JPH0477562A - Stabilized colored pigment and cosmetic containing the same - Google Patents
Stabilized colored pigment and cosmetic containing the sameInfo
- Publication number
- JPH0477562A JPH0477562A JP2187050A JP18705090A JPH0477562A JP H0477562 A JPH0477562 A JP H0477562A JP 2187050 A JP2187050 A JP 2187050A JP 18705090 A JP18705090 A JP 18705090A JP H0477562 A JPH0477562 A JP H0477562A
- Authority
- JP
- Japan
- Prior art keywords
- pigment
- purple
- colored pigment
- inorganic substance
- purple root
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000049 pigment Substances 0.000 title claims abstract description 100
- 239000002537 cosmetic Substances 0.000 title claims abstract description 16
- 239000000126 substance Substances 0.000 claims abstract description 25
- 239000013078 crystal Substances 0.000 claims abstract description 10
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 7
- 159000000009 barium salts Chemical class 0.000 claims description 5
- 238000004043 dyeing Methods 0.000 abstract description 4
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052901 montmorillonite Inorganic materials 0.000 abstract description 2
- 210000004243 sweat Anatomy 0.000 abstract description 2
- 238000004040 coloring Methods 0.000 abstract 1
- 239000002932 luster Substances 0.000 abstract 1
- NEZONWMXZKDMKF-JTQLQIEISA-N Alkannin Chemical compound C1=CC(O)=C2C(=O)C([C@@H](O)CC=C(C)C)=CC(=O)C2=C1O NEZONWMXZKDMKF-JTQLQIEISA-N 0.000 description 16
- UNNKKUDWEASWDN-UHFFFAOYSA-N alkannin Natural products CC(=CCC(O)c1cc(O)c2C(=O)C=CC(=O)c2c1O)C UNNKKUDWEASWDN-UHFFFAOYSA-N 0.000 description 16
- 241001071917 Lithospermum Species 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- 238000000605 extraction Methods 0.000 description 11
- 239000003960 organic solvent Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000002904 solvent Substances 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 8
- 239000010445 mica Substances 0.000 description 8
- 229910052618 mica group Inorganic materials 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 238000001228 spectrum Methods 0.000 description 8
- 235000019646 color tone Nutrition 0.000 description 7
- 239000012141 concentrate Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 230000003595 spectral effect Effects 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 235000019441 ethanol Nutrition 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 235000012211 aluminium silicate Nutrition 0.000 description 4
- 238000004113 cell culture Methods 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 229910010272 inorganic material Inorganic materials 0.000 description 4
- 239000011147 inorganic material Substances 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- 239000000454 talc Substances 0.000 description 4
- 229910052623 talc Inorganic materials 0.000 description 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- -1 Kaipan as a mordant Chemical class 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 244000172533 Viola sororia Species 0.000 description 3
- 230000003110 anti-inflammatory effect Effects 0.000 description 3
- 235000008429 bread Nutrition 0.000 description 3
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 3
- 229910001679 gibbsite Inorganic materials 0.000 description 3
- 230000003100 immobilizing effect Effects 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229910052627 muscovite Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 241001237961 Amanita rubescens Species 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229930192627 Naphthoquinone Natural products 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 206010040829 Skin discolouration Diseases 0.000 description 2
- 235000005811 Viola adunca Nutrition 0.000 description 2
- 240000009038 Viola odorata Species 0.000 description 2
- 235000013487 Viola odorata Nutrition 0.000 description 2
- 235000002254 Viola papilionacea Nutrition 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 2
- 229910001626 barium chloride Inorganic materials 0.000 description 2
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical class [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000002791 naphthoquinones Chemical class 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 230000000144 pharmacologic effect Effects 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 239000001057 purple pigment Substances 0.000 description 2
- 238000010898 silica gel chromatography Methods 0.000 description 2
- 125000005624 silicic acid group Chemical group 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- KEIFWROAQVVDBN-UHFFFAOYSA-N 1,2-dihydronaphthalene Chemical compound C1=CC=C2C=CCCC2=C1 KEIFWROAQVVDBN-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- 241000118825 Alkanna tinctoria Species 0.000 description 1
- 235000005039 Brassica rapa var. dichotoma Nutrition 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 206010020649 Hyperkeratosis Diseases 0.000 description 1
- BVRYLTBIGIAADD-MRXNPFEDSA-N Isobutylshikonin Chemical compound C1=CC(O)=C2C(=O)C([C@@H](CC=C(C)C)OC(=O)C(C)C)=CC(=O)C2=C1O BVRYLTBIGIAADD-MRXNPFEDSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- PHTGVPBJVHRZJY-UHFFFAOYSA-N Shikonine Natural products CC(CC=C(C)C)C1=C(O)C(=O)c2c(O)ccc(O)c2C1=O PHTGVPBJVHRZJY-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 240000001417 Vigna umbellata Species 0.000 description 1
- 235000011453 Vigna umbellata Nutrition 0.000 description 1
- MXANJRGHSFELEJ-MRXNPFEDSA-N [(1r)-1-(5,8-dihydroxy-1,4-dioxonaphthalen-2-yl)-4-methylpent-3-enyl] 3-hydroxy-3-methylbutanoate Chemical compound C1=CC(O)=C2C(=O)C([C@H](OC(=O)CC(C)(C)O)CC=C(C)C)=CC(=O)C2=C1O MXANJRGHSFELEJ-MRXNPFEDSA-N 0.000 description 1
- WNFXUXZJJKTDOZ-HNNXBMFYSA-N [(1s)-1-(5,8-dihydroxy-1,4-dioxonaphthalen-2-yl)-4-methylpent-3-enyl] acetate Chemical compound C1=CC(O)=C2C(=O)C([C@@H](OC(C)=O)CC=C(C)C)=CC(=O)C2=C1O WNFXUXZJJKTDOZ-HNNXBMFYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- HDYRYUINDGQKMC-UHFFFAOYSA-M acetyloxyaluminum;dihydrate Chemical compound O.O.CC(=O)O[Al] HDYRYUINDGQKMC-UHFFFAOYSA-M 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229940009827 aluminum acetate Drugs 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- BATBOVZTQBLKIL-QGZVFWFLSA-N beta,beta-Dimethylacrylshikonin Chemical compound C1=CC(O)=C2C(=O)C([C@H](OC(=O)C=C(C)C)CC=C(C)C)=CC(=O)C2=C1O BATBOVZTQBLKIL-QGZVFWFLSA-N 0.000 description 1
- MXANJRGHSFELEJ-UHFFFAOYSA-N beta:-hydroxy isovaleryl shikonin Natural products C1=CC(O)=C2C(=O)C(C(OC(=O)CC(C)(C)O)CC=C(C)C)=CC(=O)C2=C1O MXANJRGHSFELEJ-UHFFFAOYSA-N 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 244000130745 brown sarson Species 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 230000010261 cell growth Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- BVRYLTBIGIAADD-UHFFFAOYSA-N isobutyryl shikonin Natural products C1=CC(O)=C2C(=O)C(C(CC=C(C)C)OC(=O)C(C)C)=CC(=O)C2=C1O BVRYLTBIGIAADD-UHFFFAOYSA-N 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 125000001288 lysyl group Chemical group 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- KVOIJEARBNBHHP-UHFFFAOYSA-N potassium;oxido(oxo)alumane Chemical compound [K+].[O-][Al]=O KVOIJEARBNBHHP-UHFFFAOYSA-N 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000013587 production medium Substances 0.000 description 1
- 210000001938 protoplast Anatomy 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- WNFXUXZJJKTDOZ-UHFFFAOYSA-N shikonin acetate Natural products C1=CC(O)=C2C(=O)C(C(OC(C)=O)CC=C(C)C)=CC(=O)C2=C1O WNFXUXZJJKTDOZ-UHFFFAOYSA-N 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910000108 silver(I,III) oxide Inorganic materials 0.000 description 1
- 230000037380 skin damage Effects 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- FKHIFSZMMVMEQY-UHFFFAOYSA-N talc Chemical compound [Mg+2].[O-][Si]([O-])=O FKHIFSZMMVMEQY-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、新規な安定化された有色顔料及びそれを含有
する化粧料に関するものである。さらに詳しくいえば、
本発明は、紫根の色素をマイカなどの層状結晶構造を有
する微粒状無機物質に固定化し、安定化させて成る有色
顔料及びこのものを含有して成る化粧料に関するもので
ある。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a novel stabilized colored pigment and cosmetics containing the same. In more detail,
The present invention relates to a colored pigment made by fixing and stabilizing a purple root pigment in a fine particulate inorganic substance having a layered crystal structure, such as mica, and to cosmetics containing this colored pigment.
従来の技術
従来、薬草ムラサキ（Ｌｉｔｈｏｓｐｅｒｍｕｍ ｏｆ
ｆｉｎｎａｌｅ）の根部、すなわち紫根にはナフトキノ
ン系色素であるシコニンやそのエステル体が含まれてい
ることが知られている。Conventional technology Traditionally, the medicinal herb Lithospermum of
It is known that the roots of P. finnale, that is, the purple roots, contain the naphthoquinone pigment shikonin and its esters.
この紫根の色素は、ｐＨによって酸性領域の赤色からア
ルカリ領域の青色まで色調が変化する性質を有し、鮮や
かな赤色を呈する状態で紫根の色素を安定的に固定化さ
せることは、これまで容易でなかった。The color of this purple root pigment changes depending on the pH, from red in the acidic region to blue in the alkaline region, and until now it has been easy to stably immobilize the purple root pigment in a state where it exhibits a bright red color. It wasn't.
紫根の色素を安定的に固定化させる方法としては、通常
開パンなどのアルミニウム塩を媒染剤として用いる方法
が行われているが、この方法においては、固定化され発
色する色調は紫ないし青紫であって、赤色を星する状態
で安定的に固定化することができないという欠点がある
。The usual method for stably fixing purple root pigments is to use aluminum salts such as Kaipan as a mordant, but in this method, the color tone that is fixed and developed is purple or blue-purple. However, it has the disadvantage that it cannot be stably immobilized in a red-colored state.
また、紫根の色素を顔料化して化粧料に用いることが試
みられているが、この場合、用いられる顔料は、絹の微
粉末などの有機物質に、前記のように明パンなどのアル
ミニウム塩を媒染剤とじて用いて、紫根の色素を紫ない
し胃紫の色調に発色させ、固定化させたものであって、
鮮やかな赤色を呈する状態で安定的に固定化させたもの
ではない。In addition, attempts have been made to turn purple root pigments into pigments and use them in cosmetics, but in this case, the pigments used are organic substances such as fine silk powder mixed with aluminum salts such as light bread as described above. It is made by using a mordant to develop and fix the pigment of the purple root to a purple or gastropurple tone,
It is not stably immobilized in a state where it exhibits a bright red color.
二のように、紫根の色素を鮮やかな赤色を呈する状態で
安定的に固定化させて成る顔料は、これまで見い出され
ていないのが実状である。また、マイカやタルクなどの
無機質担体に、紫根の色素を安定的に固定化させた例は
これまで知られていない。The reality is that no pigment has been found so far that is made by stably immobilizing a purple root pigment in a state that gives it a bright red color. Furthermore, there is no known example of stably immobilizing purple root pigment on an inorganic carrier such as mica or talc.
発明が解決しようとする課題
本発明は、このような事情のもとで、紫根の色素を無機
質担体に安定的に固定化した顔料、特に赤色を呈する状
態で安定的に固定化した顔料及びこのものを含有して成
る化粧料を提供することを目的としてなされＩこもので
ある。Problems to be Solved by the Invention Under these circumstances, the present invention provides a pigment in which a purple root pigment is stably immobilized on an inorganic carrier, particularly a pigment stably immobilized in a red color, and a pigment in which this pigment is stably immobilized in a red color. This product was created for the purpose of providing cosmetics containing the following ingredients:
課題を解決するための手段
本発明者らは、紫根の色素を安定的に固定化させること
について鋭意研究を重ねた結果、担体として層状結晶構
造を有する微粒状無機物質を用いることにより、紫根の
色素を安定的に固定することができ、しかも条件によっ
ては鮮やかな赤色を呈する状態で安定的に固定化しうろ
ことを見い出し、この知見に基づいて本発明を完成する
に至りＩこ。Means for Solving the Problems As a result of intensive research into stably immobilizing the pigment of purple root, the present inventors found that by using a fine particulate inorganic substance with a layered crystal structure as a carrier, the pigment of purple root can be stably immobilized. We have discovered scales that can stably immobilize pigments and, depending on the conditions, can stably immobilize them with a bright red color.Based on this knowledge, we have completed the present invention.
すなわち、本発明は、層状結晶構造を有する無機物質に
、紫根の色素を含浸させて成る安定化された有色顔料、
及びこの安定化された有色顔料を含有して成る化粧料を
提供するものである。That is, the present invention provides a stabilized colored pigment made by impregnating an inorganic substance with a layered crystal structure with a purple pigment,
The present invention also provides a cosmetic containing this stabilized colored pigment.
以下、本発明の詳細な説明する。The present invention will be explained in detail below.
本発明において用いられる無機物質については、層状結
晶構造すなわち板状結晶が重なりあって層状を形成する
構造を有するものであればよく、特に制限はないが、例
えばケイ酸四面体の層と層との間に、アルミニウム原子
及びカリウム原子を含んだ三層構造を有し、化学式
％式％（）
で表わされるマイカ（白雲母）、該マイカ（白雲母）と
同様の一般組成を有するが、５：０２とＡｇ２Ｏ，との
比において、５ｉ０２の割合の多い組成をもつセリサイ
ト、三層構造型四面網状ケイ酸基を有し、化学式
％式％（）
で表わされるタルク、ケイ酸四面体の層とジブサイト層
との二層構造を有し、化学式
％式％（）
で表わされるカオリン及び天然のコロイド性含水ケイ酸
アルミニウムの１種でベントナイトの主成分であり、ケ
イ酸四面体層−アルミナ八面体層−ケイ酸四面体層が重
なりあって結合した結晶層を有し、モデル的に化学式
％式％（）
で表わされるモンモリロナイトなどが好ましく用いられ
る。The inorganic substance used in the present invention is not particularly limited as long as it has a layered crystal structure, that is, a structure in which plate crystals overlap to form a layer. Mica (muscovite) has a three-layer structure containing an aluminum atom and a potassium atom in between, and has the same general composition as mica (muscovite), which is represented by the chemical formula % (). :02 and Ag2O, sericite has a composition with a high proportion of 5i02, has a three-layer structure type tetrahedral network silicic acid group, and has a chemical formula of % talc and silicate tetrahedron. It has a two-layer structure of a gibbsite layer and a gibbsite layer, and is a type of kaolin and natural colloidal hydrous aluminum silicate represented by the chemical formula % () and is the main component of bentonite. Montmorillonite, which has a crystal layer in which an octahedral layer and a silicate tetrahedral layer are overlapped and bonded, and is represented by the chemical formula %() as a model, is preferably used.
本発明においては、これらの層状結晶構造を有する微粒
状無機物質をそのまま用いてもよいし、あるいは水溶性
アルミニウム塩又はバリウム塩で処理したものを用いて
もよい。このように処理したものを用いると得られる顔
料は耐光性が向上する傾向がみられる。水溶性アルミニ
ウム塩としては、例えば塩化アルミニウム、酢酸アルミ
ニウム、明パン、アルミン酸ナトリウム、アルミン酸カ
リウムなどが挙げられ、これらの水溶性アルミニウム塩
で処理したものを用いると青色系の色調を有する有色顔
料が得られる。また、水溶性バリウム塩としては、例え
ば塩化バリウム、酸化バリウム、硝酸バリウム、水酸化
バリウムなどが挙げられ、これらの水溶性バリウム塩で
処理したものを用いると赤色系の色調を有する有色顔料
が得られる。In the present invention, these fine particulate inorganic substances having a layered crystal structure may be used as they are, or those treated with a water-soluble aluminum salt or barium salt may be used. Pigments obtained by such treatment tend to have improved light resistance. Examples of water-soluble aluminum salts include aluminum chloride, aluminum acetate, light bread, sodium aluminate, potassium aluminate, etc. When treated with these water-soluble aluminum salts, colored pigments with a blue tone can be produced. is obtained. Examples of water-soluble barium salts include barium chloride, barium oxide, barium nitrate, barium hydroxide, etc. When treated with these water-soluble barium salts, colored pigments with a red tone can be obtained. It will be done.
処理方法としては、例えば前記水溶性のアルミニウム塩
やバリウム塩を溶解した水溶液中に、層状構造を有する
微粒状無機物質を、８０〜９０°Ｃ程度の温度でｌＯ〜
１００分間程度浸せき処理したのち、ろ過などの手段で
取り出し、乾燥するといった方法が用いられる。As a treatment method, for example, fine particulate inorganic substances having a layered structure are added to an aqueous solution containing the water-soluble aluminum salt or barium salt at a temperature of about 80 to 90°C.
A method is used in which the material is soaked for about 100 minutes, then taken out by means such as filtration, and dried.
本発明ｌ二おいて、紫根色素の担体として用いられる前
記微粒状無機物質の平均粒子径は、通常０．１〜５０μ
ｍの範囲で選ばれる。In the second aspect of the present invention, the average particle diameter of the fine particulate inorganic substance used as a carrier for the purple root pigment is usually 0.1 to 50μ.
selected within the range of m.
一方、本発明において用いられる紫根の色素は、天然の
ムラサキの根から抽出した色素抽出物であってもよいし
、バイオテクノロジーにより細胞培養や毛状根培養によ
って得られたシコニンであってもよく、あるいは化学合
成により得られたシコニンであってもよい。On the other hand, the purple root pigment used in the present invention may be a pigment extract extracted from natural purple roots, or may be shikonin obtained by cell culture or hairy root culture using biotechnology. Alternatively, shikonin obtained by chemical synthesis may be used.
天然の紫根には、−数式
（式中のＲは水素原子又は有機基である）で表わされる
ナフトキノン系色素のシコニン系化合物か含まれている
。前記−数式（Ｖ）において、Ｒか水素原子の場合、該
化合物はシコニンであるが、通常Ｒが有機基のエステル
体として存在する。Natural purple roots contain a shikonine compound, a naphthoquinone pigment, represented by the formula - (in which R is a hydrogen atom or an organic group). In the formula (V) above, when R is a hydrogen atom, the compound is shikonin, but R usually exists as an ester of an organic group.
また、欧州産ムラサキ科植物Ａｌｃａｎｎａ ｔｉｎｃ
ｔｏｒｉａの根には、前記シコニンの光学対掌体アルカ
ンニンが含まれているが、本発明においてはこのものも
用いることもできる。In addition, Alcanna tinc, a European plant of the Murasaceae family,
toria root contains alkanine, which is the optical antipode of the above-mentioned shikonin, and this can also be used in the present invention.
本発明において用いられる紫根の色素を、紫根から抽出
する場合、通常ムラサキの根を十分に乾燥させたのち、
細かく砕き、これに適当な抽出溶媒を加えて、２〜５日
間程度放置し、次いで遠心分離やろ過などの手段を用い
て固形分を除去し、得られた抽出液から溶媒を留去させ
ることによって、色素抽出物（濃縮物）を得る方法が用
いられる。When extracting the purple root pigment used in the present invention from the purple root, the purple root is usually sufficiently dried and then
Grind it finely, add an appropriate extraction solvent to it, leave it for about 2 to 5 days, then remove the solid content using means such as centrifugation or filtration, and distill off the solvent from the resulting extract. A method for obtaining a pigment extract (concentrate) is used.
この際、使用する抽出溶媒としては、例えばメチルアル
コール、エチルアルコーノ呟プロピルアルコール、イソ
プロピルアルコール、ブチルアルコール、エチレングリ
コーノへプロピレンクリコール、ジメチルエーテル、ジ
エチルエーテル、イソプロピルエーテル、ジオキサン、
アセトン、メチルイソブチルケトン、メチルエチルケト
ン、酢酸エチル、ジクロロメタン、クロロホルム、四塩
化炭素、トリクレン、パークレン、ベンゼン、トルエン
なとの通常の有機溶媒を挙げることができ、これらの溶
媒は１種用いてもよいし、２種以上混合して用いてもよ
い。In this case, the extraction solvent used is, for example, methyl alcohol, ethyl alcohol, propyl alcohol, isopropyl alcohol, butyl alcohol, ethylene glycol, propylene glycol, dimethyl ether, diethyl ether, isopropyl ether, dioxane,
Usual organic solvents such as acetone, methyl isobutyl ketone, methyl ethyl ketone, ethyl acetate, dichloromethane, chloroform, carbon tetrachloride, trichlene, perchlorene, benzene, and toluene can be mentioned, and one type of these solvents may be used or , two or more types may be used in combination.
このようにして得られた色素抽出物の収量は、天然産の
ムラサキの根を用いる場合、その乾燥重量に対し、通常
４〜５重量％程度である。また、該色素抽出物には、通
常シコニン、イソブチル−シコニン、β、β−ジメチル
アクリルーシコニン、アセチル−シコニン、テラクリル
−シコニン、β−ヒドロキシイソバレリル−シコニンな
どのシコニン系化合物から成る色素、さらに水溶性の脂
肪酸及び吉草酸などの夾雑物が含まれており、この夾雑
物による臭気が紫根の特異臭となっている。The yield of the pigment extract thus obtained is usually about 4 to 5% by weight based on the dry weight of naturally produced purple roots. In addition, the pigment extract usually includes pigments consisting of shikonin compounds such as shikonin, isobutyl-shikonin, β, β-dimethylacryl-shikonin, acetyl-shikonin, terracryl-shikonin, and β-hydroxyisovaleryl-shikonin. Furthermore, it contains impurities such as water-soluble fatty acids and valeric acid, and the odor caused by these impurities is the characteristic odor of purple root.
この夾雑物は前記抽出処理において、抽出温度が高く、
かつ処理時間が長くなると増加するので、抽出処理は室
温で２日ないし３日間前後が適当である。また、紫根の
特異臭を特に嫌う場合には、前記のようにして得られた
色素抽出物をさらに精製して用いることが好ましい。These impurities are removed at a high extraction temperature in the extraction process,
Since the amount increases as the treatment time increases, it is appropriate to perform the extraction treatment at room temperature for about 2 to 3 days. In addition, if the peculiar odor of purple root is particularly disliked, it is preferable to use the pigment extract obtained as described above after further purification.
該色素抽出物から、水溶性の夾雑物を取り除き、シコニ
ンなどの色素成分のみを分割して取り出すための精製方
法としては、例えば抽出物をシリカゲルクロマトグラフ
ィーや７０リジル（７０リジル社製、商品名、活性化ケ
イ酸マグネシウム）で処理する方法などを用いることか
できる。As a purification method for removing water-soluble impurities from the pigment extract and dividing and extracting only pigment components such as shikonin, for example, the extract can be purified using silica gel chromatography or 70 Lysyl (manufactured by 70 Lysyl Co., Ltd., trade name). , activated magnesium silicate), etc. can be used.
前記シリカゲルクロマトグラフィーなとによる精製を行
う際に用いられる溶離液としては、比較的極性が低く、
しかもシコニン系化合物の中には熱に不安定なものがあ
ることから、濃縮時の減圧沸点が５０°Ｃ／ １０〜３
０ ｍｍＨｇを超えない有機溶媒が好ましい。このよう
な溶媒としては、例えばジクロロメタン、クロロホルム
、四塩化炭素、トリクレン、パークレンなどの塩素化炭
化水素類、トルエン、ベンゼンなどの芳香族炭化水素な
どが挙げられ、これらの溶媒は１種用いてもよいし、２
種以上を混合して用いてもよい。The eluent used for purification by silica gel chromatography has relatively low polarity;
Moreover, some shikonin compounds are unstable to heat, so the boiling point under reduced pressure during concentration is 50°C/10~3
Organic solvents that do not exceed 0 mmHg are preferred. Examples of such solvents include chlorinated hydrocarbons such as dichloromethane, chloroform, carbon tetrachloride, tricrene, and perchlorene, and aromatic hydrocarbons such as toluene and benzene. Good, 2
A mixture of more than one species may be used.
また、ムラサキの細胞培養によって得られるシコニンは
、ムラサキの切り口から生成したカルス（無定形の細胞
集塊）の酵素処理によって得られるプロトプラスト（原
形質体）からシコニンの生産性が高い株を選択し、これ
を第一段の細胞増殖培地と第二段のシコニン生産培地か
ら成る２段培養生産プロセスによって生産される。この
ような細胞培養によるシコニンはすでに商業生産されて
いる。In addition, shikonin can be obtained by cell culture of purple violets by selecting a strain with high shikonin productivity from protoplasts obtained by enzymatic treatment of callus (amorphous cell aggregates) generated from cut ends of purple violet. This is produced by a two-stage culture production process consisting of a cell growth medium in the first stage and a shikonin production medium in the second stage. Shikonin has already been commercially produced using such cell culture.
さらに、合成シコニンは、ジヒドロナフタレン又は２−
ホルミル−１，４，５，８−テトラメトキンナフタレン
を原料として製造される。In addition, synthetic shikonin may be dihydronaphthalene or 2-
It is manufactured using formyl-1,4,5,8-tetramethquinaphthalene as a raw material.
このような紫根の色素を、前記の層状構造を有する微粒
状無機物質に含浸させて、有色顔料を調製するには、通
常有機溶媒で紫根の色素を溶解した溶液を水浴に加えて
、かきまぜながら層状構造を有する無機物質粉末を、染
浴中に分散させる方法が用いられる。In order to prepare a colored pigment by impregnating such a purple root pigment into the above-mentioned fine particulate inorganic substance having a layered structure, a solution of the purple root pigment dissolved in an organic solvent is usually added to a water bath, and the mixture is stirred. A method is used in which an inorganic substance powder having a layered structure is dispersed in a dye bath.
染浴は、酸性であることが好ましく、有機溶媒で紫根の
色素を溶解した溶液を水浴に加えた染浴のｐＨは、都合
よく４〜５の弱酸性の範囲で維持される。したがって、
酸性水溶液などでｐＨを調整することなく紫根の色素を
層状構造を有する無機物質に含浸させることかできる。The dye bath is preferably acidic, and the pH of the dye bath is conveniently maintained in a slightly acidic range of 4 to 5 by adding a solution of purple root pigment in an organic solvent to the water bath. therefore,
It is possible to impregnate an inorganic substance having a layered structure with a purple root pigment without adjusting the pH using an acidic aqueous solution or the like.
所定温度で所定時間染着すると染浴中の紫根の色素によ
って、層状構造を有する無機物質は所望の色に染着され
る。染着された無機物質をろ過分数し、乾燥したのち、
必要に応じ湿式粉砕機などで粉砕することによって、所
望の色調、例えば赤、青紫、暗緑色、紫などの色調を有
する有色顔料を得ることができる。When dyed at a predetermined temperature for a predetermined time, the inorganic substance having a layered structure is dyed in the desired color by the purple pigment in the dye bath. After filtering and drying the dyed inorganic substances,
By pulverizing with a wet pulverizer or the like as necessary, a colored pigment having a desired color tone, for example, red, blue-violet, dark green, purple, etc., can be obtained.
このようにして得られた有色顔料は、微粉砕しても白色
化することはなく、安定した色調を呈し、堅牢度に優れ
ている。また、染着条件を適当に選択することにより、
鮮やかな色調を有する赤色系〜青色系の顔料を得ること
ができる。The colored pigment thus obtained does not turn white even when pulverized, exhibits a stable color tone, and has excellent fastness. In addition, by appropriately selecting the dyeing conditions,
A red to blue pigment with a vivid color tone can be obtained.
ムラサキの根から抽出した紫根の色素抽出物を用いる場
合には、抽出溶液を濃縮することなく、得られた抽出溶
液を、そのまま使用することもできる。When using a purple root pigment extract extracted from the roots of the purple root, the obtained extraction solution can be used as it is without concentrating the extraction solution.
紫根の色素抽出物（濃縮物）や細胞培養によって得られ
るシコニンなとを溶解する有機溶媒としては、ムラサキ
の根から紫根の色素を抽出するために用いた溶媒と同様
の有機溶媒が好ましい。有機溶媒が水と混和しない溶媒
である場合ｌコは、染浴は、用いた有機溶媒と水との二
層に分離しｔ：不均一な溶媒系となるが、それでも差し
支えない。The organic solvent for dissolving the purple root pigment extract (concentrate) and shikonin obtained by cell culture is preferably the same organic solvent as the solvent used to extract the purple root pigment from the purple root. If the organic solvent is a solvent that is immiscible with water, the dye bath will separate into two layers, the organic solvent used and water, resulting in a non-uniform solvent system, but this is acceptable.
このようにして調製される染浴は水と紫根の色素を溶解
するために用いた有機溶媒との混合溶媒となるが、この
水と有機溶媒の混合比は自由に選択できる。また、この
水と有機溶媒が混合した染浴中の溶媒量は、層状構造を
有する無機物質の重量に対して、重量対容量比で５〜３
０倍が適当である。The dyebath prepared in this way is a mixed solvent of water and the organic solvent used to dissolve the purple root pigment, but the mixing ratio of water and organic solvent can be freely selected. In addition, the amount of solvent in the dye bath in which water and organic solvent are mixed is 5 to 3 in weight-to-volume ratio relative to the weight of the inorganic material having a layered structure.
0 times is appropriate.
紫根の色素の使用量は、用いる層状構造を有する無機物
質に対して、１重量％以上、好ましくは５重量％以上が
望ましいが、使用量が１重量％未満であっても、同様の
染着処理を繰り返すことによって、鮮やかな色調を有す
る有色顔料を得ることができる。The amount of purple root pigment to be used is preferably 1% by weight or more, preferably 5% by weight or more, based on the inorganic material with a layered structure used, but even if the amount used is less than 1% by weight, the same dyeing effect will occur. By repeating the process, colored pigments with vivid color tones can be obtained.
染浴中での処理温度は、６０°Ｃ以下が好ましく室温で
もよいが、４０〜５０℃の範囲が適している。また、処
理時間は１５分以上、好ましくは３０分〜２時間が適し
ている。The treatment temperature in the dyebath is preferably 60°C or less, and may be room temperature, but a range of 40 to 50°C is suitable. Further, the processing time is suitable for 15 minutes or more, preferably 30 minutes to 2 hours.
紫根の色素成分であるシコニン系化合物は、抗炎、抗菌
、皮膚損傷治ゆなとの薬理作用を有することが知られて
おり、したがって本発明の有色顔料は、化粧料の着色剤
として極めて好適である。Shikonin compounds, which are pigment components of purple root, are known to have pharmacological effects such as anti-inflammatory, antibacterial, and skin damage-healing properties. Therefore, the colored pigment of the present invention is extremely suitable as a coloring agent for cosmetics. be.
本発明のもう１つの目的は、前記の有色顔料を含有する
化粧料を提供することにある。化粧料としては、例えば
アイシャドウ、はお紅、おしろい、口紅、美爪料などが
挙げられる。Another object of the present invention is to provide a cosmetic containing the above-mentioned colored pigment. Cosmetics include, for example, eye shadow, blusher, face powder, lipstick, nail polish, and the like.
該有色顔料を含有する本発明の化粧料は、光沢のある色
調を有し、かつ肌の透明感が極めて良好である上、肌へ
の着色性と耐水性（耐汗性）に優れるなどの特徴を有し
ている。The cosmetic of the present invention containing the colored pigment has a glossy color tone, extremely good skin transparency, and has excellent skin coloring properties and water resistance (sweat resistance). It has characteristics.
発明の効果
本発明の有色顔料は、層状構造を有する微粒状無機物質
に紫根の色素を含浸させて、該色素のもつ鮮やかな色調
、例えば赤、青紫、暗緑色、紫などの色調を安定化させ
たものであって、化粧料などの着色剤として好適に用い
られる。Effects of the Invention The colored pigment of the present invention is produced by impregnating a fine particulate inorganic material with a layered structure with a purple-root pigment, thereby stabilizing the vivid color tones of the pigment, such as red, blue-violet, dark green, and violet. It is suitable for use as a coloring agent in cosmetics and the like.
また、本発明の化粧料は前記顔料を含有するものであっ
て、肌への着色性と耐水性に優れ、かつ光沢のある色調
をもち、しかも該顔料に含まれる紫根の色素が抗炎、抗
菌、皮膚損傷治ゆなとの薬理作用を有するなどの優れた
特徴を有し、例えばアイシャドウ、はお紅、おしろい、
口紅、美爪料などとして用いられる。In addition, the cosmetic of the present invention contains the pigment, has excellent skin coloring properties and water resistance, and has a glossy tone, and the purple root pigment contained in the pigment has anti-inflammatory and anti-inflammatory properties. It has excellent characteristics such as antibacterial and pharmacological effects that help heal skin damage.
It is used as lipstick, nail polish, etc.
実施例
次に、実施例により本発明をさらに詳細に説明するが、
本発明はこれらの例によってなんら限定されるものでは
ない。Examples Next, the present invention will be explained in more detail with reference to examples.
The present invention is not limited in any way by these examples.
なお、得られた顔料の物性は次のようにして求め ｌこ
。The physical properties of the pigment obtained were determined as follows.
（１）外観 目視観察による。(1) Appearance By visual observation.
（２）色相Ｈ１明度■、彩度Ｃ
積分球を用いた分光光度計〔日本分光工業（株）製、分
光光度計ｒＵｂｅｓｔ ５０Ｊ）によって、波長７８０
〜３８０ｎｍの反射スペクトルを測定し、Ｃ光源（青空
を含む昼光）を標準光源とし、国際照明委員会（ＣＩＢ
）の定めた２度視野に基づく表色系に従ったマンセル座
標を求める色彩計算プログラム〔日本分光工業（株）製
、ＴＳＶ −４３３型色彩計算プログラム〕を用いて、
色相Ｈ１明度Ｖ１彩度Ｃを測定した。なお、色相Ｈにお
いて、Ｒは赤の色相領域、Ｂは青の色相領域、Ｐは紫の
色相領域、ＲＰは赤紫の色相領域を示す。(2) Hue H1 Lightness ■, Chroma C Spectrophotometer using an integrating sphere [Spectrophotometer rUbest 50J, manufactured by JASCO Corporation], at wavelength 780
The reflection spectrum at ~380 nm was measured, and the C light source (daylight including blue sky) was used as the standard light source, and the International Commission on Illumination (CIB)
), using a color calculation program [TSV-433 type color calculation program manufactured by JASCO Corporation] that calculates the Munsell coordinates according to the color system based on the 2-degree field of view determined by
Hue H1 brightness V1 chroma C were measured. In the hue H, R indicates a red hue region, B indicates a blue hue region, P indicates a purple hue region, and RP indicates a reddish-purple hue region.
また、層状構造を有する無機物質として、次に示すもの
を用いた。In addition, the following materials were used as inorganic materials having a layered structure.
・マイカＭ
栗色ピグメント社製、平均粒子径２０μｍの白雲母微粉
砕物、化学式ＬＡＬ（Ｓｉ６・ＡＬ）Ｏｚｏ（ＯＨ）イ
ケイ酸四面体の層と層との間に、ＡＱとＫを含む三層構
造のもの。・Mica M Manufactured by Maroon Pigment Co., finely ground muscovite with an average particle size of 20 μm, chemical formula LAL (Si6 AL) Ozo (OH) Three layers containing AQ and K between the layers of silicate tetrahedron. Something of structure.
・タルクＳ
栗色ピグメント社製、平均粒子径１８μｍ１三層構造型
４面網状ケイ酸基を有する組成のもの。- Talc S Manufactured by Maroon Pigment Co., Ltd., with an average particle size of 18 μm, 1 three-layer structure, and a composition having four-sided network silicic acid groups.
・カオリンＡ
栗色ピグメント社製、平均粒子径０．５μｍ、ケイ酸四
面体の層とジブサイト層との二層構造のもの。・Kaolin A, manufactured by Maroon Pigment Co., Ltd., average particle size 0.5 μm, two-layer structure consisting of a silicate tetrahedron layer and a gibbsite layer.
・セリサイトＪ
栗色ピグメント社製、平均粒子径４．３μｍ、マイカＭ
と同様の構造を有するもの。・Sericite J Manufactured by Maroon Pigment Co., Ltd., average particle size 4.3 μm, Mica M
Something with a similar structure.
調製例１ 紫根の色素抽出物の調製
乾燥した局法「紫檀」 （ムラサキの根、産地：中国、
剤形：生）１ｋｇを細かく砕いて、ステンレス製の２０
ｆｆ蓋付円筒容器に取り、これに抽出溶媒としてエチル
アルコール（純度９９．５％）５１Ｊ。Preparation Example 1 Preparation of Pigment Extract of Purple Root Dried Topically
Dosage form: raw) 1 kg is finely crushed into a stainless steel 20
ff Transfer to a cylindrical container with a lid, and add 51 J of ethyl alcohol (purity 99.5%) as an extraction solvent.
え、密閉することなく室温で３日間放置したのち、ろ過
して濃い赤紫色のエチルアルコール抽出溶液４．４１０
＋＋ｏ２を得た。Well, let it stand at room temperature for 3 days without sealing it, then filter it to get a dark reddish-purple ethyl alcohol extraction solution 4.410
++O2 was obtained.
次いで、この抽出溶液中のエチルアルコールを減圧下で
留去し、濃縮することにより、シラツブ状の濃い赤紫色
を呈する紫根の粗製色素抽出物（濃縮物） ４７．ｈを
得た。Next, the ethyl alcohol in this extraction solution is distilled off under reduced pressure and concentrated to obtain a crude pigment extract (concentrate) of purple root that exhibits a thick reddish-purple color.47. I got h.
エチルアルコール抽出溶液中に含有されていた紫根の粗
製色素抽出物（濃縮物）は１．０７ｗ／ｖ％であり、使
用した乾燥紫根（ムラサキの根）に対する粗製色素抽出
物（濃縮物）の収量は４．７０ｗｔ％であっｔこ。The crude pigment extract (concentrate) of purple root contained in the ethyl alcohol extraction solution was 1.07 w/v%, and the yield of the crude pigment extract (concentrate) was based on the dried purple root (purple root) used. is 4.70wt%.
次いで、この粗製色素抽出物（濃縮物）２０ｇを、４５
ｍｍ Ｉ Ｘ ７５０ｍｍのガラス製クロマト管にシ
リカゲル（メルク社製、Ｋｉｅｓｅｌｇｅｌ ６０．７
０−２３０ｍｅｓ７０−２３Ｏを湿式充填したカラムに
入れ、クロロホルム溶液として展開した。溶出液が赤色
を呈している画分を合わせ、減圧下に濃縮し、暗紅色シ
ラツブ状の精製色素抽出物７．２ｇを得た。Next, 20 g of this crude pigment extract (concentrate) was
Silica gel (manufactured by Merck & Co., Kieselgel 60.7
0-230mes70-23O was placed in a wet-packed column and developed as a chloroform solution. Fractions in which the eluate had a red color were combined and concentrated under reduced pressure to obtain 7.2 g of a purified pigment extract in the form of a dark red slag.
調製例２ 紫根の色素抽出物の調製
調製例１で得た紫根の粗製色素抽出物（濃縮物）２０ｇ
に、トルエン２００ｒｎＱを加えて溶解し、これに７０
リジル（ＦＬＯＲＩＳＩＬ、７０リジル社登録商標、活
性化ケイ酸マグネシウム）ｌ Ｏｇを加えて、室温下１
時間かきまぜたのち、ろ過し、ろ液を減圧濃縮し、暗紅
色シラツブ状の精製色素抽出物８．６ｇを得ｔこ。Preparation example 2 Preparation of pigment extract of purple root 20 g of crude pigment extract (concentrate) of purple root obtained in Preparation example 1
To this, add 200rnQ of toluene and dissolve, and add 70rnQ to this.
Add 1 Og of FLORISIL (registered trademark of 70 Lysil Co., Ltd., activated magnesium silicate) and
After stirring for an hour, it was filtered, and the filtrate was concentrated under reduced pressure to obtain 8.6 g of a purified pigment extract in the form of a dark red slag.
有色顔料の製造
実施例１
調製例２で得た紫根の精製色素抽出物１．０ｇをエタノ
ール１ＯｒｎＱに溶解したものを、精製水８０．０＋＋
＋１２に加えて染浴を調製しくｐＨ５，４０）、次いで
かきまぜながら、これにマイカＭ５ｇを添加して５０〜
５８°Ｃで６０分間染着処理したのち、固形分をろ別し
、乾燥することにより、赤色バール状の外観を有する顔
料が得られた。また、ろ液は赤色を呈し、ｐＨ６，４０
であった。結果を第１表に示す。このようにして得られ
た顔料の分光反射スペクトルを第１図に示す。Production Example 1 of Colored Pigment 1.0 g of purified pigment extract of purple root obtained in Preparation Example 2 was dissolved in 1 OrnQ of ethanol, and 80.0++ of purified water was dissolved.
In addition to +12, prepare a dye bath (pH 5,40), then add 5g of mica M to this while stirring to make it 50~
After dyeing at 58°C for 60 minutes, the solid content was filtered off and dried to obtain a pigment with a red burl-like appearance. In addition, the filtrate has a red color and has a pH of 6.40.
Met. The results are shown in Table 1. The spectral reflection spectrum of the pigment thus obtained is shown in FIG.
実施例２〜６
第１表に示す条件で、実施例１と同様にしてマイカＭの
染着処理を行い顔料を調製した。その結果を第１表に示
す。Examples 2 to 6 Mica M was dyed in the same manner as in Example 1 under the conditions shown in Table 1 to prepare pigments. The results are shown in Table 1.
また、得られた顔料の分光反射スペクトルを第２図（実
施例２）、第３図（実施例３）、第４図（実施例４）、
第５図（実施例５）及び第６図（実施例６）に示す。In addition, the spectral reflection spectra of the obtained pigments are shown in Figure 2 (Example 2), Figure 3 (Example 3), Figure 4 (Example 4),
It is shown in FIG. 5 (Example 5) and FIG. 6 (Example 6).
実施例７〜９
層状構造を有する微粒状無機物質として、タルクＳ（実
施例７）、カオリンＡ（実施例８）及びセリサイトＪ（
実施例９）を用い、第２表に示す条件で実施例１と同様
ｌコして寅施し、有色顔料を得た。その結果を第２表に
示す。Examples 7 to 9 Talc S (Example 7), Kaolin A (Example 8) and Sericite J (
Example 9) was applied in the same manner as in Example 1 under the conditions shown in Table 2 to obtain a colored pigment. The results are shown in Table 2.
また、得られた顔料の分光反射スペクトルを、第７図（
実施例７）、第８図（実施例８）及び第９図（実施例９
）に示す。In addition, the spectral reflection spectrum of the obtained pigment is shown in Figure 7 (
Example 7), Figure 8 (Example 8) and Figure 9 (Example 9)
).
第
表
実施例１０
マイカＭ２０ｇ、塩化アルミニウム６ｇを精製水２００
ｍｆｆに溶解した水溶病中に、層状構造を有する無機物
質として、８０〜９０℃で６０分間浸せきしたのち、放
冷し、ろ過乾燥して得た処理マイカ１０ｇを用い、第３
表Ｊこ示す条件で、実施例１と同様にして実施し、有色
顔料を得た。その結果を第３表に示す。Table Example 10 20 g of mica M, 6 g of aluminum chloride and 200 g of purified water
Using 10 g of treated mica obtained by immersing it as an inorganic substance with a layered structure at 80 to 90°C for 60 minutes in a water-soluble disease dissolved in mff, cooling it, and filtering and drying it, the third
A colored pigment was obtained by carrying out the same procedure as in Example 1 under the conditions shown in Table J. The results are shown in Table 3.
また、得られた顔料の分光反射スペクトルを第１０図に
示す。Moreover, the spectral reflection spectrum of the obtained pigment is shown in FIG.
実施例１１
実施例１０において、塩化アルミニウムの代りに明パン
を用いた以外は、実施例１０と同様にして有色顔料を得
た。その結果を第３表に示す。Example 11 A colored pigment was obtained in the same manner as in Example 10, except for using light bread instead of aluminum chloride. The results are shown in Table 3.
また、得られた顔料の分光反射スペクトルを第１１図に
示す。Moreover, the spectral reflection spectrum of the obtained pigment is shown in FIG.
実施例１２
実施例１Ｏにおいて、塩化アルミニウムの代りに塩化バ
リウムを用いた以外は、実施例ＩＯと同様にして有色顔
料を得た。その結果を第３表に示す。Example 12 A colored pigment was obtained in the same manner as in Example IO, except that barium chloride was used instead of aluminum chloride in Example 1O. The results are shown in Table 3.
また、得られた顔料の分光反射スペクトルを第１２図に
示す。Moreover, the spectral reflection spectrum of the obtained pigment is shown in FIG.
第
表
化粧料の製造
実施例１３ はお紅の製造
（Ａ）成分
実施例４の顔料
セリサイト
１８．０重量部
５０．０ ／／
カオリン ２０．０ ／／（Ｂ
）成分
流動パラフィン ４．０重量部セレシン
１．Ｑ ／／ラノリン
２．Ｑｔｔ ４゜スクワラン
４．０〃ステアリン酸
１．Ｑ ｔｔ前記（Ａ）成分を均一に混合した
のち、これを（Ｂ）成分の溶解混合物中に添加して混和
し、次いで粉砕したのち、ふるい分けし、金をに打型し
てほお紅を得た。Production Example 13 of Cosmetics in Table 1 Production of red bean paste (A) Pigment sericite of Ingredient Example 4 18.0 parts by weight 50.0 // Kaolin 20.0 // (B
) Ingredients Liquid paraffin 4.0 parts by weight Ceresin 1. Q // Lanolin
2. Qtt 4゜Squalane
4.0 Stearic acid
1. Q ttAfter uniformly mixing the above component (A), it was added to the dissolved mixture of component (B) and mixed, then crushed, sieved, and stamped with gold to obtain a blusher. .
実施例１４ アイシャドウの製造
（Ａ）成分
実施例１１の顔料 １２．０重量部雲母チタ
ン ３０．０ ／／セリサイト
４５．ＯＮ（Ｂ）成分
ラノリン ３．０重量部スクワラ
ン ６．０〃ミリスチン酸
４．Ｑ ／／前記（Ａ）成分を均一に混
合したのち、これを（Ｂ）成分の溶解混合物に添加して
混和し、次いで粉砕したのち、ふるい分けし、金型に打
型してアイシャドウを得た。Example 14 Production of eye shadow (A) Component Pigment of Example 11 12.0 parts by weight Mica titanium 30.0 //Sericite
45. ON (B) component lanolin 3.0 parts by weight squalane 6.0 myristic acid
4. Q // After uniformly mixing the above component (A), it is added to the dissolved mixture of component (B) and mixed, then pulverized, sieved, and cast into a mold to obtain an eye shadow. Ta.
第１図〜第１２図は、それぞれ本発明の有色顔料の異な
った例の分光反射スペクトル図である。
特許出願人 イハラケミカル工業株式会社（ほか２名）1 to 12 are spectral reflection spectra of different examples of the colored pigment of the present invention, respectively. Patent applicant Ihara Chemical Industry Co., Ltd. (and 2 others)
Claims (1)
素を含浸させて成る安定化された有色顔料。 ２ 微粒状無機物質が水溶性のアルミニウム塩又はバリ
ウム塩で処理したものである請求項１記載の安定化され
た有色顔料。 ３ 請求項１又は２記載の安定化された有色顔料を含有
してなる化粧料。[Scope of Claims] 1. A stabilized colored pigment obtained by impregnating a finely divided inorganic substance with a layered crystal structure with a purple root pigment. 2. The stabilized colored pigment according to claim 1, wherein the particulate inorganic substance is treated with a water-soluble aluminum salt or barium salt. 3. A cosmetic comprising the stabilized colored pigment according to claim 1 or 2.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2187050A JPH0477562A (en) | 1990-07-17 | 1990-07-17 | Stabilized colored pigment and cosmetic containing the same |
| KR1019910012121A KR940008384B1 (en) | 1990-07-17 | 1991-07-16 | Stabilized colored pigment and cosmetic containing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2187050A JPH0477562A (en) | 1990-07-17 | 1990-07-17 | Stabilized colored pigment and cosmetic containing the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0477562A true JPH0477562A (en) | 1992-03-11 |
Family
ID=16199299
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2187050A Pending JPH0477562A (en) | 1990-07-17 | 1990-07-17 | Stabilized colored pigment and cosmetic containing the same |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPH0477562A (en) |
| KR (1) | KR940008384B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014008101A (en) * | 2012-06-28 | 2014-01-20 | Tadashi Kawakita | Thermotherapeutic device |
-
1990
- 1990-07-17 JP JP2187050A patent/JPH0477562A/en active Pending
-
1991
- 1991-07-16 KR KR1019910012121A patent/KR940008384B1/en not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014008101A (en) * | 2012-06-28 | 2014-01-20 | Tadashi Kawakita | Thermotherapeutic device |
Also Published As
| Publication number | Publication date |
|---|---|
| KR940008384B1 (en) | 1994-09-14 |
| KR920002711A (en) | 1992-02-28 |
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