JPH0459859A - Printing roller for plotter - Google Patents
Printing roller for plotterInfo
- Publication number
- JPH0459859A JPH0459859A JP16971690A JP16971690A JPH0459859A JP H0459859 A JPH0459859 A JP H0459859A JP 16971690 A JP16971690 A JP 16971690A JP 16971690 A JP16971690 A JP 16971690A JP H0459859 A JPH0459859 A JP H0459859A
- Authority
- JP
- Japan
- Prior art keywords
- printing roller
- phenolic resin
- weight
- parts
- plotter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000007639 printing Methods 0.000 title claims abstract description 29
- 239000005011 phenolic resin Substances 0.000 claims abstract description 29
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 25
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000011256 inorganic filler Substances 0.000 claims abstract description 6
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 6
- 239000000654 additive Substances 0.000 claims abstract description 5
- 239000012779 reinforcing material Substances 0.000 claims abstract description 5
- 238000000465 moulding Methods 0.000 claims abstract 2
- 239000011342 resin composition Substances 0.000 claims description 6
- 238000004132 cross linking Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 8
- 239000003086 colorant Substances 0.000 abstract description 3
- 239000000314 lubricant Substances 0.000 abstract description 3
- 239000003365 glass fiber Substances 0.000 abstract description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 abstract description 2
- 239000001095 magnesium carbonate Substances 0.000 abstract description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 abstract description 2
- 239000011490 mineral wool Substances 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 description 11
- 229920003986 novolac Polymers 0.000 description 11
- 238000000034 method Methods 0.000 description 9
- GVYLCNUFSHDAAW-UHFFFAOYSA-N mirex Chemical group ClC12C(Cl)(Cl)C3(Cl)C4(Cl)C1(Cl)C1(Cl)C2(Cl)C3(Cl)C4(Cl)C1(Cl)Cl GVYLCNUFSHDAAW-UHFFFAOYSA-N 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 229920003051 synthetic elastomer Polymers 0.000 description 6
- 239000005061 synthetic rubber Substances 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 239000006229 carbon black Substances 0.000 description 4
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229920003987 resole Polymers 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 235000012438 extruded product Nutrition 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000011134 resol-type phenolic resin Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000006230 acetylene black Substances 0.000 description 2
- -1 blast furnace slag Chemical compound 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 2
- 239000004312 hexamethylene tetramine Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000010680 novolac-type phenolic resin Substances 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 241000218645 Cedrus Species 0.000 description 1
- 101100136092 Drosophila melanogaster peng gene Proteins 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 241000277331 Salmonidae Species 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- AUNAPVYQLLNFOI-UHFFFAOYSA-L [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O Chemical compound [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O AUNAPVYQLLNFOI-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000004018 acid anhydride group Chemical group 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229910002113 barium titanate Inorganic materials 0.000 description 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 125000003262 carboxylic acid ester group Chemical group [H]C([H])([*:2])OC(=O)C([H])([H])[*:1] 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910052851 sillimanite Inorganic materials 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、コンピューター情報のグラフ化、図形化に使
用されるプロッタ用印字ローラーで、作図速度の高速化
に伴う作図精度の向上、軽量化を改良したプロッタ用印
字ローラーに関するものである。[Detailed Description of the Invention] [Industrial Field of Application] The present invention is a printing roller for a plotter used for graphing and graphicalizing computer information. This invention relates to a printing roller for plotters that has been improved.
従来より、プロッタ用印字ローラーは鉄、アルミニウム
、ステンレススチール（以降ＳＵＳという）等の金属を
切削加工し使用されてきた。Conventionally, printing rollers for plotters have been used by cutting metals such as iron, aluminum, and stainless steel (hereinafter referred to as SUS).
近年コンビエータ−情報の作図速度の高速化、作図の大
型化に伴い金属の印字ローラーでは作図精度が悪くなる
と共に、駆動モーターの出力増大で騒音問題が発生し作
図精度の向上と軽量化が急務となった。In recent years, as the drawing speed of combiator information has increased and the drawings have become larger, the printing accuracy of metal printing rollers has deteriorated, and noise problems have arisen due to the increased output of the drive motor, so there is an urgent need to improve drawing accuracy and reduce weight. became.
アルミニウムは鉄、ＳＵＳに比較゛し、軽量であり作図
精度も比較的良いが他の金属と同様に高度な切削加工を
必要とし、口径が大きくなる程加工が困難となる欠点が
あった。Compared to iron and SUS, aluminum is lightweight and has relatively good drawing accuracy, but like other metals, it requires advanced cutting, and the larger the diameter, the more difficult it is to process.
本発明は上記の問題点を解決するためになされたもので
あり、作図速度の高速化に伴う作図精度を向上し、騒音
を減少させ、軽量化を可能とし、しかも切削加工を要せ
ず形状精度に優れたプロッタ用印字ローラーを提供する
ことを目的とする。The present invention was made in order to solve the above problems, and it improves the drawing accuracy accompanying the increase in the drawing speed, reduces noise, makes it possible to reduce the weight, and moreover, it is possible to form the shape without the need for cutting. The purpose is to provide a printing roller for plotters with excellent accuracy.
本発明者らは上記目的を達成するため鋭意検討の結果、
特定の硬度を持つフェノール系樹脂組成物よりなる印字
ローラーを用いることにより、作図精度が優れ、騒音が
少なくなることを見出し本発明を完成するに到った。As a result of intensive studies to achieve the above object, the present inventors found that
The present invention was completed based on the discovery that by using a printing roller made of a phenolic resin composition having a specific hardness, printing accuracy is excellent and noise is reduced.
即ち本発明は、フェノール系樹脂に繊維状補強材、無゛
機質充填材並びに必要に応して各種の添加剤を所望量配
合した樹脂組成物を用いて成形してなるローラーにおい
て、該樹脂組成物を架橋させてローラー表面のバーコル
硬度が６０〜８０であることを特徴とするプロッタ用印
字ローラーである。That is, the present invention provides a roller molded using a resin composition containing a phenolic resin, a fibrous reinforcing material, an inorganic filler, and various additives as required in desired amounts. This is a printing roller for a plotter, characterized in that the composition is crosslinked and the roller surface has a Barcol hardness of 60 to 80.
以下、本発明を更に詳細に説明する。The present invention will be explained in more detail below.
本発明に於いて使用するフェノール系樹脂は、ノボラッ
ク系フェノール樹脂とレゾール系フェノール樹脂が挙げ
られる。The phenolic resins used in the present invention include novolac phenolic resins and resol phenolic resins.
ノボラック系フェノール樹脂としては、フェノールノボ
ラック樹脂、タレゾールノボラック樹脂、ｔｅｒｔ−ブ
チルフェノールノボラック樹脂、ノニルフェノールノボ
ラック樹脂、フェノールアルキル樹脂、ジシクロペンタ
ジェンフェノールノボランク樹脂等が挙げられる。Examples of the novolak-based phenolic resin include phenol novolac resin, talesol novolak resin, tert-butylphenol novolak resin, nonylphenol novolak resin, phenol alkyl resin, dicyclopentadienephenol novolak resin, and the like.
具体例としてはミレックス１１０００（三井東圧化学■
製）、ミレックス雲１０００Ｈ３（三井東圧化学■製）
、ミレックス１２０００（三井東圧化学■製製）、ミレ
ックス１５００ＨＸ（三井東圧化学■製）、ミレックス
ＲＮ２４１０（三井東圧化学■製）、ミレンクス１２Ｎ
９４１θ（三井東圧化学鱒製）、ミレックス１１７００
０（三井東圧化学■製）、ミレックス１９０００（三井
東圧化学■製）などがある。A specific example is Mirex 11000 (Mitsui Toatsu Chemical)
(manufactured by Mitsui Toatsu Chemical), Mirex Cloud 1000H3 (manufactured by Mitsui Toatsu Chemical)
, Mirex 12000 (manufactured by Mitsui Toatsu Chemicals), Mirex 1500HX (manufactured by Mitsui Toatsu Chemicals), Mirex RN2410 (manufactured by Mitsui Toatsu Chemicals), Mirex 12N
941θ (manufactured by Mitsui Toatsu Chemical Trout), Mirex 11700
0 (manufactured by Mitsui Toatsu Chemical Co., Ltd.) and Mirex 19000 (manufactured by Mitsui Toatsu Chemical Co., Ltd.).
尚、ノボラック系フェノール樹脂を使用する場合には、
架橋剤を添加する必要がある。In addition, when using novolak phenolic resin,
It is necessary to add a crosslinking agent.
架橋剤としては、−ｉにヘキサメチレンテトラミンが用
いられる。As a crosslinking agent, hexamethylenetetramine is used for -i.
レゾール系フェノール樹脂としては、固形レゾール、液
状レゾールの各れも使用されるが、固形レゾールが望ま
しい。又レゾール系フェノール樹脂単独では硬化速度が
遅くなるため、ノボラック系フェノール樹脂との併用が
望ましい。As the resol type phenolic resin, both solid resol and liquid resol can be used, but solid resol is preferable. Furthermore, since the curing speed of resol type phenolic resin alone is slow, it is desirable to use it in combination with novolak type phenolic resin.
具体例としては、群栄化学工業■製、昭和高分子■製な
どがある。Specific examples include those manufactured by Gunei Kagaku Kogyo ■ and Showa Kobunshi ■.
本発明に於いてバーコル硬度を６０〜８０に１！節する
方法としては、例えばカーボンブラック、アクリロニト
リル−ブタジェン系共重合体等を添加して調節すること
もできる。In the present invention, the Barcol hardness is 1 in 60 to 80! For example, carbon black, an acrylonitrile-butadiene copolymer, or the like can be added to control the stiffness.
アクリロニトリル−ブタジェン系共重合体としては、ア
クリロニトリル−ブタジェン共重合体及び該共重合体に
カルボキシル基、ヒドロキシル基、カルボン酸エステル
基、酸無水物本、ビニル基ノ群から選ばられる少なくと
も１種類を含有する変性アクリロニトリル−ブタジェン
共重合体である。The acrylonitrile-butadiene copolymer includes an acrylonitrile-butadiene copolymer and at least one type selected from the group consisting of a carboxyl group, a hydroxyl group, a carboxylic acid ester group, an acid anhydride group, and a vinyl group. It is a modified acrylonitrile-butadiene copolymer.
具体例としては、ＪＳＲ−Ｎ２２０Ｓ（日本合成ゴム■
製）、ＪＳＲ−Ｎ２２１Ｈ（日本合成ゴム■製）、ＪＳ
Ｒ・Ｎ２３０Ｓ（日本合成ゴム■製）、ＪＳＲ・２３３
（日本合成ゴム■製）、ＪＳＲ−Ｎ２０４Ｓ（日本合成
ゴム■製）等が挙げられる。A specific example is JSR-N220S (Japanese Synthetic Rubber ■
(manufactured by Japan Synthetic Rubber), JSR-N221H (manufactured by Japan Synthetic Rubber), JS
R・N230S (manufactured by Japan Synthetic Rubber), JSR・233
(manufactured by Japan Synthetic Rubber ■), JSR-N204S (manufactured by Japan Synthetic Rubber ■), and the like.
アクリロニトリル−ブタジェン系共重合体の添加量はフ
ェノール系樹脂１００重量部に対して、アクリロニトリ
ル−ブタジェン系共重合体１０重量部以下が好ましく、
さらに、好ましくは５重量部以下である。 １０重量部
を餡えると所望の硬度が得られ難く、また印字ローラー
の形状精度が悪くなる。The amount of the acrylonitrile-butadiene copolymer added is preferably 10 parts by weight or less per 100 parts by weight of the phenol resin.
Furthermore, it is preferably 5 parts by weight or less. If 10 parts by weight is added, it will be difficult to obtain the desired hardness and the shape accuracy of the printing roller will deteriorate.
カーボンブラックとしては、アセチレンブラック、スピ
リットブラック、ケッチエンブランク等が挙げられる。Examples of carbon black include acetylene black, spirit black, and Ketchen blank.
カーボンブラックの添加量はフェノール系樹脂１００重
量部に対して、２０重量部以下が好ましい、２０重量部
を超えると成形性が悪くなる。The amount of carbon black added is preferably 20 parts by weight or less per 100 parts by weight of the phenolic resin; if it exceeds 20 parts by weight, moldability will deteriorate.
ヘキサメチレンテトラミンはノボラック系フェノール樹
脂の場合に必要であり、８〜３０重量部が好ましく、ざ
らに好ましくは１０〜２５重量部である。Hexamethylenetetramine is necessary in the case of a novolak phenolic resin, and is preferably 8 to 30 parts by weight, more preferably 10 to 25 parts by weight.
８重量部未満ではノボラック系フェノール樹脂の架橋が
十分でなく、３０重量部を超えると印字ローラーとした
ときに膨れ、巣が発生し易い。If it is less than 8 parts by weight, the crosslinking of the novolak phenol resin will not be sufficient, and if it exceeds 30 parts by weight, it will swell and tend to form cavities when used as a printing roller.
本発明に於いて使用する繊維状補強材としては、ガラス
繊維、ロックウール、ジルコニア、アルミナシリカ、チ
タン酸カリウム、チタン酸バリウム、アルミナ、シリカ
、高炉スラグ等の無機繊維、ウオラストナイト、等の鉱
石繊維、炭化けい素、ボロンナイトライド、窒化けい素
、三重化けい素、塩基性硫酸マグネシウム、ボロン等の
ウィスカーアラミド繊維、フェノール樹脂の炭素繊維等
の合成繊維、木粉（セル杉、松、ラワン等）が挙げられ
る。繊維状補強材はの添加量はフェノール系樹脂１００
重量部に対して５０〜２００重量部が好ましく、さらに
好ましくは１００〜１５０重量部である。５０重量部未
満では印字ローラーの強度が十分でなく、２００重量部
を超えると印字ロール−の表面性が悪くなる傾向にある
。The fibrous reinforcing materials used in the present invention include glass fiber, rock wool, zirconia, alumina-silica, potassium titanate, barium titanate, alumina, silica, inorganic fibers such as blast furnace slag, and wollastonite. Mineral fibers, silicon carbide, boron nitride, silicon nitride, silicon tritide, basic magnesium sulfate, whisker aramid fibers such as boron, synthetic fibers such as phenolic resin carbon fibers, wood flour (cellulose cedar, pine, Rawan et al.). The amount of fibrous reinforcement added is phenolic resin 100%
It is preferably 50 to 200 parts by weight, more preferably 100 to 150 parts by weight. If it is less than 50 parts by weight, the strength of the printing roller will not be sufficient, and if it exceeds 200 parts by weight, the surface properties of the printing roll will tend to deteriorate.
本発明に於いて使用する無機質充填材としては、炭酸マ
グネシウム、炭酸バリウム、炭酸カルシウム等の炭酸塩
、沈降性硫酸カルシウム、焼き石膏等の硫酸塩、マグネ
シア、酸化チタン、亜鉛華、ホワイトカーボン、無定形
シリカ、水酸化アルミニウム、酸化アンチモン、珪藻土
、酸性白土、焼成りレー、ガラス粉、ガラスピーズ、セ
リサイト、ベントナイト、シリマナイト、けい酸カルシ
ウム、マイカ、バーミキュライト、タルク、カオリン等
が挙げられる。無機質充填材の添加量はフェノール系樹
脂１００重量部に対して１０〜２００重量部が好ましく
、さらに好ましくは２０〜１５０重量部である。Inorganic fillers used in the present invention include carbonates such as magnesium carbonate, barium carbonate, and calcium carbonate, precipitated calcium sulfate, sulfates such as calcined gypsum, magnesia, titanium oxide, zinc white, white carbon, and mineral fillers. Examples include regular silica, aluminum hydroxide, antimony oxide, diatomaceous earth, acid clay, fired clay, glass powder, glass peas, sericite, bentonite, sillimanite, calcium silicate, mica, vermiculite, talc, and kaolin. The amount of the inorganic filler added is preferably 10 to 200 parts by weight, more preferably 20 to 150 parts by weight, per 100 parts by weight of the phenolic resin.
１０重量部未満では印字ローラーの表面性が悪く、２０
０重量部をこえると印字ローラーの強度が低下する。If it is less than 10 parts by weight, the surface properties of the printing roller will be poor;
If it exceeds 0 parts by weight, the strength of the printing roller will decrease.
本発明に於いて使用する着色剤としては、アセチレンブ
ラック、スピリットブラック、ケッチエンブラック等の
カーボンブラック、カドミウム赤、モリブデン赤、バリ
ウム黄、クロム黄、チタン黄、コバルト緑、酸化クロム
緑、亜鉛縁、群青、紺青、コバルト紫、マルス紫などが
挙げられる。着色剤は印字ローラーを所望の色に着色す
るための添加量でよく、限定できないが、通常フェノー
ル系樹脂１００重量部に対して０．５〜ｌＯ重量部程度
が好ましい。Coloring agents used in the present invention include carbon black such as acetylene black, spirit black, and Ketschien black, cadmium red, molybdenum red, barium yellow, chrome yellow, titanium yellow, cobalt green, chromium oxide green, and zinc rim. , ultramarine blue, navy blue, cobalt purple, and Mars purple. The coloring agent may be added in an amount sufficient to color the printing roller in a desired color, and is not particularly limited, but it is usually preferably about 0.5 to 10 parts by weight per 100 parts by weight of the phenolic resin.
本発明に於いて使用する滑剤としては、ステアリン酸、
ステアリン酸ナトリウム、ステアリン酸亜鉛、ステアリ
ン酸マグネシウム、ステアリン酸カルシウム等のステア
リン酸の金属塩類、カルナバワックス、天然ワックス、
アマイド類等が挙げられる。滑剤の添加量はフェノール
系樹脂１００重量部に対して１〜７重量部が好ましく、
さらに好ましくは２〜４重量部である。１重量部未満で
は樹脂組成物のロール混線時にロールへの付着が大とな
りハクリが困難となるので好ましくない。７重量部を超
えると印字ローラーの機械強度が低下するので好ましく
ない。The lubricants used in the present invention include stearic acid,
Metal salts of stearic acid such as sodium stearate, zinc stearate, magnesium stearate, calcium stearate, carnauba wax, natural wax,
Amides and the like can be mentioned. The amount of the lubricant added is preferably 1 to 7 parts by weight per 100 parts by weight of the phenolic resin.
More preferably, it is 2 to 4 parts by weight. If it is less than 1 part by weight, it is not preferable because the resin composition adheres to the rolls when the rolls are crossed, making it difficult to peel off. If it exceeds 7 parts by weight, the mechanical strength of the printing roller will decrease, which is not preferable.
なお、アクリロニトリル−ブタジェン系共重合体をフェ
ノール系樹脂に添加する有効な方法はフェノール系樹脂
中に、アクリロニトリル−ブタジェン系共重合体を均一
に分散させることが望ましい。Note that an effective method for adding the acrylonitrile-butadiene copolymer to the phenol resin is to uniformly disperse the acrylonitrile-butadiene copolymer in the phenol resin.
その方法としては、粉末状又は液状アクリロニトリル−
ブタジェン系共重合体のうち少なくともいずれか１種を
■フェノール系樹脂を軟化点以上に加熱し、これに混合
する方法、■フェノール系樹脂の合成工程で反応釜に投
入する方法、■溶剤に溶かしたフェノール系樹脂溶液に
添加した後、溶剤を除去する方法などによりフェノール
系樹脂中に均一に分散させる。The method is to use powdered or liquid acrylonitrile.
At least one of the butadiene-based copolymers is heated to a temperature above the softening point of the phenolic resin and mixed with it, ■ is added to a reaction vessel during the phenolic resin synthesis process, or is dissolved in a solvent. After adding it to the phenolic resin solution, it is uniformly dispersed in the phenolic resin by a method such as removing the solvent.
いずれの方法を用いても良いが生産性の観点から■の方
法が望ましい。Although any method may be used, method (2) is preferable from the viewpoint of productivity.
具体的には、フェノール系樹脂は軟化点以上に加熱すれ
ば良い、但しアクリロニトリル−ブタジェン系共重合体
をより均一に分散させるためには、フェノール系樹脂を
１３０〜１７０°Ｃに加熱溶融させておき、アクリロニ
トリル−ブタジェン系共重合体を加え、２０〜３０分間
撹拌混合することが望ましい。Specifically, the phenolic resin may be heated above its softening point; however, in order to more uniformly disperse the acrylonitrile-butadiene copolymer, the phenolic resin should be heated and melted at 130 to 170°C. It is desirable to add the acrylonitrile-butadiene copolymer and stir and mix for 20 to 30 minutes.
粉末状のアクリロニトリル−ブタジェン系共重合体は粉
砕したフェノール系樹脂とヘンシェルミキサー、リボン
ブレンダー、万能混合機等で充分に混合し、使用するこ
とも勿論可能である。It is of course possible to use the powdered acrylonitrile-butadiene copolymer by thoroughly mixing it with the pulverized phenolic resin using a Henschel mixer, ribbon blender, all-purpose mixer, or the like.
本発明のプロッタ用印字ローラーは上述の配合剤を常法
により混合後ロール混練、粉砕したあと、特開昭６０−
１４９６５３号公報に準じて、押出成形機を用いてプロ
ッタ用ロールが得られる。The printing roller for a plotter of the present invention is prepared by mixing the above-mentioned ingredients in a conventional manner, then kneading and pulverizing them with a roll.
According to Japanese Patent No. 149653, a roll for a plotter is obtained using an extrusion molding machine.
バーコル硬度は６０〜８０の範囲が好ましい。６０未満
では印字ロールの形状精度が悪くなり好ましくない、ま
た８０を超えると作図精度が悪くなると共に騒音が大き
くなる。The Barcol hardness is preferably in the range of 60 to 80. If it is less than 60, the shape accuracy of the printing roll will deteriorate, which is undesirable, and if it exceeds 80, the drawing accuracy will deteriorate and noise will increase.
以下、本発明を実施例により具体的に説明する。 Hereinafter, the present invention will be specifically explained with reference to Examples.
実施例１〜３及び比較例１
ノボラック型フェノール系樹脂、充填材及びその他の添
加材を第１表に示す配合割合（重量部）で配合し、ブレ
ンダーを使用して混合した。Examples 1 to 3 and Comparative Example 1 Novolac type phenolic resin, filler, and other additives were blended in the proportions (parts by weight) shown in Table 1, and mixed using a blender.
得られた混合物を前ロール８０〜９０°Ｃ１後ロール４
０〜５０℃の温度条件で１０分間混練した。この混練物
をパワーミル（スクリーン２．５ｍｍ）で粉砕、整粒し
て樹脂組成物の造粒品を得た。The obtained mixture was passed through the front roll at 80 to 90°C and the back roll at 4
The mixture was kneaded for 10 minutes at a temperature of 0 to 50°C. This kneaded material was pulverized and sized using a power mill (screen 2.5 mm) to obtain a granulated product of the resin composition.
次いで得られた樹脂組成物を口径６０ｍ、 Ｌ ／ Ｄ
＝２２の押出機により、スクリュー底部の径が５２ｍ、
計量部に続く先端部に径５２ｍ、長さ９０ｍ（３Ｄ）の
平滑部を有する圧縮比２．０のスクリューを用い、径６
０鵬、肉厚４閣の押出パイプを成形し、長さ１０００■
に切断して印字ローラーを得た。Next, the obtained resin composition was heated to a diameter of 60 m, L/D
= 22 extruder, the screw bottom diameter is 52 m,
Using a screw with a compression ratio of 2.0 and a smooth part with a diameter of 52 m and a length of 90 m (3D) at the tip following the measuring part,
0 Peng, extruded pipe with 4 wall thickness, length 1000cm
A printing roller was obtained by cutting into pieces.
押出の条件はホッパー下より２Ｄは室温、続いて３〜Ｉ
ＯＤは６０℃、１１〜１４０は８０℃、■５〜１８Ｄは
１００℃、１９〜２２Ｄは１４０℃に設定し、スクリュ
ー回転数は３５ｒ、ｐ、ｍ、の条件で押出を行なった。The extrusion conditions are room temperature for 2D from the bottom of the hopper, then 3 to I.
Extrusion was performed under the following conditions: OD was set at 60°C, 80°C for 11-140, 100°C for 5-18D, and 140°C for 19-22D, and the screw rotation speed was 35 r, p, m.
得られた印字ローラーにつき下記物性を測定した、結果
を第２表に示す。The following physical properties were measured for the obtained printing roller, and the results are shown in Table 2.
実施例４〜５
ノボラック型フェノール樹脂、レゾール型フェノール樹
脂、充填材及びその他の添加剤を第１表に示す配合割合
（重量部）で配合しプレンダーを使用して混合した。Examples 4 to 5 A novolac type phenolic resin, a resol type phenolic resin, a filler, and other additives were blended at the proportions (parts by weight) shown in Table 1 and mixed using a blender.
得られた混合物を前ロール１２０〜１３０°Ｃ１後ロー
ル９０〜１００°Ｃの温度条件で１０分間混練した。こ
の混合物をパワーミル（スクリーン２．５ｍ）で粉砕し
た。The resulting mixture was kneaded for 10 minutes at a temperature of 120 to 130°C with the front roll and 90 to 100°C with the back roll. This mixture was ground in a power mill (screen 2.5 m).
以下、実施例１と同様に処理し、印字ローラーを得た。Thereafter, the same process as in Example 1 was carried out to obtain a printing roller.
参考例
従来の鉄及びアルミニウム製印字ローラーの物性を測定
した。結果を第２表に示す。Reference Example The physical properties of conventional printing rollers made of iron and aluminum were measured. The results are shown in Table 2.
押出成形品の物性測定は下記の方法による。The physical properties of the extrusion molded product were measured by the following method.
〈バーコル硬度〉
バーコル硬度計（米国コルマン社製ＧＹＺＪ９３４−１
型）を使用してＪＩＳ Ｋ−６９１１に準拠してパイプ
表面の硬度を測定した。<Barcol hardness> Barcol hardness tester (GYZJ934-1 manufactured by Colman, USA)
The hardness of the pipe surface was measured using a mold) in accordance with JIS K-6911.
〈騒音〉
実機のプロッタにブロック用印字ローラーと紙を装着し
、印字ヘッドで発注する音をプロッタから−ｍの位置に
於いてマイクロホンで捕らえ、騒音計に接続して最高値
を測定した。<Noise> A block printing roller and paper were attached to an actual plotter, and the sound produced by the print head was captured by a microphone at a position -m from the plotter, and the highest value was measured by connecting it to a sound level meter.
〈振れ〉
押出成形品を２３±２℃、相対湿度５０±５％で８時間
以上放置した後、レーザースキャンマイクロメーター（
ミツトヨ製ＬＳＭ−１６１０Ｍ））で押出成形品の中央
部を測定した。<Runout> After leaving the extruded product at 23 ± 2°C and relative humidity 50 ± 5% for more than 8 hours, test it with a laser scanning micrometer (
The central part of the extrusion molded product was measured using Mitutoyo LSM-1610M).
〈表面粗度〉
押出成形品を２３±２℃、相対湿度５０±５％で８時間
以上放置した後、サーフコム（東京精密■製）で測定し
た。<Surface Roughness> After the extruded product was left at 23±2° C. and relative humidity of 50±5% for 8 hours or more, it was measured using Surfcom (manufactured by Tokyo Seimitsu ■).
く真円度〉
押出成形品を２３±２℃、相対湿度５０±５％で８時間
以上放置した後、マイクロメーターで挟み、その最大径
と最小径との差（１）を求める。また、穴の内側にマイ
クロメーターを挿入し、最大値と最小値の差（２）を求
める。（１）と（２）の大きい方を表示した。Roundness> After leaving the extruded product at 23±2° C. and relative humidity 50±5% for 8 hours or more, it is held between micrometers and the difference (1) between its maximum diameter and minimum diameter is determined. Also, insert a micrometer inside the hole and find the difference (2) between the maximum value and the minimum value. The larger of (1) and (2) is displayed.
本発明のプロッタ用印字ローラーは、ローラー表面を特
定の、バーコル硬度にすることにより、作図精度を向上
し、騒音を減少し、しかもローラーの形状精度、表面粗
度が良好で軽量化されたものであり、産業に貢献するこ
と大である。The printing roller for plotters of the present invention improves plotting accuracy and reduces noise by making the roller surface a specific Barcol hardness, and has good shape accuracy and surface roughness, making it lightweight. Therefore, it is a great contribution to industry.
Claims (1)
びに必要に応じて各種の添加剤を所望量配合した樹脂組
成物を用いて成形してなるローラーにおいて、該樹脂組
成物を架橋させてローラー表面のバーコル硬度が６０〜
８０であることを特徴とするプロッタ用印字ローラー。1. A roller formed by molding a resin composition containing a phenolic resin, a fibrous reinforcing material, an inorganic filler, and various additives as necessary in desired amounts, by crosslinking the resin composition. Surface hardness is 60~
A printing roller for a plotter, characterized in that it has a diameter of 80.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16971690A JPH0459859A (en) | 1990-06-29 | 1990-06-29 | Printing roller for plotter |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16971690A JPH0459859A (en) | 1990-06-29 | 1990-06-29 | Printing roller for plotter |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0459859A true JPH0459859A (en) | 1992-02-26 |
Family
ID=15891543
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16971690A Pending JPH0459859A (en) | 1990-06-29 | 1990-06-29 | Printing roller for plotter |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0459859A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9577235B2 (en) | 2012-12-18 | 2017-02-21 | Sabic Global Technologies B.V. | High temperature melt integrity battery separators via spinning |
-
1990
- 1990-06-29 JP JP16971690A patent/JPH0459859A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9577235B2 (en) | 2012-12-18 | 2017-02-21 | Sabic Global Technologies B.V. | High temperature melt integrity battery separators via spinning |
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