JPH054670B2 - - Google Patents
Info
- Publication number
- JPH054670B2 JPH054670B2 JP60242884A JP24288485A JPH054670B2 JP H054670 B2 JPH054670 B2 JP H054670B2 JP 60242884 A JP60242884 A JP 60242884A JP 24288485 A JP24288485 A JP 24288485A JP H054670 B2 JPH054670 B2 JP H054670B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- substituted
- carrier
- unsubstituted
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000126 substance Substances 0.000 claims description 56
- 108091008695 photoreceptors Proteins 0.000 claims description 43
- -1 phthalocyanine compound Chemical class 0.000 claims description 34
- 239000000463 material Substances 0.000 claims description 19
- 125000003118 aryl group Chemical group 0.000 claims description 13
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 238000002441 X-ray diffraction Methods 0.000 claims description 8
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 6
- 125000005843 halogen group Chemical group 0.000 claims description 6
- 125000003545 alkoxy group Chemical group 0.000 claims description 5
- 125000003277 amino group Chemical group 0.000 claims description 5
- 238000001228 spectrum Methods 0.000 claims description 5
- 125000000623 heterocyclic group Chemical group 0.000 claims description 4
- 239000010410 layer Substances 0.000 description 58
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical class N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 29
- 230000035945 sensitivity Effects 0.000 description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 9
- 239000011230 binding agent Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 239000000049 pigment Substances 0.000 description 7
- 239000011669 selenium Substances 0.000 description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229910052711 selenium Inorganic materials 0.000 description 6
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 4
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 4
- 229940126062 Compound A Drugs 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 238000000862 absorption spectrum Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 230000009102 absorption Effects 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 2
- 150000004056 anthraquinones Chemical class 0.000 description 2
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 2
- 125000002837 carbocyclic group Chemical group 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000002612 dispersion medium Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000006575 electron-withdrawing group Chemical group 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 125000003367 polycyclic group Chemical group 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- NYNZQNWKBKUAII-KBXCAEBGSA-N (3s)-n-[5-[(2r)-2-(2,5-difluorophenyl)pyrrolidin-1-yl]pyrazolo[1,5-a]pyrimidin-3-yl]-3-hydroxypyrrolidine-1-carboxamide Chemical compound C1[C@@H](O)CCN1C(=O)NC1=C2N=C(N3[C@H](CCC3)C=3C(=CC=C(F)C=3)F)C=CN2N=C1 NYNZQNWKBKUAII-KBXCAEBGSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- NMNSBFYYVHREEE-UHFFFAOYSA-N 1,2-dinitroanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=C([N+]([O-])=O)C([N+](=O)[O-])=CC=C3C(=O)C2=C1 NMNSBFYYVHREEE-UHFFFAOYSA-N 0.000 description 1
- IZUKQUVSCNEFMJ-UHFFFAOYSA-N 1,2-dinitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1[N+]([O-])=O IZUKQUVSCNEFMJ-UHFFFAOYSA-N 0.000 description 1
- XVMIKRZPDSXBTP-UHFFFAOYSA-N 1,3-dibromobutan-2-one Chemical compound CC(Br)C(=O)CBr XVMIKRZPDSXBTP-UHFFFAOYSA-N 0.000 description 1
- WDCYWAQPCXBPJA-UHFFFAOYSA-N 1,3-dinitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC([N+]([O-])=O)=C1 WDCYWAQPCXBPJA-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- HJRJRUMKQCMYDL-UHFFFAOYSA-N 1-chloro-2,4,6-trinitrobenzene Chemical compound [O-][N+](=O)C1=CC([N+]([O-])=O)=C(Cl)C([N+]([O-])=O)=C1 HJRJRUMKQCMYDL-UHFFFAOYSA-N 0.000 description 1
- HZNVUJQVZSTENZ-UHFFFAOYSA-N 2,3-dichloro-5,6-dicyano-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(C#N)=C(C#N)C1=O HZNVUJQVZSTENZ-UHFFFAOYSA-N 0.000 description 1
- VHQGURIJMFPBKS-UHFFFAOYSA-N 2,4,7-trinitrofluoren-9-one Chemical compound [O-][N+](=O)C1=CC([N+]([O-])=O)=C2C3=CC=C([N+](=O)[O-])C=C3C(=O)C2=C1 VHQGURIJMFPBKS-UHFFFAOYSA-N 0.000 description 1
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 1
- SLAMLWHELXOEJZ-UHFFFAOYSA-N 2-nitrobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1[N+]([O-])=O SLAMLWHELXOEJZ-UHFFFAOYSA-N 0.000 description 1
- UKYNESNNFCHAEV-UHFFFAOYSA-N 3,4-dibromooxolane-2,5-dione Chemical compound BrC1C(Br)C(=O)OC1=O UKYNESNNFCHAEV-UHFFFAOYSA-N 0.000 description 1
- VYWYYJYRVSBHJQ-UHFFFAOYSA-N 3,5-dinitrobenzoic acid Chemical compound OC(=O)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1 VYWYYJYRVSBHJQ-UHFFFAOYSA-N 0.000 description 1
- LWFUFLREGJMOIZ-UHFFFAOYSA-N 3,5-dinitrosalicylic acid Chemical compound OC(=O)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O LWFUFLREGJMOIZ-UHFFFAOYSA-N 0.000 description 1
- ITUYMTWJWYTELW-UHFFFAOYSA-N 4-chloroiminocyclohexa-2,5-dien-1-one Chemical compound ClN=C1C=CC(=O)C=C1 ITUYMTWJWYTELW-UHFFFAOYSA-N 0.000 description 1
- ROFZMKDROVBLNY-UHFFFAOYSA-N 4-nitro-2-benzofuran-1,3-dione Chemical compound [O-][N+](=O)C1=CC=CC2=C1C(=O)OC2=O ROFZMKDROVBLNY-UHFFFAOYSA-N 0.000 description 1
- OTLNPYWUJOZPPA-UHFFFAOYSA-N 4-nitrobenzoic acid Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1 OTLNPYWUJOZPPA-UHFFFAOYSA-N 0.000 description 1
- NKJIFDNZPGLLSH-UHFFFAOYSA-N 4-nitrobenzonitrile Chemical compound [O-][N+](=O)C1=CC=C(C#N)C=C1 NKJIFDNZPGLLSH-UHFFFAOYSA-N 0.000 description 1
- MMVIDXVHQANYAE-UHFFFAOYSA-N 5-nitro-2-benzofuran-1,3-dione Chemical compound [O-][N+](=O)C1=CC=C2C(=O)OC(=O)C2=C1 MMVIDXVHQANYAE-UHFFFAOYSA-N 0.000 description 1
- MEXUTNIFSHFQRG-UHFFFAOYSA-N 6,7,12,13-tetrahydro-5h-indolo[2,3-a]pyrrolo[3,4-c]carbazol-5-one Chemical compound C12=C3C=CC=C[C]3NC2=C2NC3=CC=C[CH]C3=C2C2=C1C(=O)NC2 MEXUTNIFSHFQRG-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004419 Panlite Substances 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- QHWKHLYUUZGSCW-UHFFFAOYSA-N Tetrabromophthalic anhydride Chemical compound BrC1=C(Br)C(Br)=C2C(=O)OC(=O)C2=C1Br QHWKHLYUUZGSCW-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- UATJOMSPNYCXIX-UHFFFAOYSA-N Trinitrobenzene Chemical compound [O-][N+](=O)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1 UATJOMSPNYCXIX-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 125000006615 aromatic heterocyclic group Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 229910003437 indium oxide Inorganic materials 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229940102253 isopropanolamine Drugs 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- NNYHMCFMPHPHOQ-UHFFFAOYSA-N mellitic anhydride Chemical compound O=C1OC(=O)C2=C1C(C(OC1=O)=O)=C1C1=C2C(=O)OC1=O NNYHMCFMPHPHOQ-UHFFFAOYSA-N 0.000 description 1
- 239000000113 methacrylic resin Substances 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- OXNIZHLAWKMVMX-UHFFFAOYSA-N picric acid Chemical compound OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000012264 purified product Substances 0.000 description 1
- 238000001226 reprecipitation Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003839 salts Chemical group 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229960005265 selenium sulfide Drugs 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- PWEBUXCTKOWPCW-UHFFFAOYSA-N squaric acid Chemical compound OC1=C(O)C(=O)C1=O PWEBUXCTKOWPCW-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- UGNWTBMOAKPKBL-UHFFFAOYSA-N tetrachloro-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O UGNWTBMOAKPKBL-UHFFFAOYSA-N 0.000 description 1
- AUHHYELHRWCWEZ-UHFFFAOYSA-N tetrachlorophthalic anhydride Chemical compound ClC1=C(Cl)C(Cl)=C2C(=O)OC(=O)C2=C1Cl AUHHYELHRWCWEZ-UHFFFAOYSA-N 0.000 description 1
- NLDYACGHTUPAQU-UHFFFAOYSA-N tetracyanoethylene Chemical group N#CC(C#N)=C(C#N)C#N NLDYACGHTUPAQU-UHFFFAOYSA-N 0.000 description 1
- PCCVSPMFGIFTHU-UHFFFAOYSA-N tetracyanoquinodimethane Chemical compound N#CC(C#N)=C1C=CC(=C(C#N)C#N)C=C1 PCCVSPMFGIFTHU-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 238000001132 ultrasonic dispersion Methods 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0622—Heterocyclic compounds
- G03G5/0624—Heterocyclic compounds containing one hetero ring
- G03G5/0635—Heterocyclic compounds containing one hetero ring being six-membered
- G03G5/0637—Heterocyclic compounds containing one hetero ring being six-membered containing one hetero atom
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0622—Heterocyclic compounds
- G03G5/0624—Heterocyclic compounds containing one hetero ring
- G03G5/0627—Heterocyclic compounds containing one hetero ring being five-membered
- G03G5/0629—Heterocyclic compounds containing one hetero ring being five-membered containing one hetero atom
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0664—Dyes
- G03G5/0666—Dyes containing a methine or polymethine group
- G03G5/0668—Dyes containing a methine or polymethine group containing only one methine or polymethine group
- G03G5/067—Dyes containing a methine or polymethine group containing only one methine or polymethine group containing hetero rings
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Photoreceptors In Electrophotography (AREA)
Description
ç£æ¥äžã®å©çšåé
æ¬çºæã¯ãé»ååçæå
äœã«ä¿ããç¹ã«ããªã³
ã¿ãè€åæ©çã«äœ¿çšãããå¯èŠå ããé·æ³¢é·å ã
åå°äœã¬ãŒã¶ãŒå ã«å¯ŸããŠé«æ床ã瀺ãæå äœã«
é¢ãããã®ã§ããã çºæã®èæ¯ åŸæ¥ãå¯èŠå ã«é«æ床ãæããé»ååççšæå
äœã¯è€åæ©ãããªã³ã¿ãŒçã«åºã䜿çšãããŠã
ãããã®ãããªé»ååçæå äœãšããŠã¯ãã»ã¬
ã³ãé žåäºéãç¡«åã«ãããŠã çã®ç¡æ©å å°é»ç©
質ãäž»æåãšããæå å±€ãèšããç¡æ©æå äœãåº
ã䜿çšãããŠãããããããªããããã®ãããªç¡
æ©æå äœã¯è€åæ©çã®é»ååçæå äœãšããŠèŠæ±
ãããå æ床ãç±å®å®æ§ãè湿æ§ãèä¹ æ§çã®ç¹
æ§ã«ãããŠå¿ ãããæºè¶³ã§ãããã®ã§ã¯ãªããäŸ
ãã°ãã»ã¬ã³ã¯ç±ãæã§è§Šã€ããšãã®æçŽã®æ±ã
çã«ããçµæ¶åãããããé»ååçæå äœãšããŠ
ã®äžèšç¹æ§ãå£åãæãããŸãç¡«åã«ãããŠã ã
çšããé»ååçæå äœã¯è湿æ§ãèä¹ æ§ã«å£ãã
ãŸãé žåäºéãçšããé»ååçæå äœã¯èä¹ æ§ã«
åé¡ãããããŸããã»ã¬ã³ãç¡«åã«ãããŠã ã®é»
ååçæå äœã¯è£œé äžãåæ±ãäžã®å¶çŽã倧ãã
ãšããæ¬ ç¹ãããã ãã®ãããªç¡æ©å å°é»æ§ç©è³ªã®åé¡ç¹ãæ¹åã
ãããã«ãçš®ã ã®ææ©ã®å å°é»æ§ç©è³ªãé»ååç
æå äœã®æå å±€ã«äœ¿çšããããšãè©Šã¿ãããè¿å¹Ž
掻çºã«ç 究ãéçºãè¡ãªãããŠãããäŸãã°ãç¹
å ¬æ50â10496å·å ¬å ±ã«ã¯ãããªââããã«ã«
ã«ããŸãŒã«ãšïŒïŒïŒïŒïŒâããªãããâïŒâãã«
ãªã¬ãã³ãå«æããæå å±€ãæããææ©æå äœã
èšèŒãããŠããããããããã®æå äœãæ床åã³
èä¹ æ§ã«ãããŠååã§ãªãããã®ãããæå å±€ã
äºå±€ã«åããŠãã€ãªã¢çºçå±€ãšãã€ãªã¢èŒžéå±€ã
å¥ã ã«æ§æããããããã«ãã€ãªã¢çºçç©è³ªãã
ã€ãªã¢èŒžéç©è³ªãå«æãããæ©èœåé¢åã®é»åå
çæå äœãéçºããããããã¯ããã€ãªã¢çºçæ©
èœãšãã€ãªã¢èŒžéæ©èœãç°ãªãç©è³ªã«åå¥ã«åæ
ãããããšãã§ãããããåæ©èœãçºæ®ããç©è³ª
ãåºãç¯å²ã®ãã®ããéžæããããšãã§ããã®
ã§ãä»»æã®ç¹æ§ãæããé»ååçæå äœãæ¯èŒç
容æã«åŸããããããã€ãŠæ床ãé«ããèä¹ æ§ã®
倧ããææ©æå äœãåŸãããããšãæåŸ ãããŠã
ãã ãã®ãããªæ©èœåé¢åã®é»ååçæå äœã®ãã€
ãªã¢çºçå±€ã«æå¹ãªãã€ãªã¢çºçç©è³ªãšããŠã¯ã
åŸæ¥æ°å€ãã®ç©è³ªãææ¡ãããŠãããç¡æ©ç©è³ªã
çšããäŸãšããŠã¯ãäŸãã°ç¹å ¬æ43â16198å·å ¬
å ±ã«èšèŒãããŠããããã«ç¡å®åœ¢ã»ã¬ã³ãæãã
ããããã®ç¡å®åœ¢ã»ã¬ã³ãå«æãããã€ãªã¢çºç
å±€ã¯ææ©ãã€ãªã¢èŒžéç©è³ªãå«æãããã€ãªã¢èŒž
éå±€ãšçµã¿åããããŠäœ¿çšãããããããããã®
ç¡å®åœ¢ã»ã¬ã³ãããªããã€ãªã¢çºçå±€ã¯ãäžèšã
ãããã«ç±çã«ããçµæ¶åããŠãã®ç¹æ§ãå£åã
ããšããåé¡ç¹ãããããŸããææ©ç©è³ªãäžèšã®
ãã€ãªã¢çºçç©è³ªãšããŠçšããäŸãšããŠã¯ãææ©
ææãææ©é¡æãæãããããäŸãã°ããã¹ã¢ãŸ
ååç©ãå«æããæå å±€ãæãããã®ãšããŠã¯ã
ç¹éæ47â37543å·å ¬å ±ãç¹éæ55â22834å·å ¬
å ±ãç¹éæ54â79632å·å ¬å ±ãç¹éæ56â116040
å·å ¬å ±çã«ãããã§ã«ç¥ãããŠããã ããããªããããããã®å ¬ç¥ã®ãã¹ã¢ãŸååç©
ã¯çæ³¢é·è¥ããã¯äžæ³¢é·åã§ã¯æ¯èŒçè¯å¥œãªæ床
ã瀺ãããé·æ³¢é·åã§ã®æ床ãäœããé«ä¿¡é Œæ§ã®
æåŸ ãããåå°äœã¬ãŒã¶ãŒå æºãçšããã¬ãŒã¶ãŒ
ããªã³ã¿ã«çšããããšã¯å°é£ã§ãã€ãã çŸåšãåå°äœã¬ãŒã¶ãŒãšããŠåºç¯å²ã«çšããã
ãŠããã¬ãªãŠã âã¢ã«ãããŠã âãçŽ ïŒGaã»
Alã»AsïŒç³»çºå çŽ åã¯ãçºæ¯æ³¢é·ã750nmçšåºŠ
以äžã§ããããã®ãããªé·æ³¢é·å ã«é«æ床ã®é»å
åçæå äœãåŸãããã«ãåŸæ¥æ°å€ãã®æ€èšããª
ãããŠãããäŸãã°ãå¯èŠå é åã«é«æ床ãæã
ãSeãCdSçã®æå ææã«æ°ãã«é·æ³¢é·åããã
ãã®å¢æå€ãæ·»å ããæ¹æ³ãèããããããSeã
CdSã¯äžèšããããã«æž©åºŠã湿床çã«å¯Ÿããèç°
å¢æ§ãååã§ãªãããŸããå€æ°ç¥ãããŠããææ©
ç³»å å°é»ææããäžèšããããã«ãã®æ床ãéåžž
700nm以äžã®å¯èŠå é åã«éå®ãããããããé·
æ³¢é·åã«ååãªæ床ãæããææã¯å°ãªãã ãããã®ãã¡ã§ãææ©ç³»å å°é»ææã®äžã€ã§ã
ããã¿ãã·ã¢ãã³ç³»ååç©ã¯ãä»ã®ãã®ã«æ¯ã¹æ
å åãé·æ³¢é·åã«æ¡å€§ããŠããããšãç¥ãããŠã
ãããããŠÎ±åã®ãã¿ãã·ã¢ãã³ååç©ãçµæ¶åœ¢
ã®å®å®ãªÎ²åã®ãã¿ãã·ã¢ãã³ååç©ã«å€ããé
çšã§åçš®çµæ¶åœ¢ã®ãã¿ãã·ã¢ãã³ååç©ãèŠåºã
ããŠããããããã®å å°é»æ§ã瀺ããã¿ãã·ã¢ã
ã³ç³»ååç©ãšããŠã¯ãäŸãã°ç¹å ¬æ49â4338å·å ¬
å ±èšèŒã®ïŒžåç¡éå±ãã¿ãã·ã¢ãã³ååç©åã³ç¹
éæ58â182639å·å ¬å ±ãç¹éæ60â19151å·å ¬å ±
ã«èšèŒãããŠããÏãÏâ²ãηãηâ²åç¡éå±ãã¿ã
ã·ã¢ãã³ååç©ãæããããã ãšããã§ãäžè¬ã«æå äœã«ãããŠã¯ãããç¹å®
ã®ãã€ãªã¢çºçç©è³ªã«å¯ŸããŠæå¹ãªãã€ãªã¢èŒžé
ç©è³ªãä»ã®ãã€ãªã¢çºçç©è³ªã«å¯ŸããŠãæå¹ã§ã
ããšã¯éãããéã«ç¹å®ã®ãã€ãªã¢èŒžéç©è³ªã«å¯Ÿ
ããŠæå¹ãªãã€ãªã¢çºçç©è³ªãä»ã®ãã€ãªã¢èŒžé
ç©è³ªã«å¯ŸããŠãæå¹ã§ãããšãèšãããšãã§ããª
ããçµå±ã®ãšãããé»ååçæå äœã«çšãããã
ããã«ã¯ãã€ãªã¢çºçç©è³ªãšãã€ãªã¢èŒžéç©è³ªã®
äž¡ç©è³ªã«ã¯é©åœãªçµã¿åãããå¿ èŠã§ããããã®
çµã¿åãããäžé©åœã§ãããšãé»ååçæå äœãš
ããŠã®æ床ãäœããªãã°ããã§ãªããç¹ã«äœé»ç
æã®æŸé»å¹çãæªããããããããæ®çé»äœã倧
ãããªããææªã®å Žåã«ã¯ãã®é»ååçæå äœã
äŸãã°è€åæ©ã«äœ¿çšããŠãããããªãšãã«ã¯ãã®
å埩䜿çšããŠãã床ã«é»è·ãèç©ãããã®ããã
ããŒãéç»åéšã«ãä»çããŠè€åç©ã®å°æ±ããèµ·
ãããããé®®æãªè€åç»åãåŸãããšãã§ããªã
ããšãããã ãã®ãã€ãªã¢çºçç©è³ªãšãã€ãªã¢èŒžéç©è³ªã®å¥œ
é©ãªçµã¿åããã«ã€ããŠã¯ããçšåºŠã®æ³åæ§ã¯ã¿
ãããããå šãŠã®ç©è³ªã«åœãŠã¯ãŸããšãããããª
ãã®ã§ã¯ãªããå®éã«ã¯ããŸã®ãšãããå€ãã®ç©
質矀ã®äžããæå©ãªçµã¿åãããå®éšçã«éžæã
ãããšãè¡ãããŠããã çºæã解決ããããšããèª²é¡ ããããªããããã¿ãã·ã¢ãã³ååç©ãšããã©
ãŸã³ååç©ã®çµã¿åããã«ã€ããŠã¯ãããã©ãŸã³
ååç©ãèšèŒããç¹éæ58â166354å·å ¬å ±ãç¹é
æ58â134642å·å ¬å ±çã«ãããŠäŸç€ºãããå€ãã®
ãã€ãªã¢çºçç©è³ªã®äžã€ãšããŠãã¿ãã·ã¢ãã³ã
瀺ãããŠããã ãã§ãã€ãŠãäžè¬æœè±¡çã«èšèŒã
ããŠããã«éããããã®å ·äœçå®æœäŸãããã®å ·
äœçå¹æã«ã€ããŠã¯çªºãããšãã§ããªãã ç¹ã«ç¡éå±ãã¿ãã·ã¢ãã³ãšããã©ãŸã³ååç©
ã䜵çšããŠåŸãããé»ååçæå äœã«ã€ããŠãäŸ
ãã°780nmã®é·æ³¢é·å ã«å¯Ÿããæ床ããç¹°ãè¿ã
䜿çšåŸã®æ®çé»äœãååæºè¶³ã§ãããããªãã®ã«
ã€ããŠã¯ãäžèšå ¬å ±çããã¯å šã窺ãããšãã§ã
ããåŸæ¥ã®ç¡éå±ãã¿ãã·ã¢ãã³ååç©ã«ã€ããŠ
ã®ã¿ãªãããåŸæ¥ã«ãªãç¡éå±ãã¿ãã·ã¢ãã³å
åç©ã«ã€ããŠãã®æ€èšãæãŸããŠããã æ¬çºæã®ç¬¬ïŒã®ç®çã¯ãåŸæ¥ã®ãã¿ãã·ã¢ãã³
ç³»ååç©ãšããã©ãŸã³ååç©ã䜵çšããå Žåã«ã¯
åŸãããªãé»äœç¹æ§ãããªãã¡ç¹°ãè¿ã䜿çšæã§
ãæ®çé»äœãå¢å ãããšãããããªããšã®ãªãã
é»äœã®å±¥æŽç¶æ ãå®å®ã«ç¶æãããé»ååçæå
äœãæäŸããããšã«ããã æ¬çºæã®ç¬¬ïŒã®ç®çã¯ãåŸæ¥ã®ãã¿ãã·ã¢ãã³
ç³»ååç©ãšããã©ãŸã³ååç©ã䜵çšããå Žåã«ã¯
åŸãããªãæ床ç¹æ§ãããªãã¡é·æ³¢é·å ãåå°äœ
ã¬ãŒã¶ãŒå ã«é«æ床ãæããé»ååçæå äœãæ
äŸããããšã«ããã 課é¡ã解決ããããã®æ段 äžèšèª²é¡ã解決ããããã«ãæ¬çºæã¯ããã€ãª
ã¢çºçç©è³ªåã³ãã€ãªã¢èŒžéç©è³ªãå«æããæå
å±€ãæããé»ååçæå äœã«ãããŠãåèšãã€ãª
ã¢çºçç©è³ªãCuk α1.541â«ã®ïŒžç·ã«å¯Ÿãããã©
ãã°è§åºŠã7.7ã9.3ã16.9ã17.6ã22.4ã28.8ã«äž»
èŠããŒã¯ãæããç·åæã¹ãã¯ãã«ãæããã
ã€ãã®ïŒžç·åæã¹ãã¯ãã«ã®äžèšãã©ãã°è§åºŠ
9.3ã«å¯Ÿãããã©ãã°è§åºŠ16.9ã®ããŒã¯ã®åŒ·åºŠæ¯
ã0.8ã1.0ã§ããããã€äžèšãã©ãã°è§åºŠ9.3ã®ã
ãŒã¯ã«å¯Ÿãããã©ãã°è§åºŠ22.4åã³28.8ã®ããã
ãã®ããŒã¯ã®åŒ·åºŠæ¯ã0.4以äžã§ããç¡éå±ãã¿
ãã·ã¢ãã³ååç©ãå«ã¿ãåèšãã€ãªã¢èŒžéç©è³ª
ãäžèšäžè¬åŒãããããã§è¡šãããããã©ãŸã³
ååç©ã®å°ãªããšãïŒã€ãå«ãããšãç¹åŸŽãšãã
é»ååçæå äœãæäŸãããã®ã§ããã äžè¬åŒãã ïŒäœããã®äžè¬åŒäžR1ã¯ã眮æè¥ããã¯æªçœ®
æã®ã¢ãªãŒã«åºåã¯çœ®æè¥ããã¯æªçœ®æã®
è€çŽ ç°åºã R2ã¯ãæ°ŽçŽ ååã眮æè¥ããã¯æªçœ®æ
ã®ã¢ã«ãã«åºãåã¯çœ®æè¥ããã¯æªçœ®æã®
ã¢ãªãŒã«åºã X1ã¯ãæ°ŽçŽ ååãããã²ã³ååãã¢ã«
ãã«åºã眮æã¢ããåºãã¢ã«ã³ãã·åºãå
ã¯ã·ã¢ãåºã ïœã¯ãïŒåã¯ïŒã®æŽæ°ãè¡šããïŒ äžè¬åŒãã ïŒäœããã®äžè¬åŒäžR3ã¯ã眮æè¥ããã¯æªçœ®
æã®ã¢ãªãŒã«åºåã¯çœ®æè¥ããã¯æªçœ®æã®
è€çŽ ç°åºã R4ã¯ãæ°ŽçŽ ååã眮æè¥ããã¯æªçœ®æ
ã®ã¢ã«ãã«åºãåã¯çœ®æè¥ããã¯æªçœ®æã®
ã¢ãªãŒã«åºã X2ã¯ãæ°ŽçŽ ååãããã²ã³ååãã¢ã«
ãã«åºã眮æã¢ããåºãã¢ã«ã³ãã·åºãå
ã¯ã·ã¢ãåºã ïœã¯ãïŒåã¯ïŒã®æŽæ°ãè¡šããïŒ æ¬¡ã«æ¬çºæã詳现ã«èª¬æããã æ¬çºæã«äœ¿çšããããã¿ãã·ã¢ãã³ååç©ã¯ã
第ïŒå³ã«ç€ºãããã«Cuk α1.541â«ã®ïŒžç·ã«å¯Ÿã
ããã©ãã°è§åºŠïŒèª€å·®2α0.2床ïŒã7.7ã9.3ã
16.9ã17.6ã22.4ã28.8ã«äž»èŠãªããŒã¯ãæãã
ç·åæã¹ãã¯ãã«ãæãããã®ãã©ãã°è§åºŠ
9.3ã®ããŒã¯ã«å¯Ÿãããã©ãã°è§åºŠ16.9ã®ããŒã¯
ã®åŒ·åºŠæ¯ã0.8ã1.0ã§ãããäžèšãã©ãã°è§åºŠ9.3
ã®ããŒã¯ã«å¯Ÿãããã©ãã°è§åºŠ22.4åã³28.8ã®ã
ãããã®ããŒã¯ã®åŒ·åºŠæ¯ã0.4以äžã§ããã第ïŒ
å³ã«ç€ºãããã«ããã®èµ€å€ç·åžåã¹ãã¯ãã«ã¯
700ã760cm-1ã®éã«720±ïŒcm-1ãæã匷ãïŒæ¬
ã®åžå垯ã1320±ïŒcm-1ã3288±ïŒcm-1ã«ç¹åŸŽç
ãªåžåãæããããã«å¯èŠãè¿èµ€å€ç·åžåã¹ãã¯
ãã«ã®æ¥µå€§ã第ïŒå³ã«ç€ºãããã«ã770nm以äž
790nmæªæºã«ãããã®ã奜ãŸãã䜿çšã§ãããã
ã®ç¡éå±ãã¿ãã·ã¢ãã³ååç©ïŒ¡ã¯ãã®çµæ¶åœ¢ã
å®å®ã§ãã¢ã»ãã³ãããã©ããããã©ã³ããã«ãš
ã³ãé ¢é žãšãã«ãïŒïŒïŒâãžã¯ãããšã¿ã³çã®æ
æ©æº¶å€ã«æµžæŒ¬ããããäŸãã°200âã«50æéæŸçœ®
ããããããã«ã¯ããªã³ã°çã®æ©æ¢°çæªåãå ã
ãŠããã®çµæ¶åœ¢ã®è»¢ç§»ãèµ·ããé£ããæå äœã®ç¹°
ãè¿ã䜿çšã«å¯Ÿããé»äœå®å®æ§çã«ãåªããŠã
ãã奜ãŸããããªãããã¯ææ60幎ïŒæ26æ¥ä»ç¹
èš±é¡ã®æ现æžã«è©³çŽ°ã«èšèŒãããŠãããæ¬çºæã«
䜿çšãããäžèšãã¿ãã·ã¢ãã³ååç©ã¯ãä»ã®ç¡
éå±ãã¿ãã·ã¢ãã³ååç©ãéå±ãã¿ãã·ã¢ãã³
ååç©ãšçµã¿åãããŠäœ¿çšã§ãããŸãããããã®
ããããã®ãã¿ãã·ã¢ãã³ååç©ã«å±ããåæ°å
ã¯è€æ°ã®ãã¿ãã·ã¢ãã³ååç©ãšäœµçšããããšã
ã§ããããããã®äœµçšã§ãããã¿ãã·ã¢ãã³åå
ç©ã«ã¯ãäŸãã°Î±ãβãγãÏãÏâ²ãηãηâ²ã
åç¡éå±ãã¿ãã·ã¢ãã³ååç©åã³Îµåã®ãã¿ã
ã·ã¢ãã³ååç©ãæãããããç¡éå±ãã¿ãã·ã¢
ãã³ååç©ã¯ãæ床ã垯é»å®å®æ§ã«åªããŠãããš
ããç¹é·ãããããããã®ãã¡ã®ç¡éå±ãã¿ãã·
ã¢ãã³ååç©ã®ããã€ãã®ç¹æ§å€ãè¡šïŒã«ç€ºãã ãªãããããã®ç¡éå±ãã¿ãã·ã¢ãã³ååç©ã¯
ç¹å ¬æ49â4338å·å ¬å ±ãç¹éæ60â19154å·å ¬å ±ã
ç¹éæ58â182639å·å ¬å ±ã«è©³çŽ°ã«èšèŒãããŠã
ãã
ã¿ãè€åæ©çã«äœ¿çšãããå¯èŠå ããé·æ³¢é·å ã
åå°äœã¬ãŒã¶ãŒå ã«å¯ŸããŠé«æ床ã瀺ãæå äœã«
é¢ãããã®ã§ããã çºæã®èæ¯ åŸæ¥ãå¯èŠå ã«é«æ床ãæããé»ååççšæå
äœã¯è€åæ©ãããªã³ã¿ãŒçã«åºã䜿çšãããŠã
ãããã®ãããªé»ååçæå äœãšããŠã¯ãã»ã¬
ã³ãé žåäºéãç¡«åã«ãããŠã çã®ç¡æ©å å°é»ç©
質ãäž»æåãšããæå å±€ãèšããç¡æ©æå äœãåº
ã䜿çšãããŠãããããããªããããã®ãããªç¡
æ©æå äœã¯è€åæ©çã®é»ååçæå äœãšããŠèŠæ±
ãããå æ床ãç±å®å®æ§ãè湿æ§ãèä¹ æ§çã®ç¹
æ§ã«ãããŠå¿ ãããæºè¶³ã§ãããã®ã§ã¯ãªããäŸ
ãã°ãã»ã¬ã³ã¯ç±ãæã§è§Šã€ããšãã®æçŽã®æ±ã
çã«ããçµæ¶åãããããé»ååçæå äœãšããŠ
ã®äžèšç¹æ§ãå£åãæãããŸãç¡«åã«ãããŠã ã
çšããé»ååçæå äœã¯è湿æ§ãèä¹ æ§ã«å£ãã
ãŸãé žåäºéãçšããé»ååçæå äœã¯èä¹ æ§ã«
åé¡ãããããŸããã»ã¬ã³ãç¡«åã«ãããŠã ã®é»
ååçæå äœã¯è£œé äžãåæ±ãäžã®å¶çŽã倧ãã
ãšããæ¬ ç¹ãããã ãã®ãããªç¡æ©å å°é»æ§ç©è³ªã®åé¡ç¹ãæ¹åã
ãããã«ãçš®ã ã®ææ©ã®å å°é»æ§ç©è³ªãé»ååç
æå äœã®æå å±€ã«äœ¿çšããããšãè©Šã¿ãããè¿å¹Ž
掻çºã«ç 究ãéçºãè¡ãªãããŠãããäŸãã°ãç¹
å ¬æ50â10496å·å ¬å ±ã«ã¯ãããªââããã«ã«
ã«ããŸãŒã«ãšïŒïŒïŒïŒïŒâããªãããâïŒâãã«
ãªã¬ãã³ãå«æããæå å±€ãæããææ©æå äœã
èšèŒãããŠããããããããã®æå äœãæ床åã³
èä¹ æ§ã«ãããŠååã§ãªãããã®ãããæå å±€ã
äºå±€ã«åããŠãã€ãªã¢çºçå±€ãšãã€ãªã¢èŒžéå±€ã
å¥ã ã«æ§æããããããã«ãã€ãªã¢çºçç©è³ªãã
ã€ãªã¢èŒžéç©è³ªãå«æãããæ©èœåé¢åã®é»åå
çæå äœãéçºããããããã¯ããã€ãªã¢çºçæ©
èœãšãã€ãªã¢èŒžéæ©èœãç°ãªãç©è³ªã«åå¥ã«åæ
ãããããšãã§ãããããåæ©èœãçºæ®ããç©è³ª
ãåºãç¯å²ã®ãã®ããéžæããããšãã§ããã®
ã§ãä»»æã®ç¹æ§ãæããé»ååçæå äœãæ¯èŒç
容æã«åŸããããããã€ãŠæ床ãé«ããèä¹ æ§ã®
倧ããææ©æå äœãåŸãããããšãæåŸ ãããŠã
ãã ãã®ãããªæ©èœåé¢åã®é»ååçæå äœã®ãã€
ãªã¢çºçå±€ã«æå¹ãªãã€ãªã¢çºçç©è³ªãšããŠã¯ã
åŸæ¥æ°å€ãã®ç©è³ªãææ¡ãããŠãããç¡æ©ç©è³ªã
çšããäŸãšããŠã¯ãäŸãã°ç¹å ¬æ43â16198å·å ¬
å ±ã«èšèŒãããŠããããã«ç¡å®åœ¢ã»ã¬ã³ãæãã
ããããã®ç¡å®åœ¢ã»ã¬ã³ãå«æãããã€ãªã¢çºç
å±€ã¯ææ©ãã€ãªã¢èŒžéç©è³ªãå«æãããã€ãªã¢èŒž
éå±€ãšçµã¿åããããŠäœ¿çšãããããããããã®
ç¡å®åœ¢ã»ã¬ã³ãããªããã€ãªã¢çºçå±€ã¯ãäžèšã
ãããã«ç±çã«ããçµæ¶åããŠãã®ç¹æ§ãå£åã
ããšããåé¡ç¹ãããããŸããææ©ç©è³ªãäžèšã®
ãã€ãªã¢çºçç©è³ªãšããŠçšããäŸãšããŠã¯ãææ©
ææãææ©é¡æãæãããããäŸãã°ããã¹ã¢ãŸ
ååç©ãå«æããæå å±€ãæãããã®ãšããŠã¯ã
ç¹éæ47â37543å·å ¬å ±ãç¹éæ55â22834å·å ¬
å ±ãç¹éæ54â79632å·å ¬å ±ãç¹éæ56â116040
å·å ¬å ±çã«ãããã§ã«ç¥ãããŠããã ããããªããããããã®å ¬ç¥ã®ãã¹ã¢ãŸååç©
ã¯çæ³¢é·è¥ããã¯äžæ³¢é·åã§ã¯æ¯èŒçè¯å¥œãªæ床
ã瀺ãããé·æ³¢é·åã§ã®æ床ãäœããé«ä¿¡é Œæ§ã®
æåŸ ãããåå°äœã¬ãŒã¶ãŒå æºãçšããã¬ãŒã¶ãŒ
ããªã³ã¿ã«çšããããšã¯å°é£ã§ãã€ãã çŸåšãåå°äœã¬ãŒã¶ãŒãšããŠåºç¯å²ã«çšããã
ãŠããã¬ãªãŠã âã¢ã«ãããŠã âãçŽ ïŒGaã»
Alã»AsïŒç³»çºå çŽ åã¯ãçºæ¯æ³¢é·ã750nmçšåºŠ
以äžã§ããããã®ãããªé·æ³¢é·å ã«é«æ床ã®é»å
åçæå äœãåŸãããã«ãåŸæ¥æ°å€ãã®æ€èšããª
ãããŠãããäŸãã°ãå¯èŠå é åã«é«æ床ãæã
ãSeãCdSçã®æå ææã«æ°ãã«é·æ³¢é·åããã
ãã®å¢æå€ãæ·»å ããæ¹æ³ãèããããããSeã
CdSã¯äžèšããããã«æž©åºŠã湿床çã«å¯Ÿããèç°
å¢æ§ãååã§ãªãããŸããå€æ°ç¥ãããŠããææ©
ç³»å å°é»ææããäžèšããããã«ãã®æ床ãéåžž
700nm以äžã®å¯èŠå é åã«éå®ãããããããé·
æ³¢é·åã«ååãªæ床ãæããææã¯å°ãªãã ãããã®ãã¡ã§ãææ©ç³»å å°é»ææã®äžã€ã§ã
ããã¿ãã·ã¢ãã³ç³»ååç©ã¯ãä»ã®ãã®ã«æ¯ã¹æ
å åãé·æ³¢é·åã«æ¡å€§ããŠããããšãç¥ãããŠã
ãããããŠÎ±åã®ãã¿ãã·ã¢ãã³ååç©ãçµæ¶åœ¢
ã®å®å®ãªÎ²åã®ãã¿ãã·ã¢ãã³ååç©ã«å€ããé
çšã§åçš®çµæ¶åœ¢ã®ãã¿ãã·ã¢ãã³ååç©ãèŠåºã
ããŠããããããã®å å°é»æ§ã瀺ããã¿ãã·ã¢ã
ã³ç³»ååç©ãšããŠã¯ãäŸãã°ç¹å ¬æ49â4338å·å ¬
å ±èšèŒã®ïŒžåç¡éå±ãã¿ãã·ã¢ãã³ååç©åã³ç¹
éæ58â182639å·å ¬å ±ãç¹éæ60â19151å·å ¬å ±
ã«èšèŒãããŠããÏãÏâ²ãηãηâ²åç¡éå±ãã¿ã
ã·ã¢ãã³ååç©ãæããããã ãšããã§ãäžè¬ã«æå äœã«ãããŠã¯ãããç¹å®
ã®ãã€ãªã¢çºçç©è³ªã«å¯ŸããŠæå¹ãªãã€ãªã¢èŒžé
ç©è³ªãä»ã®ãã€ãªã¢çºçç©è³ªã«å¯ŸããŠãæå¹ã§ã
ããšã¯éãããéã«ç¹å®ã®ãã€ãªã¢èŒžéç©è³ªã«å¯Ÿ
ããŠæå¹ãªãã€ãªã¢çºçç©è³ªãä»ã®ãã€ãªã¢èŒžé
ç©è³ªã«å¯ŸããŠãæå¹ã§ãããšãèšãããšãã§ããª
ããçµå±ã®ãšãããé»ååçæå äœã«çšãããã
ããã«ã¯ãã€ãªã¢çºçç©è³ªãšãã€ãªã¢èŒžéç©è³ªã®
äž¡ç©è³ªã«ã¯é©åœãªçµã¿åãããå¿ èŠã§ããããã®
çµã¿åãããäžé©åœã§ãããšãé»ååçæå äœãš
ããŠã®æ床ãäœããªãã°ããã§ãªããç¹ã«äœé»ç
æã®æŸé»å¹çãæªããããããããæ®çé»äœã倧
ãããªããææªã®å Žåã«ã¯ãã®é»ååçæå äœã
äŸãã°è€åæ©ã«äœ¿çšããŠãããããªãšãã«ã¯ãã®
å埩䜿çšããŠãã床ã«é»è·ãèç©ãããã®ããã
ããŒãéç»åéšã«ãä»çããŠè€åç©ã®å°æ±ããèµ·
ãããããé®®æãªè€åç»åãåŸãããšãã§ããªã
ããšãããã ãã®ãã€ãªã¢çºçç©è³ªãšãã€ãªã¢èŒžéç©è³ªã®å¥œ
é©ãªçµã¿åããã«ã€ããŠã¯ããçšåºŠã®æ³åæ§ã¯ã¿
ãããããå šãŠã®ç©è³ªã«åœãŠã¯ãŸããšãããããª
ãã®ã§ã¯ãªããå®éã«ã¯ããŸã®ãšãããå€ãã®ç©
質矀ã®äžããæå©ãªçµã¿åãããå®éšçã«éžæã
ãããšãè¡ãããŠããã çºæã解決ããããšããèª²é¡ ããããªããããã¿ãã·ã¢ãã³ååç©ãšããã©
ãŸã³ååç©ã®çµã¿åããã«ã€ããŠã¯ãããã©ãŸã³
ååç©ãèšèŒããç¹éæ58â166354å·å ¬å ±ãç¹é
æ58â134642å·å ¬å ±çã«ãããŠäŸç€ºãããå€ãã®
ãã€ãªã¢çºçç©è³ªã®äžã€ãšããŠãã¿ãã·ã¢ãã³ã
瀺ãããŠããã ãã§ãã€ãŠãäžè¬æœè±¡çã«èšèŒã
ããŠããã«éããããã®å ·äœçå®æœäŸãããã®å ·
äœçå¹æã«ã€ããŠã¯çªºãããšãã§ããªãã ç¹ã«ç¡éå±ãã¿ãã·ã¢ãã³ãšããã©ãŸã³ååç©
ã䜵çšããŠåŸãããé»ååçæå äœã«ã€ããŠãäŸ
ãã°780nmã®é·æ³¢é·å ã«å¯Ÿããæ床ããç¹°ãè¿ã
䜿çšåŸã®æ®çé»äœãååæºè¶³ã§ãããããªãã®ã«
ã€ããŠã¯ãäžèšå ¬å ±çããã¯å šã窺ãããšãã§ã
ããåŸæ¥ã®ç¡éå±ãã¿ãã·ã¢ãã³ååç©ã«ã€ããŠ
ã®ã¿ãªãããåŸæ¥ã«ãªãç¡éå±ãã¿ãã·ã¢ãã³å
åç©ã«ã€ããŠãã®æ€èšãæãŸããŠããã æ¬çºæã®ç¬¬ïŒã®ç®çã¯ãåŸæ¥ã®ãã¿ãã·ã¢ãã³
ç³»ååç©ãšããã©ãŸã³ååç©ã䜵çšããå Žåã«ã¯
åŸãããªãé»äœç¹æ§ãããªãã¡ç¹°ãè¿ã䜿çšæã§
ãæ®çé»äœãå¢å ãããšãããããªããšã®ãªãã
é»äœã®å±¥æŽç¶æ ãå®å®ã«ç¶æãããé»ååçæå
äœãæäŸããããšã«ããã æ¬çºæã®ç¬¬ïŒã®ç®çã¯ãåŸæ¥ã®ãã¿ãã·ã¢ãã³
ç³»ååç©ãšããã©ãŸã³ååç©ã䜵çšããå Žåã«ã¯
åŸãããªãæ床ç¹æ§ãããªãã¡é·æ³¢é·å ãåå°äœ
ã¬ãŒã¶ãŒå ã«é«æ床ãæããé»ååçæå äœãæ
äŸããããšã«ããã 課é¡ã解決ããããã®æ段 äžèšèª²é¡ã解決ããããã«ãæ¬çºæã¯ããã€ãª
ã¢çºçç©è³ªåã³ãã€ãªã¢èŒžéç©è³ªãå«æããæå
å±€ãæããé»ååçæå äœã«ãããŠãåèšãã€ãª
ã¢çºçç©è³ªãCuk α1.541â«ã®ïŒžç·ã«å¯Ÿãããã©
ãã°è§åºŠã7.7ã9.3ã16.9ã17.6ã22.4ã28.8ã«äž»
èŠããŒã¯ãæããç·åæã¹ãã¯ãã«ãæããã
ã€ãã®ïŒžç·åæã¹ãã¯ãã«ã®äžèšãã©ãã°è§åºŠ
9.3ã«å¯Ÿãããã©ãã°è§åºŠ16.9ã®ããŒã¯ã®åŒ·åºŠæ¯
ã0.8ã1.0ã§ããããã€äžèšãã©ãã°è§åºŠ9.3ã®ã
ãŒã¯ã«å¯Ÿãããã©ãã°è§åºŠ22.4åã³28.8ã®ããã
ãã®ããŒã¯ã®åŒ·åºŠæ¯ã0.4以äžã§ããç¡éå±ãã¿
ãã·ã¢ãã³ååç©ãå«ã¿ãåèšãã€ãªã¢èŒžéç©è³ª
ãäžèšäžè¬åŒãããããã§è¡šãããããã©ãŸã³
ååç©ã®å°ãªããšãïŒã€ãå«ãããšãç¹åŸŽãšãã
é»ååçæå äœãæäŸãããã®ã§ããã äžè¬åŒãã ïŒäœããã®äžè¬åŒäžR1ã¯ã眮æè¥ããã¯æªçœ®
æã®ã¢ãªãŒã«åºåã¯çœ®æè¥ããã¯æªçœ®æã®
è€çŽ ç°åºã R2ã¯ãæ°ŽçŽ ååã眮æè¥ããã¯æªçœ®æ
ã®ã¢ã«ãã«åºãåã¯çœ®æè¥ããã¯æªçœ®æã®
ã¢ãªãŒã«åºã X1ã¯ãæ°ŽçŽ ååãããã²ã³ååãã¢ã«
ãã«åºã眮æã¢ããåºãã¢ã«ã³ãã·åºãå
ã¯ã·ã¢ãåºã ïœã¯ãïŒåã¯ïŒã®æŽæ°ãè¡šããïŒ äžè¬åŒãã ïŒäœããã®äžè¬åŒäžR3ã¯ã眮æè¥ããã¯æªçœ®
æã®ã¢ãªãŒã«åºåã¯çœ®æè¥ããã¯æªçœ®æã®
è€çŽ ç°åºã R4ã¯ãæ°ŽçŽ ååã眮æè¥ããã¯æªçœ®æ
ã®ã¢ã«ãã«åºãåã¯çœ®æè¥ããã¯æªçœ®æã®
ã¢ãªãŒã«åºã X2ã¯ãæ°ŽçŽ ååãããã²ã³ååãã¢ã«
ãã«åºã眮æã¢ããåºãã¢ã«ã³ãã·åºãå
ã¯ã·ã¢ãåºã ïœã¯ãïŒåã¯ïŒã®æŽæ°ãè¡šããïŒ æ¬¡ã«æ¬çºæã詳现ã«èª¬æããã æ¬çºæã«äœ¿çšããããã¿ãã·ã¢ãã³ååç©ã¯ã
第ïŒå³ã«ç€ºãããã«Cuk α1.541â«ã®ïŒžç·ã«å¯Ÿã
ããã©ãã°è§åºŠïŒèª€å·®2α0.2床ïŒã7.7ã9.3ã
16.9ã17.6ã22.4ã28.8ã«äž»èŠãªããŒã¯ãæãã
ç·åæã¹ãã¯ãã«ãæãããã®ãã©ãã°è§åºŠ
9.3ã®ããŒã¯ã«å¯Ÿãããã©ãã°è§åºŠ16.9ã®ããŒã¯
ã®åŒ·åºŠæ¯ã0.8ã1.0ã§ãããäžèšãã©ãã°è§åºŠ9.3
ã®ããŒã¯ã«å¯Ÿãããã©ãã°è§åºŠ22.4åã³28.8ã®ã
ãããã®ããŒã¯ã®åŒ·åºŠæ¯ã0.4以äžã§ããã第ïŒ
å³ã«ç€ºãããã«ããã®èµ€å€ç·åžåã¹ãã¯ãã«ã¯
700ã760cm-1ã®éã«720±ïŒcm-1ãæã匷ãïŒæ¬
ã®åžå垯ã1320±ïŒcm-1ã3288±ïŒcm-1ã«ç¹åŸŽç
ãªåžåãæããããã«å¯èŠãè¿èµ€å€ç·åžåã¹ãã¯
ãã«ã®æ¥µå€§ã第ïŒå³ã«ç€ºãããã«ã770nm以äž
790nmæªæºã«ãããã®ã奜ãŸãã䜿çšã§ãããã
ã®ç¡éå±ãã¿ãã·ã¢ãã³ååç©ïŒ¡ã¯ãã®çµæ¶åœ¢ã
å®å®ã§ãã¢ã»ãã³ãããã©ããããã©ã³ããã«ãš
ã³ãé ¢é žãšãã«ãïŒïŒïŒâãžã¯ãããšã¿ã³çã®æ
æ©æº¶å€ã«æµžæŒ¬ããããäŸãã°200âã«50æéæŸçœ®
ããããããã«ã¯ããªã³ã°çã®æ©æ¢°çæªåãå ã
ãŠããã®çµæ¶åœ¢ã®è»¢ç§»ãèµ·ããé£ããæå äœã®ç¹°
ãè¿ã䜿çšã«å¯Ÿããé»äœå®å®æ§çã«ãåªããŠã
ãã奜ãŸããããªãããã¯ææ60幎ïŒæ26æ¥ä»ç¹
èš±é¡ã®æ现æžã«è©³çŽ°ã«èšèŒãããŠãããæ¬çºæã«
䜿çšãããäžèšãã¿ãã·ã¢ãã³ååç©ã¯ãä»ã®ç¡
éå±ãã¿ãã·ã¢ãã³ååç©ãéå±ãã¿ãã·ã¢ãã³
ååç©ãšçµã¿åãããŠäœ¿çšã§ãããŸãããããã®
ããããã®ãã¿ãã·ã¢ãã³ååç©ã«å±ããåæ°å
ã¯è€æ°ã®ãã¿ãã·ã¢ãã³ååç©ãšäœµçšããããšã
ã§ããããããã®äœµçšã§ãããã¿ãã·ã¢ãã³åå
ç©ã«ã¯ãäŸãã°Î±ãβãγãÏãÏâ²ãηãηâ²ã
åç¡éå±ãã¿ãã·ã¢ãã³ååç©åã³Îµåã®ãã¿ã
ã·ã¢ãã³ååç©ãæãããããç¡éå±ãã¿ãã·ã¢
ãã³ååç©ã¯ãæ床ã垯é»å®å®æ§ã«åªããŠãããš
ããç¹é·ãããããããã®ãã¡ã®ç¡éå±ãã¿ãã·
ã¢ãã³ååç©ã®ããã€ãã®ç¹æ§å€ãè¡šïŒã«ç€ºãã ãªãããããã®ç¡éå±ãã¿ãã·ã¢ãã³ååç©ã¯
ç¹å ¬æ49â4338å·å ¬å ±ãç¹éæ60â19154å·å ¬å ±ã
ç¹éæ58â182639å·å ¬å ±ã«è©³çŽ°ã«èšèŒãããŠã
ãã
ãè¡šã
æ¬çºæã«äœ¿çšãããç¡éå±ãã¿ãã·ã¢ãã³åå
ç©ã«äœµçšã§ãããã€ãªã¢çºçç©è³ªãšããŠã¯ãã¢ãŸ
é¡æãã¢ã³ãã©ããã³é¡æãããªã¬ã³é¡æãå€ç°
ããã³é¡æãã¹ã¯ã¢ãªãã¯é žã¡ãã³é¡æçãæã
ãããããããã®å ·äœäŸã«ã€ããŠã¯åŸè¿°ããã æ¬çºæã«äœ¿çšãããç¡éå±ãã¿ãã·ã¢ãã³åå
ç©ãšçµã¿åãããŠäžèšäžè¬åŒãããããã§ç€ºã
ãããã€ãªã¢èŒžéç©è³ªã®å°ãªããšãïŒã€ãçšãã
ãããããã®å ·äœäŸãšããŠã¯äŸãã°æ¬¡ã®ãã®ãæ
ããããã æŽã«ãåèšäžè¬åŒããã§ç€ºãããããã©ãŸã³
ååç©ã®å ·äœäŸãšããŠã¯ãäŸãã°æ¬¡ã®æ§é åŒãæ
ãããã®ãæããããšãã§ãããããããã«éå®
ããããã®ã§ã¯ãªãã æ¬çºæã«äœ¿çšãããç¡éå±ãã¿ãã·ã¢ãã³åå
ç©ãšäœµçšã§ãããã€ãªã¢çºçç©è³ªãšããŠã®ã¢ãŸé¡
æãšããŠã¯ãäŸãã°ä»¥äžã®ãã®ãæããããã (â5) âïŒïŒ®âAr1âCHïŒCHâAr2âïŒ
â (â6) âïŒïŒ®âAr1âCHïŒCHâAr2âïŒ
âAr3âïŒïŒ®â (â8) âïŒïŒ®âAr1âïŒïŒ®âAr2âïŒïŒ®
â (â9) âïŒïŒ®âAr1âïŒïŒ®âAr2âïŒïŒ®
âAr2âïŒïŒ®â ãäœããã®äžè¬åŒäžã Ar1ïŒAr2åã³Ar3ïŒããããã眮æè¥ããã¯æª
眮æã®ççŽ ç°åŒè³éŠæç°åºã R5ïŒR6ïŒR7åã³ïŒR8ïŒãããããé»ååžåŒæ§
åºåã¯æ°ŽçŽ ååã§ãã€ãŠãR5ãR8ã®å°ãª
ããšãïŒã€ã¯ã·ã¢ãåºçã®é»ååžåŒæ§åºã
ç©ã«äœµçšã§ãããã€ãªã¢çºçç©è³ªãšããŠã¯ãã¢ãŸ
é¡æãã¢ã³ãã©ããã³é¡æãããªã¬ã³é¡æãå€ç°
ããã³é¡æãã¹ã¯ã¢ãªãã¯é žã¡ãã³é¡æçãæã
ãããããããã®å ·äœäŸã«ã€ããŠã¯åŸè¿°ããã æ¬çºæã«äœ¿çšãããç¡éå±ãã¿ãã·ã¢ãã³åå
ç©ãšçµã¿åãããŠäžèšäžè¬åŒãããããã§ç€ºã
ãããã€ãªã¢èŒžéç©è³ªã®å°ãªããšãïŒã€ãçšãã
ãããããã®å ·äœäŸãšããŠã¯äŸãã°æ¬¡ã®ãã®ãæ
ããããã æŽã«ãåèšäžè¬åŒããã§ç€ºãããããã©ãŸã³
ååç©ã®å ·äœäŸãšããŠã¯ãäŸãã°æ¬¡ã®æ§é åŒãæ
ãããã®ãæããããšãã§ãããããããã«éå®
ããããã®ã§ã¯ãªãã æ¬çºæã«äœ¿çšãããç¡éå±ãã¿ãã·ã¢ãã³åå
ç©ãšäœµçšã§ãããã€ãªã¢çºçç©è³ªãšããŠã®ã¢ãŸé¡
æãšããŠã¯ãäŸãã°ä»¥äžã®ãã®ãæããããã (â5) âïŒïŒ®âAr1âCHïŒCHâAr2âïŒ
â (â6) âïŒïŒ®âAr1âCHïŒCHâAr2âïŒ
âAr3âïŒïŒ®â (â8) âïŒïŒ®âAr1âïŒïŒ®âAr2âïŒïŒ®
â (â9) âïŒïŒ®âAr1âïŒïŒ®âAr2âïŒïŒ®
âAr2âïŒïŒ®â ãäœããã®äžè¬åŒäžã Ar1ïŒAr2åã³Ar3ïŒããããã眮æè¥ããã¯æª
眮æã®ççŽ ç°åŒè³éŠæç°åºã R5ïŒR6ïŒR7åã³ïŒR8ïŒãããããé»ååžåŒæ§
åºåã¯æ°ŽçŽ ååã§ãã€ãŠãR5ãR8ã®å°ãª
ããšãïŒã€ã¯ã·ã¢ãåºçã®é»ååžåŒæ§åºã
ãåŒã
ïŒïŒžã¯ãããããã·åºã
ãåŒããŸãã¯
ââHSO2âR12
ïŒäœãR10åã³R11ã¯ãããããæ°ŽçŽ åå
åã¯çœ®æè¥ããã¯æªçœ®æã®ã¢ã«ãã«åºã
R12ã¯çœ®æè¥ããã¯æªçœ®æã®ã¢ã«ãã«åºãŸ
ãã¯çœ®æè¥ããã¯æªçœ®æã®ã¢ãªãŒã«åºåº
ïŒã ã¯ãæ°ŽçŽ ååãããã²ã³ååã眮æè¥ããã¯
æªçœ®æã®ã¢ã«ãã«åºãã¢ã«ã³ãã·åºãã«ã«
ããã·ã«åºãã¹ã«ãåºã眮æè¥ããã¯æªçœ®
æã®ã«ã«ãã¢ã€ã«åºãŸãã¯çœ®æè¥ããã¯æª
眮æã®ã¹ã«ãã¢ã¢ã€ã«åºïŒäœãïœãïŒä»¥äž
ã®ãšãã¯ãäºãã«ç°ãªãåºã§ãã€ãŠãã
ããïŒã ã¯ã眮æè¥ããã¯æªçœ®æã®ççŽ ç°åŒè³éŠæç°
ãŸãã¯çœ®æè¥ããã¯æªçœ®æã®è€çŽ ç°åŒè³éŠ
æç°ãæ§æããã«å¿ èŠãªåå矀ã R9ã¯ãæ°ŽçŽ ååã眮æè¥ããã¯æªçœ®æã®ã¢ã
ãåºã眮æè¥ããã¯æªçœ®æã®ã«ã«ãã¢ã€ã«
åºãã«ã«ããã·ã«åºãŸãã¯ãã®ãšã¹ãã«
åºã Aâ²ã¯ã眮æè¥ããã¯æªçœ®æã®ã¢ãªãŒã«åºã ïœã¯ãïŒãŸãã¯ïŒã®æŽæ°ã ïœã¯ãïŒãïŒã®æŽæ°ã§ãããïŒã ãŸããå€ç°ããã³é¡æãšããŠã¯æ¬¡ã®äžè¬åŒ
ããã®ååç©ãæããããã äžè¬åŒãã ïŒãã®äžè¬åŒäžãXâ²ã¯ããã²ã³ååãããã
åºãã·ã¢ãåºãã¢ã·ã«åºåã¯ã«ã«ããã·ã«åºãè¡š
ããïœã¯ïŒãïŒã®æŽæ°ãè¡šããïŒ å ·äœäŸã¯æ¬¡ã®éãã§ããã æ¬çºæã®é»ååççšæå äœã®æå å±€ãæ§æãã
ããã«ã¯ããã€ãªã¢çºçç©è³ªãšãã€ãªã¢èŒžéç©è³ª
ãšãçµã¿åãããç©å±€åè¥ããã¯åæ£åã®ããã
ãæ©èœåé¢åæå å±€ãèšããããã®å Žåéåžžã¯ç¬¬
ïŒå³ã第ïŒå³ã®ããã«ãããããªãã¡ã第ïŒå³ã«
瀺ãå±€æ§æã¯ãå°é»æ§æ¯æäœïŒäžã«ç¡éå±ãã¿ã
ã·ã¢ãã³ååç©ãå«ããã€ãªã¢çºçå±€ïŒã圢æ
ããããã«äžèšãã€ãªã¢èŒžéç©è³ªãå«æãããã€
ãªã¢èŒžéå±€ïŒãç©å±€ããŠæå å±€ïŒã圢æãããã®
ã§ããã第ïŒå³ã¯ãããã®ãã€ãªã¢çºçå±€ïŒãšã
ã€ãªã¢èŒžéå±€ïŒãéã«ããæå å±€ïŒâ²ã圢æãã
ãã®ã§ããã第ïŒå³ã®å±€æ§æã¯ç¬¬ïŒå³ã®å±€æ§æã®
æå å±€ïŒãšå°é»æ§æ¯æäœïŒã®éã«äžéå±€ïŒãèš
ãã第ïŒå³ã¯ç¬¬ïŒå³ã®å±€æ§æã®æå å±€ïŒâ²ãšå°é»
æ§æ¯æäœïŒãšã®éã«äžéå±€ïŒãèšããããããå°
é»æ§æ¯æäœïŒã®ããªãŒãšã¬ã¯ããã³ã®æ³šå ¥ãé²æ¢
ããããã«ãããã®ã§ããã第ïŒå³ã第ïŒå³ã«ç€º
ããå±€æ§æã¯æ£åž¯é»çšæå äœãšããŠå¥œé©ã«çšãã
ãããã®å Žåãã€ãªã¢çºçå±€ïŒäžã«ãã€ãªã¢çºç
ç©è³ªãšãšãã«ãã€ãªã¢èŒžéç©è³ªãå«æããŠãè¯
ãã第ïŒå³ã®å±€æ§æã¯ç¡éå±ãã¿ãã·ã¢ãã³åå
ç©ãå«æãããã€ãªã¢çºçç©è³ªïŒãšãããšçµã¿å
ãããããã€ãªã¢èŒžéç©è³ªïŒãå«æããæå å±€
ïŒâ³ã圢æãããã®ã§ããã第ïŒå³ã®å±€æ§æã¯ã
ã®æå å±€ïŒâ³ãšå°é»æ§æ¯æäœïŒãšã®éã«äžèšã®äž
éå±€ïŒãèšãããã®ã§ããã äºå±€æ§æã®æå å±€ã圢æããå Žåã«ããããã€
ãªã¢çºçå±€ïŒã¯ã次ã®åŠãæ¹æ³ã«ãã€ãŠèšããã
ãšãã§ããã (ã€) ãã€ãªã¢çºçç©è³ªãé©åœãªæº¶å€ã«æº¶è§£ãã溶
液ãããã¯ããã«ãã€ã³ããŒãå ããŠæ··å溶解
ãã溶液ãå¡åžããæ¹æ³ã (ã) ãã€ãªã¢çºçç©è³ªãããŒã«ãã«ããã¢ãããµ
ãŒçã«ãã€ãŠåæ£åªäžã§åŸ®çŽ°ç²åãšããå¿ èŠã«
å¿ããŠãã€ã³ããŒãå ããŠæ··ååæ£ããŠåŸãã
ãåæ£æ¶²ãå¡åžããæ¹æ³ã ãããã®æ¹æ³ã«ãããŠè¶ é³æ³¢ã®äœçšäžã«ç²åã
åæ£ããããšãåäžåæ£ãå¯èœã«ãªãã ãã€ãªã¢çºçå±€ã®åœ¢æã«äœ¿çšããã溶å€ããã
ã¯åæ£åªãšããŠã¯ãïœâããã«ã¢ãã³ããžãšãã«
ã¢ãã³ããšãã¬ã³ãžã¢ãã³ãã€ãœãããããŒã«ã¢
ãã³ãããªãšã¿ããŒã«ã¢ãã³ãããªãšãã¬ã³ãžã¢
ãã³ãïŒïŒ®âãžã¡ãã«ãã«ã ã¢ãããã¢ã»ã
ã³ãã¡ãã«ãšãã«ã±ãã³ãã·ã¯ããããµãã³ãã
ã³ãŒã³ããã«ãšã³ããã·ã¬ã³ãã¯ãããã«ã ã
ïŒïŒïŒâãžã¯ãããšã¿ã³ããžã¯ããã¡ã¿ã³ããã
ã©ããããã©ã³ããžãªããµã³ãã¡ã¿ããŒã«ããšã¿
ããŒã«ãã€ãœãããããŒã«ãé ¢é žãšãã«ãé ¢é žã
ãã«ããžã¡ãã«ã¹ã«ããã·ãçãæããããšãã§
ããã ãã€ãªã¢çºçå±€è¥ããã¯ãã€ãªã¢èŒžéå±€ã®åœ¢æ
ã«ãã€ã³ããŒãçšããå Žåã«ããã®ãã€ã³ããŒãš
ããŠã¯ä»»æã®ãã®ãçšããããšãã§ããããç¹ã«
çæ°Žæ§ã§ãã€èªé»çãé«ãé»æ°çµ¶çžæ§ã®ãã€ã«ã
圢æèœãæããé«ååéåäœã奜ãŸãããããã
ãéåäœãšããŠã¯ãäŸãã°æ¬¡ã®ãã®ãæããããš
ãã§ããããå¿è«ãããã«éå®ããããã®ã§ã¯ãª
ãã ïœ ãããªã«ãŒãããŒã ïœ ããªãšã¹ãã« ïœ ã¡ã¿ã¯ãªã«æš¹è ïœ ã¢ã¯ãªã«æš¹è ïœ ããªå¡©åããã« ïœ ããªå¡©åãããªãã³ ïœ ããªã¹ãã¬ã³ ïœ ããªããã«ã¢ã»ããŒã ïœ ã¹ãã¬ã³âãã¿ãžãšã³å ±éåäœ ïœ å¡©åãããªãã³âã¢ã¯ãªããããªã«å ±éå
äœ ïœ å¡©åããã«âé ¢é žããã«å ±éåäœ ïœ å¡©åããã«âé ¢é žããã«âç¡æ°Žãã¬ã€ã³é ž
å ±éåäœ ïœ ã·ãªã³ã³æš¹è ïœ ã·ãªã³ã³âã¢ã«ãããæš¹è ïœ ããšããŒã«âãã«ã ã¢ã«ãããæš¹è ïœ ã¹ãã¬ã³âã¢ã«ãããæš¹è ïœ ããªââããã«ã«ã«ããŸãŒã« ïœ ããªããã«ããã©ãŒã« ãããã®ãã€ã³ããŒã¯ãåç¬ãããã¯ïŒçš®ä»¥äž
ã®æ··åç©ãšããŠçšããããšãã§ããããŸããã€ã³
ããŒã«å¯Ÿãããã€ãªã¢çºçç©è³ªã®å²åã¯10ã600
ééïŒ ã奜ãŸããã¯50ã400ééïŒ ããã€ãªã¢èŒž
éç©è³ªã¯10ã500ééïŒ ãšããã®ãè¯ãã ãã®ããã«ããŠåœ¢æããããã€ãªã¢çºçå±€ïŒã®
åãã¯0.01ã20ÎŒmã§ããããšã奜ãŸããããã
ãã«å¥œãŸããã¯0.05ã5ÎŒmã§ããããã€ãªã¢èŒžé
å±€ã®åã¿ã¯ïŒã100ÎŒmã奜ãŸããã¯ïŒã30ÎŒmã§
ããã äžèšãã€ãªã¢çºçç©è³ªãåæ£ããããŠæå å±€ã
圢æããå Žåã«ãããŠã¯ãåœè©²ãã€ãªã¢çºçç©è³ª
ã¯2ÎŒm以äžã奜ãŸããã¯1ÎŒm以äžã®å¹³åç²åŸã®ç²
ç²äœãšãããã®ã奜ãŸãããããªãã¡ãç²åŸãäœ
ã倧ãããšå±€äžãžã®åæ£ãæªããªããšãšãã«ãç²
åãè¡šé¢ã«äžéšçªåºããŠè¡šé¢ã®å¹³æ»æ§ãæªããª
ããå Žåã«ãã€ãŠã¯ç²åã®çªåºéšåã§æŸé»ãçã
ããããããã¯ããã«ãããŒç²åãä»çããŠãã
ãŒãã€ã«ãã³ã°çŸè±¡ãçãæãããã€ãªã¢çºçç©
質ãšããŠé·æ³¢é·å ïŒã700nmïŒã«å¯ŸããŠæ床ãæ
ãããã®ã¯ããã€ãªã¢çºçç©è³ªã®äžã§ã®ç±å±èµ·ã
ã€ãªã¢ã®çºçã«ããè¡šé¢é»è·ãäžåããããã€ãª
ã¢çºçç©è³ªã®ç²åŸã倧ãããšãã®äžåå¹æã倧ã
ããšæãããã ããã«ãäžèšæå å±€ã«ã¯æ床ã®åäžãæ®çé»äœ
ä¹è³å埩䜿çšæã®ç²åŽäœæžçãç®çãšããŠãäžçš®
åã¯äºçš®ä»¥äžã®é»åå容ç©è³ªãå«æããããããš
ãã§ãããããã«çšããããšã®ã§ããé»åå容æ§
ç©è³ªãšããŠã¯ãäŸãã°ç¡æ°Žã³ãã¯é žãç¡æ°Žãã¬ã€
ã³é žããžããã ç¡æ°Žã³ãã¯é žãç¡æ°Žãã¿ã«é žãã
ãã©ã¯ãã«ç¡æ°Žãã¿ã«é žãããã©ããã ç¡æ°Žãã¿
ã«é žãïŒâãããç¡æ°Žãã¿ã«é žãïŒâãããç¡æ°Ž
ãã¿ã«é žãç¡æ°Žããã¡ãªããé žãç¡æ°Žã¡ãªãã
é žãããã©ã·ã¢ããšãã¬ã³ãããã©ã·ã¢ããããž
ã¡ã¿ã³ãïœâãžããããã³ãŒã³ãïœâãžãããã
ã³ãŒã³ãïŒïŒïŒïŒïŒâããªããããã³ãŒã³ããã©
ããããã³ãŸãããªã«ããã¯ãªã«ã¯ãã©ã€ããã
ãã³ã¯ãã«ã€ãããã¯ãã©ãã«ããã«ããã«ããž
ã¯ãããžã·ã¢ããã©ãã³ãŸããã³ãã¢ã³ãã©ãã
ã³ããžãããã¢ã³ãã©ããã³ãïŒâãã«ãªã¬ããª
ãã³ããžã·ã¢ãã¡ãã¬ã³ããããžãããªã«ããã
ãªãããâïŒâãã«ãªã¬ããªãã³âããžã·ã¢ãã¡
ãã¬ã³ããããžãããªã«ãããã¯ãªã³é žãïœâã
ããå®æ¯éŠé žãïœâãããå®æ¯éŠé žãïŒïŒïŒâãž
ãããå®æ¯éŠé žããã³ã¿ãã«ãªãå®æ¯éŠé žãïŒâ
ããããµã«ãã«é žãïŒïŒïŒâãžããããµãªãã«
é žããã¿ã«é žãã¡ãªããé žããã®ä»ã®é»å芪åå
ã®å€§ããååç©ãæããããšãã§ããããŸããé»
åå容æ§ç©è³ªã®æ·»å å²åã¯ãééæ¯ã§ãã€ãªã€çº
çç©è³ªïŒé»åå容ç©è³ªã¯100ïŒ0.01ã200ã奜ãŸã
ãã¯100ïŒ0.1ã100ã§ããã ãªããäžèšã®æå å±€ãèšããã¹ãæ¯æäœïŒã¯é
å±æ¿ãéå±ãã©ã åã¯å°é»æ§ããªããŒãé žåã€ã³
ãžãŠã çã®å°é»æ§ååç©è¥ããã¯ã¢ã«ãããŠãŒ
ã ããã©ãžãŠã ãéçã®éå±ãããªãå°é»æ§èå±€
ãå¡åžãèžçãã©ãããŒãçã®æ段ã«ãããçŽã
ãã©ã¹ããã¯ãã€ã«ã çã®åºäœã«èšããŠæããã®
ãçšãããããæ¥çå±€ãããã¯ããªã€ãŒå±€çãšã
ãŠæ©èœããäžéå±€ãšããŠã¯ãäžèšã®ãã€ã³ããŒæš¹
èãšããŠèª¬æãããããªé«ååéåäœãããªãã
ã«ã¢ã«ã³ãŒã«ããšãã«ã»ã«ããŒãºãã«ã«ããã·ã¡
ãã«ã»ã«ããŒãºãªã©ã®ææ©é«ååç©è³ªåã¯é žåã¢
ã«ãããŠãŒã ãªã©ããæããã®ãçšããããã çºæã®å¹æ æ¬çºæã¯ã以äžèª¬æããããã«ãäžèšã®ãã©ã
ã°è§22.4ã28.8ã«ç¹ç°ããŒã¯ãæããåŸæ¥ã«ãªã
æ°èŠãªç¡éå±ãã¿ãã·ã¢ãã³ååç©ããã€ãªã¢çº
çç©è³ªã«çšããäžèšã®ããã©ãŸã³ååç©ããã€ãª
ã¢èŒžéç©è³ªã«çšããã®ã§ãåŸæ¥ã®ç¡éå±ãã¿ãã·
ã¢ãã³ååç©ãšããã©ãŸã³ååç©ãšãçµã¿åãã
ãŠåŸãããæå äœããã¯é¡èã«åªããé«æ床ãæ
ã€ããšãã§ãããšãšãã«ãç¹°ãè¿ã䜿çšæã®é»äœ
ã®å±¥æŽãå°ãªããæ®çé»äœã®å€åãé¡èã«å°ãã
ããããšãã§ããããæå äœç¹æ§ãå®å®ã«ç¶æã§
ããããŸãããã¿ãã·ã¢ãã³ååç©ã®ç±åã³å å®
å®æ§ã®ç¹æ§ã掻ãããé»ååçæå äœãæäŸã§ã
ãããããã«ãããç¹ã«é·æ³¢é·å ãã¬ãŒã¶ãŒå ã«
察ããåŸæ¥ã«ãªãåªããé»ååçæå äœãæäŸã§
ããã å®æœäŸ 以äžã«å®æœäŸã説æããããããã«å ç«ã€ãŠç¬¬
ïŒå³ãªãã第ïŒå³ã«ç€ºãç¹æ§ããã€ç¡éå±ãã¿ã
ã·ã¢ãã³ååç©ïŒ¡ã®åæäŸåã³Ïåç¡éå±ãã¿ã
ã·ã¢ãã³ååç©ã®åæäŸã瀺ãã åæäŸ ïŒ ãªããŠã ãã¿ãã·ã¢ãã³50ïœãïŒâã«ãããŠå
åæ¹æããæ¿ç¡«é žã®600mlã«å ããã次ãã§ãã®
æ··åç©ã¯ãã®æž©åºŠã«ãããŠïŒæéæ¹æãããã次
ãã§ã§ãã溶液ã¯ç²ãçŒçµãããã¬ã©ã¹æ¿Ÿæãé
ããŠæ¿ŸéãããŠãïŒãªããã«ã®æ°·ãšæ°Žã®äžãžæ¹æ
ããªããåŸã ã«æ³šå ¥ããããæ°æéæŸçœ®ããåŸ
ã«ããã®æ··åç©ã¯æ¿ŸéãããåŸãããå¡ãã¯äžæ§
ã«ãªããŸã§æ°Žã§æŽæµããããã€ãã§ãã®å¡ã¯æçµ
çã«ã¡ã¿ããŒã«ã§æ°åæŽæµãããã€ç©ºæ°äžã§ä¹Ÿç¥
ãããããããã®ä¹Ÿç¥ãããç²æ«ã¯24æéé£ç¶æœ
åºè£ 眮äžã§ã¢ã»ãã³ã«ãã€ãŠæœåºãããã€ç©ºæ°äž
ã§ä¹Ÿç¥ãããããŠéãç²æ«ãšãªãã äžèšã«ãããŠãªããŠã ã«å¯ŸããŠå¡©ã®æ®æž£ãä¿èšŒ
ããããã«æåºã¯å埩ãããããã®ããã«ããŠ
30.5ïœã®éãç²æ«ãåŸãããããã®åŸããããã®
ã¯ããã®ïŒžç·åæå³åœ¢ããã§ã«åºçãããŠããè³
æã«èšèŒãããŠããαåãã¿ãã·ã¢ãã³ååç©ã®
ç·åæå³åœ¢ãšäžèŽããŠããã ãã®ããã«ããŠåŸãããéå±ãå«ãŸãªãαåã
ã¿ãã·ã¢ãã³ååç©30ïœãçŽåŸ13/16ã€ã³ãã®ã
ãŒã«ã§ååæºããããå 容ç©900mlã®ç£è£œããŒã«
ãã«äžã«ä»èŸŒã¿ãçŽ80rpmã§164æéããªã³ã°ã
ãããã®åŸããã©ããããã©ã³ãïŒïŒïŒâãžã¯ã
ããšã¿ã³çã®ææ©æº¶å€200mlãããŒã«ãã«äžã«å
ãã24æéå床ããªã³ã°ããããã®ããªã³ã°ãã
åŸã®åæ£æ¶²ã«ã€ããŠææ©æº¶å€ã®é€å»åã³ä¹Ÿç¥ãè¡
ãªããç¡éå±ãã¿ãã·ã¢ãã³ååç©A28.2ïœãåŸ
ãã åæäŸ ïŒ Î±åç¡éå±ãã¿ãã·ã¢ãã³ååç©ïŒICI補ã¢ã
ã©ã€ããã¢ãŒã¹ããã«GSïŒãå ç±ãããžã¡ãã«
ãã«ã ã¢ã«ãããã«ããïŒåæœåºããŠç²Ÿè£œããã
ãã®æäœã«ãã粟補ç©ã¯Î²åã«è»¢ç§»ããã次ã«ã
ã®Î²åç¡éå±ãã¿ãã·ã¢ãã³ååç©ã®ïŒéšåãæ¿
ç¡«é žã«æº¶è§£ãããã®æº¶æ¶²ãæ°·æ°Žäžã«æ³šãã§åæ²æŸ±
ãããããšã«ãããαåã«è»¢ç§»ãããããã®åæ²
柱ç©ãã¢ã³ã¢ãã¢æ°Žãã¡ã¿ããŒã«çã§æŽæµåŸ10â
ã§ä¹Ÿç¥ããã次ã«äžèšã«ãã粟補ããαåç¡éå±
ãã¿ãã·ã¢ãã³ååç©ã磚ç å©å€åã³åæ£å€ãšãš
ãã«ãµã³ããã«ã«å ¥ãã枩床100±20âã§15ã25
æéæ··ç·Žããããã®æäœã«ããçµæ¶åœ¢ãÏåã«è»¢
移ããã®ã確èªåŸã容åšããåãåºããæ°Žåã³ã¡
ã¿ããŒã«çã§ç£šç å©å€åã³åæ£å€ãååé€ããåŸ
也ç¥ããŠé®®æãªéå³ã垯ã³ãÏåç¡éå±ãã¿ãã·
ã¢ãã³ã®éè²çµæ¶ãåŸãã å®æœäŸ ïŒ ã¢ã«ãããŠãŒã ãèžçããããªãšã¹ãã«ãã€ã«
ã ãããªãå°é»æ§æ¯æäœäžã«åæäŸïŒã§åŸããã
ç¡éå±ãã¿ãã·ã¢ãã³ååç©1.0ïœãšããªã¡ãã«
ã¡ã¿ã¯ãªã¬ãŒãïŒãšã«ããµã€ãâ2010ãããŠãã³
瀟補ïŒ2.0ïœãïŒïŒïŒâãžã¯ãããšã¿ã³100mlã«å
ããŠè¶ é³æ³¢åæ£ã«ããåæ£ããããã®åæ£æ¶²ã也
ç¥ããåŸã®èåã0.5ÎŒmãšãªãããã«å¡åžä¹Ÿç¥ã
ãŠãã€ãªã¢çºçå±€ã圢æããã ããã«ãã®äžã«è¡šïŒã«ç€ºããäžèšäŸç€ºâ14ã®
ãã€ãªã¢èŒžéç©è³ª12.4ïœãšããªã«ãŒãããŒãïŒã
ã³ã©ã€ãâ1250ãåžäººåæ瀟補ïŒ16.5ïœãšã
ïŒïŒïŒâãžã¯ãããšã¿ã³100mlã«æº¶è§£ãã溶液ã
也ç¥åŸã®èåã12ÎŒmãšãªãããã«å¡åžä¹Ÿç¥ããŠ
ãã€ãªã€èŒžéå±€ã圢æããé»ååçæå äœãåŸ
ãã å®æœäŸïŒãïŒãæ¯èŒäŸïŒãïŒ å®æœäŸïŒã«ãããŠè¡šïŒã®æ¬ã®ç©è³ªã®ä»£ããã«å®
æœäŸïŒãïŒãæ¯èŒäŸïŒãïŒã®ããããã«è©²åœãã
æ¬ã«èšèŒãããŠããç©è³ªãçšãã以å€ã¯åæ§ã«ã
ãŠããããå®æœäŸïŒãïŒãæ¯èŒäŸïŒãïŒã®é»åå
çæå äœãåŸãã æ¯èŒäŸ ïŒãïŒ å®æœäŸïŒã«ãããŠãã€ãªã¢èŒžéç©è³ªãšããŠæ¯èŒ
äŸïŒãïŒã«è©²åœããæ¬ã«èšèŒãããŠããç©è³ªãçš
ãã以å€ã¯åæ§ã«ããŠæ¯èŒäŸïŒãïŒã®é»ååçæ
å äœãåŸãã æ¯èŒäŸ ïŒãïŒ å®æœäŸïŒã«ãããŠåæäŸïŒã®Ïåãã¿ãã·ã¢ã
ã³ååç©ãçšããæ¯èŒäŸïŒãïŒã®ããããã®æ¬ã«
èšèŒããããã€ãªã¢èŒžéç©è³ªãçšãã以å€ã¯åæ§
ã«ããŠæ¯èŒäŸïŒãïŒã®é»ååçæå äœãåŸãã è©äŸ¡è©Šéš 以äžã®ããã«ããŠåŸãããé»ååçæå äœã®
åã ã«ã€ããŠãããšã¬ã¯ããã¡ãŒã¿ãŒSP428åã
ïŒå·å£é»æ°è£œäœæ補ïŒãçšããŠããã®é»ååçç¹
æ§ã調ã¹ããããªãã¡ãæå äœè¡šé¢ã垯é»é»å§â
6KVã§ïŒç§é垯é»ãããæã®å容é»äœVA(V)ãšã
ïŒç§éææžè¡°ãããåŸã®é»äœV1ïŒåæé»äœïŒã1/
ïŒã«æžè¡°ãããããã«å¿ èŠãªé²å é1/2ïŒLuxã»
ç§ïŒïŒã¿ã³ã°ã¹ãã³å æºã䜿çšïŒãšãææžè¡°ç
ïŒVAâV1ïŒïŒV1Ã100ïŒ åã³10ïŒLuxã»secïŒé²å
åŸã®æ®çé»äœVR(V)ã枬å®ããã 次ã«åæ§ã®æž¬å®ç³»ã«ãããŠå æºã«ã¿ã³ã°ã¹ãã³
å æºãçšããã¢ãã¯ãã¡ãŒã¿ãéããŠãç¹ã«åé¡
ãšããæ³¢é·780nm±1nmã®å ã«å¯Ÿããåæžé²å é
E1/2ïŒÎ»ïŒ780ïŒïŒergïŒcm2ïŒã枬å®ããããŸããäž
èšå容é»äœVA(V)ãšæ®çé»äœã«ã€ããŠã¯äžäžåã³
ããŒåŸã«ã€ããŠã枬å®ããã ãããã®çµæã«ã€ããŠè¡šïŒã«ç€ºããè¡šäžÎVAã
ÎVRã¯ããããã®åæç¹æ§å€ããäžäžæã³ããŒåŸ
ã®ç¹æ§å€ãåŒããå€ã§ããã
åã¯çœ®æè¥ããã¯æªçœ®æã®ã¢ã«ãã«åºã
R12ã¯çœ®æè¥ããã¯æªçœ®æã®ã¢ã«ãã«åºãŸ
ãã¯çœ®æè¥ããã¯æªçœ®æã®ã¢ãªãŒã«åºåº
ïŒã ã¯ãæ°ŽçŽ ååãããã²ã³ååã眮æè¥ããã¯
æªçœ®æã®ã¢ã«ãã«åºãã¢ã«ã³ãã·åºãã«ã«
ããã·ã«åºãã¹ã«ãåºã眮æè¥ããã¯æªçœ®
æã®ã«ã«ãã¢ã€ã«åºãŸãã¯çœ®æè¥ããã¯æª
眮æã®ã¹ã«ãã¢ã¢ã€ã«åºïŒäœãïœãïŒä»¥äž
ã®ãšãã¯ãäºãã«ç°ãªãåºã§ãã€ãŠãã
ããïŒã ã¯ã眮æè¥ããã¯æªçœ®æã®ççŽ ç°åŒè³éŠæç°
ãŸãã¯çœ®æè¥ããã¯æªçœ®æã®è€çŽ ç°åŒè³éŠ
æç°ãæ§æããã«å¿ èŠãªåå矀ã R9ã¯ãæ°ŽçŽ ååã眮æè¥ããã¯æªçœ®æã®ã¢ã
ãåºã眮æè¥ããã¯æªçœ®æã®ã«ã«ãã¢ã€ã«
åºãã«ã«ããã·ã«åºãŸãã¯ãã®ãšã¹ãã«
åºã Aâ²ã¯ã眮æè¥ããã¯æªçœ®æã®ã¢ãªãŒã«åºã ïœã¯ãïŒãŸãã¯ïŒã®æŽæ°ã ïœã¯ãïŒãïŒã®æŽæ°ã§ãããïŒã ãŸããå€ç°ããã³é¡æãšããŠã¯æ¬¡ã®äžè¬åŒ
ããã®ååç©ãæããããã äžè¬åŒãã ïŒãã®äžè¬åŒäžãXâ²ã¯ããã²ã³ååãããã
åºãã·ã¢ãåºãã¢ã·ã«åºåã¯ã«ã«ããã·ã«åºãè¡š
ããïœã¯ïŒãïŒã®æŽæ°ãè¡šããïŒ å ·äœäŸã¯æ¬¡ã®éãã§ããã æ¬çºæã®é»ååççšæå äœã®æå å±€ãæ§æãã
ããã«ã¯ããã€ãªã¢çºçç©è³ªãšãã€ãªã¢èŒžéç©è³ª
ãšãçµã¿åãããç©å±€åè¥ããã¯åæ£åã®ããã
ãæ©èœåé¢åæå å±€ãèšããããã®å Žåéåžžã¯ç¬¬
ïŒå³ã第ïŒå³ã®ããã«ãããããªãã¡ã第ïŒå³ã«
瀺ãå±€æ§æã¯ãå°é»æ§æ¯æäœïŒäžã«ç¡éå±ãã¿ã
ã·ã¢ãã³ååç©ãå«ããã€ãªã¢çºçå±€ïŒã圢æ
ããããã«äžèšãã€ãªã¢èŒžéç©è³ªãå«æãããã€
ãªã¢èŒžéå±€ïŒãç©å±€ããŠæå å±€ïŒã圢æãããã®
ã§ããã第ïŒå³ã¯ãããã®ãã€ãªã¢çºçå±€ïŒãšã
ã€ãªã¢èŒžéå±€ïŒãéã«ããæå å±€ïŒâ²ã圢æãã
ãã®ã§ããã第ïŒå³ã®å±€æ§æã¯ç¬¬ïŒå³ã®å±€æ§æã®
æå å±€ïŒãšå°é»æ§æ¯æäœïŒã®éã«äžéå±€ïŒãèš
ãã第ïŒå³ã¯ç¬¬ïŒå³ã®å±€æ§æã®æå å±€ïŒâ²ãšå°é»
æ§æ¯æäœïŒãšã®éã«äžéå±€ïŒãèšããããããå°
é»æ§æ¯æäœïŒã®ããªãŒãšã¬ã¯ããã³ã®æ³šå ¥ãé²æ¢
ããããã«ãããã®ã§ããã第ïŒå³ã第ïŒå³ã«ç€º
ããå±€æ§æã¯æ£åž¯é»çšæå äœãšããŠå¥œé©ã«çšãã
ãããã®å Žåãã€ãªã¢çºçå±€ïŒäžã«ãã€ãªã¢çºç
ç©è³ªãšãšãã«ãã€ãªã¢èŒžéç©è³ªãå«æããŠãè¯
ãã第ïŒå³ã®å±€æ§æã¯ç¡éå±ãã¿ãã·ã¢ãã³åå
ç©ãå«æãããã€ãªã¢çºçç©è³ªïŒãšãããšçµã¿å
ãããããã€ãªã¢èŒžéç©è³ªïŒãå«æããæå å±€
ïŒâ³ã圢æãããã®ã§ããã第ïŒå³ã®å±€æ§æã¯ã
ã®æå å±€ïŒâ³ãšå°é»æ§æ¯æäœïŒãšã®éã«äžèšã®äž
éå±€ïŒãèšãããã®ã§ããã äºå±€æ§æã®æå å±€ã圢æããå Žåã«ããããã€
ãªã¢çºçå±€ïŒã¯ã次ã®åŠãæ¹æ³ã«ãã€ãŠèšããã
ãšãã§ããã (ã€) ãã€ãªã¢çºçç©è³ªãé©åœãªæº¶å€ã«æº¶è§£ãã溶
液ãããã¯ããã«ãã€ã³ããŒãå ããŠæ··å溶解
ãã溶液ãå¡åžããæ¹æ³ã (ã) ãã€ãªã¢çºçç©è³ªãããŒã«ãã«ããã¢ãããµ
ãŒçã«ãã€ãŠåæ£åªäžã§åŸ®çŽ°ç²åãšããå¿ èŠã«
å¿ããŠãã€ã³ããŒãå ããŠæ··ååæ£ããŠåŸãã
ãåæ£æ¶²ãå¡åžããæ¹æ³ã ãããã®æ¹æ³ã«ãããŠè¶ é³æ³¢ã®äœçšäžã«ç²åã
åæ£ããããšãåäžåæ£ãå¯èœã«ãªãã ãã€ãªã¢çºçå±€ã®åœ¢æã«äœ¿çšããã溶å€ããã
ã¯åæ£åªãšããŠã¯ãïœâããã«ã¢ãã³ããžãšãã«
ã¢ãã³ããšãã¬ã³ãžã¢ãã³ãã€ãœãããããŒã«ã¢
ãã³ãããªãšã¿ããŒã«ã¢ãã³ãããªãšãã¬ã³ãžã¢
ãã³ãïŒïŒ®âãžã¡ãã«ãã«ã ã¢ãããã¢ã»ã
ã³ãã¡ãã«ãšãã«ã±ãã³ãã·ã¯ããããµãã³ãã
ã³ãŒã³ããã«ãšã³ããã·ã¬ã³ãã¯ãããã«ã ã
ïŒïŒïŒâãžã¯ãããšã¿ã³ããžã¯ããã¡ã¿ã³ããã
ã©ããããã©ã³ããžãªããµã³ãã¡ã¿ããŒã«ããšã¿
ããŒã«ãã€ãœãããããŒã«ãé ¢é žãšãã«ãé ¢é žã
ãã«ããžã¡ãã«ã¹ã«ããã·ãçãæããããšãã§
ããã ãã€ãªã¢çºçå±€è¥ããã¯ãã€ãªã¢èŒžéå±€ã®åœ¢æ
ã«ãã€ã³ããŒãçšããå Žåã«ããã®ãã€ã³ããŒãš
ããŠã¯ä»»æã®ãã®ãçšããããšãã§ããããç¹ã«
çæ°Žæ§ã§ãã€èªé»çãé«ãé»æ°çµ¶çžæ§ã®ãã€ã«ã
圢æèœãæããé«ååéåäœã奜ãŸãããããã
ãéåäœãšããŠã¯ãäŸãã°æ¬¡ã®ãã®ãæããããš
ãã§ããããå¿è«ãããã«éå®ããããã®ã§ã¯ãª
ãã ïœ ãããªã«ãŒãããŒã ïœ ããªãšã¹ãã« ïœ ã¡ã¿ã¯ãªã«æš¹è ïœ ã¢ã¯ãªã«æš¹è ïœ ããªå¡©åããã« ïœ ããªå¡©åãããªãã³ ïœ ããªã¹ãã¬ã³ ïœ ããªããã«ã¢ã»ããŒã ïœ ã¹ãã¬ã³âãã¿ãžãšã³å ±éåäœ ïœ å¡©åãããªãã³âã¢ã¯ãªããããªã«å ±éå
äœ ïœ å¡©åããã«âé ¢é žããã«å ±éåäœ ïœ å¡©åããã«âé ¢é žããã«âç¡æ°Žãã¬ã€ã³é ž
å ±éåäœ ïœ ã·ãªã³ã³æš¹è ïœ ã·ãªã³ã³âã¢ã«ãããæš¹è ïœ ããšããŒã«âãã«ã ã¢ã«ãããæš¹è ïœ ã¹ãã¬ã³âã¢ã«ãããæš¹è ïœ ããªââããã«ã«ã«ããŸãŒã« ïœ ããªããã«ããã©ãŒã« ãããã®ãã€ã³ããŒã¯ãåç¬ãããã¯ïŒçš®ä»¥äž
ã®æ··åç©ãšããŠçšããããšãã§ããããŸããã€ã³
ããŒã«å¯Ÿãããã€ãªã¢çºçç©è³ªã®å²åã¯10ã600
ééïŒ ã奜ãŸããã¯50ã400ééïŒ ããã€ãªã¢èŒž
éç©è³ªã¯10ã500ééïŒ ãšããã®ãè¯ãã ãã®ããã«ããŠåœ¢æããããã€ãªã¢çºçå±€ïŒã®
åãã¯0.01ã20ÎŒmã§ããããšã奜ãŸããããã
ãã«å¥œãŸããã¯0.05ã5ÎŒmã§ããããã€ãªã¢èŒžé
å±€ã®åã¿ã¯ïŒã100ÎŒmã奜ãŸããã¯ïŒã30ÎŒmã§
ããã äžèšãã€ãªã¢çºçç©è³ªãåæ£ããããŠæå å±€ã
圢æããå Žåã«ãããŠã¯ãåœè©²ãã€ãªã¢çºçç©è³ª
ã¯2ÎŒm以äžã奜ãŸããã¯1ÎŒm以äžã®å¹³åç²åŸã®ç²
ç²äœãšãããã®ã奜ãŸãããããªãã¡ãç²åŸãäœ
ã倧ãããšå±€äžãžã®åæ£ãæªããªããšãšãã«ãç²
åãè¡šé¢ã«äžéšçªåºããŠè¡šé¢ã®å¹³æ»æ§ãæªããª
ããå Žåã«ãã€ãŠã¯ç²åã®çªåºéšåã§æŸé»ãçã
ããããããã¯ããã«ãããŒç²åãä»çããŠãã
ãŒãã€ã«ãã³ã°çŸè±¡ãçãæãããã€ãªã¢çºçç©
質ãšããŠé·æ³¢é·å ïŒã700nmïŒã«å¯ŸããŠæ床ãæ
ãããã®ã¯ããã€ãªã¢çºçç©è³ªã®äžã§ã®ç±å±èµ·ã
ã€ãªã¢ã®çºçã«ããè¡šé¢é»è·ãäžåããããã€ãª
ã¢çºçç©è³ªã®ç²åŸã倧ãããšãã®äžåå¹æã倧ã
ããšæãããã ããã«ãäžèšæå å±€ã«ã¯æ床ã®åäžãæ®çé»äœ
ä¹è³å埩䜿çšæã®ç²åŽäœæžçãç®çãšããŠãäžçš®
åã¯äºçš®ä»¥äžã®é»åå容ç©è³ªãå«æããããããš
ãã§ãããããã«çšããããšã®ã§ããé»åå容æ§
ç©è³ªãšããŠã¯ãäŸãã°ç¡æ°Žã³ãã¯é žãç¡æ°Žãã¬ã€
ã³é žããžããã ç¡æ°Žã³ãã¯é žãç¡æ°Žãã¿ã«é žãã
ãã©ã¯ãã«ç¡æ°Žãã¿ã«é žãããã©ããã ç¡æ°Žãã¿
ã«é žãïŒâãããç¡æ°Žãã¿ã«é žãïŒâãããç¡æ°Ž
ãã¿ã«é žãç¡æ°Žããã¡ãªããé žãç¡æ°Žã¡ãªãã
é žãããã©ã·ã¢ããšãã¬ã³ãããã©ã·ã¢ããããž
ã¡ã¿ã³ãïœâãžããããã³ãŒã³ãïœâãžãããã
ã³ãŒã³ãïŒïŒïŒïŒïŒâããªããããã³ãŒã³ããã©
ããããã³ãŸãããªã«ããã¯ãªã«ã¯ãã©ã€ããã
ãã³ã¯ãã«ã€ãããã¯ãã©ãã«ããã«ããã«ããž
ã¯ãããžã·ã¢ããã©ãã³ãŸããã³ãã¢ã³ãã©ãã
ã³ããžãããã¢ã³ãã©ããã³ãïŒâãã«ãªã¬ããª
ãã³ããžã·ã¢ãã¡ãã¬ã³ããããžãããªã«ããã
ãªãããâïŒâãã«ãªã¬ããªãã³âããžã·ã¢ãã¡
ãã¬ã³ããããžãããªã«ãããã¯ãªã³é žãïœâã
ããå®æ¯éŠé žãïœâãããå®æ¯éŠé žãïŒïŒïŒâãž
ãããå®æ¯éŠé žããã³ã¿ãã«ãªãå®æ¯éŠé žãïŒâ
ããããµã«ãã«é žãïŒïŒïŒâãžããããµãªãã«
é žããã¿ã«é žãã¡ãªããé žããã®ä»ã®é»å芪åå
ã®å€§ããååç©ãæããããšãã§ããããŸããé»
åå容æ§ç©è³ªã®æ·»å å²åã¯ãééæ¯ã§ãã€ãªã€çº
çç©è³ªïŒé»åå容ç©è³ªã¯100ïŒ0.01ã200ã奜ãŸã
ãã¯100ïŒ0.1ã100ã§ããã ãªããäžèšã®æå å±€ãèšããã¹ãæ¯æäœïŒã¯é
å±æ¿ãéå±ãã©ã åã¯å°é»æ§ããªããŒãé žåã€ã³
ãžãŠã çã®å°é»æ§ååç©è¥ããã¯ã¢ã«ãããŠãŒ
ã ããã©ãžãŠã ãéçã®éå±ãããªãå°é»æ§èå±€
ãå¡åžãèžçãã©ãããŒãçã®æ段ã«ãããçŽã
ãã©ã¹ããã¯ãã€ã«ã çã®åºäœã«èšããŠæããã®
ãçšãããããæ¥çå±€ãããã¯ããªã€ãŒå±€çãšã
ãŠæ©èœããäžéå±€ãšããŠã¯ãäžèšã®ãã€ã³ããŒæš¹
èãšããŠèª¬æãããããªé«ååéåäœãããªãã
ã«ã¢ã«ã³ãŒã«ããšãã«ã»ã«ããŒãºãã«ã«ããã·ã¡
ãã«ã»ã«ããŒãºãªã©ã®ææ©é«ååç©è³ªåã¯é žåã¢
ã«ãããŠãŒã ãªã©ããæããã®ãçšããããã çºæã®å¹æ æ¬çºæã¯ã以äžèª¬æããããã«ãäžèšã®ãã©ã
ã°è§22.4ã28.8ã«ç¹ç°ããŒã¯ãæããåŸæ¥ã«ãªã
æ°èŠãªç¡éå±ãã¿ãã·ã¢ãã³ååç©ããã€ãªã¢çº
çç©è³ªã«çšããäžèšã®ããã©ãŸã³ååç©ããã€ãª
ã¢èŒžéç©è³ªã«çšããã®ã§ãåŸæ¥ã®ç¡éå±ãã¿ãã·
ã¢ãã³ååç©ãšããã©ãŸã³ååç©ãšãçµã¿åãã
ãŠåŸãããæå äœããã¯é¡èã«åªããé«æ床ãæ
ã€ããšãã§ãããšãšãã«ãç¹°ãè¿ã䜿çšæã®é»äœ
ã®å±¥æŽãå°ãªããæ®çé»äœã®å€åãé¡èã«å°ãã
ããããšãã§ããããæå äœç¹æ§ãå®å®ã«ç¶æã§
ããããŸãããã¿ãã·ã¢ãã³ååç©ã®ç±åã³å å®
å®æ§ã®ç¹æ§ã掻ãããé»ååçæå äœãæäŸã§ã
ãããããã«ãããç¹ã«é·æ³¢é·å ãã¬ãŒã¶ãŒå ã«
察ããåŸæ¥ã«ãªãåªããé»ååçæå äœãæäŸã§
ããã å®æœäŸ 以äžã«å®æœäŸã説æããããããã«å ç«ã€ãŠç¬¬
ïŒå³ãªãã第ïŒå³ã«ç€ºãç¹æ§ããã€ç¡éå±ãã¿ã
ã·ã¢ãã³ååç©ïŒ¡ã®åæäŸåã³Ïåç¡éå±ãã¿ã
ã·ã¢ãã³ååç©ã®åæäŸã瀺ãã åæäŸ ïŒ ãªããŠã ãã¿ãã·ã¢ãã³50ïœãïŒâã«ãããŠå
åæ¹æããæ¿ç¡«é žã®600mlã«å ããã次ãã§ãã®
æ··åç©ã¯ãã®æž©åºŠã«ãããŠïŒæéæ¹æãããã次
ãã§ã§ãã溶液ã¯ç²ãçŒçµãããã¬ã©ã¹æ¿Ÿæãé
ããŠæ¿ŸéãããŠãïŒãªããã«ã®æ°·ãšæ°Žã®äžãžæ¹æ
ããªããåŸã ã«æ³šå ¥ããããæ°æéæŸçœ®ããåŸ
ã«ããã®æ··åç©ã¯æ¿ŸéãããåŸãããå¡ãã¯äžæ§
ã«ãªããŸã§æ°Žã§æŽæµããããã€ãã§ãã®å¡ã¯æçµ
çã«ã¡ã¿ããŒã«ã§æ°åæŽæµãããã€ç©ºæ°äžã§ä¹Ÿç¥
ãããããããã®ä¹Ÿç¥ãããç²æ«ã¯24æéé£ç¶æœ
åºè£ 眮äžã§ã¢ã»ãã³ã«ãã€ãŠæœåºãããã€ç©ºæ°äž
ã§ä¹Ÿç¥ãããããŠéãç²æ«ãšãªãã äžèšã«ãããŠãªããŠã ã«å¯ŸããŠå¡©ã®æ®æž£ãä¿èšŒ
ããããã«æåºã¯å埩ãããããã®ããã«ããŠ
30.5ïœã®éãç²æ«ãåŸãããããã®åŸããããã®
ã¯ããã®ïŒžç·åæå³åœ¢ããã§ã«åºçãããŠããè³
æã«èšèŒãããŠããαåãã¿ãã·ã¢ãã³ååç©ã®
ç·åæå³åœ¢ãšäžèŽããŠããã ãã®ããã«ããŠåŸãããéå±ãå«ãŸãªãαåã
ã¿ãã·ã¢ãã³ååç©30ïœãçŽåŸ13/16ã€ã³ãã®ã
ãŒã«ã§ååæºããããå 容ç©900mlã®ç£è£œããŒã«
ãã«äžã«ä»èŸŒã¿ãçŽ80rpmã§164æéããªã³ã°ã
ãããã®åŸããã©ããããã©ã³ãïŒïŒïŒâãžã¯ã
ããšã¿ã³çã®ææ©æº¶å€200mlãããŒã«ãã«äžã«å
ãã24æéå床ããªã³ã°ããããã®ããªã³ã°ãã
åŸã®åæ£æ¶²ã«ã€ããŠææ©æº¶å€ã®é€å»åã³ä¹Ÿç¥ãè¡
ãªããç¡éå±ãã¿ãã·ã¢ãã³ååç©A28.2ïœãåŸ
ãã åæäŸ ïŒ Î±åç¡éå±ãã¿ãã·ã¢ãã³ååç©ïŒICI補ã¢ã
ã©ã€ããã¢ãŒã¹ããã«GSïŒãå ç±ãããžã¡ãã«
ãã«ã ã¢ã«ãããã«ããïŒåæœåºããŠç²Ÿè£œããã
ãã®æäœã«ãã粟補ç©ã¯Î²åã«è»¢ç§»ããã次ã«ã
ã®Î²åç¡éå±ãã¿ãã·ã¢ãã³ååç©ã®ïŒéšåãæ¿
ç¡«é žã«æº¶è§£ãããã®æº¶æ¶²ãæ°·æ°Žäžã«æ³šãã§åæ²æŸ±
ãããããšã«ãããαåã«è»¢ç§»ãããããã®åæ²
柱ç©ãã¢ã³ã¢ãã¢æ°Žãã¡ã¿ããŒã«çã§æŽæµåŸ10â
ã§ä¹Ÿç¥ããã次ã«äžèšã«ãã粟補ããαåç¡éå±
ãã¿ãã·ã¢ãã³ååç©ã磚ç å©å€åã³åæ£å€ãšãš
ãã«ãµã³ããã«ã«å ¥ãã枩床100±20âã§15ã25
æéæ··ç·Žããããã®æäœã«ããçµæ¶åœ¢ãÏåã«è»¢
移ããã®ã確èªåŸã容åšããåãåºããæ°Žåã³ã¡
ã¿ããŒã«çã§ç£šç å©å€åã³åæ£å€ãååé€ããåŸ
也ç¥ããŠé®®æãªéå³ã垯ã³ãÏåç¡éå±ãã¿ãã·
ã¢ãã³ã®éè²çµæ¶ãåŸãã å®æœäŸ ïŒ ã¢ã«ãããŠãŒã ãèžçããããªãšã¹ãã«ãã€ã«
ã ãããªãå°é»æ§æ¯æäœäžã«åæäŸïŒã§åŸããã
ç¡éå±ãã¿ãã·ã¢ãã³ååç©1.0ïœãšããªã¡ãã«
ã¡ã¿ã¯ãªã¬ãŒãïŒãšã«ããµã€ãâ2010ãããŠãã³
瀟補ïŒ2.0ïœãïŒïŒïŒâãžã¯ãããšã¿ã³100mlã«å
ããŠè¶ é³æ³¢åæ£ã«ããåæ£ããããã®åæ£æ¶²ã也
ç¥ããåŸã®èåã0.5ÎŒmãšãªãããã«å¡åžä¹Ÿç¥ã
ãŠãã€ãªã¢çºçå±€ã圢æããã ããã«ãã®äžã«è¡šïŒã«ç€ºããäžèšäŸç€ºâ14ã®
ãã€ãªã¢èŒžéç©è³ª12.4ïœãšããªã«ãŒãããŒãïŒã
ã³ã©ã€ãâ1250ãåžäººåæ瀟補ïŒ16.5ïœãšã
ïŒïŒïŒâãžã¯ãããšã¿ã³100mlã«æº¶è§£ãã溶液ã
也ç¥åŸã®èåã12ÎŒmãšãªãããã«å¡åžä¹Ÿç¥ããŠ
ãã€ãªã€èŒžéå±€ã圢æããé»ååçæå äœãåŸ
ãã å®æœäŸïŒãïŒãæ¯èŒäŸïŒãïŒ å®æœäŸïŒã«ãããŠè¡šïŒã®æ¬ã®ç©è³ªã®ä»£ããã«å®
æœäŸïŒãïŒãæ¯èŒäŸïŒãïŒã®ããããã«è©²åœãã
æ¬ã«èšèŒãããŠããç©è³ªãçšãã以å€ã¯åæ§ã«ã
ãŠããããå®æœäŸïŒãïŒãæ¯èŒäŸïŒãïŒã®é»åå
çæå äœãåŸãã æ¯èŒäŸ ïŒãïŒ å®æœäŸïŒã«ãããŠãã€ãªã¢èŒžéç©è³ªãšããŠæ¯èŒ
äŸïŒãïŒã«è©²åœããæ¬ã«èšèŒãããŠããç©è³ªãçš
ãã以å€ã¯åæ§ã«ããŠæ¯èŒäŸïŒãïŒã®é»ååçæ
å äœãåŸãã æ¯èŒäŸ ïŒãïŒ å®æœäŸïŒã«ãããŠåæäŸïŒã®Ïåãã¿ãã·ã¢ã
ã³ååç©ãçšããæ¯èŒäŸïŒãïŒã®ããããã®æ¬ã«
èšèŒããããã€ãªã¢èŒžéç©è³ªãçšãã以å€ã¯åæ§
ã«ããŠæ¯èŒäŸïŒãïŒã®é»ååçæå äœãåŸãã è©äŸ¡è©Šéš 以äžã®ããã«ããŠåŸãããé»ååçæå äœã®
åã ã«ã€ããŠãããšã¬ã¯ããã¡ãŒã¿ãŒSP428åã
ïŒå·å£é»æ°è£œäœæ補ïŒãçšããŠããã®é»ååçç¹
æ§ã調ã¹ããããªãã¡ãæå äœè¡šé¢ã垯é»é»å§â
6KVã§ïŒç§é垯é»ãããæã®å容é»äœVA(V)ãšã
ïŒç§éææžè¡°ãããåŸã®é»äœV1ïŒåæé»äœïŒã1/
ïŒã«æžè¡°ãããããã«å¿ èŠãªé²å é1/2ïŒLuxã»
ç§ïŒïŒã¿ã³ã°ã¹ãã³å æºã䜿çšïŒãšãææžè¡°ç
ïŒVAâV1ïŒïŒV1Ã100ïŒ åã³10ïŒLuxã»secïŒé²å
åŸã®æ®çé»äœVR(V)ã枬å®ããã 次ã«åæ§ã®æž¬å®ç³»ã«ãããŠå æºã«ã¿ã³ã°ã¹ãã³
å æºãçšããã¢ãã¯ãã¡ãŒã¿ãéããŠãç¹ã«åé¡
ãšããæ³¢é·780nm±1nmã®å ã«å¯Ÿããåæžé²å é
E1/2ïŒÎ»ïŒ780ïŒïŒergïŒcm2ïŒã枬å®ããããŸããäž
èšå容é»äœVA(V)ãšæ®çé»äœã«ã€ããŠã¯äžäžåã³
ããŒåŸã«ã€ããŠã枬å®ããã ãããã®çµæã«ã€ããŠè¡šïŒã«ç€ºããè¡šäžÎVAã
ÎVRã¯ããããã®åæç¹æ§å€ããäžäžæã³ããŒåŸ
ã®ç¹æ§å€ãåŒããå€ã§ããã
ãè¡šã
ãè¡šã
第ïŒå³ã¯æ¬çºæã«äœ¿çšããç¡éå±ãã¿ãã·ã¢ã
ã³ååç©ïŒ¡ã®ïŒžç·åæå³ã第ïŒå³ã¯ãã®èµ€å€ç·åž
åã¹ãã¯ãã«å³ã第ïŒå³ã¯ãã®ãã¿ãã·ã¢ãã³ã®
è¿èµ€å€ç·åžåã¹ãã¯ãã«å³ã第ïŒå³ã第ïŒå³ã第
ïŒå³ã第ïŒå³ã第ïŒå³åã³ç¬¬ïŒå³ã¯æ¬çºæã®é»å
åçæå äœã®å±€æ§æã®å ·äœäŸã瀺ãããã®ã§ã
ãã å³äžãïŒã¯å°é»æ§æ¯æäœãïŒã¯ãã€ãªã¢çºç
å±€ãïŒã¯ãã€ãªã¢èŒžéå±€ãïŒïŒïŒâ²ïŒïŒâ³ã¯æå
å±€ãïŒã¯äžéå±€ãïŒã¯ãã€ãªã¢çºçç©è³ªãïŒã¯ã
ã€ãªã¢èŒžéç©è³ªã§ããã
ã³ååç©ïŒ¡ã®ïŒžç·åæå³ã第ïŒå³ã¯ãã®èµ€å€ç·åž
åã¹ãã¯ãã«å³ã第ïŒå³ã¯ãã®ãã¿ãã·ã¢ãã³ã®
è¿èµ€å€ç·åžåã¹ãã¯ãã«å³ã第ïŒå³ã第ïŒå³ã第
ïŒå³ã第ïŒå³ã第ïŒå³åã³ç¬¬ïŒå³ã¯æ¬çºæã®é»å
åçæå äœã®å±€æ§æã®å ·äœäŸã瀺ãããã®ã§ã
ãã å³äžãïŒã¯å°é»æ§æ¯æäœãïŒã¯ãã€ãªã¢çºç
å±€ãïŒã¯ãã€ãªã¢èŒžéå±€ãïŒïŒïŒâ²ïŒïŒâ³ã¯æå
å±€ãïŒã¯äžéå±€ãïŒã¯ãã€ãªã¢çºçç©è³ªãïŒã¯ã
ã€ãªã¢èŒžéç©è³ªã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ãã€ãªã¢çºçç©è³ªåã³ãã€ãªã¢èŒžéç©è³ªãå«
æããæå å±€ãæããé»ååçæå äœã«ãããŠã
åèšãã€ãªã¢çºçç©è³ªãCuk α1.541â«ã®ïŒžç·ã«
察ãããã©ãã°è§åºŠã7.7ã9.3ã16.9ã17.6ã
22.4ã28.8ã«äž»èŠããŒã¯ãæããç·åæã¹ãã¯
ãã«ãæãããã€ãã®ïŒžç·åæã¹ãã¯ãã«ã®äžèš
ãã©ãã°è§åºŠ9.3ã«å¯Ÿãããã©ãã°è§åºŠ16.9ã®ã
ãŒã¯ã®åŒ·åºŠæ¯ã0.8ã1.0ã§ããããã€äžèšãã©ã
ã°è§åºŠ9.3ã®ããŒã¯ã«å¯Ÿãããã©ãã°è§åºŠ22.4å
ã³28.8ã®ããããã®ããŒã¯ã®åŒ·åºŠæ¯ã0.4以äžã§
ããç¡éå±ãã¿ãã·ã¢ãã³ååç©ãå«ã¿ãåèšã
ã€ãªã¢èŒžéç©è³ªãäžèšäžè¬åŒãããããã§è¡šã
ããããã©ãŸã³ååç©ã®å°ãªããšãïŒã€ãå«ãã
ãšãç¹åŸŽãšããé»ååçæå äœã äžè¬åŒãã ïŒäœããã®äžè¬åŒäžR1ã¯ã眮æè¥ããã¯æªçœ®
æã®ã¢ãªãŒã«åºåã¯çœ®æè¥ããã¯æªçœ®æã®
è€çŽ ç°åºã R2ã¯ãæ°ŽçŽ ååã眮æè¥ããã¯æªçœ®æ
ã®ã¢ã«ãã«åºãåã¯çœ®æè¥ããã¯æªçœ®æã®
ã¢ãªãŒã«åºã X1ã¯æ°ŽçŽ ååãããã²ã³ååãã¢ã«ã
ã«åºã眮æã¢ããåºãã¢ã«ã³ãã·åºãåã¯
ã·ã¢ãåºã ïœã¯ãïŒåã¯ïŒã®æŽæ°ãè¡šããïŒ äžè¬åŒãã ïŒäœããã®äžè¬åŒäžR3ã¯ã眮æè¥ããã¯æªçœ®
æã®ã¢ãªãŒã«åºåã¯çœ®æè¥ããã¯æªçœ®æã®
è€çŽ ç°åºã R4ã¯ãæ°ŽçŽ ååã眮æè¥ããã¯æªçœ®æ
ã®ã¢ã«ãã«åºãåã¯çœ®æè¥ããã¯æªçœ®æã®
ã¢ãªãŒã«åºã X2ã¯ãæ°ŽçŽ ååãããã²ã³ååãã¢ã«
ãã«åºã眮æã¢ããåºãã¢ã«ã³ãã·åºãå
ã¯ã·ã¢ãåºã ïœã¯ãïŒåã¯ïŒã®æŽæ°ãè¡šããïŒ
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24288485A JPS62103652A (ja) | 1985-10-31 | 1985-10-31 | é»ååçæå äœ |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24288485A JPS62103652A (ja) | 1985-10-31 | 1985-10-31 | é»ååçæå äœ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62103652A JPS62103652A (ja) | 1987-05-14 |
| JPH054670B2 true JPH054670B2 (ja) | 1993-01-20 |
Family
ID=17095664
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP24288485A Granted JPS62103652A (ja) | 1985-10-31 | 1985-10-31 | é»ååçæå äœ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62103652A (ja) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8960528B2 (en) | 2004-04-22 | 2015-02-24 | Dixie Consumer Products Llc | Insulating cup wrapper and insulated container formed with wrapper |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58134642A (ja) * | 1982-02-05 | 1983-08-10 | Konishiroku Photo Ind Co Ltd | é»ååçæå äœ |
| JPS58166354A (ja) * | 1982-03-27 | 1983-10-01 | Konishiroku Photo Ind Co Ltd | é»ååçæå äœ |
| JPS5962861A (ja) * | 1982-07-08 | 1984-04-10 | Dainippon Ink & Chem Inc | é»ååççšæå äœ |
| JPS59113445A (ja) * | 1982-12-21 | 1984-06-30 | Dainippon Ink & Chem Inc | é»ååççšæå äœ |
| JPS60143352A (ja) * | 1983-12-29 | 1985-07-29 | Konishiroku Photo Ind Co Ltd | æå äœ |
-
1985
- 1985-10-31 JP JP24288485A patent/JPS62103652A/ja active Granted
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58134642A (ja) * | 1982-02-05 | 1983-08-10 | Konishiroku Photo Ind Co Ltd | é»ååçæå äœ |
| JPS58166354A (ja) * | 1982-03-27 | 1983-10-01 | Konishiroku Photo Ind Co Ltd | é»ååçæå äœ |
| JPS5962861A (ja) * | 1982-07-08 | 1984-04-10 | Dainippon Ink & Chem Inc | é»ååççšæå äœ |
| JPS59113445A (ja) * | 1982-12-21 | 1984-06-30 | Dainippon Ink & Chem Inc | é»ååççšæå äœ |
| JPS60143352A (ja) * | 1983-12-29 | 1985-07-29 | Konishiroku Photo Ind Co Ltd | æå äœ |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8960528B2 (en) | 2004-04-22 | 2015-02-24 | Dixie Consumer Products Llc | Insulating cup wrapper and insulated container formed with wrapper |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62103652A (ja) | 1987-05-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0797221B2 (ja) | ç»å圢ææ¹æ³ | |
| JP2657836B2 (ja) | é»ååçæå äœ | |
| JPS62103650A (ja) | é»ååçæå äœ | |
| JPH0560863B2 (ja) | ||
| JP2000112157A (ja) | é»ååçæå äœ | |
| JP2700859B2 (ja) | æå äœ | |
| JPH0530263B2 (ja) | ||
| JP2687235B2 (ja) | é»ååçæå äœ | |
| JP2867045B2 (ja) | é»ååçæå äœ | |
| JP2000098640A (ja) | é»ååçæå äœ | |
| JPS6019154A (ja) | é»ååççšæå äœ | |
| JPH0477906B2 (ja) | ||
| JPH054670B2 (ja) | ||
| JP2981994B2 (ja) | ç»å圢ææ¹æ³ | |
| JPS62121460A (ja) | é»ååçæå äœ | |
| JPH0823705B2 (ja) | æå äœ | |
| JP2563810B2 (ja) | æå äœ | |
| JPH0789230B2 (ja) | æå äœ | |
| JPH0786692B2 (ja) | æå äœ | |
| JPH0518424B2 (ja) | ||
| JPH0299969A (ja) | é»ååçæå äœ | |
| JPS62103653A (ja) | é»ååçæå äœ | |
| JPS63148269A (ja) | æå äœ | |
| JPH02165156A (ja) | é»ååçæå äœ | |
| JPS63149653A (ja) | æå äœ |