の高いポ
リカーボネート、ポリサルフオン、ポリフエニレ
ンオキサイド、ポリアリレート、セルロース誘導
体等が特に有効である。
又、インキ調製のための溶剤としては、メタノ
ール、エタノール、プロパノール、ブタノールな
どのアルコール類、メチルセロソルブ、エチルセ
ロソルブなどのセロソルブ類、ベンゼン、トルエ
ン、キシレンなどの芳香族、酢酸ブチルなどのエ
ステル類、アセトン、メチルエチルケトン、シク
ロヘキサノンなどのケトン類、リグロイン、シク
ロヘキサン、ケロシンなどの炭化水素類、ジメチ
ルホルムアミド、塩化メチレン、クロロベンゼ
ン、クロロホルム等のハロゲン化炭化水素などが
使用できるが、水性系樹脂を使用の場合には水ま
たは水と上記の溶剤類を混合し使用することもで
きる。
高分子組成物層3に含まれる微粒子の材質は、
特に限定されるものでなく、金属、無機系、有機
系の各種粒子を用いることができる。例えば、金
属酸化物、金属硫化物、金属炭化物、金属窒化
物、金属フツ化物、黒鉛、フツ化カーボン、カー
ボンブラツク、鉱物、無機塩、有機塩、有機顔
料、四フツ化エチレン、ポリイミド等の高分子等
がある。
特に合成非晶質シリカ、カーボンブラツク、ア
ルミナ、酸化チタン、二硫化モリブデン、窒化ホ
ウ素、フツ化カーボン、珪酸カルシウム、珪酸ア
ルミニウム等が有力である。合成非晶質シリカに
は無水シリカ及び含水シリカがある。無水シリカ
としては気相法で作製された超微粒子が有用であ
る。例えば、***デグサ社で開発された高純度の
超微粒子状シリカ(商品名:アエロジル、日本ア
エロジル株式会社)、同様に気相法で作製された
酸化アルミニウム、酸化チタン(いずれも、日本
アエロジル株式会社)等がある。
含水シリカあるいはホワイトカーボンとして、
例えば、塩野義製薬株式会社「カープレツクス」
日本シリカ工業株式会社「ニツプシール」、水澤
化学工業株式会社「シルトン」、徳山曹達株式会
社「フアインシール、トクシール」等が市販され
ている。
シリカは使用する染料の特性によつては染料と
反応する場合もあるため、シリカに存在するシラ
ノール基を化学的にメチル基あるいは有機珪素化
合物等で一部置換結合させた疎水性シリカを用い
ることが好ましい。
微粒子の高分子物質に対する添加比率は0.1〜
200重量%の範囲で用いることができる。特に、
添加比率が5〜100重量%の範囲で安定した特性
を示す。超微粒子は、超音波、三本ロール、ホモ
ジナイザー等によりよく分散される。
微粒子の大きさは、その粒径が小さい程画質へ
の影響が少なく、特に平均粒径が6μm以下の場
合にドロツプアウトがほとんど生じなくなるので
望ましい。
微粒子は高分子組成物層の内部に含有されると
ともに表面にも露出するよう用いられる。
高分子組成物層は、その含有成分が微粒子のみ
ではステイツクを起こして安定に走行しないた
め、種々の滑剤、界面活性剤、潤滑性物質等の摩
擦抵抗を低下させる液状潤滑性物質を含んでい
る。液状潤滑性物質は、25℃、1気圧で液体の潤
滑性物質である。
高分子物質はその材質を特に限定されるもので
なく、例えば、各種熱可塑性樹脂、熱、光、電子
線等による各種硬化性樹脂の硬化樹脂である。特
に各種硬化性樹脂が基体との接着性および耐熱性
が良好である。
例えば、シリコーン樹脂、エポキシ樹脂、不飽
和アルデヒド樹脂、ユリア樹脂、不飽和ポリエス
テル樹脂、アルキド樹脂、フラン樹脂、オリゴア
クリレート等がある。
中でもオリゴアクリレートの硬化樹脂が優れた
特性を示す。又、光、電子線による硬化樹脂が短
時間で容易に硬化し、又、基材裏面への未反応樹
脂、硬化剤等の転移がほとんどないため長尺の転
写体を作製しやすく、又、良好な特性を示す。例
えば、オリゴアクリレートの光、あるいは電子線
硬化樹脂、あるいは芳香族ジアゾニウム塩、ある
いは芳香族ヨードニウム塩、あるいは芳香族スル
ホニウム塩触媒によるエポキシ樹脂の光硬化樹脂
が優れている。
オリゴアクリレートとして、例えば、ポリオー
ルアクリレート、ポリエステルアクリレート、エ
ポキシアクリレート、ウレタンアクリレート、シ
リコーンアクリレート、ポリアセタールのアクリ
レート等、
エポキシ樹脂として、例えば、ビニルシクロヘ
キセンジオキシド、3,4−エポキシシクロヘキ
シルメチル−3,4−エポキシシクロヘキサンカ
ルボキシレイト等の環状脂肪族エポキシ樹脂があ
る。
又、テトラヒドロフルフリルアクリレート、ラ
ウリルアクリレート等の反応性希釈剤を樹脂に添
加して用いることもできる。
高分子組成物の膜厚は特に限定されるものでな
い。一般に製造面から0.1μm以上の膜厚を有する
高分子組成物が得やすく均一な特性を示す。
本発明に用いる基体は特に限定するものではな
いが高分子フイルムであれば特に有用である。例
えば、ポリエチレンテレフタレート、ポリエチレ
ンナフタレート、ポリカーボネート等のエステル
系高分子、ナイロン等のアミド系高分子、アセチ
ルセルロース、セロハン等のセルロース誘導体、
ポリフツ化ビニリデン、4フツ化エチレン−6フ
ツ化プロピレン共重合体、テフロン等のフツ素系
高分子、ポリオキシメチレン、ポリアセタール等
のエーテル系高分子、ポリスチレン、ポリエチレ
ン、ポリプロピレン、メチルペンテンポリマー等
のオレフイン系高分子、ポリイミド、ポリアミド
イミド、ポリエーテルイミド等のイミド系高分子
等を用いることができる。
特に、ポリエステル系高分子は薄く、ある程度
の耐熱性もあり、安価であるので有用である。
又、ポリエステル系高分子より耐熱性のあるイミ
ド系、アミド系等の高分子は、転写体を繰り返し
使用する場合、高速で使用する場合に耐熱的に優
れているので基体として有用である。
更に具体的な実施例を説明する。
実施例 1
基体に厚さ9μmPETフイルムを用いる。この
フイルムの一方の面に表1に示した組成からなる
塗工液No.1をワイヤーバーで塗工し、60℃の熱風
で溶媒を蒸発させた後、1KWの高圧水銀灯を照
射して硬化させた。塗工液No.2〜No.4も同様にし
て、片面に硬化した高分子組成物層を有する
PETフイルムをそれぞれ作製した。
次に、下記構造式(1)で表わされる昇華性染料5
体積部、ポリカーボネート5体積部、ジクロロメ
タン100体積部とシリカ粒子(平均粒径5μm)10
体積部からなる分散液をボールミル撹拌した後、
上記フイルムの他方の面にそれぞれワイヤーバで
塗工して4種類の転写体を得た。
これらを用いてサーマルヘツドでポリエステル
と無機物を含む層が塗工されている記録紙(A−
5版)、10枚に画像を描かせた。記録条件は次の
とおりである。
主走査、副走査の線密度:4ドツト/mm
記録電力:0.7W/ドツト
ヘツドの加熱時間;7ms
試験結果は表1に示されるとおり、本発明に係
る添加剤No.1,2を用いた場合は、記録紙を10枚
記録しても画像に白線を生じるドロツプアウトラ
インの発生は皆無であつた。一方、比較例No.3は
1枚目の記録紙上に2本の白線を発生し、No.4は
11枚目の記録においてヘツドに融着して転写体が
切断したためドロツプアウトの評価は不可能であ
つた。
実験No.1,2で得られた記録画像の色濃度は
1.6の高い濃度が得られた。
INDUSTRIAL APPLICATION FIELD The present invention relates to a heat-sensitive recording transfer member used for recording by thermal transfer, and is particularly used for high-speed recording using electronic devices such as thermal heads and laser beams. Conventional structure and problems Conventionally, this recording method used a transfer body containing a highly stable dye for transfer printing of polyester fibers. It was difficult to obtain sufficient color density using the thermal energy of a normal thermal head. In addition, although ionic dyes containing color formers with high sublimability can provide sufficient color density,
There was a problem with storage stability. Furthermore, it has been proposed that a transfer substrate made of an inexpensive, homogeneous film used to obtain a uniform image should be provided with a resin layer to prevent the head from fusing, especially when a thermal head is used as a recording means. However, since the above resin layer has minute irregularities of several micrometers near the heating element of the head, the polymer or additives in the resin layer are scraped away and accumulate on the heating element, causing white lines on the image. A major drawback was that dropouts occurred. Purpose of the Invention The purpose of the present invention is to obtain a heat-sensitive recording transfer member that uses a dye that is stable and has excellent sublimation ability to obtain sufficient color density, and also provides a uniform recorded image without white lines. . Structure of the Invention The transfer body of the present invention is provided with a coloring material layer containing at least one type of sublimable dye represented by the general formula (), (), () on one side of the base,
Carbon fluoride, carbon black on the other side,
A polymer composition layer is provided which is made of fine particles selected from the group consisting of graphite, a liquid lubricating substance made of silicone oil, and a polymer substance, and the surface of the polymer composition layer is roughened by the fine particles. It is characterized by (In the formula, X represents a hydrogen atom or a methyl group, and R and R' represent a methyl group, an ethyl group, a linear or branched propyl group, or a butyl group, respectively.) By having the above structure, , the color material layer containing the dye having the chemical structure described above has excellent storage stability and provides a recorded image with sufficient color density and excellent hue, and the polymer composition layer forms a uniform image without white lines. Contribute to Description of Examples Examples of the present invention will be described below. The figure shows a schematic cross-sectional view of a transfer body that is an example of the present invention. A coloring material layer 2 is provided on the upper surface of the substrate 1, and a polymer composition layer 3 is provided on the lower surface. Specific examples of the sublimable dyes represented by the general formulas (), (), and () include the following. Those exhibiting a cyan color represented by () 1,5-bis(methylamino)-4,8-naphthoquinone, 1,5-bis(ethylamino)-4,
8-naphthoquinone, 1,5-bis((n)-propylamino)-4,8-naphthoquinone, 1,5-bis((iso)-propylamino)-4,8-naphthoquinone, 1,5-bis( (n)-butylamino)-4,8
-naphthoquinone, 1,5-bis((iso)-butylamino)-4,8-naphthoquinone, 1-methylamino-5-ethylamino-4,8-naphthoquinone, 1-methylamino-5-(n)- Propylamino-4,8-naphthoquinone, 1-methylamino-5
-(n)-butylamino-4,8-naphthoquinone, 1
-Methylamino-5-(iso)-propylamino-
4,8-naphthoquinone, ethylamino-5-(n)-
Propylamino-4,8-naphthoquinone, 1-ethylamino-5-(n)-butylamino-4,8-naphthoquinone, 1-(n)-propylamino-5-(n)-
Butylamino-4,8-naphthoquinone. Yellow color represented by () 4-(2,2-dicyanovinyl)-N,N-dimethylaniline, 4-(2,2-dicyanovinyl)-
N,N-diethylaniline, 4-(2,2-dicyanovinyl)-N,N-di(n)-propylaniline,
4-(2,2-dicyanovinyl)-N,N-di{iso)-propylaniline, 4-(2,2-dicyanovinyl)-N,N-di(n)-butylaniline, 4
-(2,2-dicyanovinyl)-N,N-di{iso)
-butylaniline, 4-(2,2-dicyanovinyl)-N,N-di(sec)-butylaniline, 3-
Methyl-4-(2,2-dicyanovinyl)-N,N
-dimethylaniline, 3-methyl-4-(2,2
-dicyanovinyl)-N,N-diethylaniline,
3-Methyl-4-(2,2-dicyanovinyl)-
N,N-di(n)-propylaniline, 3-methyl-
4-(2,2-dicyanovinyl)-N,N-di{iso)-propylaniline, 3-methyl-4-
(2,2-dicyanovinyl)-N,N-di(n)-butylaniline, 3-methyl-4-(2,2-dicyanovinyl)-N,N-di(iso)-butylaniline,
3-Methyl-4-(2,2-dicyanovinyl)-
N,N-di(sec)-butylaniline, 4-(2,
2-dicyanovinyl)-N-ethyl-N-(n)-propylaniline, 4-(2,2-dicyanovinyl)
-N-ethyl-N-(n)-butylaniline, 4-
(2,2-dicyanovinyl)-N-methyl-N-(n)
-propylaniline, 4-(2,2-dicyanovinyl)-N-methyl-N-(n)-butylaniline,
3-Methyl-4-(2,2-dicyanovinyl)-N
-Methyl-N-(n)-propylaniline, 3-methyl-4-(2,2-dicyanovinyl)-N-methyl-N-(n)-butylaniline, 3-methyl-4-
(2,2-dicyanovinyl)-N-ethyl-N-(n)
-propylaniline, 3-methyl-4-(2,2
-dicyanovinyl)-N-ethyl-N-(n)-butylaniline, which exhibits a magenta color represented by () 4-tricyanovinyl-N,N-dimethylaniline, 4-tricyanovinyl-N,N -diethylaniline, 4-tricyanovinyl-N,N-di(n)
-Propylaniline, 4-tricyanovinyl-
N,N-di(iso)-propylaniline, 4-tricyanovinyl-N,N-di(n)-butylaniline,
4-tricyanovinyl-N,N-di(iso)-butylaniline, 4-tricyanovinyl-N,N-di(sec)-butylaniline, 3-methyl-4-tricyanovinyl-N,N- dimethylaniline, 4-
Tricyanovinyl-N-methyl-N-(n)-propylaniline, 4-tricyanovinyl-N-methyl-N-(n)-butylaniline, 4-tricyanovinyl-N-ethyl-N-(n )-propylaniline, 4
-tricyanovinyl-N-ethyl-N-(n)-butylaniline, 4-tricyanovinyl-N-ethyl-N-(iso)-butylaniline, 4-tricyanovinyl-N-ethyl-N-( sec)-butylaniline, 4-tricyanovinyl-N-(n)-propyl-
N-(n)-butylaniline, 3-methyl-4-tricyanovinyl-N-methyl-N-ethylaniline, The ink for forming the coloring material layer has the above general formula () or () or () It can be prepared by mixing the dye represented by the formula with a resin having a high melting point or softening point and a solvent such as a solvent or water. Further, non-sublimable particles, surfactants, etc. can also be added to the coloring material layer. As the resin for preparing the above ink,
Any ink used in normal printing inks may be used, such as rosin, phenol, xylene, petroleum, vinyl, polyimide, alkyd, nitrocellulose, alkylcellulose, alkylcelluloses, ether, ester, etc. Oil-based resins or aqueous resins such as maleic acid-based, acrylic acid-based, casein, silica, glue, etc. can be used, but more specifically, polycarbonate, polysulfone, polyphenylene oxide, polyarylate, which have a high melting point or softening point. , cellulose derivatives, etc. are particularly effective. In addition, as solvents for ink preparation, alcohols such as methanol, ethanol, propanol, and butanol, cellosolves such as methyl cellosolve and ethyl cellosolve, aromatic solvents such as benzene, toluene, and xylene, esters such as butyl acetate, Ketones such as acetone, methyl ethyl ketone, and cyclohexanone, hydrocarbons such as ligroin, cyclohexane, and kerosene, and halogenated hydrocarbons such as dimethylformamide, methylene chloride, chlorobenzene, and chloroform can be used, but when using water-based resins, It is also possible to use water or a mixture of water and the above-mentioned solvents. The material of the fine particles contained in the polymer composition layer 3 is as follows:
There are no particular limitations, and various metal, inorganic, and organic particles can be used. For example, metal oxides, metal sulfides, metal carbides, metal nitrides, metal fluorides, graphite, carbon fluoride, carbon black, minerals, inorganic salts, organic salts, organic pigments, tetrafluoroethylene, polyimide, etc. There are molecules, etc. In particular, synthetic amorphous silica, carbon black, alumina, titanium oxide, molybdenum disulfide, boron nitride, carbon fluoride, calcium silicate, aluminum silicate, etc. are effective. Synthetic amorphous silica includes anhydrous silica and hydrated silica. As the anhydrous silica, ultrafine particles produced by a gas phase method are useful. For example, high-purity ultrafine particulate silica (product name: Aerosil, Nippon Aerosil Co., Ltd.) developed by West German Degussa, aluminum oxide and titanium oxide (both produced by Nippon Aerosil Co., Ltd.) similarly produced by a gas phase method. ) etc. As hydrated silica or white carbon,
For example, Shionogi & Co., Ltd. “Carplex”
Nippon Silica Kogyo Co., Ltd.'s ``Nipseal'', Mizusawa Chemical Industry Co., Ltd.'s ``Silton'', Tokuyama Soda Co., Ltd.'s ``Fuin Seal, Tokuseal'', etc. are commercially available. Since silica may react with dyes depending on the characteristics of the dye used, it is recommended to use hydrophobic silica in which the silanol groups present in silica are partially substituted and bonded with methyl groups or organic silicon compounds. is preferred. Addition ratio of fine particles to polymeric substance is 0.1~
It can be used in a range of 200% by weight. especially,
It shows stable characteristics when the addition ratio is in the range of 5 to 100% by weight. Ultrafine particles are well dispersed by ultrasonic waves, triple rolls, homogenizers, and the like. Regarding the size of the fine particles, it is preferable that the smaller the particle size, the less the influence on the image quality, and especially when the average particle size is 6 μm or less, dropout hardly occurs. The fine particles are contained inside the polymer composition layer and are also exposed on the surface. The polymer composition layer contains liquid lubricating substances such as various lubricants, surfactants, and lubricating substances that reduce frictional resistance, because if the polymer composition layer contains only fine particles, it will cause stagnation and will not run stably. . The liquid lubricating substance is a lubricating substance that is liquid at 25°C and 1 atmosphere. The material of the polymeric substance is not particularly limited, and examples thereof include various thermoplastic resins and various resins cured by heat, light, electron beams, etc. In particular, various curable resins have good adhesion to the substrate and good heat resistance. Examples include silicone resins, epoxy resins, unsaturated aldehyde resins, urea resins, unsaturated polyester resins, alkyd resins, furan resins, oligoacrylates, and the like. Among these, oligoacrylate cured resins exhibit excellent properties. In addition, the resin cured by light or electron beams is easily cured in a short time, and there is almost no transfer of unreacted resin, curing agent, etc. to the back surface of the base material, making it easy to produce long transfer bodies. Shows good properties. For example, light- or electron beam-curable resins of oligoacrylates, or photo-curable resins of epoxy resins catalyzed by aromatic diazonium salts, aromatic iodonium salts, or aromatic sulfonium salts are excellent. Examples of oligoacrylates include polyol acrylate, polyester acrylate, epoxy acrylate, urethane acrylate, silicone acrylate, polyacetal acrylate, etc. Epoxy resins include vinylcyclohexene dioxide, 3,4-epoxycyclohexylmethyl-3,4-epoxy There are cycloaliphatic epoxy resins such as cyclohexane carboxylate. Additionally, a reactive diluent such as tetrahydrofurfuryl acrylate or lauryl acrylate may be added to the resin. The film thickness of the polymer composition is not particularly limited. Generally, from a production standpoint, a polymer composition having a film thickness of 0.1 μm or more is easily obtained and exhibits uniform characteristics. The substrate used in the present invention is not particularly limited, but a polymer film is particularly useful. For example, ester polymers such as polyethylene terephthalate, polyethylene naphthalate, and polycarbonate, amide polymers such as nylon, cellulose derivatives such as acetyl cellulose and cellophane,
Polyvinylidene fluoride, tetrafluoroethylene-hexafluoropropylene copolymer, fluorine polymers such as Teflon, ether polymers such as polyoxymethylene and polyacetal, olefins such as polystyrene, polyethylene, polypropylene, methylpentene polymers, etc. Imide-based polymers such as polyimide, polyamideimide, polyetherimide, etc. can be used. In particular, polyester polymers are useful because they are thin, have a certain degree of heat resistance, and are inexpensive.
Furthermore, imide-based and amide-based polymers, which are more heat resistant than polyester polymers, are useful as substrates because they have excellent heat resistance when the transfer body is used repeatedly or at high speeds. A more specific example will be described. Example 1 A PET film with a thickness of 9 μm is used as the substrate. Coating liquid No. 1 having the composition shown in Table 1 was applied to one side of the film using a wire bar, and after evaporating the solvent with hot air at 60℃, it was cured by irradiating it with a 1KW high-pressure mercury lamp. I let it happen. Coating liquids No. 2 to No. 4 similarly had a cured polymer composition layer on one side.
PET films were produced respectively. Next, sublimable dye 5 represented by the following structural formula (1)
Parts by volume, 5 parts by volume of polycarbonate, 100 parts by volume of dichloromethane, and 10 parts by volume of silica particles (average particle size 5 μm)
After stirring the dispersion consisting of parts by volume in a ball mill,
The other side of the above film was coated with a wire bar to obtain four types of transfer bodies. Using these materials, a recording paper (A-
5th edition), I had them draw images on 10 sheets. The recording conditions were as follows. Linear density in main scanning and sub-scanning: 4 dots/mm Recording power: 0.7 W/dot Head heating time: 7 ms The test results are shown in Table 1, using additives No. 1 and 2 according to the present invention. In this case, there was no drop outline, which causes white lines on the image, even after recording on 10 sheets of recording paper. On the other hand, Comparative Example No. 3 generated two white lines on the first recording paper, and No. 4 generated two white lines on the first sheet of recording paper.
In the 11th recording, it was impossible to evaluate dropout because the transfer body was fused to the head and cut. The color density of the recorded images obtained in Experiment No. 1 and 2 is
A high concentration of 1.6 was obtained.
【表】【table】
【表】
実施例 2
下記の第(1),(2),(3)式の構造式で表わされるシ
アン色、イエロー色、マゼンタ色の昇華性染料の
それぞれについて、染料5体積部、ポリスルフオ
ン5体積部、モノクロルベンゼン100体積部とと
もに、ボールミル撹拌してインキとした後、表1
の実験No.1と同様に作成された高分子組成物層を
一方の面に有するPET基体の他方の面に、上記
インキを別々にそれぞれ塗工して、3種類の転写
体を得た。
実施例1の記録条件で記録した結果、記録濃度
はシアン1.6、マゼンタ1.55、イエロー1.0であつ
た。
次に3種類の転写体を試験管に巻回して40℃、
90%RHの温湿度環境下に100時間保存後、記録
濃度を測定した結果、シアン1.55、マゼンタ
1.60、イエロー1.0であつた。
比較例 1
実施例2で使用した色素の代わりに、下記式で
表わされる塩基性染料5体積部を使用し、実施例
2と同様の方法によりインキの調製、転写体の作
製、転写記録方法を行つた。転写体を実施例2と
同じ温湿度試験条件下に保持した結果、試験前の
シアン色の色濃度1.5は、保存後1.1に低下した。
発明の効果
以上のように本発明の感熱記録用転写体は、保
存安定性に優れ、十分な色濃度を与えるととも
に、画像に白線のない均一な記録画像が得られ
る。また、シアン、マゼンタおよびイエローに発
色する三種類の転写体を用いてフルカラーの画像
を得ることも可能である。[Table] Example 2 For each of the cyan, yellow, and magenta sublimable dyes represented by the structural formulas (1), (2), and (3) below, 5 parts by volume of the dye and 5 parts by volume of polysulfon were added. After stirring in a ball mill with 100 parts by volume of monochlorobenzene to form an ink, Table 1
The above ink was separately applied to the other side of a PET substrate having a polymer composition layer on one side prepared in the same manner as in Experiment No. 1 to obtain three types of transfer bodies. As a result of recording under the recording conditions of Example 1, the recording density was 1.6 for cyan, 1.55 for magenta, and 1.0 for yellow. Next, the three types of transfer materials were wound around a test tube and heated to 40°C.
After storing for 100 hours in a temperature and humidity environment of 90% RH, the recorded density was measured: cyan 1.55, magenta
1.60, yellow 1.0. Comparative Example 1 In place of the dye used in Example 2, 5 parts by volume of a basic dye represented by the following formula was used, and the ink preparation, transfer body preparation, and transfer recording method were carried out in the same manner as in Example 2. I went. As a result of holding the transfer body under the same temperature and humidity test conditions as in Example 2, the color density of cyan color before the test was 1.5, but after storage, it decreased to 1.1. Effects of the Invention As described above, the heat-sensitive recording transfer member of the present invention has excellent storage stability, provides sufficient color density, and can provide a uniform recorded image without white lines. Further, it is also possible to obtain a full-color image using three types of transfer bodies that develop colors in cyan, magenta, and yellow.
図は本発明の一実施例における転写体の概略断
面図である。
1……基体、2……色材層、3……高分子組成
物層。
The figure is a schematic cross-sectional view of a transfer body in one embodiment of the present invention. 1...Substrate, 2...Coloring material layer, 3...Polymer composition layer.
Claims (1)
()で表される昇華性染料のうち少なくとも1
種類を含む色材層が設けられ、他方の面にフツ化
カーボン、カーボンブラツク、黒鉛からなる群よ
り選ばれる微粒子とシリコーンオイルからなる液
状潤滑性物質と高分子物質とからなる高分子組成
物層が設けられ、かつ前記微粒子 (式中、Xは水素原子またはメチル基を、R及
びR′はそれぞれメチル基 エチル基 直鎖状も
しくは分岐鎖状のプロピル基又はプチル基を表わ
す)により前記高分子組成物層の表面が粗面化さ
れている昇華型感熱記録用転写体。 2 色材層が、前記一般式における置換基の異な
る2種以上の昇華性染料を含む特許請求の範囲第
1項記載の昇華型感熱記録用転写体。 3 一般式(),(),()からそれぞれ選ば
れた少なくとも1種類ずつの昇華性染料を含む色
相の異なる3面の色材層を面順次に配置した特許
請求の範囲第1項記載の昇華型感熱記録用転写
体。 4 一般式(),(),()からそれぞれ選ば
れた少なくとも1種類ずつの昇華性染料を含む3
面の色材層と、一般式(),(),()のそれ
ぞれから少なくとも1種類ずつ選ばれてなる第4
の色材層を面順次に配置した特許請求の範囲第1
項記載の昇華型感熱記録用転写体。[Claims] 1. The following general formulas (), (),
At least one of the sublimable dyes represented by ()
A coloring material layer including a coloring agent is provided on the other surface, and a polymer composition layer is formed on the other surface of a liquid lubricating substance consisting of fine particles selected from the group consisting of carbon fluoride, carbon black, and graphite, a liquid lubricating substance consisting of silicone oil, and a polymeric substance. is provided, and the fine particles (In the formula, X represents a hydrogen atom or a methyl group, R and R' each represent a methyl group, an ethyl group, a linear or branched propyl group, or a butyl group), so that the surface of the polymer composition layer is roughened. A surface-printed transfer material for sublimation type heat-sensitive recording. 2. The transfer material for sublimation type heat-sensitive recording according to claim 1, wherein the coloring material layer contains two or more kinds of sublimable dyes having different substituents in the general formula. 3. The method according to claim 1, wherein three colorant layers containing at least one type of sublimable dye selected from the general formulas (), (), and () and having different hues are sequentially arranged. Transfer material for sublimation type thermal recording. 4 Containing at least one sublimable dye selected from the general formulas (), (), ()
a coloring material layer on the surface and a fourth colorant layer made of at least one type selected from each of the general formulas (), (), and
Claim 1, in which the coloring material layers are arranged in a plane-sequential manner.
A transfer body for sublimation type heat-sensitive recording as described in 2.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59086532A JPS60229787A (en) | 1984-04-27 | 1984-04-27 | Transfer body for thermal recording |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59086532A JPS60229787A (en) | 1984-04-27 | 1984-04-27 | Transfer body for thermal recording |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60229787A JPS60229787A (en) | 1985-11-15 |
JPH0548198B2 true JPH0548198B2 (en) | 1993-07-20 |
Family
ID=13889604
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59086532A Granted JPS60229787A (en) | 1984-04-27 | 1984-04-27 | Transfer body for thermal recording |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60229787A (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3630279A1 (en) * | 1986-09-05 | 1988-03-17 | Basf Ag | METHOD FOR TRANSMITTING DYES |
US4829050A (en) * | 1987-06-16 | 1989-05-09 | Eastman Kodak Company | Solid particle lubricants for slipping layer of dye-donor element used in thermal dye transfer |
EP0701907A1 (en) | 1994-09-13 | 1996-03-20 | Agfa-Gevaert N.V. | A dye donor element for use in a thermal dye transfer process |
EP0713133B1 (en) | 1994-10-14 | 2001-05-16 | Agfa-Gevaert N.V. | Receiving element for use in thermal transfer printing |
EP0733487B1 (en) | 1995-01-30 | 2000-05-24 | Agfa-Gevaert N.V. | Method for making a lithographic printing plate requiring no wet processing |
DE69613208T2 (en) | 1996-02-27 | 2002-04-25 | Agfa-Gevaert N.V., Mortsel | Dye donor element for use in a thermal transfer printing process |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56155794A (en) * | 1980-05-06 | 1981-12-02 | Fuji Kagaku Kogyo Kk | Thermo-sensitive transfer material |
JPS57129789A (en) * | 1981-02-05 | 1982-08-11 | Fuji Kagakushi Kogyo Co Ltd | Heat sensitive transferring material |
JPS58101095A (en) * | 1981-12-12 | 1983-06-16 | Fuji Kagakushi Kogyo Co Ltd | Heat transfer recording medium |
JPS58171992A (en) * | 1982-04-01 | 1983-10-08 | Dainippon Printing Co Ltd | Heat sensitive transfer sheet |
JPS58187396A (en) * | 1982-04-27 | 1983-11-01 | Dainippon Printing Co Ltd | Heat-sensitive transfer sheet |
JPS5978896A (en) * | 1982-10-28 | 1984-05-07 | Mitsubishi Chem Ind Ltd | Coloring matter for heat-sensitive transfer recording |
JPS5978894A (en) * | 1982-10-28 | 1984-05-07 | Mitsubishi Chem Ind Ltd | Coloring matter for heat-sensitive transfer recording |
JPS5978895A (en) * | 1982-10-28 | 1984-05-07 | Mitsubishi Chem Ind Ltd | Coloring matter for heat-sensitive transfer recording |
JPS59227493A (en) * | 1983-06-09 | 1984-12-20 | Mitsubishi Chem Ind Ltd | Transfer sheet |
-
1984
- 1984-04-27 JP JP59086532A patent/JPS60229787A/en active Granted
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56155794A (en) * | 1980-05-06 | 1981-12-02 | Fuji Kagaku Kogyo Kk | Thermo-sensitive transfer material |
JPS57129789A (en) * | 1981-02-05 | 1982-08-11 | Fuji Kagakushi Kogyo Co Ltd | Heat sensitive transferring material |
JPS58101095A (en) * | 1981-12-12 | 1983-06-16 | Fuji Kagakushi Kogyo Co Ltd | Heat transfer recording medium |
JPS58171992A (en) * | 1982-04-01 | 1983-10-08 | Dainippon Printing Co Ltd | Heat sensitive transfer sheet |
JPS58187396A (en) * | 1982-04-27 | 1983-11-01 | Dainippon Printing Co Ltd | Heat-sensitive transfer sheet |
JPS5978896A (en) * | 1982-10-28 | 1984-05-07 | Mitsubishi Chem Ind Ltd | Coloring matter for heat-sensitive transfer recording |
JPS5978894A (en) * | 1982-10-28 | 1984-05-07 | Mitsubishi Chem Ind Ltd | Coloring matter for heat-sensitive transfer recording |
JPS5978895A (en) * | 1982-10-28 | 1984-05-07 | Mitsubishi Chem Ind Ltd | Coloring matter for heat-sensitive transfer recording |
JPS59227493A (en) * | 1983-06-09 | 1984-12-20 | Mitsubishi Chem Ind Ltd | Transfer sheet |
Also Published As
Publication number | Publication date |
---|---|
JPS60229787A (en) | 1985-11-15 |
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