JPH07119162B2 - Foam aerosol insecticide and coating method using the same - Google Patents
Foam aerosol insecticide and coating method using the sameInfo
- Publication number
- JPH07119162B2 JPH07119162B2 JP3106349A JP10634991A JPH07119162B2 JP H07119162 B2 JPH07119162 B2 JP H07119162B2 JP 3106349 A JP3106349 A JP 3106349A JP 10634991 A JP10634991 A JP 10634991A JP H07119162 B2 JPH07119162 B2 JP H07119162B2
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- weight
- insecticide
- water
- insecticidal
- aerosol
- Prior art date
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Description
【０００１】[0001]
【産業上の利用分野】本発明は、ゴキブリ等の大小様々
な家住性害虫の駆除用として好適な、発泡エアゾール殺
虫剤ならびにこれを用いた塗布方法に関するものであ
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a foamed aerosol insecticide suitable for controlling household insects such as cockroaches of various sizes and a coating method using the same.
【０００２】[0002]
【従来の技術】家住性害虫の駆除方法としては、従来、
殺虫剤を噴霧する方法あるいは粘着テープを含む捕獲器
を使用する方法などが知られている。前者の噴霧式のも
のは噴霧により空気中に殺虫剤が飛散するため人体への
付着あるいは呼吸による吸入の危険が伴う。一方、捕獲
器を用いる方法は、害虫の発生、増殖に対しては防止効
果がなく家屋内の害虫の一部のみしか退治することがで
きない等の問題を有している。2. Description of the Related Art As a method for exterminating house-dwelling pests, conventionally,
Known methods include spraying pesticides and using traps containing adhesive tape. In the former spray type, the insecticide is scattered in the air by spraying, so that there is a risk of being attached to the human body or inhaling by breathing. On the other hand, the method using a trap has a problem that it has no preventive effect on the generation and multiplication of harmful insects and that only a part of the harmful insects in the house can be exterminated.
【０００３】また、最近、実公昭６２−１６８４０号公
報に開示されているように、殺虫剤収納筒に塗布チップ
を備えた害虫駆除用具も提案されているが、塗布時の滲
出量にバラツキがあり、特に垂直面に塗布すると液ダレ
等により処理薬量が不均一となって所望の駆除効果が得
られなかったり、あるいは処理面の汚染を招くなどの問
題点を有していた。Recently, as disclosed in Japanese Utility Model Publication No. 62-16840, there has been proposed a pest control tool having a coating tip on a pesticide storage cylinder, but the amount of exudation during coating varies. However, particularly when applied on a vertical surface, there is a problem in that the amount of the treatment agent becomes non-uniform due to liquid sagging or the like and the desired extermination effect cannot be obtained, or the treated surface is contaminated.
【０００４】[0004]
【発明が解決しようとする課題】本発明は、ゴキブリ等
の家住性害虫駆除用に供される殺虫剤について、飛散薬
剤を吸入することの危険性がない発泡塗布式殺虫剤に着
目し、従来からの提案ではいまだ十分に果たし得なかっ
た均一塗布、液ダレ防止、汚染防止などの要求を全て満
足させることのできるを発泡エアゾール殺虫剤ならびに
これを用いた塗布方法を提供することを目的としてなさ
れたものである。DISCLOSURE OF INVENTION Problems to be Solved by the Invention The present invention focuses on foam-applied pesticides that are not dangerous for inhaling scattered chemicals among insecticides used for exterminating domestic pests such as cockroaches. In order to provide a foaming aerosol insecticide and a coating method using the same, which can satisfy all the requirements such as uniform coating, liquid dripping prevention, and contamination prevention, which cannot be sufficiently achieved by the proposal from It is a thing.
【０００５】[0005]
【課題を解決するための手段】上記目的を達成するため
の本発明は、（イ）ピレスロイド系殺虫剤及びピレスロ
イド様殺虫剤から選ばれた１種又は２種以上の殺虫成分
０．０５〜１０．０重量％、（ロ）ＨＬＢが５〜１５の
非イオン系界面活性剤０．１〜５．０重量％、（ハ）非
水溶性溶剤１．０〜１５．０重量％、（ニ）水７０〜９
５重量％、を主成分として含有する殺虫原液７０重量％
以上と、噴射剤３０重量％以下とからなる内容液をエア
ゾール容器に充填するようにした発泡エアゾール殺虫
剤、ならびにこれを用いた塗布方法に係る。Means for Solving the Problems The present invention for achieving the above-mentioned object is (a) one or more insecticide components selected from pyrethroid insecticides and pyrethroid-like insecticides 0.05 to 10 0.0% by weight, (B) 0.1 to 5.0% by weight of nonionic surfactant having HLB of 5 to 15, (C) 1.0 to 15.0% by weight of non-water-soluble solvent, (D) Water 70-9
5% by weight, pesticidal stock solution containing 70% by weight
The above relates to a foamed aerosol insecticide in which an aerosol container is filled with a content liquid containing 30% by weight or less of a propellant, and a coating method using the same.
【０００６】[0006]
【作用】本発明で用いられる殺虫成分としては、ピレス
ロイド系殺虫剤、ピレスロイド様殺虫剤を用いるように
しているが、これは、効力と安全性の点からいって好ま
しいためである。例えば、フェノトリン、シフェノトリ
ン、アレスリン、フタールスリン、レスメトリン、フラ
メトリン、プラレトリン、ペルメトリン、シペルメトリ
ン、エトフェンプロックス、シラフルオフェンなどを例
示できるが、これらに限定されるものでなく、また光学
異性体あるいは幾何異性体が存在する場合は、それらの
各々ならびに任意の混合物が包含されることはもちろん
である。本発明では、これらの殺虫成分の１種または２
種以上が殺虫原液中に０．０５〜１０．０重量％配合さ
れるが、さらに忌避剤、殺菌剤、防カビ剤、共力剤、安
定剤、香料などを適宣配合して多目的組成物とすること
もできる。The pyrethroid insecticide and the pyrethroid-like insecticide are used as the insecticidal ingredient in the present invention, because they are preferable from the viewpoint of efficacy and safety. For example, phenothrin, cyphenothrin, allethrin, phtalthrin, resmethrin, flamethrin, pralethrin, permethrin, cypermethrin, etofenprox, silafluophene, etc. can be exemplified, but not limited to these, and optical isomers or geometric isomers. When present, each of them as well as any mixture is, of course, included. In the present invention, one or two of these insecticidal components are used.
0.05 to 10.0 wt% of the seeds or more are blended in the insecticidal undiluted solution, and a repellent, a bactericide, an antifungal agent, a synergist, a stabilizer, a fragrance, etc. are blended appropriately, and a multipurpose composition Can also be
【０００７】非イオン系界面活性剤は、本発明の発泡エ
アゾール殺虫剤において、発泡性を付与するとともに、
前記殺虫成分を殺虫原液中で安定に均一に分散させるた
めに配合される。例えば、ポリオキシエチレンノニルフ
ェニルエーテル等のアルキルアリルエーテル型、ポリオ
キシエチレンラウリルエーテル等のアルキルエーテル
型、ポリオキシエチレンオレエート等のエステル型、ポ
リオキシエチレンラウリルアミン等のアルキルアミン
型、ソルビタンモノオレエートやポリオキシエチレンソ
ルビタンオレエート等の多価アルコール型、アルキルア
リルエーテルホルマリン縮合物等があり、殺虫原液の性
状、分散安定性、あるいは発泡性、消泡性の点からＨＬ
Ｂが５〜１５のものが好適である。これらは、１種また
は２種以上の混合物として使用することもでき、殺虫原
液中に０．１〜５．０重量％配合される。なお、ステア
リルアルコール、セタノールなどの高級アルコールを発
泡調整剤として添加することもできる。The nonionic surfactant imparts foamability to the foamed aerosol insecticide of the present invention, and
It is blended to stably and uniformly disperse the insecticidal component in the insecticidal stock solution. For example, an alkyl allyl ether type such as polyoxyethylene nonyl phenyl ether, an alkyl ether type such as polyoxyethylene lauryl ether, an ester type such as polyoxyethylene oleate, an alkylamine type such as polyoxyethylene laurylamine, and a sorbitan monoole. OH and polyoxyethylene sorbitan oleate and other polyhydric alcohol types, alkylallyl ether formalin condensates, etc., and HL from the viewpoint of the properties of the insecticidal stock solution, dispersion stability, or foaming and defoaming properties.
It is preferable that B is 5 to 15. These can be used alone or as a mixture of two or more kinds, and are added in an insecticidal stock solution in an amount of 0.1 to 5.0% by weight. Incidentally, higher alcohols such as stearyl alcohol and cetanol can be added as a foaming regulator.
【０００８】また、本発明の発泡エアゾール殺虫剤にお
いては、液の拡がりすぎを抑え、良好な塗布性能を得る
ために増粘剤を添加してもよい。増粘剤としては、アク
リル酸等からなる水溶性樹脂、ポリビニルアルコール、
アラビアゴム、カラギナン、ＣＭＣなどの水溶性高分
子、水溶性シリコーン樹脂などがあげられるが、これら
に限定されるものではない。Further, in the foamed aerosol insecticide of the present invention, a thickener may be added in order to prevent the liquid from spreading excessively and obtain good coating performance. As the thickener, a water-soluble resin made of acrylic acid or the like, polyvinyl alcohol,
Examples thereof include water-soluble polymers such as gum arabic, carrageenan, CMC, and water-soluble silicone resins, but are not limited thereto.
【０００９】本発明では、殺虫原液の溶剤として非水溶
性溶剤を用いたことに特徴を有する。従来この種の発泡
性エアゾール剤では一液性の原液となすためにアルコー
ル等の水溶性溶剤を用いるのがほとんどであったが、本
発明者らは溶剤の種類を代えて鋭意検討を行ったとこ
ろ、非水溶性溶剤の方が、発泡安定性、消泡性の点で水
溶性溶剤よりも優れ、しかも本発明の配合処方によれ
ば、使用時に倒立するのみで液が均一混合され、使用性
の点でほとんど不利にならないことも明らかとなった。
非水溶性溶剤としては、ケロシン、灯油などの脂肪族炭
化水素系溶剤、フエニルキシリルエタンなどの芳香族炭
化水素系溶剤、ナフテン系溶剤、イソプロピルミリステ
ート、ブチルステアレートなどのエステル類などがあげ
られるが、安全性、無臭性等の点からケロシン、灯油系
溶剤の使用が好ましい。非水溶性溶剤は１．０〜１５．
０重量％配合されるが、１５．０重量％を越えると発泡
性が悪くなり、しかも使用時に二液状態を均一混合する
際に困難が伴うため不適当である。なお、性状を損なわ
ない限りにおいて、他の種の溶剤、例えばエタノール、
イソプロパノールなどのアルコール類、アセトン、メチ
ルエチルケトンなどのケトン系溶剤、エチレングリコー
ル、プロピレングライコールなどの多価アルコール類、
エチレングリコールモノエチルエーテル、ジエチレング
リコールモノブチルエーテルなどのエーテル類、などの
水溶性溶剤を適宣添加してもよい。The present invention is characterized in that a non-water-soluble solvent is used as the solvent of the insecticidal stock solution. Conventionally, most of the foamable aerosols of this type used a water-soluble solvent such as alcohol to form a one-liquid undiluted solution, but the present inventors conducted diligent studies by changing the type of solvent. However, the non-water-soluble solvent is superior to the water-soluble solvent in terms of foaming stability and defoaming property, and according to the compounding formulation of the present invention, the liquid is uniformly mixed only by inversion at the time of use. It has also become clear that there is little disadvantage in terms of sex.
As the non-water-soluble solvent, kerosene, aliphatic hydrocarbon solvents such as kerosene, aromatic hydrocarbon solvents such as phenylxylylethane, naphthene solvents, isopropyl myristate, esters such as butyl stearate, etc. From the viewpoint of safety and odorlessness, it is preferable to use kerosene or kerosene solvent. The water-insoluble solvent is 1.0 to 15.
Although it is blended in an amount of 0% by weight, if it exceeds 15.0% by weight, the foaming property is deteriorated, and further, it is difficult to uniformly mix the two liquid states at the time of use. As long as the properties are not impaired, solvents of other species, such as ethanol,
Alcohols such as isopropanol, ketone-based solvents such as acetone and methyl ethyl ketone, polyhydric alcohols such as ethylene glycol and propylene glycol,
Water-soluble solvents such as ethers such as ethylene glycol monoethyl ether and diethylene glycol monobutyl ether may be added appropriately.
【００１０】本発明ではさらに水が７０〜９５重量％配
合されるが、殺虫原液の性状を安定に保持するために脱
イオン等の処理を施した精製水の使用が好ましい。In the present invention, 70 to 95% by weight of water is further added, but it is preferable to use purified water which has been subjected to a treatment such as deionization in order to stably maintain the properties of the insecticidal stock solution.
【００１１】本発明の発泡エアゾール殺虫剤は、こうし
て得られた殺虫原液７０重量％以上と、噴射剤３０重量
％以下を配合してなる内容液をエアゾール容器に充填し
て調製される。噴射剤としては、プロパン、ブタンなど
の液化石油ガス、ジメチルエーテル、フロンガス、炭酸
ガス、窒素ガスなどがあげられる。噴射剤は、内容液を
噴出した際に気泡を内包させて発泡性を高め、さらにガ
スの蒸発により消泡作用に寄与するので極めて重要であ
る。一般に噴射剤の配合量が多いほど消泡性が高くなる
傾向が認められたが、３０重量％を越えると塗布付着量
が低下し好ましくなかった。The foamed aerosol insecticide of the present invention is prepared by filling an aerosol container with a content liquid containing 70% by weight or more of the thus obtained undiluted insecticidal solution and 30% by weight or less of a propellant. Examples of the propellant include liquefied petroleum gas such as propane and butane, dimethyl ether, freon gas, carbon dioxide gas, nitrogen gas and the like. The propellant is extremely important because it encloses air bubbles when the content liquid is ejected to enhance the foamability and contributes to the defoaming action by evaporating the gas. In general, it was observed that the larger the amount of the propellant compounded, the higher the defoaming property, but if it exceeds 30% by weight, the coating adhesion amount decreases, which is not preferable.
【００１２】本発明は、発泡性かつ消泡性にすぐれた前
記内容液処方をエアゾール容器に充填し、該内容液を泡
沫状に噴出させ塗布することに特徴を有する。エアゾー
ル容器の構造は、従来の噴霧用エアゾールと同様、耐圧
容器と噴射バルブから構成され、ノズルの形状は用途に
応じて適宣選択することができる。例えば、ノズル内の
液通路をらせん状にして噴出量を調整したり、噴射口を
上面に設けさらに容器側面にサイドボタンを装填して前
方噴射型となせば使いやすくて便利である。The present invention is characterized in that the above-mentioned content liquid formulation excellent in foamability and defoaming property is filled in an aerosol container, and the content liquid is ejected in the form of foam to be applied. The structure of the aerosol container is composed of a pressure resistant container and an injection valve, like the conventional spray aerosol, and the shape of the nozzle can be appropriately selected according to the application. For example, it is convenient and convenient if the liquid passage in the nozzle is formed in a spiral shape to adjust the ejection amount, or if the ejection port is provided on the upper surface and the side button is mounted on the side surface of the container to form the front ejection type.
【００１３】こうして得られた本発明の発泡エアゾール
殺虫剤は、二液性であるが使用時に倒立するだけで均一
混合が可能で、しかも発泡性が安定しているため均一に
塗布することができ、溶液を塗布する場合のような液ダ
レの心配もない。さらに、消泡性が高いので処理後の汚
染感が少ないというメリットも有している。したがっ
て、本発明によれば、家屋内の台所、居間、玄関、窓サ
ッシ、壁などに塗布処理を施し、ゴキブリ、アリ類、ダ
ニ類、ナンキンムシ、各種害虫に高い駆除・予防効果を
奏する発泡エアゾール殺虫剤ならびにこれを用いた塗布
方法を提供するものである。The foamed aerosol insecticide of the present invention thus obtained is a two-part type, but can be mixed uniformly by simply inverting it at the time of use, and since the foaming property is stable, it can be applied uniformly. There is no need to worry about dripping as when applying a solution. Further, since it has a high defoaming property, it also has an advantage that the feeling of contamination after treatment is small. Therefore, according to the present invention, a foaming aerosol which has a high control / preventive effect against cockroaches, ants, mites, bed bugs, and various harmful insects by applying the coating treatment to the kitchen in the house, the living room, the entrance, the window sash, the wall, etc. An insecticide and a coating method using the same are provided.
【００１４】次に、本発明を試験例、実施例によりさら
に詳細に説明するが、本発明はその要旨を越えない限
り、以下の例に限定されるものではない。Next, the present invention will be described in more detail with reference to test examples and examples, but the present invention is not limited to the following examples as long as the gist thereof is not exceeded.
【００１５】（試験例１） 下記処方の殺虫原液ならびに噴射剤からなる内容液を耐
圧エアゾール容器に充填し、噴射バルブを装填して発泡
エアゾール殺虫剤を調製した。約１０ｃｍ離れたところ
からデコラ板に１０秒間噴出させ、塗布性能、使用性を
調べたところ次のとおりであった。Test Example 1 A pressure-resistant aerosol container was filled with an insecticidal stock solution having the following formulation and a propellant-containing solution, and a spray valve was loaded to prepare a foamed aerosol insecticide. When the coating performance and usability were examined by spraying the decorating plate for 10 seconds at a distance of about 10 cm, the results were as follows.
【００１６】[0016]
【表１】 [Table 1]
【００１７】試験の結果、本発明の発泡エアゾール殺虫
剤は、発泡安定性、消泡性が共にすぐれ、塗布の状態も
良好で、従来の噴霧式エアゾールのような薬液の飛散が
なく、また溶液を滲出塗布する方式にみられる液ダレの
心配も少ないことから極めて効率的・実用的な発泡塗布
方式を提供することが認められた。これに対し、対照発
泡エアゾール殺虫剤で示されるように、殺虫原液調製に
用いるケロシン配合量を１５重量％以上にした場合や、
殺虫原液／噴射剤の比率を７／３以下に減らした場合に
は、良好な発泡性あるいは塗布性能が得られず不適当で
あった。なお、ケロシンの代わりに水溶性のエタノール
を用いた場合、本発明処方の範囲では殺虫成分を溶解せ
しめるに至らず好ましくない結果が得られた。As a result of the test, the foamed aerosol insecticide of the present invention is excellent in foaming stability and defoaming property, has a good coating state, does not scatter a chemical solution like a conventional spray type aerosol, and has a solution. It has been confirmed that an extremely efficient and practical foaming coating method can be provided because there is little concern about liquid dripping observed in the method of exuding coating. On the other hand, as shown in the control foamed aerosol insecticide, when the amount of kerosene used for preparing the insecticidal stock solution is 15% by weight or more,
When the ratio of undiluted insecticide / propellant was reduced to 7/3 or less, good foamability or coating performance could not be obtained, which was unsuitable. In addition, when water-soluble ethanol was used instead of kerosene, an unfavorable result was obtained because the insecticidal component was not dissolved within the range of the formulation of the present invention.
【００１８】（実施例１） 有効成分としてシフェノトリン０．８重量％、ディート
１．５重量％、及びＰＯＥ（７．０）２級アルキルエー
テル１．０重量％、水溶性シリコーン樹脂０．１重量
％、フェニルキシリルエタン３．８重量％、精製水９
２．８重量％を含有する殺虫原液を調製した。この殺虫
原液２６０ｇを３００ｍｌ耐圧エアゾール容器に充填
し、噴射バルブを装填した後、噴射ガス（ジメチルエー
テル２０重量％とＬＰＧ８０重量％の混合ガス）３０ｇ
を圧入して、本発明の発泡エアゾール殺虫剤を得た。本
殺虫剤を台所の床、食器棚、壁面に発泡塗布処理したと
ころ、ゴキブリ等の害虫に対し十分な駆除・忌避効果を
示し、６カ月以上にわたって効力が持続した。Example 1 As active ingredients, 0.8% by weight of ciphenothrin, 1.5% by weight of diet, 1.0% by weight of POE (7.0) secondary alkyl ether, and 0.1% of water-soluble silicone resin. Wt%, phenylxylylethane 3.8 wt%, purified water 9
An insecticidal stock solution containing 2.8% by weight was prepared. 260 g of this undiluted insecticidal solution was filled in a 300 ml pressure-resistant aerosol container, and after the injection valve was loaded, 30 g of injection gas (mixed gas of dimethyl ether 20% by weight and LPG 80% by weight)
Was injected under pressure to obtain the foamed aerosol insecticide of the present invention. When this insecticide was applied to the kitchen floor, cupboard, and wall surface by foaming treatment, it showed a sufficient control and repellent effect against harmful insects such as cockroaches, and the efficacy was maintained for 6 months or longer.
【００１９】[0019]
【発明の効果】本発明によれば、発泡安定性、消泡性と
もにすぐれ、塗布の状態も良好で、従来の噴霧式エアゾ
ールのような薬液の飛散がなく、また溶液を滲出塗布す
るタイプにみられる液ダレの心配も少ない極めて効率的
・実用的な発泡エアゾール殺虫剤ならびにこれを用いた
塗布方法を提供することができる。EFFECTS OF THE INVENTION According to the present invention, the foaming stability and defoaming property are excellent, the state of application is good, and there is no scattering of the chemical liquid unlike the conventional spray type aerosol, and the solution is exuded and applied. It is possible to provide an extremely efficient and practical foamed aerosol insecticide and a coating method using the same, which is less likely to cause dripping.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ａ０１Ｎ 53/08 ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI technical display area A01N 53/08
Claims (2)
ロイド様殺虫剤から選ばれた１種又は２種以上の殺虫成
分０．０５〜１０．０重量％、（ロ）ＨＬＢが５〜１５
の非イオン系界面活性剤０．１〜５．０重量％、（ハ）
非水溶性溶剤１．０〜１５．０重量％、（ニ）水７０〜
９５重量％、を主成分として含有する殺虫原液７０重量
％以上と、噴射剤３０重量％以下とからなる内容液をエ
アゾール容器に充填するようにしたことを特徴とする発
泡エアゾール殺虫剤。1. An (a) pyrethroid insecticide and a pyrethroid-like insecticide, 0.05 to 10.0% by weight of one or more insecticidal components, and (b) 5 to 15 of HLB.
0.1 to 5.0% by weight of nonionic surfactant, (C)
Non-water-soluble solvent 1.0 to 15.0% by weight, (d) water 70 to
A foam aerosol insecticide, characterized in that an aerosol container is filled with a content liquid consisting of 70% by weight or more of an insecticidal stock solution containing 95% by weight as a main component and 30% by weight or less of a propellant.
ロイド様殺虫剤から選ばれた１種又は２種以上の殺虫成
分０．０５〜１０．０重量％、（ロ）ＨＬＢが５〜１５
の非イオン系界面活性剤０．１〜５．０重量％、（ハ）
非水溶性溶剤１．０〜１５．０重量％、（ニ）水７０〜
９５重量％、を主成分として含有する殺虫原液７０重量
％以上と、噴射剤３０重量％以下とからなる内容液をエ
アゾール容器に充填し、エアゾール容器から内容液を泡
沫状に噴出して、塗布することを特徴とする発泡エアゾ
ール殺虫剤を用いた塗布方法。2. (i) 0.05 to 10.0 wt% of one or more insecticidal components selected from pyrethroid insecticides and pyrethroid-like insecticides, and (b) HLB of 5 to 15
0.1 to 5.0% by weight of nonionic surfactant, (C)
Non-water-soluble solvent 1.0 to 15.0% by weight, (d) water 70 to
An aerosol container is filled with a content liquid consisting of 70% by weight or more of an insecticidal stock solution containing 95% by weight as a main component and 30% by weight or less of a propellant, and the content liquid is ejected in the form of foam from the aerosol container to be applied. A coating method using a foamed aerosol insecticide, which comprises:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3106349A JPH07119162B2 (en) | 1991-03-29 | 1991-03-29 | Foam aerosol insecticide and coating method using the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3106349A JPH07119162B2 (en) | 1991-03-29 | 1991-03-29 | Foam aerosol insecticide and coating method using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04305502A JPH04305502A (en) | 1992-10-28 |
| JPH07119162B2 true JPH07119162B2 (en) | 1995-12-20 |
Family
ID=14431321
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3106349A Expired - Fee Related JPH07119162B2 (en) | 1991-03-29 | 1991-03-29 | Foam aerosol insecticide and coating method using the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07119162B2 (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3272105B2 (en) * | 1993-05-25 | 2002-04-08 | アース製薬株式会社 | Aerosol insecticide and insecticide method |
| GB9621589D0 (en) * | 1996-10-16 | 1996-12-04 | Culmstock Ltd | Pesticidal methods, compositions and devices |
| JP2001019942A (en) * | 1999-07-09 | 2001-01-23 | Fumakilla Ltd | Foam aerosol |
| JP2001172104A (en) * | 1999-12-14 | 2001-06-26 | Yushiro Chem Ind Co Ltd | Spreader, agrochemical composition with the same added thereto, and method for spraying agrochemical |
| JP2002047101A (en) * | 2000-08-03 | 2002-02-12 | Yushiro Chem Ind Co Ltd | Foamable vermicide for exterminating unpleasant vermin and method for exterminating unpleasant vermin by using the same |
| JP2005298420A (en) * | 2004-04-13 | 2005-10-27 | Dainippon Jochugiku Co Ltd | Aqueous aerosol agent |
| JP2005306753A (en) * | 2004-04-19 | 2005-11-04 | Dainippon Jochugiku Co Ltd | Dissolvent for pyrethroid compound sparingly soluble in kerosene and aerosol preparation |
| JP5459755B2 (en) * | 2008-09-30 | 2014-04-02 | 住化エンビロサイエンス株式会社 | Pest control agent |
| EP2470007A2 (en) * | 2009-08-28 | 2012-07-04 | BASF Corporation | Foamable pesticide compositions and methods of application |
| JP5897329B2 (en) * | 2011-12-28 | 2016-03-30 | 住化エンバイロメンタルサイエンス株式会社 | Cleaner for foamable glass |
| KR102361200B1 (en) | 2013-09-30 | 2022-02-09 | 에프엠씨 코포레이션 | Foam formulations and apparatus for delivery |
| AR100936A1 (en) | 2014-06-24 | 2016-11-09 | Fmc Corp | FORMULATIONS OF FOAMS AND EMULSIONABLE CONCENTRATES |
| MA44111A (en) | 2015-12-23 | 2018-10-31 | Fmc Corp | IN-SITU TREATMENT OF SEEDS IN A Furrow |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS497438A (en) * | 1972-05-10 | 1974-01-23 | ||
| JPS5135436A (en) * | 1974-09-20 | 1976-03-25 | Dainippon Jochugiku Kk | SUISEIE AZOOR USATSUCHUZAI |
| JPS60104003A (en) * | 1983-11-09 | 1985-06-08 | Fumakiraa Kk | Aerosol pesticide composition having low phytotoxicity |
| JPS62252702A (en) * | 1986-04-24 | 1987-11-04 | Yuukou Yakuhin Kogyo Kk | Foamable mothproof aerosol agent |
| JP2552521B2 (en) * | 1988-02-24 | 1996-11-13 | 神東塗料株式会社 | Effervescent termite control composition |
| JPH02264703A (en) * | 1989-04-06 | 1990-10-29 | Lion Katori Kk | Foaming insect pest repellent aerosol |
-
1991
- 1991-03-29 JP JP3106349A patent/JPH07119162B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH04305502A (en) | 1992-10-28 |
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