JPH05117062A - Non-slip tile and its production - Google Patents

Non-slip tile and its production

Info

Publication number
JPH05117062A
JPH05117062A JP3284794A JP28479491A JPH05117062A JP H05117062 A JPH05117062 A JP H05117062A JP 3284794 A JP3284794 A JP 3284794A JP 28479491 A JP28479491 A JP 28479491A JP H05117062 A JPH05117062 A JP H05117062A
Authority
JP
Japan
Prior art keywords
tile
slip
uneven surface
substrate
glaze
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP3284794A
Other languages
Japanese (ja)
Other versions
JP3180923B2 (en
Inventor
Hiroshi Yamada
洋 山田
Hisashi Nawa
久 名和
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toto Ltd
Original Assignee
Toto Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toto Ltd filed Critical Toto Ltd
Priority to JP28479491A priority Critical patent/JP3180923B2/en
Publication of JPH05117062A publication Critical patent/JPH05117062A/en
Application granted granted Critical
Publication of JP3180923B2 publication Critical patent/JP3180923B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Landscapes

  • Floor Finish (AREA)

Abstract

PURPOSE:To provide a type of uneven surface of tile not stained easily and permitting to relatively readily remove stains, in a tile having an anti-slip func tion produced by the formation of the uneven surface on the surface of the tile. CONSTITUTION:In a non-slip tile, on whose surface an uneven surface is formed so that the ten-point average roughness of the uneven surface is 25-200mum and that the lustering degree of the uneven surface is 5-20%. The non-slip tile can be produced by coating the surface of the substrate of the tile with a substrate- glazing agent having a heat-resistance of pyrometric cone equivalent of SK3a-11, further coating with an uneven surface-forming glazing agent having a pyrometric cone equivalent approximately the same as or higher than that of the substrate-glazing agent when the substrate-glazing layer is in a raw state, and subsequently sintering the coated tile substrate. By controlling the unevenness and the lustering degree of the surface of the tile substrate, a tile permitting the easy removal of sedimented dust is obtained without deteriorating the non-slip function.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、浴場床、トイレ床等に
敷設する滑り止めタイル、いわゆるノンスリップタイル
に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a non-slip tile, which is a non-slip tile laid on a bath floor, a toilet floor or the like.

【0002】[0002]

【従来の技術】従来から、このノンスリップタイルとし
て、例えば特公昭60−39827号公報に記載されて
いるように、陶磁器質のタイル表面に、溶融温度がタイ
ルの焼成温度よりも高い溶融アルミナを釉薬に混合して
固定し、あるいは、溶融粘性の高い釉薬を施して表面に
凹凸面を形成して、タイルに滑り止め機能を付加してい
る。
2. Description of the Related Art Conventionally, as this non-slip tile, for example, as described in Japanese Patent Publication No. 60-39827, a glaze made of fused alumina whose melting temperature is higher than the firing temperature of the tile is applied to the surface of a ceramic tile. It is mixed and fixed to the tile, or a glaze with a high melt viscosity is applied to form an uneven surface, and the tile has a non-slip function.

【0003】ところが、かかる凹凸面への塵、汚れの堆
積物の除去は困難であり、とくに、このようなノンスリ
ップタイルを浴場床等に施した場合、この凹凸面の存在
による汚れは形成され易く、また、落ち難いため、外観
上も目立ち、不潔感をもたらす。
However, it is difficult to remove dust and dirt deposits on the uneven surface, and in particular, when such a non-slip tile is applied to a bath floor or the like, dirt is easily formed due to the presence of the uneven surface. Also, because it is hard to fall off, it looks conspicuous and gives a feeling of filth.

【0004】[0004]

【発明が解決しようとする課題】本発明の課題は、表面
に凹凸面を形成して滑り止め機能を付与したタイルにお
いて、汚れが付き難く、また、比較的簡単に汚れを除去
できる手段を、タイル凹凸の態様面から見出そうとする
ものである。
DISCLOSURE OF THE INVENTION An object of the present invention is to provide a tile which has an uneven surface on which a non-slip function is provided and which is less likely to be soiled and which can be relatively easily removed. This is intended to be found from the aspect of tile unevenness.

【0005】[0005]

【課題を解決するための手段】本発明は、タイル表面の
滑り止め機能をもたらす凹凸の程度と、タイル表面に堆
積した塵等の落ち易さの指標としての光沢度とのバラン
スから、これらの最適範囲を凹凸面の粗さが10点平均
粗さで25〜200μm、好ましくは50〜150μm
であり、且つ、光沢度が5〜20%、好ましくは8〜1
2%とすることによって上記の課題を解決した。ここ
で、光沢度は5%未満であると汚れの除去が困難とな
り、20%超であると滑りやすくなるので好ましくな
い。
According to the present invention, the balance between the degree of unevenness that provides a non-slip function on the tile surface and the glossiness as an index of the ease with which dust or the like deposited on the tile surface can be removed. The optimum range is as follows: roughness of uneven surface is 10-point average roughness of 25 to 200 μm, preferably 50 to 150 μm.
And the gloss is 5 to 20%, preferably 8 to 1
The above problem was solved by setting it to 2%. Here, if the gloss level is less than 5%, it becomes difficult to remove stains, and if it exceeds 20%, it becomes slippery, which is not preferable.

【0006】このような表面凹凸を有する滑り止めタイ
ルは、タイル素地表面に、耐火度がSK3a〜11の下
地釉薬による施釉を行い、この下地施釉層が生の状態の
ときに、耐火度が下地釉薬よりも高いか、もしくは同等
程度の凹凸表面形成用釉薬による施釉を行った後、焼成
することによって製造できる。
In the non-slip tile having such surface irregularities, the tile base material surface is glazed with a base glaze having a fire resistance of SK3a to 11, and when the ground glaze layer is in a raw state, the fire resistance is a base. It can be produced by performing glaze treatment with a glaze for forming a textured surface that is higher than or equal to that of the glaze, and then firing.

【0007】[0007]

【作用】タイル表面の滑りの防止機能、とくに、素足に
対して、しかも、表面が濡れた通常のタイルの滑りの防
止機能は、タイル表面に形成された凹凸の程度と一義的
な関係がある。また、汚れの発生と表面からの除去され
易さは、その光沢の程度と一義的な関連を有する。この
凹凸面を10点平均粗さで25〜200μmの範囲に規
定し、また、光沢度を5〜20%の範囲に規定すること
によって、滑り止め機能を何ら損なうことなく、堆積塵
が除去しやすいタイルが得られる。
The function of preventing slippage of the tile surface, in particular, the function of preventing slippage of a normal tile with bare feet is uniquely related to the degree of unevenness formed on the tile surface. .. Further, the generation of stains and the ease of removal from the surface have a unique relationship with the degree of gloss. By defining this uneven surface in a range of 25 to 200 μm with a 10-point average roughness and a gloss level of 5 to 20%, accumulated dust can be removed without impairing the slip prevention function. You can get easy tiles.

【0008】[0008]

【実施例】図1は、本発明に係る滑り止めタイルの形成
過程を示す図であり、図中1はタイル素地を示し、2は
タイル素地1上に形成された下地釉薬層を示し、3は下
地釉薬層2が生の状態にあるときに、スクリーン印刷に
よって下地釉薬層2の上に形成された凹凸面形成のため
の釉薬層を示す。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS FIG. 1 is a diagram showing a process of forming a non-slip tile according to the present invention, in which 1 indicates a tile base and 2 indicates a base glaze layer formed on the tile base 1. Indicates a glaze layer for forming an uneven surface formed on the underglaze layer 2 by screen printing when the underglaze layer 2 is in a raw state.

【0009】長石20重量部、珪石10重量部、焼タル
ク20重量部、石灰10重量部、粘土5重量部それにフ
リット35重量部とからなる融点が1180℃(耐火度
SK5a)の釉薬を調製し、これを浴場床張り用タイル
素地1の表面に400μm厚に一様に施釉して下地釉薬
層2を形成した。この下地釉薬層2が生の状態で、珪石
40重量部、焼タルク25重量部それにフリット35重
量部からなる融点が1200℃(耐火度SK6a)の表
面状態調整用の釉薬を調製し、この釉薬をスクリーン印
刷によって、凹凸面形成のための釉薬層3を形成し、こ
れをトンネル炉中で、1200℃で24時間焼成した。
A glaze having a melting point of 1180 ° C. (refractory SK5a) consisting of feldspar 20 parts by weight, silica stone 10 parts by weight, baked talc 20 parts by weight, lime 10 parts by weight, clay 5 parts by weight and frit 35 parts by weight was prepared. Then, the surface of the tile base material 1 for bath flooring was uniformly glazed to a thickness of 400 μm to form a base glaze layer 2. In the raw state of the base glaze layer 2, 40 parts by weight of silica stone, 25 parts by weight of baked talc and 35 parts by weight of frit having a melting point of 1200 ° C. (refractory level SK6a) for preparing a glaze for surface condition preparation were prepared. Was formed by screen printing to form a glaze layer 3 for forming an uneven surface, and this was baked in a tunnel furnace at 1200 ° C. for 24 hours.

【0010】これにより、表面性状が10点平均粗さが
200〜250μm、光沢度が10〜15%、滑り抵抗
(BPN値)30〜32のタイルが得られた。
As a result, a tile having a surface texture of 10-point average roughness of 200 to 250 μm, a glossiness of 10 to 15% and a slip resistance (BPN value) of 30 to 32 was obtained.

【0011】また、長石40重量部、珪石10重量部、
珪灰石15重量部、アルミナ15重量部、粘土10重量
部及び亜鉛華10重量部とからなる融点が1230℃
(耐火度SK7)の釉薬を調整し、これをトイレ床用タ
イル素地1の表面に400μm厚に一様に施釉して下地
釉薬層2を形成した。この下地釉薬層2が生の状態で、
下地釉薬層2と同組成のものにアルミナ等の耐火度を上
げる原料粉末を25重量%以内で外添加した融点が12
80℃(耐火度SK9)の表面状態調整用の釉薬を調整
し、この釉薬をスクリーン印刷によって、凹凸面形成の
ための釉薬層3を形成し、これをトンネル炉中で125
0℃で20時間焼成した。
40 parts by weight of feldspar, 10 parts by weight of silica stone,
Wollastonite 15 parts by weight, alumina 15 parts by weight, clay 10 parts by weight and zinc white 10 parts by weight, melting point 1230 ° C
A glaze having a (refractory degree SK7) was prepared, and this was evenly glazed on the surface of the toilet floor tile base 1 to a thickness of 400 μm to form a base glaze layer 2. With this base glaze layer 2 in a raw state,
The melting point of the material having the same composition as that of the base glaze layer 2 and externally added within 25% by weight of raw material powder such as alumina for increasing the fire resistance is 12
A glaze for adjusting the surface condition at 80 ° C. (refractory SK9) was prepared, and this glaze was screen-printed to form a glaze layer 3 for forming an uneven surface.
It was baked at 0 ° C. for 20 hours.

【0012】これにより、表面性状が10点平均粗さ1
10〜135μm、光沢度6〜10%、滑り抵抗(BP
N値)41〜45のタイルが得られた。
As a result, the surface texture is 10 points and the average roughness is 1
10-135 μm, gloss 6-10%, slip resistance (BP
N value) 41-45 tiles were obtained.

【0013】これらの実施例のように、この印刷用釉薬
の焼タルクとフリットの量またはアルミナと長石の量を
増減することによって、種々の表面粗さを有するタイル
を得た。
As in these examples, tiles with varying surface roughness were obtained by increasing or decreasing the amount of baked talc and frit or the amount of alumina and feldspar of this printing glaze.

【0014】また、光沢度は表面粗さの調整と同様に、
焼タルクとフリットの量まはアルミナと長石の量を増減
することによって、光沢度を変化せしめた試料タイルを
作成した。
The glossiness is the same as the adjustment of the surface roughness.
Sample tiles with varying gloss were prepared by increasing or decreasing the amount of baked talc and frit or the amount of alumina and feldspar.

【0015】表1は各試料タイル(実施例1及び2)と
従来のタイル(比較例1〜4)の表面状態と滑り抵抗と
汚れ回復度を示す。
Table 1 shows the surface condition of each sample tile (Examples 1 and 2) and the conventional tile (Comparative Examples 1 to 4), the slip resistance and the degree of stain recovery.

【0016】[0016]

【表1】 [Table 1]

【0017】表1において、10点平均粗さRzは、東
京精密株式会社製サーコム570AによってJIS B
0601規格に基づいて測定した結果を示し、滑り抵抗
は谷藤機械工業株式会社製のスベリ抵抗測定器によって
測定した。また、光沢度は、日本電色工業株式会社製
光沢度計を用いてJIS Z 8741に基づいて測定
した値を示すものである。
In Table 1, the 10-point average roughness Rz is JIS B according to Circom 570A manufactured by Tokyo Seimitsu Co., Ltd.
The result measured based on 0601 standard is shown, and the slip resistance was measured by a sliding resistance measuring instrument manufactured by Tanifuji Machine Industry Co., Ltd. Also, the glossiness is manufactured by Nippon Denshoku Industries Co., Ltd.
It shows the value measured based on JIS Z 8741 using a gloss meter.

【0018】また、同表において汚染率%は、 汚染率%={1−(汚染後の拡散反射率/汚染前の拡散
反射)}×100 として表わし、また、回復率%は、流水洗浄によって除
去処理を行ったのちの汚染状態を 回復率%=(洗浄処理後の反射率/汚染前の拡散反射)
×100 によって示す。
Further, in the same table, the pollution rate% is expressed as pollution rate% = {1- (diffuse reflectance after pollution / diffuse reflection before pollution)} × 100, and recovery rate% is obtained by washing with running water. Recovery rate% = (Reflectivity after cleaning / Diffuse reflection before contamination)
Shown by × 100.

【0019】同表において、滑り抵抗値はKODAN
(ASTM E303)221すべり評価法によれば、
湿潤状態で「問題なし」とされ、歩行性のランクとして
「良好」のランクに入るBPN値(滑り抵抗値:Bri
tish PendulumNumberによって表わ
す。)は30〜53の間にあり、その場合の10点平均
粗さは25〜200μmの範囲内にある。
In the table, the slip resistance value is KODAN.
According to the (ASTM E303) 221 slip evaluation method,
BPN value (slip resistance value: Bri) which is regarded as “no problem” in the wet state and enters the rank of “good” as the walking property rank.
Represented by tish Pendulum Number. ) Is between 30 and 53, and the 10-point average roughness in that case is in the range of 25 to 200 μm.

【0020】また、同表において、汚染率と汚染回復率
は、それぞれ5%以内、90%以上の場合が平滑面を有
するタイルに近似するもので、これを基準にすると、そ
れぞれ光沢度が5〜20%の範囲内のものが、この汚染
率と汚染回復率における許容範囲に入る。
Further, in the table, the stain rate and the stain recovery rate are respectively within 5% and above 90%, which are similar to tiles having a smooth surface. Based on this, the glossiness is 5 respectively. Those within the range of ˜20% fall within the allowable range of the contamination rate and the contamination recovery rate.

【0021】図2は、表1に示すこれらの関係を図示し
たものである。滑り止め効果を発揮するための表面凹凸
の程度は、凹凸面の粗さが10点平均粗さで25〜20
0μmであり、且つ、光沢度が5〜20%の場合に、汚
染率、汚染回復率によって表される汚れの程度が低く、
その総合的な効果はこれらがそれぞれの規定範囲にある
場合に、最高のバランス効果を示すことが判る。
FIG. 2 illustrates these relationships shown in Table 1. The degree of surface unevenness for exhibiting the anti-slip effect is such that the roughness of the uneven surface is 25 to 20 in terms of 10-point average roughness.
When it is 0 μm and the glossiness is 5 to 20%, the degree of stain represented by the stain rate and the stain recovery rate is low,
It can be seen that the overall effect shows the best balance effect when these are in their respective prescribed ranges.

【0022】[0022]

【発明の効果】本発明によって以下の効果を奏する。The present invention has the following effects.

【0023】(1)タイルを凹凸状表面に形成し、10
点平均粗さが25〜200μmであり、且つ光沢度が5
〜20%として、表面凹凸性状と光沢度をコントロール
することにより、耐滑り性と耐汚れ性の相反する機能を
両立させたタイルを得ることが可能となる。
(1) A tile is formed on an uneven surface, and 10
The point average roughness is 25 to 200 μm, and the glossiness is 5
By controlling the surface unevenness and the glossiness to be 20%, it is possible to obtain a tile having both the anti-slip property and the anti-fouling function.

【0024】(2)格別複雑な工程を付加する必要はな
く、付着しみの除去機能を有するタイルを簡単に得るこ
とができる。
(2) It is not necessary to add a particularly complicated process, and a tile having a function of removing adhered stains can be easily obtained.

【0025】(3)凹凸面形成のための釉薬層の厚みを
変えることにより、用途に応じたノンスリップタイルが
得られる。
(3) By changing the thickness of the glaze layer for forming the uneven surface, a non-slip tile suitable for the application can be obtained.

【0026】(4)印刷技法等を用いるようにすれば、
従来のノンスリップタイルに比し、装飾性が向上する。
(4) If a printing technique or the like is used,
Decorative properties are improved compared to conventional non-slip tiles.

【図面の簡単な説明】[Brief description of drawings]

【図1】 本発明に係るタイルの製造方法の過程を示す
図である。
FIG. 1 is a diagram showing a process of a method for manufacturing a tile according to the present invention.

【図2】 表面に形成した凹凸による滑り止め効果と光
沢度による汚れの回復効果との総合効果を示す図であ
る。
FIG. 2 is a diagram showing a total effect of an anti-slip effect due to unevenness formed on the surface and a stain recovery effect due to glossiness.

【符号の説明】[Explanation of symbols]

1 タイル素地 2 下地釉薬層 3 凹凸面形成のための釉薬層 1 Tile base 2 Base glaze layer 3 Glaze layer for uneven surface formation

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 タイル表面に凹凸面を形成した滑り止め
タイルにおいて、同凹凸面の粗さが10点平均粗さで2
5〜200μmであり、且つ、同凹凸面の光沢度が5〜
20%である滑り止めタイル。
1. A non-slip tile in which an uneven surface is formed on the tile surface, wherein the uneven surface has a roughness of 2 at a 10-point average roughness.
5 to 200 μm, and the glossiness of the uneven surface is 5 to
20% non-slip tiles.
【請求項2】 タイル素地表面に、耐火度がSK3a〜
11の下地釉薬による施釉を行い、この下地施釉層が生
の状態のときに耐火度が下地釉薬と同程度もしくは高耐
火度の凹凸表面形成用釉薬による施釉を行った後、焼成
する凹凸面の粗さが10点平均粗さで50〜200μm
であり、且つ、光沢度が5〜20%である滑り止めタイ
ルの製造方法。
2. A tile base material having a fire resistance of SK3a to SK3a.
Glazing with the base glaze of No. 11 is performed, and when the base glaze layer is in a raw state, the glaze is applied with the glaze for forming uneven surface having a fire resistance equal to or higher than that of the base glaze Roughness is 10-point average roughness 50 to 200 μm
And a method for producing a non-slip tile having a gloss of 5 to 20%.
JP28479491A 1991-10-30 1991-10-30 Non-slip tile and its manufacturing method Expired - Lifetime JP3180923B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP28479491A JP3180923B2 (en) 1991-10-30 1991-10-30 Non-slip tile and its manufacturing method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP28479491A JP3180923B2 (en) 1991-10-30 1991-10-30 Non-slip tile and its manufacturing method

Publications (2)

Publication Number Publication Date
JPH05117062A true JPH05117062A (en) 1993-05-14
JP3180923B2 JP3180923B2 (en) 2001-07-03

Family

ID=17683107

Family Applications (1)

Application Number Title Priority Date Filing Date
JP28479491A Expired - Lifetime JP3180923B2 (en) 1991-10-30 1991-10-30 Non-slip tile and its manufacturing method

Country Status (1)

Country Link
JP (1) JP3180923B2 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000109384A (en) * 1998-10-02 2000-04-18 Danto Corp Stainproofing and antislipping tile and its production
EP1088635A2 (en) * 1999-09-28 2001-04-04 Ri-Wal Ceramiche S.p.A. Method for manufacturing antislip ceramic floor tiles which maintain a glossy and brilliant color and organoleptic appearance substantially identical to wall tiles, and tiles obtained thereby
JP2010116308A (en) * 2008-11-14 2010-05-27 Inax Corp Floor tile and method for manufacturing the same
CN111574246A (en) * 2020-05-14 2020-08-25 东莞市唯美陶瓷工业园有限公司 Flexible anti-slip ceramic glaze, flexible anti-slip ceramic tile and preparation method thereof
CN114573374A (en) * 2022-03-09 2022-06-03 蒙娜丽莎集团股份有限公司 Antiskid ceramic tile with glaze surface with exquisite texture and preparation method thereof
WO2023032431A1 (en) * 2021-08-31 2023-03-09 株式会社Lixil Member

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000109384A (en) * 1998-10-02 2000-04-18 Danto Corp Stainproofing and antislipping tile and its production
EP1088635A2 (en) * 1999-09-28 2001-04-04 Ri-Wal Ceramiche S.p.A. Method for manufacturing antislip ceramic floor tiles which maintain a glossy and brilliant color and organoleptic appearance substantially identical to wall tiles, and tiles obtained thereby
EP1088635A3 (en) * 1999-09-28 2002-04-24 Ri-Wal Ceramiche S.p.A. Method for manufacturing antislip ceramic floor tiles which maintain a glossy and brilliant color and organoleptic appearance substantially identical to wall tiles, and tiles obtained thereby
JP2010116308A (en) * 2008-11-14 2010-05-27 Inax Corp Floor tile and method for manufacturing the same
CN111574246A (en) * 2020-05-14 2020-08-25 东莞市唯美陶瓷工业园有限公司 Flexible anti-slip ceramic glaze, flexible anti-slip ceramic tile and preparation method thereof
WO2023032431A1 (en) * 2021-08-31 2023-03-09 株式会社Lixil Member
CN114573374A (en) * 2022-03-09 2022-06-03 蒙娜丽莎集团股份有限公司 Antiskid ceramic tile with glaze surface with exquisite texture and preparation method thereof

Also Published As

Publication number Publication date
JP3180923B2 (en) 2001-07-03

Similar Documents

Publication Publication Date Title
CN110282999B (en) Wet-water high-skid-resistance ink-jet ceramic tile with fine texture and preparation method thereof
CN103467103B (en) Production method of once-fired super-spar ceramic tile and ceramic tile
EP3339271B1 (en) Antifouling matted object
CN103351179B (en) Printing glaze material and production method thereof
CN103274767B (en) Ceramic tile with purely flat glaze and manufacturing method for ceramic tile
CN114634376A (en) Antifouling and antiskid archaized brick and preparation method thereof
CN107486946A (en) A kind of preparation method of anti-skidding Dali stone ceramic tile
JPH05117062A (en) Non-slip tile and its production
JP5482572B2 (en) Sanitary ware with antifouling matte surface
CN111574246A (en) Flexible anti-slip ceramic glaze, flexible anti-slip ceramic tile and preparation method thereof
CN111217528A (en) Anti-slip antifouling glaze layer structure, preparation method of glazed tile using same and glazed tile
CN111217526B (en) Anti-slip antifouling glaze, preparation method thereof and glazed tile using same
TW201020378A (en) Floor tile and method of manufacturing the same
JP2576322B2 (en) Non-slip tile and manufacturing method thereof
JP2601078B2 (en) Non-slip tile
JPH08133870A (en) Production of glazed product having blast-treated surface
JP4153604B2 (en) Antifouling / slip-proof tile and its manufacturing method
CN107476528A (en) A kind of super clean bright on-slip brick and its manufacture method
JPH08133876A (en) Non-slip tile and its production
JP2001072460A (en) Glazed product and its production
JP2001073435A (en) Sanitary ware and manufacture thereof
CN2679283Y (en) Skid-proof ceramic bricks
EP4177236B1 (en) Method for obtaining porcelain stoneware tiles with anti-slip surface
EP1088635A2 (en) Method for manufacturing antislip ceramic floor tiles which maintain a glossy and brilliant color and organoleptic appearance substantially identical to wall tiles, and tiles obtained thereby
CN213115341U (en) Double-glaze-surface moistureproof water seepage-proof ceramic floor tile

Legal Events

Date Code Title Description
FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090420

Year of fee payment: 8

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100420

Year of fee payment: 9

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100420

Year of fee payment: 9

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110420

Year of fee payment: 10

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120420

Year of fee payment: 11

EXPY Cancellation because of completion of term
FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120420

Year of fee payment: 11