JPH0462578B2 - - Google Patents
Info
- Publication number
- JPH0462578B2 JPH0462578B2 JP59212827A JP21282784A JPH0462578B2 JP H0462578 B2 JPH0462578 B2 JP H0462578B2 JP 59212827 A JP59212827 A JP 59212827A JP 21282784 A JP21282784 A JP 21282784A JP H0462578 B2 JPH0462578 B2 JP H0462578B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- photosensitive layer
- azo pigment
- electrophotographic photoreceptor
- carrier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 108091008695 photoreceptors Proteins 0.000 claims description 49
- 239000000049 pigment Substances 0.000 claims description 43
- 239000000126 substance Substances 0.000 claims description 26
- 150000001875 compounds Chemical class 0.000 claims description 11
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 150000002367 halogens Chemical group 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 150000002431 hydrogen Chemical group 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 150000002825 nitriles Chemical group 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 65
- -1 1-octyl group Chemical group 0.000 description 26
- 238000012546 transfer Methods 0.000 description 26
- 239000011230 binding agent Substances 0.000 description 14
- 239000000243 solution Substances 0.000 description 13
- 238000010521 absorption reaction Methods 0.000 description 11
- 239000011248 coating agent Substances 0.000 description 11
- 238000000576 coating method Methods 0.000 description 11
- 239000002609 medium Substances 0.000 description 11
- 230000035945 sensitivity Effects 0.000 description 11
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 239000000975 dye Substances 0.000 description 6
- 229910052711 selenium Inorganic materials 0.000 description 6
- 239000011669 selenium Substances 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 5
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 4
- 239000010419 fine particle Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- ZXBSSAFKXWFUMF-UHFFFAOYSA-N 1,2,3-trinitrofluoren-9-one Chemical compound C12=CC=CC=C2C(=O)C2=C1C=C([N+](=O)[O-])C([N+]([O-])=O)=C2[N+]([O-])=O ZXBSSAFKXWFUMF-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- 239000002841 Lewis acid Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 125000004093 cyano group Chemical group *C#N 0.000 description 3
- 150000007517 lewis acids Chemical class 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000006163 transport media Substances 0.000 description 3
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 3
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 2
- KLJBWJNKXZYYHA-UHFFFAOYSA-N 2-(4-nitrophenyl)-2-(3-oxo-2-benzofuran-1-ylidene)acetonitrile Chemical compound C1=CC([N+](=O)[O-])=CC=C1C(C#N)=C1C2=CC=CC=C2C(=O)O1 KLJBWJNKXZYYHA-UHFFFAOYSA-N 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- NJWGQARXZDRHCD-UHFFFAOYSA-N 2-methylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(C)=CC=C3C(=O)C2=C1 NJWGQARXZDRHCD-UHFFFAOYSA-N 0.000 description 2
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000012954 diazonium Substances 0.000 description 2
- 150000001989 diazonium salts Chemical class 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920001230 polyarylate Polymers 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- GUEIZVNYDFNHJU-UHFFFAOYSA-N quinizarin Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(O)=CC=C2O GUEIZVNYDFNHJU-UHFFFAOYSA-N 0.000 description 2
- 230000027756 respiratory electron transport chain Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 125000000547 substituted alkyl group Chemical group 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
- FHIDEWWHKSJPTK-UHFFFAOYSA-N (3,5-dinitrophenyl)-phenylmethanone Chemical compound [O-][N+](=O)C1=CC([N+](=O)[O-])=CC(C(=O)C=2C=CC=CC=2)=C1 FHIDEWWHKSJPTK-UHFFFAOYSA-N 0.000 description 1
- YRTPZXMEBGTPLM-UVTDQMKNSA-N (3z)-3-benzylidene-2-benzofuran-1-one Chemical compound C12=CC=CC=C2C(=O)O\C1=C/C1=CC=CC=C1 YRTPZXMEBGTPLM-UVTDQMKNSA-N 0.000 description 1
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- VOZLLWQPJJSWPR-UHFFFAOYSA-N 1-chloro-5-nitroanthracene-9,10-dione Chemical compound O=C1C2=C(Cl)C=CC=C2C(=O)C2=C1C=CC=C2[N+](=O)[O-] VOZLLWQPJJSWPR-UHFFFAOYSA-N 0.000 description 1
- YCANAXVBJKNANM-UHFFFAOYSA-N 1-nitroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2[N+](=O)[O-] YCANAXVBJKNANM-UHFFFAOYSA-N 0.000 description 1
- MYKQKWIPLZEVOW-UHFFFAOYSA-N 11h-benzo[a]carbazole Chemical group C1=CC2=CC=CC=C2C2=C1C1=CC=CC=C1N2 MYKQKWIPLZEVOW-UHFFFAOYSA-N 0.000 description 1
- SVPKNMBRVBMTLB-UHFFFAOYSA-N 2,3-dichloronaphthalene-1,4-dione Chemical compound C1=CC=C2C(=O)C(Cl)=C(Cl)C(=O)C2=C1 SVPKNMBRVBMTLB-UHFFFAOYSA-N 0.000 description 1
- FPKCTSIVDAWGFA-UHFFFAOYSA-N 2-chloroanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(Cl)=CC=C3C(=O)C2=C1 FPKCTSIVDAWGFA-UHFFFAOYSA-N 0.000 description 1
- WGRSVHBSCVGKDP-UHFFFAOYSA-N 2-ethyl-9h-carbazole-1-carbaldehyde Chemical compound C1=CC=C2C3=CC=C(CC)C(C=O)=C3NC2=C1 WGRSVHBSCVGKDP-UHFFFAOYSA-N 0.000 description 1
- ZKUQHCRNLOUUNT-UHFFFAOYSA-N 2-hydroxy-3-[(4-nitrophenyl)methylidene]butanedinitrile Chemical compound N#CC(O)C(C#N)=CC1=CC=C([N+]([O-])=O)C=C1 ZKUQHCRNLOUUNT-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- WFFZGYRTVIPBFN-UHFFFAOYSA-N 3h-indene-1,2-dione Chemical compound C1=CC=C2C(=O)C(=O)CC2=C1 WFFZGYRTVIPBFN-UHFFFAOYSA-N 0.000 description 1
- UJEUBSWHCGDJQU-UHFFFAOYSA-N 4-chloro-1,8-naphthalic anhydride Chemical compound O=C1OC(=O)C2=CC=CC3=C2C1=CC=C3Cl UJEUBSWHCGDJQU-UHFFFAOYSA-N 0.000 description 1
- YYVYAPXYZVYDHN-UHFFFAOYSA-N 9,10-phenanthroquinone Chemical compound C1=CC=C2C(=O)C(=O)C3=CC=CC=C3C2=C1 YYVYAPXYZVYDHN-UHFFFAOYSA-N 0.000 description 1
- QGJXVBICNCIWEL-UHFFFAOYSA-N 9-ethylcarbazole-3-carbaldehyde Chemical compound O=CC1=CC=C2N(CC)C3=CC=CC=C3C2=C1 QGJXVBICNCIWEL-UHFFFAOYSA-N 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910000967 As alloy Inorganic materials 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Chemical class 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004419 Panlite Substances 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- MZZSDCJQCLYLLL-UHFFFAOYSA-N Secalonsaeure A Natural products COC(=O)C12OC3C(CC1=C(O)CC(C)C2O)C(=CC=C3c4ccc(O)c5C(=O)C6=C(O)CC(C)C(O)C6(Oc45)C(=O)OC)O MZZSDCJQCLYLLL-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- QLNFINLXAKOTJB-UHFFFAOYSA-N [As].[Se] Chemical compound [As].[Se] QLNFINLXAKOTJB-UHFFFAOYSA-N 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 125000005577 anthracene group Chemical group 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003785 benzimidazolyl group Chemical group N1=C(NC2=C1C=CC=C2)* 0.000 description 1
- 150000008366 benzophenones Chemical group 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- KFCSIQAHBXUNKH-UHFFFAOYSA-N bis(3,5-dinitrophenyl)methanone Chemical compound [O-][N+](=O)C1=CC([N+](=O)[O-])=CC(C(=O)C=2C=C(C=C(C=2)[N+]([O-])=O)[N+]([O-])=O)=C1 KFCSIQAHBXUNKH-UHFFFAOYSA-N 0.000 description 1
- 229960001506 brilliant green Drugs 0.000 description 1
- HXCILVUBKWANLN-UHFFFAOYSA-N brilliant green cation Chemical compound C1=CC(N(CC)CC)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](CC)CC)C=C1 HXCILVUBKWANLN-UHFFFAOYSA-N 0.000 description 1
- 125000004799 bromophenyl group Chemical group 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000002800 charge carrier Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 125000004803 chlorobenzyl group Chemical group 0.000 description 1
- 125000000068 chlorophenyl group Chemical group 0.000 description 1
- JPBGLQJDCUZXEF-UHFFFAOYSA-N chromenylium Chemical class [O+]1=CC=CC2=CC=CC=C21 JPBGLQJDCUZXEF-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- GBRBMTNGQBKBQE-UHFFFAOYSA-L copper;diiodide Chemical compound I[Cu]I GBRBMTNGQBKBQE-UHFFFAOYSA-L 0.000 description 1
- ZXJXZNDDNMQXFV-UHFFFAOYSA-M crystal violet Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1[C+](C=1C=CC(=CC=1)N(C)C)C1=CC=C(N(C)C)C=C1 ZXJXZNDDNMQXFV-UHFFFAOYSA-M 0.000 description 1
- 125000004802 cyanophenyl group Chemical group 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- TXCDCPKCNAJMEE-UHFFFAOYSA-N dibenzofuran Chemical group C1=CC=C2C3=CC=CC=C3OC2=C1 TXCDCPKCNAJMEE-UHFFFAOYSA-N 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- 125000006286 dichlorobenzyl group Chemical group 0.000 description 1
- 125000004188 dichlorophenyl group Chemical group 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000006575 electron-withdrawing group Chemical group 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- YLQWCDOCJODRMT-UHFFFAOYSA-N fluoren-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C2=C1 YLQWCDOCJODRMT-UHFFFAOYSA-N 0.000 description 1
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 1
- 230000005525 hole transport Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 1
- 125000001041 indolyl group Chemical group 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000006178 methyl benzyl group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- PLNYMNKTFKLJLM-UHFFFAOYSA-N n,n-diethyl-1-[5-phenyl-3-(2-phenylethenyl)-1,3-dihydropyrazol-2-yl]cyclohexa-2,4-dien-1-amine Chemical compound N1C(C=2C=CC=CC=2)=CC(C=CC=2C=CC=CC=2)N1C1(N(CC)CC)CC=CC=C1 PLNYMNKTFKLJLM-UHFFFAOYSA-N 0.000 description 1
- JGOAZQAXRONCCI-SDNWHVSQSA-N n-[(e)-benzylideneamino]aniline Chemical compound C=1C=CC=CC=1N\N=C\C1=CC=CC=C1 JGOAZQAXRONCCI-SDNWHVSQSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- RMHJJUOPOWPRBP-UHFFFAOYSA-N naphthalene-1-carboxamide Chemical compound C1=CC=C2C(C(=O)N)=CC=CC2=C1 RMHJJUOPOWPRBP-UHFFFAOYSA-N 0.000 description 1
- 125000006501 nitrophenyl group Chemical group 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 125000002971 oxazolyl group Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 239000013034 phenoxy resin Substances 0.000 description 1
- 229920006287 phenoxy resin Polymers 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 125000005936 piperidyl group Chemical group 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 125000000168 pyrrolyl group Chemical group 0.000 description 1
- WVIICGIFSIBFOG-UHFFFAOYSA-N pyrylium Chemical class C1=CC=[O+]C=C1 WVIICGIFSIBFOG-UHFFFAOYSA-N 0.000 description 1
- 125000005493 quinolyl group Chemical group 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229960005265 selenium sulfide Drugs 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000001119 stannous chloride Substances 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000010301 surface-oxidation reaction Methods 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- UGNWTBMOAKPKBL-UHFFFAOYSA-N tetrachloro-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O UGNWTBMOAKPKBL-UHFFFAOYSA-N 0.000 description 1
- NLDYACGHTUPAQU-UHFFFAOYSA-N tetracyanoethylene Chemical group N#CC(C#N)=C(C#N)C#N NLDYACGHTUPAQU-UHFFFAOYSA-N 0.000 description 1
- PCCVSPMFGIFTHU-UHFFFAOYSA-N tetracyanoquinodimethane Chemical compound N#CC(C#N)=C1C=CC(=C(C#N)C#N)C=C1 PCCVSPMFGIFTHU-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000001016 thiazine dye Substances 0.000 description 1
- 125000000335 thiazolyl group Chemical group 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 125000001425 triazolyl group Chemical group 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0664—Dyes
- G03G5/0675—Azo dyes
- G03G5/0679—Disazo dyes
- G03G5/0683—Disazo dyes containing polymethine or anthraquinone groups
- G03G5/0685—Disazo dyes containing polymethine or anthraquinone groups containing hetero rings in the part of the molecule between the azo-groups
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Light Receiving Elements (AREA)
- Photoreceptors In Electrophotography (AREA)
Description
(A) ç£æ¥äžã®å©çšåé
æ¬çºæã¯ãé»ååçæå
äœã«é¢ãã詳ããã¯ã¢
ãŸé¡æãå«æããæå å±€ãæããæ°èŠãªé»ååç
æå äœã«é¢ããã æŽã«è©³ããã¯é«æ床ã«ããŠäžã€ç¹°ãè¿ã䜿çšã«
é©ããé«èä¹ æ§é»ååçæå äœã«é¢ããã (B) åŸæ¥æè¡åã³ãã®åé¡ç¹ åŸæ¥ãé»ååçæå äœãšããŠã¯ãã»ã¬ã³ãé žå
äºéãç¡«åã«ãããŠã çã®ç¡æ©å å°é»äœãäž»æç©
ãšããæå å±€ãæãããã®ãåºãç¥ãããŠããã ãããããããã¯æ床ãç±å®å®æ§ãè湿æ§ãè
ä¹ æ§çã«ãããŠå¿ ãããæºè¶³ãåŸããã®ã§ã¯ãª
ãããŸãç¹ã«ã»ã¬ã³ããã³ç¡«åã«ããããŠã ã¯æ¯
æ§ã®ããã«ã補é äžãåãæ±ãäžã«ãå¶çŽããã€
ããäžæ¹ãææ©å å°é»æ§ååç©ãäž»æåãšããæ
å å±€ãæããé»ååçæå äœã¯è£œé ãæ¯èŒç容æ
ã§ããããšãå®äŸ¡ã§ããããšãåãæ±ãã容æã§
ããããšããŸãäžè¬ã«ã»ã¬ã³æå äœã«æ¯ã¹ãŠç±å®
å®æ§ãåªããŠããããšãªã©å€ãã®å©ç¹ãæããè¿
幎å€ãã®æ³šç®ãéããŠããã ãã®ãããªææ©å å°é»æ§ååç©ãšããŠã¯ãããª
ââããã«ã«ã«ããŸãŒã«ãããç¥ãããŠããã
ãããš2.4.7âããªãããâïŒâãã«ãªã¬ãã³ç
ã®ã«ã€ã¹é žãšãã圢æãããé»è·ç§»åé¯äœãäž»æ
åãšããæå å±€ãæããé»ååçæå äœã¯æ床ã
ãã³èä¹ æ§ã«ãããŠå¿ ãããæºè¶³ã§ãããã®ã§ã¯
ãªãã äžæ¹ããã€ãªã¢çºçæ©èœãšãã€ãªã¢ç§»åæ©èœãš
ãããããå¥åã®ç©è³ªã«åæ ãããããã«ããç©
å±€åããããã¯åæ£åã®æ©èœåé¢åæå äœã¯åã
ã®ææã®éžæç¯å²ãåºãã垯é»ç¹æ§ãæ床ãèä¹
æ§çã®é»ååçç¹æ§ã«ãããŠãä»»æã®ç¹æ§ãæã
ãé»ååçæå äœãæ¯èŒç容æã«äœæãåŸããšã
ãå©ç¹ãã€ãŠããã åŸæ¥ãã€ãªã¢çºçç©è³ªãããã¯ãã€ãªã¢ç§»åç©
質ãšããŠçš®ã ã®ãã®ãææ¡ãããŠããã ããšãã°ãç¡å®åœ¢ã»ã¬ã³ããæããã€ãªã¢çºç
å±€ãšããªââããã«ã«ã«ããŸãŒã«ãäž»æåãšã
ããã€ãªã¢ç§»åå±€ãšãçµã¿åãããæå å±€ãæã
ãé»ååçæå äœãå®çšåãããŠããã ãããç¡å®åœ¢ã»ã¬ã³ããæããã€ãªã¢çºçå±€ã¯
èä¹ æ§ã«å£ããšããæ¬ ç¹ãæããã ãŸããææ©ææãé¡æããã€ãªã¢çºçç©è³ªãšã
ãŠçšããããšãçš®ã ææ¡ãããŠããäŸãã°ã¢ãã¢
ãŸé¡æããã¹ã¢ãŸé¡æãæå å±€äžã«å«æããé»å
åçæå äœãšããŠãç¹å ¬æ48â30513å·å ¬å ±ãç¹
éæ52â4241å·å ¬å ±ãç¹éæ54â46558å·å ¬å ±ã
ç¹å ¬æ56â11945å·å ¬å ±çããã§ã«å ¬ç¥ã§ããã ãããããããã®ã¢ãŸé¡æã¯ãæ床ãæ®çé»äœ
ãããã¯ãç¹°ãè¿ã䜿çšããå Žåã®å®å®æ§çã®ç¹
æ§ã«ãããŠãå¿ ãããæºè¶³ãåŸããã®ã§ã¯ãªãã
ãŸããã€ãªã¢ç§»åç©è³ªã®éžæç¯å²ãéå®ããããª
ã©ãé»ååçããã»ã¹ã®å¹ åºãèŠæ±ãå åã«æºè¶³
ããããã®ã¯æªã åŸãããŠããªãã®ãå®æ ã§ã
ãã (C) çºæã®ç®ç æ¬çºæã®ç®çã¯ãç±ããã³å ã«å¯ŸããŠå®å®ã§äž
ã€ãã€ãªã¢çºçèœã«åªããã¢ãŸé¡æãå«æããé»
ååçæå äœãæäŸããããšã«ããã æ¬çºæã®ä»ã®ç®çã¯ãé«æ床ã«ããŠæ®çé»äœã
å°ãããäžã€ç¹°ãè¿ã䜿çšããŠããããã®ç¹æ§ã
å€åããªããèä¹ æ§ã®åªããé»ååçæå äœãæ
äŸããããšã«ããã æ¬çºæã®æŽã«ä»ã®ç®çã¯ãåºç¯ãªãã€ãªã¢ç§»å
ç©è³ªãšã®çµã¿åããã«ãããŠããæå¹ã«ãã€ãªã¢
çºçç©è³ªãšããŠäœçšãåŸãã¢ãŸé¡æãå«æããé»
ååçæå äœãæäŸããããšã«ããã (D) çºæã®æ§æ æ¬çºæè ãã¯ã以äžã®ç®çãéæãã¹ãéæç
究ã®çµæãäžèšäžè¬åŒïŒïŒã§ç€ºãããã¢ãŸé¡æ
ãæå äœã®æå¹æåãšããŠåãåŸãããšãèŠãåº
ããæ¬çºæãå®æãããã®ã§ããã ïŒåŒäžïŒžã¯æ°ŽçŽ ãããã²ã³ããããªã«ã§ããã
ã¯æ°ŽçŽ ãã¢ãªãŒã«åºã眮æãæªçœ®æã®ã¢ã«ãã«
åºã眮æãæªçœ®æã®ãã³ãžã«åºã§ãããCpã¯ã«
ããã©ãŒæ®åºã§ãããïŒ Cpã¯ãžã¢ãŸåºãšåå¿ããã«ããã©ãŒã®æ®åºã
瀺ãããç¹ã«äžèšã®äžè¬åŒïŒïŒã§ç€ºãããæ§é
ã®ã«ããã©ãŒæ®åºãæå¹ã§ããã ãåŒäžãã¯ãã³ãŒã³ç°ãšçž®åããŠããã¿ã¬
ã³ãã¢ã³ãã©ã»ã³ç°ãªã©ã®å€ç°åŒè³éŠæçåæ°ŽçŽ
ç°ãŸãã¯ãã³ãŒã³ç°ãšçž®åããŠã«ã«ããŸãŒã«ç°ã
ãã³ãŸã«ã«ããŸãŒã«ç°ããžãã³ãŸãã©ã³ç°ãªã©ã®
è€çŽ ç°ã圢æããã«å¿ èŠãªåå矀ã瀺ããR1ã¯
眮æãããŠãããã¢ã«ãã«åºïŒäŸãã°ãã¡ãã«
åºããšãã«åºãïœâãããã«åºãã€ãœâãããã«
åºãïœâããã«åºãsecâããã«åºãã¢ãã«åºã
ïŒâãªã¯ãã«åºããã³ãžã«åºãã¯ãã«ãã³ãžã«
åºããžã¯ãã«ãã³ãžã«åºãã¡ãã«ãã³ãžã«åºãïŒ
âããšãã«ãšãã«åºãαâãããã«ã¡ãã«åºãβ
âãããã«ã¡ãã«åºïŒãã¢ãªãŒã«åºïŒäŸãã°ãã
ãšãã«åºãããªã«åºããã·ãªã«åºããããšãã«
åºãã¯ããããšãã«åºããžã¯ããããšãã«åºãã
ãã ããšãã«åºãã¡ããã·ããšãã«åºããšããã·
ããšãã«åºããããã·ããšãã«åºãããšããã·ã
ãšãã«åºããããããšãã«åºãã·ã¢ãããšãã«
åºãããããã·ããšãã«åºãã«ã«ããã·ããšãã«
åºãïŒïŒ®âãžã¡ãã«ã¢ããããšãã«åºãã¢ã»ã
ã«ããšãã«åºããã³ãŸã€ã«ããšãã«åºããšãã«ã
ãšãã«åºãαïŒÎ±ïŒÎ±âããªãããã¡ãã«ããšã
ã«åºãã¡ãã«ããªããšãã«åºãαâãããã«åºã
βâãããã«åºïŒãR2ã¯R1ãšè€çŽ ç°åºïŒäŸãã°ã
ã¢ãŸãªã«åºãïŒâããããã¢ãŸãªã«åºãã«ã«ããŸ
ãªã«åºãã€ã³ããªã«åºããããªã«åºãã¢ã¯ãªãžã«
åºããã³ãŸ(b)ããªããšãã«ããã³ãŸã€ãããŸãªã«
åºããªããµãŸãªã«åºãã¯ãã«ãªããµãŸãªã«åºãã
ãªã¢ãŸãªã«åºããããªãžã«åºãããªãžã«åºããã
ãªã«åºïŒã瀺ããR3ã¯ïŒ¯ããâNHã瀺ãã
R4ãR5ã¯æ°ŽçŽ ã眮æãããŠãããã¢ã«ãã«åºã
ãããåºãã¡ããã·åºããšããã·åºãã¢ã»ãã«
åºãã·ã¢ãåºãããã²ã³ã瀺ããã¯ïŒå¡ç°ãïŒ
å¡ç°ã圢æããã®ã«å¿ èŠãªéåŒçåæ°ŽçŽ ã§ãããã ããªãã¡ãæ¬çºæã«ãããŠã¯ãåèšäžè¬åŒ
ïŒïŒã§ç€ºãããã¢ãŸé¡æããé»ååçæå äœã®
æå å±€ãæ§æããå å°é»æ§ç©è³ªãšããŠçšããããš
ã«ããããŸãæ¬çºæã®ã¢ãŸé¡æã®åªãããã€ãªã¢
çºçèœã®ã¿ãå©çšããããããã€ãªã¢ã®çºçãšç§»
åãšãããããå¥åã®ç©è³ªã§è¡ãªããããããæ©
èœåé¢åé»ååçæå äœã®ãã€ãªã¢çºçç©è³ªãšã
ãŠçšããããšã«ãããç®èç©æ§ã«åªããé»è·ä¿æ
åãæ床ãæ®çé»äœçã®é»ååçç¹æ§ã«åªããäž
ã€ç¹°ãè¿ã䜿çšããæã«ãç²åŽå£åãå°ãªãäžã
ç±ãããã¯å ã«å¯ŸããŠãäžè¿°ã®ç¹æ§ãå€åããã
ãšããªããå®å®ããç¹æ§ãçºæ®ãåŸãé»ååçæ
å äœãäœæããããšãåºæ¥ãã åèšäžè¬åŒã§ç€ºãããæ¬çºæã«æçšãªã¢ãŸé¡æ
ã®å ·äœäŸãšããŠã¯ãäŸãã°æ¬¡ã®æ§é åŒãæããã
ã®ãæããããããããã«ãã€ãŠæ¬çºæã®ã¢ãŸé¡
æãéå®ããããã®ã§ã¯ãªãã
ãŸé¡æãå«æããæå å±€ãæããæ°èŠãªé»ååç
æå äœã«é¢ããã æŽã«è©³ããã¯é«æ床ã«ããŠäžã€ç¹°ãè¿ã䜿çšã«
é©ããé«èä¹ æ§é»ååçæå äœã«é¢ããã (B) åŸæ¥æè¡åã³ãã®åé¡ç¹ åŸæ¥ãé»ååçæå äœãšããŠã¯ãã»ã¬ã³ãé žå
äºéãç¡«åã«ãããŠã çã®ç¡æ©å å°é»äœãäž»æç©
ãšããæå å±€ãæãããã®ãåºãç¥ãããŠããã ãããããããã¯æ床ãç±å®å®æ§ãè湿æ§ãè
ä¹ æ§çã«ãããŠå¿ ãããæºè¶³ãåŸããã®ã§ã¯ãª
ãããŸãç¹ã«ã»ã¬ã³ããã³ç¡«åã«ããããŠã ã¯æ¯
æ§ã®ããã«ã補é äžãåãæ±ãäžã«ãå¶çŽããã€
ããäžæ¹ãææ©å å°é»æ§ååç©ãäž»æåãšããæ
å å±€ãæããé»ååçæå äœã¯è£œé ãæ¯èŒç容æ
ã§ããããšãå®äŸ¡ã§ããããšãåãæ±ãã容æã§
ããããšããŸãäžè¬ã«ã»ã¬ã³æå äœã«æ¯ã¹ãŠç±å®
å®æ§ãåªããŠããããšãªã©å€ãã®å©ç¹ãæããè¿
幎å€ãã®æ³šç®ãéããŠããã ãã®ãããªææ©å å°é»æ§ååç©ãšããŠã¯ãããª
ââããã«ã«ã«ããŸãŒã«ãããç¥ãããŠããã
ãããš2.4.7âããªãããâïŒâãã«ãªã¬ãã³ç
ã®ã«ã€ã¹é žãšãã圢æãããé»è·ç§»åé¯äœãäž»æ
åãšããæå å±€ãæããé»ååçæå äœã¯æ床ã
ãã³èä¹ æ§ã«ãããŠå¿ ãããæºè¶³ã§ãããã®ã§ã¯
ãªãã äžæ¹ããã€ãªã¢çºçæ©èœãšãã€ãªã¢ç§»åæ©èœãš
ãããããå¥åã®ç©è³ªã«åæ ãããããã«ããç©
å±€åããããã¯åæ£åã®æ©èœåé¢åæå äœã¯åã
ã®ææã®éžæç¯å²ãåºãã垯é»ç¹æ§ãæ床ãèä¹
æ§çã®é»ååçç¹æ§ã«ãããŠãä»»æã®ç¹æ§ãæã
ãé»ååçæå äœãæ¯èŒç容æã«äœæãåŸããšã
ãå©ç¹ãã€ãŠããã åŸæ¥ãã€ãªã¢çºçç©è³ªãããã¯ãã€ãªã¢ç§»åç©
質ãšããŠçš®ã ã®ãã®ãææ¡ãããŠããã ããšãã°ãç¡å®åœ¢ã»ã¬ã³ããæããã€ãªã¢çºç
å±€ãšããªââããã«ã«ã«ããŸãŒã«ãäž»æåãšã
ããã€ãªã¢ç§»åå±€ãšãçµã¿åãããæå å±€ãæã
ãé»ååçæå äœãå®çšåãããŠããã ãããç¡å®åœ¢ã»ã¬ã³ããæããã€ãªã¢çºçå±€ã¯
èä¹ æ§ã«å£ããšããæ¬ ç¹ãæããã ãŸããææ©ææãé¡æããã€ãªã¢çºçç©è³ªãšã
ãŠçšããããšãçš®ã ææ¡ãããŠããäŸãã°ã¢ãã¢
ãŸé¡æããã¹ã¢ãŸé¡æãæå å±€äžã«å«æããé»å
åçæå äœãšããŠãç¹å ¬æ48â30513å·å ¬å ±ãç¹
éæ52â4241å·å ¬å ±ãç¹éæ54â46558å·å ¬å ±ã
ç¹å ¬æ56â11945å·å ¬å ±çããã§ã«å ¬ç¥ã§ããã ãããããããã®ã¢ãŸé¡æã¯ãæ床ãæ®çé»äœ
ãããã¯ãç¹°ãè¿ã䜿çšããå Žåã®å®å®æ§çã®ç¹
æ§ã«ãããŠãå¿ ãããæºè¶³ãåŸããã®ã§ã¯ãªãã
ãŸããã€ãªã¢ç§»åç©è³ªã®éžæç¯å²ãéå®ããããª
ã©ãé»ååçããã»ã¹ã®å¹ åºãèŠæ±ãå åã«æºè¶³
ããããã®ã¯æªã åŸãããŠããªãã®ãå®æ ã§ã
ãã (C) çºæã®ç®ç æ¬çºæã®ç®çã¯ãç±ããã³å ã«å¯ŸããŠå®å®ã§äž
ã€ãã€ãªã¢çºçèœã«åªããã¢ãŸé¡æãå«æããé»
ååçæå äœãæäŸããããšã«ããã æ¬çºæã®ä»ã®ç®çã¯ãé«æ床ã«ããŠæ®çé»äœã
å°ãããäžã€ç¹°ãè¿ã䜿çšããŠããããã®ç¹æ§ã
å€åããªããèä¹ æ§ã®åªããé»ååçæå äœãæ
äŸããããšã«ããã æ¬çºæã®æŽã«ä»ã®ç®çã¯ãåºç¯ãªãã€ãªã¢ç§»å
ç©è³ªãšã®çµã¿åããã«ãããŠããæå¹ã«ãã€ãªã¢
çºçç©è³ªãšããŠäœçšãåŸãã¢ãŸé¡æãå«æããé»
ååçæå äœãæäŸããããšã«ããã (D) çºæã®æ§æ æ¬çºæè ãã¯ã以äžã®ç®çãéæãã¹ãéæç
究ã®çµæãäžèšäžè¬åŒïŒïŒã§ç€ºãããã¢ãŸé¡æ
ãæå äœã®æå¹æåãšããŠåãåŸãããšãèŠãåº
ããæ¬çºæãå®æãããã®ã§ããã ïŒåŒäžïŒžã¯æ°ŽçŽ ãããã²ã³ããããªã«ã§ããã
ã¯æ°ŽçŽ ãã¢ãªãŒã«åºã眮æãæªçœ®æã®ã¢ã«ãã«
åºã眮æãæªçœ®æã®ãã³ãžã«åºã§ãããCpã¯ã«
ããã©ãŒæ®åºã§ãããïŒ Cpã¯ãžã¢ãŸåºãšåå¿ããã«ããã©ãŒã®æ®åºã
瀺ãããç¹ã«äžèšã®äžè¬åŒïŒïŒã§ç€ºãããæ§é
ã®ã«ããã©ãŒæ®åºãæå¹ã§ããã ãåŒäžãã¯ãã³ãŒã³ç°ãšçž®åããŠããã¿ã¬
ã³ãã¢ã³ãã©ã»ã³ç°ãªã©ã®å€ç°åŒè³éŠæçåæ°ŽçŽ
ç°ãŸãã¯ãã³ãŒã³ç°ãšçž®åããŠã«ã«ããŸãŒã«ç°ã
ãã³ãŸã«ã«ããŸãŒã«ç°ããžãã³ãŸãã©ã³ç°ãªã©ã®
è€çŽ ç°ã圢æããã«å¿ èŠãªåå矀ã瀺ããR1ã¯
眮æãããŠãããã¢ã«ãã«åºïŒäŸãã°ãã¡ãã«
åºããšãã«åºãïœâãããã«åºãã€ãœâãããã«
åºãïœâããã«åºãsecâããã«åºãã¢ãã«åºã
ïŒâãªã¯ãã«åºããã³ãžã«åºãã¯ãã«ãã³ãžã«
åºããžã¯ãã«ãã³ãžã«åºãã¡ãã«ãã³ãžã«åºãïŒ
âããšãã«ãšãã«åºãαâãããã«ã¡ãã«åºãβ
âãããã«ã¡ãã«åºïŒãã¢ãªãŒã«åºïŒäŸãã°ãã
ãšãã«åºãããªã«åºããã·ãªã«åºããããšãã«
åºãã¯ããããšãã«åºããžã¯ããããšãã«åºãã
ãã ããšãã«åºãã¡ããã·ããšãã«åºããšããã·
ããšãã«åºããããã·ããšãã«åºãããšããã·ã
ãšãã«åºããããããšãã«åºãã·ã¢ãããšãã«
åºãããããã·ããšãã«åºãã«ã«ããã·ããšãã«
åºãïŒïŒ®âãžã¡ãã«ã¢ããããšãã«åºãã¢ã»ã
ã«ããšãã«åºããã³ãŸã€ã«ããšãã«åºããšãã«ã
ãšãã«åºãαïŒÎ±ïŒÎ±âããªãããã¡ãã«ããšã
ã«åºãã¡ãã«ããªããšãã«åºãαâãããã«åºã
βâãããã«åºïŒãR2ã¯R1ãšè€çŽ ç°åºïŒäŸãã°ã
ã¢ãŸãªã«åºãïŒâããããã¢ãŸãªã«åºãã«ã«ããŸ
ãªã«åºãã€ã³ããªã«åºããããªã«åºãã¢ã¯ãªãžã«
åºããã³ãŸ(b)ããªããšãã«ããã³ãŸã€ãããŸãªã«
åºããªããµãŸãªã«åºãã¯ãã«ãªããµãŸãªã«åºãã
ãªã¢ãŸãªã«åºããããªãžã«åºãããªãžã«åºããã
ãªã«åºïŒã瀺ããR3ã¯ïŒ¯ããâNHã瀺ãã
R4ãR5ã¯æ°ŽçŽ ã眮æãããŠãããã¢ã«ãã«åºã
ãããåºãã¡ããã·åºããšããã·åºãã¢ã»ãã«
åºãã·ã¢ãåºãããã²ã³ã瀺ããã¯ïŒå¡ç°ãïŒ
å¡ç°ã圢æããã®ã«å¿ èŠãªéåŒçåæ°ŽçŽ ã§ãããã ããªãã¡ãæ¬çºæã«ãããŠã¯ãåèšäžè¬åŒ
ïŒïŒã§ç€ºãããã¢ãŸé¡æããé»ååçæå äœã®
æå å±€ãæ§æããå å°é»æ§ç©è³ªãšããŠçšããããš
ã«ããããŸãæ¬çºæã®ã¢ãŸé¡æã®åªãããã€ãªã¢
çºçèœã®ã¿ãå©çšããããããã€ãªã¢ã®çºçãšç§»
åãšãããããå¥åã®ç©è³ªã§è¡ãªããããããæ©
èœåé¢åé»ååçæå äœã®ãã€ãªã¢çºçç©è³ªãšã
ãŠçšããããšã«ãããç®èç©æ§ã«åªããé»è·ä¿æ
åãæ床ãæ®çé»äœçã®é»ååçç¹æ§ã«åªããäž
ã€ç¹°ãè¿ã䜿çšããæã«ãç²åŽå£åãå°ãªãäžã
ç±ãããã¯å ã«å¯ŸããŠãäžè¿°ã®ç¹æ§ãå€åããã
ãšããªããå®å®ããç¹æ§ãçºæ®ãåŸãé»ååçæ
å äœãäœæããããšãåºæ¥ãã åèšäžè¬åŒã§ç€ºãããæ¬çºæã«æçšãªã¢ãŸé¡æ
ã®å ·äœäŸãšããŠã¯ãäŸãã°æ¬¡ã®æ§é åŒãæããã
ã®ãæããããããããã«ãã€ãŠæ¬çºæã®ã¢ãŸé¡
æãéå®ããããã®ã§ã¯ãªãã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
åèšäžè¬åŒïŒïŒã§ç€ºãããã¢ãŸé¡æã¯ãäžè¬
åŒ ïŒåŒäžïŒžãã¯åèšãšå矩ã§ãããïŒã§ç€ºããã
ãžã¢ãã³ãåžžæ³ã«ãã€ãŠã¢ãŸåãã次ãã§å¯Ÿå¿ã
ãã«ããã©ãŒãã¢ã«ã«ãªã®ååšäžã§ã«ãããªã³ã°
ãããããŸãã¯åèšã®ãžã¢ãã³ã®ãžã¢ãŸããŠã å¡©
ãããŠããåå¡©ããããã¯å¡©åäºéè€å¡©çã®åœ¢ã§
äžæŠåé¢ããåŸãé©åœãªæº¶åªïŒäŸãã°ãïŒïŒ®â
ãžã¡ãã«ãã«ã ã¢ããããžã¡ãã«ã¹ã«ããªãã·ã
çïŒäžã§ã¢ã«ã«ãªã®ååšäžã«ã«ããã©ãŒãšã«ãã
ãªã³ã°ããããšã«ãã容æã«åæããããšãã§ã
ãã 次ã«ãæ¬çºæã§çšããã¢ãŸé¡æã®ä»£è¡šäŸã«ã€ã
ãŠããã®åææ³ã瀺ãã åæäŸ ïŒäŸç€ºé¡æNo.77ïŒ ïŒ®âãšãã«ã«ã«ããŸãŒã«âïŒâã«ã«ããã¢ã«ã
ããïŒèç¹90âïŒ22ïœãæ°·é ¢é ž150mlã«æº¶è§£ã滎
äžããŒããããçºç ç¡é ž30mlãæ°·é ¢é ž50mlã«æº¶è§£
ãã液ã泚ææ·±ãå ããã滎äžçµäºåŸæåºããé»
çè²ç²æ«ããåããã¡ã¿ããŒã«ã§æŽæµåŸé ¢é žãšã
ã«400mlããåçµæ¶ãè¡ãªãèç¹222.5ã224.0â
ã®é»çè²ç²æ«188.7ïœãåŸãããã®ããã«ããŠåŸ
ãïŒâãããâïŒâã«ã«ããã¢ã«ãããââãš
ãã«ã«ã«ããŸãŒã«10ïœãšïŒ°âããããã³ãžã«ã·ã¢
ãããïŒïœããžã¯ãã«ãã³ãŒã³50mlã«ç±æ溶解
ãããããªãžã³ïŒãïŒæ»Žãå ããŠå ç±æ¹æãïŒæ
éè¡ãªããæåºããèµ€çè²ç²æ«ããšã¿ããŒã«ã§å
åæŽæµã次ãã§ã¡ãã«ãšãã«ã±ãã³100mlããç±
æŽãè¡ãªããIRïŒKBré å€æ³ïŒãã2200cm-1ã«â
CNã«åºã¥ãåžå1330cm-1ã«âNO2ã«åºã¥ãåžå
ãèªããããã èç¹313.5ã3188.0â åé6.45ïŒïœïŒ ãã®ããã«ããŠåŸããããžãããäœïŒäžèšæ§é
åŒïŒ ãå¡©é žãšå¡©å第ïŒé«ïŒçµæ¶ïŒã«ããéå ãè¡ãª
ããèç¹276ã278.5âã®é»è€è²ç²æ«ãåŸãã ãã®ç²æ«ã¯IRïŒKBré å€æ³ïŒ1330cm-1ã®âNO2
ã«åºã¥ãåžåã¯æ¶æ» ããæ°ãã«3200cm-1ã3350cm
-1çã«âNH2ã«åºã¥ãåžåãèªããããã ãã®ããã«ããŠåŸãããã«ã«ããŸãŒã«ç°å«æãž
ã¢ããäœ5.2ïœïŒ15mmoleïŒãïŒmlã®æ¿å¡©é žãšæ°Ž
80mlã®æ··å液ã«å ããŠåæ£ããã2.76ïœ
ïŒ40mmoleïŒã®äºç¡é žãããªãŠã ãæ°Žã«æº¶è§£ãã
ã溶液ãæ°·å·äžã«æ»Žäžãå·åŽäžçŽïŒæéåå¿ãã
ãã次ãã§æŽ»æ§çãå ããŠéããããã©ãŸããŠ
ã 氎溶液ãåŸãã ã«ãããªã³ã°æåãšããŠïŒâããããã·âïŒâ
ïŒ3â²âαïŒÎ±ïŒÎ±âããªãããããªã«ïŒããããš
é žã¢ãã10.0ïœïŒ30mmoleïŒãææ©ã¢ãã³ãšããŠ
ããªãšã¿ããŒã«ã¢ãã³15ïœïŒ100mmoleïŒã
DMF1000mlã«æº¶è§£ããïŒãïŒâã«å·åŽããã次
ãã§äžèšãžã¢ãŸããŠã 塩溶液ãã«ããã©ãŒæº¶æ¶²äž
ã«æ»Žäžããçæããé玫è²ã®ããŒã¹ãç¶æ¶²ãïŒã
10âã«ä¿ã¡æŽã«ïŒæéæ¹æãè¡ãªã€ããçæãã
æ²æŸ±ãéããã¢ã»ãã³æ¬¡ãã§æ°Žã§ååã«æŽæµã
æåŸã«å床ã¢ã»ãã³ã§æŽæµãè¡ãªãã也ç¥åŸ8.4
ïœã®é玫è²ç²æ«ãåŸããèç¹ã¯350â以äžã§ãã€
ãã ä»ã®æ¬çºæã®ã¢ãŸé¡æãäžèšåæäŸã«æºããŠåŸ
ãäºãåºæ¥ãã æ¬çºæã®é»ååçæå äœã¯ãåèšäžè¬åŒïŒïŒ
ã§è¡šããããã¢ãŸé¡æãïŒçš®ãŸãã¯ïŒçš®ä»¥äžå«æ
ããæå å±€ãæãããçš®ã ã®åœ¢æ ã®æå å±€ãåšç¥
ã§ããããæ¬çºæã®é»ååççšæå äœã®æå å±€ã¯
ãã®ãããã«ãã€ãŠããããéåžžã次ã«äŸç€ºãã
ã¿ã€ãã®æå å±€ã§ããã ã¢ãŸé¡æãããªãæå å±€ ã¢ãŸé¡æããã€ã³ããŒäžã«åæ£ãããæå å±€ ã¢ãŸé¡æãåšç¥ã®é»è·ç§»åç©è³ªäžã«åæ£ãã
ãæå å±€ åèšãã®æå å±€ãé»è·çºçå±€ãšãããã
ã«åšç¥ã®é»è·ç§»åç©è³ªãå«ãé»è·ç§»åå±€ãç©å±€
ããæå å±€ åèšäžè¬åŒã§è¡šããããã¢ãŸé¡æã¯ãå ãåžå
ãããšæ¥µããŠé«ãå¹çã§é»è·ãã€ãªã€ãŒãçºçã
ããçºçãããã€ãªã€ãŒã¯ã¢ãŸé¡æãåªäœãšããŠ
移åããããšãã§ããããåšç¥ã®é»è·ç§»åç©è³ªã
åªäœãšããŠç§»åãããæ¹ã奜ãŸããããã®ç¹ãã
åã³ã®åœ¢æ ã®æå å±€ããšãã«å¥œãŸããã é»è·ç§»åç©è³ªã¯äžè¬ã«é»åã®ç§»åç©è³ªãšããŒã«
ã®ç§»åç©è³ªãšã®ïŒçš®é¡ã«åé¡ãããããæ¬çºæã®
æå äœã®æå å±€ã«ã¯äž¡è ãšäœ¿çšããããšãã§ãã
åçš®ã®æ©èœãæãããã®ã®æ··åç©åãç°çš®ã®æ©èœ
ãæãããã®ã®æ··åç©ãã䜿çšã§ãããé»åã®ç§»
åãæããç©è³ªãšããŠã¯ããããåºãã·ã¢ãåºã
ãšã¹ãã«åºçã®é»ååžåŒåºãæããé»ååžåŒæ§å
åç©ã§ããããããã®ãã®ãšããŠäŸãã°ã2.4.7
âããªããããã«ãªã¬ãã³ã2.4.5.7âããã©ãã
ããã€ã«ãªã¬ãã³çã®ãããåãã«ãªã¬ãã³ãã
ããã¯ããã©ã·ã¢ããããžã¡ã¿ã³ãããã©ã·ã¢ã
ãšãã¬ã³ã2.4.5.7âããã©ãããããµã³ãã³ã
2.4.8âããªãããããªããµã³ãã³çã®ååç©ãã
ãããé»ååžåæ§ååç©ãé«åååãããã®çã
ãããããã ãŸããããŒã«ã®ç§»ååªäœãšããŠã¯ãé»åäŸäžæ§
ã®ææ©å å°é»æ§ååç©ãšããŠã¯ãäŸãã°æ¬¡ã®ãã
ãªãã®ããããããã ãªã©ããããããšãã§ããããã®ä»é«ååååç©
ãšããŠãããªââããã«ã«ã«ããŸãŒã«ãããã²
ã³åããªââããã«ã«ã«ããŸãŒã«ãããªããã«
ãã¬ã³ãããªããã«ã¢ã³ãã©ã»ã³ãããªããã«ã¢
ã¯ãªãžã³ãããªã°ãªã·ãžã«ã«ã«ããŸãŒã«ãããªã
ãã«ã¢ã»ãããã¬ã³ããšãã«ã«ã«ããŸãŒã«âãã«
ã ã¢ã«ãããæš¹èããªã©ãçšããããšãã§ããã ãã€ãªã€ãŒç§»åç©è³ªã¯ãããã«èšèŒãããã®ã«
éå®ããããã®ã§ãªãããã®äœ¿çšã«éããŠã¯ãã€
ãªã€ãŒç§»åç©è³ªãïŒçš®ãããã¯ïŒçš®é¡ä»¥äžæ··åã
ãŠçšããããšãã§ããã æ¬çºæé»ååççšæå äœã¯åžžæ³ã«åŸã€ãŠè£œé ã
ãããšãã§ããã äŸãã°åèšã®ã¿ã€ãã®æå å±€ãæããé»åå
ççšæå äœã¯ãåèšäžè¬åŒ(1)ã§è¡šããããã¢ãŸé¡
æãé©åœãªåªäœäžã«æº¶è§£ãªããåæ£ãããŠåŸãã
ãå¡åžæ¶²ãå°é»æ§æ¯æäœäžã«å¡åžã也ç¥ããéåžž
0.1ÎŒmã10ÎŒmã®èåã®æå å±€ã圢æãããããš
ã«ãã補é ããããšãã§ããã å¡åžæ¶²èª¿è£œçšã®åªäœãšãŠã¯ãïœâããã«ã¢ã
ã³ããšãã¬ã³ãžã¢ãã³çã®ãã¹ã¢ãŸååç©ã溶解
ããå¡©åºæ§æº¶å€ãããã¯ãããã©ããããã©ã³ã
ïŒïŒïŒâãžãªããµã³çã®ãšãŒãã«é¡ïŒã¡ãã«ãšã
ã«ã±ãã³ãã·ã¯ããããµãã³çã®ã±ãã³é¡ïŒãã«
ãšã³ããã·ã¬ã³çã®è³éŠæçåæ°ŽçŽ ïŒïŒ®ïŒïŒ®âãž
ã¡ãã«ãã«ã ã¢ãããã¢ã»ããããªã«ãâã¡ã
ã«ãããªãã³ããžã¡ãã«ã¹ã«ããã·ãçã®éãã
ãã³æ§æ¥µæ§æº¶åªïŒã¡ã¿ããŒã«ããšã¿ããŒã«ãã€ãœ
ãããããŒã«çã®ã¢ã«ã³ãŒã«é¡ïŒé ¢é žãšãã«ãé ¢
é žã¡ãã«ãã¡ãã«ã»ããœã«ãã¢ã»ããŒãçã®ãšã¹
ãã«é¡ïŒãžã¯ãã«ãšã¿ã³ãã¯ãããã«ã çã®å¡©çŽ
åçåæ°ŽçŽ ãªã©ã®ã¢ãŸé¡æãåæ£ãããåªäœãæ
ããããã ã¢ãŸé¡æãåæ£ãããåªäœãçšããå Žåã«ã¯ã
ã¢ãŸé¡æãç²åŸ5ÎŒm以äžã奜ãŸããã¯3ÎŒm以äžã
æé©ã«ã¯1ÎŒm以äžã«åŸ®ç²ååããå¿ èŠãããã ãŸããæå å±€ã圢æãããå°é»æ§æ¯æäœãšããŠ
ã¯åšç¥ã®é»ååçæå äœã«æ¡çšãããŠãããã®ã
ãããã䜿çšã§ããã å ·äœçã«ã¯ãäŸãã°ã¢ã«ãããŠã ãé çã®éå±
ãã©ã ãã·ãŒããããã¯ãããã®éå±ç®ã®ã©ãã
ãŒãç©ãèžçç©ãæããããã æŽã«ãéå±ç²æ«ãã«ãŒãã³ãã©ãã¯ããšãŠå
é ãé«ååé»è§£è³ªçã®å°é»æ§ç©è³ªãé©åœãªãã€ã³
ããŒãšãšãã«å¡åžããŠå°é»åŠçãããã©ã¹ããã¯
ãã€ã«ã ããã©ã¹ããã¯ãã©ã ãçŽçãæããã
ãããŸããéå±ç²æ«ãã«ãŒãã³ãã©ãã¯ãççŽ ç¹
ç¶çã®å°é»æ§ç©è³ªãå«æããå°é»æ§ãšãªã€ããã©
ã¹ããã¯ã®ã·ãŒãããã©ã ãæããããã åèšã®ã¿ã€ãã®æå å±€ã圢æãããéã«çšã
ãããå¡åžæ¶²ã«ãã€ã³ããŒã溶解ãããã°ãåèš
ã®ã¿ã€ãã®æå å±€ãæããé»ååççšæå äœã
補é ããããšãã§ããã ãã®å Žåãå¡åžæ¶²ã®åªäœã¯ãã€ã³ããŒã溶解ã
ããã®ã§ããããšã奜ãŸããã ãã€ã³ããŒãšãŠã¯ãã¹ãã¬ã³ãé ¢é žããã«ãã¢
ã¯ãªã«é žãšã¹ãã«ãã¡ã¿ã¯ãªã«é žãšã¹ãã«çã®ã
ãã«ååç©ã®éåäœããã³å ±éåäœãããšããã·
æš¹èãããªã¹ã«ãã³ãã¢ãªã¬ãŒãæš¹èãããªã«ãŒ
ããã€ããããªãšã¹ãã«ãã»ã«ããŒã¹ãšã¹ãã«ã
ã»ã«ããŒã¹ãšãŒãã«ããŠã¬ã¿ã³èããšããã·æš¹
èãã¢ã¯ãªã«ããªãªãŒã«æš¹èçã®åçš®ããªããŒã
æããããã ãã€ã³ããŒã®äœ¿çšéã¯ãéåžžã¢ãŸé¡æã«å¯Ÿå¯Ÿã
0.1ãïŒééåã®ç¯å²ã§ããã ãªãããã®ã¿ã€ãã®æå å±€ã圢æãããã«ãã
ã€ãŠã¯ããã¹ã¢ãŸé¡æããã€ã³ããŒäžã«çŽ°ããã
äŸãã°ç²åŸ3ÎŒm以äžããšãã«1ÎŒm以äžã®åŸ®ç²åç¶
æ ã§ååšãããããšã奜ãŸããã åæ§ã«ãåèšã®ã¿ã€ãã®æå å±€ã圢æããã
éã«çšããããå¡åžæ¶²ã«é»è·ç§»ååªäœã溶解ãã
ãã°ãåèšã®ã¿ã€ãã®æå å±€ãæããé»ååç
çšæå äœã補é ããããšãã§ããã é»è·ç§»ååªäœãšããŠã¯å ã«äŸç€ºãããã®ããã
ãã䜿çšããããšãã§ããã ããªããã«ã«ã«ããŸãŒã«ãããªã°ãªã·ãžã«ã«ã«
ããŸãŒã«çã®ããèªèº«ãã€ã³ããŒãšããŠäœ¿çšã§ã
ãé»è·ç§»ååªäœã¯ãšããããä»ã®ãã®ã¯ãã€ã³ã
ãŒã䜿çšããããšã奜ãŸããã ãã€ã³ããŒãšããŠã¯ãå ã«äŸç€ºãããã®ããã
ãã䜿çšã§ããã ãã®å Žåããã€ã³ããŒã®äœ¿çšéã¯ã¢ãŸé¡æã«å¯Ÿ
ãéåžžïŒã10ÎŒmééåã®ç¯å²ã§ããããŸãé»è·
移ååªäœã®äœ¿çšéã¯ãã€ã³ããŒã«å¯Ÿãæ®é0.2ã
1.5ééåã奜ãŸããã¯0.3ã1.2ééåã®ç¯å²ã§ã
ããããèªèº«ãã€ã³ããŒãšããŠäœ¿çšã§ããé»è·ç§»
ååªäœã®å Žåã«ã¯ãã¢ãŸååç©ã«å¯Ÿãæ®éïŒã10
ééåçšããããã ãã®ã¿ã€ãã®æå å±€ãåèšã®ã¿ã€ãã®æå å±€
åæ§ããã¹ã¢ãŸé¡æãé»è·ç§»ååªäœåã³ãã€ã³ã
ãŒäžã«åŸ®ç²åç¶æ ã§ååšãããããšã奜ãŸããã åèšãã®ã¿ã€ãã®æå å±€äžã«é»è·ç§»ååªäœ
ãé©åœãªåªäœã«æº¶è§£ãããŠåŸãããå¡åžæ¶²ãå¡
åžã也ç¥ãé»è·ç§»åå±€ã圢æãããã°ãåèšã®
ã¿ã€ãã®æå å±€ãæããé»ååççšæå äœã補é
ããããšãã§ããã ãã®å Žåãåèšãã®ã¿ã€ãã®æå å±€ã¯ãé»
è·çºçå±€ã®åœ¹å²ãæããé»è·ç§»åå±€ã¯å¿ ãããé»
è·çºçå±€ã®äžéšã«èšããå¿ èŠã¯ãªããé»è·çºçå±€
ãšå°é»æ§æ¯æäœã®éã«èšããŠããããããããè
ä¹ æ§ã®ç¹ããåè ã®æ¹ã奜ãŸããã é»è·ç§»åå±€ã®åœ¢æã¯åèšã®æå å±€ã圢æãã
ã®ãšåæ§ã«è¡ãªããããããªãã¡ãåèšã®æå
å±€ã圢æããããã®å¡åžæ¶²ããã¢ãŸé¡æãé€ãã
ãã®ãå¡åžæ¶²ãšããŠäœ¿çšããã°ããã éåžžé»è·çºçå±€ã¯ïŒã50ÎŒmã®åãã§ããã å¿è«ãæ¬çºæé»ååççšæå äœã®æå å±€ã¯åšç¥
ã®å¢æå€ãå«ãã§ããŠãããã 奜é©ãªå¢æå€ãšããŠã¯ãææ©å å°é»æ§ç©è³ªãšé»
è·ç§»åé¯äœã圢æããã«ã€ã¹é žãææè²çŽ ãæã
ãããã ã«ã€ã¹é žãšããŠã¯ãäŸãã°ã¯ãã©ãã«ãïŒïŒïŒ
âãžã¯ãã«âïŒïŒïŒâãããããã³ãïŒâã¡ãã«
ã¢ã³ãã©ããã³ãïŒâãããã¢ã³ãã©ããã³ãïŒ
âã¯ãã«âïŒâãããã¢ã³ãã©ããã³ãïŒâã¯ã
ã«ã¢ã³ãã©ããã³ãããšãã³ãã¬ã³ããã³ã®æ§ãª
ããã³é¡ãïŒâããããã³ãºã¢ã«ããããªã©ã®ã¢
ã«ãããé¡ãïŒâãã³ãŸã€ã«ã¢ã³ãã©ã»ã³ãã€ã³
ãã³ãžãªã³ãïŒïŒïŒâãžããããã³ãŸããšãã³ã
ïŒïŒ3â²ïŒïŒïŒ5â²âããã©ããããã³ãŸããšãã³ç
ã®ã±ãã³é¡ãç¡æ°Žãã¿ã«é žãïŒâã¯ãã«ããã¿ã«
é žç¡æ°Žç©çã®é žç¡æ°Žç©ãããã©ã·ã¢ããšãã«ã³ã
ãã¬ãã¿ãŒã«ããã³ãããªã«ãïŒâããããã³ã¶
ã«ããã³ãããªã«çã®ã·ã¢ãååç©ïŒïŒâãã³ã¶
ã«ãã¿ãªããïŒâïŒÎ±âã·ã¢ãâïœâããããã³
ã¶ã«ïŒãã¿ãªããïŒâïŒÎ±âã·ã¢ãâïœâããã
ãã³ã¶ã«ïŒãã¿ãªãé¡çã®é»ååžåŒæ§ååç©ãæ
ããããã ææãšããŠã¯ãäŸãã°ã¡ãã«ãã€ãªã¬ãããã
ãªãªã¢ã³ãã°ãªãŒã³ãã¯ãªã¹ã¿ã«ãã€ãªã¬ããç
ã®ããªããšãã«ã¡ã¿ã³ææãã¡ãã¬ã³ãã«ãŒãªã©
ã®ãã¢ãžã³ææãããã¶ãªã³çã®ããã³ææãã
ã³ã·ã¢ãã³ææãããªãªãŠã å¡©ããã¢ããªãªãŠã
å¡©ããã³ãŸããªãªãŠã å¡©çãæããããã ãã®ä»ã«ãã»ã¬ã³ãã»ã¬ã³âãçŽ åéãªã©ã®ç¡
æ©å å°é»æ§åŸ®ç²åãé âãã¿ãã·ã¢ãã³é¡æãã
ãªã¬ã³é¡æãªã©ã®ææ©å å°é»æ§é¡æãå«æããŠã
ãŠãããã æŽã«ãæ¬çºæé»ååççšæå äœã®æå å±€ã¯æè
æ§ãå¯ææ§ãæ©æ¢°ç匷床ãåäžãããããã«åšç¥
ã®å¯å¡å€ãå«æããŠããŠããããå¯å¡å€ãšããŠ
ã¯ããã¿ã«é žãšã¹ãã«ãããé žãšã¹ãã«ããšãã
ã·ååç©ãå¡©çŽ åãã©ãã€ã³ãå¡©çŽ åèèªé žãšã¹
ãã«ãã¡ãã«ããã¿ãªã³ãªã©ã®è³éŠæååç©ãªã©
ãæããããã ãŸããå¿ èŠã«å¿ããŠæ¥çå±€ãäžéå±€ãéæ絶çž
å±€ãæããŠããŠãããããšã¯ããŸã§ããªãã æ¬çºæã®ã¢ãŸé¡æãçšããæå äœã¯é«æ床ã§ã
ããæè²æ§ãè¯å¥œã§ãããç¹°è¿ã䜿çšãå Žåãæ
床ã垯é»æ§ã®å€åãå°ãªããå ç²åŽãå°ãªããè
ä¹ æ§ãããããŠãããããã®ã§ããã æŽã«æ¬çºææå äœã¯é»ååçè€åæ©ã®ã»ãã¬ãŒ
ã¶ãŒããã©ãŠã³ç®¡ïŒCRTïŒãçºå ãã€ãªãŒã
ïŒLEDïŒãå æºãšããããªã³ã¿ãŒã®æå äœãªã©é»
ååçã®å¿çšåéã«ãåºãçšããããšãã§ããã 次ã«æ¬çºæãå®æœäŸã«ããæŽã«å ·äœçã«èª¬æã
ãããæ¬çºæã¯ãã®èŠæšããããªãéã以äžã®å®
æœäŸã«éå®ããããã®ã§ã¯ãªãã (E) å®æœäŸ å®æœäŸ ïŒ ã¢ã«ãããŠã ç®ãã©ãããŒãããããªãšã¹ãã«
ãã€ã«ã ïŒå€§åå工補ã¢ã«ããã85ãã¢ã«ãããŠ
ã èå10ÎŒïŒããæãå°é»æ§æ¯æäœäžã«å¡©åãã
ã«ïŒé ¢ããã«ïŒç¡æ°Žãã¬ã€ã³é žå ±éåäœïŒç©æ°Žå
åŠç€Ÿè£œãšã¹ã¬ãã¯MFâ10ïŒããæãåã0.05ÎŒã®
äžéå±€ã圢æããäŸç€ºã¢ãŸé¡æNo.30ã®ïŒïœã®ããª
ã¢ãªã¬ãŒãæš¹èïŒãŠããã«è£œïŒµâ100ïŒïŒïœãšã
ïŒïŒïŒâãžã¯ãã«ãšã¿ã³100mlã«å ããŠãã€ã³ã
ã³ã³ãã€ã·ãšããŒäžã§çŽïŒæéåæ£ããããŠåŸã
ããã¢ãŸé¡æåæ£æ¶²ããåèšäžéå±€äžã«ä¹Ÿç¥åŸã®
èåã0.3ÎŒãšãªãããã«å¡åžä¹Ÿç¥ããŠãã€ãªã€ãŒ
çºçå±€ã圢æããæŽã«ãã€ãªã€ãŒç§»åç©è³ªïŒ®ïŒïŒ®
âãžãã³ãžã«ã¢ãããã³ãºã¢ã«ãããâïŒïŒïŒâ
ãžããšãã«ããã©ãŸã³ïŒïœãããªã¢ãªã¬ãŒãæš¹è
ïŒïœãšå ±ã«ãïŒïŒïŒâãžã¯ãããšã¿ã³50mlã«æº¶è§£
ãã溶液ã也ç¥åŸã®èåã12ÎŒãšãªãããã«å¡åž
也ç¥ããŠãã€ãªã€ãŒç§»åå±€ã圢æããæ¬çºæã®é»
ååçæå äœãäœè£œãããæ¬æå äœã宀枩30âæ
æã§ãäžé±éä¿ç®¡ããåŸãæ¬é»ååçæå äœãé
é»çŽè©Šéšè£ 眮ãSPâ428ãïŒå·å£é»æ©è£œäœæ補ïŒ
ã«è£ çãã以äžã®ç¹æ§è©Šéšãè¡ãªã€ãã å³ã¡ã垯é»åšâ6kVã®é»å§ãå°å ããŠïŒç§éã³
ããæŸé»ã«ããæå å±€ã垯é»ããããã®æã®é»äœ
VoïŒâïŒã次ãã§æå 局衚é¢ã«ãããç §åºŠã
3luxãšãªãç¶æ ã§ããã²ã³ã©ã³ãããã®å ãç §å°
ãããŠæå å±€ã®è¡šé¢é»äœã1/2ã«æžè¡°ããããã®
ã«å¿ èŠãªé²å é1/2ïŒluxã»ç§ïŒãæ±ããããŸã
30luxã»ç§ã®é²å éã§é²å ããããåŸã®è¡šé¢é»äœã
å³ã¡æ®çé»äœV30ïŒâïŒãæ±ãããåæ§ã®æž¬å®
ã500åç¹°ãè¿ããŠè¡ãªã€ããå°æ®çé»äœã®é€é»
å ãšããŠã¿ã³ã°ã¹ãã³ã©ã³ããå æºãšããŠ300lux
ã§0.3ç§éæŽã«ç §å°é²å ãè¡ãªãå®å šã«æ®çé»äœ
ãïŒã«ããã çµæã¯ç¬¬ïŒè¡šã«ç€ºãéãã§ããã
åŒ ïŒåŒäžïŒžãã¯åèšãšå矩ã§ãããïŒã§ç€ºããã
ãžã¢ãã³ãåžžæ³ã«ãã€ãŠã¢ãŸåãã次ãã§å¯Ÿå¿ã
ãã«ããã©ãŒãã¢ã«ã«ãªã®ååšäžã§ã«ãããªã³ã°
ãããããŸãã¯åèšã®ãžã¢ãã³ã®ãžã¢ãŸããŠã å¡©
ãããŠããåå¡©ããããã¯å¡©åäºéè€å¡©çã®åœ¢ã§
äžæŠåé¢ããåŸãé©åœãªæº¶åªïŒäŸãã°ãïŒïŒ®â
ãžã¡ãã«ãã«ã ã¢ããããžã¡ãã«ã¹ã«ããªãã·ã
çïŒäžã§ã¢ã«ã«ãªã®ååšäžã«ã«ããã©ãŒãšã«ãã
ãªã³ã°ããããšã«ãã容æã«åæããããšãã§ã
ãã 次ã«ãæ¬çºæã§çšããã¢ãŸé¡æã®ä»£è¡šäŸã«ã€ã
ãŠããã®åææ³ã瀺ãã åæäŸ ïŒäŸç€ºé¡æNo.77ïŒ ïŒ®âãšãã«ã«ã«ããŸãŒã«âïŒâã«ã«ããã¢ã«ã
ããïŒèç¹90âïŒ22ïœãæ°·é ¢é ž150mlã«æº¶è§£ã滎
äžããŒããããçºç ç¡é ž30mlãæ°·é ¢é ž50mlã«æº¶è§£
ãã液ã泚ææ·±ãå ããã滎äžçµäºåŸæåºããé»
çè²ç²æ«ããåããã¡ã¿ããŒã«ã§æŽæµåŸé ¢é žãšã
ã«400mlããåçµæ¶ãè¡ãªãèç¹222.5ã224.0â
ã®é»çè²ç²æ«188.7ïœãåŸãããã®ããã«ããŠåŸ
ãïŒâãããâïŒâã«ã«ããã¢ã«ãããââãš
ãã«ã«ã«ããŸãŒã«10ïœãšïŒ°âããããã³ãžã«ã·ã¢
ãããïŒïœããžã¯ãã«ãã³ãŒã³50mlã«ç±æ溶解
ãããããªãžã³ïŒãïŒæ»Žãå ããŠå ç±æ¹æãïŒæ
éè¡ãªããæåºããèµ€çè²ç²æ«ããšã¿ããŒã«ã§å
åæŽæµã次ãã§ã¡ãã«ãšãã«ã±ãã³100mlããç±
æŽãè¡ãªããIRïŒKBré å€æ³ïŒãã2200cm-1ã«â
CNã«åºã¥ãåžå1330cm-1ã«âNO2ã«åºã¥ãåžå
ãèªããããã èç¹313.5ã3188.0â åé6.45ïŒïœïŒ ãã®ããã«ããŠåŸããããžãããäœïŒäžèšæ§é
åŒïŒ ãå¡©é žãšå¡©å第ïŒé«ïŒçµæ¶ïŒã«ããéå ãè¡ãª
ããèç¹276ã278.5âã®é»è€è²ç²æ«ãåŸãã ãã®ç²æ«ã¯IRïŒKBré å€æ³ïŒ1330cm-1ã®âNO2
ã«åºã¥ãåžåã¯æ¶æ» ããæ°ãã«3200cm-1ã3350cm
-1çã«âNH2ã«åºã¥ãåžåãèªããããã ãã®ããã«ããŠåŸãããã«ã«ããŸãŒã«ç°å«æãž
ã¢ããäœ5.2ïœïŒ15mmoleïŒãïŒmlã®æ¿å¡©é žãšæ°Ž
80mlã®æ··å液ã«å ããŠåæ£ããã2.76ïœ
ïŒ40mmoleïŒã®äºç¡é žãããªãŠã ãæ°Žã«æº¶è§£ãã
ã溶液ãæ°·å·äžã«æ»Žäžãå·åŽäžçŽïŒæéåå¿ãã
ãã次ãã§æŽ»æ§çãå ããŠéããããã©ãŸããŠ
ã 氎溶液ãåŸãã ã«ãããªã³ã°æåãšããŠïŒâããããã·âïŒâ
ïŒ3â²âαïŒÎ±ïŒÎ±âããªãããããªã«ïŒããããš
é žã¢ãã10.0ïœïŒ30mmoleïŒãææ©ã¢ãã³ãšããŠ
ããªãšã¿ããŒã«ã¢ãã³15ïœïŒ100mmoleïŒã
DMF1000mlã«æº¶è§£ããïŒãïŒâã«å·åŽããã次
ãã§äžèšãžã¢ãŸããŠã 塩溶液ãã«ããã©ãŒæº¶æ¶²äž
ã«æ»Žäžããçæããé玫è²ã®ããŒã¹ãç¶æ¶²ãïŒã
10âã«ä¿ã¡æŽã«ïŒæéæ¹æãè¡ãªã€ããçæãã
æ²æŸ±ãéããã¢ã»ãã³æ¬¡ãã§æ°Žã§ååã«æŽæµã
æåŸã«å床ã¢ã»ãã³ã§æŽæµãè¡ãªãã也ç¥åŸ8.4
ïœã®é玫è²ç²æ«ãåŸããèç¹ã¯350â以äžã§ãã€
ãã ä»ã®æ¬çºæã®ã¢ãŸé¡æãäžèšåæäŸã«æºããŠåŸ
ãäºãåºæ¥ãã æ¬çºæã®é»ååçæå äœã¯ãåèšäžè¬åŒïŒïŒ
ã§è¡šããããã¢ãŸé¡æãïŒçš®ãŸãã¯ïŒçš®ä»¥äžå«æ
ããæå å±€ãæãããçš®ã ã®åœ¢æ ã®æå å±€ãåšç¥
ã§ããããæ¬çºæã®é»ååççšæå äœã®æå å±€ã¯
ãã®ãããã«ãã€ãŠããããéåžžã次ã«äŸç€ºãã
ã¿ã€ãã®æå å±€ã§ããã ã¢ãŸé¡æãããªãæå å±€ ã¢ãŸé¡æããã€ã³ããŒäžã«åæ£ãããæå å±€ ã¢ãŸé¡æãåšç¥ã®é»è·ç§»åç©è³ªäžã«åæ£ãã
ãæå å±€ åèšãã®æå å±€ãé»è·çºçå±€ãšãããã
ã«åšç¥ã®é»è·ç§»åç©è³ªãå«ãé»è·ç§»åå±€ãç©å±€
ããæå å±€ åèšäžè¬åŒã§è¡šããããã¢ãŸé¡æã¯ãå ãåžå
ãããšæ¥µããŠé«ãå¹çã§é»è·ãã€ãªã€ãŒãçºçã
ããçºçãããã€ãªã€ãŒã¯ã¢ãŸé¡æãåªäœãšããŠ
移åããããšãã§ããããåšç¥ã®é»è·ç§»åç©è³ªã
åªäœãšããŠç§»åãããæ¹ã奜ãŸããããã®ç¹ãã
åã³ã®åœ¢æ ã®æå å±€ããšãã«å¥œãŸããã é»è·ç§»åç©è³ªã¯äžè¬ã«é»åã®ç§»åç©è³ªãšããŒã«
ã®ç§»åç©è³ªãšã®ïŒçš®é¡ã«åé¡ãããããæ¬çºæã®
æå äœã®æå å±€ã«ã¯äž¡è ãšäœ¿çšããããšãã§ãã
åçš®ã®æ©èœãæãããã®ã®æ··åç©åãç°çš®ã®æ©èœ
ãæãããã®ã®æ··åç©ãã䜿çšã§ãããé»åã®ç§»
åãæããç©è³ªãšããŠã¯ããããåºãã·ã¢ãåºã
ãšã¹ãã«åºçã®é»ååžåŒåºãæããé»ååžåŒæ§å
åç©ã§ããããããã®ãã®ãšããŠäŸãã°ã2.4.7
âããªããããã«ãªã¬ãã³ã2.4.5.7âããã©ãã
ããã€ã«ãªã¬ãã³çã®ãããåãã«ãªã¬ãã³ãã
ããã¯ããã©ã·ã¢ããããžã¡ã¿ã³ãããã©ã·ã¢ã
ãšãã¬ã³ã2.4.5.7âããã©ãããããµã³ãã³ã
2.4.8âããªãããããªããµã³ãã³çã®ååç©ãã
ãããé»ååžåæ§ååç©ãé«åååãããã®çã
ãããããã ãŸããããŒã«ã®ç§»ååªäœãšããŠã¯ãé»åäŸäžæ§
ã®ææ©å å°é»æ§ååç©ãšããŠã¯ãäŸãã°æ¬¡ã®ãã
ãªãã®ããããããã ãªã©ããããããšãã§ããããã®ä»é«ååååç©
ãšããŠãããªââããã«ã«ã«ããŸãŒã«ãããã²
ã³åããªââããã«ã«ã«ããŸãŒã«ãããªããã«
ãã¬ã³ãããªããã«ã¢ã³ãã©ã»ã³ãããªããã«ã¢
ã¯ãªãžã³ãããªã°ãªã·ãžã«ã«ã«ããŸãŒã«ãããªã
ãã«ã¢ã»ãããã¬ã³ããšãã«ã«ã«ããŸãŒã«âãã«
ã ã¢ã«ãããæš¹èããªã©ãçšããããšãã§ããã ãã€ãªã€ãŒç§»åç©è³ªã¯ãããã«èšèŒãããã®ã«
éå®ããããã®ã§ãªãããã®äœ¿çšã«éããŠã¯ãã€
ãªã€ãŒç§»åç©è³ªãïŒçš®ãããã¯ïŒçš®é¡ä»¥äžæ··åã
ãŠçšããããšãã§ããã æ¬çºæé»ååççšæå äœã¯åžžæ³ã«åŸã€ãŠè£œé ã
ãããšãã§ããã äŸãã°åèšã®ã¿ã€ãã®æå å±€ãæããé»åå
ççšæå äœã¯ãåèšäžè¬åŒ(1)ã§è¡šããããã¢ãŸé¡
æãé©åœãªåªäœäžã«æº¶è§£ãªããåæ£ãããŠåŸãã
ãå¡åžæ¶²ãå°é»æ§æ¯æäœäžã«å¡åžã也ç¥ããéåžž
0.1ÎŒmã10ÎŒmã®èåã®æå å±€ã圢æãããããš
ã«ãã補é ããããšãã§ããã å¡åžæ¶²èª¿è£œçšã®åªäœãšãŠã¯ãïœâããã«ã¢ã
ã³ããšãã¬ã³ãžã¢ãã³çã®ãã¹ã¢ãŸååç©ã溶解
ããå¡©åºæ§æº¶å€ãããã¯ãããã©ããããã©ã³ã
ïŒïŒïŒâãžãªããµã³çã®ãšãŒãã«é¡ïŒã¡ãã«ãšã
ã«ã±ãã³ãã·ã¯ããããµãã³çã®ã±ãã³é¡ïŒãã«
ãšã³ããã·ã¬ã³çã®è³éŠæçåæ°ŽçŽ ïŒïŒ®ïŒïŒ®âãž
ã¡ãã«ãã«ã ã¢ãããã¢ã»ããããªã«ãâã¡ã
ã«ãããªãã³ããžã¡ãã«ã¹ã«ããã·ãçã®éãã
ãã³æ§æ¥µæ§æº¶åªïŒã¡ã¿ããŒã«ããšã¿ããŒã«ãã€ãœ
ãããããŒã«çã®ã¢ã«ã³ãŒã«é¡ïŒé ¢é žãšãã«ãé ¢
é žã¡ãã«ãã¡ãã«ã»ããœã«ãã¢ã»ããŒãçã®ãšã¹
ãã«é¡ïŒãžã¯ãã«ãšã¿ã³ãã¯ãããã«ã çã®å¡©çŽ
åçåæ°ŽçŽ ãªã©ã®ã¢ãŸé¡æãåæ£ãããåªäœãæ
ããããã ã¢ãŸé¡æãåæ£ãããåªäœãçšããå Žåã«ã¯ã
ã¢ãŸé¡æãç²åŸ5ÎŒm以äžã奜ãŸããã¯3ÎŒm以äžã
æé©ã«ã¯1ÎŒm以äžã«åŸ®ç²ååããå¿ èŠãããã ãŸããæå å±€ã圢æãããå°é»æ§æ¯æäœãšããŠ
ã¯åšç¥ã®é»ååçæå äœã«æ¡çšãããŠãããã®ã
ãããã䜿çšã§ããã å ·äœçã«ã¯ãäŸãã°ã¢ã«ãããŠã ãé çã®éå±
ãã©ã ãã·ãŒããããã¯ãããã®éå±ç®ã®ã©ãã
ãŒãç©ãèžçç©ãæããããã æŽã«ãéå±ç²æ«ãã«ãŒãã³ãã©ãã¯ããšãŠå
é ãé«ååé»è§£è³ªçã®å°é»æ§ç©è³ªãé©åœãªãã€ã³
ããŒãšãšãã«å¡åžããŠå°é»åŠçãããã©ã¹ããã¯
ãã€ã«ã ããã©ã¹ããã¯ãã©ã ãçŽçãæããã
ãããŸããéå±ç²æ«ãã«ãŒãã³ãã©ãã¯ãççŽ ç¹
ç¶çã®å°é»æ§ç©è³ªãå«æããå°é»æ§ãšãªã€ããã©
ã¹ããã¯ã®ã·ãŒãããã©ã ãæããããã åèšã®ã¿ã€ãã®æå å±€ã圢æãããéã«çšã
ãããå¡åžæ¶²ã«ãã€ã³ããŒã溶解ãããã°ãåèš
ã®ã¿ã€ãã®æå å±€ãæããé»ååççšæå äœã
補é ããããšãã§ããã ãã®å Žåãå¡åžæ¶²ã®åªäœã¯ãã€ã³ããŒã溶解ã
ããã®ã§ããããšã奜ãŸããã ãã€ã³ããŒãšãŠã¯ãã¹ãã¬ã³ãé ¢é žããã«ãã¢
ã¯ãªã«é žãšã¹ãã«ãã¡ã¿ã¯ãªã«é žãšã¹ãã«çã®ã
ãã«ååç©ã®éåäœããã³å ±éåäœãããšããã·
æš¹èãããªã¹ã«ãã³ãã¢ãªã¬ãŒãæš¹èãããªã«ãŒ
ããã€ããããªãšã¹ãã«ãã»ã«ããŒã¹ãšã¹ãã«ã
ã»ã«ããŒã¹ãšãŒãã«ããŠã¬ã¿ã³èããšããã·æš¹
èãã¢ã¯ãªã«ããªãªãŒã«æš¹èçã®åçš®ããªããŒã
æããããã ãã€ã³ããŒã®äœ¿çšéã¯ãéåžžã¢ãŸé¡æã«å¯Ÿå¯Ÿã
0.1ãïŒééåã®ç¯å²ã§ããã ãªãããã®ã¿ã€ãã®æå å±€ã圢æãããã«ãã
ã€ãŠã¯ããã¹ã¢ãŸé¡æããã€ã³ããŒäžã«çŽ°ããã
äŸãã°ç²åŸ3ÎŒm以äžããšãã«1ÎŒm以äžã®åŸ®ç²åç¶
æ ã§ååšãããããšã奜ãŸããã åæ§ã«ãåèšã®ã¿ã€ãã®æå å±€ã圢æããã
éã«çšããããå¡åžæ¶²ã«é»è·ç§»ååªäœã溶解ãã
ãã°ãåèšã®ã¿ã€ãã®æå å±€ãæããé»ååç
çšæå äœã補é ããããšãã§ããã é»è·ç§»ååªäœãšããŠã¯å ã«äŸç€ºãããã®ããã
ãã䜿çšããããšãã§ããã ããªããã«ã«ã«ããŸãŒã«ãããªã°ãªã·ãžã«ã«ã«
ããŸãŒã«çã®ããèªèº«ãã€ã³ããŒãšããŠäœ¿çšã§ã
ãé»è·ç§»ååªäœã¯ãšããããä»ã®ãã®ã¯ãã€ã³ã
ãŒã䜿çšããããšã奜ãŸããã ãã€ã³ããŒãšããŠã¯ãå ã«äŸç€ºãããã®ããã
ãã䜿çšã§ããã ãã®å Žåããã€ã³ããŒã®äœ¿çšéã¯ã¢ãŸé¡æã«å¯Ÿ
ãéåžžïŒã10ÎŒmééåã®ç¯å²ã§ããããŸãé»è·
移ååªäœã®äœ¿çšéã¯ãã€ã³ããŒã«å¯Ÿãæ®é0.2ã
1.5ééåã奜ãŸããã¯0.3ã1.2ééåã®ç¯å²ã§ã
ããããèªèº«ãã€ã³ããŒãšããŠäœ¿çšã§ããé»è·ç§»
ååªäœã®å Žåã«ã¯ãã¢ãŸååç©ã«å¯Ÿãæ®éïŒã10
ééåçšããããã ãã®ã¿ã€ãã®æå å±€ãåèšã®ã¿ã€ãã®æå å±€
åæ§ããã¹ã¢ãŸé¡æãé»è·ç§»ååªäœåã³ãã€ã³ã
ãŒäžã«åŸ®ç²åç¶æ ã§ååšãããããšã奜ãŸããã åèšãã®ã¿ã€ãã®æå å±€äžã«é»è·ç§»ååªäœ
ãé©åœãªåªäœã«æº¶è§£ãããŠåŸãããå¡åžæ¶²ãå¡
åžã也ç¥ãé»è·ç§»åå±€ã圢æãããã°ãåèšã®
ã¿ã€ãã®æå å±€ãæããé»ååççšæå äœã補é
ããããšãã§ããã ãã®å Žåãåèšãã®ã¿ã€ãã®æå å±€ã¯ãé»
è·çºçå±€ã®åœ¹å²ãæããé»è·ç§»åå±€ã¯å¿ ãããé»
è·çºçå±€ã®äžéšã«èšããå¿ èŠã¯ãªããé»è·çºçå±€
ãšå°é»æ§æ¯æäœã®éã«èšããŠããããããããè
ä¹ æ§ã®ç¹ããåè ã®æ¹ã奜ãŸããã é»è·ç§»åå±€ã®åœ¢æã¯åèšã®æå å±€ã圢æãã
ã®ãšåæ§ã«è¡ãªããããããªãã¡ãåèšã®æå
å±€ã圢æããããã®å¡åžæ¶²ããã¢ãŸé¡æãé€ãã
ãã®ãå¡åžæ¶²ãšããŠäœ¿çšããã°ããã éåžžé»è·çºçå±€ã¯ïŒã50ÎŒmã®åãã§ããã å¿è«ãæ¬çºæé»ååççšæå äœã®æå å±€ã¯åšç¥
ã®å¢æå€ãå«ãã§ããŠãããã 奜é©ãªå¢æå€ãšããŠã¯ãææ©å å°é»æ§ç©è³ªãšé»
è·ç§»åé¯äœã圢æããã«ã€ã¹é žãææè²çŽ ãæã
ãããã ã«ã€ã¹é žãšããŠã¯ãäŸãã°ã¯ãã©ãã«ãïŒïŒïŒ
âãžã¯ãã«âïŒïŒïŒâãããããã³ãïŒâã¡ãã«
ã¢ã³ãã©ããã³ãïŒâãããã¢ã³ãã©ããã³ãïŒ
âã¯ãã«âïŒâãããã¢ã³ãã©ããã³ãïŒâã¯ã
ã«ã¢ã³ãã©ããã³ãããšãã³ãã¬ã³ããã³ã®æ§ãª
ããã³é¡ãïŒâããããã³ãºã¢ã«ããããªã©ã®ã¢
ã«ãããé¡ãïŒâãã³ãŸã€ã«ã¢ã³ãã©ã»ã³ãã€ã³
ãã³ãžãªã³ãïŒïŒïŒâãžããããã³ãŸããšãã³ã
ïŒïŒ3â²ïŒïŒïŒ5â²âããã©ããããã³ãŸããšãã³ç
ã®ã±ãã³é¡ãç¡æ°Žãã¿ã«é žãïŒâã¯ãã«ããã¿ã«
é žç¡æ°Žç©çã®é žç¡æ°Žç©ãããã©ã·ã¢ããšãã«ã³ã
ãã¬ãã¿ãŒã«ããã³ãããªã«ãïŒâããããã³ã¶
ã«ããã³ãããªã«çã®ã·ã¢ãååç©ïŒïŒâãã³ã¶
ã«ãã¿ãªããïŒâïŒÎ±âã·ã¢ãâïœâããããã³
ã¶ã«ïŒãã¿ãªããïŒâïŒÎ±âã·ã¢ãâïœâããã
ãã³ã¶ã«ïŒãã¿ãªãé¡çã®é»ååžåŒæ§ååç©ãæ
ããããã ææãšããŠã¯ãäŸãã°ã¡ãã«ãã€ãªã¬ãããã
ãªãªã¢ã³ãã°ãªãŒã³ãã¯ãªã¹ã¿ã«ãã€ãªã¬ããç
ã®ããªããšãã«ã¡ã¿ã³ææãã¡ãã¬ã³ãã«ãŒãªã©
ã®ãã¢ãžã³ææãããã¶ãªã³çã®ããã³ææãã
ã³ã·ã¢ãã³ææãããªãªãŠã å¡©ããã¢ããªãªãŠã
å¡©ããã³ãŸããªãªãŠã å¡©çãæããããã ãã®ä»ã«ãã»ã¬ã³ãã»ã¬ã³âãçŽ åéãªã©ã®ç¡
æ©å å°é»æ§åŸ®ç²åãé âãã¿ãã·ã¢ãã³é¡æãã
ãªã¬ã³é¡æãªã©ã®ææ©å å°é»æ§é¡æãå«æããŠã
ãŠãããã æŽã«ãæ¬çºæé»ååççšæå äœã®æå å±€ã¯æè
æ§ãå¯ææ§ãæ©æ¢°ç匷床ãåäžãããããã«åšç¥
ã®å¯å¡å€ãå«æããŠããŠããããå¯å¡å€ãšããŠ
ã¯ããã¿ã«é žãšã¹ãã«ãããé žãšã¹ãã«ããšãã
ã·ååç©ãå¡©çŽ åãã©ãã€ã³ãå¡©çŽ åèèªé žãšã¹
ãã«ãã¡ãã«ããã¿ãªã³ãªã©ã®è³éŠæååç©ãªã©
ãæããããã ãŸããå¿ èŠã«å¿ããŠæ¥çå±€ãäžéå±€ãéæ絶çž
å±€ãæããŠããŠãããããšã¯ããŸã§ããªãã æ¬çºæã®ã¢ãŸé¡æãçšããæå äœã¯é«æ床ã§ã
ããæè²æ§ãè¯å¥œã§ãããç¹°è¿ã䜿çšãå Žåãæ
床ã垯é»æ§ã®å€åãå°ãªããå ç²åŽãå°ãªããè
ä¹ æ§ãããããŠãããããã®ã§ããã æŽã«æ¬çºææå äœã¯é»ååçè€åæ©ã®ã»ãã¬ãŒ
ã¶ãŒããã©ãŠã³ç®¡ïŒCRTïŒãçºå ãã€ãªãŒã
ïŒLEDïŒãå æºãšããããªã³ã¿ãŒã®æå äœãªã©é»
ååçã®å¿çšåéã«ãåºãçšããããšãã§ããã 次ã«æ¬çºæãå®æœäŸã«ããæŽã«å ·äœçã«èª¬æã
ãããæ¬çºæã¯ãã®èŠæšããããªãéã以äžã®å®
æœäŸã«éå®ããããã®ã§ã¯ãªãã (E) å®æœäŸ å®æœäŸ ïŒ ã¢ã«ãããŠã ç®ãã©ãããŒãããããªãšã¹ãã«
ãã€ã«ã ïŒå€§åå工補ã¢ã«ããã85ãã¢ã«ãããŠ
ã èå10ÎŒïŒããæãå°é»æ§æ¯æäœäžã«å¡©åãã
ã«ïŒé ¢ããã«ïŒç¡æ°Žãã¬ã€ã³é žå ±éåäœïŒç©æ°Žå
åŠç€Ÿè£œãšã¹ã¬ãã¯MFâ10ïŒããæãåã0.05ÎŒã®
äžéå±€ã圢æããäŸç€ºã¢ãŸé¡æNo.30ã®ïŒïœã®ããª
ã¢ãªã¬ãŒãæš¹èïŒãŠããã«è£œïŒµâ100ïŒïŒïœãšã
ïŒïŒïŒâãžã¯ãã«ãšã¿ã³100mlã«å ããŠãã€ã³ã
ã³ã³ãã€ã·ãšããŒäžã§çŽïŒæéåæ£ããããŠåŸã
ããã¢ãŸé¡æåæ£æ¶²ããåèšäžéå±€äžã«ä¹Ÿç¥åŸã®
èåã0.3ÎŒãšãªãããã«å¡åžä¹Ÿç¥ããŠãã€ãªã€ãŒ
çºçå±€ã圢æããæŽã«ãã€ãªã€ãŒç§»åç©è³ªïŒ®ïŒïŒ®
âãžãã³ãžã«ã¢ãããã³ãºã¢ã«ãããâïŒïŒïŒâ
ãžããšãã«ããã©ãŸã³ïŒïœãããªã¢ãªã¬ãŒãæš¹è
ïŒïœãšå ±ã«ãïŒïŒïŒâãžã¯ãããšã¿ã³50mlã«æº¶è§£
ãã溶液ã也ç¥åŸã®èåã12ÎŒãšãªãããã«å¡åž
也ç¥ããŠãã€ãªã€ãŒç§»åå±€ã圢æããæ¬çºæã®é»
ååçæå äœãäœè£œãããæ¬æå äœã宀枩30âæ
æã§ãäžé±éä¿ç®¡ããåŸãæ¬é»ååçæå äœãé
é»çŽè©Šéšè£ 眮ãSPâ428ãïŒå·å£é»æ©è£œäœæ補ïŒ
ã«è£ çãã以äžã®ç¹æ§è©Šéšãè¡ãªã€ãã å³ã¡ã垯é»åšâ6kVã®é»å§ãå°å ããŠïŒç§éã³
ããæŸé»ã«ããæå å±€ã垯é»ããããã®æã®é»äœ
VoïŒâïŒã次ãã§æå 局衚é¢ã«ãããç §åºŠã
3luxãšãªãç¶æ ã§ããã²ã³ã©ã³ãããã®å ãç §å°
ãããŠæå å±€ã®è¡šé¢é»äœã1/2ã«æžè¡°ããããã®
ã«å¿ èŠãªé²å é1/2ïŒluxã»ç§ïŒãæ±ããããŸã
30luxã»ç§ã®é²å éã§é²å ããããåŸã®è¡šé¢é»äœã
å³ã¡æ®çé»äœV30ïŒâïŒãæ±ãããåæ§ã®æž¬å®
ã500åç¹°ãè¿ããŠè¡ãªã€ããå°æ®çé»äœã®é€é»
å ãšããŠã¿ã³ã°ã¹ãã³ã©ã³ããå æºãšããŠ300lux
ã§0.3ç§éæŽã«ç §å°é²å ãè¡ãªãå®å šã«æ®çé»äœ
ãïŒã«ããã çµæã¯ç¬¬ïŒè¡šã«ç€ºãéãã§ããã
ãè¡šã
å®æœäŸ ïŒãïŒ
ãã€ãªã€ãŒçºçç©è³ªãšããŠãåã
äŸç€ºã¢ãŸé¡æ
ïŒãïŒãïŒã24ãçšããã»ãã¯ãå®æœäŸïŒãšåæ§
ã«ããŠåèšïŒçš®é¡ã®æ¬çºæé»ååçæå äœãäœæ
ãããã®åã ã«ã€ããŠåæ§ã®ç¹æ§è©Šéšãè¡ãªã€
ããçµæã¯ç¬¬ïŒè¡šã«ç€ºãéãã§ããã
ïŒãïŒãïŒã24ãçšããã»ãã¯ãå®æœäŸïŒãšåæ§
ã«ããŠåèšïŒçš®é¡ã®æ¬çºæé»ååçæå äœãäœæ
ãããã®åã ã«ã€ããŠåæ§ã®ç¹æ§è©Šéšãè¡ãªã€
ããçµæã¯ç¬¬ïŒè¡šã«ç€ºãéãã§ããã
ãè¡šã
å®æœäŸ ïŒ
ã¢ã«ãããŠã ããæãçŽåŸ60mmã®ãã©ã ã®å€åŽ
è¡šé¢äžã«ãå¡©åããã«ïŒé ¢é žããã«ïŒ87ïŒ13ïŒå ±
éåäœïŒUCIC補VYHHïŒããæãåã0.04ÎŒã®
äžéå±€ã圢æããäŸç€ºã¢ãŸé¡æ77ã®ïŒïœãããã©
ããããã©ã³400mlã«å ããŠãã€ã³ãã³ã³ãã·ãš
ããŒãçšããŠçŽïŒæéåæ£ããããŠåŸãããåæ£
液ããåèšäžéå±€äžã«ä¹Ÿç¥åŸã®èåã0.5ÎŒãšãªã
ããã«å¡åžä¹Ÿç¥ããŠãã€ãªã€ãŒçºçå±€ã圢æã
ãããã®ãã€ãªã€ãŒçºçå±€äžã«æ§åŒ åŒ ã§ç€ºããããã€ãªã€ãŒç§»åç©è³ªïŒ®ïŒïŒ®âãžã¢ãªã«
ã¢ãããã³ãºã¢ã«ãããâïŒâããšãã«âïŒâã¡
ãã«ããã©ãŸã³10ïœãããªã«ãŒãããŒãæš¹èïŒåž
人補ãã³ã©ã€ãâ1250ïŒ12ïœãšå ±ã«ïŒïŒïŒâãž
ã¯ãã«ãšã¿ã³100mlã«æº¶è§£ãã溶液ãã也ç¥åŸã®
èå15ÎŒãšãªãããã«å¡åžä¹Ÿç¥ããŠãã€ãªã€ãŒç§»
åå±€ã圢æããæ¬çºæã«ä¿ããã©ã åé»ååçæ
å äœãäœè£œããã ãã®é»ååçæå äœãåžè²©ã®ã«ãŒããªããžåŒé»
ååçè€åæ©ã®åœç€Ÿæ¹é æ©ã«è£ çããè€åç»åã
圢æãããããšãããã³ã³ãã©ã¹ããé«ããŠåçš¿
ã«å¿ å®ã§ãã€é®®æãªå¯èŠåãåŸããããåè€åã
1000åç¹°ãè¿ããããæåŸãŸã§ç¬¬ïŒåç®ãšåçã®
å¯èŠåãåŸãããã å®æœäŸ ïŒ å®æœäŸïŒã§åŸããã©ã åé»ååçæå äœã®åå°
ã¹ãã¯ãã«ãç©åçãè£ çããåå å 床èšïŒå³¶æŽ¥
補UVâ365ïŒãã枬å®ãããã®ã°ã©ãã第ïŒå³
ã«ç€ºããããã®ã°ã©ãããæ¬æå äœã®å¯èŠéšã«æŒ
ããæ倧åžåæ³¢é·ã¯670nmä»è¿ã«ããäºãå€æã
ããæŽã«660nmã670nmã«æŒããåå æ床ãã¢ã
ã¯ãã«ã¡ãŒã¿ãŒãçšããŠæž¬å®ããæãé»äœåæžã«
èŠãããšãã«ã®ãŒã¯äž¡æ³¢é·ãšãçŽ3.5ergïŒcm2ãšé
åžžã«é«ãæå äœã§ãããå æºãšããŠçºå ãã€ãªãŒ
ãïŒLEDïŒãçšããŠãååå®çšã«èãããæå
äœã§ããäºãããã€ãã å®æœäŸ ïŒã13 ã¢ã«ãããŠã ãèžçããããªãšã¹ãã«ãã€ã«ã
ããæãå°é»æ§æ¯æäœäžã«æ°Žæº¶æ§ãã€ãã³æš¹è
ïŒAQãã€ãã³ïŒ°â70ïŒããæãåã0.05ÎŒã®äžé
å±€ã圢æããäŸç€ºã¢ãŸé¡æ12ã17ã30ã34ã85ã®
ã¢ãŸé¡æãïœâããã«ã¢ãã³ã«æº¶è§£ãã溶液ãå
èšäžéå±€äžã«å¡åžããŠèå0.1ÎŒã®ãã€ãªã€ãŒçºç
å±€ã圢æããããã次ãã§ãã®ãã€ãªã€ãŒçºçå±€
äžã«ïŒâãžãšãã«ã¢ããããšãã«âïŒâããšãã«
âïŒâã¹ããªã«ãã©ãŸãªã³ïŒïœãšããªãšã¹ãã«æš¹
èïŒæ±æŽçŽ¡è£œãã€ãã³â200ïŒïŒïœãïŒïŒïŒâãž
ã¯ãã«ãšã¿ã³40mlã«æº¶è§£ãã溶液ãã也ç¥åŸã®è
åã14ÎŒãšãªãããã«å¡åžä¹Ÿç¥ããŠãã€ãªã€ãŒç§»
åå±€ã圢æããæ¬çºæã®é»ååçæå äœãäœè£œã
ãããããåèšïŒçš®é¡ã®æå äœã®åå°åžåæ²ç·ã
æ±ãå¯èŠãè¿èµ€å€éšã®æ倧åžåæ³¢é·åã³ãã®æ³¢é·
ã§ã®é»äœåæžã«èŠãããšãã«ã®ãŒãå®æœäŸïŒã«æº
ããŠæ±ãããçµæã¯ç¬¬ïŒè¡šã«ç€ºãéãã§ããã
å°ãåæé»äœVoã¯ã©ã®æå äœã500ïŒâïŒãè¶
ããŠããã
è¡šé¢äžã«ãå¡©åããã«ïŒé ¢é žããã«ïŒ87ïŒ13ïŒå ±
éåäœïŒUCIC補VYHHïŒããæãåã0.04ÎŒã®
äžéå±€ã圢æããäŸç€ºã¢ãŸé¡æ77ã®ïŒïœãããã©
ããããã©ã³400mlã«å ããŠãã€ã³ãã³ã³ãã·ãš
ããŒãçšããŠçŽïŒæéåæ£ããããŠåŸãããåæ£
液ããåèšäžéå±€äžã«ä¹Ÿç¥åŸã®èåã0.5ÎŒãšãªã
ããã«å¡åžä¹Ÿç¥ããŠãã€ãªã€ãŒçºçå±€ã圢æã
ãããã®ãã€ãªã€ãŒçºçå±€äžã«æ§åŒ åŒ ã§ç€ºããããã€ãªã€ãŒç§»åç©è³ªïŒ®ïŒïŒ®âãžã¢ãªã«
ã¢ãããã³ãºã¢ã«ãããâïŒâããšãã«âïŒâã¡
ãã«ããã©ãŸã³10ïœãããªã«ãŒãããŒãæš¹èïŒåž
人補ãã³ã©ã€ãâ1250ïŒ12ïœãšå ±ã«ïŒïŒïŒâãž
ã¯ãã«ãšã¿ã³100mlã«æº¶è§£ãã溶液ãã也ç¥åŸã®
èå15ÎŒãšãªãããã«å¡åžä¹Ÿç¥ããŠãã€ãªã€ãŒç§»
åå±€ã圢æããæ¬çºæã«ä¿ããã©ã åé»ååçæ
å äœãäœè£œããã ãã®é»ååçæå äœãåžè²©ã®ã«ãŒããªããžåŒé»
ååçè€åæ©ã®åœç€Ÿæ¹é æ©ã«è£ çããè€åç»åã
圢æãããããšãããã³ã³ãã©ã¹ããé«ããŠåçš¿
ã«å¿ å®ã§ãã€é®®æãªå¯èŠåãåŸããããåè€åã
1000åç¹°ãè¿ããããæåŸãŸã§ç¬¬ïŒåç®ãšåçã®
å¯èŠåãåŸãããã å®æœäŸ ïŒ å®æœäŸïŒã§åŸããã©ã åé»ååçæå äœã®åå°
ã¹ãã¯ãã«ãç©åçãè£ çããåå å 床èšïŒå³¶æŽ¥
補UVâ365ïŒãã枬å®ãããã®ã°ã©ãã第ïŒå³
ã«ç€ºããããã®ã°ã©ãããæ¬æå äœã®å¯èŠéšã«æŒ
ããæ倧åžåæ³¢é·ã¯670nmä»è¿ã«ããäºãå€æã
ããæŽã«660nmã670nmã«æŒããåå æ床ãã¢ã
ã¯ãã«ã¡ãŒã¿ãŒãçšããŠæž¬å®ããæãé»äœåæžã«
èŠãããšãã«ã®ãŒã¯äž¡æ³¢é·ãšãçŽ3.5ergïŒcm2ãšé
åžžã«é«ãæå äœã§ãããå æºãšããŠçºå ãã€ãªãŒ
ãïŒLEDïŒãçšããŠãååå®çšã«èãããæå
äœã§ããäºãããã€ãã å®æœäŸ ïŒã13 ã¢ã«ãããŠã ãèžçããããªãšã¹ãã«ãã€ã«ã
ããæãå°é»æ§æ¯æäœäžã«æ°Žæº¶æ§ãã€ãã³æš¹è
ïŒAQãã€ãã³ïŒ°â70ïŒããæãåã0.05ÎŒã®äžé
å±€ã圢æããäŸç€ºã¢ãŸé¡æ12ã17ã30ã34ã85ã®
ã¢ãŸé¡æãïœâããã«ã¢ãã³ã«æº¶è§£ãã溶液ãå
èšäžéå±€äžã«å¡åžããŠèå0.1ÎŒã®ãã€ãªã€ãŒçºç
å±€ã圢æããããã次ãã§ãã®ãã€ãªã€ãŒçºçå±€
äžã«ïŒâãžãšãã«ã¢ããããšãã«âïŒâããšãã«
âïŒâã¹ããªã«ãã©ãŸãªã³ïŒïœãšããªãšã¹ãã«æš¹
èïŒæ±æŽçŽ¡è£œãã€ãã³â200ïŒïŒïœãïŒïŒïŒâãž
ã¯ãã«ãšã¿ã³40mlã«æº¶è§£ãã溶液ãã也ç¥åŸã®è
åã14ÎŒãšãªãããã«å¡åžä¹Ÿç¥ããŠãã€ãªã€ãŒç§»
åå±€ã圢æããæ¬çºæã®é»ååçæå äœãäœè£œã
ãããããåèšïŒçš®é¡ã®æå äœã®åå°åžåæ²ç·ã
æ±ãå¯èŠãè¿èµ€å€éšã®æ倧åžåæ³¢é·åã³ãã®æ³¢é·
ã§ã®é»äœåæžã«èŠãããšãã«ã®ãŒãå®æœäŸïŒã«æº
ããŠæ±ãããçµæã¯ç¬¬ïŒè¡šã«ç€ºãéãã§ããã
å°ãåæé»äœVoã¯ã©ã®æå äœã500ïŒâïŒãè¶
ããŠããã
ãè¡šã
å®æœäŸ 14
ç ç®ç«ããè¡šé¢é
žåã®Alæ¿äžã«ãã¹ãã¬ã³ïŒ
ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãïŒã¡ã¿ã¯ãªã«é žå ±éåäœ
ïŒã¹ãã¬ã³ïŒã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãïŒïŒïŒïŒéé
æ¯ãé žäŸ¡215ïŒãšäŸç€ºã¢ãŸé¡æ110åã³ããªããã
ããã¬ãã³ã1.5ïŒïŒïŒ0.2ã®ééæ¯ã§é åããã
ããžãªããµã³äžã§æº¶è§£ïŒæš¹èæåãããªãããã
ãã¬ãã³ïŒåæ£ïŒã¢ãŸé¡æïŒãã液ãå¡åžä¹Ÿç¥
ããèå6ÎŒã®äžå±€åæå äœãäœæããã ãã®ããã«ããŠäœæããæ¬çºæã®æå äœã«ã€ã
ãŠåè¿°ã®éé»çŽè©Šéšè£ 眮ã«ããé»ååçç¹æ§è©Šéš
ãè¡ãªã€ãã é»å§6kV VoïŒ480ïŒïŒïŒ¶ïŒ 1/2ïŒïŒïŒluxã»ç§ïŒ ã§ãã€ãã åãæ¬æå äœãçŸåå€ïŒãããŒïŒã§å¯èŠåå
ãã次ãã§ã¢ã«ã«ãªæ§åŠç液ïŒäŸãã°ïŒïŒ ããªãš
ã¿ããŒã«ã¢ãã³ã10ïŒ çé žã¢ã³ã¢ããŠã ããš15ïŒ
ã®å¹³åååé190ã210ã®ããªãšãã¬ã³ã°ãªã³ãŒ
ã«ãïŒïŒ ãã³ãžã«ã¢ã«ã³ãŒã«ïŒã§åŠçãããšãã
ããŒéä»çéšã¯å®¹æã«æº¶åºãã次ãã§ã±ã€é žãœãŒ
ããŒãå«ãã æ°Žã§æ°ŽæŽããããšã«ãã€ãŠãå°å·å
çã容æã«äœæãããšãã§ããã ãã®åçãçšããŠãªãã»ããå°å·ãè¡ãªããšçŽ
10æäžã®å°å·ã«ãèããäºãããã€ãã å°ããããŒå¯èŠåãåŸãçºã®ïŒå æºïŒããã²ã³
ã©ã³ãïŒæé©é²å éã¯50luxã»ç§ã§ãåå°å·åç
ãäœæããéãçäžææãçšãããã€ã¬ã¯ã補ç
ã«ããè¡ãªã€ãã
ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãïŒã¡ã¿ã¯ãªã«é žå ±éåäœ
ïŒã¹ãã¬ã³ïŒã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãïŒïŒïŒïŒéé
æ¯ãé žäŸ¡215ïŒãšäŸç€ºã¢ãŸé¡æ110åã³ããªããã
ããã¬ãã³ã1.5ïŒïŒïŒ0.2ã®ééæ¯ã§é åããã
ããžãªããµã³äžã§æº¶è§£ïŒæš¹èæåãããªãããã
ãã¬ãã³ïŒåæ£ïŒã¢ãŸé¡æïŒãã液ãå¡åžä¹Ÿç¥
ããèå6ÎŒã®äžå±€åæå äœãäœæããã ãã®ããã«ããŠäœæããæ¬çºæã®æå äœã«ã€ã
ãŠåè¿°ã®éé»çŽè©Šéšè£ 眮ã«ããé»ååçç¹æ§è©Šéš
ãè¡ãªã€ãã é»å§6kV VoïŒ480ïŒïŒïŒ¶ïŒ 1/2ïŒïŒïŒluxã»ç§ïŒ ã§ãã€ãã åãæ¬æå äœãçŸåå€ïŒãããŒïŒã§å¯èŠåå
ãã次ãã§ã¢ã«ã«ãªæ§åŠç液ïŒäŸãã°ïŒïŒ ããªãš
ã¿ããŒã«ã¢ãã³ã10ïŒ çé žã¢ã³ã¢ããŠã ããš15ïŒ
ã®å¹³åååé190ã210ã®ããªãšãã¬ã³ã°ãªã³ãŒ
ã«ãïŒïŒ ãã³ãžã«ã¢ã«ã³ãŒã«ïŒã§åŠçãããšãã
ããŒéä»çéšã¯å®¹æã«æº¶åºãã次ãã§ã±ã€é žãœãŒ
ããŒãå«ãã æ°Žã§æ°ŽæŽããããšã«ãã€ãŠãå°å·å
çã容æã«äœæãããšãã§ããã ãã®åçãçšããŠãªãã»ããå°å·ãè¡ãªããšçŽ
10æäžã®å°å·ã«ãèããäºãããã€ãã å°ããããŒå¯èŠåãåŸãçºã®ïŒå æºïŒããã²ã³
ã©ã³ãïŒæé©é²å éã¯50luxã»ç§ã§ãåå°å·åç
ãäœæããéãçäžææãçšãããã€ã¬ã¯ã補ç
ã«ããè¡ãªã€ãã
第ïŒå³ã¯ãå®æœäŸïŒã«ãããæ¬çºææå
äœã®å
å°åžåæ²ç·ã§ããããã®åžåæ²ç·ãã670nmã«ç¬¬
ïŒæ¥µå€§åžå630nmã«ç¬¬ïŒæ¥µå€§åžåããããåã
400nmä»è¿ã®åžåã¯ããã€ãªã€ãŒç§»åç©è³ªã§ãã
ããã©ãŸã³ååç©ã«åºããã®ã§ããã
å°åžåæ²ç·ã§ããããã®åžåæ²ç·ãã670nmã«ç¬¬
ïŒæ¥µå€§åžå630nmã«ç¬¬ïŒæ¥µå€§åžåããããåã
400nmä»è¿ã®åžåã¯ããã€ãªã€ãŒç§»åç©è³ªã§ãã
ããã©ãŸã³ååç©ã«åºããã®ã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ å°é»æ§æ¯æäœäžã«äžèšäžè¬åŒïŒïŒã§ç€ºãã
ãã¢ãŸé¡æãå«æããæå å±€ãæããããšãç¹åŸŽ
ãšããé»ååçæå äœã ïŒåŒäžïŒžã¯æ°ŽçŽ ãããã²ã³ããããªã«ã§ããã
ã¯æ°ŽçŽ ãã¢ãªãŒã«åºã眮æãæªçœ®æã®ã¢ã«ãã«
åºã眮æãæªçœ®æã®ãã³ãžã«åºã§ããCpã¯ã«ã
ãã©ãŒæ®åºã§ãããïŒ ïŒ åèšæå å±€ããã€ãªã€ãŒç§»ååç©è³ªãšãã€ãª
ã€ãŒçºçç©è³ªãšãå«æããåœè©²ãã€ãªã€ãŒçºçç©
質ãåèšäžè¬åŒïŒïŒã§ç€ºãããã¢ãŸé¡æã§ãã
ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®é»ååçæå äœã ïŒ åèšäžè¬åŒïŒïŒã§ç€ºãããã¢ãŸé¡æãäžèš
æ§é åŒã§ç€ºãããååç©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé èšèŒã®é»ååçæå äœã ïŒåŒäžïŒ²ãCpã¯ç¬¬ïŒé ãšå矩ã§ãããïŒ ïŒ åèšäžè¬åŒïŒïŒã§ç€ºãããã¢ãŸé¡æãäžèš
æ§é åŒã§ç€ºãããååç©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé èšèŒã®é»ååçæå äœã ïŒåŒäžïŒžãCpã¯ç¬¬ïŒé ãšå矩ã§ãããïŒ
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59212827A JPS6190164A (ja) | 1984-10-09 | 1984-10-09 | é»ååçæå äœ |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59212827A JPS6190164A (ja) | 1984-10-09 | 1984-10-09 | é»ååçæå äœ |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6190164A JPS6190164A (ja) | 1986-05-08 |
JPH0462578B2 true JPH0462578B2 (ja) | 1992-10-06 |
Family
ID=16629014
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59212827A Granted JPS6190164A (ja) | 1984-10-09 | 1984-10-09 | é»ååçæå äœ |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6190164A (ja) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2003289211A1 (en) * | 2002-12-06 | 2004-06-30 | Mitsubishi Chemical Corporation | Electrophotographic photoreceptor |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5830758A (ja) * | 1981-08-18 | 1983-02-23 | Canon Inc | é»ååçæå äœ |
-
1984
- 1984-10-09 JP JP59212827A patent/JPS6190164A/ja active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5830758A (ja) * | 1981-08-18 | 1983-02-23 | Canon Inc | é»ååçæå äœ |
Also Published As
Publication number | Publication date |
---|---|
JPS6190164A (ja) | 1986-05-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPH0518422B2 (ja) | ||
JPH0260174B2 (ja) | ||
JPH0435068B2 (ja) | ||
JPH0260173B2 (ja) | ||
JPH0260172B2 (ja) | ||
JPH0462578B2 (ja) | ||
JP2506372B2 (ja) | é»ååçæå äœ | |
JPH0260169B2 (ja) | ||
JP2672610B2 (ja) | é»ååçæå äœ | |
JPH0428303B2 (ja) | ||
JPH0260175B2 (ja) | ||
JPH0579983B2 (ja) | ||
JPH0518421B2 (ja) | ||
JP2543557B2 (ja) | é»ååçæå äœ | |
JPH0259980B2 (ja) | ||
JPH0435067B2 (ja) | ||
JPH0427545B2 (ja) | ||
JPH0260171B2 (ja) | ||
JPS61284769A (ja) | é»ååçæå äœ | |
JPH0473948B2 (ja) | ||
JPS6332557A (ja) | é»ååçæå äœ | |
JPS6266259A (ja) | é»ååçæå äœ | |
JPH0823704B2 (ja) | é»ååçæå äœ | |
JPH0529901B2 (ja) | ||
JPH0823703B2 (ja) | é»ååçæå äœ |