JPH0480936B2 - - Google Patents

Info

Publication number: JPH0480936B2
Authority: JP; Japan
Prior art keywords: copolymer; film; polymerization; olefin; compounds
Prior art date: 1984-01-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP798984A

Other languages

English (en)

Japanese (ja)

Other versions

JPS60152516A (ja

Inventor

Shuji Kitamura

Kyohiko Nakae

Tadatoshi Ogawa

Teruaki Yoshida

Hajime Sadatoshi

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Sumitomo Chemical Co Ltd

Original Assignee

Sumitomo Chemical Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-01-19

Filing date

1984-01-19

Publication date

1992-12-21

1984-01-19 Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd

1984-01-19 Priority to JP798984A priority Critical patent/JPS60152516A/ja

1985-08-10 Publication of JPS60152516A publication Critical patent/JPS60152516A/ja

1992-12-21 Publication of JPH0480936B2 publication Critical patent/JPH0480936B2/ja

Status Granted legal-status Critical Current

Links

229920001577 copolymer Polymers 0.000 claims description 45
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 42
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 25
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 15
229920006280 packaging film Polymers 0.000 claims description 14
239000012785 packaging film Substances 0.000 claims description 14
125000004432 carbon atom Chemical group C* 0.000 claims description 13
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 12
239000004711 α-olefin Substances 0.000 claims description 11
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
238000009835 boiling Methods 0.000 claims description 6
239000008096 xylene Substances 0.000 claims description 6
239000007788 liquid Substances 0.000 claims description 4
229920005604 random copolymer Polymers 0.000 claims description 4
230000000379 polymerizing effect Effects 0.000 claims 1
238000006116 polymerization reaction Methods 0.000 description 27
239000003054 catalyst Substances 0.000 description 19
150000001875 compounds Chemical class 0.000 description 14
229920000642 polymer Polymers 0.000 description 14
239000010936 titanium Substances 0.000 description 13
238000000034 method Methods 0.000 description 12
-1 titanium halogen compound Chemical class 0.000 description 12
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
239000001257 hydrogen Substances 0.000 description 9
229910052739 hydrogen Inorganic materials 0.000 description 9
229910052719 titanium Inorganic materials 0.000 description 9
230000000903 blocking effect Effects 0.000 description 7
238000012685 gas phase polymerization Methods 0.000 description 7
150000002430 hydrocarbons Chemical class 0.000 description 7
150000002681 magnesium compounds Chemical class 0.000 description 7
239000000203 mixture Substances 0.000 description 7
239000007787 solid Substances 0.000 description 7
150000003623 transition metal compounds Chemical class 0.000 description 7
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 6
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
239000005977 Ethylene Substances 0.000 description 5
229920002978 Vinylon Polymers 0.000 description 5
230000000052 comparative effect Effects 0.000 description 5
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 5
229910052736 halogen Inorganic materials 0.000 description 5
150000002367 halogens Chemical class 0.000 description 5
239000002245 particle Substances 0.000 description 5
239000011949 solid catalyst Substances 0.000 description 5
238000005406 washing Methods 0.000 description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
229930195733 hydrocarbon Natural products 0.000 description 4
238000005259 measurement Methods 0.000 description 4
150000002894 organic compounds Chemical class 0.000 description 4
239000000047 product Substances 0.000 description 4
239000002002 slurry Substances 0.000 description 4
239000002904 solvent Substances 0.000 description 4
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 4
CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 3
239000004215 Carbon black (E152) Substances 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
150000001336 alkenes Chemical class 0.000 description 3
125000003545 alkoxy group Chemical group 0.000 description 3
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
150000002431 hydrogen Chemical class 0.000 description 3
229910052749 magnesium Inorganic materials 0.000 description 3
239000011777 magnesium Substances 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
230000000737 periodic effect Effects 0.000 description 3
230000000704 physical effect Effects 0.000 description 3
238000003672 processing method Methods 0.000 description 3
238000003756 stirring Methods 0.000 description 3
CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 2
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
FHUODBDRWMIBQP-UHFFFAOYSA-N Ethyl p-anisate Chemical compound CCOC(=O)C1=CC=C(OC)C=C1 FHUODBDRWMIBQP-UHFFFAOYSA-N 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
238000011088 calibration curve Methods 0.000 description 2
238000007796 conventional method Methods 0.000 description 2
USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
238000001035 drying Methods 0.000 description 2
MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
239000007789 gas Substances 0.000 description 2
150000004679 hydroxides Chemical class 0.000 description 2
239000012442 inert solvent Substances 0.000 description 2
229920000092 linear low density polyethylene Polymers 0.000 description 2
239000004707 linear low-density polyethylene Substances 0.000 description 2
238000000465 moulding Methods 0.000 description 2
150000002901 organomagnesium compounds Chemical class 0.000 description 2
229920000098 polyolefin Polymers 0.000 description 2
239000000843 powder Substances 0.000 description 2
239000002994 raw material Substances 0.000 description 2
238000000926 separation method Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
239000004753 textile Substances 0.000 description 2
HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
239000007818 Grignard reagent Substances 0.000 description 1
LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
229910010062 TiCl3 Inorganic materials 0.000 description 1
239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
150000008065 acid anhydrides Chemical class 0.000 description 1
230000003213 activating effect Effects 0.000 description 1
239000000654 additive Substances 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
238000000137 annealing Methods 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
230000000740 bleeding effect Effects 0.000 description 1
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
239000000969 carrier Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
230000001143 conditioned effect Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
238000004512 die casting Methods 0.000 description 1
HJXBDPDUCXORKZ-UHFFFAOYSA-N diethylalumane Chemical compound CC[AlH]CC HJXBDPDUCXORKZ-UHFFFAOYSA-N 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
229920001038 ethylene copolymer Polymers 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000000835 fiber Substances 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
238000010528 free radical solution polymerization reaction Methods 0.000 description 1
150000004795 grignard reagents Chemical class 0.000 description 1
238000000227 grinding Methods 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
150000002366 halogen compounds Chemical class 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
150000002484 inorganic compounds Chemical class 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
239000011630 iodine Substances 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
229920001684 low density polyethylene Polymers 0.000 description 1
239000004702 low-density polyethylene Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
239000000155 melt Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
QSSJZLPUHJDYKF-UHFFFAOYSA-N methyl 4-methylbenzoate Chemical compound COC(=O)C1=CC=C(C)C=C1 QSSJZLPUHJDYKF-UHFFFAOYSA-N 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000000178 monomer Substances 0.000 description 1
XTAZYLNFDRKIHJ-UHFFFAOYSA-N n,n-dioctyloctan-1-amine Chemical compound CCCCCCCCN(CCCCCCCC)CCCCCCCC XTAZYLNFDRKIHJ-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
150000002903 organophosphorus compounds Chemical class 0.000 description 1
150000003961 organosilicon compounds Chemical class 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000010926 purge Methods 0.000 description 1
230000005855 radiation Effects 0.000 description 1
238000010992 reflux Methods 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
230000001932 seasonal effect Effects 0.000 description 1
239000012748 slip agent Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
238000012360 testing method Methods 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
150000003609 titanium compounds Chemical class 0.000 description 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
XTTGYFREQJCEML-UHFFFAOYSA-N tributyl phosphite Chemical compound CCCCOP(OCCCC)OCCCC XTTGYFREQJCEML-UHFFFAOYSA-N 0.000 description 1
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
238000005303 weighing Methods 0.000 description 1
PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1

Landscapes

Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Manufacture Of Macromolecular Shaped Articles (AREA)
Polymerisation Methods In General (AREA)

JP798984A 1984-01-19 1984-01-19 包装フイルム Granted JPS60152516A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP798984A JPS60152516A (ja)	1984-01-19	1984-01-19	包装フイルム

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP798984A JPS60152516A (ja)	1984-01-19	1984-01-19	包装フイルム

Publications (2)

Publication Number	Publication Date
JPS60152516A JPS60152516A (ja)	1985-08-10
JPH0480936B2 true JPH0480936B2 (de)	1992-12-21

Family

ID=11680823

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP798984A Granted JPS60152516A (ja)	1984-01-19	1984-01-19	包装フイルム

Country Status (1)

Country	Link
JP (1)	JPS60152516A (de)

1984
- 1984-01-19 JP JP798984A patent/JPS60152516A/ja active Granted

Also Published As

Publication number	Publication date
JPS60152516A (ja)	1985-08-10

Legal Events

Date	Code	Title	Description
2003-12-21	LAPS	Cancellation because of no payment of annual fees

Publication	Publication Date	Title
US4675247A (en)	1987-06-23	Laminated polypropylene film
US4820775A (en)	1989-04-11	Alpha-olefin block copolymer particles and process for the production thereof
KR920002776B1 (ko)	1992-04-03	포장용 수축 필름
EP0306939A1 (de)	1989-03-15	Fester Katalysatorbestandteil für Olefincopolymerisation und Verfahren für die Olefincopolymerisation unter Anwendung dieses Bestandteils
KR940000276B1 (ko)	1994-01-14	랜덤 공중합체의 제조방법
US4761462A (en)	1988-08-02	Packaging propylene copolymer film
US4433110A (en)	1984-02-21	Process for producing propylene block copolymers
GB2034337A (en)	1980-06-04	Preparation of ethylene-propylene
EP0719829A1 (de)	1996-07-03	Polypropylenzusammensetzung sowie laminierte und orientierte Folie daraus
JPH0582416B2 (de)	1993-11-18
JP3290293B2 (ja)	2002-06-10	ポリプロピレン樹脂および延伸フィルム
JP4759235B2 (ja)	2011-08-31	ポリプロピレン系積層フィルム
JPS61169246A (ja)	1986-07-30	ポリプロピレン積層フイルム
JPH0480936B2 (de)	1992-12-21
EP0138054B1 (de)	1991-10-23	Verpackungsfolie aus Propylencopolymer
JP3816971B2 (ja)	2006-08-30	フィルム用ポリプロピレン系樹脂及びそれを用いたフィルム
JPS5922946A (ja)	1984-02-06	フイルム成形用高品質エチレン−αオレフイン共重合体系樹脂組成物およびその製造法
JPH0481507B2 (de)	1992-12-24
JPH0527534B2 (de)	1993-04-21
JP2533321B2 (ja)	1996-09-11	ポリプロピレン積層フィルム
JP2767706B2 (ja)	1998-06-18	プロピレン共重合体組成物及びその製造方法
JPS60235812A (ja)	1985-11-22	軟質プロピレンランダム共重合体
JPH01118504A (ja)	1989-05-11	オレフィン重合用固体触媒成分の乾燥方法
JPH0481508B2 (de)	1992-12-24
JPH01247444A (ja)	1989-10-03	樹脂組成物