JPH0455497B2 - - Google Patents
Info
- Publication number
- JPH0455497B2 JPH0455497B2 JP13974685A JP13974685A JPH0455497B2 JP H0455497 B2 JPH0455497 B2 JP H0455497B2 JP 13974685 A JP13974685 A JP 13974685A JP 13974685 A JP13974685 A JP 13974685A JP H0455497 B2 JPH0455497 B2 JP H0455497B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- image
- acid
- same meaning
- silver
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 silver halide Chemical class 0.000 claims description 151
- 239000000839 emulsion Substances 0.000 claims description 98
- 229910052709 silver Inorganic materials 0.000 claims description 84
- 239000004332 silver Substances 0.000 claims description 84
- 239000000463 material Substances 0.000 claims description 83
- 150000001875 compounds Chemical class 0.000 claims description 82
- 239000000126 substance Substances 0.000 claims description 64
- 239000003094 microcapsule Substances 0.000 claims description 37
- 239000003638 chemical reducing agent Substances 0.000 claims description 20
- 230000001235 sensitizing effect Effects 0.000 claims description 17
- 239000000975 dye Substances 0.000 description 75
- 238000000034 method Methods 0.000 description 61
- 239000002253 acid Substances 0.000 description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 34
- 108010010803 Gelatin Proteins 0.000 description 31
- 239000008273 gelatin Substances 0.000 description 31
- 229920000159 gelatin Polymers 0.000 description 31
- 235000019322 gelatine Nutrition 0.000 description 31
- 235000011852 gelatine desserts Nutrition 0.000 description 31
- 239000000243 solution Substances 0.000 description 30
- 229920000642 polymer Polymers 0.000 description 28
- 239000002585 base Substances 0.000 description 27
- 238000010438 heat treatment Methods 0.000 description 26
- 238000005755 formation reaction Methods 0.000 description 25
- 239000010410 layer Substances 0.000 description 25
- 239000002245 particle Substances 0.000 description 25
- 230000035945 sensitivity Effects 0.000 description 23
- 230000015572 biosynthetic process Effects 0.000 description 22
- 238000002360 preparation method Methods 0.000 description 21
- 125000000217 alkyl group Chemical group 0.000 description 20
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 20
- 235000013339 cereals Nutrition 0.000 description 19
- 238000006243 chemical reaction Methods 0.000 description 18
- 150000003839 salts Chemical class 0.000 description 18
- 206010070834 Sensitisation Diseases 0.000 description 17
- 125000004432 carbon atom Chemical group C* 0.000 description 17
- 230000008313 sensitization Effects 0.000 description 17
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 17
- 239000002775 capsule Substances 0.000 description 16
- 239000000203 mixture Substances 0.000 description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 239000007864 aqueous solution Substances 0.000 description 14
- 239000000049 pigment Substances 0.000 description 14
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 14
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 13
- 239000002904 solvent Substances 0.000 description 13
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 12
- 229920002554 vinyl polymer Polymers 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 11
- 238000011161 development Methods 0.000 description 11
- 229910052736 halogen Inorganic materials 0.000 description 11
- 239000000178 monomer Substances 0.000 description 11
- 150000003378 silver Chemical class 0.000 description 11
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 10
- 125000003118 aryl group Chemical group 0.000 description 10
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- 125000005843 halogen group Chemical group 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 10
- 239000003921 oil Substances 0.000 description 10
- 235000019198 oils Nutrition 0.000 description 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 10
- 230000008569 process Effects 0.000 description 10
- 238000012545 processing Methods 0.000 description 10
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 10
- 150000001412 amines Chemical class 0.000 description 9
- 150000002367 halogens Chemical class 0.000 description 9
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 9
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 8
- 239000012948 isocyanate Substances 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- 150000003732 xanthenes Chemical class 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- 125000003545 alkoxy group Chemical group 0.000 description 7
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 7
- 229920002678 cellulose Polymers 0.000 description 7
- 239000003086 colorant Substances 0.000 description 7
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 7
- 125000000623 heterocyclic group Chemical group 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- 229910001961 silver nitrate Inorganic materials 0.000 description 7
- 125000000547 substituted alkyl group Chemical group 0.000 description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 239000001913 cellulose Substances 0.000 description 6
- 230000006870 function Effects 0.000 description 6
- 150000002513 isocyanates Chemical class 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000007800 oxidant agent Substances 0.000 description 6
- 239000002243 precursor Substances 0.000 description 6
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 6
- 125000001424 substituent group Chemical group 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 5
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 125000004093 cyano group Chemical group *C#N 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 238000011033 desalting Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 5
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 5
- 229920005862 polyol Polymers 0.000 description 5
- 238000006479 redox reaction Methods 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 238000006722 reduction reaction Methods 0.000 description 5
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 5
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 5
- 235000019345 sodium thiosulphate Nutrition 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- ODIRBFFBCSTPTO-UHFFFAOYSA-N 1,3-selenazole Chemical class C1=C[se]C=N1 ODIRBFFBCSTPTO-UHFFFAOYSA-N 0.000 description 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 4
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 230000006378 damage Effects 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 238000005868 electrolysis reaction Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 229910052731 fluorine Inorganic materials 0.000 description 4
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 4
- 238000003384 imaging method Methods 0.000 description 4
- 150000002460 imidazoles Chemical class 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 150000007524 organic acids Chemical class 0.000 description 4
- 125000004430 oxygen atom Chemical group O* 0.000 description 4
- LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 description 4
- 150000003077 polyols Chemical class 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 230000001737 promoting effect Effects 0.000 description 4
- 239000011241 protective layer Substances 0.000 description 4
- 150000003222 pyridines Chemical class 0.000 description 4
- 230000005070 ripening Effects 0.000 description 4
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 230000003595 spectral effect Effects 0.000 description 4
- 210000002784 stomach Anatomy 0.000 description 4
- 239000011593 sulfur Chemical group 0.000 description 4
- 125000004434 sulfur atom Chemical group 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 4
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical class C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 3
- FLFWJIBUZQARMD-UHFFFAOYSA-N 2-mercapto-1,3-benzoxazole Chemical compound C1=CC=C2OC(S)=NC2=C1 FLFWJIBUZQARMD-UHFFFAOYSA-N 0.000 description 3
- UGWULZWUXSCWPX-UHFFFAOYSA-N 2-sulfanylideneimidazolidin-4-one Chemical class O=C1CNC(=S)N1 UGWULZWUXSCWPX-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 125000002252 acyl group Chemical group 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 125000005115 alkyl carbamoyl group Chemical group 0.000 description 3
- KXNQKOAQSGJCQU-UHFFFAOYSA-N benzo[e][1,3]benzothiazole Chemical class C1=CC=C2C(N=CS3)=C3C=CC2=C1 KXNQKOAQSGJCQU-UHFFFAOYSA-N 0.000 description 3
- WMUIZUWOEIQJEH-UHFFFAOYSA-N benzo[e][1,3]benzoxazole Chemical class C1=CC=C2C(N=CO3)=C3C=CC2=C1 WMUIZUWOEIQJEH-UHFFFAOYSA-N 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical group 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 125000004386 diacrylate group Chemical group 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- 125000005442 diisocyanate group Chemical group 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical group C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 3
- 150000002357 guanidines Chemical class 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine group Chemical group N1=CCC2=CC=CC=C12 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 150000004780 naphthols Chemical class 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- 150000007530 organic bases Chemical class 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 3
- 229920000768 polyamine Polymers 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 150000003248 quinolines Chemical class 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 3
- KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical class O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 3
- 229960004889 salicylic acid Drugs 0.000 description 3
- 125000003748 selenium group Chemical group *[Se]* 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 3
- 150000003557 thiazoles Chemical class 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 229920003169 water-soluble polymer Polymers 0.000 description 3
- 125000006569 (C5-C6) heterocyclic group Chemical group 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- LBUJPTNKIBCYBY-UHFFFAOYSA-N 1,2,3,4-tetrahydroquinoline Chemical compound C1=CC=C2CCCNC2=C1 LBUJPTNKIBCYBY-UHFFFAOYSA-N 0.000 description 2
- AIGNCQCMONAWOL-UHFFFAOYSA-N 1,3-benzoselenazole Chemical class C1=CC=C2[se]C=NC2=C1 AIGNCQCMONAWOL-UHFFFAOYSA-N 0.000 description 2
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- ALQSHHUCVQOPAS-UHFFFAOYSA-N 1,5-Pentadiol Natural products OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 2
- XLPJNCYCZORXHG-UHFFFAOYSA-N 1-morpholin-4-ylprop-2-en-1-one Chemical compound C=CC(=O)N1CCOCC1 XLPJNCYCZORXHG-UHFFFAOYSA-N 0.000 description 2
- KJUGUADJHNHALS-UHFFFAOYSA-N 1H-tetrazole Chemical compound C=1N=NNN=1 KJUGUADJHNHALS-UHFFFAOYSA-N 0.000 description 2
- PTLWKRLAWHBMLM-UHFFFAOYSA-N 2,3-dihydroazete Chemical compound C1CN=C1 PTLWKRLAWHBMLM-UHFFFAOYSA-N 0.000 description 2
- ATCRIUVQKHMXSH-UHFFFAOYSA-N 2,4-dichlorobenzoic acid Chemical compound OC(=O)C1=CC=C(Cl)C=C1Cl ATCRIUVQKHMXSH-UHFFFAOYSA-N 0.000 description 2
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 2
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 2
- AYPSHJCKSDNETA-UHFFFAOYSA-N 2-chloro-1h-benzimidazole Chemical compound C1=CC=C2NC(Cl)=NC2=C1 AYPSHJCKSDNETA-UHFFFAOYSA-N 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- UYEMGAFJOZZIFP-UHFFFAOYSA-N 3,5-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC(O)=CC(O)=C1 UYEMGAFJOZZIFP-UHFFFAOYSA-N 0.000 description 2
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 2
- VVBLNCFGVYUYGU-UHFFFAOYSA-N 4,4'-Bis(dimethylamino)benzophenone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 VVBLNCFGVYUYGU-UHFFFAOYSA-N 0.000 description 2
- BOTGCZBEERTTDQ-UHFFFAOYSA-N 4-Methoxy-1-naphthol Chemical compound C1=CC=C2C(OC)=CC=C(O)C2=C1 BOTGCZBEERTTDQ-UHFFFAOYSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical class NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- HXDOZKJGKXYMEW-UHFFFAOYSA-N 4-ethylphenol Chemical compound CCC1=CC=C(O)C=C1 HXDOZKJGKXYMEW-UHFFFAOYSA-N 0.000 description 2
- UTMDJGPRCLQPBT-UHFFFAOYSA-N 4-nitro-1h-1,2,3-benzotriazole Chemical compound [O-][N+](=O)C1=CC=CC2=NNN=C12 UTMDJGPRCLQPBT-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
- 244000215068 Acacia senegal Species 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 229920000084 Gum arabic Polymers 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 241001024304 Mino Species 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- ZLHNYIHIHQEHJQ-UHFFFAOYSA-N N,N'-Diacetylhydrazine Chemical compound CC(=O)NNC(C)=O ZLHNYIHIHQEHJQ-UHFFFAOYSA-N 0.000 description 2
- ATHHXGZTWNVVOU-UHFFFAOYSA-N N-methylformamide Chemical compound CNC=O ATHHXGZTWNVVOU-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- 244000061456 Solanum tuberosum Species 0.000 description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000000205 acacia gum Substances 0.000 description 2
- 235000010489 acacia gum Nutrition 0.000 description 2
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000000783 alginic acid Substances 0.000 description 2
- 235000010443 alginic acid Nutrition 0.000 description 2
- 229920000615 alginic acid Polymers 0.000 description 2
- 229960001126 alginic acid Drugs 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 125000005153 alkyl sulfamoyl group Chemical group 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 229920006318 anionic polymer Polymers 0.000 description 2
- 150000004982 aromatic amines Chemical class 0.000 description 2
- 150000001555 benzenes Chemical group 0.000 description 2
- AMTXUWGBSGZXCJ-UHFFFAOYSA-N benzo[e][1,3]benzoselenazole Chemical class C1=CC=C2C(N=C[se]3)=C3C=CC2=C1 AMTXUWGBSGZXCJ-UHFFFAOYSA-N 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 150000001565 benzotriazoles Chemical class 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical compound C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 239000011162 core material Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000005538 encapsulation Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002085 enols Chemical class 0.000 description 2
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 229940074391 gallic acid Drugs 0.000 description 2
- 235000004515 gallic acid Nutrition 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 150000002429 hydrazines Chemical class 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 150000002462 imidazolines Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000002667 nucleating agent Substances 0.000 description 2
- 230000006911 nucleation Effects 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 235000021313 oleic acid Nutrition 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 150000002916 oxazoles Chemical class 0.000 description 2
- 150000002918 oxazolines Chemical class 0.000 description 2
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 2
- 229960001553 phloroglucinol Drugs 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M potassium chloride Inorganic materials [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- 150000003233 pyrroles Chemical class 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229960001755 resorcinol Drugs 0.000 description 2
- 229910001923 silver oxide Inorganic materials 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 125000001302 tertiary amino group Chemical group 0.000 description 2
- 150000003536 tetrazoles Chemical class 0.000 description 2
- 238000012719 thermal polymerization Methods 0.000 description 2
- 150000004897 thiazines Chemical class 0.000 description 2
- 150000003549 thiazolines Chemical class 0.000 description 2
- 125000002813 thiocarbonyl group Chemical group *C(*)=S 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
- 150000003852 triazoles Chemical class 0.000 description 2
- 125000003866 trichloromethyl group Chemical group ClC(Cl)(Cl)* 0.000 description 2
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- SCZGZDLUGUYLRV-UHFFFAOYSA-N (2-methylphenyl)hydrazine Chemical compound CC1=CC=CC=C1NN SCZGZDLUGUYLRV-UHFFFAOYSA-N 0.000 description 1
- LIZLYZVAYZQVPG-UHFFFAOYSA-N (3-bromo-2-fluorophenyl)methanol Chemical compound OCC1=CC=CC(Br)=C1F LIZLYZVAYZQVPG-UHFFFAOYSA-N 0.000 description 1
- XAMBIJWZVIZZOG-UHFFFAOYSA-N (4-methylphenyl)hydrazine Chemical compound CC1=CC=C(NN)C=C1 XAMBIJWZVIZZOG-UHFFFAOYSA-N 0.000 description 1
- POTIYWUALSJREP-UHFFFAOYSA-N 1,2,3,4,4a,5,6,7,8,8a-decahydroquinoline Chemical compound N1CCCC2CCCCC21 POTIYWUALSJREP-UHFFFAOYSA-N 0.000 description 1
- FTWMCSGJSZWKCR-UHFFFAOYSA-N 1,2,3-tricyclohexylguanidine Chemical compound C1CCCCC1NC(NC1CCCCC1)=NC1CCCCC1 FTWMCSGJSZWKCR-UHFFFAOYSA-N 0.000 description 1
- ZWVMLYRJXORSEP-UHFFFAOYSA-N 1,2,6-Hexanetriol Chemical compound OCCCCC(O)CO ZWVMLYRJXORSEP-UHFFFAOYSA-N 0.000 description 1
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 description 1
- OPNUROKCUBTKLF-UHFFFAOYSA-N 1,2-bis(2-methylphenyl)guanidine Chemical compound CC1=CC=CC=C1N\C(N)=N\C1=CC=CC=C1C OPNUROKCUBTKLF-UHFFFAOYSA-N 0.000 description 1
- XGUMTHPROBAJEA-UHFFFAOYSA-N 1,2-dicyclohexyl-3-phenylguanidine Chemical compound C1CCCCC1NC(NC=1C=CC=CC=1)=NC1CCCCC1 XGUMTHPROBAJEA-UHFFFAOYSA-N 0.000 description 1
- XBYRMPXUBGMOJC-UHFFFAOYSA-N 1,2-dihydropyrazol-3-one Chemical class OC=1C=CNN=1 XBYRMPXUBGMOJC-UHFFFAOYSA-N 0.000 description 1
- 150000005206 1,2-dihydroxybenzenes Chemical class 0.000 description 1
- RBIZQDIIVYJNRS-UHFFFAOYSA-N 1,3-benzothiazole-5-carboxylic acid Chemical compound OC(=O)C1=CC=C2SC=NC2=C1 RBIZQDIIVYJNRS-UHFFFAOYSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical class C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- 150000005207 1,3-dihydroxybenzenes Chemical class 0.000 description 1
- LNKSOGFDOODVSP-UHFFFAOYSA-N 1,3-diisocyanato-2-methylbenzene;2,4-diisocyanato-1-methylbenzene Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O.CC1=C(N=C=O)C=CC=C1N=C=O LNKSOGFDOODVSP-UHFFFAOYSA-N 0.000 description 1
- UHKAJLSKXBADFT-UHFFFAOYSA-N 1,3-indandione Chemical compound C1=CC=C2C(=O)CC(=O)C2=C1 UHKAJLSKXBADFT-UHFFFAOYSA-N 0.000 description 1
- ZRHUHDUEXWHZMA-UHFFFAOYSA-N 1,4-dihydropyrazol-5-one Chemical class O=C1CC=NN1 ZRHUHDUEXWHZMA-UHFFFAOYSA-N 0.000 description 1
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- IFKVSABTHWCIGO-UHFFFAOYSA-N 1,5-dihydropyrazol-5-ide Chemical class C=1C=NN[C-]=1 IFKVSABTHWCIGO-UHFFFAOYSA-N 0.000 description 1
- 229940043375 1,5-pentanediol Drugs 0.000 description 1
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- JOKQVDKUGLMFLU-UHFFFAOYSA-N 1-ethoxy-2-propylbenzene Chemical compound CCCC1=CC=CC=C1OCC JOKQVDKUGLMFLU-UHFFFAOYSA-N 0.000 description 1
- OLEDDXCAZXBUOG-UHFFFAOYSA-N 1-ethyl-4-(1-phenylethyl)benzene Chemical compound C1=CC(CC)=CC=C1C(C)C1=CC=CC=C1 OLEDDXCAZXBUOG-UHFFFAOYSA-N 0.000 description 1
- OOYWUJOGJNQRCK-UHFFFAOYSA-N 1-ethyl-5-methoxybenzimidazole Chemical compound COC1=CC=C2N(CC)C=NC2=C1 OOYWUJOGJNQRCK-UHFFFAOYSA-N 0.000 description 1
- DTZHXCBUWSTOPO-UHFFFAOYSA-N 1-isocyanato-4-[(4-isocyanato-3-methylphenyl)methyl]-2-methylbenzene Chemical compound C1=C(N=C=O)C(C)=CC(CC=2C=C(C)C(N=C=O)=CC=2)=C1 DTZHXCBUWSTOPO-UHFFFAOYSA-N 0.000 description 1
- FGYADSCZTQOAFK-UHFFFAOYSA-N 1-methylbenzimidazole Chemical compound C1=CC=C2N(C)C=NC2=C1 FGYADSCZTQOAFK-UHFFFAOYSA-N 0.000 description 1
- BBOCZFGVXFNCTC-UHFFFAOYSA-N 1-methylnaphthalen-2-ol Chemical compound C1=CC=C2C(C)=C(O)C=CC2=C1 BBOCZFGVXFNCTC-UHFFFAOYSA-N 0.000 description 1
- KPVMVJXYXFUVLR-UHFFFAOYSA-N 12-ethyltetradecan-1-amine Chemical compound CCC(CC)CCCCCCCCCCCN KPVMVJXYXFUVLR-UHFFFAOYSA-N 0.000 description 1
- JAAIPIWKKXCNOC-UHFFFAOYSA-N 1h-tetrazol-1-ium-5-thiolate Chemical class SC1=NN=NN1 JAAIPIWKKXCNOC-UHFFFAOYSA-N 0.000 description 1
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- ALUQMCBDQKDRAK-UHFFFAOYSA-N 2,3,3a,4-tetrahydro-1,3-benzothiazole Chemical compound C1C=CC=C2SCNC21 ALUQMCBDQKDRAK-UHFFFAOYSA-N 0.000 description 1
- WCVOGSZTONGSQY-UHFFFAOYSA-N 2,4,6-trichloroanisole Chemical compound COC1=C(Cl)C=C(Cl)C=C1Cl WCVOGSZTONGSQY-UHFFFAOYSA-N 0.000 description 1
- UFBJCMHMOXMLKC-UHFFFAOYSA-N 2,4-dinitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O UFBJCMHMOXMLKC-UHFFFAOYSA-N 0.000 description 1
- 150000001473 2,4-thiazolidinediones Chemical class 0.000 description 1
- NDELSWXIAJLWOU-UHFFFAOYSA-N 2,5-dimethyl-4h-pyrazol-3-one Chemical compound CN1N=C(C)CC1=O NDELSWXIAJLWOU-UHFFFAOYSA-N 0.000 description 1
- NSMWYRLQHIXVAP-UHFFFAOYSA-N 2,5-dimethylpiperazine Chemical compound CC1CNC(C)CN1 NSMWYRLQHIXVAP-UHFFFAOYSA-N 0.000 description 1
- DHTGRDDBCWWKQJ-UHFFFAOYSA-N 2-(2,2-dihydroxyethoxy)ethane-1,1-diol Chemical compound OC(O)COCC(O)O DHTGRDDBCWWKQJ-UHFFFAOYSA-N 0.000 description 1
- BLDLRWQLBOJPEB-UHFFFAOYSA-N 2-(2-hydroxyphenyl)sulfanylphenol Chemical compound OC1=CC=CC=C1SC1=CC=CC=C1O BLDLRWQLBOJPEB-UHFFFAOYSA-N 0.000 description 1
- QUWAJPZDCZDTJS-UHFFFAOYSA-N 2-(2-hydroxyphenyl)sulfonylphenol Chemical compound OC1=CC=CC=C1S(=O)(=O)C1=CC=CC=C1O QUWAJPZDCZDTJS-UHFFFAOYSA-N 0.000 description 1
- SUCVFLDSLQTTCO-UHFFFAOYSA-N 2-(fluoromethyl)-1h-benzimidazole Chemical compound C1=CC=C2NC(CF)=NC2=C1 SUCVFLDSLQTTCO-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- GCLLYGBAAXKCFJ-UHFFFAOYSA-N 2-[4-(2-hydroxyethoxy)phenoxy]ethanol;propane-1,2,3-triol Chemical compound OCC(O)CO.OCCOC1=CC=C(OCCO)C=C1 GCLLYGBAAXKCFJ-UHFFFAOYSA-N 0.000 description 1
- LEARFTRDZQQTDN-UHFFFAOYSA-N 2-[4-(2-hydroxypropan-2-yl)phenyl]propan-2-ol Chemical compound CC(C)(O)C1=CC=C(C(C)(C)O)C=C1 LEARFTRDZQQTDN-UHFFFAOYSA-N 0.000 description 1
- UHGULLIUJBCTEF-UHFFFAOYSA-N 2-aminobenzothiazole Chemical compound C1=CC=C2SC(N)=NC2=C1 UHGULLIUJBCTEF-UHFFFAOYSA-N 0.000 description 1
- QPKNFEVLZVJGBM-UHFFFAOYSA-N 2-aminonaphthalen-1-ol Chemical class C1=CC=CC2=C(O)C(N)=CC=C21 QPKNFEVLZVJGBM-UHFFFAOYSA-N 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- NAPDOWNULRULLI-UHFFFAOYSA-N 2-benzyl-1h-imidazole Chemical compound C=1C=CC=CC=1CC1=NC=CN1 NAPDOWNULRULLI-UHFFFAOYSA-N 0.000 description 1
- SQMYHNKDAAAVRU-UHFFFAOYSA-N 2-chloroethenylbenzene;prop-1-enylbenzene Chemical compound CC=CC1=CC=CC=C1.ClC=CC1=CC=CC=C1 SQMYHNKDAAAVRU-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- PQLFCHDUACQEPJ-UHFFFAOYSA-N 2-hydroxy-3-(2,4,4-trimethylpentan-2-yl)benzoic acid Chemical compound CC(C)(C)CC(C)(C)C1=CC=CC(C(O)=O)=C1O PQLFCHDUACQEPJ-UHFFFAOYSA-N 0.000 description 1
- CTHJQRHPNQEPAB-UHFFFAOYSA-N 2-methoxyethenylbenzene Chemical compound COC=CC1=CC=CC=C1 CTHJQRHPNQEPAB-UHFFFAOYSA-N 0.000 description 1
- SRJCJJKWVSSELL-UHFFFAOYSA-N 2-methylnaphthalen-1-ol Chemical compound C1=CC=CC2=C(O)C(C)=CC=C21 SRJCJJKWVSSELL-UHFFFAOYSA-N 0.000 description 1
- JOMNTHCQHJPVAZ-UHFFFAOYSA-N 2-methylpiperazine Chemical compound CC1CNCCN1 JOMNTHCQHJPVAZ-UHFFFAOYSA-N 0.000 description 1
- LNCZPZFNQQFXPT-UHFFFAOYSA-N 2-phenyl-1,2-propanediol Chemical compound OCC(O)(C)C1=CC=CC=C1 LNCZPZFNQQFXPT-UHFFFAOYSA-N 0.000 description 1
- CLJAWGNAPOTZQN-UHFFFAOYSA-N 2-phenyl-4,5-dihydro-1h-imidazole;1,2,3-triphenylguanidine Chemical compound N1CCN=C1C1=CC=CC=C1.C=1C=CC=CC=1NC(=NC=1C=CC=CC=1)NC1=CC=CC=C1 CLJAWGNAPOTZQN-UHFFFAOYSA-N 0.000 description 1
- WLJVXDMOQOGPHL-PPJXEINESA-N 2-phenylacetic acid Chemical compound O[14C](=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-PPJXEINESA-N 0.000 description 1
- SCNKFUNWPYDBQX-UHFFFAOYSA-N 2-sulfanyl-3h-thiadiazol-5-amine Chemical compound NC1=CNN(S)S1 SCNKFUNWPYDBQX-UHFFFAOYSA-N 0.000 description 1
- VYNUATGQEAAPAQ-UHFFFAOYSA-N 2-sulfonylacetic acid Chemical compound OC(=O)C=S(=O)=O VYNUATGQEAAPAQ-UHFFFAOYSA-N 0.000 description 1
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 1
- RVBUGGBMJDPOST-UHFFFAOYSA-N 2-thiobarbituric acid Chemical class O=C1CC(=O)NC(=S)N1 RVBUGGBMJDPOST-UHFFFAOYSA-N 0.000 description 1
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- JMTMSDXUXJISAY-UHFFFAOYSA-N 2H-benzotriazol-4-ol Chemical compound OC1=CC=CC2=C1N=NN2 JMTMSDXUXJISAY-UHFFFAOYSA-N 0.000 description 1
- MGADZUXDNSDTHW-UHFFFAOYSA-N 2H-pyran Chemical compound C1OC=CC=C1 MGADZUXDNSDTHW-UHFFFAOYSA-N 0.000 description 1
- KFJDQPJLANOOOB-UHFFFAOYSA-N 2h-benzotriazole-4-carboxylic acid Chemical compound OC(=O)C1=CC=CC2=NNN=C12 KFJDQPJLANOOOB-UHFFFAOYSA-N 0.000 description 1
- JSIAIROWMJGMQZ-UHFFFAOYSA-N 2h-triazol-4-amine Chemical class NC1=CNN=N1 JSIAIROWMJGMQZ-UHFFFAOYSA-N 0.000 description 1
- WDNBURPWRNALGP-UHFFFAOYSA-N 3,4-Dichlorophenol Chemical compound OC1=CC=C(Cl)C(Cl)=C1 WDNBURPWRNALGP-UHFFFAOYSA-N 0.000 description 1
- PRCIXKQBKWRGMA-UHFFFAOYSA-N 3,4-dimethyl-1,4-dihydropyrazol-5-one Chemical compound CC1C(C)=NNC1=O PRCIXKQBKWRGMA-UHFFFAOYSA-N 0.000 description 1
- ZWQBZEFLFSFEOS-UHFFFAOYSA-N 3,5-ditert-butyl-2-hydroxybenzoic acid Chemical compound CC(C)(C)C1=CC(C(O)=O)=C(O)C(C(C)(C)C)=C1 ZWQBZEFLFSFEOS-UHFFFAOYSA-N 0.000 description 1
- WAVOOWVINKGEHS-UHFFFAOYSA-N 3-(diethylamino)phenol Chemical compound CCN(CC)C1=CC=CC(O)=C1 WAVOOWVINKGEHS-UHFFFAOYSA-N 0.000 description 1
- MESJRHHDBDCQTH-UHFFFAOYSA-N 3-(dimethylamino)phenol Chemical compound CN(C)C1=CC=CC(O)=C1 MESJRHHDBDCQTH-UHFFFAOYSA-N 0.000 description 1
- 229940018563 3-aminophenol Drugs 0.000 description 1
- LICHZOBEUWVYSY-UHFFFAOYSA-N 3-azabicyclo[3.2.2]nonane Chemical compound C1CC2CCC1CNC2 LICHZOBEUWVYSY-UHFFFAOYSA-N 0.000 description 1
- NHLAPJMCARJFOG-UHFFFAOYSA-N 3-methyl-1,4-dihydropyrazol-5-one Chemical compound CC1=NNC(=O)C1 NHLAPJMCARJFOG-UHFFFAOYSA-N 0.000 description 1
- SXFJDZNJHVPHPH-UHFFFAOYSA-N 3-methylpentane-1,5-diol Chemical compound OCCC(C)CCO SXFJDZNJHVPHPH-UHFFFAOYSA-N 0.000 description 1
- HHSBHVJQXZLIRW-UHFFFAOYSA-N 3-n,3-n-dimethylbenzene-1,3-diamine Chemical compound CN(C)C1=CC=CC(N)=C1 HHSBHVJQXZLIRW-UHFFFAOYSA-N 0.000 description 1
- JVQIKJMSUIMUDI-UHFFFAOYSA-N 3-pyrroline Chemical compound C1NCC=C1 JVQIKJMSUIMUDI-UHFFFAOYSA-N 0.000 description 1
- ZAAMQANODYDRDF-UHFFFAOYSA-N 3-tert-butyl-2-hydroxybenzoic acid Chemical compound CC(C)(C)C1=CC=CC(C(O)=O)=C1O ZAAMQANODYDRDF-UHFFFAOYSA-N 0.000 description 1
- HCCNHYWZYYIOFM-UHFFFAOYSA-N 3h-benzo[e]benzimidazole Chemical class C1=CC=C2C(N=CN3)=C3C=CC2=C1 HCCNHYWZYYIOFM-UHFFFAOYSA-N 0.000 description 1
- MVVFUAACPKXXKJ-UHFFFAOYSA-N 4,5-dihydro-1,3-selenazole Chemical class C1CN=C[Se]1 MVVFUAACPKXXKJ-UHFFFAOYSA-N 0.000 description 1
- YLNKRLLYLJYWEN-UHFFFAOYSA-N 4-(2,2-dibutoxyethoxy)-4-oxobutanoic acid Chemical compound CCCCOC(OCCCC)COC(=O)CCC(O)=O YLNKRLLYLJYWEN-UHFFFAOYSA-N 0.000 description 1
- ZRVIYEJYXIDATJ-UHFFFAOYSA-N 4-Heptyloxybenzoic acid Chemical compound CCCCCCCOC1=CC=C(C(O)=O)C=C1 ZRVIYEJYXIDATJ-UHFFFAOYSA-N 0.000 description 1
- JZJCOIKBDYAFBQ-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]phenol;phenol Chemical compound OC1=CC=CC=C1.OC1=CC=CC=C1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 JZJCOIKBDYAFBQ-UHFFFAOYSA-N 0.000 description 1
- HJSPWKGEPDZNLK-UHFFFAOYSA-N 4-benzylphenol Chemical compound C1=CC(O)=CC=C1CC1=CC=CC=C1 HJSPWKGEPDZNLK-UHFFFAOYSA-N 0.000 description 1
- PIUXNZAIHQAHBY-UHFFFAOYSA-N 4-methyl-1,3-benzothiazole Chemical compound CC1=CC=CC2=C1N=CS2 PIUXNZAIHQAHBY-UHFFFAOYSA-N 0.000 description 1
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 1
- ZSUDUDXOEGHEJR-UHFFFAOYSA-N 4-methylnaphthalen-1-ol Chemical compound C1=CC=C2C(C)=CC=C(O)C2=C1 ZSUDUDXOEGHEJR-UHFFFAOYSA-N 0.000 description 1
- RILRYAJSOCTFBV-UHFFFAOYSA-N 4-phenyl-1,3-benzothiazole Chemical compound C1=CC=C2SC=NC2=C1C1=CC=CC=C1 RILRYAJSOCTFBV-UHFFFAOYSA-N 0.000 description 1
- NNJMFJSKMRYHSR-UHFFFAOYSA-N 4-phenylbenzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=CC=C1 NNJMFJSKMRYHSR-UHFFFAOYSA-N 0.000 description 1
- RXAGDDKHRDAVLM-UHFFFAOYSA-N 4-tert-butyl-2-[(5-tert-butyl-2-hydroxyphenyl)methyl]phenol Chemical compound CC(C)(C)C1=CC=C(O)C(CC=2C(=CC=C(C=2)C(C)(C)C)O)=C1 RXAGDDKHRDAVLM-UHFFFAOYSA-N 0.000 description 1
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 1
- CBNFYVIXCBIFSQ-UHFFFAOYSA-N 5,5-dimethyl-2,3-diphenyl-4h-imidazole Chemical compound N=1C(C)(C)CN(C=2C=CC=CC=2)C=1C1=CC=CC=C1 CBNFYVIXCBIFSQ-UHFFFAOYSA-N 0.000 description 1
- GYVLFYQMEWXHQF-UHFFFAOYSA-N 5,6-dichloro-1-ethylbenzimidazole Chemical compound ClC1=C(Cl)C=C2N(CC)C=NC2=C1 GYVLFYQMEWXHQF-UHFFFAOYSA-N 0.000 description 1
- QMUXKZBRYRPIPQ-UHFFFAOYSA-N 5,6-dimethyl-1,3-benzothiazole Chemical compound C1=C(C)C(C)=CC2=C1SC=N2 QMUXKZBRYRPIPQ-UHFFFAOYSA-N 0.000 description 1
- RWNMLYACWNIEIG-UHFFFAOYSA-N 5,6-dimethyl-1,3-benzoxazole Chemical compound C1=C(C)C(C)=CC2=C1OC=N2 RWNMLYACWNIEIG-UHFFFAOYSA-N 0.000 description 1
- QDJLLCBDLMEGEI-UHFFFAOYSA-N 5-(2-phenylethyl)-1,3-benzothiazole Chemical compound C=1C=C2SC=NC2=CC=1CCC1=CC=CC=C1 QDJLLCBDLMEGEI-UHFFFAOYSA-N 0.000 description 1
- ZYUVGYBAPZYKSA-UHFFFAOYSA-N 5-(3-hydroxybutan-2-yl)-4-methylbenzene-1,3-diol Chemical compound CC(O)C(C)C1=CC(O)=CC(O)=C1C ZYUVGYBAPZYKSA-UHFFFAOYSA-N 0.000 description 1
- ODSGKKPRKQLYDA-UHFFFAOYSA-N 5-(trifluoromethyl)-1,3-benzothiazole Chemical compound FC(F)(F)C1=CC=C2SC=NC2=C1 ODSGKKPRKQLYDA-UHFFFAOYSA-N 0.000 description 1
- KFDDRUWQFQJGNL-UHFFFAOYSA-N 5-bromo-1,3-benzothiazole Chemical compound BrC1=CC=C2SC=NC2=C1 KFDDRUWQFQJGNL-UHFFFAOYSA-N 0.000 description 1
- PGOGTWDYLFKOHI-UHFFFAOYSA-N 5-bromo-1,3-benzoxazole Chemical compound BrC1=CC=C2OC=NC2=C1 PGOGTWDYLFKOHI-UHFFFAOYSA-N 0.000 description 1
- DUMYZVKQCMCQHJ-UHFFFAOYSA-N 5-chloro-1,3-benzoselenazole Chemical group ClC1=CC=C2[se]C=NC2=C1 DUMYZVKQCMCQHJ-UHFFFAOYSA-N 0.000 description 1
- ZMOTXTVRERQBMM-UHFFFAOYSA-N 5-chloro-1,3-benzothiazole;6-chloro-1,3-benzothiazole Chemical compound ClC1=CC=C2SC=NC2=C1.ClC1=CC=C2N=CSC2=C1 ZMOTXTVRERQBMM-UHFFFAOYSA-N 0.000 description 1
- DKTVQKUFTJLEGT-UHFFFAOYSA-N 5-chloro-1-methylbenzimidazole Chemical compound ClC1=CC=C2N(C)C=NC2=C1 DKTVQKUFTJLEGT-UHFFFAOYSA-N 0.000 description 1
- GWKNDCJHRNOQAR-UHFFFAOYSA-N 5-ethoxy-1,3-benzothiazole Chemical compound CCOC1=CC=C2SC=NC2=C1 GWKNDCJHRNOQAR-UHFFFAOYSA-N 0.000 description 1
- MHWNEQOZIDVGJS-UHFFFAOYSA-N 5-ethoxy-1,3-benzoxazole Chemical compound CCOC1=CC=C2OC=NC2=C1 MHWNEQOZIDVGJS-UHFFFAOYSA-N 0.000 description 1
- PLLCCSYEGQDAIW-UHFFFAOYSA-N 5-ethyl-1,6-dimethyl-5-phenylcyclohexa-1,3-diene Chemical compound C=1C=CC=CC=1C1(CC)C=CC=C(C)C1C PLLCCSYEGQDAIW-UHFFFAOYSA-N 0.000 description 1
- ANEKYSBZODRVRB-UHFFFAOYSA-N 5-fluoro-1,3-benzothiazole Chemical compound FC1=CC=C2SC=NC2=C1 ANEKYSBZODRVRB-UHFFFAOYSA-N 0.000 description 1
- ZRMPAEOUOPNNPZ-UHFFFAOYSA-N 5-fluoro-1,3-benzoxazole Chemical compound FC1=CC=C2OC=NC2=C1 ZRMPAEOUOPNNPZ-UHFFFAOYSA-N 0.000 description 1
- PNJKZDLZKILFNF-UHFFFAOYSA-N 5-methoxy-1,3-benzothiazole Chemical compound COC1=CC=C2SC=NC2=C1 PNJKZDLZKILFNF-UHFFFAOYSA-N 0.000 description 1
- SEBIXVUYSFOUEL-UHFFFAOYSA-N 5-methyl-1,3-benzothiazole Chemical compound CC1=CC=C2SC=NC2=C1 SEBIXVUYSFOUEL-UHFFFAOYSA-N 0.000 description 1
- UBIAVBGIRDRQLD-UHFFFAOYSA-N 5-methyl-1,3-benzoxazole Chemical compound CC1=CC=C2OC=NC2=C1 UBIAVBGIRDRQLD-UHFFFAOYSA-N 0.000 description 1
- TYOXIFXYEIILLY-UHFFFAOYSA-N 5-methyl-2-phenyl-1h-imidazole Chemical compound N1C(C)=CN=C1C1=CC=CC=C1 TYOXIFXYEIILLY-UHFFFAOYSA-N 0.000 description 1
- AAKPXIJKSNGOCO-UHFFFAOYSA-N 5-phenyl-1,3-benzothiazole Chemical compound C=1C=C2SC=NC2=CC=1C1=CC=CC=C1 AAKPXIJKSNGOCO-UHFFFAOYSA-N 0.000 description 1
- NIFNXGHHDAXUGO-UHFFFAOYSA-N 5-phenyl-1,3-benzoxazole Chemical compound C=1C=C2OC=NC2=CC=1C1=CC=CC=C1 NIFNXGHHDAXUGO-UHFFFAOYSA-N 0.000 description 1
- QYFYIOWLBSPSDM-UHFFFAOYSA-N 6-aminonaphthalen-1-ol Chemical compound OC1=CC=CC2=CC(N)=CC=C21 QYFYIOWLBSPSDM-UHFFFAOYSA-N 0.000 description 1
- YJOUISWKEOXIMC-UHFFFAOYSA-N 6-bromo-1,3-benzothiazole Chemical compound BrC1=CC=C2N=CSC2=C1 YJOUISWKEOXIMC-UHFFFAOYSA-N 0.000 description 1
- JJOOKXUUVWIARB-UHFFFAOYSA-N 6-chloro-1,3-benzoxazole Chemical compound ClC1=CC=C2N=COC2=C1 JJOOKXUUVWIARB-UHFFFAOYSA-N 0.000 description 1
- OCIFJWVZZUDMRL-UHFFFAOYSA-N 6-hydroxyhexyl prop-2-enoate Chemical compound OCCCCCCOC(=O)C=C OCIFJWVZZUDMRL-UHFFFAOYSA-N 0.000 description 1
- AHOIGFLSEXUWNV-UHFFFAOYSA-N 6-methoxy-1,3-benzothiazole Chemical compound COC1=CC=C2N=CSC2=C1 AHOIGFLSEXUWNV-UHFFFAOYSA-N 0.000 description 1
- FKYKJYSYSGEDCG-UHFFFAOYSA-N 6-methoxy-1,3-benzoxazole Chemical compound COC1=CC=C2N=COC2=C1 FKYKJYSYSGEDCG-UHFFFAOYSA-N 0.000 description 1
- SUQXTXGQPDMMLX-UHFFFAOYSA-N 6-methoxy-5-methyl-1,3-benzothiazole Chemical compound C1=C(C)C(OC)=CC2=C1N=CS2 SUQXTXGQPDMMLX-UHFFFAOYSA-N 0.000 description 1
- XCJCAMHJUCETPI-UHFFFAOYSA-N 6-methyl-1,3-benzothiazol-5-ol Chemical compound C1=C(O)C(C)=CC2=C1N=CS2 XCJCAMHJUCETPI-UHFFFAOYSA-N 0.000 description 1
- IVKILQAPNDCUNJ-UHFFFAOYSA-N 6-methyl-1,3-benzothiazole Chemical compound CC1=CC=C2N=CSC2=C1 IVKILQAPNDCUNJ-UHFFFAOYSA-N 0.000 description 1
- SZWNDAUMBWLYOQ-UHFFFAOYSA-N 6-methylbenzoxazole Chemical compound CC1=CC=C2N=COC2=C1 SZWNDAUMBWLYOQ-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- KVHHMYZBFBSVDI-UHFFFAOYSA-N 8-aminonaphthalen-2-ol Chemical compound C1=C(O)C=C2C(N)=CC=CC2=C1 KVHHMYZBFBSVDI-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- 239000004953 Aliphatic polyamide Substances 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
- 239000005695 Ammonium acetate Substances 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical compound NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 description 1
- 241000283726 Bison Species 0.000 description 1
- HTVITOHKHWFJKO-UHFFFAOYSA-N Bisphenol B Chemical compound C=1C=C(O)C=CC=1C(C)(CC)C1=CC=C(O)C=C1 HTVITOHKHWFJKO-UHFFFAOYSA-N 0.000 description 1
- SDDLEVPIDBLVHC-UHFFFAOYSA-N Bisphenol Z Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCCC1 SDDLEVPIDBLVHC-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- RKSQEIADDGCGMS-UHFFFAOYSA-N C(=C)CC1=CC=CC=C1.ClC=CC1=CC=CC=C1 Chemical compound C(=C)CC1=CC=CC=C1.ClC=CC1=CC=CC=C1 RKSQEIADDGCGMS-UHFFFAOYSA-N 0.000 description 1
- SNKOMFDIIZGSHO-UHFFFAOYSA-N C(CCCCCN=C=O)N=C=O.C(CCN=C=O)N=C=O Chemical compound C(CCCCCN=C=O)N=C=O.C(CCN=C=O)N=C=O SNKOMFDIIZGSHO-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- LSPHULWDVZXLIL-UHFFFAOYSA-N Camphoric acid Natural products CC1(C)C(C(O)=O)CCC1(C)C(O)=O LSPHULWDVZXLIL-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000001263 FEMA 3042 Substances 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical group FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 241001481824 Indri Species 0.000 description 1
- 238000012695 Interfacial polymerization Methods 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 241001553014 Myrsine salicina Species 0.000 description 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
- KQJQICVXLJTWQD-UHFFFAOYSA-N N-Methylthiourea Chemical compound CNC(N)=S KQJQICVXLJTWQD-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- IIYYSVCDYLYLRI-UHFFFAOYSA-N NC(=O)C=CCCCC=CC(N)=O Chemical compound NC(=O)C=CCCCC=CC(N)=O IIYYSVCDYLYLRI-UHFFFAOYSA-N 0.000 description 1
- 101150006989 NDEL1 gene Proteins 0.000 description 1
- PCKPVGOLPKLUHR-UHFFFAOYSA-N OH-Indolxyl Natural products C1=CC=C2C(O)=CNC2=C1 PCKPVGOLPKLUHR-UHFFFAOYSA-N 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- 241000233855 Orchidaceae Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 240000007320 Pinus strobus Species 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical group [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 241000270666 Testudines Species 0.000 description 1
- QPMIVFWZGPTDPN-UHFFFAOYSA-N Tetrabromophenol blue Chemical compound C1=C(Br)C(O)=C(Br)C=C1C1(C=2C=C(Br)C(O)=C(Br)C=2)C(C(Br)=C(Br)C(Br)=C2Br)=C2S(=O)(=O)O1 QPMIVFWZGPTDPN-UHFFFAOYSA-N 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 1
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 1
- BWVAOONFBYYRHY-UHFFFAOYSA-N [4-(hydroxymethyl)phenyl]methanol Chemical compound OCC1=CC=C(CO)C=C1 BWVAOONFBYYRHY-UHFFFAOYSA-N 0.000 description 1
- XCFIVNQHHFZRNR-UHFFFAOYSA-N [Ag].Cl[IH]Br Chemical compound [Ag].Cl[IH]Br XCFIVNQHHFZRNR-UHFFFAOYSA-N 0.000 description 1
- HOLVRJRSWZOAJU-UHFFFAOYSA-N [Ag].ICl Chemical compound [Ag].ICl HOLVRJRSWZOAJU-UHFFFAOYSA-N 0.000 description 1
- JFRWJMLAHIULCB-UHFFFAOYSA-L [K+].[Br-].[Br-].[Ag+] Chemical compound [K+].[Br-].[Br-].[Ag+] JFRWJMLAHIULCB-UHFFFAOYSA-L 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- VJHCJDRQFCCTHL-UHFFFAOYSA-N acetic acid 2,3,4,5,6-pentahydroxyhexanal Chemical compound CC(O)=O.OCC(O)C(O)C(O)C(O)C=O VJHCJDRQFCCTHL-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- OFLXLNCGODUUOT-UHFFFAOYSA-N acetohydrazide Chemical compound C\C(O)=N\N OFLXLNCGODUUOT-UHFFFAOYSA-N 0.000 description 1
- 229940081735 acetylcellulose Drugs 0.000 description 1
- 238000010669 acid-base reaction Methods 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- 125000004423 acyloxy group Chemical group 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 150000007824 aliphatic compounds Chemical class 0.000 description 1
- 229920003231 aliphatic polyamide Polymers 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 125000004390 alkyl sulfonyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 235000010210 aluminium Nutrition 0.000 description 1
- 125000000747 amidyl group Chemical group [H][N-]* 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 150000003931 anilides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000001450 anions Chemical group 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical group 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 150000007860 aryl ester derivatives Chemical class 0.000 description 1
- 150000008378 aryl ethers Chemical class 0.000 description 1
- 125000004391 aryl sulfonyl group Chemical group 0.000 description 1
- 238000006149 azo coupling reaction Methods 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 125000005337 azoxy group Chemical group [N+]([O-])(=N*)* 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- CJPQIRJHIZUAQP-MRXNPFEDSA-N benalaxyl-M Chemical compound CC=1C=CC=C(C)C=1N([C@H](C)C(=O)OC)C(=O)CC1=CC=CC=C1 CJPQIRJHIZUAQP-MRXNPFEDSA-N 0.000 description 1
- 150000001556 benzimidazoles Chemical class 0.000 description 1
- 125000005605 benzo group Chemical group 0.000 description 1
- HJLDPBXWNCCXGM-UHFFFAOYSA-N benzo[f][1,3]benzothiazole Chemical compound C1=CC=C2C=C(SC=N3)C3=CC2=C1 HJLDPBXWNCCXGM-UHFFFAOYSA-N 0.000 description 1
- IEICFDLIJMHYQB-UHFFFAOYSA-N benzo[g][1,3]benzoselenazole Chemical compound C1=CC=CC2=C([se]C=N3)C3=CC=C21 IEICFDLIJMHYQB-UHFFFAOYSA-N 0.000 description 1
- BVVBQOJNXLFIIG-UHFFFAOYSA-N benzo[g][1,3]benzoxazole Chemical compound C1=CC=CC2=C(OC=N3)C3=CC=C21 BVVBQOJNXLFIIG-UHFFFAOYSA-N 0.000 description 1
- WARCRYXKINZHGQ-UHFFFAOYSA-N benzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1 WARCRYXKINZHGQ-UHFFFAOYSA-N 0.000 description 1
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N benzoic acid ethyl ester Natural products CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 239000003130 blood coagulation factor inhibitor Substances 0.000 description 1
- 150000001642 boronic acid derivatives Chemical group 0.000 description 1
- 229940006460 bromide ion Drugs 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 description 1
- KVCNVTICIMHGNP-UHFFFAOYSA-N butane-1,4-diol;propane-1,3-diol Chemical compound OCCCO.OCCCCO KVCNVTICIMHGNP-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- FKRUWNAHJPUFHE-UHFFFAOYSA-N butyl acetate;ethyl propanoate Chemical compound CCOC(=O)CC.CCCCOC(C)=O FKRUWNAHJPUFHE-UHFFFAOYSA-N 0.000 description 1
- COPHVUDURPSYBO-UHFFFAOYSA-N butyl dioctyl phosphate Chemical compound CCCCCCCCOP(=O)(OCCCC)OCCCCCCCC COPHVUDURPSYBO-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- LSPHULWDVZXLIL-QUBYGPBYSA-N camphoric acid Chemical compound CC1(C)[C@H](C(O)=O)CC[C@]1(C)C(O)=O LSPHULWDVZXLIL-QUBYGPBYSA-N 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000001768 cations Chemical group 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- ZUIVNYGZFPOXFW-UHFFFAOYSA-N chembl1717603 Chemical compound N1=C(C)C=C(O)N2N=CN=C21 ZUIVNYGZFPOXFW-UHFFFAOYSA-N 0.000 description 1
- 238000005354 coacervation Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- PDXRQENMIVHKPI-UHFFFAOYSA-N cyclohexane-1,1-diol Chemical compound OC1(O)CCCCC1 PDXRQENMIVHKPI-UHFFFAOYSA-N 0.000 description 1
- NHADDZMCASKINP-HTRCEHHLSA-N decarboxydihydrocitrinin Natural products C1=C(O)C(C)=C2[C@H](C)[C@@H](C)OCC2=C1O NHADDZMCASKINP-HTRCEHHLSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 125000004663 dialkyl amino group Chemical group 0.000 description 1
- 239000012954 diazonium Substances 0.000 description 1
- YPUGLZQRXQQCSX-UHFFFAOYSA-N dibenzylpiperazine Chemical compound C=1C=CC=CC=1CN(CC1)CCN1CC1=CC=CC=C1 YPUGLZQRXQQCSX-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- XWVQUJDBOICHGH-UHFFFAOYSA-N dioctyl nonanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCC(=O)OCCCCCCCC XWVQUJDBOICHGH-UHFFFAOYSA-N 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- QELUYTUMUWHWMC-UHFFFAOYSA-N edaravone Chemical compound O=C1CC(C)=NN1C1=CC=CC=C1 QELUYTUMUWHWMC-UHFFFAOYSA-N 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000005674 electromagnetic induction Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- YQGOJNYOYNNSMM-UHFFFAOYSA-N eosin Chemical compound [Na+].OC(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C(O)=C(Br)C=C21 YQGOJNYOYNNSMM-UHFFFAOYSA-N 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 1
- ZEUUVJSRINKECZ-UHFFFAOYSA-N ethanedithioic acid Chemical compound CC(S)=S ZEUUVJSRINKECZ-UHFFFAOYSA-N 0.000 description 1
- NHOGGUYTANYCGQ-UHFFFAOYSA-N ethenoxybenzene Chemical compound C=COC1=CC=CC=C1 NHOGGUYTANYCGQ-UHFFFAOYSA-N 0.000 description 1
- AZDCYKCDXXPQIK-UHFFFAOYSA-N ethenoxymethylbenzene Chemical compound C=COCC1=CC=CC=C1 AZDCYKCDXXPQIK-UHFFFAOYSA-N 0.000 description 1
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 229910001447 ferric ion Inorganic materials 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- FWQHNLCNFPYBCA-UHFFFAOYSA-N fluoran Chemical compound C12=CC=CC=C2OC2=CC=CC=C2C11OC(=O)C2=CC=CC=C21 FWQHNLCNFPYBCA-UHFFFAOYSA-N 0.000 description 1
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- LRBQNJMCXXYXIU-QWKBTXIPSA-N gallotannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@H]2[C@@H]([C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-QWKBTXIPSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- CZLCEPVHPYKDPJ-UHFFFAOYSA-N guanidine;2,2,2-trichloroacetic acid Chemical compound NC(N)=N.OC(=O)C(Cl)(Cl)Cl CZLCEPVHPYKDPJ-UHFFFAOYSA-N 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- SXCBDZAEHILGLM-UHFFFAOYSA-N heptane-1,7-diol Chemical compound OCCCCCCCO SXCBDZAEHILGLM-UHFFFAOYSA-N 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- HSEMFIZWXHQJAE-UHFFFAOYSA-N hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 description 1
- TZMQHOJDDMFGQX-UHFFFAOYSA-N hexane-1,1,1-triol Chemical compound CCCCCC(O)(O)O TZMQHOJDDMFGQX-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- OHMBHFSEKCCCBW-UHFFFAOYSA-N hexane-2,5-diol Chemical compound CC(O)CCC(C)O OHMBHFSEKCCCBW-UHFFFAOYSA-N 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- AKCUHGBLDXXTOM-UHFFFAOYSA-N hydroxy-oxo-phenyl-sulfanylidene-$l^{6}-sulfane Chemical compound SS(=O)(=O)C1=CC=CC=C1 AKCUHGBLDXXTOM-UHFFFAOYSA-N 0.000 description 1
- NPZTUJOABDZTLV-UHFFFAOYSA-N hydroxybenzotriazole Substances O=C1C=CC=C2NNN=C12 NPZTUJOABDZTLV-UHFFFAOYSA-N 0.000 description 1
- 150000002443 hydroxylamines Chemical class 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 150000004693 imidazolium salts Chemical group 0.000 description 1
- 125000002883 imidazolyl group Chemical group 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 125000001841 imino group Chemical group [H]N=* 0.000 description 1
- 125000003454 indenyl group Chemical class C1(C=CC2=CC=CC=C12)* 0.000 description 1
- JYGFTBXVXVMTGB-UHFFFAOYSA-N indolin-2-one Chemical compound C1=CC=C2NC(=O)CC2=C1 JYGFTBXVXVMTGB-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 1
- 229940006461 iodide ion Drugs 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- XHQSLVIGPHXVAK-UHFFFAOYSA-K iron(3+);octadecanoate Chemical compound [Fe+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XHQSLVIGPHXVAK-UHFFFAOYSA-K 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical class OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- VJPLIHZPOJDHLB-UHFFFAOYSA-N lead titanium Chemical compound [Ti].[Pb] VJPLIHZPOJDHLB-UHFFFAOYSA-N 0.000 description 1
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 125000003588 lysine group Chemical group [H]N([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(N([H])[H])C(*)=O 0.000 description 1
- 229940018564 m-phenylenediamine Drugs 0.000 description 1
- GPSDUZXPYCFOSQ-UHFFFAOYSA-N m-toluic acid Chemical compound CC1=CC=CC(C(O)=O)=C1 GPSDUZXPYCFOSQ-UHFFFAOYSA-N 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 239000006249 magnetic particle Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- VYQNWZOUAUKGHI-UHFFFAOYSA-N monobenzone Chemical compound C1=CC(O)=CC=C1OCC1=CC=CC=C1 VYQNWZOUAUKGHI-UHFFFAOYSA-N 0.000 description 1
- CLWJIABBMNILFU-UHFFFAOYSA-N morpholine;2,2,2-trichloroacetic acid Chemical compound C1COCC[NH2+]1.[O-]C(=O)C(Cl)(Cl)Cl CLWJIABBMNILFU-UHFFFAOYSA-N 0.000 description 1
- 150000002780 morpholines Chemical class 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- MXHTZQSKTCCMFG-UHFFFAOYSA-N n,n-dibenzyl-1-phenylmethanamine Chemical compound C=1C=CC=CC=1CN(CC=1C=CC=CC=1)CC1=CC=CC=C1 MXHTZQSKTCCMFG-UHFFFAOYSA-N 0.000 description 1
- OVHHHVAVHBHXAK-UHFFFAOYSA-N n,n-diethylprop-2-enamide Chemical compound CCN(CC)C(=O)C=C OVHHHVAVHBHXAK-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- BPCNEKWROYSOLT-UHFFFAOYSA-N n-phenylprop-2-enamide Chemical compound C=CC(=O)NC1=CC=CC=C1 BPCNEKWROYSOLT-UHFFFAOYSA-N 0.000 description 1
- YCTXMPFTEVXUSO-UHFFFAOYSA-N naphthalen-2-ol;phenol Chemical compound OC1=CC=CC=C1.C1=CC=CC2=CC(O)=CC=C21 YCTXMPFTEVXUSO-UHFFFAOYSA-N 0.000 description 1
- XOOMNEFVDUTJPP-UHFFFAOYSA-N naphthalene-1,3-diol Chemical compound C1=CC=CC2=CC(O)=CC(O)=C21 XOOMNEFVDUTJPP-UHFFFAOYSA-N 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 150000004957 nitroimidazoles Chemical class 0.000 description 1
- 150000002832 nitroso derivatives Chemical class 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 238000010534 nucleophilic substitution reaction Methods 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- VECVSKFWRQYTAL-UHFFFAOYSA-N octyl benzoate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1 VECVSKFWRQYTAL-UHFFFAOYSA-N 0.000 description 1
- OIPPWFOQEKKFEE-UHFFFAOYSA-N orcinol Chemical compound CC1=CC(O)=CC(O)=C1 OIPPWFOQEKKFEE-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- QUANRIQJNFHVEU-UHFFFAOYSA-N oxirane;propane-1,2,3-triol Chemical compound C1CO1.OCC(O)CO QUANRIQJNFHVEU-UHFFFAOYSA-N 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- 150000004989 p-phenylenediamines Chemical class 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- GTCCGKPBSJZVRZ-UHFFFAOYSA-N pentane-2,4-diol Chemical compound CC(O)CC(C)O GTCCGKPBSJZVRZ-UHFFFAOYSA-N 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Chemical compound [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical class C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- XNERWVPQCYSMLC-UHFFFAOYSA-N phenylpropiolic acid Chemical compound OC(=O)C#CC1=CC=CC=C1 XNERWVPQCYSMLC-UHFFFAOYSA-N 0.000 description 1
- ZYIBVBKZZZDFOY-UHFFFAOYSA-N phloxine O Chemical compound O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(Br)=C(O)C(Br)=C1OC1=C(Br)C(O)=C(Br)C=C21 ZYIBVBKZZZDFOY-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical group 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 150000004885 piperazines Chemical class 0.000 description 1
- 150000003053 piperidines Chemical class 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 150000004804 polysaccharides Chemical class 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- VPJDULFXCAQHRC-UHFFFAOYSA-N prop-2-enylurea Chemical compound NC(=O)NCC=C VPJDULFXCAQHRC-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- UORVCLMRJXCDCP-UHFFFAOYSA-N propynoic acid Chemical class OC(=O)C#C UORVCLMRJXCDCP-UHFFFAOYSA-N 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 150000003236 pyrrolines Chemical class 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- GJAWHXHKYYXBSV-UHFFFAOYSA-N quinolinic acid Chemical group OC(=O)C1=CC=CN=C1C(O)=O GJAWHXHKYYXBSV-UHFFFAOYSA-N 0.000 description 1
- GGWBHVILAJZWKJ-KJEVSKRMSA-N ranitidine hydrochloride Chemical compound [H+].[Cl-].[O-][N+](=O)\C=C(/NC)NCCSCC1=CC=C(CN(C)C)O1 GGWBHVILAJZWKJ-KJEVSKRMSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- SONJTKJMTWTJCT-UHFFFAOYSA-K rhodium(iii) chloride Chemical class [Cl-].[Cl-].[Cl-].[Rh+3] SONJTKJMTWTJCT-UHFFFAOYSA-K 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 1
- 229940081974 saccharin Drugs 0.000 description 1
- 235000019204 saccharin Nutrition 0.000 description 1
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 1
- 229940058287 salicylic acid derivative anticestodals Drugs 0.000 description 1
- 150000003872 salicylic acid derivatives Chemical class 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- AQRYNYUOKMNDDV-UHFFFAOYSA-M silver behenate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O AQRYNYUOKMNDDV-UHFFFAOYSA-M 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 125000003003 spiro group Chemical group 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 125000004354 sulfur functional group Chemical group 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 150000003475 thallium Chemical class 0.000 description 1
- JJJPTTANZGDADF-UHFFFAOYSA-N thiadiazole-4-thiol Chemical class SC1=CSN=N1 JJJPTTANZGDADF-UHFFFAOYSA-N 0.000 description 1
- 150000003566 thiocarboxylic acids Chemical class 0.000 description 1
- 125000005323 thioketone group Chemical group 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- BRNULMACUQOKMR-UHFFFAOYSA-N thiomorpholine Chemical compound C1CSCCN1 BRNULMACUQOKMR-UHFFFAOYSA-N 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- 239000001003 triarylmethane dye Substances 0.000 description 1
- NJPOTNJJCSJJPJ-UHFFFAOYSA-N tributyl benzene-1,3,5-tricarboxylate Chemical compound CCCCOC(=O)C1=CC(C(=O)OCCCC)=CC(C(=O)OCCCC)=C1 NJPOTNJJCSJJPJ-UHFFFAOYSA-N 0.000 description 1
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
- DANYXEHCMQHDNX-UHFFFAOYSA-K trichloroiridium Chemical compound Cl[Ir](Cl)Cl DANYXEHCMQHDNX-UHFFFAOYSA-K 0.000 description 1
- QMKYBPDZANOJGF-UHFFFAOYSA-N trimesic acid Natural products OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 1
- SWRKBUGJWNPDJT-UHFFFAOYSA-M trimethyl-[2-[methyl(propan-2-yloxy)phosphoryl]sulfanylethyl]azanium;iodide Chemical compound [I-].CC(C)OP(C)(=O)SCC[N+](C)(C)C SWRKBUGJWNPDJT-UHFFFAOYSA-M 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/0285—Silver salts, e.g. a latent silver salt image
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/494—Silver salt compositions other than silver halide emulsions; Photothermographic systems ; Thermographic systems using noble metal compounds
- G03C1/498—Photothermographic systems, e.g. dry silver
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/002—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor using materials containing microcapsules; Preparing or processing such materials, e.g. by pressure; Devices or apparatus specially designed therefor
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
Description
ãçºæã®è©³çŽ°ãªèª¬æã
çºæã®èæ¯
æè¡åé
æ¬çºæã¯ãéåæ§ååç©ããã³è²ç»å圢æç©è³ª
ãå°å ¥ãããã€ã¯ãã«ãã»ã«ãå«æããæå ææ
ã«é¢ãããããã«è©³ããã¯æå æ§ããã²ã³åéã
ã»ã³ãµãŒãšãã掻æ§ç·ç §å°æã«ãã®ããã²ã³åé
äžã«åœ¢æãããåæ§ã®æœåãå©çšããŠãåæ§ã«é«
ååååç©ãçæãããå ±åããè²ç»å圢æç©è³ª
ãäžååãããæå ææã«é¢ããã å è¡æè¡ãšãã®åé¡ç¹ ãã€ã¯ãã«ãã»ã«ãå©çšããèšé²ææãšããŠã¯
çš®ã ã®ãã®ãç¥ãããŠããã äŸãã°ãç¹å ¬æ42â14344å·ïŒç±³åœç¹èš±ç¬¬
3219446å·ïŒã«ã¯ãå ãç §å°ãããšéæµåæ§ã«ãª
ãå€ãã®æµåäœå°æ»Žãæããææã·ãŒãã«ç»åæ§
ã®é²å ããããããååã·ãŒããžéããŠã·ãŒãå š
äœã«å§åãå ããããšã«ããããã®ååã·ãŒãäž
ã«é²å ã«å¿ããç»åã転åãããæ¹æ³ãé瀺ãã
ãŠããã ãŸãç¹éæ52â89915å·ã«ã¯ãäºæååæç±çº
è²ç©è³ªã®äžæåãšå éåæ§ã¢ãããŒããã€ã¯ãã«
ãã»ã«ã«å°å ¥ãæç±çºè²ç©è³ªã®ããäžæ¹ã®æåãš
ãã®ãã€ã¯ãã«ãã»ã«ãæ··åããåºäœã·ãŒãã«å¡
åžãããã®æå ã·ãŒããç»åæ§é²å ããŠé²å éšã®
ãã€ã¯ãã«ãã»ã«ã硬åãããåŸãå šé¢å ç±ããŠ
æªé²å éšã®ã¿ãçºè²ãããããšã«ããç»åãåŸã
æ¹æ³ãé瀺ãããŠããã æŽã«ãç¹éæ57â124343å·ãå57â179836å·ã
å57â197538å·ã«ã¯ãããã«ååç©ãšå éåéå§
å€ãšè²çŽ ãã¬ã«ãŒãµãŒãå«ããã€ã¯ãã«ãã»ã«ã
å©çšããç»å圢ææ³ãšããŠãé²å åŸå šäœã«å§åã
å ããããšã«ãããå ç±ãå¿ èŠãšããªãè²çŽ ç»å
ã®åœ¢ææ¹æ³ãé瀺ãããŠããã ãŸããç¹å ¬æ54â20852å·ïŒç±³åœç¹èš±ç¬¬3700439
å·ïŒã«ã¯ããã©ãŒã®ã±ãã³ãæå æ§ç©è³ªãšããŠã
ã«ãã»ã«å°å ¥ããŠãå©çšããç»å圢ææ³ãé瀺ã
ããŠããã ãŸããç±³åœç¹èš±ç¬¬3072481å·ã«ã¯ã液äœäžã§ã¯
çè²ãã圢æ ã«å®¹æã«è»¢åããããåºäœã§ããæ
ã«ã¯äžæå æ§ã§ããæå æ§ç©è³ªãã«ãã»ã«å°å ¥
ãããã®ã«ãã»ã«å°å ¥ç©ã®å±€ãç»åæ§é²å ãã
åŸãã«ãã»ã«ãç Žè£ãããŠæº¶åªãèžçºãããããš
ã«ãããç»åã圢æããæ¹æ³ãããããæå æå§
ã«ããç»å圢ææ¹æ³ãé瀺ãããŠããã åè¿°ã®ãã€ã¯ãã«ãã»ã«ãå©çšããç»å圢ææ³
ã¯çš®ã ã®ãã®ãç¥ãããŠããããããããå ±éã
ãŠå ã«å¯Ÿããæ床ãäœããç¹ã«ç·è²å ãèµ€è²å ã«
察ããæ床ãèããäžè¶³ããŠããããŸãããã®æ
床ãäžããããšãããšä¿åå®å®æ§ãäœäžãããšã
ãæ¬ ç¹ãæããŠããã äžæ¹ããã²ã³åéãå ã»ã³ãµãŒãšããŠå©çšãã
ç»å圢ææ³ã§ã¯ããããã³ã³ãã³ã·ãšãã«åçæ
å ææ以å€ã®ãã®ãçš®ã ç¥ãããŠããã äŸãã°è±åœç¹èš±ç¬¬866631å·ã«ã¯ãããã²ã³åé
ã觊åªã«çšããŠãå éåãçŽæ¥èµ·ããããæ¹æ³ã
é瀺ãããŠãããããã®æ¹æ³ã§ã¯ããã²ã³åéã®
å å解ã§çããçæç©ãéåã®è§Šåªãšãªããšèã
ãããŠãããéåžžã®çŸåã«ãã€ãŠããã²ã³åéã
éå ããå Žåçšã®é«æ床ã¯åŸãããŠããªãã ãŸããã«ã®ãŒç¹èš±ç¬¬642477å·ã«ã¯é²å ãããã
ãã²ã³åéç²åãéåžžã®çŸå液ã«ãã€ãŠçŸåãã
åŸãçããéç»åãããã¯æªåå¿ã®ããã²ã³åé
ã觊åªãšããŠéåãèµ·ããããé«ååååç©ãç»
åæ§ã«åœ¢æãããæ¹æ³ãé瀺ãããŠãããããã®
å Žåã«ã¯è€éãªæäœãå¿ èŠãšããã æŽã«ç¹å ¬æ45â11149å·ãå47â20741å·ãå49
â10697å·ãå57â138632å·ãå58â169143å·ã«
ã¯ãé²å ãããããã²ã³åéãéå å€ãçšããŠçŸ
åããéããã®éå å€ãé žåããããšåæã«å ±å
ããããã«ååç©ãéåãéå§ãç»åæ§ã®é«åå
ç©è³ªã圢æããæ¹æ³ãé瀺ãããŠãããããã®æ¹
æ³ã§ã¯æ¶²äœãçšããçŸåå·¥çšãå¿ èŠãšããŠããã ãã®ãããªããã²ã³åéãå ã»ã³ãµãŒãšããŠçš
ããç»å圢ææ³ã¯çš®ã ç¥ãããŠãããã®ããã
ããããããé«æ床ãåŸãããªãã€ãããè€éãª
çŸååŠçå·¥çšãå¿ èŠãšãããªã©ã®æ¬ ç¹ãæããŠã
ãã çºæã®ç®ç æ¬çºæã®ç®çã¯ãé«æ床ã§ãã€çµæå®å®æ§ã«åª
ããæå ææãæäŸããããšã«ãããããã§ãã
çµæå®å®æ§ãšã¯ãç±çŸååŠçåã®æå ææã®ä¿å
ã«ããæé«æ¿åºŠãæäœæ¿åºŠãæ床çã®åçæ§èœã®
å€åãæå³ããã çºæã®é瀺 ãã®ãããªç®çã¯äžèšã®æ¬çºæã«ãã€ãŠéæã
ããã ããªãã¡ãæ¬çºæã¯ãæ¯æäœäžã«å°ãªããšãæ
å æ§ããã²ã³åéä¹³å€ãéå å€ãéåæ§ååç©ã
ãã³è²ç»å圢æç©è³ªãæãããã€ãããã®äžã®å°
ãªããšãéåæ§ååç©ãšè²ç»å圢æç©è³ªãšãåäž
ã®ãã€ã¯ãã«ãã»ã«ã«å°å ¥ãããç¶æ ã§å«æãã
ãæå ææã«ãããŠãåæ§é²å ã«ããæœåã圢æ
ããããã²ã³åéä¹³å€ãå¢æè²çŽ ã®ååšäžã§åœ¢æ
ãããããã²ã³åéç²åãå«ãããšãç¹åŸŽãšãã
æå ææã§ããã çºæã®å ·äœçæ§æ 以äžãæ¬çºæã®å ·äœçæ§æã«ã€ããŠè©³çŽ°ã«èª¬æ
ããã æ¬çºæã®æå ææã¯ãæ¯æäœäžã«å°ãªããšãæ
å æ§ããã²ã³åéä¹³å€ãéå å€ãéåæ§ååç©ã
ãã³è²ç»å圢æç©è³ªãæãããã€ãããã®äžã®å°
ãªããšãéåæ§ååç©ãšè²ç»å圢æç©è³ªãšãåäž
ã®ãã€ã¯ãã«ãã»ã«ã«å°å ¥ãããŠããããããŠã
ããã²ã³åéä¹³å€ã¯ãåæ§é²å ã«ããæœåã圢æ
ãããã®ã§ãå¢æè²çŽ ã®ååšäžã§åœ¢æããããã
ã²ã³åéç²åãå«ãã æ¬çºæã®æå ææã¯æå æ§ããã²ã³åéãå ã»
ã³ãµãŒãšããé²å ã«ããçããããã²ã³åéã®æœ
åæ žã觊åªãšãªã€ãŠéå¡©ãšéå å€ãšã®é žåéå å
å¿ãèµ·ããããã®éçšã§çããã©ãžã«ã«äžéäœã
éå§å€ãšããŠéååå¿ãè¡ãªãããããããã¯ç¬¬
ïŒã®éå å€ãšéå¡©ãšãé žåéå åå¿ãèµ·ãããåŸ
ãã®çæç©ãããã«ä»ã®ååç©ãšåå¿ãããããš
ã«ãã€ãŠçæããã©ãžã«ã«ãéå§å€ãšããŠéåå
å¿ãè¡ãªãããã®ã§ããããã®äžé£ã®åå¿ãå ç±
ãããã¯åäžé²å ã«ããèããä¿é²ãããããšã¯
åŸæ¥ã®ç¥èŠããã¯äºæ³ãåŸãªãã€ãããšã§ããã
ç¹ã«ãçŸå液ã䜿çšããªã也åŒç³»ã§éå¡©ãšéå å€
ãšã®åå¿ã«ããã©ãžã«ã«äžéäœãçºçããããšã¯
å šãæ°ããç¥èŠã§ããã æ¬çºæã§ã¯äœ¿çšããæå æ§ããã²ã³åéã®çš®é¡
ã«ããé²å éšãæªé²å éšã®ãããã«ã察å¿ããŠé«
ååååç©ãçæãããããšãå¯èœã§ãããé«å
åååç©ãçæããéšåïŒãã€ã¯ãã«ãã»ã«ïŒã§
ã¯ãçæããŠããªãéšåïŒãã€ã¯ãã«ãã»ã«ïŒã«
æ¯èŒããŠãèå§æ§ãå¢ãããã®çµæãé«åååå
ç©ãçæããŠããªãéšåãå å§ã«ããååææã«
転åãããããšãªã©ã«ããè²ç»å圢æç©è³ªãå©çš
ããè²åã圢æããããšãã§ããããããã€ãŠæ¬
çºæã§ã¯äœ¿çšããæå æ§ããã²ã³åéã®çš®é¡ãã
ãã¯æ¡çšããè²å圢æéçšã«ãã€ãŠãåç»ã«å¯Ÿã
ãŠãã¬åç»åãããžåç»åãèªç±ã«äœãããšãã§
ããå Žåã«ãã€ãŠã¯ãã¬ããžäž¡ç»åãåæã«äœã
ããšãã§ããã äŸãã°ãé«ååååç©ãçæããŠããªãéšåã
転åãããŠè²ç»åãåŸãå Žåã«ã¯ãéåžžã®ãã¬å
ããã²ã³åéä¹³å€ãçšãããšåç»ã«å¯ŸããŠããžå
ã®ç»åãåŸãããšãã§ããäžæ¹ããã¬åç»åã圢
æãããããã«ã¯ç±³åœç¹èš±ç¬¬2592250å·ãå第
3206313å·ãå第3367778å·ãå第3447927å·ã«èš
èŒã®å éšç»åããã²ã³åéä¹³å€ãããŸãç±³åœç¹èš±
第2996382å·ã«èšèŒãããŠãããããªè¡šé¢ç»åã
ãã²ã³åéä¹³å€ãšå éšç»åããã²ã³åéä¹³å€ãšã®
æ··åç©ã䜿çšããããšãã§ããã æ¬çºæã«ãããŠæžè²æ³ã®ã€ãšããŒãããŒã³ã¿ã
ã·ã¢ã³ã®ïŒåè²ãçšããŠãè²åºŠå³å ã®åºç¯å²ã®è²
ãåŸãããã«ã¯ãæå ææã¯ãå°ãªããšãïŒçš®ã®
ããããç°ãªãã¹ãã¯ãã«é åã«æå æ§ãæã€ã
ãã²ã³åéä¹³å€ãæããå¿ èŠããããäºãã«ç°ãª
ãã¹ãã¯ãã«é åã«æå æ§ãæã€å°ãªããšãïŒã€
ã®æå æ§ããã²ã³åéä¹³å€ã®ä»£è¡šçãªçµåããšã
ãŠã¯ãéææ§ä¹³å€ãç·ææ§ä¹³å€ããã³èµ€ææ§ä¹³å€
ã®çµåããç·ææ§ä¹³å€ãèµ€ææ§ä¹³å€ããã³èµ€å€å
æå æ§ä¹³å€ã®çµåããéææ§ä¹³å€ãç·ææ§ä¹³å€ã
ãã³èµ€å€å æå æ§ä¹³å€ã®çµåããéææ§ä¹³å€ãèµ€
ææ§ä¹³å€ããã³èµ€å€å æå æ§ä¹³å€ãªã©ãããããª
ãããã§èµ€å€å æå æ§ä¹³å€ãšã¯700nm以äžãç¹ã«
740nm以äžã®å ã«å¯ŸããŠæå æ§ãæã€ä¹³å€ãã
ãã äŸãã°ãéææ§ä¹³å€ãç·ææ§ä¹³å€ããã³èµ€ææ§
ä¹³å€ã®çµåããã䜿çšããå Žåã¯ãéæå æ§ã®ã
ã€ã¯ãã«ãã»ã«ãã€ãšããŒç»å圢æç©è³ªãå«ã¿ã
ç·æå æ§ãã€ã¯ãã«ãã»ã«ãããŒã³ã¿ç»å圢æç©
質ãå«ã¿èµ€æå æ§ã®ãã€ã¯ãã«ãã»ã«ãã·ã¢ã³ç»
å圢æç©è³ªãå«ãããã«ããŠããã°ããã ãã®ããã«ãã€ã¯ãã«ãã»ã«ã䜿çšããããšã«
ããã€ãšããŒãããŒã³ã¿ãã·ã¢ã³ã®ç»å圢æç©è³ª
ãåé¢ããŠåäžã®æå èŠçŽ äžã«å«ãŸããããšãå¯
èœãšãªããããã«ãã簡䟿ãªæäœã§ã«ã©ãŒç»åã
圢æãããããšãã§ããã åè¿°ã®å ¬ç¥æè¡ã§ã«ã©ãŒç»åã圢æãããããš
ãããšã (1)ç·è²å ãèµ€è²å ã«å¯Ÿããæ床ããªãã(2)éè²
å ã«å¯ŸããŠãæ床ãäœãã(3)çµæå®å®æ§ãä¹ã
ãã(4)è€éãªæäœãå¿ èŠãšããã(5)液äœãçšãã
åŠçå·¥çšãå¿ èŠãšããããªã©ã®ããããã®æ¬ ç¹ã
åé¿ããããšãã§ããªãããæ¬çºæã®æå ææã§
ã¯ãããã®åé¡ããã¹ãŠè§£æ±ºããããšãã§ããã
åŸã€ãŠãæ¬çºæã®æå ææã¯ç¹ã«ã«ã©ãŒç»å圢æ
ã«çšãããšå€§ããªå¹æãåŸãããã æ¬çºæã«ãããæå èŠçŽ ããã³ååèŠçŽ ã®æ§æ
ãšããŠã¯ã以äžã®äŸããããããšãã§ããã ããã§ããæå èŠçŽ ãšã¯ãæå æ§ããã²ã³å
éãéå å€ãéåæ§ååç©ããã³è²ç»å圢æç©è³ª
ãå«ã¿ããã€ãããã®äžã®å°ãªããšãéåæ§åå
ç©ãšè²ç»å圢æç©è³ªãåäžã®ãã€ã¯ãã«ãã»ã«ã«
å°å ¥ãããŠããèŠçŽ ãæå³ããäžæ¹ååèŠçŽ ãš
ã¯ããã®æå èŠçŽ ããæŸåºãããè²ç»å圢æç©è³ª
ããåºå®ããããšãšãã«è²ç»åã圢æããèŠçŽ ã
æå³ããããããã®èŠçŽ ã®æ§æãšç»å圢æã®æ¹æ³
ã以äžã«è¿°ã¹ãããæ¬çºæã®æå ææã䜿ã€ãå®
æœã®æ æ§ã¯ããã«éå®ããããã®ã§ã¯ãªãã (1) è²ç»å圢æç©è³ªãããèªèº«çè²ããææãŸã
ã¯é¡æã§ããå Žåã (a) æå èŠçŽ ãšååèŠçŽ ãå¥ã ã®æ¯æäœäžã«å¡
èšãããŠãåã ãæå ææãšååææã圢æ
ãããã®æå ææãåæ§é²å åŸãå ç±ãªãã
åäžé²å ããåŸãååææãšåãããŠå å§ã
ãããšã«ããååææäžã«è²ç»åã圢æãã
ãã (b) æ¯æäœã®äžã«æå èŠçŽ ãå¡èšãããã®äžã«
å åå°å±€ãå¡èšããããã«ãã®äžã«ååèŠçŽ
ãå¡èšããããã®æå ææãæ¯æäœã®åŽãã
åæ§é²å ããå ç±ãªããåäžé²å ããåŸãå
å§ã«ãããè²ç»å圢æç©è³ªãååèŠçŽ ã«åæ§
ã«ç§»åãããååèŠçŽ äžã«è²ç»åã圢æã
ãã (2) è²ç»å圢æç©è³ªãããèªèº«ç¡è²ãªããæ·¡è²ã§
ãããã ä»ã®ãšãã«ã®ãŒãå ãããšçºè²ããå Žåãã
ã®å Žåã®æ§æã¯åèš(1)ã®(a)ããã³(b)ãšåãæ æ§
ãèãããããããããã®äŸã§ãè²ç»å圢æç©
質ãçºè²ãããããã®ãšãã«ã®ãŒãå ããå·¥çš
ãå¿ èŠãšãªããããããã®çºè²ã(1)ã®å ç±ãŸã
ã¯é²å ãŸãã¯å å§æã«åæã«èµ·ããå Žåã«ã¯ç¹
å¥ã®å·¥çšãå ããå¿ èŠã¯ãªãã (3) è²ç»å圢æç©è³ªïŒãã®å Žåçºè²å€ãšåŒã¶ïŒ
ããããèªèº«ç¡è²ãªããã¯æ·¡è²ã§ããããä»ã®
æåïŒé¡è²å€ãšåŒã¶ïŒãšæ¥è§Šããããšã«ããçº
è²ããå Žåã (a) åèš(1)ã®(a)ãšåæ§ã®æ æ§ã§ãã€ååèŠçŽ äž
ã«é¡è²å€ãå«æãããã°ãå å§ã«ããè²ç»å
圢æç©è³ªãšé¡è²å€ãæ¥è§Šããè²ç»åã圢æã
ãã (b) åèš(1)ã®(b)ãšåæ§ã®æ æ§ã§ãã€ãååèŠçŽ
äžã«é¡è²å€ãå«æãããã°ãå å§ã«ããè²ç»
å圢æç©è³ªãšãé¡è²å€ãæ¥è§Šããè²ç»åã圢
æããã (c) æå èŠçŽ ãšååèŠçŽ ãé£æ¥ãããŠæ¯æäœäž
ã«å¡èšãããããããã¯ãã®ïŒã€ã®èŠçŽ ã®æ
åãæ··åããŠå¡èšããæ æ§ãããããã®ãã
ãã®å Žåãé¡è²å€ã¯ååèŠçŽ ã®æ§ææåãšã
ãŠçšãããšãã®æå ææïŒååææãå Œã
ãïŒã«åæ§é²å ãããŠããå ç±ãããã¯åäž
é²å ããåŸå å§ããããšã«ãã€ãŠç Žå£ããã
ã€ã¯ãã«ãã»ã«ã®è¿åã§è²ç»å圢æç©è³ªãšé¡
è²å€ãæ¥è§ŠããŠçºè²ããè²ç»åã圢æããã
ãã®å Žåã«ã¯çºè²ããªãéšåã®è²ç»å圢æç©
質ããå®è³ªçã«ç¡è²ã§ãããããçŽæ¥è²ç»å
ãšããŠèŠèŠçã«ã¿ãããšãã§ããã æ¬çºæã®æå ææã«ãããããã²ã³åéä¹³å€
ã¯ãåè¿°ã®ããã«ãå¢æè²çŽ ã®ååšäžã§åœ¢æãã
ãããã²ã³åéç²åãå«ãã ãã®ãããªç²åãå«ãããã²ã³åéä¹³å€ã䜿çš
ããããšã«ãããæå ææã®ä¿åäžã«æ床ãå€å
ããåœåèšèšããå質ãšã¯å šãç°ãªããã®ã«ãªã
æå ææãšããŠã®åå䟡å€ãèŽåœçã«æãªããã
ãšããæ¬ é¥ã解決ããããããªãã¡çä¿åæ§ãæ Œ
段ãšè¯åããããŸãããããšåæã«åææ床ã®äž
æã芳枬ãããã ããã¯ãæå ææäžã®éåæ§ååç©ããã³è²ç»
å圢æç©è³ªããä¿åäžã«ãåŸæ¥æ³ã§è²å¢æããå Ž
åããã²ã³åéè¡šé¢ã«åžçããŠããå¢æè²çŽ ãè±
çãããããããŸãåŸæ¥æ³ã§ã¯æåããããçšåºŠ
ã®éã®å¢æè²çŽ ãè±çããŠãããšæšå®ããããã
ãã®ãããªçŸè±¡ãé²æ¢ããããããšèããããã å¢æè²çŽ ã¯éåžžã¡ãã³è²çŽ ãçšããããããã
ãã«ã¯ã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²çŽ ãè€åã·
ã¢ãã³è²çŽ ãè€åã¡ãã·ã¢ãã³è²çŽ ãããããŒã©
ãŒã·ã¢ãã³è²çŽ ãããã·ã¢ãã³è²çŽ ãã¹ããªã«è²
çŽ ããã³ãããªããœããŒã«è²çŽ ãå«æããããç¹
ã«æçšãªè²çŽ ã¯ãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²
çŽ ãããã³è€åã¡ãã·ã¢ãã³è²çŽ ã«å±ããè²çŽ ã§
ããããããã®è²çŽ é¡ã«ã¯ãå¡©åºæ§ç°èšç°æ žãšã
ãŠã·ã¢ãã³è²çŽ é¡ã«éåžžå©çšãããæ žã®ãããã
ãé©çšã§ãããããªãã¡ããããªã³æ žããªããµãŸ
ãªã³æ žããã¢ãŸãªã³æ žããããŒã«æ žããªããµãŸãŒ
ã«æ žããã¢ãŸãŒã«æ žãã»ã¬ããŸãŒã«æ žãã€ãããŸ
ãŒã«æ žãããã©ãŸãŒã«æ žãããªãžã³æ žãªã©ïŒãã
ãã®æ žã«èç°åŒçåæ°ŽçŽ ç°ãèåããæ žïŒããã³
ãããã®æ žã«è³éŠæçåæ°ŽçŽ ç°ãèåããæ žãå³
ã¡ãã€ã³ãã¬ãã³æ žããã³ãºã€ã³ãã¬ãã³æ žãã€
ã³ããŒã«æ žããã³ãºãªããµãŸãŒã«æ žãããããªã
ãµãŸãŒã«æ žããã³ãŸãã¢ãŸãŒã«æ žãããããã¢ãŸ
ãŒã«æ žããã³ãŸã»ã¬ããŸãŒã«æ žããã³ãºã€ãããŸ
ãŒã«æ žããããªã³æ žãªã©ãé©çšã§ããããããã®
æ žã¯ççŽ ååäžã«çœ®æãããŠããŠãããã ã¡ãã·ã¢ãã³è²çŽ ãŸãã¯è€åã¡ãã·ã¢ãã³è²çŽ
ã«ã¯ã±ãã¡ãã¬ã³æ§é ãæããæ žãšããŠããã©ãŸ
ãªã³âïŒâãªã³æ žãããªããã³ãã€ã³æ žãïŒâã
ãªãªããµãŸãªãžã³âïŒïŒïŒâãžãªã³æ žããã¢ãŸãª
ãžã³âïŒïŒïŒâãžãªã³æ žãããŒããã³æ žãããªã
ã«ãããŒã«é žæ žãªã©ã®ïŒãïŒå¡ç°èšç°æ žãé©çšã
ãããšãã§ããã æ¬çºæã«ãããŠæçšãªå¢æè²çŽ ã®å ·äœäŸãšããŠ
ã¯æ¬¡ã®äžè¬åŒ(A)ã(H)ã(J)ã(U)ã(W)ã(Y)ã§è¡šããã
ãè²çŽ ããããããã äžè¬åŒ(A) åŒäžZ1ïŒZ2ã¯ã·ã¢ãã³è²çŽ ã«éåžžçšããããã
ããç°æ žãç¹ã«ãã¢ãŸãŒã«æ žããã¢ãŸãªã³æ žãã
ã³ãŸãã¢ãŸãŒã«æ žãããããã¢ãŸãŒã«æ žããªããµ
ãŸãŒã«æ žããªããµãŸãªã³æ žããã³ãŸãªããµãŸãŒã«
æ žãããããªããµãŸãŒã«æ žãããã©ãŸãŒã«æ žãã
ãªãžã³æ žããããªã³æ žãã€ãããŸãªã³æ žãã€ãã
ãŸãŒã«æ žããã³ãŸã€ãããŸãŒã«æ žããããã€ãã
ãŸãŒã«æ žãã»ã¬ããŸãªã³æ žãã»ã¬ããŸãŒã«æ žãã
ã³ãŸã»ã¬ããŸãŒã«æ žããããã»ã¬ããŸãŒã«æ žãŸã
ã¯ã€ã³ãã¬ãã³æ žãªã©ãå®æããã«å¿ èŠãªåå矀
ãè¡šããããããã®æ žã¯ãã¡ãã«åºãªã©ã®äœçŽã¢
ã«ãã«åºãããã²ã³ååãããšãã«åºããããã
ã·ã«åºãççŽ æ°ïŒãïŒã®ã¢ã«ã³ãã·åºãã«ã«ãã
ã·ã«åºãã¢ã«ã³ãã·ã«ã«ã«ããã«åºãã¢ã«ãã«ã¹
ã«ãã¢ã¢ã€ã«åºãã¢ã«ãã«ã«ã«ãã¢ã€ã«åºãã¢ã»
ãã«åºãã¢ã»ããã·åºãã·ã¢ãåºãããªã¯ããã¡
ãã«åºãããªãã«ãªãã¡ãã«åºããããåºãªã©ã«
ãã€ãŠçœ®æãããŠããŠãããã L1ãŸãã¯L2ã¯ã¡ãã³åºã眮æã¡ãã³åºãè¡šã
ãã眮æã¡ãã³åºãšããŠã¯ãã¡ãã«åºããšãã«åº
çã®äœçŽã¢ã«ãã«åºãããšãã«åºã眮æããšãã«
åºãã¡ããã·åºããšããã·åºçã«ãã€ãŠçœ®æãã
ãã¡ãã³åºãªã©ãããã R1ãšR2ã¯ççŽ æ°ãïŒãïŒã®ã¢ã«ãã«åºïŒã«ã«
ããã·ã«åºããã€çœ®æã¢ã«ãã«åºïŒÎ³âã¹ã«ãã
ããã«åºãÎŽâã¹ã«ãããã«åºãïŒâïŒïŒâã¹ã«
ãããããã·ïŒãšãã«åºãïŒâãïŒâïŒïŒâã¹ã«ã
ããããã·ïŒãšããã·ããšãã«åºãïŒâãããã
ã·ã»ã¹ã«ããããã«åºãªã©ã®ã¹ã«ãåºããã€çœ®æ
ã¢ã«ãã«åºïŒã¢ãªã«ïŒallylïŒåºããã®ä»ã®éåžž
ã·ã¢ãã³è²çŽ ã®ïŒ®â眮æåºã«çšããããŠãã眮æ
ã¢ã«ãã«åºãè¡šãããm1ã¯ïŒïŒïŒãŸãã¯ïŒãè¡š
ããã X1 -ã¯æ²çŽ ã€ãªã³ãèçŽ ã€ãªã³ãïœâãã«ãšã³
ã¹ã«ãã³é žã€ãªã³ãéå¡©çŽ é žã€ãªã³ãªã©ã®éåžžã·
ã¢ãã³è²çŽ ã«çšããããé žã¢ããªã³åºãè¡šããã
ïœã¯ïŒãŸãã¯ïŒãè¡šããããã¿ã€ã³æ§é ããšããš
ãã¯ïœã¯ïŒã§ããã äžè¬åŒ(B) åŒäžãZ3ã¯ã·ã¢ãã³è²çŽ ã«éåžžçšããããäžè¬
åŒ(A)ã§ç€ºãããããªãããç°æ žãè¡šãããZ4ã¯é
åžžã¡ãã·ã¢ãã³è²çŽ ã«çšããããŠããã±ãããã
æ žã圢æããã«å¿ èŠãªåå矀ãè¡šãããäŸãã°ã
ãŒããã³ãããªããã³ãã€ã³ããªãã·ã€ã³ããŒ
ã«ãïŒâããªãªããµãŸãªãžã³ãžãªã³ãïŒïŒïŒâã€
ã³ãã³ãžãªã³çã®æ žã§ãããL3ãšL4ã¯L1ãšL2ãš
åæ矩ã§ãããR3ã¯R1ãŸãã¯R2ãšåæ矩ã§ããã m2ã¯ïŒïŒïŒïŒïŒãŸãã¯ïŒãè¡šããã äžè¬åŒ(C) åŒäžãZ5ã¯ïŒâãããªã³æ žãïŒâãããªã³æ žã
ãã³ããã¢ãŸãŒã«æ žããã³ããªããµãŸãŒã«æ žãã
ãããã¢ãŸãŒã«æ žããããã»ã¬ããŸãŒã«æ žããã
ããªããµãŸãŒã«æ žããã³ãŸã»ã¬ããŸãŒã«æ žãã€ã³
ãã¬ãã³æ žãå®æããã«å¿ èŠãªåå矀ãè¡šããã
p1ã¯ïŒãŸãã¯ïŒãè¡šãããR4ã¯R1ãŸãã¯R2ãšå
æ矩ãL5ãšL6ã¯ãL3ãŸãã¯L4ãšåæ矩ãè¡šããã
m3ã¯ïŒãŸãã¯ïŒãè¡šãããL7ãšL3ã¯L1ãŸãã¯L2
ãšåæ矩ãè¡šãããZ6ã¯Z4ãšåæ矩ãè¡šããã
Y1ãšY2ã¯é žçŽ ååãç¡«é»ååãã»ã¬ã³ååãŸã
ã¯ïŒïŒ®âR5ïŒR5ã¯ã¡ãã«ããšãã«ããããã«åºãª
ã©ççŽ æ°ïŒä»¥äžã®ã¢ã«ãã«åºãã¢ãªã«ïŒallylïŒ
åºãè¡šããïŒã§ãã®äžã®å°ãªããšãäžã€ã¯ïŒïŒ®â
R5åºã§ããã w1ã¯ïŒãŸãã¯ïŒãè¡šããã äžè¬åŒ(D) åŒäžãZ7ã¯Z5ãšãZ8ã¯Z6ãšãR6ã¯R1ãŸãã¯R2
ãšp2ã¯p1ãšåæ矩ãè¡šãããY3ãšY4ã¯Y1ãšY2ãš
åæ矩ãè¡šãããw2ã¯w1ãšåæ矩ã§ããã äžè¬åŒ(E) åŒäžãR7ãšR8ã¯R1ãšãZ9ãšZ10ã¯Z5ãšãp3ïŒp4
ã¯p1ãšãL9ãL13ã¯L1ãšãX2ã¯X1ãšãn2ã¯n1ãšå
æ矩ãè¡šãããY5ãšY6ã¯ãY1ãšåæ矩ãè¡šã
ããp5ïŒm4ã¯ïŒãŸãã¯ïŒãè¡šããã w3ã¯w1ãšåæ矩ã§ããã äžè¬åŒ(F) åŒäžãZ11ãšZ12ã¯ç¡çœ®æãè¥ããã¯ç¹ã«ã¡ãã«
åºãªã©ã®äœçŽã¢ã«ãã«åºãããã²ã³ååãããšã
ã«åºãããããã·ã«åºãççŽ æ°ïŒãïŒã®ã¢ã«ã³ã
ã·åºãã«ã«ããã·ã«åºãã¢ã«ã³ãã·ã«ã«ããã«
åºãã¢ã«ãã«ã¹ã«ãã¢ã¢ã€ã«åºãã¢ã«ãã«ã«ã«ã
ã¢ã€ã«åºãã¢ã»ãã«åºãã·ã¢ãåºãããªã¯ããã¡
ãã«åºãããªãã«ãªãã¡ãã«åºããããåºãªã©ã«
ãã€ãŠçœ®æããããã³ãŒã³ç°ãå®æããã«å¿ èŠãª
åå矀ããŸãã¯ããã¿ã¬ã³ç°ã圢æããã«å¿ èŠãª
åå矀ãè¡šãããR9ãšR10ã¯R1ãšåæ矩ãè¡šã
ããY7ãšY8ã¯é žçŽ ååãç¡«é»ååãã»ã¬ã³ååã ïŒR11ïŒR12ã¯ã¡ãã«åºãŸãã¯ãšãã«åºïŒãïŒïŒ®
âR13ïŒR13ã¯ã¢ã«ãã«åºãéåžžã·ã¢ãã³è²çŽ ã®ïŒ®
â眮æåºã«çšãããã眮æã¢ã«ãã«åºãŸãã¯ã¢ãª
ã«ïŒallylïŒåºãè¡šããïŒãŸãã¯âCHïŒCHâã
è¡šãããY9ã¯ïŒãŸãã¯ïŒå¡ã®è€çŽ ç°ã圢æãã
ã«å¿ èŠãªåå矀ãè¡šããã äžè¬åŒ(G) Z13ïŒZ14ã¯Z11ãšãR14ãšR15ã¯R1ãšãY10ïŒY11
ã¯Y7ãšåæ矩ãè¡šãããY12ã¯ïŒãŸãã¯ïŒå¡ã®ç
çŽ ç°ã圢æããã«å¿ èŠãªåå矀ãè¡šãããX3ã¯
X1ãšãn3ã¯n1ãšåæ矩ãè¡šããã äžè¬åŒ(H) äžè¬åŒ(J) A1ïŒâL16ïŒL17ïŒn6-1ââââL18ïŒA2ïŒX4 -ïŒo4-1 X4ãn4ã¯X1ãn1ãšåæ矩ãè¡šããã p6ã¯ïŒãŸãã¯ïŒãm5ïŒm6ã¯ïŒãŸãã¯ïŒãL14ã
L18ã¯L1ãšåæ矩ãè¡šãããZ15ã¯Z1ãšåæ矩ãè¡š
ãããp6ã¯äžè¬åŒ(C)ã®p1ãšåæ矩ã§ããã ããã«ãA1ãšããŠã¯ã
ãå°å ¥ãããã€ã¯ãã«ãã»ã«ãå«æããæå ææ
ã«é¢ãããããã«è©³ããã¯æå æ§ããã²ã³åéã
ã»ã³ãµãŒãšãã掻æ§ç·ç §å°æã«ãã®ããã²ã³åé
äžã«åœ¢æãããåæ§ã®æœåãå©çšããŠãåæ§ã«é«
ååååç©ãçæãããå ±åããè²ç»å圢æç©è³ª
ãäžååãããæå ææã«é¢ããã å è¡æè¡ãšãã®åé¡ç¹ ãã€ã¯ãã«ãã»ã«ãå©çšããèšé²ææãšããŠã¯
çš®ã ã®ãã®ãç¥ãããŠããã äŸãã°ãç¹å ¬æ42â14344å·ïŒç±³åœç¹èš±ç¬¬
3219446å·ïŒã«ã¯ãå ãç §å°ãããšéæµåæ§ã«ãª
ãå€ãã®æµåäœå°æ»Žãæããææã·ãŒãã«ç»åæ§
ã®é²å ããããããååã·ãŒããžéããŠã·ãŒãå š
äœã«å§åãå ããããšã«ããããã®ååã·ãŒãäž
ã«é²å ã«å¿ããç»åã転åãããæ¹æ³ãé瀺ãã
ãŠããã ãŸãç¹éæ52â89915å·ã«ã¯ãäºæååæç±çº
è²ç©è³ªã®äžæåãšå éåæ§ã¢ãããŒããã€ã¯ãã«
ãã»ã«ã«å°å ¥ãæç±çºè²ç©è³ªã®ããäžæ¹ã®æåãš
ãã®ãã€ã¯ãã«ãã»ã«ãæ··åããåºäœã·ãŒãã«å¡
åžãããã®æå ã·ãŒããç»åæ§é²å ããŠé²å éšã®
ãã€ã¯ãã«ãã»ã«ã硬åãããåŸãå šé¢å ç±ããŠ
æªé²å éšã®ã¿ãçºè²ãããããšã«ããç»åãåŸã
æ¹æ³ãé瀺ãããŠããã æŽã«ãç¹éæ57â124343å·ãå57â179836å·ã
å57â197538å·ã«ã¯ãããã«ååç©ãšå éåéå§
å€ãšè²çŽ ãã¬ã«ãŒãµãŒãå«ããã€ã¯ãã«ãã»ã«ã
å©çšããç»å圢ææ³ãšããŠãé²å åŸå šäœã«å§åã
å ããããšã«ãããå ç±ãå¿ èŠãšããªãè²çŽ ç»å
ã®åœ¢ææ¹æ³ãé瀺ãããŠããã ãŸããç¹å ¬æ54â20852å·ïŒç±³åœç¹èš±ç¬¬3700439
å·ïŒã«ã¯ããã©ãŒã®ã±ãã³ãæå æ§ç©è³ªãšããŠã
ã«ãã»ã«å°å ¥ããŠãå©çšããç»å圢ææ³ãé瀺ã
ããŠããã ãŸããç±³åœç¹èš±ç¬¬3072481å·ã«ã¯ã液äœäžã§ã¯
çè²ãã圢æ ã«å®¹æã«è»¢åããããåºäœã§ããæ
ã«ã¯äžæå æ§ã§ããæå æ§ç©è³ªãã«ãã»ã«å°å ¥
ãããã®ã«ãã»ã«å°å ¥ç©ã®å±€ãç»åæ§é²å ãã
åŸãã«ãã»ã«ãç Žè£ãããŠæº¶åªãèžçºãããããš
ã«ãããç»åã圢æããæ¹æ³ãããããæå æå§
ã«ããç»å圢ææ¹æ³ãé瀺ãããŠããã åè¿°ã®ãã€ã¯ãã«ãã»ã«ãå©çšããç»å圢ææ³
ã¯çš®ã ã®ãã®ãç¥ãããŠããããããããå ±éã
ãŠå ã«å¯Ÿããæ床ãäœããç¹ã«ç·è²å ãèµ€è²å ã«
察ããæ床ãèããäžè¶³ããŠããããŸãããã®æ
床ãäžããããšãããšä¿åå®å®æ§ãäœäžãããšã
ãæ¬ ç¹ãæããŠããã äžæ¹ããã²ã³åéãå ã»ã³ãµãŒãšããŠå©çšãã
ç»å圢ææ³ã§ã¯ããããã³ã³ãã³ã·ãšãã«åçæ
å ææ以å€ã®ãã®ãçš®ã ç¥ãããŠããã äŸãã°è±åœç¹èš±ç¬¬866631å·ã«ã¯ãããã²ã³åé
ã觊åªã«çšããŠãå éåãçŽæ¥èµ·ããããæ¹æ³ã
é瀺ãããŠãããããã®æ¹æ³ã§ã¯ããã²ã³åéã®
å å解ã§çããçæç©ãéåã®è§Šåªãšãªããšèã
ãããŠãããéåžžã®çŸåã«ãã€ãŠããã²ã³åéã
éå ããå Žåçšã®é«æ床ã¯åŸãããŠããªãã ãŸããã«ã®ãŒç¹èš±ç¬¬642477å·ã«ã¯é²å ãããã
ãã²ã³åéç²åãéåžžã®çŸå液ã«ãã€ãŠçŸåãã
åŸãçããéç»åãããã¯æªåå¿ã®ããã²ã³åé
ã觊åªãšããŠéåãèµ·ããããé«ååååç©ãç»
åæ§ã«åœ¢æãããæ¹æ³ãé瀺ãããŠãããããã®
å Žåã«ã¯è€éãªæäœãå¿ èŠãšããã æŽã«ç¹å ¬æ45â11149å·ãå47â20741å·ãå49
â10697å·ãå57â138632å·ãå58â169143å·ã«
ã¯ãé²å ãããããã²ã³åéãéå å€ãçšããŠçŸ
åããéããã®éå å€ãé žåããããšåæã«å ±å
ããããã«ååç©ãéåãéå§ãç»åæ§ã®é«åå
ç©è³ªã圢æããæ¹æ³ãé瀺ãããŠãããããã®æ¹
æ³ã§ã¯æ¶²äœãçšããçŸåå·¥çšãå¿ èŠãšããŠããã ãã®ãããªããã²ã³åéãå ã»ã³ãµãŒãšããŠçš
ããç»å圢ææ³ã¯çš®ã ç¥ãããŠãããã®ããã
ããããããé«æ床ãåŸãããªãã€ãããè€éãª
çŸååŠçå·¥çšãå¿ èŠãšãããªã©ã®æ¬ ç¹ãæããŠã
ãã çºæã®ç®ç æ¬çºæã®ç®çã¯ãé«æ床ã§ãã€çµæå®å®æ§ã«åª
ããæå ææãæäŸããããšã«ãããããã§ãã
çµæå®å®æ§ãšã¯ãç±çŸååŠçåã®æå ææã®ä¿å
ã«ããæé«æ¿åºŠãæäœæ¿åºŠãæ床çã®åçæ§èœã®
å€åãæå³ããã çºæã®é瀺 ãã®ãããªç®çã¯äžèšã®æ¬çºæã«ãã€ãŠéæã
ããã ããªãã¡ãæ¬çºæã¯ãæ¯æäœäžã«å°ãªããšãæ
å æ§ããã²ã³åéä¹³å€ãéå å€ãéåæ§ååç©ã
ãã³è²ç»å圢æç©è³ªãæãããã€ãããã®äžã®å°
ãªããšãéåæ§ååç©ãšè²ç»å圢æç©è³ªãšãåäž
ã®ãã€ã¯ãã«ãã»ã«ã«å°å ¥ãããç¶æ ã§å«æãã
ãæå ææã«ãããŠãåæ§é²å ã«ããæœåã圢æ
ããããã²ã³åéä¹³å€ãå¢æè²çŽ ã®ååšäžã§åœ¢æ
ãããããã²ã³åéç²åãå«ãããšãç¹åŸŽãšãã
æå ææã§ããã çºæã®å ·äœçæ§æ 以äžãæ¬çºæã®å ·äœçæ§æã«ã€ããŠè©³çŽ°ã«èª¬æ
ããã æ¬çºæã®æå ææã¯ãæ¯æäœäžã«å°ãªããšãæ
å æ§ããã²ã³åéä¹³å€ãéå å€ãéåæ§ååç©ã
ãã³è²ç»å圢æç©è³ªãæãããã€ãããã®äžã®å°
ãªããšãéåæ§ååç©ãšè²ç»å圢æç©è³ªãšãåäž
ã®ãã€ã¯ãã«ãã»ã«ã«å°å ¥ãããŠããããããŠã
ããã²ã³åéä¹³å€ã¯ãåæ§é²å ã«ããæœåã圢æ
ãããã®ã§ãå¢æè²çŽ ã®ååšäžã§åœ¢æããããã
ã²ã³åéç²åãå«ãã æ¬çºæã®æå ææã¯æå æ§ããã²ã³åéãå ã»
ã³ãµãŒãšããé²å ã«ããçããããã²ã³åéã®æœ
åæ žã觊åªãšãªã€ãŠéå¡©ãšéå å€ãšã®é žåéå å
å¿ãèµ·ããããã®éçšã§çããã©ãžã«ã«äžéäœã
éå§å€ãšããŠéååå¿ãè¡ãªãããããããã¯ç¬¬
ïŒã®éå å€ãšéå¡©ãšãé žåéå åå¿ãèµ·ãããåŸ
ãã®çæç©ãããã«ä»ã®ååç©ãšåå¿ãããããš
ã«ãã€ãŠçæããã©ãžã«ã«ãéå§å€ãšããŠéåå
å¿ãè¡ãªãããã®ã§ããããã®äžé£ã®åå¿ãå ç±
ãããã¯åäžé²å ã«ããèããä¿é²ãããããšã¯
åŸæ¥ã®ç¥èŠããã¯äºæ³ãåŸãªãã€ãããšã§ããã
ç¹ã«ãçŸå液ã䜿çšããªã也åŒç³»ã§éå¡©ãšéå å€
ãšã®åå¿ã«ããã©ãžã«ã«äžéäœãçºçããããšã¯
å šãæ°ããç¥èŠã§ããã æ¬çºæã§ã¯äœ¿çšããæå æ§ããã²ã³åéã®çš®é¡
ã«ããé²å éšãæªé²å éšã®ãããã«ã察å¿ããŠé«
ååååç©ãçæãããããšãå¯èœã§ãããé«å
åååç©ãçæããéšåïŒãã€ã¯ãã«ãã»ã«ïŒã§
ã¯ãçæããŠããªãéšåïŒãã€ã¯ãã«ãã»ã«ïŒã«
æ¯èŒããŠãèå§æ§ãå¢ãããã®çµæãé«åååå
ç©ãçæããŠããªãéšåãå å§ã«ããååææã«
転åãããããšãªã©ã«ããè²ç»å圢æç©è³ªãå©çš
ããè²åã圢æããããšãã§ããããããã€ãŠæ¬
çºæã§ã¯äœ¿çšããæå æ§ããã²ã³åéã®çš®é¡ãã
ãã¯æ¡çšããè²å圢æéçšã«ãã€ãŠãåç»ã«å¯Ÿã
ãŠãã¬åç»åãããžåç»åãèªç±ã«äœãããšãã§
ããå Žåã«ãã€ãŠã¯ãã¬ããžäž¡ç»åãåæã«äœã
ããšãã§ããã äŸãã°ãé«ååååç©ãçæããŠããªãéšåã
転åãããŠè²ç»åãåŸãå Žåã«ã¯ãéåžžã®ãã¬å
ããã²ã³åéä¹³å€ãçšãããšåç»ã«å¯ŸããŠããžå
ã®ç»åãåŸãããšãã§ããäžæ¹ããã¬åç»åã圢
æãããããã«ã¯ç±³åœç¹èš±ç¬¬2592250å·ãå第
3206313å·ãå第3367778å·ãå第3447927å·ã«èš
èŒã®å éšç»åããã²ã³åéä¹³å€ãããŸãç±³åœç¹èš±
第2996382å·ã«èšèŒãããŠãããããªè¡šé¢ç»åã
ãã²ã³åéä¹³å€ãšå éšç»åããã²ã³åéä¹³å€ãšã®
æ··åç©ã䜿çšããããšãã§ããã æ¬çºæã«ãããŠæžè²æ³ã®ã€ãšããŒãããŒã³ã¿ã
ã·ã¢ã³ã®ïŒåè²ãçšããŠãè²åºŠå³å ã®åºç¯å²ã®è²
ãåŸãããã«ã¯ãæå ææã¯ãå°ãªããšãïŒçš®ã®
ããããç°ãªãã¹ãã¯ãã«é åã«æå æ§ãæã€ã
ãã²ã³åéä¹³å€ãæããå¿ èŠããããäºãã«ç°ãª
ãã¹ãã¯ãã«é åã«æå æ§ãæã€å°ãªããšãïŒã€
ã®æå æ§ããã²ã³åéä¹³å€ã®ä»£è¡šçãªçµåããšã
ãŠã¯ãéææ§ä¹³å€ãç·ææ§ä¹³å€ããã³èµ€ææ§ä¹³å€
ã®çµåããç·ææ§ä¹³å€ãèµ€ææ§ä¹³å€ããã³èµ€å€å
æå æ§ä¹³å€ã®çµåããéææ§ä¹³å€ãç·ææ§ä¹³å€ã
ãã³èµ€å€å æå æ§ä¹³å€ã®çµåããéææ§ä¹³å€ãèµ€
ææ§ä¹³å€ããã³èµ€å€å æå æ§ä¹³å€ãªã©ãããããª
ãããã§èµ€å€å æå æ§ä¹³å€ãšã¯700nm以äžãç¹ã«
740nm以äžã®å ã«å¯ŸããŠæå æ§ãæã€ä¹³å€ãã
ãã äŸãã°ãéææ§ä¹³å€ãç·ææ§ä¹³å€ããã³èµ€ææ§
ä¹³å€ã®çµåããã䜿çšããå Žåã¯ãéæå æ§ã®ã
ã€ã¯ãã«ãã»ã«ãã€ãšããŒç»å圢æç©è³ªãå«ã¿ã
ç·æå æ§ãã€ã¯ãã«ãã»ã«ãããŒã³ã¿ç»å圢æç©
質ãå«ã¿èµ€æå æ§ã®ãã€ã¯ãã«ãã»ã«ãã·ã¢ã³ç»
å圢æç©è³ªãå«ãããã«ããŠããã°ããã ãã®ããã«ãã€ã¯ãã«ãã»ã«ã䜿çšããããšã«
ããã€ãšããŒãããŒã³ã¿ãã·ã¢ã³ã®ç»å圢æç©è³ª
ãåé¢ããŠåäžã®æå èŠçŽ äžã«å«ãŸããããšãå¯
èœãšãªããããã«ãã簡䟿ãªæäœã§ã«ã©ãŒç»åã
圢æãããããšãã§ããã åè¿°ã®å ¬ç¥æè¡ã§ã«ã©ãŒç»åã圢æãããããš
ãããšã (1)ç·è²å ãèµ€è²å ã«å¯Ÿããæ床ããªãã(2)éè²
å ã«å¯ŸããŠãæ床ãäœãã(3)çµæå®å®æ§ãä¹ã
ãã(4)è€éãªæäœãå¿ èŠãšããã(5)液äœãçšãã
åŠçå·¥çšãå¿ èŠãšããããªã©ã®ããããã®æ¬ ç¹ã
åé¿ããããšãã§ããªãããæ¬çºæã®æå ææã§
ã¯ãããã®åé¡ããã¹ãŠè§£æ±ºããããšãã§ããã
åŸã€ãŠãæ¬çºæã®æå ææã¯ç¹ã«ã«ã©ãŒç»å圢æ
ã«çšãããšå€§ããªå¹æãåŸãããã æ¬çºæã«ãããæå èŠçŽ ããã³ååèŠçŽ ã®æ§æ
ãšããŠã¯ã以äžã®äŸããããããšãã§ããã ããã§ããæå èŠçŽ ãšã¯ãæå æ§ããã²ã³å
éãéå å€ãéåæ§ååç©ããã³è²ç»å圢æç©è³ª
ãå«ã¿ããã€ãããã®äžã®å°ãªããšãéåæ§åå
ç©ãšè²ç»å圢æç©è³ªãåäžã®ãã€ã¯ãã«ãã»ã«ã«
å°å ¥ãããŠããèŠçŽ ãæå³ããäžæ¹ååèŠçŽ ãš
ã¯ããã®æå èŠçŽ ããæŸåºãããè²ç»å圢æç©è³ª
ããåºå®ããããšãšãã«è²ç»åã圢æããèŠçŽ ã
æå³ããããããã®èŠçŽ ã®æ§æãšç»å圢æã®æ¹æ³
ã以äžã«è¿°ã¹ãããæ¬çºæã®æå ææã䜿ã€ãå®
æœã®æ æ§ã¯ããã«éå®ããããã®ã§ã¯ãªãã (1) è²ç»å圢æç©è³ªãããèªèº«çè²ããææãŸã
ã¯é¡æã§ããå Žåã (a) æå èŠçŽ ãšååèŠçŽ ãå¥ã ã®æ¯æäœäžã«å¡
èšãããŠãåã ãæå ææãšååææã圢æ
ãããã®æå ææãåæ§é²å åŸãå ç±ãªãã
åäžé²å ããåŸãååææãšåãããŠå å§ã
ãããšã«ããååææäžã«è²ç»åã圢æãã
ãã (b) æ¯æäœã®äžã«æå èŠçŽ ãå¡èšãããã®äžã«
å åå°å±€ãå¡èšããããã«ãã®äžã«ååèŠçŽ
ãå¡èšããããã®æå ææãæ¯æäœã®åŽãã
åæ§é²å ããå ç±ãªããåäžé²å ããåŸãå
å§ã«ãããè²ç»å圢æç©è³ªãååèŠçŽ ã«åæ§
ã«ç§»åãããååèŠçŽ äžã«è²ç»åã圢æã
ãã (2) è²ç»å圢æç©è³ªãããèªèº«ç¡è²ãªããæ·¡è²ã§
ãããã ä»ã®ãšãã«ã®ãŒãå ãããšçºè²ããå Žåãã
ã®å Žåã®æ§æã¯åèš(1)ã®(a)ããã³(b)ãšåãæ æ§
ãèãããããããããã®äŸã§ãè²ç»å圢æç©
質ãçºè²ãããããã®ãšãã«ã®ãŒãå ããå·¥çš
ãå¿ èŠãšãªããããããã®çºè²ã(1)ã®å ç±ãŸã
ã¯é²å ãŸãã¯å å§æã«åæã«èµ·ããå Žåã«ã¯ç¹
å¥ã®å·¥çšãå ããå¿ èŠã¯ãªãã (3) è²ç»å圢æç©è³ªïŒãã®å Žåçºè²å€ãšåŒã¶ïŒ
ããããèªèº«ç¡è²ãªããã¯æ·¡è²ã§ããããä»ã®
æåïŒé¡è²å€ãšåŒã¶ïŒãšæ¥è§Šããããšã«ããçº
è²ããå Žåã (a) åèš(1)ã®(a)ãšåæ§ã®æ æ§ã§ãã€ååèŠçŽ äž
ã«é¡è²å€ãå«æãããã°ãå å§ã«ããè²ç»å
圢æç©è³ªãšé¡è²å€ãæ¥è§Šããè²ç»åã圢æã
ãã (b) åèš(1)ã®(b)ãšåæ§ã®æ æ§ã§ãã€ãååèŠçŽ
äžã«é¡è²å€ãå«æãããã°ãå å§ã«ããè²ç»
å圢æç©è³ªãšãé¡è²å€ãæ¥è§Šããè²ç»åã圢
æããã (c) æå èŠçŽ ãšååèŠçŽ ãé£æ¥ãããŠæ¯æäœäž
ã«å¡èšãããããããã¯ãã®ïŒã€ã®èŠçŽ ã®æ
åãæ··åããŠå¡èšããæ æ§ãããããã®ãã
ãã®å Žåãé¡è²å€ã¯ååèŠçŽ ã®æ§ææåãšã
ãŠçšãããšãã®æå ææïŒååææãå Œã
ãïŒã«åæ§é²å ãããŠããå ç±ãããã¯åäž
é²å ããåŸå å§ããããšã«ãã€ãŠç Žå£ããã
ã€ã¯ãã«ãã»ã«ã®è¿åã§è²ç»å圢æç©è³ªãšé¡
è²å€ãæ¥è§ŠããŠçºè²ããè²ç»åã圢æããã
ãã®å Žåã«ã¯çºè²ããªãéšåã®è²ç»å圢æç©
質ããå®è³ªçã«ç¡è²ã§ãããããçŽæ¥è²ç»å
ãšããŠèŠèŠçã«ã¿ãããšãã§ããã æ¬çºæã®æå ææã«ãããããã²ã³åéä¹³å€
ã¯ãåè¿°ã®ããã«ãå¢æè²çŽ ã®ååšäžã§åœ¢æãã
ãããã²ã³åéç²åãå«ãã ãã®ãããªç²åãå«ãããã²ã³åéä¹³å€ã䜿çš
ããããšã«ãããæå ææã®ä¿åäžã«æ床ãå€å
ããåœåèšèšããå質ãšã¯å šãç°ãªããã®ã«ãªã
æå ææãšããŠã®åå䟡å€ãèŽåœçã«æãªããã
ãšããæ¬ é¥ã解決ããããããªãã¡çä¿åæ§ãæ Œ
段ãšè¯åããããŸãããããšåæã«åææ床ã®äž
æã芳枬ãããã ããã¯ãæå ææäžã®éåæ§ååç©ããã³è²ç»
å圢æç©è³ªããä¿åäžã«ãåŸæ¥æ³ã§è²å¢æããå Ž
åããã²ã³åéè¡šé¢ã«åžçããŠããå¢æè²çŽ ãè±
çãããããããŸãåŸæ¥æ³ã§ã¯æåããããçšåºŠ
ã®éã®å¢æè²çŽ ãè±çããŠãããšæšå®ããããã
ãã®ãããªçŸè±¡ãé²æ¢ããããããšèããããã å¢æè²çŽ ã¯éåžžã¡ãã³è²çŽ ãçšããããããã
ãã«ã¯ã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²çŽ ãè€åã·
ã¢ãã³è²çŽ ãè€åã¡ãã·ã¢ãã³è²çŽ ãããããŒã©
ãŒã·ã¢ãã³è²çŽ ãããã·ã¢ãã³è²çŽ ãã¹ããªã«è²
çŽ ããã³ãããªããœããŒã«è²çŽ ãå«æããããç¹
ã«æçšãªè²çŽ ã¯ãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²
çŽ ãããã³è€åã¡ãã·ã¢ãã³è²çŽ ã«å±ããè²çŽ ã§
ããããããã®è²çŽ é¡ã«ã¯ãå¡©åºæ§ç°èšç°æ žãšã
ãŠã·ã¢ãã³è²çŽ é¡ã«éåžžå©çšãããæ žã®ãããã
ãé©çšã§ãããããªãã¡ããããªã³æ žããªããµãŸ
ãªã³æ žããã¢ãŸãªã³æ žããããŒã«æ žããªããµãŸãŒ
ã«æ žããã¢ãŸãŒã«æ žãã»ã¬ããŸãŒã«æ žãã€ãããŸ
ãŒã«æ žãããã©ãŸãŒã«æ žãããªãžã³æ žãªã©ïŒãã
ãã®æ žã«èç°åŒçåæ°ŽçŽ ç°ãèåããæ žïŒããã³
ãããã®æ žã«è³éŠæçåæ°ŽçŽ ç°ãèåããæ žãå³
ã¡ãã€ã³ãã¬ãã³æ žããã³ãºã€ã³ãã¬ãã³æ žãã€
ã³ããŒã«æ žããã³ãºãªããµãŸãŒã«æ žãããããªã
ãµãŸãŒã«æ žããã³ãŸãã¢ãŸãŒã«æ žãããããã¢ãŸ
ãŒã«æ žããã³ãŸã»ã¬ããŸãŒã«æ žããã³ãºã€ãããŸ
ãŒã«æ žããããªã³æ žãªã©ãé©çšã§ããããããã®
æ žã¯ççŽ ååäžã«çœ®æãããŠããŠãããã ã¡ãã·ã¢ãã³è²çŽ ãŸãã¯è€åã¡ãã·ã¢ãã³è²çŽ
ã«ã¯ã±ãã¡ãã¬ã³æ§é ãæããæ žãšããŠããã©ãŸ
ãªã³âïŒâãªã³æ žãããªããã³ãã€ã³æ žãïŒâã
ãªãªããµãŸãªãžã³âïŒïŒïŒâãžãªã³æ žããã¢ãŸãª
ãžã³âïŒïŒïŒâãžãªã³æ žãããŒããã³æ žãããªã
ã«ãããŒã«é žæ žãªã©ã®ïŒãïŒå¡ç°èšç°æ žãé©çšã
ãããšãã§ããã æ¬çºæã«ãããŠæçšãªå¢æè²çŽ ã®å ·äœäŸãšããŠ
ã¯æ¬¡ã®äžè¬åŒ(A)ã(H)ã(J)ã(U)ã(W)ã(Y)ã§è¡šããã
ãè²çŽ ããããããã äžè¬åŒ(A) åŒäžZ1ïŒZ2ã¯ã·ã¢ãã³è²çŽ ã«éåžžçšããããã
ããç°æ žãç¹ã«ãã¢ãŸãŒã«æ žããã¢ãŸãªã³æ žãã
ã³ãŸãã¢ãŸãŒã«æ žãããããã¢ãŸãŒã«æ žããªããµ
ãŸãŒã«æ žããªããµãŸãªã³æ žããã³ãŸãªããµãŸãŒã«
æ žãããããªããµãŸãŒã«æ žãããã©ãŸãŒã«æ žãã
ãªãžã³æ žããããªã³æ žãã€ãããŸãªã³æ žãã€ãã
ãŸãŒã«æ žããã³ãŸã€ãããŸãŒã«æ žããããã€ãã
ãŸãŒã«æ žãã»ã¬ããŸãªã³æ žãã»ã¬ããŸãŒã«æ žãã
ã³ãŸã»ã¬ããŸãŒã«æ žããããã»ã¬ããŸãŒã«æ žãŸã
ã¯ã€ã³ãã¬ãã³æ žãªã©ãå®æããã«å¿ èŠãªåå矀
ãè¡šããããããã®æ žã¯ãã¡ãã«åºãªã©ã®äœçŽã¢
ã«ãã«åºãããã²ã³ååãããšãã«åºããããã
ã·ã«åºãççŽ æ°ïŒãïŒã®ã¢ã«ã³ãã·åºãã«ã«ãã
ã·ã«åºãã¢ã«ã³ãã·ã«ã«ã«ããã«åºãã¢ã«ãã«ã¹
ã«ãã¢ã¢ã€ã«åºãã¢ã«ãã«ã«ã«ãã¢ã€ã«åºãã¢ã»
ãã«åºãã¢ã»ããã·åºãã·ã¢ãåºãããªã¯ããã¡
ãã«åºãããªãã«ãªãã¡ãã«åºããããåºãªã©ã«
ãã€ãŠçœ®æãããŠããŠãããã L1ãŸãã¯L2ã¯ã¡ãã³åºã眮æã¡ãã³åºãè¡šã
ãã眮æã¡ãã³åºãšããŠã¯ãã¡ãã«åºããšãã«åº
çã®äœçŽã¢ã«ãã«åºãããšãã«åºã眮æããšãã«
åºãã¡ããã·åºããšããã·åºçã«ãã€ãŠçœ®æãã
ãã¡ãã³åºãªã©ãããã R1ãšR2ã¯ççŽ æ°ãïŒãïŒã®ã¢ã«ãã«åºïŒã«ã«
ããã·ã«åºããã€çœ®æã¢ã«ãã«åºïŒÎ³âã¹ã«ãã
ããã«åºãÎŽâã¹ã«ãããã«åºãïŒâïŒïŒâã¹ã«
ãããããã·ïŒãšãã«åºãïŒâãïŒâïŒïŒâã¹ã«ã
ããããã·ïŒãšããã·ããšãã«åºãïŒâãããã
ã·ã»ã¹ã«ããããã«åºãªã©ã®ã¹ã«ãåºããã€çœ®æ
ã¢ã«ãã«åºïŒã¢ãªã«ïŒallylïŒåºããã®ä»ã®éåžž
ã·ã¢ãã³è²çŽ ã®ïŒ®â眮æåºã«çšããããŠãã眮æ
ã¢ã«ãã«åºãè¡šãããm1ã¯ïŒïŒïŒãŸãã¯ïŒãè¡š
ããã X1 -ã¯æ²çŽ ã€ãªã³ãèçŽ ã€ãªã³ãïœâãã«ãšã³
ã¹ã«ãã³é žã€ãªã³ãéå¡©çŽ é žã€ãªã³ãªã©ã®éåžžã·
ã¢ãã³è²çŽ ã«çšããããé žã¢ããªã³åºãè¡šããã
ïœã¯ïŒãŸãã¯ïŒãè¡šããããã¿ã€ã³æ§é ããšããš
ãã¯ïœã¯ïŒã§ããã äžè¬åŒ(B) åŒäžãZ3ã¯ã·ã¢ãã³è²çŽ ã«éåžžçšããããäžè¬
åŒ(A)ã§ç€ºãããããªãããç°æ žãè¡šãããZ4ã¯é
åžžã¡ãã·ã¢ãã³è²çŽ ã«çšããããŠããã±ãããã
æ žã圢æããã«å¿ èŠãªåå矀ãè¡šãããäŸãã°ã
ãŒããã³ãããªããã³ãã€ã³ããªãã·ã€ã³ããŒ
ã«ãïŒâããªãªããµãŸãªãžã³ãžãªã³ãïŒïŒïŒâã€
ã³ãã³ãžãªã³çã®æ žã§ãããL3ãšL4ã¯L1ãšL2ãš
åæ矩ã§ãããR3ã¯R1ãŸãã¯R2ãšåæ矩ã§ããã m2ã¯ïŒïŒïŒïŒïŒãŸãã¯ïŒãè¡šããã äžè¬åŒ(C) åŒäžãZ5ã¯ïŒâãããªã³æ žãïŒâãããªã³æ žã
ãã³ããã¢ãŸãŒã«æ žããã³ããªããµãŸãŒã«æ žãã
ãããã¢ãŸãŒã«æ žããããã»ã¬ããŸãŒã«æ žããã
ããªããµãŸãŒã«æ žããã³ãŸã»ã¬ããŸãŒã«æ žãã€ã³
ãã¬ãã³æ žãå®æããã«å¿ èŠãªåå矀ãè¡šããã
p1ã¯ïŒãŸãã¯ïŒãè¡šãããR4ã¯R1ãŸãã¯R2ãšå
æ矩ãL5ãšL6ã¯ãL3ãŸãã¯L4ãšåæ矩ãè¡šããã
m3ã¯ïŒãŸãã¯ïŒãè¡šãããL7ãšL3ã¯L1ãŸãã¯L2
ãšåæ矩ãè¡šãããZ6ã¯Z4ãšåæ矩ãè¡šããã
Y1ãšY2ã¯é žçŽ ååãç¡«é»ååãã»ã¬ã³ååãŸã
ã¯ïŒïŒ®âR5ïŒR5ã¯ã¡ãã«ããšãã«ããããã«åºãª
ã©ççŽ æ°ïŒä»¥äžã®ã¢ã«ãã«åºãã¢ãªã«ïŒallylïŒ
åºãè¡šããïŒã§ãã®äžã®å°ãªããšãäžã€ã¯ïŒïŒ®â
R5åºã§ããã w1ã¯ïŒãŸãã¯ïŒãè¡šããã äžè¬åŒ(D) åŒäžãZ7ã¯Z5ãšãZ8ã¯Z6ãšãR6ã¯R1ãŸãã¯R2
ãšp2ã¯p1ãšåæ矩ãè¡šãããY3ãšY4ã¯Y1ãšY2ãš
åæ矩ãè¡šãããw2ã¯w1ãšåæ矩ã§ããã äžè¬åŒ(E) åŒäžãR7ãšR8ã¯R1ãšãZ9ãšZ10ã¯Z5ãšãp3ïŒp4
ã¯p1ãšãL9ãL13ã¯L1ãšãX2ã¯X1ãšãn2ã¯n1ãšå
æ矩ãè¡šãããY5ãšY6ã¯ãY1ãšåæ矩ãè¡šã
ããp5ïŒm4ã¯ïŒãŸãã¯ïŒãè¡šããã w3ã¯w1ãšåæ矩ã§ããã äžè¬åŒ(F) åŒäžãZ11ãšZ12ã¯ç¡çœ®æãè¥ããã¯ç¹ã«ã¡ãã«
åºãªã©ã®äœçŽã¢ã«ãã«åºãããã²ã³ååãããšã
ã«åºãããããã·ã«åºãççŽ æ°ïŒãïŒã®ã¢ã«ã³ã
ã·åºãã«ã«ããã·ã«åºãã¢ã«ã³ãã·ã«ã«ããã«
åºãã¢ã«ãã«ã¹ã«ãã¢ã¢ã€ã«åºãã¢ã«ãã«ã«ã«ã
ã¢ã€ã«åºãã¢ã»ãã«åºãã·ã¢ãåºãããªã¯ããã¡
ãã«åºãããªãã«ãªãã¡ãã«åºããããåºãªã©ã«
ãã€ãŠçœ®æããããã³ãŒã³ç°ãå®æããã«å¿ èŠãª
åå矀ããŸãã¯ããã¿ã¬ã³ç°ã圢æããã«å¿ èŠãª
åå矀ãè¡šãããR9ãšR10ã¯R1ãšåæ矩ãè¡šã
ããY7ãšY8ã¯é žçŽ ååãç¡«é»ååãã»ã¬ã³ååã ïŒR11ïŒR12ã¯ã¡ãã«åºãŸãã¯ãšãã«åºïŒãïŒïŒ®
âR13ïŒR13ã¯ã¢ã«ãã«åºãéåžžã·ã¢ãã³è²çŽ ã®ïŒ®
â眮æåºã«çšãããã眮æã¢ã«ãã«åºãŸãã¯ã¢ãª
ã«ïŒallylïŒåºãè¡šããïŒãŸãã¯âCHïŒCHâã
è¡šãããY9ã¯ïŒãŸãã¯ïŒå¡ã®è€çŽ ç°ã圢æãã
ã«å¿ èŠãªåå矀ãè¡šããã äžè¬åŒ(G) Z13ïŒZ14ã¯Z11ãšãR14ãšR15ã¯R1ãšãY10ïŒY11
ã¯Y7ãšåæ矩ãè¡šãããY12ã¯ïŒãŸãã¯ïŒå¡ã®ç
çŽ ç°ã圢æããã«å¿ èŠãªåå矀ãè¡šãããX3ã¯
X1ãšãn3ã¯n1ãšåæ矩ãè¡šããã äžè¬åŒ(H) äžè¬åŒ(J) A1ïŒâL16ïŒL17ïŒn6-1ââââL18ïŒA2ïŒX4 -ïŒo4-1 X4ãn4ã¯X1ãn1ãšåæ矩ãè¡šããã p6ã¯ïŒãŸãã¯ïŒãm5ïŒm6ã¯ïŒãŸãã¯ïŒãL14ã
L18ã¯L1ãšåæ矩ãè¡šãããZ15ã¯Z1ãšåæ矩ãè¡š
ãããp6ã¯äžè¬åŒ(C)ã®p1ãšåæ矩ã§ããã ããã«ãA1ãšããŠã¯ã
ãåŒããŸãã¯
ãåŒããã
ãŸããA2ãšããŠã¯ã
ãåŒããŸãã¯
ã奜ãŸãããã®ãšããŠæããããšãã§ããã
R16ïŒR18ã¯æ°ŽçŽ ååãã¢ã«ãã«åºã眮æã¢ã«
ãã«åºãã¢ãªãŒã«åºãè¡šãããR17ã¯ããã²ã³å
åããããåºãäœçŽã¢ã«ãã«åºãã¢ã«ã³ãã·åºã
ã¢ã«ã³ãã·ã«ã«ããã«åºãã¢ã«ãã«ã¹ã«ããã«
åºãã¢ãªãŒã«ã¹ã«ããã«åºãè¡šããã R19ïŒR20ïŒR21ã¯æ°ŽçŽ ååãããã²ã³ååãã¢
ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºãã¢ãªãŒã«åºãããª
ãžã³åºãã«ã«ããã·åºãã¢ã«ã³ãã·ã«ã«ããã«åº
ãè¡šãããã¯ããŒããã³ãïŒâããªãªããµãŸãª
ãžã³ãžãªã³ãïŒâããªããã³ãã€ã³ããã«ããã«
é žãªã©ã®ïŒãïŒå¡ã®è€çŽ ç°æ žãå®æããã«å¿ èŠãª
åå矀ãè¡šããã äžè¬åŒ(K) R22ã¯R1ãšãZ16ã¯Z1ãšãL19ïŒL20ã¯L1ãšåæ矩
ãè¡šãããp7ã¯ïŒãŸãã¯ïŒããp8ã¯ïŒïŒïŒãŸãã¯
ïŒãè¡šããã G1ïŒG2ã¯ãåãã§ãç°ãªã€ãŠããŠããããR1
ãšåæ矩ãè¡šããããŸããå ±åã§ç°ç¶ã®ïŒçŽã¢ã
ã³ïŒäŸãã°ãããªãã³ãïŒâãããªã³ããããªãž
ã³ãããã©ãžã³ãã¢ã«ããªã³ãïŒïŒïŒïŒïŒïŒïŒâ
ããã©ããããããªã³ããã«ããããããªã³ãïŒ
âã¢ã¶ãã·ã¯ããïŒïŒïŒïŒïŒãããã³ãã€ã³ããª
ã³ãã¢ãŒãã³ãããŠãããµãããã¢ãŒãã³ïŒã圢
æããå¿ èŠãªåå矀ãè¡šãããX5ã¯X1ãšãn5ã¯
n1ãšåæ矩ãè¡šããã äžè¬åŒ(L) Z17ã¯Z4ãšãL21ïŒL22ïŒL23ã¯L1ãšãG3ïŒG4ã¯
G1ãšåæ矩ãè¡šãããp9ã¯ïŒïŒïŒïŒïŒãŸãã¯ïŒ
ãè¡šããã èµ€å€å æå æ§ãä»äžããã®ã«ç¹ã«æçšãªè²çŽ ã¯
次ã®äžè¬åŒ(M)ã(U)ã(W)ã(Y)ã§è¡šããããè²çŽ ã§ã
ãã äžè¬åŒ(M) ããã§R101ããã³R102ã¯åã åäžã§ãã€ãŠãç°
ãªã€ãŠããŠããããããããã¢ã«ãã«åºïŒå¥œãŸã
ãã¯ççŽ ååæ°ïŒãïŒãäŸãã°ã¡ãã«åºããšãã«
åºããããã«åºãããã«åºããã³ãã«åºãããã
ã«åºãªã©ïŒã眮æã¢ã«ãã«åºïŒçœ®æåºãšããŠäŸã
ã°ã«ã«ããã·åºãã¹ã«ãåºãã·ã¢ãåºãããã²ã³
ååïŒäŸãã°ããçŽ ååãå¡©çŽ ååãèçŽ ååãª
ã©ïŒãããããã·åºãã¢ã«ã³ãã·ã«ã«ããã«åº
ïŒççŽ ååæ°ïŒä»¥äžãäŸãã°ã¡ããã·ã«ã«ããã«
åºããšããã·ã«ã«ããã«åºããã³ãžã«ãªãã·ã«ã«
ããã«åºãªã©ïŒãã¢ã«ã³ãã·åºïŒççŽ ååæ°ïŒä»¥
äžãäŸãã°ã¡ããã·åºããšããã·åºãããããã·
åºããããã·åºããã³ãžã«ãªãã·åºãªã©ïŒãã¢ãª
ãŒã«ãªãã·åºïŒäŸãã°ããšããã·åºãïœâããªã«
ãªãã·åºãªã©ïŒãã¢ã·ã«ãªãã·åºïŒççŽ ååæ°ïŒ
以äžãäŸãã°ã¢ã»ãã«ãªãã·åºãããããªãã«ãª
ãã·åºãªã©ïŒãã¢ã·ã«åºïŒççŽ ååæ°ïŒä»¥äžãäŸ
ãã°ã¢ã»ãã«åºãããããªãã«åºããã³ãŸã€ã«
åºãã¡ã·ã«åºãªã©ïŒãã«ã«ãã¢ã€ã«åºïŒäŸãã°ã«
ã«ãã¢ã€ã«åºãïŒïŒ®âãžã¡ãã«ã«ã«ãã¢ã€ã«
åºãã¢ã«ããªãã«ã«ãã¢ã€ã«åºããããªãžãã«ã«
ãã¢ã€ã«åºãªã©ïŒãã¹ã«ãã¢ã¢ã€ã«åºïŒäŸãã°ã¹
ã«ãã¢ã¢ã€ã«åºãïŒïŒ®âãžã¡ãã«ã¹ã«ãã¢ã¢ã€
ã«åºãã¢ã«ããªãã¹ã«ããã«åºãªã©ïŒãã¢ãªãŒã«
åºïŒäŸãã°ããšãã«åºãïœâããããã·ããšãã«
åºãïœâã«ã«ããã·ããšãã«åºãïœâã¹ã«ãããš
ãã«åºãαâãããã«åºãªã©ïŒãªã©ã§çœ®æããã
ã¢ã«ãã«åºïŒççŽ ååæ°ïŒä»¥äžãäœããã®çœ®æåº
ã¯ïŒã€ä»¥äžçµåããŠã¢ã«ãã«åºã«çœ®æãããŠã
ããïŒãè¡šããã äžè¬åŒ(M)ã«ãããŠY101ïŒY102ã¯é žçŽ ååãç¡«é»
ååãã»ã¬ã³ååã ïŒR103ïŒR104ã¯ã¡ãã«åºãŸãã¯ãšãã«åºïŒãïŒïŒ®
âR105ãR105ã¯ççŽ æ°ïŒä»¥äžã®ç¡çœ®æãŸãã¯çœ®æ
ãããã¢ã«ãã«åºïŒçœ®æåºãšããŠã¯ããããã·ã«
åºãããã²ã³ååãã«ã«ããã·ã«åºãã¹ã«ãåºã
ã¢ã«ã³ãã·åºãªã©ããïŒãŸãã¯ã¢ãªã«åºããŸãã¯
âCHïŒCHâãè¡šããã äžè¬åŒ(M)ã«ãããŠZ101ïŒZ102ã¯ç¡çœ®æãŸãã¯çœ®
æããããã³ãŒã³ç°ãããã¯ãããã«ç°ã圢æã
ãã«å¿ èŠãªåå矀ãè¡šããã眮æåºãšããŠã¯ã¡ã
ã«åºãªã©ã®äœçŽã¢ã«ãã«åºãããã²ã³ååãããš
ãã«åºãããããã·ã«åºãççŽ æ°ïŒãïŒã®ã¢ã«ã³
ãã·åºãã«ã«ããã·ã«åºãã¢ã«ã³ãã·ã«ã«ããã«
åºãã¢ã«ãã«ã¹ã«ãã¢ã¢ã€ã«åºãã¢ã«ãã«ã«ã«ã
ã¢ã€ã«åºãã¢ã·ã«åºãã·ã¢ãåºãããªãã«ãªãã¡
ãã«åºããããåºãªã©ãããã Y101ãå«ãç°ãšZ101ããŸãã¯Y102ãå«ãç°ãš
Z102ã§äœãããå«çªçŽ è€çŽ ç°ãšããŠã¯äŸãã°ãã¢
ãŸãŒã«æ žç³»ãäŸãã°ãã³ãŸãã¢ãŸãŒã«ãïŒâã¯ã
ã«ãã³ãŸãã¢ãŸãŒã«ãïŒâã¯ãã«ãã³ãŸãã¢ãŸãŒ
ã«ãïŒâã¯ãã«ãã³ãŸãã¢ãŸãŒã«ãïŒâã¯ãã«ã
ã³ãŸãã¢ãŸãŒã«ãïŒâã¡ãã«ãã³ãŸãã¢ãŸãŒã«ã
ïŒâã¡ãã«ãã³ãŸãã¢ãŸãŒã«ãïŒâã¡ãã«ãã³ãŸ
ãã¢ãŸãŒã«ãïŒâããã¢ãã³ãŸãã¢ãŸãŒã«ãïŒâ
ããã¢ãã³ãŸãã¢ãŸãŒã«ãïŒâãšãŒããã³ãŸãã¢
ãŸãŒã«ãïŒâããšãã«ãã³ãŸãã¢ãŸãŒã«ãïŒâã¡
ããã·ãã³ãŸãã¢ãŸãŒã«ãïŒâã¡ããã·ãã³ãŸã
ã¢ãŸãŒã«ãïŒâãšããã·ãã³ãŸãã¢ãŸãŒã«ãïŒâ
ã«ã«ããã·ãã³ãŸãã¢ãŸãŒã«ãïŒâãšããã·ã«ã«
ããã«ãã³ãŸãã¢ãŸãŒã«ãïŒâããšããã«ãã³ãŸ
ãã¢ãŸãŒã«ãïŒâãã«ãªããã³ãŸãã¢ãŸãŒã«ãïŒ
âããªãã«ãªãã¡ãã«ãã³ãŸãã¢ãŸãŒã«ãïŒïŒïŒ
âãžã¡ãã«ãã³ãŸãã¢ãŸãŒã«ãïŒâã¡ãã«âïŒâ
ã¡ããã·ãã³ãŸãã¢ãŸãŒã«ãïŒâããããã·âïŒ
âã¡ãã«ãã³ãŸãã¢ãŸãŒã«ãããã©ããããã³ãŸ
ãã¢ãŸãŒã«ãïŒâããšãã«ãã³ãŸãã¢ãŸãŒã«ãã
ãããïŒïŒïŒâïœããã¢ãŸãŒã«ãããããïŒïŒïŒ
âïœããã¢ãŸãŒã«ãããããïŒïŒïŒâïœããã¢ãŸ
ãŒã«ãïŒâã¡ããã·ããããïŒïŒïŒâïœããã¢ãŸ
ãŒã«ãïŒâã¡ããã·ããããïŒïŒïŒâïœããã¢ãŸ
ãŒã«ãïŒâã¡ããã·ããããïŒïŒïŒâïœããã¢ãŸ
ãŒã«ãïŒâã¡ããã·ããããïŒïŒïŒâïœããã¢ãŸ
ãŒã«ãªã©ããã»ã¬ããŸãŒã«æ žç³»ãäŸãã°ãã³ãŸã»
ã¬ããŸãŒã«ãïŒâã¯ãã«ãã³ãŸã»ã¬ããŸãŒã«æ žã
ïŒâã¡ããã·ãã³ãŸãã¢ãŸãŒã«ãïŒâã¡ãã«ãã³
ãŸã»ã¬ããŸãŒã«ãïŒâããããã·ãã³ãŸã»ã¬ããŸ
ãŒã«ãããããïŒïŒïŒâïœãã»ã¬ããŸãŒã«ããã
ããïŒïŒïŒâïœãã»ã¬ããŸãŒã«ãªã©ãããªããµãŸ
ãŒã«æ žç³»ãäŸãã°ãã³ãŸãªããµã¢ãŸãŒã«ãïŒâã¯
ãã«ãã³ãŸãªããµãŸãŒã«ãïŒâã¡ãã«ãã³ãŸãªã
ãµãŸãŒã«ãïŒâããã ãã³ãŸãªããµãŸãŒã«ãïŒâ
ãã«ãªããã³ãŸãªããµãŸãŒã«ãïŒâããšãã«ãã³
ãŸãªããµãŸãŒã«ãïŒâã¡ããã·ãã³ãŸãªããµãŸãŒ
ã«ãïŒâããªãã«ãªãã¡ãã«ãã³ãŸãªããµãŸãŒ
ã«ãïŒâããããã·ãã³ãŸãªããµãŸãŒã«ãïŒâã«
ã«ããã·ãã³ãŸãªããµãŸãŒã«ãïŒâã¡ãã«ãã³ãŸ
ãªããµãŸãŒã«ãïŒâã¯ãã«ãã³ãŸãªããµãŸãŒã«ã
ïŒâã¡ããã·ãã³ãŸãªããµãŸãŒã«ãïŒâãããã
ã·ãã³ãŸãªããµãŸãŒã«ãïŒïŒïŒâãžã¡ãã«ãã³ãŸ
ãªããµãŸãŒã«ãïŒïŒïŒâãžã¡ãã«ãã³ãŸãªããµãŸ
ãŒã«ãïŒâãšããã·ãã³ãŸãªããµãŸãŒã«ãããã
ãïŒïŒïŒâïœããªããµãŸãŒã«ãããããïŒïŒïŒâ
ïœããªããµãŸãŒã«ãããããïŒïŒïŒâïœããªããµ
ãŸãŒã«ãªã©ãããããªã³æ žãäŸãã°ïŒâãããªã³ã
ïŒâã¡ãã«âïŒâãããªã³ãïŒâãšãã«âïŒâã
ããªã³ãïŒâã¡ãã«âïŒâãããªã³ãïŒâãã«ãª
ãâïŒâãããªã³ãïŒâã¡ããã·âïŒâãããª
ã³ãïŒâããããã·âïŒâãããªã³ãïŒâã¯ãã
âïŒâãããªã³ãïŒâãã«ãªãâïŒâãããªã³ãª
ã©ããïŒïŒïŒâãžã¢ã«ãã«ã€ã³ãã¬ãã³æ žïŒäŸã
ã°ãïŒïŒïŒâãžã¡ãã«ã€ã³ãã¬ãã³ãïŒïŒïŒâãž
ãšãã«ã€ã³ãã¬ãã³ãïŒïŒïŒâãžã¡ãã«âïŒâã·
ã¢ãã€ã³ãã¬ãã³ãïŒïŒïŒâãžã¡ãã«âïŒâã¡ã
ãã·ã€ã³ãã¬ãã³ãïŒïŒïŒâãžã¡ãã«âïŒâã¡ã
ã«ã€ã³ãã¬ãã³ãïŒïŒïŒâãžã¡ãã«âïŒâã¯ãã«
ã€ã³ãã¬ãã³ãªã©ïŒãã€ãããŸãŒã«æ žïŒäŸãã°ã
ïŒâã¡ãã«ãã³ãŸã€ãããŸãŒã«ãïŒâãšãã«ãã³
ãŸã€ãããŸãŒã«ãïŒâã¡ãã«âïŒâã¯ãã«ãã³ãŸ
ã€ãããŸãŒã«ãïŒâãšãã«âïŒâã¯ãã«ãã³ãŸã€
ãããŸãŒã«ãïŒâã¡ãã«âïŒïŒïŒâãžã¯ãã«ãã³
ãŸã€ãããŸãŒã«ãïŒâãšãã«âïŒïŒïŒâãžã¯ãã«
ãã³ãŸã€ãããŸãŒã«ãïŒâãšãã«âïŒâã¡ããã·
ãã³ãŸã€ãããŸãŒã«ãïŒâã¡ãã«âïŒâã·ã¢ãã
ã³ãŸã€ãããŸãŒã«ãïŒâãšãã«âïŒâã·ã¢ããã³
ãŸã€ãããŸãŒã«ãïŒâã¡ãã«âïŒâãã«ãªããã³
ãŸã€ãããŸãŒã«ãïŒâãšãã«âïŒâãã«ãªããã³
ãŸã€ãããŸãŒã«ãïŒâããšãã«âïŒïŒïŒâãžã¯ã
ã«ãã³ãŸã€ãããŸãŒã«ãïŒâã¢ãªã«âïŒïŒïŒâãž
ã¯ãã«ãã³ãŸã€ãããŸãŒã«ãïŒâã¢ãªã«âïŒâã¯
ãã«ãã³ãŸã€ãããŸãŒã«ãïŒâããšãã«ãã³ãŸã€
ãããŸãŒã«ãïŒâããšãã«âïŒâã¯ãã«ãã³ãŸã€
ãããŸãŒã«ãïŒâã¡ãã«âïŒâããªãã«ãªãã¡ã
ã«ãã³ãŸã€ãããŸãŒã«ãïŒâãšãã«âïŒâããªã
ã«ãªãã¡ãã«ãã³ãŸã€ãããŸãŒã«ãïŒâãšãã«ã
ãããïŒïŒïŒâïœãã€ãããŸãŒã«ãªã©ïŒãããã
ããã äžè¬åŒ(M)ã«ãããŠïŒ¹ã¯ïŒå¡ãŸãã¯ïŒå¡ã®ççŽ ç°
ã圢æããã®ã«å¿ èŠãªåå矀ãŸãã¯ç°ã圢æããª
ãå Žåã¯åã«ã¡ãã³éãè¡šããã äžè¬åŒ(M)ã«ãããŠã m101ã¯ïŒãŸãã¯ïŒãè¡šããã X101ã¯é žæ®åºãè¡šããã m102ã¯ïŒãŸãã¯ïŒãè¡šãããè²çŽ ããã¿ã€ã³
æ§é ããšããšãã¯ïŒã§ããã L101ïŒL102ã¯ã¡ãã³åºãŸãã¯çœ®æã¡ãã³åºãè¡š
ããã眮æã¡ãã³åºãšããŠã¯ççŽ æ°ïŒãïŒã®äœçŽ
ã¢ã«ãã«åºãäœçŽã¢ã«ã³ãã·åºãã¢ãªãŒã«åºïŒã
ã®ã¢ãªãŒã«åºã«ã¯ããã²ã³ååãççŽ æ°ïŒãïŒã®
ã¢ã«ãã«åºãççŽ æ°ïŒãïŒã®ã¢ã«ã³ãã·åºãã¹ã«
ãåºãã«ã«ããã·åºãªã©ã眮æããŠããŠãããïŒã
ã¢ã©ã«ãã«åºïŒãã³ãžã«åºãªã©ïŒãªã©ã«ãã眮æ
ãããã¡ãã³åºããããããã äžè¬åŒ(N) åŒäžã Y103ïŒY104ã¯Y101ãšåæ矩ã§ããã R106ïŒR107ã¯R101ãšåæ矩ã§ããã Z103ïŒZ104ã¯Z101ãšåæ矩ã§ããã X102ã¯X101ãšåæ矩ã§ããã m103ã¯m102ãšåæ矩ã§ããã ïŒããã§åæ矩ãšã¯äžè¬åŒ(M)ã®å®çŸ©ãšåæ矩ã§
ããããšããããïŒ äžè¬åŒ(O) åŒäžã Z105ã¯ïŒâãããªã³æ žãïŒâãããªã³æ žãå®æ
ããã«å¿ èŠãªåå矀ãè¡šããã Z106ã¯Z101ãšåæ矩ã§ããã p101ã¯ïŒãŸãã¯ïŒãè¡šããã m104ã¯ïŒãŸãã¯ïŒãè¡šããã Y105ã¯Y101ãšåæ矩ã§ããã R108ïŒR109ã¯R101ãšåæ矩ã§ããã X103ã¯X101ãšåæ矩ã§ããã m105ã¯m102ãšåæ矩ã§ããã L103ãL104ã¯L101ãšåæ矩ã§ããã ïŒããã§åæ矩ãšã¯äžè¬åŒ(M)ã®å®çŸ©ãšåæ矩ã§
ããããšããããïŒ äžè¬åŒ(P) åŒäžã Z109ã¯Z101ïŒZ100ãšåæ矩ã§ããã R110ïŒR111ã¯R101ãšåæ矩ã§ããã Y108ã¯ïŒ¹ãšåæ矩ã§ããã X104ã¯X101ãšåæ矩ã§ããã m106ã¯m102ãšåæ矩ã§ããã Y106ïŒY107ã¯Y101ãšåæ矩ã§ããã ïŒããã§åæ矩ãšã¯äžè¬åŒ(M)ã®å®çŸ©ãšåæ矩ã§
ããããšããããïŒ R112ïŒR113ã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«åºãŸãã¯
ããšãã«åºãŸãã¯R112ïŒR113ãé£çµããŠïŒãŸãã¯
ïŒå¡è€çŽ ç°ã圢æããã«å¿ èŠãªåå矀ãè¡šããã äžè¬åŒ(Q) åŒäžã Z110ã¯Z101ãšåæ矩ã§ããã Y109ã¯Y101ãšåæ矩ã§ããã Y111ã¯é žçŽ ååãç¡«é»ååãã»ã¬ã³ååãïŒïŒ®
âR116ïŒR116ã¯R105ãšåæ矩ïŒãè¡šããã R114ã¯R101ãšåæ矩ã§ããã R115ã¯R101ãšåæ矩ã®åºã®ä»ãããšãã«åºãã
ãªãžã«åºã眮æããšãã«åºã眮æããªãžã«åºãè¡š
ããã眮æåºãšããŠã¯ãã¹ã«ãã³åºãã«ã«ããã·
åºãã·ã¢ãåºãããã²ã³ååïŒäŸãã°å¡©çŽ ååã
èçŽ ååãããçŽ ååãªã©ïŒãC1ãC4ã®ã¢ã«ãã«
åºãC1ãC4ã®ã¢ã«ã³ãã·åºããžã¢ã«ãã«ã¢ãã
åºãã¢ã·ã«åºãã¢ã«ã³ãã·ã«ã«ããã«åºãªã©ãã
ãã Y110ã¯ïŒ¹ãšåæ矩ã§ããã m107ã¯m101ãšåæ矩ã§ããã L105ïŒL106ã¯L101ãšåæ矩ã§ããã ïŒããã§åæ矩ãšã¯äžè¬åŒ(M)ã®å®çŸ©ãšåæ矩ã§
ããããšããããïŒ äžè¬åŒ(R) åŒäžã Z110ïŒY109ïŒY110ïŒY111ïŒR114ïŒR115L105ãã
ã³L106ããã³m107ã¯äžè¬åŒ(Q)ã«ããããã®ãšåæ
矩ã§ããã äžè¬åŒ(S) åŒäžã Z111ïŒZ112ã¯Z101ãšåæ矩ã§ããã Y112ïŒY114ã¯Y101ãšåæ矩ã§ããã R117ïŒR119ã¯R101ãšåæ矩ã§ããã R118ã¯R105ãšåæ矩ã§ããã Y113ã¯ïŒ¹ãšåæ矩ã§ããã X105ã¯X101ãšåæ矩ã§ããã m108ã¯m102ãšåæ矩ã§ããã ïŒããã§åæ矩ãšã¯äžè¬åŒ(M)ã®å®çŸ©ãšåæ矩ã§
ããããšããããïŒ äžè¬åŒ(T) åŒäžã Z113ïŒZ114ã¯Z101ãšåæ矩ã§ããã Y115ïŒY116ã¯Y101ãšåæ矩ã§ããã R121ïŒR122ã¯R101ãšåæ矩ã§ããã X106ã¯X101ãšåæ矩ã§ããã m109ã¯m102ãšåæ矩ã§ããã ïŒä»¥äžã§åæ矩ãšã¯äžè¬åŒ(M)ã®å®çŸ©ãšåæ矩ã§
ããããšããããïŒ R120ã¯äžè¬åŒ(S)ã®R118ãšåæ矩ã§ããã äžè¬åŒ(U) åŒäžã Y117ã¯ïŒ¹ãšåæ矩ã§ããã Y108ã¯Y101ãšåæ矩ã§ããã Z115ã¯Z105ãšåæ矩ã§ããã Z116ã¯Z101ãšåæ矩ã§ããã R123ïŒR124ã¯R101ãšåæ矩ã§ããã ïœã¯äžè¬åŒ(C)ã®p1ãšåæ矩ã§ããã X107ã¯X101ãšåæ矩ã§ããã m110ã¯m102ãšåæ矩ã§ããã ïŒä»¥äžã§åæ矩ãšã¯äžè¬åŒ(M)ã®å®çŸ©ãšåæ矩ã§
ããããšããããïŒ R125ã¯äžè¬åŒ(S)ã®R118ãšåæ矩ã§ããã äžè¬åŒ(W) åŒäžã Z117ãZ118ã¯Z101ãšåæ矩ã§ããã Y119ãY120ã¯Y101ãšåæ矩ã§ããã R126ãR127ã¯R101ãšåæ矩ã§ããã X108ã¯X101ãšåæ矩ã§ããã m111ã¯m102ãšåæ矩ã§ããã L107ã¯L101ãšåæ矩ã§ããã ïŒä»¥äžã§åæ矩ãšã¯äžè¬åŒ(M)ã®å®çŸ©ãšåæ矩ã§
ããããšããããïŒ R128ã¯äžè¬åŒ(S)ã®R118ãšåæ矩ã§ããã äžè¬åŒ(Y) åŒäžã Z119ïŒZ120ã¯Z101ãšåæ矩ã§ããã Y121ïŒY122ã¯Y101ãšåæ矩ã§ããã R129ïŒR130ã¯R101ãšåæ矩ã§ããã L108ïŒL109ïŒL110ïŒL111ïŒL112ïŒL113ïŒL114ã¯
L101ãšåæ矩ã§ããã X109ã¯X101ãšåæ矩ã§ããã m112ã¯ã¯m102ãšåæ矩ã§ããã ïŒããã§åæ矩ãšã¯äžè¬åŒ(M)ã®å®çŸ©ãšåæ矩ã§
ããããšããããïŒ æ¬çºæã«ãããŠåèšå¢æè²çŽ ã¯ãç±³åœç¹èš±ç¬¬
4183756å·ã«åŸã€ãŠããã²ã³åéç²åãçããå
ã«å¯æº¶æ§éå¡©ïŒäŸãã°ç¡é žéïŒãšããã²ã³åç©
ïŒäŸãã°èåã«ãªãŠã ïŒãšã®åå¿ç³»ã«ååšãããŠ
ãããããç±³åœç¹èš±ç¬¬4225666å·ã«åŸã€ãŠããã²
ã³åéç²åã®æ žåœ¢æåŸã§ãäžã€ããã²ã³åéç²å
圢æå·¥çšçµäºåã«ãäžèšã®åå¿ç³»ã«ååšãããŠã
ããããŸãããã²ã³åéç²å圢æãšåæããªãã¡
äžèšéå¡©ãšããã²ã³åç©ãšãæ··åããã®ãšåæã«
å¢æè²çŽ ãåå¿æ¶²äžã«ååšãããŠãããããã®æ¹
æ³ã¯ãã®ããã«ããŠäœã€ãä¹³å€ãå«ãæå ææã®
é«æž©ç¶æ ã§ã®ä¿åæ§ãããåªããŠãããšããç¹ã§
ç¹ã«å¥œãŸããã äžèšã®ãããã®æ·»å æ¹æ³ã«ãããŠããè²çŽ ã®ç·
æ·»å éãäžåºŠã«æ·»å ããŠãããããŸããäœåãã«
åå²ããŠæ·»å ããŠããããããã«ã¯å¯æº¶æ§éå¡©ã
ãã³ïŒãŸãã¯ããã²ã³åç©ãšã®æ··åç©ã®åœ¢ã§è²çŽ
ãæ·»å ããŠãè¯ãã ãŸãäžçš®é¡ã®è²çŽ ãåç¬ã§çšããŠããäºçš®ä»¥äž
ãè²çŽ ã䜵çšããŠãïŒæ··åããŠæ·»å ããŠããå¥ã
ã«æ·»å ããŠãããããã¯æ·»å ææãããããŠäžçš®
é¡ãã€æ·»å ããŠãïŒãããã§ããããåŸè ã®å Ž
åããã®äžã«åŒ·è²å¢æå€ãå«ãã§ãè¯ãã è²çŽ ã¯æ¶²é¢æ·»å ã液äžæ·»å ãããã§ãå¯èœã§ã
ããæ¹æãåŸæ¥ã®ãããã®æ¹æãçšããããšãã§
ããã å¢æè²çŽ ã¯ã¡ã¿ããŒã«ããšã¿ããŒã«ããããã
ãŒã«ãããçŽ åã¢ã«ã³ãŒã«ã¡ãã«ã»ããœã«ãããž
ã¡ãã«ãã«ã ã¢ãããã¢ã»ãã³çã®æ°Žãšçžæº¶æ§ã®
ããææ©æº¶å€ãæ°ŽïŒã¢ã«ã«ãªæ§ã§ãé žæ§ã§ãã
ãïŒã«æº¶è§£ãããŠæ·»å ããŠãããããäžèšã®ãã®
ãïŒçš®é¡ä»¥äžäœµçšããŠãããããŸãæ°ŽïŒãŒã©ãã³
åæ£ç³»ã«åæ£ãã圢ã§ãŸãã¯åçµä¹Ÿç¥ããç²æ«ã®
圢ã§æ·»å ããŠããããããã«çé¢æŽ»æ§å€ãçšããŠ
åæ£ããç²æ«ã¯ã溶液ã®åœ¢ã§æ·»å ããŠãããã å¢æè²çŽ ã®äœ¿çšéã¯ä¹³å€è£œé ã«äœ¿çšããé100
ïœããã0.001ïœã20ïœãé©åœã§ããã奜ãŸãã
ã¯0.01ïœãïŒïœã§ããã ããã²ã³åéç²å圢æåå¿éçšã«ãããåå¿æ¶²
äžã®å¢æè²çŽ ã®æ¿åºŠã¯ãïŒééïŒ ä»¥äžãé©åœã§ã
ãã奜ãŸããã¯0.1ééïŒ ä»¥äžã§ããã æ¬çºæã«ãŠäœè£œããããã²ã³åéä¹³å€ã®ååŠç
æéçšäžãŸãã¯ãä¹³å€å¡åžåã®ä»ã®éçšäžã«ãã
ãŠããã«åçš®ãŸãã¯å¥çš®ã®å¢æè²çŽ ãããã¯åŒ·è²
å¢æå€ãè¿œå æ·»å ããŠãè¯ãã 匷è²å¢æå€ãšããŠã¯äŸãã°ãå«çªçŽ ç°ç¯ç°åºã§
眮æãããã¢ããã¹ããªã«ååç©ïŒããšãã°ç±³åœ
ç¹èš±ç¬¬2933390å·ãå第3635721å·ã«èšèŒã®ãã®ïŒã
è³éŠæææ©é žãã«ã ã¢ã«ãããçž®åç©ïŒããšãã°
ç±³åœç¹èš±ç¬¬3743510å·ã«èšèŒã®ãã®ïŒãã«ãããŠã
å¡©ãã¢ã¶ã€ã³ãã³ååç©ãªã©ãå«ãã§ããããç±³
åœç¹èš±ç¬¬3615613å·ãå第3615641å·ãå第
3617295å·ãå第3635721å·ã«èšèŒã®çµåãã¯ç¹ã«
æçšã§ããã æ¬çºæã«ãããŠã¯å°ãªããšãïŒçš®ã®ããããç°
ãªãã¹ãã¯ãã«é åã«å¯èœæ§ãæããããã²ã³å
éãå¿ èŠã§ãããããã®éæ¬çºæã®ä¹³å€ãšéåžžã®
ããã²ã³åéç²å圢æåŸã«å¢æè²çŽ ãæ·»å ããŠè²
å¢æïŒã¹ãã¯ãã«é åã¯ç°ãªã€ãŠããŠããåãã§
ãè¯ãïŒããä¹³å€ãšã䜵çšããããšãå¯èœã§ã
ããæ·»å ããè²çŽ ããã³ãã®æº¶å€ã«ã€ããŠã¯å ã«
èšãããã®ãåèã«ããããšãã§ããã æ¬çºæã«äœ¿çšãããããã²ã³åéã¯ãå¡©åéã
èåéãæ²åéããããã¯å¡©èåéãå¡©æ²åéã
æ²èåéãå¡©æ²èåéã®ãããã§ããããç²åå
ã®ããã²ã³çµæãåäžã§ãã€ãŠããããè¡šé¢ãšå
éšã§çµæã®ç°ã€ãå€éæ§é ã§ãã€ãŠãããïŒç¹é
æ57â154232å·ãå58â108533å·ãå59â48755
å·ãå59â52237å·ãç±³åœç¹èš±ç¬¬4433048å·ããã³
殎å·ç¹èš±ç¬¬100984å·ïŒããŸããç²åã®åã¿ã0.5ã
ã¯ãã³ä»¥äžãç²åŸã¯å°ãªããšã0.6ãã¯ãã³ã§å¹³
åã¢ã¹ãã¯ãæ¯ãïŒä»¥äžã®å¹³æ¿ç²åïŒç±³åœç¹èš±ç¬¬
4414310å·ãå4435499å·ããã³***å ¬éç¹èš±
ïŒOLSïŒç¬¬3241646A1ãªã©ïŒãããã¯ç²åãµã€ãº
ååžã®åäžã«è¿ãååæ£ä¹³å€ïŒç¹éæ57â178235
å·ãå58â100846å·ãå58â14829å·ãåœéå ¬é
83ïŒ02338A1å·ã殎å·ç¹èš±ç¬¬64412A3ãããã³å
第83377A1ãªã©ïŒãæ¬çºæã«äœ¿çšããããæ¶çã
ããã²ã³çµæãç²åãµã€ãºãç²åãµã€ãºååžãªã©
ãç°ã€ãïŒçš®ä»¥äžã®ããã²ã³åéã䜵çšããŠãã
ããç²åãµã€ãºã®ç°ãªãäºçš®ä»¥äžã®ååæ£ä¹³å€ã
æ··åããŠãé調ã調ç¯ããããšãã§ããã æ¬çºæã§çšããããããã²ã³åéã®ç²åãµã€ãº
ã¯ãå¹³åç²åŸã0.001ãã¯ãã³ãã10ãã¯ãã³ã®
ãã®ã奜ãŸããã0.001ãã¯ãã³ãã5ÎŒã®ãã®ã¯
ããã«å¥œãŸããããããã®ããã²ã³åéä¹³å€ã¯ã
é žæ§æ³ãäžæ§æ³ãŸãã¯ã¢ã³ã¢ãã¢æ³ã®ãããã§èª¿
補ããŠããããå¯æº¶æ§éå¡©ãšå¯æº¶æ§ããã²ã³å¡©ãš
ã®åå¿åœ¢åŒãšããŠã¯ãçåŽæ··åæ³ãåææ··åæ³ãŸ
ãã¯ãããã®çµåãã®ãããã§ããããç²åãé
ã€ãªã³éå°ã®äžã§åœ¢æããéæ··åæ³ããŸãã¯pAg
ãäžå®ã«ä¿ã€ã³ã³ãããŒã«ãã»ããã«ãžãšããæ³
ãæ¡çšã§ããããŸããç²åæé·ãéãããããæ·»
å ããéå¡©ããã³ããã²ã³å¡©ã®æ·»å æ¿åºŠãæ·»å é
ãŸãã¯æ·»å é床ãäžæãããŠãããïŒç¹éæ55â
142329å·ãå55â158124å·ãç±³åœç¹èš±ç¬¬3650757
å·ãªã©ïŒã ãšãã¿ãã·ã¢ã«æ¥ååã®ããã²ã³åéç²åã䜿
çšã§ããïŒç¹éæ56â16124å·ãç±³åœç¹èš±ç¬¬
4094684å·ïŒã æ¬çºæã§ææ©éå¡©é žåå€ã䜵çšããã«ããã²ã³
åéãåç¬ã§äœ¿çšãããšãã¯ã奜ãŸããã¯æ²åé
çµæ¶ã®ïŒžç·ãã¿ãŒã³ãèªããããããªå¡©æ²åéã
æ²èåéãå¡©æ²èåéã§ãããäŸãã°èåã«ãªãŠ
ã 溶液äžã«ç¡é žé溶液ãæ·»å ããŠèåéç²åãäœ
ããããã«æ²åã«ãªãŠã ãæ·»å ãããšäžèšã®ç¹æ§
ãæããæ²èåéãåŸãããã æ¬çºæã§äœ¿çšããããã²ã³åéç²åã®åœ¢æ段é
ã«ãããŠãããã²ã³åé溶å€ãšããŠã¢ã³ã¢ãã¢ã
ç¹å ¬æ47â11386å·ã«èšèŒã®ææ©ããªãšãŒãã«èª
å°äœãŸãã¯ç¹éæ53â144319å·ã«èšèŒãããŠãã
å«ç¡«é»ååç©ãªã©ãçšããããšãã§ãããç²å圢
æãŸãã¯ç©ççæã®éçšã«ãããŠãã«ãããŠã
å¡©ãäºéå¡©ãéå¡©ãã¿ãªãŠã å¡©ãªã©ãå ±åãããŠ
ãããã ããã«é«ç §åºŠäžè»ãäœç §åºŠäžè»ãæ¹è¯ããç®ç
ã§å¡©åã€ãªãžãŠã ïŒïŒïŒããããµã¯ããã€ãª
ãžãŠã é žã¢ã³ã¢ããŠã ãªã©ã®æ°Žæº¶æ§ã€ãªãžãŠã
å¡©ããããã¯å¡©åããžãŠã ãªã©ã®æ°Žæº¶æ§ããžãŠã
å¡©ãçšããããšãã§ããã ããã²ã³åéã¯ä¹³å€ãšããŠçšããããããä¹³å€
ã¯æ²æŸ±åœ¢æåŸãããã¯ç©ççæåŸã«å¯æº¶æ§å¡©é¡ã
é€å»ããŠãããããã®ããããŒãã«æ°ŽæŽæ³ãæ²é
æ³ã«åŸãããšãã§ãããããã²ã³åéä¹³å€ã¯ãæª
åŸçã®ãŸãŸäœ¿çšããŠããããéåžžã¯ååŠå¢æããŠ
䜿çšãããéåžžåææçšä¹³å€ã§å ¬ç¥ã®ç¡«é»å¢æ
æ³ãéå å¢ææ³ã貎éå±å¢ææ³ãªã©ãåç¬ãŸãã¯
çµåããŠçšããããšãã§ããããããã®ååŠå¢æ
ãå«çªçŽ è€çŽ ç°ååç©ã®ååšäžã§ãè¡ãããšãã§
ããïŒç¹éæ58â126526å·ãå58â215644å·ïŒã æ¬çºæã®ããã²ã³åéä¹³å€ã¯ãäž»ãšããŠæœåã
ç²åè¡šé¢ã«åœ¢æãããè¡šé¢æœååã§ãã€ãŠããç²
åå éšã«åœ¢æãããå éšæœååã§ãã€ãŠãããã
å éšæœååä¹³å€ãšé æ žå€ãšãçµåããçŽæ¥å転乳
å€ã䜿çšããããšãã§ããããã®ç®çã«é©ããå
éšæœååä¹³å€ã¯ç±³åœç¹èš±ç¬¬2592250å·ãå第
3761276å·ãç¹å ¬æ58â3534å·ããã³ç¹éæ57â
136641å·ãªã©ã«èšèŒãããŠããã çµåããã®ã«å¥œãŸããé æ žå€ã¯ãç±³åœç¹èš±ç¬¬
3227552å·ãå第4245037å·ãå第4255511å·ãå
第4266013å·ãå第4276364å·ããã³***å ¬éç¹èš±
ïŒOLSïŒç¬¬2635316å·ã«èšèŒãããŠããã æ¬çºæã«ãããŠäœ¿çšãããæå æ§ããã²ã³åé
ã®å¡èšéã¯éæç®ïŒmgãªãã10ïœïŒm2ã®ç¯å²ã§ã
ãã æ¬çºæã«ãããŠã¯ãæå æ§ããã²ã³åéã«å ã«
察ããŠæ¯èŒçå®å®ãªææ©éå¡©ãé žåå€ãšããŠäœµçš
ããããšãã§ããããã®å Žåãæå æ§ããã²ã³å
éã®å¡èšéã¯éæç®ïŒmgãªãã10ïœïŒm2ã®ç¯å²ã§
ããã æ¬çºæã«ãããŠã¯ãæå æ§ããã²ã³åéã«å ã«
察ããŠæ¯èŒçå®å®ãªææ©éå¡©ãé žåå€ãšããŠäœµçš
ããããšãã§ããããã®å Žåãæå æ§ããã²ã³å
éãšææ©éå¡©ãšã¯æ¥è§Šç¶æ ãããã¯æ¥è¿ããè·é¢
ã«ããããšãå¿ èŠã§ããã80â以äžå¥œãŸããã¯
100â以äžã®æž©åºŠã«å ç±ããããšãããã²ã³åé
ã®æœåã觊åªãšããŠãææ©éå±é žåå€ãã¬ããã¯
ã¹ã«é¢äžãããšèããããã ãã®ãããªææ©éå¡©é žåå€ã圢æããã®ã«äœ¿çš
ãããææ©ååç©ãšããŠã¯ãèèªæãããã¯è³éŠ
æã®ã«ã«ãã³é žãã¡ã«ã«ããåºãããã¯Î±âæ°ŽçŽ
ãæããããªã«ã«ããã«åºå«æååç©ãããã³ã€
ããåºå«æååç©ãªã©ãæããããã èèªæã«ã«ãã³é žã®éå¡©ãšããŠã¯ãããã³é žã
ã¹ãã¢ãªã³é žããªã¬ã€ã³é žãã©ãŠãªã³é žãã«ããª
ã³é žãããªã¹ãã³é žããã«ããã³é žããã¬ã€ã³
é žããããŒã«é žãé ç³é žãããã€ã³é žããªããŒã«
é žããªãã¬ã³é žããªã¬ã€ã³é žãã¢ãžãã³é žãã»ã
ã·ã³é žããã¯ãé žãé ¢é žãé ªé žããŸãã¯æšè³é žã
ãèªå°ãããéå¡©ãå žåäŸãšããŠæãããããã
ããã®èèªæã®ããã²ã³ååãããã¯æ°Žé žåºçœ®æ
äœãŸãã¯ããªãšãŒãã«åºãæããèèªæã«ã«ãã³
é žãªã©ããèªå°ãããéå¡©ããŸã䜿çšã§ããã è³éŠæã«ã«ãã³é žããã³ãã®ä»ã®ã«ã«ããã·ã«
åºå«æååç©ã®éå¡©ãšããŠãå®æ¯éŠé žãïŒïŒïŒâ
ãžããããã·å®æ¯éŠé žãïœâãïœâãããã¯ïœâ
ã¡ãã«å®æ¯éŠé žãïŒïŒïŒâãžã¯ãã«å®æ¯éŠé žãã¢
ã»ãã¢ããå®æ¯éŠé žãïœâããšãã«å®æ¯éŠé žã没
é£åé žãã¿ã³ãã³é žããã¿ã«é žããã¬ãã¿ã«é žã
ãµãªãã«é žãããšãã«é ¢é žãããã¡ãªããé žãŸã
ã¯ïŒâã«ã«ããã·ã¡ãã«âïŒâã¡ãã«âïŒâãã¢
ãŸãªã³âïŒâããªã³ãªã©ããèªå°ãããéå¡©ã代
è¡šäŸãšããŠæããããã ã¡ã«ã«ãããããã¯ããªã«ã«ããã«åºãæãã
ååç©ã®éå¡©ãšããŠã¯ãïŒâã¡ã«ã«ããâïŒâã
ãšãã«âïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«ãïŒâã¡ã«ã«
ãããã³ãŸã€ãããŸãŒã«ãïŒâã¡ã«ã«ããâïŒâ
ã¢ãããã¢ãžã¢ãŸãŒã«ãïŒâã¡ã«ã«ãããã³ãã
ã¢ãŸãŒã«ãâã¢ã«ãã«ããªã°ãªã³ãŒã«é žïŒã¢ã«
ãã«åºççŽ æ°12ãªãã22ïŒããžããªé ¢é žãªã©ãžã
ãªã«ã«ãã³é žé¡ãããªã¹ãã¢ãã¢ãããªã©ããªã¢
ããé¡ãïŒâã«ã«ããã·âïŒâã¡ãã«âïŒâããš
ãã«âïŒâããªããªãžã³ãã¡ã«ã«ããããªã¢ãž
ã³ãïŒâã¡ã«ã«ãããã³ãŸãªããµãŸãŒã«ãã¡ã«ã«
ãããªããµãžã¢ãŸãŒã«ãŸãã¯ïŒâã¢ããâïŒâã
ã³ãžã«ããªâïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«ãªã©ç±³åœ
ç¹èš±ç¬¬4123274å·èšèŒã®ã¡ã«ã«ããååç©ãªã©ã
ãèªå°ãããéå¡©ãæããããã ã€ããåºãæããååç©ã®éå¡©ãšããŠã¯ãç¹å ¬
æ44â30270å·ãŸãã¯å45â18416å·èšèŒã®ãã³ãŸ
ããªã¢ãŸãŒã«ãããã¯ãã®èªå°äœäŸãã°ãã³ãŸã
ãªã¢ãŸãŒã«ãã¡ãã«ãã³ãŸããªã¢ãŸãŒã«ãªã©ã¢ã«
ãã«çœ®æãã³ãŸããªã¢ãŸãŒã«é¡ãïŒâã¯ãããã³
ãŸããªã¢ãŸãŒã«ãªã©ããã²ã³çœ®æãã³ãŸããªã¢ãŸ
ãŒã«é¡ãããã«ã«ã«ãã€ãããã³ãŸããªã¢ãŸãŒã«
ãªã©ã«ã«ãã€ãããã³ãŸããªã¢ãŸãŒã«é¡ãç¹éæ
58â118639å·èšèŒã®ããããã³ãŸããªã¢ãŸãŒã«
é¡ãç¹éæ58â118638å·èšèŒã®ã¹ã«ããã³ãŸããª
ã¢ãŸãŒã«ãã«ã«ããã·ãã³ãŸããªã¢ãŸãŒã«ããã
ã¯ãã®å¡©ããŸãã¯ããããã·ãã³ãŸããªã¢ãŸãŒã«
ãªã©ãç±³åœç¹èš±ç¬¬4220709å·èšèŒã®ïŒïŒïŒïŒïŒâ
ããªã¢ãŸãŒã«ã1Hâããã©ãŸãŒã«ãã«ã«ããŸãŒ
ã«ããµãã«ãªã³ãã€ãããŸãŒã«ããã³ãã®èªå°äœ
ãªã©ããèªå°ãããéå¡©ã代衚äŸãšããŠæããã
ãã ãŸããªãµãŒãã»ãã€ã¹ã¯ããŒãžã€ãŒèª17029
ïŒ1978幎ïŒæïŒã«èšèŒãããŠããéå¡©ãã¹ãã¢ãª
ã³é žé ãªã©ã®é塩以å€ã®ææ©éå±å¡©ãç¹é¡æ58â
221535å·èšèŒã®ããšãã«ããããªãŒã«é žãªã©ã¢ã«
ããã«åºãæããã«ã«ãã³é žã®éå¡©ãæ¬çºæã§äœ¿
çšã§ããã 以äžã®ææ©éå¡©ã¯æå æ§ããã²ã³åéïŒã¢ã«ã
ããã0.01ãªãã10ã¢ã«ã奜ãŸããã¯0.01ãªãã
ïŒã¢ã«ã䜵çšããããšãã§ãããæå æ§ããã²ã³
åéãšææ©éå¡©ã®å¡åžéåèšã¯ïŒmgãªãã10ïœïŒ
m2ãé©åœã§ããã æ¬çºæã«çšããããä¹³å€ã«ã¯ãæå ææã®è£œé
å·¥çšãä¿åäžãããã¯åçåŠçäžã®ã«ããªãé²æ¢
ãããããã¯åçæ§èœãå®å®åãããç®çã§ã
çš®ã ã®ååç©ãå«æãããããšãã§ããã ããªãã¡ã¢ãŸãŒã«é¡ãäŸãã°ãã³ãŸãã¢ãŸãªãŠ
ã å¡©ããããã€ãããŸãŒã«é¡ãããããã³ãºã€ã
ããŸãŒã«é¡ãã¯ãããã³ãºã€ãããŸãŒã«é¡ããã
ã¢ãã³ãºã€ãããŸãŒã«é¡ãã¡ã«ã«ãããã¢ãŸãŒã«
é¡ãã¡ã«ã«ãããã³ãŸãã¢ãŸãŒã«é¡ãã¡ã«ã«ãã
ãã³ãºã€ãããŸãŒã«é¡ãã¡ã«ã«ãããã¢ãžã¢ãŸãŒ
ã«é¡ãã¢ããããªã¢ãŸãŒã«é¡ããã³ãŸããªã¢ãŸãŒ
ã«é¡ãããããã³ãŸããªã¢ãŸãŒã«é¡ãã¡ã«ã«ãã
ããã©ãŸãŒã«é¡ïŒç¹ã«ïŒâããšãã«âïŒâã¡ã«ã«
ããããã©ãŸãŒã«ïŒãªã©ïŒã¡ã«ã«ããããªããžã³
é¡ïŒã¡ã«ã«ããããªã¢ãžã³é¡ïŒããšãã°ãªããµã
ãªã³ããªã³ã®ãããªããªã±ãååç©ïŒã¢ãžã€ã³ã
ã³é¡ãããšãã°ããªã¢ã¶ã€ã³ãã³é¡ïŒããã©ã¢ã¶
ã€ã³ãã³é¡ïŒç¹ã«ïŒâããããã·çœ®æïŒïŒïŒïŒïŒ
3aïŒïŒïŒããã©ã¢ã¶ã€ã³ãã³é¡ïŒããã³ã¿ã¢ã¶ã€
ã³ãã³é¡ãªã©ïŒãã³ãŒã³ããªã¹ã«ããªã³é žããã³
ãŒã³ã¹ã«ãã€ã³é žããã³ãŒã³ã¹ã«ããªã³é žã¢ãã
çã®ãããªã«ããªé²æ¢å€ãŸãã¯å®å®å€ãšããŠç¥ã
ãããå€ãã®ååç©ãå ããããšãã§ãããããš
ãã°ç±³åœç¹èš±ç¬¬3954474å·ãå第3982947å·ãç¹å ¬
æ52â28660å·çã«èšèŒããããã®ãçšããããš
ãã§ããã æ¬çºæã®ããã²ã³åé調補æ³ã«ãããŠã¯ãä¿è·
ã³ãã€ããšããŠãŒã©ãã³ãçšããã®ãæå©ã§ãã
ãããã以å€ã®èŠªæ°Žæ§ã³ãã€ããçšããããšãã§
ããã ããšãã°ãŒã©ãã³èªå°äœããŒã©ãã³ãšä»ã®é«å
åãšã®ã°ã©ããããªããŒãã¢ã«ããã³ãã«ãŒã€ã³
çã®èçœè³ªïŒããããã·ãšãã«ã»ã«ããŒã¹ãã«ã«
ããã·ã¡ãã«ã»ã«ããŒã¹ãã»ã«ããŒã¹ç¡«é žãšã¹ã
ã«é¡çã®ãããªã»ã«ããŒã¹èªå°äœãã¢ã«ã®ã³é žãœ
ãŒãã柱ç²èªå°äœãªã©ã®ç³èªå°äœïŒããªããã«ã¢
ã«ã³ãŒã«ãããªããã«ã¢ã«ã³ãŒã«éšåã¢ã»ã¿ãŒ
ã«ãããªââããã«ãããªãã³ãããªã¢ã¯ãªã«
é žãããªã¡ã¿ã¯ãªã«é žãããªã¢ã¯ãªã«ã¢ãããã
ãªããã«ã€ãããŸãŒã«ãããªããã«ãã©ãŸãŒã«ç
ã®åäžãããã¯å ±éåäœã®ãããªå€çš®ã®åæ芪氎
æ§é«ååç©è³ªãçšããããšãã§ããã ãŒã©ãã³ãšããŠã¯ç³ç°åŠçãŒã©ãã³ã®ã»ãé žåŠ
çãŒã©ãã³ãããªãã³ ãªã 㶠ãœãµã€ã€ãã€
ãªã ãµã€ãšã³ããã€ã㯠ããªãã°ã©ãã€
ãªã ãžã€ãã³ïŒBull.Soc.Sci.Phot.JapanïŒïŒã
ã³ããŒïŒNo.ïŒ16ã30é ïŒ1966ïŒã«èšèŒããããã
ãªé µçŽ åŠçãŒã©ãã³ãçšããŠãããããŸããŒã©ã
ã³ã®å æ°Žå解ç©ãé µçŽ å解ç©ãçšããããšãã§ã
ãã æ¬çºæã«äœ¿çšã§ããéå å€ãšããŠã¯ç¹å ¬æ47â
20741ãå第45â11149å·ãå第49â10697å·ãå
第57â138632å·ãå第58â169143å·æ现æžã«èšèŒ
ã®ååç©ãäŸãã°ã¬ãŸã«ã·ã³é¡ãã¢ããããšããŒ
ã«é¡ãããšãã¬ã³ãžã¢ãã³é¡ãïŒâãã©ãŸãã³
é¡ãã¢ã«ãã«ããšããŒã«é¡ãã¢ã«ã³ãã·ããšããŒ
ã«é¡ãããããŒã«é¡ãã¢ããããããŒã«é¡ããã
ã¿ã¬ã³ãžãªãŒã«é¡ãã¢ã«ã³ãã·ããããŒã«é¡ãã
ãã©ãžã³é¡çãå©çšã§ããã ãããã®å ·äœäŸãšããŠã¯ã¬ãŸã«ã·ã³ãïŒâã¡ã
ã«ã¬ãŸã«ã·ã³ããªã«ã·ã³ããããã°ã«ã·ã³ããã
ãã°ã«ã·ã³ã¢ãã¡ãã«ãšãŒãã«ããããã°ã«ã·ã³
ãžã¡ãã«ãšãŒãã«ãïœâã¢ããããšããŒã«ãïœâ
ãžã¡ãã«ã¢ããããšããŒã«ãïœâãžãšãã«ã¢ãã
ããšããŒã«ãïŒïŒ®âãžã¡ãã«âïœâããšãã¬ã³
ãžã¢ãã³ãïŒïŒ®âãžãšãã«âïœâããšãã¬ã³ãž
ã¢ãã³ãïŒâã¡ãã«âïŒâãã©ãŸãã³ãïŒïŒïŒâ
ãžã¡ãã«âïŒâãã©ãŸãã³ãïŒïŒïŒâãžã¡ãã«â
ïŒâãã©ãŸãã³ãïŒâããšãã«âïŒâã¡ãã«âïŒ
âãã©ãŸãã³ãâãšãã«ããšããŒã«ãâãã
ã·ã«ããšããŒã«ãâã¡ããã·ããšããŒã«ãâ
ãã³ãžã«ãªãã·ããšããŒã«ãâããããã·ãžã
ãšãã«ãšãŒãã«ãïŒâã¡ãã«âïŒâããããŒã«ã
ïŒâã¡ãã«âïŒâããããŒã«ãïŒâã¡ãã«âïŒâ
ããããŒã«ãïŒâã¢ããâïŒâããããŒã«ãïŒâ
ã¢ããâïŒâããããŒã«ãïŒïŒïŒâãžããããã·
ããã¿ã¬ã³ãïŒâã¡ããã·âïŒâããããŒã«ã
âããªã«ããã©ãžã³å¡©é žå¡©ãâããªã«ããã©ãž
ã³å¡©é žå¡©ãã¢ã»ãããã©ãžãããã³ãºããã©ãž
ãããã«ãšã³ã¹ã«ããã«ããã©ãžã³ãïŒNâ²â
ãžã¢ã»ãã«ããã©ãžã³ãβâã¢ã·ã«ããšãã«ãã
ã©ãžã³é¡ãäŸãã°Î²âã¢ã»ãã«ããšãã«ããã©ãž
ã³ãβâã¢ã»ãã«ââããªã«ããã©ãžã³ãβâ
ã¢ã»ãã«ââã¡ããã·ããšãã«ããã©ãžã³ãβ
âã¢ã»ãã«ââã¢ããããšãã«ããã©ãžã³ãβ
âãã«ãã«ââã¢ããããšãã«ããã©ãžã³ãβ
âãã«ãã«âïŒïŒïŒâãžã¡ãã«ããšãã«ããã©ãž
ã³ãβâãã³ãŸã€ã«âïŒïŒïŒâãžã¡ããã·ããšã
ã«ããã©ãžã³ãβâãããã€ã«ââããªã«ãã
ã©ãžã³ãβâãããã€ã«ââã¢ã»ãã«ã¢ããã
ãšãã«ããã©ãžã³ãβâããããªãã«ââãžã¡
ãã«ã¢ããããšãã«ããã©ãžã³ãβâãšããã·ã«
ã«ããã«ââã¢ããããšãã«ããã©ãžã³ãβâ
ãžã¡ãã«ã«ã«ãã¢ã€ã«ââãã³ãŒã³ã¹ã«ãã³ã¢
ããããšãã«ããã©ãžã³ãβâã¢ã«ããªãã«ã«ã
ãã«ââã¢ããããšãã«ããã©ãžã³çãæãã
ããããããã®éå å€ã¯å¿ èŠã«å¿ããŠäºçš®ä»¥äžã
䜵çšããããšãã§ããããŸããäžèšã®éå å€ãšã³
ã³ãã³ã·ãšãã«åçç³»ã®çŸåè¬ãäŸãã°ãã€ãã
ããã³ãã«ãã³ãŒã«ãâ眮æã¢ããããšããŒã«
é¡ãâããšãã¬ã³ãžã¢ãã³é¡ãïŒâãã©ãŸãªã
ã³é¡çã䜵çšããããšãã§ãããéå å€ã®æ·»å é
ã¯å·Ÿåºãå€ããããšãã§ããããäžè¬ã«ã¯éå¡©ã«
察ãã0.1ã1500ã¢ã«ïŒ ã奜ãŸããã¯10ã300ã¢ã«
ïŒ ã§ãããæ¬çºæã«äœ¿çšã§ããéåæ§ååç©ãšã
ãŠã¯ãä»å éåæ§ã®ã¢ãããŒããã³ãã®ãªãªãŽã
ãŒãããªããŒãæããããšãã§ãããä»å éåæ§
ã®ã¢ãããŒãšããŠã¯ãççŽ âççŽ äžé£œåçµåãïŒ
å以äžæããååç©ãå©çšã§ããããããã®äŸãš
ããŠã¯ã¢ã¯ãªã«é žããã³ãã®å¡©ãã¢ã¯ãªã«é žãšã¹
ãã«é¡ãã¢ã¯ãªã«ã¢ããé¡ãã¡ã¿ã¯ãªã«é žããã³
ãã®å¡©ãã¡ã¿ã¯ãªã«é žãšã¹ãã«é¡ãã¡ã¿ã¯ãªã«ã¢
ããé¡ãç¡æ°Žãã¬ã€ã³é žããã¬ã€ã³é žãšã¹ãã«
é¡ãã€ã¿ã³ã³é žãšã¹ãã«é¡ãã¹ãã¬ã³é¡ãããã«
ãšãŒãã«é¡ãããã«ãšã¹ãã«é¡ãâããã«è€çŽ
ç°é¡ãã¢ãªãŒã«ãšãŒãã«é¡ãã¢ãªãŒã«ãšã¹ãã«é¡
ããã³ãããã®èªå°äœãããã ãããã®ååç©ã¯ããããæ¬çºæã«æçšã§ãã
ããæ¬çºæã§ã¯å ç±çŸååŠçãè¡ãªãããå ç±æ
ã«æ®æ£ãã«ããã沞ç¹ã80â以äžã®ãã®ã奜ãŸã
ãããŸãåŸãããè²ç»åã®ïŒ³ïŒïŒ®æ¯ãé«ãããã
ã«ãçæããé«ååååç©ã®ç²åºŠãŸãã¯ç¡¬å床ã
é«ããäœçšãæããæ¶æ©æ§ååç©ã䜵çšããããš
ãæãŸãããããã§èšãæ¶æ©æ§ååç©ãšã¯ååäž
ã«è€æ°ã®ããã«åºãŸãã¯ãããªãã³åºãæããã
ããããå€å®èœã¢ãããŒã§ããã以äžã«æ¬çºæã«
䜿çšãããéåæ§ååç©ã®å¥œãŸããäŸã瀺ãã ã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žãã¢ã¯ãªã«é žãã
ã«ãã¢ã¯ãªã«é žã¡ããã·ãšãã«ãã¡ã¿ã¯ãªã«é žã
ãã«ãã¢ã¯ãªã«ã¢ãããïŒïŒ®âãžã¡ãã«ã¢ã¯ãª
ã«ã¢ãããïŒïŒ®âãžãšãã«ã¢ã¯ãªã«ã¢ããã
âã¢ã¯ãªãã€ã«ã¢ã«ããªã³ãâã¢ã¯ãªãã€ã«ã
ããªãžã³ãã°ãªã·ãžã«ã¢ã¯ãªã¬ãŒããïŒâãšãã«
ããã·ã«ã¢ã¯ãªã¬ãŒããã¢ã¯ãªã«é žã¢ããªããã¡
ã¿ã¯ãªã«é žã¢ããªããã¹ãã¬ã³ãããã«ãã«ãš
ã³ãã¯ããã¹ãã¬ã³ãã¡ããã·ã¹ãã¬ã³ãã¯ãã
ã¡ãã«ã¹ãã¬ã³ãïŒâããã«âïŒâã¡ãã«ã€ãã
ãŸãŒã«ãïŒâããã«âïŒâãŠã³ãã·ã«ã€ãããŸãŒ
ã«ãïŒâããã«âïŒâãŠã³ãã·ã«ã€ãããŸãªã³ã
âããã«ãããªãã³ãâããã«ã«ã«ããŸãŒ
ã«ãããã«ãã³ãžã«ãšãŒãã«ãããã«ããšãã«ãš
ãŒãã«ãã¡ãã¬ã³âãã¹âã¢ã¯ãªã«ã¢ãããããª
ã¡ãã¬ã³âãã¹âã¢ã¯ãªã«ã¢ããããããµã¡ãã¬
ã³âãã¹âã¢ã¯ãªã«ã¢ãããïŒNâ²âãžã¢ã¯ãª
ãã€ã«ããã©ãžã³ãïœâããšãã¬ã³âãã¹âã¢ã¯
ãªã«ã¢ãããâããšãã¬ã³âãã¹âã¢ã¯ãªã«ã¢
ããããšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãããã
ãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒãããžãšãã¬ã³
ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒããããªãšãã¬ã³ã°ãªã³
ãŒã«ãžã¢ã¯ãªã¬ãŒãããã¹ïŒïŒâã¢ã¯ãªããã·ã
ãªãšããã·ããšãã«ïŒãããã³ãïŒïŒïŒâãã³ã¿
ã³ãžãªãŒã«ãžã¢ã¯ãªã¬ãŒããããªãã³ãã«ã°ãªã³
ãŒã«ãžã¢ã¯ãªã¬ãŒããïŒïŒïŒâãããµã³ãžãªãŒã«
ã¢ã¯ãªã¬ãŒããããªãããã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯
ãªã¬ãŒãããã³ã¿ãšãªã¹ãªããŒã«ããªã¢ã¯ãªã¬ãŒ
ããããªã¡ãããŒã«ãããã³ããªã¢ã¯ãªã¬ãŒãã
ãã³ã¿ãšãªã¹ãªããŒã«ããã©ã¢ã¯ãªã¬ãŒããâ
ã¡ãããŒã«ã¢ã¯ãªã«ã¢ããããžã¢ã»ãã³ã¢ã¯ãªã«
ã¢ãããããªãšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒ
ãããã³ã¿ãšãªã¹ãªããŒã«ããã©ã¢ãªãŒã«ãšãŒã
ã«ã ãŸããããã«åºãŸãã¯ãããªãã³åºãæããé«
ååååç©ãäŸãã°ãåŽéã«ããããã·ã«åºãã¢
ããåºããšããã·åºãããã²ã³ååãã¹ã«ããã«
ãªãã·åºãæããé«ååååç©ãšã¢ã¯ãªã«é žãã¡
ã¿ã¯ãªã«é žãããã¯ãããã®èªå°äœãšã®çž®åç©ç
ãæ¬çºæã«å©çšã§ããã ããã«ãåè¿°ã®éå å€ã®æ¯æ žã«ããã«åºããã
ãªãã³åºãçµåããååç©ãäŸãã°ãïœâïŒïŒ®
âãžïŒã¢ã¯ãªãã€ã«ãªãã·ãšãã«ïŒã¢ããããšã
ãŒã«ãâã¢ã¯ãªãã€ã«ãªãã·ãšããã·ããšããŒ
ã«çãéåæ§ååç©ãšããŠå©çšã§ãããã®å Žåã«
ã¯ãéå å€ãšéåæ§ååç©ãå Œçšããããšãã§ã
ããããã«ãè²ç»å圢æç©è³ªãäŸãã°è²çŽ ãŸãã¯
ãã€ã³è²çŽ ã®ååäžã«ããã«åºãå«æããååç©
ãéåæ§ååç©ãšããŠå©çšã§ãããã®å Žåã«ã¯é
åæ§ååç©ãšè²ç»å圢æç©è³ªãå Œããããšãã§ã
ãã æ¬çºæã®éåæ§ååç©ã¯ããã²ã³åéå¡©ïŒéé
éšã«å¯ŸããŠïŒãªãã1.2Ã105éééšã奜ãŸããã¯
12ãªãã1.2Ã104éééšçšããããšãã§ããã æ¬çºæã«å©çšã§ããè²ç»å圢æç©è³ªã«ã¯çš®ã ã®
ãã®ããããäŸãã°ãããèªèº«ãçè²ããŠããã
ã®ãšããŠææãé¡æãæãããããããããçšã
ãå Žåã«ã¯ãé«ååéåç©ãçæããŠããªãéšå
ïŒãã€ã¯ãã«ãã»ã«ïŒãç Žå£ããŠååææã«é©åœ
ãªæ¹æ³ãçšããŠè»¢åããããšã«ããè²ç»åã圢æ
ããããšãã§ãããææãé¡æã¯åžè²©ã®ãã®ã®
ä»ãåçš®æç®çïŒäŸãã°ãææ䟿芧ãææ©åæå
åŠåäŒç·šéãæå45幎åããææ°é¡æ䟿芧ãæ¥æ¬
é¡ææè¡åäŒç·šéãæå52幎åïŒã«èšèŒãããŠã
ãå ¬ç¥ã®ãã®ãå©çšã§ããããããã®ææãŸãã¯
é¡æã¯ã溶解ãªããåæ£ããŠçšããããã äžæ¹ãçè²ããŠããªãè²ç»å圢æç©è³ªãšããŠ
ã¯ãããèªèº«ã¯ç¡è²ãªããæ·¡è²ã§ãããå ç±ãå
å§ãå ç §å°çãäœããã®ãšãã«ã®ãŒã«ããçºè²ã
ããã®ãšããèªèº«ã¯ãšãã«ããŒãå ããŠãçºè²ã
ãªãããå¥ã®æåãšæ¥è§Šããããšã«ããçºè²ãã
ãã®ã«åé¡ããããåè ã®äŸãšããŠã¯ãµãŒã¢ã¯ã
ããã¯ååç©ãããšãŸã¯ãããã¯ååç©ãããã¯
ãããã¯ååç©ããã³ããªã¢ãªãŒã«ã¡ã¿ã³ææã
ããã³ç³»ææãã€ã³ãžãŽã€ãææãã¢ãžã³ææç
ã®ãã€ã³äœãªã©ãç¥ãããŠããããããã¯ããã
ãå ç±ãå å§ãå ç §å°ãããã¯ç©ºæ°é žåã«ããçº
è²ãããã®ã§ãããåŸè ã®äŸãšããŠã¯ïŒçš®ä»¥äžã®
æåã®éã®é žå¡©åºåå¿ãé žåéå åå¿ãã«ãããª
ã³ã°åå¿ããã¬ãŒã圢æåå¿çã«ããçºè²ãã
çš®ã ã®ã·ã¹ãã ãå å«ããããäŸãã°ãæå§çŽç
ã«å©çšãããŠããã©ã¯ãã³ãã©ã¯ã¿ã ãã¹ããã
ã©ã³çã®éšåæ§é ãæããçºè²å€ãšé žæ§çœåãã
ãšããŒã«é¡çã®é žæ§ç©è³ªïŒé¡è²å€ïŒãããªãçºè²
ã·ã¹ãã ïŒè³éŠæãžã¢ãŸããŠã å¡©ããžã¢ãŸã¿ãŒ
ãããžã¢ãŸã¹ã«ãããŒãé¡ãšããããŒã«é¡ãã¢ã
ãªã³é¡ã掻æ§ã¡ãã¬ã³é¡çã®ã¢ãŸã«ãããªã³ã°å
å¿ãå©çšããã·ã¹ãã ïŒãããµã¡ãã¬ã³ããã©ã
ã³ãšç¬¬ïŒéã€ãªã³ããã³æ²¡é£åé žãšã®åå¿ãããš
ããŒã«ãã¿ã¬ã€ã³âã³ã³ãã¬ã¯ãœã³é¡ãšã¢ã«ã«ãª
åé¡éå±ã€ãªã³ãšã®åå¿ãªã©ã®ãã¬ãŒã圢æå
å¿ïŒã¹ãã¢ãªã³é žç¬¬ïŒéãšããã¬ããŒã«ãšã®åå¿
ãããã³é žéãšïŒâã¡ããã·âïŒâããããŒã«ã®
åå¿ãªã©ã®é žåéå åå¿ãªã©ãå©çšã§ããã ãŸããåããïŒæåã®éã®åå¿ã«ããçºè²ãã
ã·ã¹ãã ã®ä»ã®äŸãšããŠããã®åå¿ãå ç±ã«ãã
é²è¡ããå Žåãç¥ãããŠããããã®å Žåã«ã¯å å§
æã®ãã€ã¯ãã«ãã»ã«ç Žå£ã«ãã€ãŠïŒæåãæ··å
ããããšåææãã¯å å§ã®çŽåŸã«å ç±ããããšã
å¿ èŠã§ããã çºè²å€ïŒé¡è²å€ã·ã¹ãã ã«ãããçºè²å€ãšããŠ
ã¯ã(1)ããªã¢ãªãŒã«ã¡ã¿ã³ç³»ã(2)ãžããšãã«ã¡ã¿
ã³ç³»ã(3)ããµã³ãã³ç³»ã(4)ãã¢ãžã³ç³»ã(5)ã¹ãã
ãã©ã³ç³»ååç©ãªã©ããããå ·äœçãªäŸãšããŠ
ã¯ãç¹éæ55â27253å·çã«èšèŒãããŠãããã®
çãããããããäžã§ã(1)ããªã¢ãªãŒã«ã¡ã¿ã³
ç³»ã(3)ããµã³ãã³ç³»ã®çºè²å€ã¯ã«ããªãå°ãªãã
é«ãçºè²æ¿åºŠãäžãããã®ãå€ã奜ãŸãããå ·äœ
äŸãšããŠã¯ãã¯ãªã¹ã¿ã«ãã€ãªã¬ããã©ã¯ãã³ã
ïŒâãžãšãã«ã¢ããâïŒâã¯ããâïŒâïŒÎ²âãš
ããã·ãšãã«ã¢ããïŒãã«ãªã©ã³ãïŒâãžãšãã«
ã¢ããâïŒâã¡ãã«âïŒâã¢ããªããã«ãªã©ã³ã
ïŒâããªãšãã«ã¢ããâïŒâã¡ãã«âïŒâã¢ããª
ããã«ãªã©ã³ãïŒâã·ã¯ãããã·ã«ã¡ãã«ã¢ãã
âïŒâã¡ãã«âïŒâã¢ããªããã«ãªã©ã³ãïŒâãž
ãšãã«ã¢ããâïŒâïœâã¯ããã¢ããªããã«ãªã©
ã³çãããããããã¯åç¬ãããã¯æ··åããŠçšã
ãããã é¡è²å€ãšããŠã¯ãããšããŒã«ç³»ååç©ãææ©é ž
ãããã¯ãã®éå±å¡©ããªãã·å®æ¯éŠé žãšã¹ãã«ã
é žæ§çœåãªã©ãçšããããã ããšããŒã«ååç©ã®äŸã瀺ãã°ãïŒïŒ4â²âã€ãœ
ããããªãã³âãžããšããŒã«ïŒãã¹ããšããŒã«
ïŒãïœâtertâããã«ããšããŒã«ãïŒïŒïŒâãž
ãããããšããŒã«ãïŒïŒïŒâãžã¯ããããšããŒ
ã«ãïŒïŒ4â²âã¡ãã¬ã³âãã¹ïŒïŒïŒïŒâãžãŒtert
âããã«ããšããŒã«ïŒãïœâããšãã«ããšããŒã«ã
ïŒïŒïŒâãã¹ïŒïŒâããããã·ããšãã«ïŒã·ã¯ã
ãããµã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·ããšã
ã«ïŒâïŒâãšãã«ãããµã³ãïŒïŒïŒâãã¹ïŒïŒâ
ããããã·ããšãã«ïŒãã¿ã³ãïŒïŒ2â²âã¡ãã¬ã³
ãã¹ïŒïŒâtertâããã«ããšããŒã«ïŒãïŒïŒ2â²âã¡
ãã¬ã³ãã¹ïŒÎ±âããšãã«âïœâã¯ã¬ãŸãŒã«ïŒã
ãªãžããšããŒã«ãïŒïŒ4â²âããªãã¹ïŒïŒâtertâ
ããã«âïœâã¯ã¬ãŸãŒã«ïŒã¹ã«ããã«ãžããšããŒ
ã«ã®ã»ããïœâtertâããã«ããšããŒã«âãã«ã
ãªã³çž®åç©ãïœâããšãã«ããšããŒã«ãã«ããªã³
çž®åç©ãªã©ãããã ææ©é žãããã¯ãã®éå±å¡©ãšããŠã¯ããã¿ã«
é žãç¡æ°Žãã¿ã«é žããã¬ã€ã³é žãå®æ¯éŠé žã没é£
åé žãïœâãã«ã€ã«é žãïœâãã«ã€ã«é žããµãªã
ã«é žãïŒâtertâããã«ãµãªãã«é žãïŒïŒïŒâãž
âtertâããã«ãµãªãã«é žãïŒâαâã¡ãã«ãã³
ãžã«ãµãªãã«é žãïŒïŒïŒâïŒÎ±âã¡ãã«ãã³ãžã«ïŒ
ãµãªãã«é žãïŒâtertâãªã¯ãã«ãµãªãã«é žãã
ã³ãã®äºéãéãã¢ã«ãããŠã å¡©ããã°ãã·ãŠã
å¡©ãããã±ã«å¡©çãæçšã§ãããç¹ã«ãµãªãã«é ž
èªå°äœããã³ãã®äºéå¡©ããŸãã¯ã¢ã«ãããŠã å¡©
ã¯ãé¡è²èœãçºè²åã®å ç¢æ§ãèšé²ã·ãŒãã®ä¿å
æ§ãªã©ã®ç¹ã§ããããŠããã ãªãã·å®æ¯éŠé žãšã¹ãã«ãšããŠã¯ãïœâãªãã·
å®æ¯éŠé žãšãã«ãïœâãªãã·å®æ¯éŠé žããã«ãïœ
âãªãã·å®æ¯éŠé žãžããã«ãïœâãªãã·å®æ¯éŠé ž
ãã³ãžã«çãããã åãåžæ²¹æ§ã®çœè²é¡æã䜵çšããŠãã«ãã»ã«å
å ç©ã®æ¡æ£ãšåºå®åãã¯ããããšãã§ããã ãããã®é¡è²å€ã¯åžæãã枩床ã§è解ããçºè²
åå¿ãçããããããã«ãäœèç¹ã®ç±å¯èæ§ç©è³ª
ãšã®å ±èç©ãšããŠæ·»å ãããããŸãã¯äœèç¹åå
ç©ãé¡è²å€ç²åã®è¡šé¢ã«èçããŠããç¶æ ã§æ·»å
ããäºã奜ãŸããã äœèç¹ååç©ã®å ·äœçäŸãšããŠã¯ãé«çŽèèªé ž
ã¢ãããäŸãã°ã¹ãã¢ãªã³é žã¢ããããšã«ã«é žã¢
ããããã«ããã³é žã¢ããããšãã¬ã³ãã¹ã¹ãã¢
ãã¢ãããããã¯é«çŽèèªé žãšã¹ãã«çã®ã¯ãã¯
ã¹é¡ããããã¯å®æ¯éŠé žããšãã«èªå°äœãè³éŠæ
ãšãŒãã«èªå°äœããããã¯å°¿çŽ èªå°äœããããã
ããã«éå®ããããã®ã§ã¯ãªãã å¥ãªçºè²å€ïŒé¡è²å€ã·ã¹ãã ã®çºè²å€ãšããŠ
ã¯ãäŸãã°ããšããŒã«ãã¿ã¬ã€ã³ããã«ãªã¬ãã»
ã€ã³ã2â²ïŒ4â²ïŒ5â²ïŒ7â²âããã©ããã¢âïŒïŒïŒïŒ
ïŒïŒïŒâããã©ã¯ãããã«ãªã¬ãã»ã€ã³ãããã©
ããã¢ããšããŒã«ãã«ãŒãïŒïŒïŒïŒïŒïŒïŒâãã
ã©ããã¢ããšããŒã«ãã¿ã¬ã€ã³ããšãªã·ã³ãã¢ãŠ
ãªã³ã¯ã¬ãŸãŒã«ã¬ãããïŒâããããŒã«ããšããŒ
ã«ãã¿ã¬ã€ã³ãªã©ãããã é¡è²å€ãšããŠã¯ãç¡æ©ããã³ææ©ã¢ã³ã¢ããŠã
å¡©ãææ©ã¢ãã³ãã¢ãããå°¿çŽ ãããªå°¿çŽ ããã³
ãã®èªå°äœããã¢ãŸãŒã«é¡ããããŒã«é¡ãããªã
ãžã³é¡ãããã©ãžã³é¡ãã°ã¢ããžã³é¡ãã€ã³ããŒ
ã«é¡ãã€ãããŸãŒã«é¡ãã€ãããŸãªã³é¡ãããªã¢
ãŸãŒã«é¡ãã¢ã«ããªã³é¡ããããªãžã³é¡ãã¢ããž
ã³é¡ãããªã«ã ã¢ãžã³é¡ãããªãžã³é¡çã®å«çªçŽ
ååç©ãæããããããããã®å ·äœäŸãšããŠã¯ã
äŸãã°é ¢é žã¢ã³ã¢ããŠã ãããªã·ã¯ãããã·ã«ã¢
ãã³ãããªãã³ãžã«ã¢ãã³ããªã¯ã¿ãã·ã«ãã³ãž
ã«ã¢ãã³ãã¹ãã¢ãªã«ã¢ãã³ãã¢ãªã«å°¿çŽ ãããª
å°¿çŽ ãã¡ãã«ããªå°¿çŽ ãã¢ãªã«ããªå°¿çŽ ããšãã¬
ã³ããªå°¿çŽ ãïŒâãã³ãžã«ã€ãããŸãŒã«ãïŒâã
ãšãã«ã€ãããŸãŒã«ãïŒâããšãã«âïŒâã¡ãã«
âã€ãããŸãŒã«ãïŒâãŠã³ãã·ã«âã€ãããŸãª
ã³ãïŒïŒïŒïŒïŒâããªããªã«âïŒâã€ãããŸãª
ã³ãïŒïŒïŒâãžããšãã«âïŒïŒïŒâãžã¡ãã«âïŒ
âã€ãããŸãªã³ãïŒâããšãã«âïŒâã€ãããŸãª
ã³ãïŒïŒïŒïŒïŒâããªããšãã«ã°ã¢ããžã³ãïŒïŒ
ïŒâãžããªã«ã°ã¢ããžã³ãïŒïŒïŒâãžã·ã¯ããã
ã·ã«ã°ã¢ããžã³ãïŒïŒïŒâãžã·ã¯ãããã·ã«âïŒ
âããšãã«ã°ã¢ããžã³ãïŒïŒïŒïŒïŒâããªã·ã¯ã
ããã·ã«ã°ã¢ããžã³ãã°ã¢ããžã³ããªã¯ããé ¢é ž
å¡©ãïŒNâ²âãžãã³ãžã«ããã©ãžã³ãïŒïŒ4â²âãž
ããªã¢ã«ããªã³ãã¢ã«ããªããŠã ããªã¯ããé ¢é ž
å¡©ãïŒâã¢ããâãã³ãŸãã¢ãŸãŒã«ãïŒâãã³ãŸ
ã€ã«ããã©ãžãâãã³ãŸãã¢ãŸãŒã«ãããã æ¬çºæã®è²ç»å圢æç©è³ªã¯ãéåæ§ååç©100
éééšã«å¯ŸããŠ0.5ã20éééšãç¹ã«å¥œãŸããã¯
ïŒãïŒéééšã®å²åã§çšãããããé¡è²å€ã¯çºè²
å€ïŒéééšã«å¯ŸããŠçŽ0.3ã80éééšã®å²åã§çš
ããããã ãŸããç±éåé²æ¢å€ããã€ã¯ãã«ãã»ã«ã«å å
ããŠä¿åæ§ãæ¹è¯ããããšãã§ãããç±éåé²æ¢
å€ã®æ·»å éã¯éåæ§ååç©ã«å¯ŸããŠã0.1ã10ã¢
ã«ïŒ ã®å²åã奜ãŸããã æ¬çºæã«çšãããã€ã¯ãã«ãã»ã«ã¯åœæ¥çå ¬ç¥
ã®æ¹æ³ã§ã€ããããšãã§ãããäŸãã°ç±³åœç¹èš±ç¬¬
2800457å·ãå第2800458å·ã«ã¿ããããããªèŠªæ°Ž
æ§å£åœ¢æææã®ã³ã¢ã»ã«ããŒã·ãšã³ãå©çšããæ¹
æ³ãç±³åœç¹èš±ç¬¬3287154å·ãè±åœç¹èš±ç¬¬990443å·ã
ç¹å ¬æ38â19574å·ãå42â446å·ãå42â771å·
ã«ã¿ããããããªçé¢éåæ³ãç±³åœç¹èš±ç¬¬
3418250å·ãå第3660304å·ã«ã¿ãããããªããŒã®
æåºã«ããæ¹æ³ãç±³åœç¹èš±ç¬¬3796669å·ã«ã¿ãã
ãã€ãœã·ã¢ããŒãâããªãªãŒã«å£ææãçšããæ¹
æ³ãç±³åœç¹èš±ç¬¬3914511å·ã«ã¿ãããã€ãœã·ã¢ã
ãŒãå£ææãçšããæ¹æ³ãç±³åœç¹èš±ç¬¬4001140å·ã
å第4087376å·ãå第4089802å·ã«ã¿ãããå°¿çŽ â
ãã«ã ã¢ã«ãããç³»ãããã¯å°¿çŽ ãã«ã ã¢ã«ãã
ãâã¬ãŸã«ã·ããŒã«ç³»å£åœ¢æææãçšããæ¹æ³ã
ç±³åœç¹èš±ç¬¬4025455å·ã«ã¿ãããã¡ã©ãã³âãã«
ã ã¢ã«ãããæš¹èãããããã·ãããã«ã»ã«ããŒ
ã¹çã®å£åœ¢æææãçšããæ¹æ³ãç¹å ¬æ36â9168
å·ãç¹éæ51â9079å·ã«ã¿ãããã¢ãããŒã®éå
ã«ããinsituæ³ãè±åœç¹èš±ç¬¬952807å·ãå第
965074å·ã«ã¿ãããé»è§£åæ£å·åŽæ³ãç±³åœç¹èš±ç¬¬
3111407å·ãç±³åœç¹èš±ç¬¬930422å·ã«ã¿ãããã¹ã
ã¬ãŒãã©ã€ã³ã°æ³ãªã©ãããããããã«éå®ãã
ããã®ã§ã¯ãªãããè¯ç©è³ªãä¹³åããåŸãã€ã¯ã
ã«ãã»ã«å£ãšããŠé«ååèã圢æããããšã奜ãŸ
ããã æ¬çºæã®ãã€ã¯ãã«ãã»ã«å£ã®äœãæ¹ãšããŠã¯
ç¹ã«æ²¹æ»Žå éšããã®ãªã¢ã¯ã¿ã³ãã®éåã«ããã
ã€ã¯ãã«ãã»ã«åæ³ã䜿çšããå Žåããã®å¹æã
倧ãããå³ã¡ãçæéå ã«ãåäžãªç²åŸããã¡ã
çä¿åæ§ã«ããããæå ææãšããŠå¥œãŸããã«ã
ã»ã«ãåŸãããšãã§ããã äŸãã°ããªãŠã¬ã¿ã³ãã«ãã»ã«å£æãšããŠçšã
ãå Žåã«ã¯å€äŸ¡ã€ãœã·ã¢ããŒãããã³ãããšåå¿
ãã«ãã»ã«å£ã圢æãã第ïŒã®ç©è³ªïŒããšãã°ã
ãªãªãŒã«ãããªã¢ãã³ïŒãã«ãã»ã«åãã¹ãæ²¹æ§
液äœäžã«æ··åãæ°Žäžã«ä¹³ååæ£ã次ã«æž©åºŠãäžæ
ããããšã«ããã油滎çé¢ã§é«åå圢æåå¿ãèµ·
ããŠããã€ã¯ãã«ãã»ã«å£ã圢æããããã®ãšã
æ²¹æ§æ¶²äœäžã«äœæ²žç¹ã®æº¶è§£åã®åŒ·ãè£å©æº¶å€ãçš
ããããšãã§ããã ãã®å Žåã«ãçšããå€äŸ¡ã€ãœã·ã¢ããŒãããã³
ãããšåå¿ããçžæã®ããªãªãŒã«ãããªã¢ãã³ã«
ã€ããŠã¯ç±³åœç¹èš±ç¬¬3281383å·ãå第3773695å·ã
å第3793268å·ãç¹å ¬æ48â40347å·ãå49â
24159å·ãç¹éæ48â80191å·ãå48â84086å·ã«
é瀺ãããŠããããããã䜿çšããããšãã§ã
ãã å€äŸ¡ã€ãœã·ã¢ããŒããšããŠã¯ãäŸãã°ãïœâã
ãšãã¬ã³ãžã€ãœã·ã¢ããŒããïœâããšãã¬ã³ãžã€
ãœã·ã¢ããŒããïŒïŒïŒâããªã¬ã³ãžã€ãœã·ã¢ããŒ
ããïŒïŒïŒâããªã¬ã³ãžã€ãœã·ã¢ããŒããããã¿
ã¬ã³âïŒïŒïŒâãžã€ãœã·ã¢ããŒãããžããšãã«ã¡
ã¿ã³âïŒïŒ4â²âãžã€ãœã·ã¢ããŒããïŒïŒ3â²âãžã¡
ããã·âïŒïŒ4â²âãããšãã«âãžã€ãœã·ã¢ããŒ
ããïŒïŒ3â²âãžã¡ãã«ãžããšãã«ã¡ã¿ã³âïŒïŒ
4â²âãžã€ãœã·ã¢ããŒãããã·ãªã¬ã³âïŒïŒïŒâãž
ã€ãœã·ã¢ããŒããïŒïŒ4â²âãžããšãã«ãããã³ãž
ã€ãœã·ã¢ããŒããããªã¡ãã¬ã³ãžã€ãœã·ã¢ããŒ
ãããããµã¡ãã¬ã³ãžã€ãœã·ã¢ããŒãããããã¬
ã³âïŒïŒïŒâãžã€ãœã·ã¢ããŒããããã¬ã³âïŒïŒ
ïŒâãžã€ãœã·ã¢ããŒããã·ã¯ãããã·ã¬ã³âïŒïŒ
ïŒâãžã€ãœã·ã¢ããŒããã·ã¯ãããã·ã¬ã³âïŒïŒ
ïŒâãžã€ãœã·ã¢ããŒãçã®ãžã€ãœã·ã¢ããŒãã
ïŒïŒ4â²ïŒ4â³âããªããšãã«ã¡ã¿ã³ããªã€ãœã·ã¢ã
ãŒãããã«ãšã³âïŒïŒïŒïŒïŒâããªã€ãœã·ã¢ããŒ
ãã®ãããªããªã€ãœã·ã¢ããŒããïŒïŒ4â²âãžã¡ã
ã«ãžããšãã«ã¡ã¿ã³âïŒïŒ2â²ïŒïŒïŒ5â²âããã©ã€
ãœã·ã¢ããŒãã®ãããªããã©ã€ãœã·ã¢ããŒããã
ããµã¡ãã¬ã³ãžã€ãœã·ã¢ããŒããšããªã¡ãããŒã«
ãããã³ã®ä»å ç©ãïŒïŒïŒâããªã¬ã³ãžã€ãœã·ã¢
ããŒããšããªã¡ãããŒã«ãããã³ã®ä»å ç©ããã·
ãªã¬ã³ãžã€ãœã·ã¢ããŒããšããªã¡ãããŒã«ããã
ã³ã®ä»å ç©ãããªã¬ã³ãžã€ãœã·ã¢ããŒããšãããµ
ã³ããªãªãŒã«ã®ä»å ç©ã®ãããªã€ãœã·ã¢ããŒãã
ã¬ããªããŒãããã ããªãªãŒã«ãšããŠã¯ãèèªæãè³éŠæã®å€äŸ¡ã¢
ã«ã³ãŒã«ãããããã·ããªãšã¹ãã«ãããããã·
ããªã¢ã«ãã¬ã³ãšãŒãã«ã®ãããªãã®ãããã ç¹é¡æ58â158469å·æ现æžã«èšèŒãããäžèšã®
ããªãªãŒã«ãçšããããã ãšãã¬ã³ã°ãªã³ãŒã«ãïŒïŒïŒâãããã³ãžãªãŒ
ã«ãïŒïŒïŒâãã¿ã³ãžãªãŒã«ãïŒïŒïŒâãã³ã¿ã³
ãžãªãŒã«ãïŒïŒïŒâãããµã³ãžãªãŒã«ãïŒïŒïŒâ
ããã¿ã³ãžãªãŒã«ãïŒïŒïŒâãªã¯ã¿ã³ãžãªãŒã«ã
ãããã¬ã³ã°ãªã³ãŒã«ãïŒïŒïŒâãžããããã·ã
ã¿ã³ãïŒïŒïŒâãžããããã·ãã¿ã³ãïŒïŒïŒâãž
ããããã·ãã¿ã³ãïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâ
ãããã³ãžãªãŒã«ãïŒïŒïŒâãã³ã¿ã³ãžãªãŒã«ã
ïŒïŒïŒâãããµã³ãžãªãŒã«ãïŒâã¡ãã«âïŒïŒïŒ
âãã³ã¿ã³ãžãªãŒã«ãïŒïŒïŒâã·ã¯ããããµã³ãž
ã¡ã¿ããŒã«ããžããããã·ã·ã¯ããããµã³ããžãš
ãã¬ã³ã°ãªã³ãŒã«ãïŒïŒïŒïŒïŒâããªããããã·
ãããµã³ãïŒâããšãã«ãããã¬ã³ã°ãªã³ãŒã«ã
ïŒïŒïŒïŒïŒâããªã¡ãããŒã«ãããã³ããããµã³
ããªãªãŒã«ããã³ã¿ãšãªã¹ãªããŒã«ããã³ã¯ãšãª
ã¹ãªããŒã«ãšãã¬ã³ãªããµã€ãä»å ç©ãã°ãªã»ãª
ã³ãšãã¬ã³ãªããµã€ãä»å ç©ãã°ãªã»ãªã³ïŒïŒïŒ
âãžïŒïŒâããããã·ãšããã·ïŒãã³ã»ã³ãã¬ãŸ
ã«ã·ããŒã«ãžããããã·ãšãã«ãšãŒãã«çã®è³éŠ
æå€äŸ¡ã¢ã«ã³ãŒã«ãšã¢ã«ãã¬ã³ãªããµã€ããšã®çž®
åçæç©ãïœâãã·ãªã¬ã³ã°ãªã³ãŒã«ãïœâãã·
ãªã¬ã³ã°ãªã³ãŒã«ãαïŒÎ±â²âãžããããã·âïœâ
ãžã€ãœãããã«ãã³ãŒã³ãïŒïŒ4â²âãžããããã·
âãžããšãã«ã¡ã¿ã³ãïŒâïŒïœïŒpâ²âãžãããã
ã·ããšãã«ã¡ãã«ïŒãã³ãžã«ã¢ã«ã³ãŒã«ããã¹ã
ãšããŒã«ïŒ¡ã«ãšãã¬ã³ãªããµã€ãã®ä»å ç©ããã¹
ããšããŒã«ïŒ¡ã«ãããã¬ã³ãªããµã€ãã®ä»å ç©ãª
ã©ãããããããããªãªãŒã«ã¯ã€ãœã·ã¢ããŒãåº
ïŒã¢ã«ã«å¯ŸããŠãæ°Žé žåºã®å²åã0.02ãïŒã¢ã«ã§
䜿çšããã®ã奜ãŸããã ããªã¢ãã³ãšããŠã¯ãšãã¬ã³ãžã¢ãã³ãããªã¡
ãã¬ã³ãžã¢ãã³ãããã©ã¡ãã¬ã³ãžã¢ãã³ããã³
ã¿ã¡ãã¬ã³ãžã¢ãã³ããããµã¡ãã¬ã³ãžã¢ãã³ã
ïœâããšãã¬ã³ãžã¢ãã³ãïœâããšãã¬ã³ãžã¢ã
ã³ãããã©ãžã³ãïŒâã¡ãã«ããã©ãžã³ãïŒïŒïŒ
âãžã¡ãã«ããã©ãžã³ãïŒâããããã·ããªã¡ã
ã¬ã³ãžã¢ãã³ããžãšãã¬ã³ããªã¢ãã³ãããªãšã
ã¬ã³ããªã¢ãã³ãããªãšãã¬ã³ããã©ãã³ããžãš
ãã«ã¢ãããããã«ã¢ãã³ãããã©ãšãã«ãã³ã¿
ãã³ããšããã·ååç©ã®ã¢ãã³ã®ä»å ç©çããã
ãããã å€äŸ¡ã€ãœã·ã¢ããŒãã¯æ°Žãšåå¿ããŠé«ååç©è³ª
ã圢æããããšãã§ããã ãã€ã¯ãã«ãã»ã«ãäœããšãã«ã氎溶æ§é«åå
ãçšããããšãã§ãããã氎溶æ§é«ååã¯æ°Žæº¶æ§
ã®ã¢ããªã³æ§é«ååããããªã³æ§é«ååãäž¡æ§é«
ååã®ãããã§ãè¯ããã¢ããªã³æ§é«ååãšããŠ
ã¯ã倩ç¶ã®ãã®ã§ãåæã®ãã®ã§ãçšããããšã
ã§ããäŸãã°âCOO-ãâSO3 -åºçãæãããã®
ãæããããã å ·äœçãªã¢ããªã³æ§ã®å€©ç¶é«ååãšããŠã¯ã¢ã©
ãã€ãŽã ãã¢ã«ã®ã³é žãªã©ããããååæåãšã
ãŠã¯ã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹ããã¿ã«åãŒã©
ãã³ãç¡«é žåãã³ãã³ãç¡«é žåã»ã«ããŒã¹ããªã°
ãã³ã¹ã«ãã³é žãªã©ãããã ãŸãåæåãšããŠã¯ç¡æ°Žãã¬ã€ã³é žç³»ïŒå æ°Žå
解ãããã®ãå«ãïŒå ±éåäœãã¢ã¯ãªã«é žç³»ïŒã¡
ã¿ã¯ãªã«é žç³»ãå«ãïŒéåäœããã³å ±éåäœãã
ãã«ãã³ãŒã³ã¹ã«ãã³é žç³»éåäœããã³å ±éå
äœãã«ã«ããã·å€æ§ããªããã«ã¢ã«ã³ãŒã«ãªã©ã
ããããããªã³æ§é«ååãšããŠã¯ãããªããã«ã¢
ã«ã³ãŒã«ãããããã·ãšãã«ã»ã«ããŒã¹ããšãã«
ã»ã«ããŒã¹çãããã äž¡æ§ã®ååç©ãšããŠã¯ãŒã©ãã³çãããã ãããã®æ°Žæº¶æ§é«ååã¯0.01ã10wtïŒ ã®æ°Žæº¶æ¶²
ãšããŠçšããããã ãã®ãããªãã€ã¯ãã«ãã»ã«äžã«ã¯ãå°ãªããš
ãéåæ§ååç©ããã³è²ç»å圢æç©è³ªãå°å ¥ãã
ãããã®å Žåãéåžžã¯ãããã²ã³åéãéå å€ç
ããã®ã«ãã»ã«äžã«å°å ¥ããããããã®å Žåã«
ã¯ããŸãè²ç»å圢æç©è³ªã溶解ããéåæ§ååç©
äžã«ããã²ã³åéããã³éå å€ãåæ£ãŸãã¯æº¶è§£
ãããã®ãæ²¹çžãšãããããšèŠªæ°Žæ§é«ååååç©
ã溶解ããæ°Žçžãšãæ··åããŠä¹³å€åæ£ãããšãã«
ãžãšã³ãäœãããã®ä¹³ååæ£ãšåæãŸãã¯åŒç¶ã
ãŠãšãã«ãžãšã³ç²åã®æ²¹ïŒæ°Žçé¢ã«åšç¥ã®æ¹æ³ã§
å£ã圢æãããããšãã§ããããã€ã¯ãã«ãã»ã«
ã®äœãæ¹ãšããŠã¯ããã«éãããçš®ã ã®æ¹æ³ãé©
çšããããšãã§ããã æ¬çºæã«çšããã«ãã»ã«ã®å€§ããã¯80Ό以äžã§
ãããç¹ã«ä¿åæ§ãåãæ±ãæ§ã®ç¹ãã20Ό以äž
ã奜ãŸããããŸãã«ãã»ã«ãå°ããããå Žåã«ã¯
åºè³ªã®åãŸãã¯ç¹ç¶äžã«æ¶å€±ããæãããããã
ããã¯åºè³ªãŸãã¯æ¯æäœã®æ§è³ªã«äŸåããã®ã§äž
æŠã«ã¯ãããªããã0.1Ό以äžã奜ãŸããã æ¬çºæã«çšããã«ãã»ã«ã¯å§åçŽ10KgïŒcm2以äž
ã§ã¯å®è³ªçã«å€åããªããããã«ãã倧ããªå§å
ãå ããããæã«ã¯ç Žå£ãèµ·ããããšã奜ãŸã
ãããã®ç Žå£ã®èµ·ããå§åã®å€§ããã¯ãçšéã«å¿
ããŠå€ããããšãã§ãããã®ã§ããç¹å®ã®æ°å€ã«
éå®ããããã®ã§ã¯ãªãããçŽ500KgïŒcm2çšåºŠä»¥
äžã®å§åã§ç Žå£ããããšã奜ãŸãããã«ãã»ã«ã®
ç²åŸãã«ãã»ã«å£ã®åããçšããå£å€ã®çš®é¡ã«ã
ãããããã®å§åç¹æ§ãå¶åŸ¡ããããšãã§ããã æ¬çºæã®æå ææã«ã¯ãç±åå¿æ§ãå€ãããã
ã«ç¹é¡æ60â25838å·æ现æžã«èšèŒãããããã
ã·ååç©ãã«ã«ããã³é žãšã¹ãã«ååç©ãè³éŠæ
ã¡ããã·ååç©ãææ©ã¹ã«ãã³ã¢ããååç©ãã
ã€ã¯ãã«ãã»ã«ãŸãã¯ãã€ã¯ãã«ãã»ã«ã®å€ã«çš
ããããšãã§ããããããã®ååç©ã¯ãã€ã¯ãã«
ãã»ã«å£ã®ã¬ã©ã¹è»¢ç§»ç¹ãå€ãããã®ãšæãã
ãã æ¬çºæã«ã¯çš®ã ã®ç»å圢æä¿é²å€ãçšããããš
ãã§ãããç»å圢æä¿é²å€ã«ã¯éå¡©é žåå€ãšéå
å€ãšã®é žåéå åå¿ã®ä¿é²ãæå ææå±€ããåå
å±€ãžã®ç»å圢æç©è³ªã®ç§»åã®ä¿é²çã®æ©èœãã
ããç©çååŠçãªæ©èœããã¯å¡©åºãŸãã¯å¡©åºãã¬
ã«ãŒãµãŒããªã€ã«ãç±æº¶å€ãçé¢æŽ»æ§å€ãéãŸã
ã¯éã€ãªã³çžäºäœçšãæã€ååç©çã«åé¡ãã
ãããã ãããããã®ç©è³ªçŸ€ã¯äžè¬ã«è€åæ©èœã
æããŠãããäžèšã®ä¿é²å¹æã®ããã€ããåãã
æã€ã®ãåžžã§ããã 以äžã«ãããã®ç»å圢æä¿é²å€ãæ©èœå¥ã«åé¡
ããŠãããããã®å ·äœäŸã瀺ããããã®åé¡ã¯äŸ¿
å®çãªãã®ã§ãããå®éã«ã¯ïŒã€ã®ååç©ãè€æ°
ã®æ©èœãå ŒåããŠããããšãå€ãã 奜ãŸããå¡©åºã®äŸãšããŠã¯ãç¡æ©ã®å¡©åºãšããŠ
ã¢ã«ã«ãªéå±ãŸãã¯ã¢ã«ã«ãªåé¡éå±ã®æ°Žé žå
ç©ã第ïŒãŸãã¯ç¬¬ïŒãªã³é žå¡©ãããŠé žå¡©ãçé ž
å¡©ããããªã³é žå¡©ãã¡ã¿ããŠé žå¡©ïŒã¢ã³ã¢ããŠã
æ°Žé žåç©ïŒïŒçŽã¢ã«ãã«ã¢ã³ã¢ããŠã ã®æ°Žé žå
ç©ïŒãã®ä»ã®éå±ã®æ°Žé žåç©çãæããããææ©
ã®å¡©åºãšããŠã¯èèªæã¢ãã³é¡ïŒããªã¢ã«ãã«ã¢
ãã³é¡ãããããã·ã«ã¢ãã³é¡ãèèªæããªã¢ã
ã³é¡ïŒïŒè³éŠæã¢ãã³é¡ïŒïŒ®âã¢ã«ãã«çœ®æè³éŠ
æã¢ãã³é¡ãâããããã·ã«ã¢ã«ãã«çœ®æè³éŠ
æã¢ãã³é¡ããã³ãã¹ãïœâïŒãžã¢ã«ãã«ã¢ããïŒ
ããšãã«ãã¡ã¿ã³é¡ïŒãè€çŽ ç°ç¶ã¢ãã³é¡ãã¢ã
ãžã³é¡ãç°ç¶ã¢ããžã³é¡ãã°ã¢ããžã³é¡ãç°ç¶ã°
ã¢ããžã³é¡ãæããããç¹ã«pKaãïŒä»¥äžã®ãã®
ã奜ãŸããã å¡©åºãã¬ã«ãŒãµãŒãšããŠã¯ãå ç±ã«ããè±çé ž
ããææ©é žãšå¡©åºã®å¡©ãååå æ±æ žçœ®æåå¿ãã
ãã»ã³è»¢ç§»ãããã¯ãã³è»¢ç§»çã®åå¿ã«ããã¢ã
ã³é¡ãæŸåºããååç©ãªã©ãå ç±ã«ããäœããã®
åå¿ãèµ·ãããŠå¡©åºãæŸåºãããã®ããã³é»è§£ãª
ã©ã«ããå¡©åºãçºçãããååç©ã奜ãŸããçšã
ããããåè ã®å ç±ã«ããå¡©åºãçºçããã¿ã€ã
ã®å¥œãŸããå¡©åºãã¬ã«ãŒãµãŒãšããŠã¯è±åœç¹èš±ç¬¬
998949å·çã«èšèŒã®ããªã¯ããé ¢é žã®å¡©ãç±³åœç¹
蚱第4060420å·ã«èšèŒã®Î±âã¹ã«ããã«é ¢é žã®å¡©ã
ç¹éæ59â180537å·èšèŒã®ããããªãŒã«é žé¡ã®
å¡©ãç±³åœç¹èš±ç¬¬4088496å·ã«èšèŒã®ïŒâã«ã«ãã
ã·ã«ã«ãããµããèªå°äœãå¡©åºæåã«ææ©å¡©åºã®
ä»ã«ã¢ã«ã«ãªéå±ãã¢ã«ã«ãªåé¡éå±ãçšããç±
å解æ§é žãšã®å¡©ïŒç¹éæ59â195237å·ïŒãããã»
ã³è»¢äœãå©çšããç¹éæ59â168440å·ã«èšèŒã®ã
ããããµã ã«ã«ãã¡ãŒãé¡ãå ç±ã«ãããããªã«
ãçæããç¹é¡æ58â31614å·ã«èšèŒã®ã¢ã«ãã
ã·ã ã«ã«ãã¡ãŒãé¡ãªã©ãæããããããã®ä»ã
è±åœç¹èš±ç¬¬998945å·ãç±³åœç¹èš±ç¬¬3220846å·ãç¹
éæ50â22625å·ãè±åœç¹èš±ç¬¬2079480å·çã«èšèŒ
ã®å¡©åºãã¬ã«ãŒãµãŒãæçšã§ããã é»è§£ã«ããå¡©åºãçºçãããååç©ãšããŠæ¬¡ã®
ãã®ãæããããšãã§ããã äŸãã°ãé»è§£é žåãçšããæ¹æ³ã®ä»£è¡šãšããŠå
çš®èèªé žå¡©ã®é»è§£ãæããããšãã§ããããã®å
å¿ã«ãã€ãŠã¢ã«ã«ãªéå±ãã°ã¢ããžã³é¡ãã¢ããž
ã³é¡çã®ææ©å¡©åºã«çé žå¡©ã極ããŠå¹çè¯ãåŸã
ããšãã§ããã ãŸãé»è§£éå ãçšããæ¹æ³ãšããŠã¯ããããã
ãã³ããããœååç©ã®éå ã«ããã¢ãã³é¡ã®ç
æïŒãããªã«é¡ã®éå ã«ããã¢ãã³é¡ã®çæïŒã
ããååç©ãã¢ãŸååç©ãã¢ãŸãã·ååç©çã®é
å ã«ããïœâã¢ããããšããŒã«é¡ãïœâããšãã¬
ã³ãžã¢ãã³é¡ãããã©ãžã³é¡ã®çæçãæããã
ãšãã§ãããïœâã¢ããããšããŒã«é¡ãïœâããš
ãã¬ã³ãžã¢ãã³é¡ãããã©ãžã³é¡ã¯å¡©åºãšããŠçš
ããã ãã§ãªããããããçŽæ¥è²ç»å圢æç©è³ªãš
ããŠäœ¿çšããããšãã§ããããŸããçš®ã ã®ç¡æ©å¡©
å ±åäžã§ã®æ°Žã®é»è§£ã«ããã¢ã«ã«ãªæåãçæã
ããããšããã¡ããå©çšã§ããããŸãããããã®
å¡©åºãããã¯å¡©åºãã¬ã«ãŒãµãŒã¯æå å±€ã®ç·åºåœ¢
åéã®50ééïŒ ä»¥äžã奜ãŸãããæŽã«å¥œãŸããã¯
0.01ã40ééïŒ ã奜ãŸããã ãªã€ã«ãšããŠã¯çæ°Žæ§ååç©ã®ä¹³ååæ£æã«æº¶
åªãšããŠçšããããé«æ²žç¹ææ©æº¶åªãçšããããš
ãã§ããã ç±æº¶å€ãšããŠã¯éåžžã®æž©åºŠã§ã¯åºäœã§ãããçŸ
å枩床è¿åã§æº¶èããŠæº¶åªãšããŠåããã®ã§ãå°¿
çŽ é¡ããŠã¬ã¿ã³é¡ãã¢ããé¡ãããªãžã³é¡ãã¹ã«
ãã³ã¢ããé¡ãã¹ã«ãã³ãã¹ã«ããã·ãé¡ããšã¹
ãã«é¡ãã±ãã³é¡ããšãŒãã«é¡ã®ååç©ã§40â以
äžã§åºäœã®ãã®ãçšããããšãã§ããããŸããç±
溶å€ã¯ãæå å±€ã®ç·åºåœ¢åéã®0.1ã50ééïŒ ã
奜ãŸãããæŽã«å¥œãŸããã¯ïŒã20ééïŒ ã§ããã çé¢æŽ»æ§å€ãšããŠã¯ç¹éæ59â74547å·èšèŒã®
ããªãžããŠã å¡©é¡ãã¢ã³ã¢ããŠã å¡©é¡ããã¹ãã
ãŠã å¡©é¡ãç¹éæ59â57231å·èšèŒã®ããªã¢ã«ã
ã¬ã³ãªãã·ãé¡ãæããããšãã§ããã éãŸãã¯éã€ãªã³ãšçžäºäœçšããã€ååç©ãšã
ãŠã¯ãã€ããé¡ãç¹éæ59â177550å·èšèŒã®å«çª
çŽ ãããç°é¡ãç¹éæ59â111636å·èšèŒã®ããªãŒ
ã«é¡ãããªå°¿çŽ é¡ãããªãšãŒãã«é¡ãæããããš
ãã§ããã ç»å圢æä¿é²å€ã¯æå ææãååææã®ããã
ã«å èµãããŠããããäž¡æ¹ã«å èµãããŠãããã
ãŸãå èµãããå±€ãä¹³å€å±€ãäžéå±€ãä¿è·å±€ãå
åå±€ãããã³ãããã«é£æ¥ãããããã®å±€ã«ãå
èµãããŠãããæå å±€ãšååå±€ãšãåäžæ¯æäœäž
ã«æãã圢æ ã«ãããŠãåæ§ã§ããã ç»å圢æä¿é²å€ã¯åç¬ã§ãããŸãæ°çš®ã䜵çšã
ãŠäœ¿çšããããšãã§ããããäžè¬ã«ã¯æ°çš®ã䜵çš
ããæ¹ããã倧ããªä¿é²å¹æãåŸãããã ç¹ã«å¡©åºãŸãã¯å¡©åºãã¬ã«ãŒãµãŒãšä»ã®ä¿é²å€
ã䜵çšãããšé¡èãªä¿é²å¹æãçºçŸãããã æ¬çºæã«ãããŠã¯ãç±çŸåæã®åŠç枩床ããã³
åŠçæéã®å€åã«å¯Ÿããåžžã«äžå®ã®ç»åãåŸãç®
çã§çš®ã ã®çŸååæ¢å€ãçšããããšãã§ããã ããã§ããçŸååæ¢å€ãšã¯ãé©æ£çŸååŸãéã
ãã«å¡©åºãäžåãŸãã¯å¡©åºãšåå¿ããŠèäžã®å¡©åº
æ¿åºŠãäžãçŸåãåæ¢ããååç©ãŸãã¯éããã³
éå¡©ãšçžäºäœçšããŠçŸåãæå¶ããååç©ã§ã
ããå ·äœçã«ã¯ãå ç±ã«ããé žãæŸåºããé žãã¬
ã«ãŒãµãå ç±ã«ããå ±åããå¡©åºãšçœ®æåå¿ãèµ·
ãã芪é»åååç©ããŸãã¯å«çªçŽ ãããç°åå
ç©ãã¡ã«ã«ããååç©çãæãããããé žãã¬ã«
ãŒãµãŒã«ã¯äŸãã°ç¹é¡æ58â216928å·ããã³ç¹é¡
æ59â48305å·ã«èšèŒã®ãªãã·ã ãšã¹ãã«é¡ãç¹
é¡æ59â85834å·èšèŒã®ããã»ã³è»¢äœã«ããé žã
æŸåºããååç©çãæããããå ç±ã«ããå¡©åºãš
眮æåå¿ãèµ·ãã芪é»åååç©ã«ã¯äŸãã°ãç¹é¡
æ59â85836å·ã«èšèŒã®ååç©ãªã©ãæããããã æ¬çºæã®ååèŠçŽ ã¯æå èŠçŽ ããæŸåºãããè²
ç»å圢æç©è³ªãåºå®ããããã®èŠçŽ ã§ãããæå
èŠçŽ ãšåäžã®æ¯æäœäžã«å¡èšããããæãã¯æå
èŠçŽ ãæããæå ææãšã¯å¥ã®æ¯æäœäžã«å¡èšã
ãŠååææãæ§æããã ããã«æ¬çºæã®ååèŠçŽ ã¯å¿ èŠã«å¿ããŠãåªæ
å€ãå«ãå±€ãå°ãªããšãïŒå±€æããããšãã§ã
ããååèŠçŽ ãè¡šé¢ã«äœçœ®ããå Žåããã«ä¿è·å±€
ãèšããããšãã§ããããŸããå¿ èŠã«å¿ããŠåªæ
åã®ç°ãªãåªæå€ãçšããŠïŒå±€ä»¥äžã§æ§æãããŠ
ãããã ååå±€ãšããŠåªæå€ãçšããå Žåã¯ãæ¡æ£è»¢å
åæå ææã«äœ¿çšãããåªæå€ã®äžããä»»æã«éž
ã¶ããšãã§ãããããããã®äžã§ãç¹ã«ããªããŒ
åªæå€ã奜ãŸãããããã§ããªããŒåªæå€ãšã¯ã
äžçŽã¢ããåºãå«ãããªããŒãå«çªçŽ è€çŽ ç°éšå
ãæããããªããŒãããã³ãããã®ïŒçŽã«ããªã³
åºãå«ãããªããŒçã§ããã äžçŽã¢ããåºãæããããã«ã¢ãããŒåäœãå«
ãããªããŒã«ã€ããŠã¯ãç¹é¡æ58â169012å·ãç¹
é¡æ58â166135å·çã«èšèŒãããŠãããäžçŽã€ã
ããŸãŒã«åºãæããããã«ã¢ãããŒåäœãå«ãã
ãªããŒã®å ·äœäŸãšããŠã¯ç¹é¡æ58â226497å·ãå
58â232071å·ãç±³åœç¹èš±ç¬¬4282305å·ãå第
4115124å·ãå第3148061å·ãªã©ã«èšèŒãããŠã
ãã åçŽã€ãããŸãªãŠã å¡©ãæããããã«ã¢ãããŒ
åäœãå«ãããªããŒã®å¥œãŸããå ·äœäŸãšããŠã¯è±
åœç¹èš±ç¬¬2056101å·ãå第2093041å·ãå第
1594961å·ãç±³åœç¹èš±ç¬¬4124386å·ãå第4115124
å·ãå第4273853å·ãå第4450224å·ãç¹éæ48â
28225å·çã«èšèŒãããŠããã ãã®ä»åçŽã¢ã³ã¢ããŠã å¡©ãæããããã«ã¢ã
ããŒåäœãå«ãããªããŒã®å¥œãŸããå ·äœäŸãšããŠ
ã¯ãç±³åœç¹èš±ç¬¬3709690å·ãå第3898088å·ãå第
3958995å·ãç¹é¡æ58â166135å·ãå58â169012
å·ãå58â232070å·ãå58â232072å·ããã³å59
â91620å·ãªã©ã«èšèŒãããŠããã æ¬çºæã«ãããŠã¯ãéåæ§ååç©ãè²ç»å圢æ
ç©è³ªã®ã«ãã»ã«åã«éããŠæº¶åªã䜵çšããããšã
ã§ããããŸãéå å€ãé¡è²å€çãå¿ èŠãªèŠçŽ äžã«
å°å ¥ããå Žåã«ã溶åªãçšããããšãã§ãããäŸ
ãã°æ°ŽãŸãã¯èŠªæ°Žæ§ææ©æº¶åªã«æº¶ããã溶液ãå¿
èŠã«å¿ããŠãã€ã³ããŒãšãšãã«çŽæ¥æ¯æäœäžã«å¡
èšããããšãã§ããããç±³åœç¹èš±ç¬¬2322027å·èš
èŒã®æ¹æ³ãªã©ã®å ¬ç¥ã®æ¹æ³ã«ããå¿ èŠãªèŠçŽ äžã«
å°å ¥ããããšãã§ããããã€ã¯ãã«ãã»ã«äžã«æº¶
åªã䜵çšããããšã«ããå å§ã®éã®ã«ãã»ã«ã®ç Ž
å£ã®çšåºŠããã³ã«ãã»ã«å ã®è²ç»å圢æç©è³ªã®å
åèŠçŽ ãžã®ç§»åéãã³ã³ãããŒã«ããããšãã§ã
ããã«ãã»ã«å ã«äœµçšãã溶åªã®éã¯éåæ§åå
ç©100éééšã«å¯ŸããŠïŒã500éééšã®å²åã奜ãŸ
ããã æ¬çºæã«ãããŠçšãããã溶åªãšããŠå€©ç¶æ²¹ãŸ
ãã¯åææ²¹ãåç¬ãŸãã¯äœµçšããããšãã§ããã
ããã溶åªã®äŸãšããŠäŸãã°ç¶¿å®æ²¹ãç¯æ²¹ãèèª
æã±ãã³ãèèªæãšã¹ãã«ããã©ãã€ã³ãããã
ã³æ²¹ãã¢ã«ãã«åãããšãã«ãã¢ã«ãã«åã¿ãŒã
ãšãã«ãå¡©çŽ åãã©ãã€ã³ãã¢ã«ãã«åããã¿ã¬
ã³ãããã³ïŒâããšãã«âïŒâãã·ãªã«ãšã¿ã³ã
ïŒâããšãã«âïŒâïœâãšãã«ããšãã«ãšã¿ã³ã
ïŒïŒ1â²âãžããªã«ãšã¿ã³çã®ãããªãžã¢ãªãŒã«ãš
ã¿ã³ããã¿ãŒã«é žã¢ã«ãã«ãšã¹ãã«ïŒãžããã«ã
ã¿ã¬ãŒãããžãªã¯ãã«ãã¿ã¬ãŒããªã©ïŒããªã³é ž
ãšã¹ãã«ïŒãžããšãã«ãã¹ããšãŒããããªããšã
ã«ãã¹ããšãŒããããªã¯ã¬ãžã«ãã¹ããšãŒãããž
ãªã¯ãã«ããã«ãã¹ããšãŒãïŒãã¯ãšã³é žãšã¹ã
ã«ïŒäŸãã°ã¢ã»ãã«ã¯ãšã³é žããªããã«ïŒãå®æ¯
éŠé žãšã¹ãã«ïŒå®æ¯éŠé žãªã¯ãã«ïŒãã¢ã«ãã«ã¢
ããïŒäŸãã°ãžãšãã«ã©ãŠãªã«ã¢ããïŒãèèªé ž
ãšã¹ãã«é¡ïŒäŸãã°ãžãããã·ãšãã«ãµã¯ã·ããŒ
ãããžãªã¯ãã«ã¢ãŒã¬ãŒãïŒãããªã¡ã·ã³é žãšã¹
ãã«é¡ïŒäŸãã°ããªã¡ã·ã³é žããªããã«ïŒé ¢é žãš
ãã«ãé ¢é žããã«ã®ãããªäœçŽã¢ã«ãã«ã¢ã»ããŒ
ããããããªã³é žãšãã«ãäºçŽããã«ã¢ã«ã³ãŒ
ã«ãã¡ãã«ã€ãœããã«ã±ãã³ãβâãšããã·ãšã
ã«ã¢ã»ããŒããã¡ãã«ã»ããœã«ãã¢ã»ããŒããã·
ã¯ããããµãã³ãªã©ãããã æ¬çºæã®æå ææããã³ååææã«çšãããã
ãã€ã³ããŒã¯ãåç¬ã§ãããã¯çµã¿åãããŠå«æ
ããããšãã§ããããã®ãã€ã³ããŒã«ã¯äž»ã«èŠªæ°Ž
æ§ã®ãã®ãçšããããšãã§ããã芪氎æ§ãã€ã³ã
ãŒãšããŠã¯ãéæãåéæã®èŠªæ°Žæ§ãã€ã³ããŒã
代衚çã§ãããäŸãã°ãŒã©ãã³ããŒã©ãã³èªå°
äœãã»ã«ããŒã¹èªå°äœçã®ã¿ã³ãã¯è³ªãããã³ã
ã³ãã¢ã©ãã€ãŽã çã®å€ç³é¡ã®ãããªå€©ç¶ç©è³ª
ãšãããªããã«ãããªãã³ãã¢ã¯ãªã«ã¢ããéå
äœçã®æ°Žæº¶æ§ã®ããªããã«ååç©ã®ãããªåæé
åç©è³ªãå«ããä»ã®åæéåç©è³ªã¯ãã©ããã¯ã¹
ã®åœ¢ã§ããšãã«åçææã®å¯žåºŠå®å®æ§ãå¢å ãã
ãåæ£ç¶ããã«ååç©ãããã æ¬çºæã«æŒããæå ææããã³ååææã«äœ¿çš
ãããæ¯æäœã¯ãåŠç枩床ã«èããããšã®ã§ãã
ãã®ã§ãããäžè¬çãªæ¯æäœãšããŠã¯ãã¬ã©ã¹ã
çŽãäžè³ªçŽãåæçŽãéå±ããã³ãã®é¡äŒŒäœãçš
ããããã°ããã§ãªããã¢ã»ãã«ã»ã«ããŒã¹ãã€
ã«ã ãã»ã«ããŒã¹ãšã¹ãã«ãã€ã«ã ãããªããã«
ã¢ã»ã¿ãŒã«ãã€ã«ã ãããªã¹ãã¬ã³ãã€ã«ã ãã
ãªã«ãŒãããŒããã€ã«ã ãããªãšãã¬ã³ãã¬ãã¿
ã¬ãŒããã€ã«ã ããã³ãããã«é¢é£ãããã€ã«ã
ãŸãã¯æš¹èææãå«ãŸããããŸãããªãšãã¬ã³ç
ã®ããªããŒã«ãã€ãŠã©ãããŒããããçŽæ¯æäœã
çšããããšãã§ãããç±³åœç¹èš±ç¬¬3634089å·ãå
第3725070å·èšèŒã®ããªãšã¹ãã«ãã€ã«ã ã¯å¥œãŸ
ããçšããããã æ¬çºæã®æå ææã¯å¿ èŠã«å¿ããŠä¿è·å±€ãäžé
å±€ã垯é»é²æ¢å±€ãã«ãŒã«é²æ¢å±€ãã¯ããå±€ããã
ãå€å±€ãªã©ã®è£å©å±€ãèšããããšãã§ãããç¹ã«
ä¿è·å±€ã¯æ¥çé²æ¢ã®ç®çã§ææ©ãç¡æ©ã®ãããå€
ãå«ãŸããã®ãæãŸããã ãŸããæå ææãååææã«ã¯å¿ èŠã«å¿ããŠã«
ããªé²æ¢å€ãããå å¢çœå€ãéè²é²æ¢å€ããã¬ãŒ
ã·ãšã³ãã€ã©ãžãšãŒã·ãšã³é²æ¢ææãé¡æïŒé žå
ãã¿ã³ãªã©ã®çœè²é¡æãå«ãïŒãæ°ŽæŸåºå€ãç±é
åé²æ¢å€ãçé¢æŽ»æ§å€ãç±æº¶å€åæ£ç¶ããã«åå
ç©çãå«ãã§ããŠãããã æ¬çºæã«ãããŠã¯çš®ã ã®é²å æ段ãçšããããš
ãã§ãããæœåã¯ãå¯èŠå ãå«ã茻å°ç·ã®ç»åç¶
é²å ã«ãã€ãŠåŸããããäžè¬ã«ã¯ãé垞䜿ããã
å æºãäŸãã°å€ªéœå ãã¹ãããããã©ãã·ãŠãã¿
ã³ã°ã¹ãã³ã©ã³ããæ°Žéç¯ããšãŒãã©ã³ããªã©ã®
ããã²ã³ã©ã³ãããã»ãã³ã©ã³ããã¬ãŒã¶ãŒå
ç·ãããã³CRTå æºããã©ãºãå æºãèå 管ã
çºå ãã€ãªãŒããªã©ãå æºãšããŠäœ¿ãããšãã§ã
ãããŸããLCDïŒæ¶²æ¶ïŒãPLZTïŒã©ã³ã¿ã³ãããŒ
ããããã¿ã³ãžã«ã³ããŠã é žéïŒãªã©ãå©çšãã
ãã€ã¯ãã·ã€ãã¿ãŒã¢ã¬ã€ãšç·ç¶å æºãããã¯å¹³
é¢ç¶å æºãçµåããé²å æ段ãçšããããšãã§ã
ãã å æºã®çš®é¡ãé²å éã¯ããã²ã³åéã®è²çŽ å¢æ
ã«ããæå æ³¢é·ããæ床ã«å¿ããŠéžæããããšã
ã§ããã æ¬çºæã«ãããŠçšããåç»ã¯çœé»ç»åã§ãã«ã©
ãŒç»åã§ãããã åç»ãšããŠã¯ã補å³ãªã©ã®ç·ç»åã¯ãã¡ããã®
ããšãé調ãæããåçç»åã§ãããããŸãã«ã¡
ã©ãçšããŠäººç©åã颚æ¯åãæ®åœ±ããããšãå¯èœ
ã§ãããåç»ããã®çŒä»ã¯ãåç»ãšéããŠå¯ççŒ
ä»ãããŠããåå°çŒä»ãããŠããããŸãåŒäŒžãçŒ
ä»ãããŠãããã ãŸããããªã«ã¡ã©ãªã©ã«ããæ®åœ±ãããç»åã
ãã¬ãå±ããéãããŠããç»åæ å ±ããçŽæ¥
CRTãFOTã«åºãããã®åãå¯çãã¬ã³ãºã«ã
ãæå ææäžã«çµåãããŠãçŒä»ãããšãå¯èœã§
ããã ãŸãæè¿å€§å·Ÿãªé²æ©ãèŠãããLEDïŒçºå ãã€
ãªãŒãïŒã¯ãåçš®ã®æ©åšã«ãããŠãé²å æ段ãšã
ãŠãŸãã¯è¡šç€ºæ段ãšããŠçšãããã€ã€ããããã®
LEDã¯ãéå ãæå¹ã«åºããã®ãäœãããšãå°
é£ã§ããããã®å Žåãã«ã©ãŒç»åãåçããã«
ã¯ãLEDãšããŠç·å ãèµ€å ãèµ€å€å ãçºããïŒ
çš®ã䜿ãããããã®å ã«æå ããä¹³å€éšåã
åã ãã€ãšããŒãããŒã³ã¿ãã·ã¢ã³ã®ç»å圢æç©
質ãå«ãããã«èšèšããã°ããã ããªãã¡ç·æå éšãã€ãšããŒç»å圢æç©è³ªãå«
ã¿ãèµ€æå éšãããŒã³ã¿ç»å圢æç©è³ªããèµ€å€æ
å éšãã·ã¢ã³ç»å圢æç©è³ªãå«ãããã«ããŠãã
ã°ããããã以å€ã®å¿ èŠã«å¿ããŠç°ãªã€ãçµåã
ãå¯èœã§ããã äžèšã®åå³ãçŽæ¥ã«å¯çãŸãã¯æ圱ããæ¹æ³ä»¥
å€ã«ãå æºã«ããç §å°ãããåå³ãå é»ç®¡ã
CCDãªã©ã®åå çŽ åã«ãããèªã¿ãšãã³ã³ããŠ
ãŒã¿ãŒãªã©ã®ã¡ã¢ãªãŒã«å ¥ãããã®æ å ±ãå¿ èŠã«
å¿ããŠå å·¥ããããããç»ååŠçãã»ã©ããã
åŸããã®ç»åæ å ±ãCRTã«åçããããããç»
åå æºãšããŠå©çšããããåŠçãããæ å ±ã«ããš
ã¥ããŠãçŽæ¥ïŒçš®LEDãçºå ãããŠé²å ããæ¹
æ³ãããã ãããã®é²å éã¯ãçšããããã²ã³åéã®çš®é¡
ããå¢æçšåºŠã«ãã€ãŠå€ãã€ãŠããã æ¬çºæã«ãããŠåæ§é²å åŸã®å ç±æ¹æ³ãšããŠã¯
åŸæ¥å ¬ç¥ã®æ¹æ³ãçšããããšãã§ãããäŸãã°ã
ããããã¬ãŒããªã©ã®ç±æ¿ãããã¯ãã©ã ã«æå
ææãçŽæ¥è§ŠããããããããŒãããŒã©ãŒãçšã
ãŠæ¬éããããããããšãã§ããã ãŸãé«æž©ã«å ç±ãã空æ°ãçšãããé«åšæ³¢å ç±
ãã¬ãŒã¶ãŒããŒã ã«ããå ç±ããããšãã§ããã
æå ææã«ãã€ãŠã¯èµ€å€ç·ããŒã¿ãŒãçšããŠå ç±
ããããšãã§ãããããã«é»ç£èªå°ã«ããçºçã
ã枊é»æµãå©çšããŠå ç±ããæ¹æ³ãå¿çšããããš
ãã§ããã ãŸããæå ææã«å¯ŸããŠäžæŽ»æ§ã®æ¶²äœãããšã
ã°ããçŽ ç³»ã®æ¶²äœãå ç±ãããã¹äžã§æå ææã
å ç±ããŠãè¯ãã ããã«ãäžèšã®å ç±æ段ãšã¯å¥ã«å ç±æºãæå
ææã«ããããããšã§å ç±ããŠããããããšã
ã°ãã«ãŒãã³ãã©ãã¯ãã°ã©ãã¢ã€ããªã©ã®å°é»
æ§ç²åã®å±€ãæå ææäžã«ããããéé»ããæã«
çºçãããžãŠãŒã«ç±ãå©çšããŠãããããã®éã®
å ç±æž©åºŠã¯äžè¬ã«80âã200âã奜ãŸããã¯100â
ã160âã§ããã æå ææãå ç±ãããã¿ãŒã³ãšããŠã¯ãçš®ã ã®
ãã¿ãŒã³ãå¿çšã§ãããäžå®æž©åºŠã§å ç±ããæ¹æ³
ãæãäžè¬çã§ããããæå ææã®ç¹æ§ã«ãã€ãŠ
ã¯å€æ®µéå ç±âããšãã°é«æž©çæéå ç±ã®åŸåŸã
ã«æž©åºŠãäœäžãããæ¹æ³âãæå¹ã§ããããã®å Ž
åã®å ç±æéã¯äžè¬ã«ïŒç§ãïŒåã奜ãŸããã¯ïŒ
ç§ããïŒåã§ããã å ç±ã«éããŠæå ææã空æ°é žåã®åœ±é¿ããã
ãããå Žåã«ã¯å ç±éšåšèŸºã®è±æ°ãŸãã¯äžæŽ»æ§ã¬
ã¹ãžã®çœ®æãæå¹ã§ããããŸãæå ææã®è¡šé¢ã
å ç±éšåãžçŽæ¥æ¥è§ŠãããŠããããã空æ°ã«ãã
ããŠããããæå ææè¡šé¢ã空æ°åŽã«ããŠçŸåã
ãå Žåã«ã¯æå ææäžããã®æ°Žåãæ®çºæåã®èž
çºãé²ãã ããä¿æž©ã®ç®çã§ã«ããŒããšãã€ãã
ã®ãæå¹ã§ããã çºæã®å ·äœçäœçšå¹æ æ¬çºæã«ããã°ãæ¯æäœäžã«å°ãªããšãæå æ§
ããã²ã³åéä¹³å€ãéå å€ãéåæ§ååç©ããã³
è²ç»å圢æç©è³ªãæãããã€ãããã®äžã®å°ãªã
ãšãéåæ§ååç©ãšè²ç»å圢æç©è³ªãšãåäžã®ã
ã€ã¯ãã«ãã»ã«ã«å°å ¥ãããç¶æ ã§å«æãããŠã
ããåæ§é²å ã«ããæœåã圢æããããã²ã³åé
ä¹³å€ãå¢æè²çŽ ã®ååšäžã§åœ¢æãããããã²ã³å
éç²åãå«ããããé«æ床ã§ãã€çµæå®å®æ§ã«åª
ããæå ææãåŸããããç¹ã«ãã®å¹æã¯ç·è²å
ããã³èµ€è²å ã«å¯ŸããŠé¡èã§ããã çºæã®å ·äœçå®æœäŸ 以äžãæ¬çºæã®å ·äœçå®æœäŸã瀺ããæ¬çºæã®
å¹æãããã«è©³çŽ°ã«èª¬æããã å®æœäŸ ïŒ ïŒ»æå æ§ããã²ã³åéä¹³å€ã®èª¿è£œïŒœ ä¹³å€(A)ã®èª¿è£œæ³ è¯ãæ¹æããŠãããŒã©ãã³æ°Žæº¶æ¶²ïŒæ°Ž1000mlã®
äžã«ãŒã©ãã³20ïœãšå¡©åãããªãŠã ïŒïœãšã溶解
ãããŠ75âã«ä¿æž©ãããã®ïŒã«èåã«ãªãŠã ãšå¡©
åãããªãŠã ãšãå«ãïŒåãããŠ0.59ã¢ã«ïŒæ°Žæº¶
液600mlãš0.59ã¢ã«ã®ç¡é žéãå«ã氎溶液600mlãš
ãåæã«çæµéã§40åãããŠæ·»å ããAgBr80ã¢
ã«ïŒ ã§ãµã€ãºã0.5ÎŒã®ç«æ¹äœååæ£å¡©èåéç²å
ãäœã€ãããã®ä¹³å€ãæ°ŽæŽãè±å¡©åŸããŒã©ãã³ïŒ
ïœãšæ°Ž200mlãå ããŠãPHã調ç¯ããããªç¡«é žã
ããªãŠã ãšå¡©åéé žããã³ãïŒâããããã·âïŒ
âã¡ãã«âïŒïŒïŒïŒ3aïŒïŒâããã©ã¶ã€ã³ãã³
ãçšããŠæé©ã®ååŠå¢æãè¡ã€ããä¹³å€ã®åéã¯
700ïœã§ãããããããŠåŸãããä¹³å€ã(A)ãšããã ä¹³å€(B)ã®èª¿è£œæ³ è¯ãæ¹æããŠãããŒã©ãã³æ°Žæº¶æ¶²ïŒæ°Ž1000mläž
ã«ãŒã©ãã³20ïœãšå¡©åãããªãŠã ïŒïœãšã溶解ã
ããŠ60âã«ä¿æž©ãããã®ïŒã«èåã«ãªãŠã ãšå¡©å
ãããªãŠã ãšãå«ãïŒåããŠ0.59ã¢ã«ïŒæ°Žæº¶æ¶²
600mlãš0.59ã¢ã«ã®ç¡é žéãå«ã氎溶液600mlãšã
åæã«çæµéã§25åãããŠæ·»å ããBr80ã¢ã«ïŒ
ã§ãµã€ãºã0.25ÎŒã®ç«æ¹äœååæ£å¡©èåéç²åã
äœã€ãããã®éããã²ã³åéç²å圢æéå§ãšåæ
ã«è²çŽ 0.16ïœãã¡ã¿ããŒã«400c.c.ã«æº¶è§£ãã液
ã15åãããŠãŒã©ãã³æ°Žæº¶æ¶²äžã«æ·»å ãããæ°Ž
æŽãè±å¡©åŸãŒã©ãã³ïŒïœãšæ°Ž200mlãå ããŠPHã
調ç¯ãããªç¡«é žãããªãŠã ãšå¡©åéé žãšïŒâãã
ããã·âïŒâã¡ãã«âïŒïŒïŒïŒ3aïŒïŒâããã©
ã¶ã€ã³ãã³ãçšããŠæé©ã®ååŠå¢æãè¡ã€ããä¹³
å€ã®åéã¯700ïœã§ããããã®æ§ã«ããŠåŸããã
ä¹³å€ã(B)ãšããã è²çŽ ä¹³å€(C)ã®èª¿è£œæ³ è¯ãæ¹æããŠãããŒã©ãã³æ°Žæº¶æ¶²ïŒæ°Ž1000mläž
ã«ãŒã©ãã³20ïœãšå¡©åãããªãŠã 10ïœãšã溶解ã
ããŠ75âã«ä¿æž©ãããã®ïŒã«èåã«ãªãŠã ãšå¡©å
ãããªãŠã ãšãå«ãïŒåããŠ0.59ã¢ã«ïŒæ°Žæº¶æ¶²
600mlãš0.59ã¢ã«ã®ç¡é žéãå«ã氎溶液600mlãšã
60åãããŠæ·»å ãBr55ã¢ã«ïŒ ã§å¹³åç²åãµã€ãº
ã0.65ÎŒã®ç«æ¹äœå¡©èåéç²åãäœã€ãããã®é
ç²å圢æéå§ïŒååã«è²çŽ 0.16ïœãã¡ã¿ããŒã«
160c.c.ã«æº¶è§£ããè²çŽ 溶液ããŒã©ãã³æ°Žæº¶æ¶²ã«æ·»
å ãããæ°ŽæŽãè±å¡©åŸãŒã©ãã³ïŒïœãšæ°Ž200mlã
å ããŠPHã調ç¯ããããªç¡«é žãããªãŠã ãšæ žé žå
解ç©ãçšããŠæé©ã®ååŠå¢æãè¡ã€ãã ä¹³å€ã®åéã¯700ïœã§ãããããããŠåŸããã
ä¹³å€ã(C)ãšããã è²çŽ ä¹³å€(D)ã®èª¿è£œæ³ åèšä¹³å€(B)ã®äœãæ¹ã«ãããŠããã®éçšããè²
çŽ ãããã²ã³åéç²å圢æäžã«ã¯æ·»å ããã代
ãã«åéã®è²çŽ ãååŠå¢æçµäºåŸãçŽã¡ã«æ·»å
ããä»ã¯ä¹³å€(B)ãšåæ§ã«ããŠèª¿è£œãããã®ãä¹³å€
(D)ãšããã ä¹³å€(E)ã®èª¿è£œæ³ åèšä¹³å€(C)ã®äœãæ¹ã«ãããŠããã®éçšããè²
çŽ ããŒã©ãã³æ°Žæº¶æ¶²ã«ã¯æ·»å ããã代ãã«åé
ã®è²çŽ ãååŠå¢æçµäºåŸçŽã¡ã«æ·»å ããä»ã¯ä¹³
å€(C)ãšåæ§ã«ããŠèª¿è£œãããã®ãä¹³å€(E)ãšããã ä¹³å€(D)ã®èª¿è£œæ³ åèšä¹³å€(B)ã®äœãæ¹ã«ãããŠããã®éçšããè²
çŽ ãããã²ã³åéç²å圢æäžã«ã¯æ·»å ããã代
ãã«åéã®è²çŽ ãååŠå¢æçµäºåŸãçŽã¡ã«æ·»å
ããä»ã¯ä¹³å€(B)ãšåæ§ã«ããŠèª¿è£œãããã®ãä¹³å€
(D)ãšããã ä¹³å€(E)ã®èª¿è£œæ³ åèšä¹³å€(C)ã®äœãæ¹ã«ãããŠããã®éçšããè²
çŽ ããŒã©ãã³æ°Žæº¶æ¶²ã«ã¯æ·»å ããã代ãã«åé
ã®è²çŽ ãååŠå¢æçµäºåŸçŽã¡ã«æ·»å ããä»ã¯ä¹³
å€(C)ãšåæ§ã«ããŠèª¿è£œãããã®ãä¹³å€(E)ãšããã ä¹³å€(F)ã®èª¿è£œæ³ æ°Ž600mlãå«ãããŒã«ãŒäžã«ããŒã©ãã³20ïœã
èåã«ãªãŠã 1.2ïœããã³25ïŒ ã¢ã³ã¢ãã¢æ°ŽïŒc.c.
ãå ¥ãæ¹æ溶解ãããããã®æº¶æ¶²ã50âã«ä¿ã¡ãª
ããç¡é žé100ïœãæ°Ž600mlã«æº¶è§£ããã液ããã³
èåã«ãªãŠã 116ïœãæ²åã«ãªãŠã ïŒïœãæ°Ž100ml
ã«æº¶è§£ããã液ãã³ã³ãããŒã«ãããã«ãžãšãã
æ³ã§æ¶²ã®pAgã8.9ã«ä¿ã¡ãªãã50åéã§æ·»å ã
ãããã®ãšãããã²ã³æº¶æ¶²ãšç¡é žé溶液ã®æ·»å é
å§ãšåæã«è²çŽ 0.15ïœãã¡ã¿ããŒã«75mlã«æº¶è§£
ããã液ã®æ·»å ãã¯ããã25åéã§å šéãæ·»å ã
ãã è²çŽ æ°ŽæŽãè±å¡©åŸãŒã©ãã³ïŒïœãšæ°Ž100mlãå ããŠ
PHã調補ããèåã«ãªãŠã ãå ããŠãpAgã0.3
ãšããã次ã«ããªç¡«é žãããªãŠã ãçšããŠæé©ã®
ååŠå¢æãè¡ããç²åãµã€ãº0.5ÎŒmããžã€ã¬ã€ã¢
圢ã§ãåé700ïœã®ãã³ã¯ãå¢ææ²èåéä¹³å€(F)
ãåŸãã ä¹³å€(G)ã®èª¿è£œæ³ æ°Ž600mlãå«ãããŒã«ãŒäžã«ããŒã©ãã³20ïœã
èåã«ãªãŠã 1.2ïœããã³ HOïŒâCH2ïŒâ2SïŒâCH2ïŒâ2SïŒâCH2ïŒâ2OH 0.5ïœãå ¥ãæ¹æ溶解ãããããã®æº¶æ¶²ã60âã«
ä¿ã¡ãä¹³å€(F)ã§çšããè²çŽ 0.15ïœãã¡ã¿ããŒã«
75mlã«æº¶è§£ããã液ãããã³è²çŽ 0.05ïœãã¡ã¿
ããŒã«125c.c.ã«æº¶è§£ããã液ãæ·»å ããã次ã«ç¡
é žé100ïœãæ°Ž600mlã«æº¶è§£ããã液ããã³èåã«
ãªãŠã 64ïœãæ²åã«ãªãŠã 10ïœãæ°Ž600mlã«æº¶è§£
ããã液ã50åéã§æ·»å ããã æ°ŽæŽãè±å¡©åŸãŒã©ãã³ïŒïœãšæ°Ž100mlãå ããŠ
PHã調補ããèåã«ãªãŠã ãå ããŠãpAgã8.5
ãšããã次ã«ããªç¡«é žãããªãŠã ãšïŒâãããã
ã·âïŒâã¡ãã«âïŒïŒïŒïŒ3aïŒïŒâããã©ã¶ã€
ã³ãã³ãçšããŠæé©ã®ååŠå¢æãè¡ããç²åãµã€
ãº0.3ÎŒããžã€ã¬ã€ã¢åœ¢ã§ãåé700ïœã®ãã³ã¯ã
å¢ææ²èåéä¹³å€(G)ãåŸãã è²çŽ ä¹³å€(H)ã®èª¿è£œæ³ åèšä¹³å€(F)ã®äœãæ¹ã«ãããŠãä¹³å€(F)ã§çšãã
è²çŽ ãããã²ã³åéç²å圢æäžã«æ·»å ããã代
ãã«åéã®è²çŽ ãååŠå¢æçµäºåŸçŽã¡ã«æ·»å ã
ãä»ã¯ä¹³å€(F)ãšåæ§ã«ããŠèª¿è£œãããã®ãä¹³å€(H)
ãšããã ä¹³å€(I)ã®èª¿è£œæ³ åèšä¹³å€(G)ã®äœãæ¹ã«ãããŠãä¹³å€(F)ã§çšãã
è²çŽ ããã³ä¹³å€(G)ã§çšããè²çŽ ããŒã©ãã³æº¶
液äžã«æ·»å ããã代ãã«åéã®è²çŽ ããã³ã
ååŠå¢æåŸçŽã ã¡ã«æ·»å ããä»ã¯ä¹³å€(G)ãšåæ§ã«
ããŠèª¿è£œãããã®ãä¹³å€(I)ãšããã ãã€ã¯ãã«ãã»ã«ã®èª¿è£œããã³æå ã·ãŒãã®
äœè£œïŒœ ããªã¡ãããŒã«ãããã³ããªã¢ã¯ãªã¬ãŒã28ïœ
ããã³ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãïŒïœã®ã¢ãããŒæ··å
ç©ã«å¡©åã¡ãã¬ã³ïŒïœäžã«æº¶è§£ããçºè²å€ã®ïŒâ
ãžãšãã«ã¢ããâïŒâã¯ãã«âïŒâã¢ããªããã«
ãªã©ã³2.1ïœãæ·»å ããã¢ãããŒæ··åç©ãšããã
ãã®ã¢ãããŒæ··åç©ã«ä¹³å€(A)ïŒïœãå ããŠæ··åã
ããã®ãæºåããã äžæ¹10ïŒ ã¢ã©ãã¢ãŽã 氎溶液17.5ïœã12ïŒ ã€ãœ
ããã¬ã³ïŒç¡æ°Žãã¬ã€ã³é žæ°Žæº¶æ¶²18.5ïœãèžçæ°Ž
26.5ïœã®æ··åç©ããç¡«é žã§PH3.5ã«èª¿è£œããæŽã«
å°¿çŽ 4.6ïœãã¬ãŸã«ã·ã³0.6ïœãå ãããã®æº¶æ¶²ã«
å ã®ããã²ã³åéãå«ãã¢ãããŒæ··åç©ãä¹³åå
æ£ãã3ÎŒãšãããã€ãã§36ïŒ ãã«ããªã³12.9ïœã
å ãæ¹æãã€ã€60âãŸã§ææž©ããïŒæéåŸã«ïŒïŒ
ç¡«é žã¢ã³ã¢ããŠã 氎溶液9.0ïœãå ããæŽã«60â
ã«ä¿ã¡ã€ã€ïŒæéæ¹æåŸå·åŽããããã®åŸ
NaOHã«ããPHã9.0ãšããã ããããŠåŸãã«ãã»ã«æ¶²ïŒïœã«15ïŒ ããªããã«
ã¢ã«ã³ãŒã«æ°Žæº¶æ¶²1.53ïœãèžçæ°Ž3.47ïœãã§ãã¶
ã0.57ïœããã³Î²âã¢ã»ãã«âïœâã¢ãã³ããšã
ã«ããã©ãžã³5.5mgãå ãå¡åžæ¶²ãšãããããã
ã³ãŒãã€ã³ã°ããã10ãçšããŠãã¢ãŒãçŽã«å¡åž
ãã50âã§15åé也ç¥ããæå ã·ãŒãïŒãåŸãã æå ã·ãŒãïŒã«ãããŠãä¹³å€(A)ã®ä»£ããã«ä¹³å€
(B)ã(I)ïŒè¡šïŒïŒãçšããŠäœè£œãããã®ããããã
æå ã·ãŒãïŒãïŒïŒè¡šïŒïŒãšããã ååã·ãŒãã®äœè£œïŒœ 21.8ïœã®æ°Žã«48ïŒ ã®SBRã©ããã¯ã¹0.6ïœã10
ïŒ ãšãŒãã«åã§ãã¶ã氎溶液ïŒïœãçé žäºé2.1
ïœãã±ã€é žãœãŒã50ïŒ æ°Žæº¶æ¶²1.3ïœããããµã¡ã¿
ãªã³é žãœãŒã0.1ïœãé žæ§çœå13ïœãå ãããã¢
ãžãã€ã¶ãŒã§15åéæ¹æããã ãããã³ãŒãã€ã³ã°ããã18ãçšããŠã¢ãŒãçŽ
ã«å¡åžãã100âã§ïŒåé也ç¥ããååã·ãŒãã
åŸãã ç»åã®åçããã³çµæ äžè¿°ã®æå ã·ãŒãã«ç·ç»ã®åçš¿ãä»ããŠããã
ã²ã³ã©ã³ããçšãã400ã700nmã®æ³¢é·ã®å ãç §
å°ãããé²å åŸããã®æå ã·ãŒãã120âã«ãŠ30
ç§éå ç±ãããããã«ããã®åŸæå ã·ãŒããšåå
ã·ãŒãã®å¡åžé¢ã察åããããã«éããŠãç·å§
100KgïŒcmã®å å§ããŒã©ãŒã«éãããæªé²å éšã®
ã«ãã»ã«ã¯ç Žå£ãããååã·ãŒãã«è»¢åãããã
転åãããéšåã¯æ¿åºŠ1.0ã®é®®æãªé»è²ç»åãäž
ããã é²å éšã«å¯Ÿå¿ããéšåã¯é²å éã«å¿ãæ¿åºŠãå€
åããããæ¿åºŠ0.1以äžãšãªãæäœé²å éããæ
床ãè©äŸ¡ããã ãŸããäžèšã®æå ã·ãŒãã25âã§ïŒã±æéä¿å
ãããã®ã«ã€ããŠãåæ§ã«ããŠæ床ãè©äŸ¡ããã çµæãè¡šïŒã«ç€ºãã ãªããçžå¯Ÿæ床ã¯ãæå ã·ãŒãïŒã®æ床ã100
ãšããŠè¡šç€ºããã
ãã«åºãã¢ãªãŒã«åºãè¡šãããR17ã¯ããã²ã³å
åããããåºãäœçŽã¢ã«ãã«åºãã¢ã«ã³ãã·åºã
ã¢ã«ã³ãã·ã«ã«ããã«åºãã¢ã«ãã«ã¹ã«ããã«
åºãã¢ãªãŒã«ã¹ã«ããã«åºãè¡šããã R19ïŒR20ïŒR21ã¯æ°ŽçŽ ååãããã²ã³ååãã¢
ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºãã¢ãªãŒã«åºãããª
ãžã³åºãã«ã«ããã·åºãã¢ã«ã³ãã·ã«ã«ããã«åº
ãè¡šãããã¯ããŒããã³ãïŒâããªãªããµãŸãª
ãžã³ãžãªã³ãïŒâããªããã³ãã€ã³ããã«ããã«
é žãªã©ã®ïŒãïŒå¡ã®è€çŽ ç°æ žãå®æããã«å¿ èŠãª
åå矀ãè¡šããã äžè¬åŒ(K) R22ã¯R1ãšãZ16ã¯Z1ãšãL19ïŒL20ã¯L1ãšåæ矩
ãè¡šãããp7ã¯ïŒãŸãã¯ïŒããp8ã¯ïŒïŒïŒãŸãã¯
ïŒãè¡šããã G1ïŒG2ã¯ãåãã§ãç°ãªã€ãŠããŠããããR1
ãšåæ矩ãè¡šããããŸããå ±åã§ç°ç¶ã®ïŒçŽã¢ã
ã³ïŒäŸãã°ãããªãã³ãïŒâãããªã³ããããªãž
ã³ãããã©ãžã³ãã¢ã«ããªã³ãïŒïŒïŒïŒïŒïŒïŒâ
ããã©ããããããªã³ããã«ããããããªã³ãïŒ
âã¢ã¶ãã·ã¯ããïŒïŒïŒïŒïŒãããã³ãã€ã³ããª
ã³ãã¢ãŒãã³ãããŠãããµãããã¢ãŒãã³ïŒã圢
æããå¿ èŠãªåå矀ãè¡šãããX5ã¯X1ãšãn5ã¯
n1ãšåæ矩ãè¡šããã äžè¬åŒ(L) Z17ã¯Z4ãšãL21ïŒL22ïŒL23ã¯L1ãšãG3ïŒG4ã¯
G1ãšåæ矩ãè¡šãããp9ã¯ïŒïŒïŒïŒïŒãŸãã¯ïŒ
ãè¡šããã èµ€å€å æå æ§ãä»äžããã®ã«ç¹ã«æçšãªè²çŽ ã¯
次ã®äžè¬åŒ(M)ã(U)ã(W)ã(Y)ã§è¡šããããè²çŽ ã§ã
ãã äžè¬åŒ(M) ããã§R101ããã³R102ã¯åã åäžã§ãã€ãŠãç°
ãªã€ãŠããŠããããããããã¢ã«ãã«åºïŒå¥œãŸã
ãã¯ççŽ ååæ°ïŒãïŒãäŸãã°ã¡ãã«åºããšãã«
åºããããã«åºãããã«åºããã³ãã«åºãããã
ã«åºãªã©ïŒã眮æã¢ã«ãã«åºïŒçœ®æåºãšããŠäŸã
ã°ã«ã«ããã·åºãã¹ã«ãåºãã·ã¢ãåºãããã²ã³
ååïŒäŸãã°ããçŽ ååãå¡©çŽ ååãèçŽ ååãª
ã©ïŒãããããã·åºãã¢ã«ã³ãã·ã«ã«ããã«åº
ïŒççŽ ååæ°ïŒä»¥äžãäŸãã°ã¡ããã·ã«ã«ããã«
åºããšããã·ã«ã«ããã«åºããã³ãžã«ãªãã·ã«ã«
ããã«åºãªã©ïŒãã¢ã«ã³ãã·åºïŒççŽ ååæ°ïŒä»¥
äžãäŸãã°ã¡ããã·åºããšããã·åºãããããã·
åºããããã·åºããã³ãžã«ãªãã·åºãªã©ïŒãã¢ãª
ãŒã«ãªãã·åºïŒäŸãã°ããšããã·åºãïœâããªã«
ãªãã·åºãªã©ïŒãã¢ã·ã«ãªãã·åºïŒççŽ ååæ°ïŒ
以äžãäŸãã°ã¢ã»ãã«ãªãã·åºãããããªãã«ãª
ãã·åºãªã©ïŒãã¢ã·ã«åºïŒççŽ ååæ°ïŒä»¥äžãäŸ
ãã°ã¢ã»ãã«åºãããããªãã«åºããã³ãŸã€ã«
åºãã¡ã·ã«åºãªã©ïŒãã«ã«ãã¢ã€ã«åºïŒäŸãã°ã«
ã«ãã¢ã€ã«åºãïŒïŒ®âãžã¡ãã«ã«ã«ãã¢ã€ã«
åºãã¢ã«ããªãã«ã«ãã¢ã€ã«åºããããªãžãã«ã«
ãã¢ã€ã«åºãªã©ïŒãã¹ã«ãã¢ã¢ã€ã«åºïŒäŸãã°ã¹
ã«ãã¢ã¢ã€ã«åºãïŒïŒ®âãžã¡ãã«ã¹ã«ãã¢ã¢ã€
ã«åºãã¢ã«ããªãã¹ã«ããã«åºãªã©ïŒãã¢ãªãŒã«
åºïŒäŸãã°ããšãã«åºãïœâããããã·ããšãã«
åºãïœâã«ã«ããã·ããšãã«åºãïœâã¹ã«ãããš
ãã«åºãαâãããã«åºãªã©ïŒãªã©ã§çœ®æããã
ã¢ã«ãã«åºïŒççŽ ååæ°ïŒä»¥äžãäœããã®çœ®æåº
ã¯ïŒã€ä»¥äžçµåããŠã¢ã«ãã«åºã«çœ®æãããŠã
ããïŒãè¡šããã äžè¬åŒ(M)ã«ãããŠY101ïŒY102ã¯é žçŽ ååãç¡«é»
ååãã»ã¬ã³ååã ïŒR103ïŒR104ã¯ã¡ãã«åºãŸãã¯ãšãã«åºïŒãïŒïŒ®
âR105ãR105ã¯ççŽ æ°ïŒä»¥äžã®ç¡çœ®æãŸãã¯çœ®æ
ãããã¢ã«ãã«åºïŒçœ®æåºãšããŠã¯ããããã·ã«
åºãããã²ã³ååãã«ã«ããã·ã«åºãã¹ã«ãåºã
ã¢ã«ã³ãã·åºãªã©ããïŒãŸãã¯ã¢ãªã«åºããŸãã¯
âCHïŒCHâãè¡šããã äžè¬åŒ(M)ã«ãããŠZ101ïŒZ102ã¯ç¡çœ®æãŸãã¯çœ®
æããããã³ãŒã³ç°ãããã¯ãããã«ç°ã圢æã
ãã«å¿ èŠãªåå矀ãè¡šããã眮æåºãšããŠã¯ã¡ã
ã«åºãªã©ã®äœçŽã¢ã«ãã«åºãããã²ã³ååãããš
ãã«åºãããããã·ã«åºãççŽ æ°ïŒãïŒã®ã¢ã«ã³
ãã·åºãã«ã«ããã·ã«åºãã¢ã«ã³ãã·ã«ã«ããã«
åºãã¢ã«ãã«ã¹ã«ãã¢ã¢ã€ã«åºãã¢ã«ãã«ã«ã«ã
ã¢ã€ã«åºãã¢ã·ã«åºãã·ã¢ãåºãããªãã«ãªãã¡
ãã«åºããããåºãªã©ãããã Y101ãå«ãç°ãšZ101ããŸãã¯Y102ãå«ãç°ãš
Z102ã§äœãããå«çªçŽ è€çŽ ç°ãšããŠã¯äŸãã°ãã¢
ãŸãŒã«æ žç³»ãäŸãã°ãã³ãŸãã¢ãŸãŒã«ãïŒâã¯ã
ã«ãã³ãŸãã¢ãŸãŒã«ãïŒâã¯ãã«ãã³ãŸãã¢ãŸãŒ
ã«ãïŒâã¯ãã«ãã³ãŸãã¢ãŸãŒã«ãïŒâã¯ãã«ã
ã³ãŸãã¢ãŸãŒã«ãïŒâã¡ãã«ãã³ãŸãã¢ãŸãŒã«ã
ïŒâã¡ãã«ãã³ãŸãã¢ãŸãŒã«ãïŒâã¡ãã«ãã³ãŸ
ãã¢ãŸãŒã«ãïŒâããã¢ãã³ãŸãã¢ãŸãŒã«ãïŒâ
ããã¢ãã³ãŸãã¢ãŸãŒã«ãïŒâãšãŒããã³ãŸãã¢
ãŸãŒã«ãïŒâããšãã«ãã³ãŸãã¢ãŸãŒã«ãïŒâã¡
ããã·ãã³ãŸãã¢ãŸãŒã«ãïŒâã¡ããã·ãã³ãŸã
ã¢ãŸãŒã«ãïŒâãšããã·ãã³ãŸãã¢ãŸãŒã«ãïŒâ
ã«ã«ããã·ãã³ãŸãã¢ãŸãŒã«ãïŒâãšããã·ã«ã«
ããã«ãã³ãŸãã¢ãŸãŒã«ãïŒâããšããã«ãã³ãŸ
ãã¢ãŸãŒã«ãïŒâãã«ãªããã³ãŸãã¢ãŸãŒã«ãïŒ
âããªãã«ãªãã¡ãã«ãã³ãŸãã¢ãŸãŒã«ãïŒïŒïŒ
âãžã¡ãã«ãã³ãŸãã¢ãŸãŒã«ãïŒâã¡ãã«âïŒâ
ã¡ããã·ãã³ãŸãã¢ãŸãŒã«ãïŒâããããã·âïŒ
âã¡ãã«ãã³ãŸãã¢ãŸãŒã«ãããã©ããããã³ãŸ
ãã¢ãŸãŒã«ãïŒâããšãã«ãã³ãŸãã¢ãŸãŒã«ãã
ãããïŒïŒïŒâïœããã¢ãŸãŒã«ãããããïŒïŒïŒ
âïœããã¢ãŸãŒã«ãããããïŒïŒïŒâïœããã¢ãŸ
ãŒã«ãïŒâã¡ããã·ããããïŒïŒïŒâïœããã¢ãŸ
ãŒã«ãïŒâã¡ããã·ããããïŒïŒïŒâïœããã¢ãŸ
ãŒã«ãïŒâã¡ããã·ããããïŒïŒïŒâïœããã¢ãŸ
ãŒã«ãïŒâã¡ããã·ããããïŒïŒïŒâïœããã¢ãŸ
ãŒã«ãªã©ããã»ã¬ããŸãŒã«æ žç³»ãäŸãã°ãã³ãŸã»
ã¬ããŸãŒã«ãïŒâã¯ãã«ãã³ãŸã»ã¬ããŸãŒã«æ žã
ïŒâã¡ããã·ãã³ãŸãã¢ãŸãŒã«ãïŒâã¡ãã«ãã³
ãŸã»ã¬ããŸãŒã«ãïŒâããããã·ãã³ãŸã»ã¬ããŸ
ãŒã«ãããããïŒïŒïŒâïœãã»ã¬ããŸãŒã«ããã
ããïŒïŒïŒâïœãã»ã¬ããŸãŒã«ãªã©ãããªããµãŸ
ãŒã«æ žç³»ãäŸãã°ãã³ãŸãªããµã¢ãŸãŒã«ãïŒâã¯
ãã«ãã³ãŸãªããµãŸãŒã«ãïŒâã¡ãã«ãã³ãŸãªã
ãµãŸãŒã«ãïŒâããã ãã³ãŸãªããµãŸãŒã«ãïŒâ
ãã«ãªããã³ãŸãªããµãŸãŒã«ãïŒâããšãã«ãã³
ãŸãªããµãŸãŒã«ãïŒâã¡ããã·ãã³ãŸãªããµãŸãŒ
ã«ãïŒâããªãã«ãªãã¡ãã«ãã³ãŸãªããµãŸãŒ
ã«ãïŒâããããã·ãã³ãŸãªããµãŸãŒã«ãïŒâã«
ã«ããã·ãã³ãŸãªããµãŸãŒã«ãïŒâã¡ãã«ãã³ãŸ
ãªããµãŸãŒã«ãïŒâã¯ãã«ãã³ãŸãªããµãŸãŒã«ã
ïŒâã¡ããã·ãã³ãŸãªããµãŸãŒã«ãïŒâãããã
ã·ãã³ãŸãªããµãŸãŒã«ãïŒïŒïŒâãžã¡ãã«ãã³ãŸ
ãªããµãŸãŒã«ãïŒïŒïŒâãžã¡ãã«ãã³ãŸãªããµãŸ
ãŒã«ãïŒâãšããã·ãã³ãŸãªããµãŸãŒã«ãããã
ãïŒïŒïŒâïœããªããµãŸãŒã«ãããããïŒïŒïŒâ
ïœããªããµãŸãŒã«ãããããïŒïŒïŒâïœããªããµ
ãŸãŒã«ãªã©ãããããªã³æ žãäŸãã°ïŒâãããªã³ã
ïŒâã¡ãã«âïŒâãããªã³ãïŒâãšãã«âïŒâã
ããªã³ãïŒâã¡ãã«âïŒâãããªã³ãïŒâãã«ãª
ãâïŒâãããªã³ãïŒâã¡ããã·âïŒâãããª
ã³ãïŒâããããã·âïŒâãããªã³ãïŒâã¯ãã
âïŒâãããªã³ãïŒâãã«ãªãâïŒâãããªã³ãª
ã©ããïŒïŒïŒâãžã¢ã«ãã«ã€ã³ãã¬ãã³æ žïŒäŸã
ã°ãïŒïŒïŒâãžã¡ãã«ã€ã³ãã¬ãã³ãïŒïŒïŒâãž
ãšãã«ã€ã³ãã¬ãã³ãïŒïŒïŒâãžã¡ãã«âïŒâã·
ã¢ãã€ã³ãã¬ãã³ãïŒïŒïŒâãžã¡ãã«âïŒâã¡ã
ãã·ã€ã³ãã¬ãã³ãïŒïŒïŒâãžã¡ãã«âïŒâã¡ã
ã«ã€ã³ãã¬ãã³ãïŒïŒïŒâãžã¡ãã«âïŒâã¯ãã«
ã€ã³ãã¬ãã³ãªã©ïŒãã€ãããŸãŒã«æ žïŒäŸãã°ã
ïŒâã¡ãã«ãã³ãŸã€ãããŸãŒã«ãïŒâãšãã«ãã³
ãŸã€ãããŸãŒã«ãïŒâã¡ãã«âïŒâã¯ãã«ãã³ãŸ
ã€ãããŸãŒã«ãïŒâãšãã«âïŒâã¯ãã«ãã³ãŸã€
ãããŸãŒã«ãïŒâã¡ãã«âïŒïŒïŒâãžã¯ãã«ãã³
ãŸã€ãããŸãŒã«ãïŒâãšãã«âïŒïŒïŒâãžã¯ãã«
ãã³ãŸã€ãããŸãŒã«ãïŒâãšãã«âïŒâã¡ããã·
ãã³ãŸã€ãããŸãŒã«ãïŒâã¡ãã«âïŒâã·ã¢ãã
ã³ãŸã€ãããŸãŒã«ãïŒâãšãã«âïŒâã·ã¢ããã³
ãŸã€ãããŸãŒã«ãïŒâã¡ãã«âïŒâãã«ãªããã³
ãŸã€ãããŸãŒã«ãïŒâãšãã«âïŒâãã«ãªããã³
ãŸã€ãããŸãŒã«ãïŒâããšãã«âïŒïŒïŒâãžã¯ã
ã«ãã³ãŸã€ãããŸãŒã«ãïŒâã¢ãªã«âïŒïŒïŒâãž
ã¯ãã«ãã³ãŸã€ãããŸãŒã«ãïŒâã¢ãªã«âïŒâã¯
ãã«ãã³ãŸã€ãããŸãŒã«ãïŒâããšãã«ãã³ãŸã€
ãããŸãŒã«ãïŒâããšãã«âïŒâã¯ãã«ãã³ãŸã€
ãããŸãŒã«ãïŒâã¡ãã«âïŒâããªãã«ãªãã¡ã
ã«ãã³ãŸã€ãããŸãŒã«ãïŒâãšãã«âïŒâããªã
ã«ãªãã¡ãã«ãã³ãŸã€ãããŸãŒã«ãïŒâãšãã«ã
ãããïŒïŒïŒâïœãã€ãããŸãŒã«ãªã©ïŒãããã
ããã äžè¬åŒ(M)ã«ãããŠïŒ¹ã¯ïŒå¡ãŸãã¯ïŒå¡ã®ççŽ ç°
ã圢æããã®ã«å¿ èŠãªåå矀ãŸãã¯ç°ã圢æããª
ãå Žåã¯åã«ã¡ãã³éãè¡šããã äžè¬åŒ(M)ã«ãããŠã m101ã¯ïŒãŸãã¯ïŒãè¡šããã X101ã¯é žæ®åºãè¡šããã m102ã¯ïŒãŸãã¯ïŒãè¡šãããè²çŽ ããã¿ã€ã³
æ§é ããšããšãã¯ïŒã§ããã L101ïŒL102ã¯ã¡ãã³åºãŸãã¯çœ®æã¡ãã³åºãè¡š
ããã眮æã¡ãã³åºãšããŠã¯ççŽ æ°ïŒãïŒã®äœçŽ
ã¢ã«ãã«åºãäœçŽã¢ã«ã³ãã·åºãã¢ãªãŒã«åºïŒã
ã®ã¢ãªãŒã«åºã«ã¯ããã²ã³ååãççŽ æ°ïŒãïŒã®
ã¢ã«ãã«åºãççŽ æ°ïŒãïŒã®ã¢ã«ã³ãã·åºãã¹ã«
ãåºãã«ã«ããã·åºãªã©ã眮æããŠããŠãããïŒã
ã¢ã©ã«ãã«åºïŒãã³ãžã«åºãªã©ïŒãªã©ã«ãã眮æ
ãããã¡ãã³åºããããããã äžè¬åŒ(N) åŒäžã Y103ïŒY104ã¯Y101ãšåæ矩ã§ããã R106ïŒR107ã¯R101ãšåæ矩ã§ããã Z103ïŒZ104ã¯Z101ãšåæ矩ã§ããã X102ã¯X101ãšåæ矩ã§ããã m103ã¯m102ãšåæ矩ã§ããã ïŒããã§åæ矩ãšã¯äžè¬åŒ(M)ã®å®çŸ©ãšåæ矩ã§
ããããšããããïŒ äžè¬åŒ(O) åŒäžã Z105ã¯ïŒâãããªã³æ žãïŒâãããªã³æ žãå®æ
ããã«å¿ èŠãªåå矀ãè¡šããã Z106ã¯Z101ãšåæ矩ã§ããã p101ã¯ïŒãŸãã¯ïŒãè¡šããã m104ã¯ïŒãŸãã¯ïŒãè¡šããã Y105ã¯Y101ãšåæ矩ã§ããã R108ïŒR109ã¯R101ãšåæ矩ã§ããã X103ã¯X101ãšåæ矩ã§ããã m105ã¯m102ãšåæ矩ã§ããã L103ãL104ã¯L101ãšåæ矩ã§ããã ïŒããã§åæ矩ãšã¯äžè¬åŒ(M)ã®å®çŸ©ãšåæ矩ã§
ããããšããããïŒ äžè¬åŒ(P) åŒäžã Z109ã¯Z101ïŒZ100ãšåæ矩ã§ããã R110ïŒR111ã¯R101ãšåæ矩ã§ããã Y108ã¯ïŒ¹ãšåæ矩ã§ããã X104ã¯X101ãšåæ矩ã§ããã m106ã¯m102ãšåæ矩ã§ããã Y106ïŒY107ã¯Y101ãšåæ矩ã§ããã ïŒããã§åæ矩ãšã¯äžè¬åŒ(M)ã®å®çŸ©ãšåæ矩ã§
ããããšããããïŒ R112ïŒR113ã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«åºãŸãã¯
ããšãã«åºãŸãã¯R112ïŒR113ãé£çµããŠïŒãŸãã¯
ïŒå¡è€çŽ ç°ã圢æããã«å¿ èŠãªåå矀ãè¡šããã äžè¬åŒ(Q) åŒäžã Z110ã¯Z101ãšåæ矩ã§ããã Y109ã¯Y101ãšåæ矩ã§ããã Y111ã¯é žçŽ ååãç¡«é»ååãã»ã¬ã³ååãïŒïŒ®
âR116ïŒR116ã¯R105ãšåæ矩ïŒãè¡šããã R114ã¯R101ãšåæ矩ã§ããã R115ã¯R101ãšåæ矩ã®åºã®ä»ãããšãã«åºãã
ãªãžã«åºã眮æããšãã«åºã眮æããªãžã«åºãè¡š
ããã眮æåºãšããŠã¯ãã¹ã«ãã³åºãã«ã«ããã·
åºãã·ã¢ãåºãããã²ã³ååïŒäŸãã°å¡©çŽ ååã
èçŽ ååãããçŽ ååãªã©ïŒãC1ãC4ã®ã¢ã«ãã«
åºãC1ãC4ã®ã¢ã«ã³ãã·åºããžã¢ã«ãã«ã¢ãã
åºãã¢ã·ã«åºãã¢ã«ã³ãã·ã«ã«ããã«åºãªã©ãã
ãã Y110ã¯ïŒ¹ãšåæ矩ã§ããã m107ã¯m101ãšåæ矩ã§ããã L105ïŒL106ã¯L101ãšåæ矩ã§ããã ïŒããã§åæ矩ãšã¯äžè¬åŒ(M)ã®å®çŸ©ãšåæ矩ã§
ããããšããããïŒ äžè¬åŒ(R) åŒäžã Z110ïŒY109ïŒY110ïŒY111ïŒR114ïŒR115L105ãã
ã³L106ããã³m107ã¯äžè¬åŒ(Q)ã«ããããã®ãšåæ
矩ã§ããã äžè¬åŒ(S) åŒäžã Z111ïŒZ112ã¯Z101ãšåæ矩ã§ããã Y112ïŒY114ã¯Y101ãšåæ矩ã§ããã R117ïŒR119ã¯R101ãšåæ矩ã§ããã R118ã¯R105ãšåæ矩ã§ããã Y113ã¯ïŒ¹ãšåæ矩ã§ããã X105ã¯X101ãšåæ矩ã§ããã m108ã¯m102ãšåæ矩ã§ããã ïŒããã§åæ矩ãšã¯äžè¬åŒ(M)ã®å®çŸ©ãšåæ矩ã§
ããããšããããïŒ äžè¬åŒ(T) åŒäžã Z113ïŒZ114ã¯Z101ãšåæ矩ã§ããã Y115ïŒY116ã¯Y101ãšåæ矩ã§ããã R121ïŒR122ã¯R101ãšåæ矩ã§ããã X106ã¯X101ãšåæ矩ã§ããã m109ã¯m102ãšåæ矩ã§ããã ïŒä»¥äžã§åæ矩ãšã¯äžè¬åŒ(M)ã®å®çŸ©ãšåæ矩ã§
ããããšããããïŒ R120ã¯äžè¬åŒ(S)ã®R118ãšåæ矩ã§ããã äžè¬åŒ(U) åŒäžã Y117ã¯ïŒ¹ãšåæ矩ã§ããã Y108ã¯Y101ãšåæ矩ã§ããã Z115ã¯Z105ãšåæ矩ã§ããã Z116ã¯Z101ãšåæ矩ã§ããã R123ïŒR124ã¯R101ãšåæ矩ã§ããã ïœã¯äžè¬åŒ(C)ã®p1ãšåæ矩ã§ããã X107ã¯X101ãšåæ矩ã§ããã m110ã¯m102ãšåæ矩ã§ããã ïŒä»¥äžã§åæ矩ãšã¯äžè¬åŒ(M)ã®å®çŸ©ãšåæ矩ã§
ããããšããããïŒ R125ã¯äžè¬åŒ(S)ã®R118ãšåæ矩ã§ããã äžè¬åŒ(W) åŒäžã Z117ãZ118ã¯Z101ãšåæ矩ã§ããã Y119ãY120ã¯Y101ãšåæ矩ã§ããã R126ãR127ã¯R101ãšåæ矩ã§ããã X108ã¯X101ãšåæ矩ã§ããã m111ã¯m102ãšåæ矩ã§ããã L107ã¯L101ãšåæ矩ã§ããã ïŒä»¥äžã§åæ矩ãšã¯äžè¬åŒ(M)ã®å®çŸ©ãšåæ矩ã§
ããããšããããïŒ R128ã¯äžè¬åŒ(S)ã®R118ãšåæ矩ã§ããã äžè¬åŒ(Y) åŒäžã Z119ïŒZ120ã¯Z101ãšåæ矩ã§ããã Y121ïŒY122ã¯Y101ãšåæ矩ã§ããã R129ïŒR130ã¯R101ãšåæ矩ã§ããã L108ïŒL109ïŒL110ïŒL111ïŒL112ïŒL113ïŒL114ã¯
L101ãšåæ矩ã§ããã X109ã¯X101ãšåæ矩ã§ããã m112ã¯ã¯m102ãšåæ矩ã§ããã ïŒããã§åæ矩ãšã¯äžè¬åŒ(M)ã®å®çŸ©ãšåæ矩ã§
ããããšããããïŒ æ¬çºæã«ãããŠåèšå¢æè²çŽ ã¯ãç±³åœç¹èš±ç¬¬
4183756å·ã«åŸã€ãŠããã²ã³åéç²åãçããå
ã«å¯æº¶æ§éå¡©ïŒäŸãã°ç¡é žéïŒãšããã²ã³åç©
ïŒäŸãã°èåã«ãªãŠã ïŒãšã®åå¿ç³»ã«ååšãããŠ
ãããããç±³åœç¹èš±ç¬¬4225666å·ã«åŸã€ãŠããã²
ã³åéç²åã®æ žåœ¢æåŸã§ãäžã€ããã²ã³åéç²å
圢æå·¥çšçµäºåã«ãäžèšã®åå¿ç³»ã«ååšãããŠã
ããããŸãããã²ã³åéç²å圢æãšåæããªãã¡
äžèšéå¡©ãšããã²ã³åç©ãšãæ··åããã®ãšåæã«
å¢æè²çŽ ãåå¿æ¶²äžã«ååšãããŠãããããã®æ¹
æ³ã¯ãã®ããã«ããŠäœã€ãä¹³å€ãå«ãæå ææã®
é«æž©ç¶æ ã§ã®ä¿åæ§ãããåªããŠãããšããç¹ã§
ç¹ã«å¥œãŸããã äžèšã®ãããã®æ·»å æ¹æ³ã«ãããŠããè²çŽ ã®ç·
æ·»å éãäžåºŠã«æ·»å ããŠãããããŸããäœåãã«
åå²ããŠæ·»å ããŠããããããã«ã¯å¯æº¶æ§éå¡©ã
ãã³ïŒãŸãã¯ããã²ã³åç©ãšã®æ··åç©ã®åœ¢ã§è²çŽ
ãæ·»å ããŠãè¯ãã ãŸãäžçš®é¡ã®è²çŽ ãåç¬ã§çšããŠããäºçš®ä»¥äž
ãè²çŽ ã䜵çšããŠãïŒæ··åããŠæ·»å ããŠããå¥ã
ã«æ·»å ããŠãããããã¯æ·»å ææãããããŠäžçš®
é¡ãã€æ·»å ããŠãïŒãããã§ããããåŸè ã®å Ž
åããã®äžã«åŒ·è²å¢æå€ãå«ãã§ãè¯ãã è²çŽ ã¯æ¶²é¢æ·»å ã液äžæ·»å ãããã§ãå¯èœã§ã
ããæ¹æãåŸæ¥ã®ãããã®æ¹æãçšããããšãã§
ããã å¢æè²çŽ ã¯ã¡ã¿ããŒã«ããšã¿ããŒã«ããããã
ãŒã«ãããçŽ åã¢ã«ã³ãŒã«ã¡ãã«ã»ããœã«ãããž
ã¡ãã«ãã«ã ã¢ãããã¢ã»ãã³çã®æ°Žãšçžæº¶æ§ã®
ããææ©æº¶å€ãæ°ŽïŒã¢ã«ã«ãªæ§ã§ãé žæ§ã§ãã
ãïŒã«æº¶è§£ãããŠæ·»å ããŠãããããäžèšã®ãã®
ãïŒçš®é¡ä»¥äžäœµçšããŠãããããŸãæ°ŽïŒãŒã©ãã³
åæ£ç³»ã«åæ£ãã圢ã§ãŸãã¯åçµä¹Ÿç¥ããç²æ«ã®
圢ã§æ·»å ããŠããããããã«çé¢æŽ»æ§å€ãçšããŠ
åæ£ããç²æ«ã¯ã溶液ã®åœ¢ã§æ·»å ããŠãããã å¢æè²çŽ ã®äœ¿çšéã¯ä¹³å€è£œé ã«äœ¿çšããé100
ïœããã0.001ïœã20ïœãé©åœã§ããã奜ãŸãã
ã¯0.01ïœãïŒïœã§ããã ããã²ã³åéç²å圢æåå¿éçšã«ãããåå¿æ¶²
äžã®å¢æè²çŽ ã®æ¿åºŠã¯ãïŒééïŒ ä»¥äžãé©åœã§ã
ãã奜ãŸããã¯0.1ééïŒ ä»¥äžã§ããã æ¬çºæã«ãŠäœè£œããããã²ã³åéä¹³å€ã®ååŠç
æéçšäžãŸãã¯ãä¹³å€å¡åžåã®ä»ã®éçšäžã«ãã
ãŠããã«åçš®ãŸãã¯å¥çš®ã®å¢æè²çŽ ãããã¯åŒ·è²
å¢æå€ãè¿œå æ·»å ããŠãè¯ãã 匷è²å¢æå€ãšããŠã¯äŸãã°ãå«çªçŽ ç°ç¯ç°åºã§
眮æãããã¢ããã¹ããªã«ååç©ïŒããšãã°ç±³åœ
ç¹èš±ç¬¬2933390å·ãå第3635721å·ã«èšèŒã®ãã®ïŒã
è³éŠæææ©é žãã«ã ã¢ã«ãããçž®åç©ïŒããšãã°
ç±³åœç¹èš±ç¬¬3743510å·ã«èšèŒã®ãã®ïŒãã«ãããŠã
å¡©ãã¢ã¶ã€ã³ãã³ååç©ãªã©ãå«ãã§ããããç±³
åœç¹èš±ç¬¬3615613å·ãå第3615641å·ãå第
3617295å·ãå第3635721å·ã«èšèŒã®çµåãã¯ç¹ã«
æçšã§ããã æ¬çºæã«ãããŠã¯å°ãªããšãïŒçš®ã®ããããç°
ãªãã¹ãã¯ãã«é åã«å¯èœæ§ãæããããã²ã³å
éãå¿ èŠã§ãããããã®éæ¬çºæã®ä¹³å€ãšéåžžã®
ããã²ã³åéç²å圢æåŸã«å¢æè²çŽ ãæ·»å ããŠè²
å¢æïŒã¹ãã¯ãã«é åã¯ç°ãªã€ãŠããŠããåãã§
ãè¯ãïŒããä¹³å€ãšã䜵çšããããšãå¯èœã§ã
ããæ·»å ããè²çŽ ããã³ãã®æº¶å€ã«ã€ããŠã¯å ã«
èšãããã®ãåèã«ããããšãã§ããã æ¬çºæã«äœ¿çšãããããã²ã³åéã¯ãå¡©åéã
èåéãæ²åéããããã¯å¡©èåéãå¡©æ²åéã
æ²èåéãå¡©æ²èåéã®ãããã§ããããç²åå
ã®ããã²ã³çµæãåäžã§ãã€ãŠããããè¡šé¢ãšå
éšã§çµæã®ç°ã€ãå€éæ§é ã§ãã€ãŠãããïŒç¹é
æ57â154232å·ãå58â108533å·ãå59â48755
å·ãå59â52237å·ãç±³åœç¹èš±ç¬¬4433048å·ããã³
殎å·ç¹èš±ç¬¬100984å·ïŒããŸããç²åã®åã¿ã0.5ã
ã¯ãã³ä»¥äžãç²åŸã¯å°ãªããšã0.6ãã¯ãã³ã§å¹³
åã¢ã¹ãã¯ãæ¯ãïŒä»¥äžã®å¹³æ¿ç²åïŒç±³åœç¹èš±ç¬¬
4414310å·ãå4435499å·ããã³***å ¬éç¹èš±
ïŒOLSïŒç¬¬3241646A1ãªã©ïŒãããã¯ç²åãµã€ãº
ååžã®åäžã«è¿ãååæ£ä¹³å€ïŒç¹éæ57â178235
å·ãå58â100846å·ãå58â14829å·ãåœéå ¬é
83ïŒ02338A1å·ã殎å·ç¹èš±ç¬¬64412A3ãããã³å
第83377A1ãªã©ïŒãæ¬çºæã«äœ¿çšããããæ¶çã
ããã²ã³çµæãç²åãµã€ãºãç²åãµã€ãºååžãªã©
ãç°ã€ãïŒçš®ä»¥äžã®ããã²ã³åéã䜵çšããŠãã
ããç²åãµã€ãºã®ç°ãªãäºçš®ä»¥äžã®ååæ£ä¹³å€ã
æ··åããŠãé調ã調ç¯ããããšãã§ããã æ¬çºæã§çšããããããã²ã³åéã®ç²åãµã€ãº
ã¯ãå¹³åç²åŸã0.001ãã¯ãã³ãã10ãã¯ãã³ã®
ãã®ã奜ãŸããã0.001ãã¯ãã³ãã5ÎŒã®ãã®ã¯
ããã«å¥œãŸããããããã®ããã²ã³åéä¹³å€ã¯ã
é žæ§æ³ãäžæ§æ³ãŸãã¯ã¢ã³ã¢ãã¢æ³ã®ãããã§èª¿
補ããŠããããå¯æº¶æ§éå¡©ãšå¯æº¶æ§ããã²ã³å¡©ãš
ã®åå¿åœ¢åŒãšããŠã¯ãçåŽæ··åæ³ãåææ··åæ³ãŸ
ãã¯ãããã®çµåãã®ãããã§ããããç²åãé
ã€ãªã³éå°ã®äžã§åœ¢æããéæ··åæ³ããŸãã¯pAg
ãäžå®ã«ä¿ã€ã³ã³ãããŒã«ãã»ããã«ãžãšããæ³
ãæ¡çšã§ããããŸããç²åæé·ãéãããããæ·»
å ããéå¡©ããã³ããã²ã³å¡©ã®æ·»å æ¿åºŠãæ·»å é
ãŸãã¯æ·»å é床ãäžæãããŠãããïŒç¹éæ55â
142329å·ãå55â158124å·ãç±³åœç¹èš±ç¬¬3650757
å·ãªã©ïŒã ãšãã¿ãã·ã¢ã«æ¥ååã®ããã²ã³åéç²åã䜿
çšã§ããïŒç¹éæ56â16124å·ãç±³åœç¹èš±ç¬¬
4094684å·ïŒã æ¬çºæã§ææ©éå¡©é žåå€ã䜵çšããã«ããã²ã³
åéãåç¬ã§äœ¿çšãããšãã¯ã奜ãŸããã¯æ²åé
çµæ¶ã®ïŒžç·ãã¿ãŒã³ãèªããããããªå¡©æ²åéã
æ²èåéãå¡©æ²èåéã§ãããäŸãã°èåã«ãªãŠ
ã 溶液äžã«ç¡é žé溶液ãæ·»å ããŠèåéç²åãäœ
ããããã«æ²åã«ãªãŠã ãæ·»å ãããšäžèšã®ç¹æ§
ãæããæ²èåéãåŸãããã æ¬çºæã§äœ¿çšããããã²ã³åéç²åã®åœ¢æ段é
ã«ãããŠãããã²ã³åé溶å€ãšããŠã¢ã³ã¢ãã¢ã
ç¹å ¬æ47â11386å·ã«èšèŒã®ææ©ããªãšãŒãã«èª
å°äœãŸãã¯ç¹éæ53â144319å·ã«èšèŒãããŠãã
å«ç¡«é»ååç©ãªã©ãçšããããšãã§ãããç²å圢
æãŸãã¯ç©ççæã®éçšã«ãããŠãã«ãããŠã
å¡©ãäºéå¡©ãéå¡©ãã¿ãªãŠã å¡©ãªã©ãå ±åãããŠ
ãããã ããã«é«ç §åºŠäžè»ãäœç §åºŠäžè»ãæ¹è¯ããç®ç
ã§å¡©åã€ãªãžãŠã ïŒïŒïŒããããµã¯ããã€ãª
ãžãŠã é žã¢ã³ã¢ããŠã ãªã©ã®æ°Žæº¶æ§ã€ãªãžãŠã
å¡©ããããã¯å¡©åããžãŠã ãªã©ã®æ°Žæº¶æ§ããžãŠã
å¡©ãçšããããšãã§ããã ããã²ã³åéã¯ä¹³å€ãšããŠçšããããããä¹³å€
ã¯æ²æŸ±åœ¢æåŸãããã¯ç©ççæåŸã«å¯æº¶æ§å¡©é¡ã
é€å»ããŠãããããã®ããããŒãã«æ°ŽæŽæ³ãæ²é
æ³ã«åŸãããšãã§ãããããã²ã³åéä¹³å€ã¯ãæª
åŸçã®ãŸãŸäœ¿çšããŠããããéåžžã¯ååŠå¢æããŠ
䜿çšãããéåžžåææçšä¹³å€ã§å ¬ç¥ã®ç¡«é»å¢æ
æ³ãéå å¢ææ³ã貎éå±å¢ææ³ãªã©ãåç¬ãŸãã¯
çµåããŠçšããããšãã§ããããããã®ååŠå¢æ
ãå«çªçŽ è€çŽ ç°ååç©ã®ååšäžã§ãè¡ãããšãã§
ããïŒç¹éæ58â126526å·ãå58â215644å·ïŒã æ¬çºæã®ããã²ã³åéä¹³å€ã¯ãäž»ãšããŠæœåã
ç²åè¡šé¢ã«åœ¢æãããè¡šé¢æœååã§ãã€ãŠããç²
åå éšã«åœ¢æãããå éšæœååã§ãã€ãŠãããã
å éšæœååä¹³å€ãšé æ žå€ãšãçµåããçŽæ¥å転乳
å€ã䜿çšããããšãã§ããããã®ç®çã«é©ããå
éšæœååä¹³å€ã¯ç±³åœç¹èš±ç¬¬2592250å·ãå第
3761276å·ãç¹å ¬æ58â3534å·ããã³ç¹éæ57â
136641å·ãªã©ã«èšèŒãããŠããã çµåããã®ã«å¥œãŸããé æ žå€ã¯ãç±³åœç¹èš±ç¬¬
3227552å·ãå第4245037å·ãå第4255511å·ãå
第4266013å·ãå第4276364å·ããã³***å ¬éç¹èš±
ïŒOLSïŒç¬¬2635316å·ã«èšèŒãããŠããã æ¬çºæã«ãããŠäœ¿çšãããæå æ§ããã²ã³åé
ã®å¡èšéã¯éæç®ïŒmgãªãã10ïœïŒm2ã®ç¯å²ã§ã
ãã æ¬çºæã«ãããŠã¯ãæå æ§ããã²ã³åéã«å ã«
察ããŠæ¯èŒçå®å®ãªææ©éå¡©ãé žåå€ãšããŠäœµçš
ããããšãã§ããããã®å Žåãæå æ§ããã²ã³å
éã®å¡èšéã¯éæç®ïŒmgãªãã10ïœïŒm2ã®ç¯å²ã§
ããã æ¬çºæã«ãããŠã¯ãæå æ§ããã²ã³åéã«å ã«
察ããŠæ¯èŒçå®å®ãªææ©éå¡©ãé žåå€ãšããŠäœµçš
ããããšãã§ããããã®å Žåãæå æ§ããã²ã³å
éãšææ©éå¡©ãšã¯æ¥è§Šç¶æ ãããã¯æ¥è¿ããè·é¢
ã«ããããšãå¿ èŠã§ããã80â以äžå¥œãŸããã¯
100â以äžã®æž©åºŠã«å ç±ããããšãããã²ã³åé
ã®æœåã觊åªãšããŠãææ©éå±é žåå€ãã¬ããã¯
ã¹ã«é¢äžãããšèããããã ãã®ãããªææ©éå¡©é žåå€ã圢æããã®ã«äœ¿çš
ãããææ©ååç©ãšããŠã¯ãèèªæãããã¯è³éŠ
æã®ã«ã«ãã³é žãã¡ã«ã«ããåºãããã¯Î±âæ°ŽçŽ
ãæããããªã«ã«ããã«åºå«æååç©ãããã³ã€
ããåºå«æååç©ãªã©ãæããããã èèªæã«ã«ãã³é žã®éå¡©ãšããŠã¯ãããã³é žã
ã¹ãã¢ãªã³é žããªã¬ã€ã³é žãã©ãŠãªã³é žãã«ããª
ã³é žãããªã¹ãã³é žããã«ããã³é žããã¬ã€ã³
é žããããŒã«é žãé ç³é žãããã€ã³é žããªããŒã«
é žããªãã¬ã³é žããªã¬ã€ã³é žãã¢ãžãã³é žãã»ã
ã·ã³é žããã¯ãé žãé ¢é žãé ªé žããŸãã¯æšè³é žã
ãèªå°ãããéå¡©ãå žåäŸãšããŠæãããããã
ããã®èèªæã®ããã²ã³ååãããã¯æ°Žé žåºçœ®æ
äœãŸãã¯ããªãšãŒãã«åºãæããèèªæã«ã«ãã³
é žãªã©ããèªå°ãããéå¡©ããŸã䜿çšã§ããã è³éŠæã«ã«ãã³é žããã³ãã®ä»ã®ã«ã«ããã·ã«
åºå«æååç©ã®éå¡©ãšããŠãå®æ¯éŠé žãïŒïŒïŒâ
ãžããããã·å®æ¯éŠé žãïœâãïœâãããã¯ïœâ
ã¡ãã«å®æ¯éŠé žãïŒïŒïŒâãžã¯ãã«å®æ¯éŠé žãã¢
ã»ãã¢ããå®æ¯éŠé žãïœâããšãã«å®æ¯éŠé žã没
é£åé žãã¿ã³ãã³é žããã¿ã«é žããã¬ãã¿ã«é žã
ãµãªãã«é žãããšãã«é ¢é žãããã¡ãªããé žãŸã
ã¯ïŒâã«ã«ããã·ã¡ãã«âïŒâã¡ãã«âïŒâãã¢
ãŸãªã³âïŒâããªã³ãªã©ããèªå°ãããéå¡©ã代
è¡šäŸãšããŠæããããã ã¡ã«ã«ãããããã¯ããªã«ã«ããã«åºãæãã
ååç©ã®éå¡©ãšããŠã¯ãïŒâã¡ã«ã«ããâïŒâã
ãšãã«âïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«ãïŒâã¡ã«ã«
ãããã³ãŸã€ãããŸãŒã«ãïŒâã¡ã«ã«ããâïŒâ
ã¢ãããã¢ãžã¢ãŸãŒã«ãïŒâã¡ã«ã«ãããã³ãã
ã¢ãŸãŒã«ãâã¢ã«ãã«ããªã°ãªã³ãŒã«é žïŒã¢ã«
ãã«åºççŽ æ°12ãªãã22ïŒããžããªé ¢é žãªã©ãžã
ãªã«ã«ãã³é žé¡ãããªã¹ãã¢ãã¢ãããªã©ããªã¢
ããé¡ãïŒâã«ã«ããã·âïŒâã¡ãã«âïŒâããš
ãã«âïŒâããªããªãžã³ãã¡ã«ã«ããããªã¢ãž
ã³ãïŒâã¡ã«ã«ãããã³ãŸãªããµãŸãŒã«ãã¡ã«ã«
ãããªããµãžã¢ãŸãŒã«ãŸãã¯ïŒâã¢ããâïŒâã
ã³ãžã«ããªâïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«ãªã©ç±³åœ
ç¹èš±ç¬¬4123274å·èšèŒã®ã¡ã«ã«ããååç©ãªã©ã
ãèªå°ãããéå¡©ãæããããã ã€ããåºãæããååç©ã®éå¡©ãšããŠã¯ãç¹å ¬
æ44â30270å·ãŸãã¯å45â18416å·èšèŒã®ãã³ãŸ
ããªã¢ãŸãŒã«ãããã¯ãã®èªå°äœäŸãã°ãã³ãŸã
ãªã¢ãŸãŒã«ãã¡ãã«ãã³ãŸããªã¢ãŸãŒã«ãªã©ã¢ã«
ãã«çœ®æãã³ãŸããªã¢ãŸãŒã«é¡ãïŒâã¯ãããã³
ãŸããªã¢ãŸãŒã«ãªã©ããã²ã³çœ®æãã³ãŸããªã¢ãŸ
ãŒã«é¡ãããã«ã«ã«ãã€ãããã³ãŸããªã¢ãŸãŒã«
ãªã©ã«ã«ãã€ãããã³ãŸããªã¢ãŸãŒã«é¡ãç¹éæ
58â118639å·èšèŒã®ããããã³ãŸããªã¢ãŸãŒã«
é¡ãç¹éæ58â118638å·èšèŒã®ã¹ã«ããã³ãŸããª
ã¢ãŸãŒã«ãã«ã«ããã·ãã³ãŸããªã¢ãŸãŒã«ããã
ã¯ãã®å¡©ããŸãã¯ããããã·ãã³ãŸããªã¢ãŸãŒã«
ãªã©ãç±³åœç¹èš±ç¬¬4220709å·èšèŒã®ïŒïŒïŒïŒïŒâ
ããªã¢ãŸãŒã«ã1Hâããã©ãŸãŒã«ãã«ã«ããŸãŒ
ã«ããµãã«ãªã³ãã€ãããŸãŒã«ããã³ãã®èªå°äœ
ãªã©ããèªå°ãããéå¡©ã代衚äŸãšããŠæããã
ãã ãŸããªãµãŒãã»ãã€ã¹ã¯ããŒãžã€ãŒèª17029
ïŒ1978幎ïŒæïŒã«èšèŒãããŠããéå¡©ãã¹ãã¢ãª
ã³é žé ãªã©ã®é塩以å€ã®ææ©éå±å¡©ãç¹é¡æ58â
221535å·èšèŒã®ããšãã«ããããªãŒã«é žãªã©ã¢ã«
ããã«åºãæããã«ã«ãã³é žã®éå¡©ãæ¬çºæã§äœ¿
çšã§ããã 以äžã®ææ©éå¡©ã¯æå æ§ããã²ã³åéïŒã¢ã«ã
ããã0.01ãªãã10ã¢ã«ã奜ãŸããã¯0.01ãªãã
ïŒã¢ã«ã䜵çšããããšãã§ãããæå æ§ããã²ã³
åéãšææ©éå¡©ã®å¡åžéåèšã¯ïŒmgãªãã10ïœïŒ
m2ãé©åœã§ããã æ¬çºæã«çšããããä¹³å€ã«ã¯ãæå ææã®è£œé
å·¥çšãä¿åäžãããã¯åçåŠçäžã®ã«ããªãé²æ¢
ãããããã¯åçæ§èœãå®å®åãããç®çã§ã
çš®ã ã®ååç©ãå«æãããããšãã§ããã ããªãã¡ã¢ãŸãŒã«é¡ãäŸãã°ãã³ãŸãã¢ãŸãªãŠ
ã å¡©ããããã€ãããŸãŒã«é¡ãããããã³ãºã€ã
ããŸãŒã«é¡ãã¯ãããã³ãºã€ãããŸãŒã«é¡ããã
ã¢ãã³ãºã€ãããŸãŒã«é¡ãã¡ã«ã«ãããã¢ãŸãŒã«
é¡ãã¡ã«ã«ãããã³ãŸãã¢ãŸãŒã«é¡ãã¡ã«ã«ãã
ãã³ãºã€ãããŸãŒã«é¡ãã¡ã«ã«ãããã¢ãžã¢ãŸãŒ
ã«é¡ãã¢ããããªã¢ãŸãŒã«é¡ããã³ãŸããªã¢ãŸãŒ
ã«é¡ãããããã³ãŸããªã¢ãŸãŒã«é¡ãã¡ã«ã«ãã
ããã©ãŸãŒã«é¡ïŒç¹ã«ïŒâããšãã«âïŒâã¡ã«ã«
ããããã©ãŸãŒã«ïŒãªã©ïŒã¡ã«ã«ããããªããžã³
é¡ïŒã¡ã«ã«ããããªã¢ãžã³é¡ïŒããšãã°ãªããµã
ãªã³ããªã³ã®ãããªããªã±ãååç©ïŒã¢ãžã€ã³ã
ã³é¡ãããšãã°ããªã¢ã¶ã€ã³ãã³é¡ïŒããã©ã¢ã¶
ã€ã³ãã³é¡ïŒç¹ã«ïŒâããããã·çœ®æïŒïŒïŒïŒïŒ
3aïŒïŒïŒããã©ã¢ã¶ã€ã³ãã³é¡ïŒããã³ã¿ã¢ã¶ã€
ã³ãã³é¡ãªã©ïŒãã³ãŒã³ããªã¹ã«ããªã³é žããã³
ãŒã³ã¹ã«ãã€ã³é žããã³ãŒã³ã¹ã«ããªã³é žã¢ãã
çã®ãããªã«ããªé²æ¢å€ãŸãã¯å®å®å€ãšããŠç¥ã
ãããå€ãã®ååç©ãå ããããšãã§ãããããš
ãã°ç±³åœç¹èš±ç¬¬3954474å·ãå第3982947å·ãç¹å ¬
æ52â28660å·çã«èšèŒããããã®ãçšããããš
ãã§ããã æ¬çºæã®ããã²ã³åé調補æ³ã«ãããŠã¯ãä¿è·
ã³ãã€ããšããŠãŒã©ãã³ãçšããã®ãæå©ã§ãã
ãããã以å€ã®èŠªæ°Žæ§ã³ãã€ããçšããããšãã§
ããã ããšãã°ãŒã©ãã³èªå°äœããŒã©ãã³ãšä»ã®é«å
åãšã®ã°ã©ããããªããŒãã¢ã«ããã³ãã«ãŒã€ã³
çã®èçœè³ªïŒããããã·ãšãã«ã»ã«ããŒã¹ãã«ã«
ããã·ã¡ãã«ã»ã«ããŒã¹ãã»ã«ããŒã¹ç¡«é žãšã¹ã
ã«é¡çã®ãããªã»ã«ããŒã¹èªå°äœãã¢ã«ã®ã³é žãœ
ãŒãã柱ç²èªå°äœãªã©ã®ç³èªå°äœïŒããªããã«ã¢
ã«ã³ãŒã«ãããªããã«ã¢ã«ã³ãŒã«éšåã¢ã»ã¿ãŒ
ã«ãããªââããã«ãããªãã³ãããªã¢ã¯ãªã«
é žãããªã¡ã¿ã¯ãªã«é žãããªã¢ã¯ãªã«ã¢ãããã
ãªããã«ã€ãããŸãŒã«ãããªããã«ãã©ãŸãŒã«ç
ã®åäžãããã¯å ±éåäœã®ãããªå€çš®ã®åæ芪氎
æ§é«ååç©è³ªãçšããããšãã§ããã ãŒã©ãã³ãšããŠã¯ç³ç°åŠçãŒã©ãã³ã®ã»ãé žåŠ
çãŒã©ãã³ãããªãã³ ãªã 㶠ãœãµã€ã€ãã€
ãªã ãµã€ãšã³ããã€ã㯠ããªãã°ã©ãã€
ãªã ãžã€ãã³ïŒBull.Soc.Sci.Phot.JapanïŒïŒã
ã³ããŒïŒNo.ïŒ16ã30é ïŒ1966ïŒã«èšèŒããããã
ãªé µçŽ åŠçãŒã©ãã³ãçšããŠãããããŸããŒã©ã
ã³ã®å æ°Žå解ç©ãé µçŽ å解ç©ãçšããããšãã§ã
ãã æ¬çºæã«äœ¿çšã§ããéå å€ãšããŠã¯ç¹å ¬æ47â
20741ãå第45â11149å·ãå第49â10697å·ãå
第57â138632å·ãå第58â169143å·æ现æžã«èšèŒ
ã®ååç©ãäŸãã°ã¬ãŸã«ã·ã³é¡ãã¢ããããšããŒ
ã«é¡ãããšãã¬ã³ãžã¢ãã³é¡ãïŒâãã©ãŸãã³
é¡ãã¢ã«ãã«ããšããŒã«é¡ãã¢ã«ã³ãã·ããšããŒ
ã«é¡ãããããŒã«é¡ãã¢ããããããŒã«é¡ããã
ã¿ã¬ã³ãžãªãŒã«é¡ãã¢ã«ã³ãã·ããããŒã«é¡ãã
ãã©ãžã³é¡çãå©çšã§ããã ãããã®å ·äœäŸãšããŠã¯ã¬ãŸã«ã·ã³ãïŒâã¡ã
ã«ã¬ãŸã«ã·ã³ããªã«ã·ã³ããããã°ã«ã·ã³ããã
ãã°ã«ã·ã³ã¢ãã¡ãã«ãšãŒãã«ããããã°ã«ã·ã³
ãžã¡ãã«ãšãŒãã«ãïœâã¢ããããšããŒã«ãïœâ
ãžã¡ãã«ã¢ããããšããŒã«ãïœâãžãšãã«ã¢ãã
ããšããŒã«ãïŒïŒ®âãžã¡ãã«âïœâããšãã¬ã³
ãžã¢ãã³ãïŒïŒ®âãžãšãã«âïœâããšãã¬ã³ãž
ã¢ãã³ãïŒâã¡ãã«âïŒâãã©ãŸãã³ãïŒïŒïŒâ
ãžã¡ãã«âïŒâãã©ãŸãã³ãïŒïŒïŒâãžã¡ãã«â
ïŒâãã©ãŸãã³ãïŒâããšãã«âïŒâã¡ãã«âïŒ
âãã©ãŸãã³ãâãšãã«ããšããŒã«ãâãã
ã·ã«ããšããŒã«ãâã¡ããã·ããšããŒã«ãâ
ãã³ãžã«ãªãã·ããšããŒã«ãâããããã·ãžã
ãšãã«ãšãŒãã«ãïŒâã¡ãã«âïŒâããããŒã«ã
ïŒâã¡ãã«âïŒâããããŒã«ãïŒâã¡ãã«âïŒâ
ããããŒã«ãïŒâã¢ããâïŒâããããŒã«ãïŒâ
ã¢ããâïŒâããããŒã«ãïŒïŒïŒâãžããããã·
ããã¿ã¬ã³ãïŒâã¡ããã·âïŒâããããŒã«ã
âããªã«ããã©ãžã³å¡©é žå¡©ãâããªã«ããã©ãž
ã³å¡©é žå¡©ãã¢ã»ãããã©ãžãããã³ãºããã©ãž
ãããã«ãšã³ã¹ã«ããã«ããã©ãžã³ãïŒNâ²â
ãžã¢ã»ãã«ããã©ãžã³ãβâã¢ã·ã«ããšãã«ãã
ã©ãžã³é¡ãäŸãã°Î²âã¢ã»ãã«ããšãã«ããã©ãž
ã³ãβâã¢ã»ãã«ââããªã«ããã©ãžã³ãβâ
ã¢ã»ãã«ââã¡ããã·ããšãã«ããã©ãžã³ãβ
âã¢ã»ãã«ââã¢ããããšãã«ããã©ãžã³ãβ
âãã«ãã«ââã¢ããããšãã«ããã©ãžã³ãβ
âãã«ãã«âïŒïŒïŒâãžã¡ãã«ããšãã«ããã©ãž
ã³ãβâãã³ãŸã€ã«âïŒïŒïŒâãžã¡ããã·ããšã
ã«ããã©ãžã³ãβâãããã€ã«ââããªã«ãã
ã©ãžã³ãβâãããã€ã«ââã¢ã»ãã«ã¢ããã
ãšãã«ããã©ãžã³ãβâããããªãã«ââãžã¡
ãã«ã¢ããããšãã«ããã©ãžã³ãβâãšããã·ã«
ã«ããã«ââã¢ããããšãã«ããã©ãžã³ãβâ
ãžã¡ãã«ã«ã«ãã¢ã€ã«ââãã³ãŒã³ã¹ã«ãã³ã¢
ããããšãã«ããã©ãžã³ãβâã¢ã«ããªãã«ã«ã
ãã«ââã¢ããããšãã«ããã©ãžã³çãæãã
ããããããã®éå å€ã¯å¿ èŠã«å¿ããŠäºçš®ä»¥äžã
䜵çšããããšãã§ããããŸããäžèšã®éå å€ãšã³
ã³ãã³ã·ãšãã«åçç³»ã®çŸåè¬ãäŸãã°ãã€ãã
ããã³ãã«ãã³ãŒã«ãâ眮æã¢ããããšããŒã«
é¡ãâããšãã¬ã³ãžã¢ãã³é¡ãïŒâãã©ãŸãªã
ã³é¡çã䜵çšããããšãã§ãããéå å€ã®æ·»å é
ã¯å·Ÿåºãå€ããããšãã§ããããäžè¬ã«ã¯éå¡©ã«
察ãã0.1ã1500ã¢ã«ïŒ ã奜ãŸããã¯10ã300ã¢ã«
ïŒ ã§ãããæ¬çºæã«äœ¿çšã§ããéåæ§ååç©ãšã
ãŠã¯ãä»å éåæ§ã®ã¢ãããŒããã³ãã®ãªãªãŽã
ãŒãããªããŒãæããããšãã§ãããä»å éåæ§
ã®ã¢ãããŒãšããŠã¯ãççŽ âççŽ äžé£œåçµåãïŒ
å以äžæããååç©ãå©çšã§ããããããã®äŸãš
ããŠã¯ã¢ã¯ãªã«é žããã³ãã®å¡©ãã¢ã¯ãªã«é žãšã¹
ãã«é¡ãã¢ã¯ãªã«ã¢ããé¡ãã¡ã¿ã¯ãªã«é žããã³
ãã®å¡©ãã¡ã¿ã¯ãªã«é žãšã¹ãã«é¡ãã¡ã¿ã¯ãªã«ã¢
ããé¡ãç¡æ°Žãã¬ã€ã³é žããã¬ã€ã³é žãšã¹ãã«
é¡ãã€ã¿ã³ã³é žãšã¹ãã«é¡ãã¹ãã¬ã³é¡ãããã«
ãšãŒãã«é¡ãããã«ãšã¹ãã«é¡ãâããã«è€çŽ
ç°é¡ãã¢ãªãŒã«ãšãŒãã«é¡ãã¢ãªãŒã«ãšã¹ãã«é¡
ããã³ãããã®èªå°äœãããã ãããã®ååç©ã¯ããããæ¬çºæã«æçšã§ãã
ããæ¬çºæã§ã¯å ç±çŸååŠçãè¡ãªãããå ç±æ
ã«æ®æ£ãã«ããã沞ç¹ã80â以äžã®ãã®ã奜ãŸã
ãããŸãåŸãããè²ç»åã®ïŒ³ïŒïŒ®æ¯ãé«ãããã
ã«ãçæããé«ååååç©ã®ç²åºŠãŸãã¯ç¡¬å床ã
é«ããäœçšãæããæ¶æ©æ§ååç©ã䜵çšããããš
ãæãŸãããããã§èšãæ¶æ©æ§ååç©ãšã¯ååäž
ã«è€æ°ã®ããã«åºãŸãã¯ãããªãã³åºãæããã
ããããå€å®èœã¢ãããŒã§ããã以äžã«æ¬çºæã«
䜿çšãããéåæ§ååç©ã®å¥œãŸããäŸã瀺ãã ã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žãã¢ã¯ãªã«é žãã
ã«ãã¢ã¯ãªã«é žã¡ããã·ãšãã«ãã¡ã¿ã¯ãªã«é žã
ãã«ãã¢ã¯ãªã«ã¢ãããïŒïŒ®âãžã¡ãã«ã¢ã¯ãª
ã«ã¢ãããïŒïŒ®âãžãšãã«ã¢ã¯ãªã«ã¢ããã
âã¢ã¯ãªãã€ã«ã¢ã«ããªã³ãâã¢ã¯ãªãã€ã«ã
ããªãžã³ãã°ãªã·ãžã«ã¢ã¯ãªã¬ãŒããïŒâãšãã«
ããã·ã«ã¢ã¯ãªã¬ãŒããã¢ã¯ãªã«é žã¢ããªããã¡
ã¿ã¯ãªã«é žã¢ããªããã¹ãã¬ã³ãããã«ãã«ãš
ã³ãã¯ããã¹ãã¬ã³ãã¡ããã·ã¹ãã¬ã³ãã¯ãã
ã¡ãã«ã¹ãã¬ã³ãïŒâããã«âïŒâã¡ãã«ã€ãã
ãŸãŒã«ãïŒâããã«âïŒâãŠã³ãã·ã«ã€ãããŸãŒ
ã«ãïŒâããã«âïŒâãŠã³ãã·ã«ã€ãããŸãªã³ã
âããã«ãããªãã³ãâããã«ã«ã«ããŸãŒ
ã«ãããã«ãã³ãžã«ãšãŒãã«ãããã«ããšãã«ãš
ãŒãã«ãã¡ãã¬ã³âãã¹âã¢ã¯ãªã«ã¢ãããããª
ã¡ãã¬ã³âãã¹âã¢ã¯ãªã«ã¢ããããããµã¡ãã¬
ã³âãã¹âã¢ã¯ãªã«ã¢ãããïŒNâ²âãžã¢ã¯ãª
ãã€ã«ããã©ãžã³ãïœâããšãã¬ã³âãã¹âã¢ã¯
ãªã«ã¢ãããâããšãã¬ã³âãã¹âã¢ã¯ãªã«ã¢
ããããšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãããã
ãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒãããžãšãã¬ã³
ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒããããªãšãã¬ã³ã°ãªã³
ãŒã«ãžã¢ã¯ãªã¬ãŒãããã¹ïŒïŒâã¢ã¯ãªããã·ã
ãªãšããã·ããšãã«ïŒãããã³ãïŒïŒïŒâãã³ã¿
ã³ãžãªãŒã«ãžã¢ã¯ãªã¬ãŒããããªãã³ãã«ã°ãªã³
ãŒã«ãžã¢ã¯ãªã¬ãŒããïŒïŒïŒâãããµã³ãžãªãŒã«
ã¢ã¯ãªã¬ãŒããããªãããã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯
ãªã¬ãŒãããã³ã¿ãšãªã¹ãªããŒã«ããªã¢ã¯ãªã¬ãŒ
ããããªã¡ãããŒã«ãããã³ããªã¢ã¯ãªã¬ãŒãã
ãã³ã¿ãšãªã¹ãªããŒã«ããã©ã¢ã¯ãªã¬ãŒããâ
ã¡ãããŒã«ã¢ã¯ãªã«ã¢ããããžã¢ã»ãã³ã¢ã¯ãªã«
ã¢ãããããªãšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒ
ãããã³ã¿ãšãªã¹ãªããŒã«ããã©ã¢ãªãŒã«ãšãŒã
ã«ã ãŸããããã«åºãŸãã¯ãããªãã³åºãæããé«
ååååç©ãäŸãã°ãåŽéã«ããããã·ã«åºãã¢
ããåºããšããã·åºãããã²ã³ååãã¹ã«ããã«
ãªãã·åºãæããé«ååååç©ãšã¢ã¯ãªã«é žãã¡
ã¿ã¯ãªã«é žãããã¯ãããã®èªå°äœãšã®çž®åç©ç
ãæ¬çºæã«å©çšã§ããã ããã«ãåè¿°ã®éå å€ã®æ¯æ žã«ããã«åºããã
ãªãã³åºãçµåããååç©ãäŸãã°ãïœâïŒïŒ®
âãžïŒã¢ã¯ãªãã€ã«ãªãã·ãšãã«ïŒã¢ããããšã
ãŒã«ãâã¢ã¯ãªãã€ã«ãªãã·ãšããã·ããšããŒ
ã«çãéåæ§ååç©ãšããŠå©çšã§ãããã®å Žåã«
ã¯ãéå å€ãšéåæ§ååç©ãå Œçšããããšãã§ã
ããããã«ãè²ç»å圢æç©è³ªãäŸãã°è²çŽ ãŸãã¯
ãã€ã³è²çŽ ã®ååäžã«ããã«åºãå«æããååç©
ãéåæ§ååç©ãšããŠå©çšã§ãããã®å Žåã«ã¯é
åæ§ååç©ãšè²ç»å圢æç©è³ªãå Œããããšãã§ã
ãã æ¬çºæã®éåæ§ååç©ã¯ããã²ã³åéå¡©ïŒéé
éšã«å¯ŸããŠïŒãªãã1.2Ã105éééšã奜ãŸããã¯
12ãªãã1.2Ã104éééšçšããããšãã§ããã æ¬çºæã«å©çšã§ããè²ç»å圢æç©è³ªã«ã¯çš®ã ã®
ãã®ããããäŸãã°ãããèªèº«ãçè²ããŠããã
ã®ãšããŠææãé¡æãæãããããããããçšã
ãå Žåã«ã¯ãé«ååéåç©ãçæããŠããªãéšå
ïŒãã€ã¯ãã«ãã»ã«ïŒãç Žå£ããŠååææã«é©åœ
ãªæ¹æ³ãçšããŠè»¢åããããšã«ããè²ç»åã圢æ
ããããšãã§ãããææãé¡æã¯åžè²©ã®ãã®ã®
ä»ãåçš®æç®çïŒäŸãã°ãææ䟿芧ãææ©åæå
åŠåäŒç·šéãæå45幎åããææ°é¡æ䟿芧ãæ¥æ¬
é¡ææè¡åäŒç·šéãæå52幎åïŒã«èšèŒãããŠã
ãå ¬ç¥ã®ãã®ãå©çšã§ããããããã®ææãŸãã¯
é¡æã¯ã溶解ãªããåæ£ããŠçšããããã äžæ¹ãçè²ããŠããªãè²ç»å圢æç©è³ªãšããŠ
ã¯ãããèªèº«ã¯ç¡è²ãªããæ·¡è²ã§ãããå ç±ãå
å§ãå ç §å°çãäœããã®ãšãã«ã®ãŒã«ããçºè²ã
ããã®ãšããèªèº«ã¯ãšãã«ããŒãå ããŠãçºè²ã
ãªãããå¥ã®æåãšæ¥è§Šããããšã«ããçºè²ãã
ãã®ã«åé¡ããããåè ã®äŸãšããŠã¯ãµãŒã¢ã¯ã
ããã¯ååç©ãããšãŸã¯ãããã¯ååç©ãããã¯
ãããã¯ååç©ããã³ããªã¢ãªãŒã«ã¡ã¿ã³ææã
ããã³ç³»ææãã€ã³ãžãŽã€ãææãã¢ãžã³ææç
ã®ãã€ã³äœãªã©ãç¥ãããŠããããããã¯ããã
ãå ç±ãå å§ãå ç §å°ãããã¯ç©ºæ°é žåã«ããçº
è²ãããã®ã§ãããåŸè ã®äŸãšããŠã¯ïŒçš®ä»¥äžã®
æåã®éã®é žå¡©åºåå¿ãé žåéå åå¿ãã«ãããª
ã³ã°åå¿ããã¬ãŒã圢æåå¿çã«ããçºè²ãã
çš®ã ã®ã·ã¹ãã ãå å«ããããäŸãã°ãæå§çŽç
ã«å©çšãããŠããã©ã¯ãã³ãã©ã¯ã¿ã ãã¹ããã
ã©ã³çã®éšåæ§é ãæããçºè²å€ãšé žæ§çœåãã
ãšããŒã«é¡çã®é žæ§ç©è³ªïŒé¡è²å€ïŒãããªãçºè²
ã·ã¹ãã ïŒè³éŠæãžã¢ãŸããŠã å¡©ããžã¢ãŸã¿ãŒ
ãããžã¢ãŸã¹ã«ãããŒãé¡ãšããããŒã«é¡ãã¢ã
ãªã³é¡ã掻æ§ã¡ãã¬ã³é¡çã®ã¢ãŸã«ãããªã³ã°å
å¿ãå©çšããã·ã¹ãã ïŒãããµã¡ãã¬ã³ããã©ã
ã³ãšç¬¬ïŒéã€ãªã³ããã³æ²¡é£åé žãšã®åå¿ãããš
ããŒã«ãã¿ã¬ã€ã³âã³ã³ãã¬ã¯ãœã³é¡ãšã¢ã«ã«ãª
åé¡éå±ã€ãªã³ãšã®åå¿ãªã©ã®ãã¬ãŒã圢æå
å¿ïŒã¹ãã¢ãªã³é žç¬¬ïŒéãšããã¬ããŒã«ãšã®åå¿
ãããã³é žéãšïŒâã¡ããã·âïŒâããããŒã«ã®
åå¿ãªã©ã®é žåéå åå¿ãªã©ãå©çšã§ããã ãŸããåããïŒæåã®éã®åå¿ã«ããçºè²ãã
ã·ã¹ãã ã®ä»ã®äŸãšããŠããã®åå¿ãå ç±ã«ãã
é²è¡ããå Žåãç¥ãããŠããããã®å Žåã«ã¯å å§
æã®ãã€ã¯ãã«ãã»ã«ç Žå£ã«ãã€ãŠïŒæåãæ··å
ããããšåææãã¯å å§ã®çŽåŸã«å ç±ããããšã
å¿ èŠã§ããã çºè²å€ïŒé¡è²å€ã·ã¹ãã ã«ãããçºè²å€ãšããŠ
ã¯ã(1)ããªã¢ãªãŒã«ã¡ã¿ã³ç³»ã(2)ãžããšãã«ã¡ã¿
ã³ç³»ã(3)ããµã³ãã³ç³»ã(4)ãã¢ãžã³ç³»ã(5)ã¹ãã
ãã©ã³ç³»ååç©ãªã©ããããå ·äœçãªäŸãšããŠ
ã¯ãç¹éæ55â27253å·çã«èšèŒãããŠãããã®
çãããããããäžã§ã(1)ããªã¢ãªãŒã«ã¡ã¿ã³
ç³»ã(3)ããµã³ãã³ç³»ã®çºè²å€ã¯ã«ããªãå°ãªãã
é«ãçºè²æ¿åºŠãäžãããã®ãå€ã奜ãŸãããå ·äœ
äŸãšããŠã¯ãã¯ãªã¹ã¿ã«ãã€ãªã¬ããã©ã¯ãã³ã
ïŒâãžãšãã«ã¢ããâïŒâã¯ããâïŒâïŒÎ²âãš
ããã·ãšãã«ã¢ããïŒãã«ãªã©ã³ãïŒâãžãšãã«
ã¢ããâïŒâã¡ãã«âïŒâã¢ããªããã«ãªã©ã³ã
ïŒâããªãšãã«ã¢ããâïŒâã¡ãã«âïŒâã¢ããª
ããã«ãªã©ã³ãïŒâã·ã¯ãããã·ã«ã¡ãã«ã¢ãã
âïŒâã¡ãã«âïŒâã¢ããªããã«ãªã©ã³ãïŒâãž
ãšãã«ã¢ããâïŒâïœâã¯ããã¢ããªããã«ãªã©
ã³çãããããããã¯åç¬ãããã¯æ··åããŠçšã
ãããã é¡è²å€ãšããŠã¯ãããšããŒã«ç³»ååç©ãææ©é ž
ãããã¯ãã®éå±å¡©ããªãã·å®æ¯éŠé žãšã¹ãã«ã
é žæ§çœåãªã©ãçšããããã ããšããŒã«ååç©ã®äŸã瀺ãã°ãïŒïŒ4â²âã€ãœ
ããããªãã³âãžããšããŒã«ïŒãã¹ããšããŒã«
ïŒãïœâtertâããã«ããšããŒã«ãïŒïŒïŒâãž
ãããããšããŒã«ãïŒïŒïŒâãžã¯ããããšããŒ
ã«ãïŒïŒ4â²âã¡ãã¬ã³âãã¹ïŒïŒïŒïŒâãžãŒtert
âããã«ããšããŒã«ïŒãïœâããšãã«ããšããŒã«ã
ïŒïŒïŒâãã¹ïŒïŒâããããã·ããšãã«ïŒã·ã¯ã
ãããµã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·ããšã
ã«ïŒâïŒâãšãã«ãããµã³ãïŒïŒïŒâãã¹ïŒïŒâ
ããããã·ããšãã«ïŒãã¿ã³ãïŒïŒ2â²âã¡ãã¬ã³
ãã¹ïŒïŒâtertâããã«ããšããŒã«ïŒãïŒïŒ2â²âã¡
ãã¬ã³ãã¹ïŒÎ±âããšãã«âïœâã¯ã¬ãŸãŒã«ïŒã
ãªãžããšããŒã«ãïŒïŒ4â²âããªãã¹ïŒïŒâtertâ
ããã«âïœâã¯ã¬ãŸãŒã«ïŒã¹ã«ããã«ãžããšããŒ
ã«ã®ã»ããïœâtertâããã«ããšããŒã«âãã«ã
ãªã³çž®åç©ãïœâããšãã«ããšããŒã«ãã«ããªã³
çž®åç©ãªã©ãããã ææ©é žãããã¯ãã®éå±å¡©ãšããŠã¯ããã¿ã«
é žãç¡æ°Žãã¿ã«é žããã¬ã€ã³é žãå®æ¯éŠé žã没é£
åé žãïœâãã«ã€ã«é žãïœâãã«ã€ã«é žããµãªã
ã«é žãïŒâtertâããã«ãµãªãã«é žãïŒïŒïŒâãž
âtertâããã«ãµãªãã«é žãïŒâαâã¡ãã«ãã³
ãžã«ãµãªãã«é žãïŒïŒïŒâïŒÎ±âã¡ãã«ãã³ãžã«ïŒ
ãµãªãã«é žãïŒâtertâãªã¯ãã«ãµãªãã«é žãã
ã³ãã®äºéãéãã¢ã«ãããŠã å¡©ããã°ãã·ãŠã
å¡©ãããã±ã«å¡©çãæçšã§ãããç¹ã«ãµãªãã«é ž
èªå°äœããã³ãã®äºéå¡©ããŸãã¯ã¢ã«ãããŠã å¡©
ã¯ãé¡è²èœãçºè²åã®å ç¢æ§ãèšé²ã·ãŒãã®ä¿å
æ§ãªã©ã®ç¹ã§ããããŠããã ãªãã·å®æ¯éŠé žãšã¹ãã«ãšããŠã¯ãïœâãªãã·
å®æ¯éŠé žãšãã«ãïœâãªãã·å®æ¯éŠé žããã«ãïœ
âãªãã·å®æ¯éŠé žãžããã«ãïœâãªãã·å®æ¯éŠé ž
ãã³ãžã«çãããã åãåžæ²¹æ§ã®çœè²é¡æã䜵çšããŠãã«ãã»ã«å
å ç©ã®æ¡æ£ãšåºå®åãã¯ããããšãã§ããã ãããã®é¡è²å€ã¯åžæãã枩床ã§è解ããçºè²
åå¿ãçããããããã«ãäœèç¹ã®ç±å¯èæ§ç©è³ª
ãšã®å ±èç©ãšããŠæ·»å ãããããŸãã¯äœèç¹åå
ç©ãé¡è²å€ç²åã®è¡šé¢ã«èçããŠããç¶æ ã§æ·»å
ããäºã奜ãŸããã äœèç¹ååç©ã®å ·äœçäŸãšããŠã¯ãé«çŽèèªé ž
ã¢ãããäŸãã°ã¹ãã¢ãªã³é žã¢ããããšã«ã«é žã¢
ããããã«ããã³é žã¢ããããšãã¬ã³ãã¹ã¹ãã¢
ãã¢ãããããã¯é«çŽèèªé žãšã¹ãã«çã®ã¯ãã¯
ã¹é¡ããããã¯å®æ¯éŠé žããšãã«èªå°äœãè³éŠæ
ãšãŒãã«èªå°äœããããã¯å°¿çŽ èªå°äœããããã
ããã«éå®ããããã®ã§ã¯ãªãã å¥ãªçºè²å€ïŒé¡è²å€ã·ã¹ãã ã®çºè²å€ãšããŠ
ã¯ãäŸãã°ããšããŒã«ãã¿ã¬ã€ã³ããã«ãªã¬ãã»
ã€ã³ã2â²ïŒ4â²ïŒ5â²ïŒ7â²âããã©ããã¢âïŒïŒïŒïŒ
ïŒïŒïŒâããã©ã¯ãããã«ãªã¬ãã»ã€ã³ãããã©
ããã¢ããšããŒã«ãã«ãŒãïŒïŒïŒïŒïŒïŒïŒâãã
ã©ããã¢ããšããŒã«ãã¿ã¬ã€ã³ããšãªã·ã³ãã¢ãŠ
ãªã³ã¯ã¬ãŸãŒã«ã¬ãããïŒâããããŒã«ããšããŒ
ã«ãã¿ã¬ã€ã³ãªã©ãããã é¡è²å€ãšããŠã¯ãç¡æ©ããã³ææ©ã¢ã³ã¢ããŠã
å¡©ãææ©ã¢ãã³ãã¢ãããå°¿çŽ ãããªå°¿çŽ ããã³
ãã®èªå°äœããã¢ãŸãŒã«é¡ããããŒã«é¡ãããªã
ãžã³é¡ãããã©ãžã³é¡ãã°ã¢ããžã³é¡ãã€ã³ããŒ
ã«é¡ãã€ãããŸãŒã«é¡ãã€ãããŸãªã³é¡ãããªã¢
ãŸãŒã«é¡ãã¢ã«ããªã³é¡ããããªãžã³é¡ãã¢ããž
ã³é¡ãããªã«ã ã¢ãžã³é¡ãããªãžã³é¡çã®å«çªçŽ
ååç©ãæããããããããã®å ·äœäŸãšããŠã¯ã
äŸãã°é ¢é žã¢ã³ã¢ããŠã ãããªã·ã¯ãããã·ã«ã¢
ãã³ãããªãã³ãžã«ã¢ãã³ããªã¯ã¿ãã·ã«ãã³ãž
ã«ã¢ãã³ãã¹ãã¢ãªã«ã¢ãã³ãã¢ãªã«å°¿çŽ ãããª
å°¿çŽ ãã¡ãã«ããªå°¿çŽ ãã¢ãªã«ããªå°¿çŽ ããšãã¬
ã³ããªå°¿çŽ ãïŒâãã³ãžã«ã€ãããŸãŒã«ãïŒâã
ãšãã«ã€ãããŸãŒã«ãïŒâããšãã«âïŒâã¡ãã«
âã€ãããŸãŒã«ãïŒâãŠã³ãã·ã«âã€ãããŸãª
ã³ãïŒïŒïŒïŒïŒâããªããªã«âïŒâã€ãããŸãª
ã³ãïŒïŒïŒâãžããšãã«âïŒïŒïŒâãžã¡ãã«âïŒ
âã€ãããŸãªã³ãïŒâããšãã«âïŒâã€ãããŸãª
ã³ãïŒïŒïŒïŒïŒâããªããšãã«ã°ã¢ããžã³ãïŒïŒ
ïŒâãžããªã«ã°ã¢ããžã³ãïŒïŒïŒâãžã·ã¯ããã
ã·ã«ã°ã¢ããžã³ãïŒïŒïŒâãžã·ã¯ãããã·ã«âïŒ
âããšãã«ã°ã¢ããžã³ãïŒïŒïŒïŒïŒâããªã·ã¯ã
ããã·ã«ã°ã¢ããžã³ãã°ã¢ããžã³ããªã¯ããé ¢é ž
å¡©ãïŒNâ²âãžãã³ãžã«ããã©ãžã³ãïŒïŒ4â²âãž
ããªã¢ã«ããªã³ãã¢ã«ããªããŠã ããªã¯ããé ¢é ž
å¡©ãïŒâã¢ããâãã³ãŸãã¢ãŸãŒã«ãïŒâãã³ãŸ
ã€ã«ããã©ãžãâãã³ãŸãã¢ãŸãŒã«ãããã æ¬çºæã®è²ç»å圢æç©è³ªã¯ãéåæ§ååç©100
éééšã«å¯ŸããŠ0.5ã20éééšãç¹ã«å¥œãŸããã¯
ïŒãïŒéééšã®å²åã§çšãããããé¡è²å€ã¯çºè²
å€ïŒéééšã«å¯ŸããŠçŽ0.3ã80éééšã®å²åã§çš
ããããã ãŸããç±éåé²æ¢å€ããã€ã¯ãã«ãã»ã«ã«å å
ããŠä¿åæ§ãæ¹è¯ããããšãã§ãããç±éåé²æ¢
å€ã®æ·»å éã¯éåæ§ååç©ã«å¯ŸããŠã0.1ã10ã¢
ã«ïŒ ã®å²åã奜ãŸããã æ¬çºæã«çšãããã€ã¯ãã«ãã»ã«ã¯åœæ¥çå ¬ç¥
ã®æ¹æ³ã§ã€ããããšãã§ãããäŸãã°ç±³åœç¹èš±ç¬¬
2800457å·ãå第2800458å·ã«ã¿ããããããªèŠªæ°Ž
æ§å£åœ¢æææã®ã³ã¢ã»ã«ããŒã·ãšã³ãå©çšããæ¹
æ³ãç±³åœç¹èš±ç¬¬3287154å·ãè±åœç¹èš±ç¬¬990443å·ã
ç¹å ¬æ38â19574å·ãå42â446å·ãå42â771å·
ã«ã¿ããããããªçé¢éåæ³ãç±³åœç¹èš±ç¬¬
3418250å·ãå第3660304å·ã«ã¿ãããããªããŒã®
æåºã«ããæ¹æ³ãç±³åœç¹èš±ç¬¬3796669å·ã«ã¿ãã
ãã€ãœã·ã¢ããŒãâããªãªãŒã«å£ææãçšããæ¹
æ³ãç±³åœç¹èš±ç¬¬3914511å·ã«ã¿ãããã€ãœã·ã¢ã
ãŒãå£ææãçšããæ¹æ³ãç±³åœç¹èš±ç¬¬4001140å·ã
å第4087376å·ãå第4089802å·ã«ã¿ãããå°¿çŽ â
ãã«ã ã¢ã«ãããç³»ãããã¯å°¿çŽ ãã«ã ã¢ã«ãã
ãâã¬ãŸã«ã·ããŒã«ç³»å£åœ¢æææãçšããæ¹æ³ã
ç±³åœç¹èš±ç¬¬4025455å·ã«ã¿ãããã¡ã©ãã³âãã«
ã ã¢ã«ãããæš¹èãããããã·ãããã«ã»ã«ããŒ
ã¹çã®å£åœ¢æææãçšããæ¹æ³ãç¹å ¬æ36â9168
å·ãç¹éæ51â9079å·ã«ã¿ãããã¢ãããŒã®éå
ã«ããinsituæ³ãè±åœç¹èš±ç¬¬952807å·ãå第
965074å·ã«ã¿ãããé»è§£åæ£å·åŽæ³ãç±³åœç¹èš±ç¬¬
3111407å·ãç±³åœç¹èš±ç¬¬930422å·ã«ã¿ãããã¹ã
ã¬ãŒãã©ã€ã³ã°æ³ãªã©ãããããããã«éå®ãã
ããã®ã§ã¯ãªãããè¯ç©è³ªãä¹³åããåŸãã€ã¯ã
ã«ãã»ã«å£ãšããŠé«ååèã圢æããããšã奜ãŸ
ããã æ¬çºæã®ãã€ã¯ãã«ãã»ã«å£ã®äœãæ¹ãšããŠã¯
ç¹ã«æ²¹æ»Žå éšããã®ãªã¢ã¯ã¿ã³ãã®éåã«ããã
ã€ã¯ãã«ãã»ã«åæ³ã䜿çšããå Žåããã®å¹æã
倧ãããå³ã¡ãçæéå ã«ãåäžãªç²åŸããã¡ã
çä¿åæ§ã«ããããæå ææãšããŠå¥œãŸããã«ã
ã»ã«ãåŸãããšãã§ããã äŸãã°ããªãŠã¬ã¿ã³ãã«ãã»ã«å£æãšããŠçšã
ãå Žåã«ã¯å€äŸ¡ã€ãœã·ã¢ããŒãããã³ãããšåå¿
ãã«ãã»ã«å£ã圢æãã第ïŒã®ç©è³ªïŒããšãã°ã
ãªãªãŒã«ãããªã¢ãã³ïŒãã«ãã»ã«åãã¹ãæ²¹æ§
液äœäžã«æ··åãæ°Žäžã«ä¹³ååæ£ã次ã«æž©åºŠãäžæ
ããããšã«ããã油滎çé¢ã§é«åå圢æåå¿ãèµ·
ããŠããã€ã¯ãã«ãã»ã«å£ã圢æããããã®ãšã
æ²¹æ§æ¶²äœäžã«äœæ²žç¹ã®æº¶è§£åã®åŒ·ãè£å©æº¶å€ãçš
ããããšãã§ããã ãã®å Žåã«ãçšããå€äŸ¡ã€ãœã·ã¢ããŒãããã³
ãããšåå¿ããçžæã®ããªãªãŒã«ãããªã¢ãã³ã«
ã€ããŠã¯ç±³åœç¹èš±ç¬¬3281383å·ãå第3773695å·ã
å第3793268å·ãç¹å ¬æ48â40347å·ãå49â
24159å·ãç¹éæ48â80191å·ãå48â84086å·ã«
é瀺ãããŠããããããã䜿çšããããšãã§ã
ãã å€äŸ¡ã€ãœã·ã¢ããŒããšããŠã¯ãäŸãã°ãïœâã
ãšãã¬ã³ãžã€ãœã·ã¢ããŒããïœâããšãã¬ã³ãžã€
ãœã·ã¢ããŒããïŒïŒïŒâããªã¬ã³ãžã€ãœã·ã¢ããŒ
ããïŒïŒïŒâããªã¬ã³ãžã€ãœã·ã¢ããŒããããã¿
ã¬ã³âïŒïŒïŒâãžã€ãœã·ã¢ããŒãããžããšãã«ã¡
ã¿ã³âïŒïŒ4â²âãžã€ãœã·ã¢ããŒããïŒïŒ3â²âãžã¡
ããã·âïŒïŒ4â²âãããšãã«âãžã€ãœã·ã¢ããŒ
ããïŒïŒ3â²âãžã¡ãã«ãžããšãã«ã¡ã¿ã³âïŒïŒ
4â²âãžã€ãœã·ã¢ããŒãããã·ãªã¬ã³âïŒïŒïŒâãž
ã€ãœã·ã¢ããŒããïŒïŒ4â²âãžããšãã«ãããã³ãž
ã€ãœã·ã¢ããŒããããªã¡ãã¬ã³ãžã€ãœã·ã¢ããŒ
ãããããµã¡ãã¬ã³ãžã€ãœã·ã¢ããŒãããããã¬
ã³âïŒïŒïŒâãžã€ãœã·ã¢ããŒããããã¬ã³âïŒïŒ
ïŒâãžã€ãœã·ã¢ããŒããã·ã¯ãããã·ã¬ã³âïŒïŒ
ïŒâãžã€ãœã·ã¢ããŒããã·ã¯ãããã·ã¬ã³âïŒïŒ
ïŒâãžã€ãœã·ã¢ããŒãçã®ãžã€ãœã·ã¢ããŒãã
ïŒïŒ4â²ïŒ4â³âããªããšãã«ã¡ã¿ã³ããªã€ãœã·ã¢ã
ãŒãããã«ãšã³âïŒïŒïŒïŒïŒâããªã€ãœã·ã¢ããŒ
ãã®ãããªããªã€ãœã·ã¢ããŒããïŒïŒ4â²âãžã¡ã
ã«ãžããšãã«ã¡ã¿ã³âïŒïŒ2â²ïŒïŒïŒ5â²âããã©ã€
ãœã·ã¢ããŒãã®ãããªããã©ã€ãœã·ã¢ããŒããã
ããµã¡ãã¬ã³ãžã€ãœã·ã¢ããŒããšããªã¡ãããŒã«
ãããã³ã®ä»å ç©ãïŒïŒïŒâããªã¬ã³ãžã€ãœã·ã¢
ããŒããšããªã¡ãããŒã«ãããã³ã®ä»å ç©ããã·
ãªã¬ã³ãžã€ãœã·ã¢ããŒããšããªã¡ãããŒã«ããã
ã³ã®ä»å ç©ãããªã¬ã³ãžã€ãœã·ã¢ããŒããšãããµ
ã³ããªãªãŒã«ã®ä»å ç©ã®ãããªã€ãœã·ã¢ããŒãã
ã¬ããªããŒãããã ããªãªãŒã«ãšããŠã¯ãèèªæãè³éŠæã®å€äŸ¡ã¢
ã«ã³ãŒã«ãããããã·ããªãšã¹ãã«ãããããã·
ããªã¢ã«ãã¬ã³ãšãŒãã«ã®ãããªãã®ãããã ç¹é¡æ58â158469å·æ现æžã«èšèŒãããäžèšã®
ããªãªãŒã«ãçšããããã ãšãã¬ã³ã°ãªã³ãŒã«ãïŒïŒïŒâãããã³ãžãªãŒ
ã«ãïŒïŒïŒâãã¿ã³ãžãªãŒã«ãïŒïŒïŒâãã³ã¿ã³
ãžãªãŒã«ãïŒïŒïŒâãããµã³ãžãªãŒã«ãïŒïŒïŒâ
ããã¿ã³ãžãªãŒã«ãïŒïŒïŒâãªã¯ã¿ã³ãžãªãŒã«ã
ãããã¬ã³ã°ãªã³ãŒã«ãïŒïŒïŒâãžããããã·ã
ã¿ã³ãïŒïŒïŒâãžããããã·ãã¿ã³ãïŒïŒïŒâãž
ããããã·ãã¿ã³ãïŒïŒïŒâãžã¡ãã«âïŒïŒïŒâ
ãããã³ãžãªãŒã«ãïŒïŒïŒâãã³ã¿ã³ãžãªãŒã«ã
ïŒïŒïŒâãããµã³ãžãªãŒã«ãïŒâã¡ãã«âïŒïŒïŒ
âãã³ã¿ã³ãžãªãŒã«ãïŒïŒïŒâã·ã¯ããããµã³ãž
ã¡ã¿ããŒã«ããžããããã·ã·ã¯ããããµã³ããžãš
ãã¬ã³ã°ãªã³ãŒã«ãïŒïŒïŒïŒïŒâããªããããã·
ãããµã³ãïŒâããšãã«ãããã¬ã³ã°ãªã³ãŒã«ã
ïŒïŒïŒïŒïŒâããªã¡ãããŒã«ãããã³ããããµã³
ããªãªãŒã«ããã³ã¿ãšãªã¹ãªããŒã«ããã³ã¯ãšãª
ã¹ãªããŒã«ãšãã¬ã³ãªããµã€ãä»å ç©ãã°ãªã»ãª
ã³ãšãã¬ã³ãªããµã€ãä»å ç©ãã°ãªã»ãªã³ïŒïŒïŒ
âãžïŒïŒâããããã·ãšããã·ïŒãã³ã»ã³ãã¬ãŸ
ã«ã·ããŒã«ãžããããã·ãšãã«ãšãŒãã«çã®è³éŠ
æå€äŸ¡ã¢ã«ã³ãŒã«ãšã¢ã«ãã¬ã³ãªããµã€ããšã®çž®
åçæç©ãïœâãã·ãªã¬ã³ã°ãªã³ãŒã«ãïœâãã·
ãªã¬ã³ã°ãªã³ãŒã«ãαïŒÎ±â²âãžããããã·âïœâ
ãžã€ãœãããã«ãã³ãŒã³ãïŒïŒ4â²âãžããããã·
âãžããšãã«ã¡ã¿ã³ãïŒâïŒïœïŒpâ²âãžãããã
ã·ããšãã«ã¡ãã«ïŒãã³ãžã«ã¢ã«ã³ãŒã«ããã¹ã
ãšããŒã«ïŒ¡ã«ãšãã¬ã³ãªããµã€ãã®ä»å ç©ããã¹
ããšããŒã«ïŒ¡ã«ãããã¬ã³ãªããµã€ãã®ä»å ç©ãª
ã©ãããããããããªãªãŒã«ã¯ã€ãœã·ã¢ããŒãåº
ïŒã¢ã«ã«å¯ŸããŠãæ°Žé žåºã®å²åã0.02ãïŒã¢ã«ã§
䜿çšããã®ã奜ãŸããã ããªã¢ãã³ãšããŠã¯ãšãã¬ã³ãžã¢ãã³ãããªã¡
ãã¬ã³ãžã¢ãã³ãããã©ã¡ãã¬ã³ãžã¢ãã³ããã³
ã¿ã¡ãã¬ã³ãžã¢ãã³ããããµã¡ãã¬ã³ãžã¢ãã³ã
ïœâããšãã¬ã³ãžã¢ãã³ãïœâããšãã¬ã³ãžã¢ã
ã³ãããã©ãžã³ãïŒâã¡ãã«ããã©ãžã³ãïŒïŒïŒ
âãžã¡ãã«ããã©ãžã³ãïŒâããããã·ããªã¡ã
ã¬ã³ãžã¢ãã³ããžãšãã¬ã³ããªã¢ãã³ãããªãšã
ã¬ã³ããªã¢ãã³ãããªãšãã¬ã³ããã©ãã³ããžãš
ãã«ã¢ãããããã«ã¢ãã³ãããã©ãšãã«ãã³ã¿
ãã³ããšããã·ååç©ã®ã¢ãã³ã®ä»å ç©çããã
ãããã å€äŸ¡ã€ãœã·ã¢ããŒãã¯æ°Žãšåå¿ããŠé«ååç©è³ª
ã圢æããããšãã§ããã ãã€ã¯ãã«ãã»ã«ãäœããšãã«ã氎溶æ§é«åå
ãçšããããšãã§ãããã氎溶æ§é«ååã¯æ°Žæº¶æ§
ã®ã¢ããªã³æ§é«ååããããªã³æ§é«ååãäž¡æ§é«
ååã®ãããã§ãè¯ããã¢ããªã³æ§é«ååãšããŠ
ã¯ã倩ç¶ã®ãã®ã§ãåæã®ãã®ã§ãçšããããšã
ã§ããäŸãã°âCOO-ãâSO3 -åºçãæãããã®
ãæããããã å ·äœçãªã¢ããªã³æ§ã®å€©ç¶é«ååãšããŠã¯ã¢ã©
ãã€ãŽã ãã¢ã«ã®ã³é žãªã©ããããååæåãšã
ãŠã¯ã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹ããã¿ã«åãŒã©
ãã³ãç¡«é žåãã³ãã³ãç¡«é žåã»ã«ããŒã¹ããªã°
ãã³ã¹ã«ãã³é žãªã©ãããã ãŸãåæåãšããŠã¯ç¡æ°Žãã¬ã€ã³é žç³»ïŒå æ°Žå
解ãããã®ãå«ãïŒå ±éåäœãã¢ã¯ãªã«é žç³»ïŒã¡
ã¿ã¯ãªã«é žç³»ãå«ãïŒéåäœããã³å ±éåäœãã
ãã«ãã³ãŒã³ã¹ã«ãã³é žç³»éåäœããã³å ±éå
äœãã«ã«ããã·å€æ§ããªããã«ã¢ã«ã³ãŒã«ãªã©ã
ããããããªã³æ§é«ååãšããŠã¯ãããªããã«ã¢
ã«ã³ãŒã«ãããããã·ãšãã«ã»ã«ããŒã¹ããšãã«
ã»ã«ããŒã¹çãããã äž¡æ§ã®ååç©ãšããŠã¯ãŒã©ãã³çãããã ãããã®æ°Žæº¶æ§é«ååã¯0.01ã10wtïŒ ã®æ°Žæº¶æ¶²
ãšããŠçšããããã ãã®ãããªãã€ã¯ãã«ãã»ã«äžã«ã¯ãå°ãªããš
ãéåæ§ååç©ããã³è²ç»å圢æç©è³ªãå°å ¥ãã
ãããã®å Žåãéåžžã¯ãããã²ã³åéãéå å€ç
ããã®ã«ãã»ã«äžã«å°å ¥ããããããã®å Žåã«
ã¯ããŸãè²ç»å圢æç©è³ªã溶解ããéåæ§ååç©
äžã«ããã²ã³åéããã³éå å€ãåæ£ãŸãã¯æº¶è§£
ãããã®ãæ²¹çžãšãããããšèŠªæ°Žæ§é«ååååç©
ã溶解ããæ°Žçžãšãæ··åããŠä¹³å€åæ£ãããšãã«
ãžãšã³ãäœãããã®ä¹³ååæ£ãšåæãŸãã¯åŒç¶ã
ãŠãšãã«ãžãšã³ç²åã®æ²¹ïŒæ°Žçé¢ã«åšç¥ã®æ¹æ³ã§
å£ã圢æãããããšãã§ããããã€ã¯ãã«ãã»ã«
ã®äœãæ¹ãšããŠã¯ããã«éãããçš®ã ã®æ¹æ³ãé©
çšããããšãã§ããã æ¬çºæã«çšããã«ãã»ã«ã®å€§ããã¯80Ό以äžã§
ãããç¹ã«ä¿åæ§ãåãæ±ãæ§ã®ç¹ãã20Ό以äž
ã奜ãŸããããŸãã«ãã»ã«ãå°ããããå Žåã«ã¯
åºè³ªã®åãŸãã¯ç¹ç¶äžã«æ¶å€±ããæãããããã
ããã¯åºè³ªãŸãã¯æ¯æäœã®æ§è³ªã«äŸåããã®ã§äž
æŠã«ã¯ãããªããã0.1Ό以äžã奜ãŸããã æ¬çºæã«çšããã«ãã»ã«ã¯å§åçŽ10KgïŒcm2以äž
ã§ã¯å®è³ªçã«å€åããªããããã«ãã倧ããªå§å
ãå ããããæã«ã¯ç Žå£ãèµ·ããããšã奜ãŸã
ãããã®ç Žå£ã®èµ·ããå§åã®å€§ããã¯ãçšéã«å¿
ããŠå€ããããšãã§ãããã®ã§ããç¹å®ã®æ°å€ã«
éå®ããããã®ã§ã¯ãªãããçŽ500KgïŒcm2çšåºŠä»¥
äžã®å§åã§ç Žå£ããããšã奜ãŸãããã«ãã»ã«ã®
ç²åŸãã«ãã»ã«å£ã®åããçšããå£å€ã®çš®é¡ã«ã
ãããããã®å§åç¹æ§ãå¶åŸ¡ããããšãã§ããã æ¬çºæã®æå ææã«ã¯ãç±åå¿æ§ãå€ãããã
ã«ç¹é¡æ60â25838å·æ现æžã«èšèŒãããããã
ã·ååç©ãã«ã«ããã³é žãšã¹ãã«ååç©ãè³éŠæ
ã¡ããã·ååç©ãææ©ã¹ã«ãã³ã¢ããååç©ãã
ã€ã¯ãã«ãã»ã«ãŸãã¯ãã€ã¯ãã«ãã»ã«ã®å€ã«çš
ããããšãã§ããããããã®ååç©ã¯ãã€ã¯ãã«
ãã»ã«å£ã®ã¬ã©ã¹è»¢ç§»ç¹ãå€ãããã®ãšæãã
ãã æ¬çºæã«ã¯çš®ã ã®ç»å圢æä¿é²å€ãçšããããš
ãã§ãããç»å圢æä¿é²å€ã«ã¯éå¡©é žåå€ãšéå
å€ãšã®é žåéå åå¿ã®ä¿é²ãæå ææå±€ããåå
å±€ãžã®ç»å圢æç©è³ªã®ç§»åã®ä¿é²çã®æ©èœãã
ããç©çååŠçãªæ©èœããã¯å¡©åºãŸãã¯å¡©åºãã¬
ã«ãŒãµãŒããªã€ã«ãç±æº¶å€ãçé¢æŽ»æ§å€ãéãŸã
ã¯éã€ãªã³çžäºäœçšãæã€ååç©çã«åé¡ãã
ãããã ãããããã®ç©è³ªçŸ€ã¯äžè¬ã«è€åæ©èœã
æããŠãããäžèšã®ä¿é²å¹æã®ããã€ããåãã
æã€ã®ãåžžã§ããã 以äžã«ãããã®ç»å圢æä¿é²å€ãæ©èœå¥ã«åé¡
ããŠãããããã®å ·äœäŸã瀺ããããã®åé¡ã¯äŸ¿
å®çãªãã®ã§ãããå®éã«ã¯ïŒã€ã®ååç©ãè€æ°
ã®æ©èœãå ŒåããŠããããšãå€ãã 奜ãŸããå¡©åºã®äŸãšããŠã¯ãç¡æ©ã®å¡©åºãšããŠ
ã¢ã«ã«ãªéå±ãŸãã¯ã¢ã«ã«ãªåé¡éå±ã®æ°Žé žå
ç©ã第ïŒãŸãã¯ç¬¬ïŒãªã³é žå¡©ãããŠé žå¡©ãçé ž
å¡©ããããªã³é žå¡©ãã¡ã¿ããŠé žå¡©ïŒã¢ã³ã¢ããŠã
æ°Žé žåç©ïŒïŒçŽã¢ã«ãã«ã¢ã³ã¢ããŠã ã®æ°Žé žå
ç©ïŒãã®ä»ã®éå±ã®æ°Žé žåç©çãæããããææ©
ã®å¡©åºãšããŠã¯èèªæã¢ãã³é¡ïŒããªã¢ã«ãã«ã¢
ãã³é¡ãããããã·ã«ã¢ãã³é¡ãèèªæããªã¢ã
ã³é¡ïŒïŒè³éŠæã¢ãã³é¡ïŒïŒ®âã¢ã«ãã«çœ®æè³éŠ
æã¢ãã³é¡ãâããããã·ã«ã¢ã«ãã«çœ®æè³éŠ
æã¢ãã³é¡ããã³ãã¹ãïœâïŒãžã¢ã«ãã«ã¢ããïŒ
ããšãã«ãã¡ã¿ã³é¡ïŒãè€çŽ ç°ç¶ã¢ãã³é¡ãã¢ã
ãžã³é¡ãç°ç¶ã¢ããžã³é¡ãã°ã¢ããžã³é¡ãç°ç¶ã°
ã¢ããžã³é¡ãæããããç¹ã«pKaãïŒä»¥äžã®ãã®
ã奜ãŸããã å¡©åºãã¬ã«ãŒãµãŒãšããŠã¯ãå ç±ã«ããè±çé ž
ããææ©é žãšå¡©åºã®å¡©ãååå æ±æ žçœ®æåå¿ãã
ãã»ã³è»¢ç§»ãããã¯ãã³è»¢ç§»çã®åå¿ã«ããã¢ã
ã³é¡ãæŸåºããååç©ãªã©ãå ç±ã«ããäœããã®
åå¿ãèµ·ãããŠå¡©åºãæŸåºãããã®ããã³é»è§£ãª
ã©ã«ããå¡©åºãçºçãããååç©ã奜ãŸããçšã
ããããåè ã®å ç±ã«ããå¡©åºãçºçããã¿ã€ã
ã®å¥œãŸããå¡©åºãã¬ã«ãŒãµãŒãšããŠã¯è±åœç¹èš±ç¬¬
998949å·çã«èšèŒã®ããªã¯ããé ¢é žã®å¡©ãç±³åœç¹
蚱第4060420å·ã«èšèŒã®Î±âã¹ã«ããã«é ¢é žã®å¡©ã
ç¹éæ59â180537å·èšèŒã®ããããªãŒã«é žé¡ã®
å¡©ãç±³åœç¹èš±ç¬¬4088496å·ã«èšèŒã®ïŒâã«ã«ãã
ã·ã«ã«ãããµããèªå°äœãå¡©åºæåã«ææ©å¡©åºã®
ä»ã«ã¢ã«ã«ãªéå±ãã¢ã«ã«ãªåé¡éå±ãçšããç±
å解æ§é žãšã®å¡©ïŒç¹éæ59â195237å·ïŒãããã»
ã³è»¢äœãå©çšããç¹éæ59â168440å·ã«èšèŒã®ã
ããããµã ã«ã«ãã¡ãŒãé¡ãå ç±ã«ãããããªã«
ãçæããç¹é¡æ58â31614å·ã«èšèŒã®ã¢ã«ãã
ã·ã ã«ã«ãã¡ãŒãé¡ãªã©ãæããããããã®ä»ã
è±åœç¹èš±ç¬¬998945å·ãç±³åœç¹èš±ç¬¬3220846å·ãç¹
éæ50â22625å·ãè±åœç¹èš±ç¬¬2079480å·çã«èšèŒ
ã®å¡©åºãã¬ã«ãŒãµãŒãæçšã§ããã é»è§£ã«ããå¡©åºãçºçãããååç©ãšããŠæ¬¡ã®
ãã®ãæããããšãã§ããã äŸãã°ãé»è§£é žåãçšããæ¹æ³ã®ä»£è¡šãšããŠå
çš®èèªé žå¡©ã®é»è§£ãæããããšãã§ããããã®å
å¿ã«ãã€ãŠã¢ã«ã«ãªéå±ãã°ã¢ããžã³é¡ãã¢ããž
ã³é¡çã®ææ©å¡©åºã«çé žå¡©ã極ããŠå¹çè¯ãåŸã
ããšãã§ããã ãŸãé»è§£éå ãçšããæ¹æ³ãšããŠã¯ããããã
ãã³ããããœååç©ã®éå ã«ããã¢ãã³é¡ã®ç
æïŒãããªã«é¡ã®éå ã«ããã¢ãã³é¡ã®çæïŒã
ããååç©ãã¢ãŸååç©ãã¢ãŸãã·ååç©çã®é
å ã«ããïœâã¢ããããšããŒã«é¡ãïœâããšãã¬
ã³ãžã¢ãã³é¡ãããã©ãžã³é¡ã®çæçãæããã
ãšãã§ãããïœâã¢ããããšããŒã«é¡ãïœâããš
ãã¬ã³ãžã¢ãã³é¡ãããã©ãžã³é¡ã¯å¡©åºãšããŠçš
ããã ãã§ãªããããããçŽæ¥è²ç»å圢æç©è³ªãš
ããŠäœ¿çšããããšãã§ããããŸããçš®ã ã®ç¡æ©å¡©
å ±åäžã§ã®æ°Žã®é»è§£ã«ããã¢ã«ã«ãªæåãçæã
ããããšããã¡ããå©çšã§ããããŸãããããã®
å¡©åºãããã¯å¡©åºãã¬ã«ãŒãµãŒã¯æå å±€ã®ç·åºåœ¢
åéã®50ééïŒ ä»¥äžã奜ãŸãããæŽã«å¥œãŸããã¯
0.01ã40ééïŒ ã奜ãŸããã ãªã€ã«ãšããŠã¯çæ°Žæ§ååç©ã®ä¹³ååæ£æã«æº¶
åªãšããŠçšããããé«æ²žç¹ææ©æº¶åªãçšããããš
ãã§ããã ç±æº¶å€ãšããŠã¯éåžžã®æž©åºŠã§ã¯åºäœã§ãããçŸ
å枩床è¿åã§æº¶èããŠæº¶åªãšããŠåããã®ã§ãå°¿
çŽ é¡ããŠã¬ã¿ã³é¡ãã¢ããé¡ãããªãžã³é¡ãã¹ã«
ãã³ã¢ããé¡ãã¹ã«ãã³ãã¹ã«ããã·ãé¡ããšã¹
ãã«é¡ãã±ãã³é¡ããšãŒãã«é¡ã®ååç©ã§40â以
äžã§åºäœã®ãã®ãçšããããšãã§ããããŸããç±
溶å€ã¯ãæå å±€ã®ç·åºåœ¢åéã®0.1ã50ééïŒ ã
奜ãŸãããæŽã«å¥œãŸããã¯ïŒã20ééïŒ ã§ããã çé¢æŽ»æ§å€ãšããŠã¯ç¹éæ59â74547å·èšèŒã®
ããªãžããŠã å¡©é¡ãã¢ã³ã¢ããŠã å¡©é¡ããã¹ãã
ãŠã å¡©é¡ãç¹éæ59â57231å·èšèŒã®ããªã¢ã«ã
ã¬ã³ãªãã·ãé¡ãæããããšãã§ããã éãŸãã¯éã€ãªã³ãšçžäºäœçšããã€ååç©ãšã
ãŠã¯ãã€ããé¡ãç¹éæ59â177550å·èšèŒã®å«çª
çŽ ãããç°é¡ãç¹éæ59â111636å·èšèŒã®ããªãŒ
ã«é¡ãããªå°¿çŽ é¡ãããªãšãŒãã«é¡ãæããããš
ãã§ããã ç»å圢æä¿é²å€ã¯æå ææãååææã®ããã
ã«å èµãããŠããããäž¡æ¹ã«å èµãããŠãããã
ãŸãå èµãããå±€ãä¹³å€å±€ãäžéå±€ãä¿è·å±€ãå
åå±€ãããã³ãããã«é£æ¥ãããããã®å±€ã«ãå
èµãããŠãããæå å±€ãšååå±€ãšãåäžæ¯æäœäž
ã«æãã圢æ ã«ãããŠãåæ§ã§ããã ç»å圢æä¿é²å€ã¯åç¬ã§ãããŸãæ°çš®ã䜵çšã
ãŠäœ¿çšããããšãã§ããããäžè¬ã«ã¯æ°çš®ã䜵çš
ããæ¹ããã倧ããªä¿é²å¹æãåŸãããã ç¹ã«å¡©åºãŸãã¯å¡©åºãã¬ã«ãŒãµãŒãšä»ã®ä¿é²å€
ã䜵çšãããšé¡èãªä¿é²å¹æãçºçŸãããã æ¬çºæã«ãããŠã¯ãç±çŸåæã®åŠç枩床ããã³
åŠçæéã®å€åã«å¯Ÿããåžžã«äžå®ã®ç»åãåŸãç®
çã§çš®ã ã®çŸååæ¢å€ãçšããããšãã§ããã ããã§ããçŸååæ¢å€ãšã¯ãé©æ£çŸååŸãéã
ãã«å¡©åºãäžåãŸãã¯å¡©åºãšåå¿ããŠèäžã®å¡©åº
æ¿åºŠãäžãçŸåãåæ¢ããååç©ãŸãã¯éããã³
éå¡©ãšçžäºäœçšããŠçŸåãæå¶ããååç©ã§ã
ããå ·äœçã«ã¯ãå ç±ã«ããé žãæŸåºããé žãã¬
ã«ãŒãµãå ç±ã«ããå ±åããå¡©åºãšçœ®æåå¿ãèµ·
ãã芪é»åååç©ããŸãã¯å«çªçŽ ãããç°åå
ç©ãã¡ã«ã«ããååç©çãæãããããé žãã¬ã«
ãŒãµãŒã«ã¯äŸãã°ç¹é¡æ58â216928å·ããã³ç¹é¡
æ59â48305å·ã«èšèŒã®ãªãã·ã ãšã¹ãã«é¡ãç¹
é¡æ59â85834å·èšèŒã®ããã»ã³è»¢äœã«ããé žã
æŸåºããååç©çãæããããå ç±ã«ããå¡©åºãš
眮æåå¿ãèµ·ãã芪é»åååç©ã«ã¯äŸãã°ãç¹é¡
æ59â85836å·ã«èšèŒã®ååç©ãªã©ãæããããã æ¬çºæã®ååèŠçŽ ã¯æå èŠçŽ ããæŸåºãããè²
ç»å圢æç©è³ªãåºå®ããããã®èŠçŽ ã§ãããæå
èŠçŽ ãšåäžã®æ¯æäœäžã«å¡èšããããæãã¯æå
èŠçŽ ãæããæå ææãšã¯å¥ã®æ¯æäœäžã«å¡èšã
ãŠååææãæ§æããã ããã«æ¬çºæã®ååèŠçŽ ã¯å¿ èŠã«å¿ããŠãåªæ
å€ãå«ãå±€ãå°ãªããšãïŒå±€æããããšãã§ã
ããååèŠçŽ ãè¡šé¢ã«äœçœ®ããå Žåããã«ä¿è·å±€
ãèšããããšãã§ããããŸããå¿ èŠã«å¿ããŠåªæ
åã®ç°ãªãåªæå€ãçšããŠïŒå±€ä»¥äžã§æ§æãããŠ
ãããã ååå±€ãšããŠåªæå€ãçšããå Žåã¯ãæ¡æ£è»¢å
åæå ææã«äœ¿çšãããåªæå€ã®äžããä»»æã«éž
ã¶ããšãã§ãããããããã®äžã§ãç¹ã«ããªããŒ
åªæå€ã奜ãŸãããããã§ããªããŒåªæå€ãšã¯ã
äžçŽã¢ããåºãå«ãããªããŒãå«çªçŽ è€çŽ ç°éšå
ãæããããªããŒãããã³ãããã®ïŒçŽã«ããªã³
åºãå«ãããªããŒçã§ããã äžçŽã¢ããåºãæããããã«ã¢ãããŒåäœãå«
ãããªããŒã«ã€ããŠã¯ãç¹é¡æ58â169012å·ãç¹
é¡æ58â166135å·çã«èšèŒãããŠãããäžçŽã€ã
ããŸãŒã«åºãæããããã«ã¢ãããŒåäœãå«ãã
ãªããŒã®å ·äœäŸãšããŠã¯ç¹é¡æ58â226497å·ãå
58â232071å·ãç±³åœç¹èš±ç¬¬4282305å·ãå第
4115124å·ãå第3148061å·ãªã©ã«èšèŒãããŠã
ãã åçŽã€ãããŸãªãŠã å¡©ãæããããã«ã¢ãããŒ
åäœãå«ãããªããŒã®å¥œãŸããå ·äœäŸãšããŠã¯è±
åœç¹èš±ç¬¬2056101å·ãå第2093041å·ãå第
1594961å·ãç±³åœç¹èš±ç¬¬4124386å·ãå第4115124
å·ãå第4273853å·ãå第4450224å·ãç¹éæ48â
28225å·çã«èšèŒãããŠããã ãã®ä»åçŽã¢ã³ã¢ããŠã å¡©ãæããããã«ã¢ã
ããŒåäœãå«ãããªããŒã®å¥œãŸããå ·äœäŸãšããŠ
ã¯ãç±³åœç¹èš±ç¬¬3709690å·ãå第3898088å·ãå第
3958995å·ãç¹é¡æ58â166135å·ãå58â169012
å·ãå58â232070å·ãå58â232072å·ããã³å59
â91620å·ãªã©ã«èšèŒãããŠããã æ¬çºæã«ãããŠã¯ãéåæ§ååç©ãè²ç»å圢æ
ç©è³ªã®ã«ãã»ã«åã«éããŠæº¶åªã䜵çšããããšã
ã§ããããŸãéå å€ãé¡è²å€çãå¿ èŠãªèŠçŽ äžã«
å°å ¥ããå Žåã«ã溶åªãçšããããšãã§ãããäŸ
ãã°æ°ŽãŸãã¯èŠªæ°Žæ§ææ©æº¶åªã«æº¶ããã溶液ãå¿
èŠã«å¿ããŠãã€ã³ããŒãšãšãã«çŽæ¥æ¯æäœäžã«å¡
èšããããšãã§ããããç±³åœç¹èš±ç¬¬2322027å·èš
èŒã®æ¹æ³ãªã©ã®å ¬ç¥ã®æ¹æ³ã«ããå¿ èŠãªèŠçŽ äžã«
å°å ¥ããããšãã§ããããã€ã¯ãã«ãã»ã«äžã«æº¶
åªã䜵çšããããšã«ããå å§ã®éã®ã«ãã»ã«ã®ç Ž
å£ã®çšåºŠããã³ã«ãã»ã«å ã®è²ç»å圢æç©è³ªã®å
åèŠçŽ ãžã®ç§»åéãã³ã³ãããŒã«ããããšãã§ã
ããã«ãã»ã«å ã«äœµçšãã溶åªã®éã¯éåæ§åå
ç©100éééšã«å¯ŸããŠïŒã500éééšã®å²åã奜ãŸ
ããã æ¬çºæã«ãããŠçšãããã溶åªãšããŠå€©ç¶æ²¹ãŸ
ãã¯åææ²¹ãåç¬ãŸãã¯äœµçšããããšãã§ããã
ããã溶åªã®äŸãšããŠäŸãã°ç¶¿å®æ²¹ãç¯æ²¹ãèèª
æã±ãã³ãèèªæãšã¹ãã«ããã©ãã€ã³ãããã
ã³æ²¹ãã¢ã«ãã«åãããšãã«ãã¢ã«ãã«åã¿ãŒã
ãšãã«ãå¡©çŽ åãã©ãã€ã³ãã¢ã«ãã«åããã¿ã¬
ã³ãããã³ïŒâããšãã«âïŒâãã·ãªã«ãšã¿ã³ã
ïŒâããšãã«âïŒâïœâãšãã«ããšãã«ãšã¿ã³ã
ïŒïŒ1â²âãžããªã«ãšã¿ã³çã®ãããªãžã¢ãªãŒã«ãš
ã¿ã³ããã¿ãŒã«é žã¢ã«ãã«ãšã¹ãã«ïŒãžããã«ã
ã¿ã¬ãŒãããžãªã¯ãã«ãã¿ã¬ãŒããªã©ïŒããªã³é ž
ãšã¹ãã«ïŒãžããšãã«ãã¹ããšãŒããããªããšã
ã«ãã¹ããšãŒããããªã¯ã¬ãžã«ãã¹ããšãŒãããž
ãªã¯ãã«ããã«ãã¹ããšãŒãïŒãã¯ãšã³é žãšã¹ã
ã«ïŒäŸãã°ã¢ã»ãã«ã¯ãšã³é žããªããã«ïŒãå®æ¯
éŠé žãšã¹ãã«ïŒå®æ¯éŠé žãªã¯ãã«ïŒãã¢ã«ãã«ã¢
ããïŒäŸãã°ãžãšãã«ã©ãŠãªã«ã¢ããïŒãèèªé ž
ãšã¹ãã«é¡ïŒäŸãã°ãžãããã·ãšãã«ãµã¯ã·ããŒ
ãããžãªã¯ãã«ã¢ãŒã¬ãŒãïŒãããªã¡ã·ã³é žãšã¹
ãã«é¡ïŒäŸãã°ããªã¡ã·ã³é žããªããã«ïŒé ¢é žãš
ãã«ãé ¢é žããã«ã®ãããªäœçŽã¢ã«ãã«ã¢ã»ããŒ
ããããããªã³é žãšãã«ãäºçŽããã«ã¢ã«ã³ãŒ
ã«ãã¡ãã«ã€ãœããã«ã±ãã³ãβâãšããã·ãšã
ã«ã¢ã»ããŒããã¡ãã«ã»ããœã«ãã¢ã»ããŒããã·
ã¯ããããµãã³ãªã©ãããã æ¬çºæã®æå ææããã³ååææã«çšãããã
ãã€ã³ããŒã¯ãåç¬ã§ãããã¯çµã¿åãããŠå«æ
ããããšãã§ããããã®ãã€ã³ããŒã«ã¯äž»ã«èŠªæ°Ž
æ§ã®ãã®ãçšããããšãã§ããã芪氎æ§ãã€ã³ã
ãŒãšããŠã¯ãéæãåéæã®èŠªæ°Žæ§ãã€ã³ããŒã
代衚çã§ãããäŸãã°ãŒã©ãã³ããŒã©ãã³èªå°
äœãã»ã«ããŒã¹èªå°äœçã®ã¿ã³ãã¯è³ªãããã³ã
ã³ãã¢ã©ãã€ãŽã çã®å€ç³é¡ã®ãããªå€©ç¶ç©è³ª
ãšãããªããã«ãããªãã³ãã¢ã¯ãªã«ã¢ããéå
äœçã®æ°Žæº¶æ§ã®ããªããã«ååç©ã®ãããªåæé
åç©è³ªãå«ããä»ã®åæéåç©è³ªã¯ãã©ããã¯ã¹
ã®åœ¢ã§ããšãã«åçææã®å¯žåºŠå®å®æ§ãå¢å ãã
ãåæ£ç¶ããã«ååç©ãããã æ¬çºæã«æŒããæå ææããã³ååææã«äœ¿çš
ãããæ¯æäœã¯ãåŠç枩床ã«èããããšã®ã§ãã
ãã®ã§ãããäžè¬çãªæ¯æäœãšããŠã¯ãã¬ã©ã¹ã
çŽãäžè³ªçŽãåæçŽãéå±ããã³ãã®é¡äŒŒäœãçš
ããããã°ããã§ãªããã¢ã»ãã«ã»ã«ããŒã¹ãã€
ã«ã ãã»ã«ããŒã¹ãšã¹ãã«ãã€ã«ã ãããªããã«
ã¢ã»ã¿ãŒã«ãã€ã«ã ãããªã¹ãã¬ã³ãã€ã«ã ãã
ãªã«ãŒãããŒããã€ã«ã ãããªãšãã¬ã³ãã¬ãã¿
ã¬ãŒããã€ã«ã ããã³ãããã«é¢é£ãããã€ã«ã
ãŸãã¯æš¹èææãå«ãŸããããŸãããªãšãã¬ã³ç
ã®ããªããŒã«ãã€ãŠã©ãããŒããããçŽæ¯æäœã
çšããããšãã§ãããç±³åœç¹èš±ç¬¬3634089å·ãå
第3725070å·èšèŒã®ããªãšã¹ãã«ãã€ã«ã ã¯å¥œãŸ
ããçšããããã æ¬çºæã®æå ææã¯å¿ èŠã«å¿ããŠä¿è·å±€ãäžé
å±€ã垯é»é²æ¢å±€ãã«ãŒã«é²æ¢å±€ãã¯ããå±€ããã
ãå€å±€ãªã©ã®è£å©å±€ãèšããããšãã§ãããç¹ã«
ä¿è·å±€ã¯æ¥çé²æ¢ã®ç®çã§ææ©ãç¡æ©ã®ãããå€
ãå«ãŸããã®ãæãŸããã ãŸããæå ææãååææã«ã¯å¿ èŠã«å¿ããŠã«
ããªé²æ¢å€ãããå å¢çœå€ãéè²é²æ¢å€ããã¬ãŒ
ã·ãšã³ãã€ã©ãžãšãŒã·ãšã³é²æ¢ææãé¡æïŒé žå
ãã¿ã³ãªã©ã®çœè²é¡æãå«ãïŒãæ°ŽæŸåºå€ãç±é
åé²æ¢å€ãçé¢æŽ»æ§å€ãç±æº¶å€åæ£ç¶ããã«åå
ç©çãå«ãã§ããŠãããã æ¬çºæã«ãããŠã¯çš®ã ã®é²å æ段ãçšããããš
ãã§ãããæœåã¯ãå¯èŠå ãå«ã茻å°ç·ã®ç»åç¶
é²å ã«ãã€ãŠåŸããããäžè¬ã«ã¯ãé垞䜿ããã
å æºãäŸãã°å€ªéœå ãã¹ãããããã©ãã·ãŠãã¿
ã³ã°ã¹ãã³ã©ã³ããæ°Žéç¯ããšãŒãã©ã³ããªã©ã®
ããã²ã³ã©ã³ãããã»ãã³ã©ã³ããã¬ãŒã¶ãŒå
ç·ãããã³CRTå æºããã©ãºãå æºãèå 管ã
çºå ãã€ãªãŒããªã©ãå æºãšããŠäœ¿ãããšãã§ã
ãããŸããLCDïŒæ¶²æ¶ïŒãPLZTïŒã©ã³ã¿ã³ãããŒ
ããããã¿ã³ãžã«ã³ããŠã é žéïŒãªã©ãå©çšãã
ãã€ã¯ãã·ã€ãã¿ãŒã¢ã¬ã€ãšç·ç¶å æºãããã¯å¹³
é¢ç¶å æºãçµåããé²å æ段ãçšããããšãã§ã
ãã å æºã®çš®é¡ãé²å éã¯ããã²ã³åéã®è²çŽ å¢æ
ã«ããæå æ³¢é·ããæ床ã«å¿ããŠéžæããããšã
ã§ããã æ¬çºæã«ãããŠçšããåç»ã¯çœé»ç»åã§ãã«ã©
ãŒç»åã§ãããã åç»ãšããŠã¯ã補å³ãªã©ã®ç·ç»åã¯ãã¡ããã®
ããšãé調ãæããåçç»åã§ãããããŸãã«ã¡
ã©ãçšããŠäººç©åã颚æ¯åãæ®åœ±ããããšãå¯èœ
ã§ãããåç»ããã®çŒä»ã¯ãåç»ãšéããŠå¯ççŒ
ä»ãããŠããåå°çŒä»ãããŠããããŸãåŒäŒžãçŒ
ä»ãããŠãããã ãŸããããªã«ã¡ã©ãªã©ã«ããæ®åœ±ãããç»åã
ãã¬ãå±ããéãããŠããç»åæ å ±ããçŽæ¥
CRTãFOTã«åºãããã®åãå¯çãã¬ã³ãºã«ã
ãæå ææäžã«çµåãããŠãçŒä»ãããšãå¯èœã§
ããã ãŸãæè¿å€§å·Ÿãªé²æ©ãèŠãããLEDïŒçºå ãã€
ãªãŒãïŒã¯ãåçš®ã®æ©åšã«ãããŠãé²å æ段ãšã
ãŠãŸãã¯è¡šç€ºæ段ãšããŠçšãããã€ã€ããããã®
LEDã¯ãéå ãæå¹ã«åºããã®ãäœãããšãå°
é£ã§ããããã®å Žåãã«ã©ãŒç»åãåçããã«
ã¯ãLEDãšããŠç·å ãèµ€å ãèµ€å€å ãçºããïŒ
çš®ã䜿ãããããã®å ã«æå ããä¹³å€éšåã
åã ãã€ãšããŒãããŒã³ã¿ãã·ã¢ã³ã®ç»å圢æç©
質ãå«ãããã«èšèšããã°ããã ããªãã¡ç·æå éšãã€ãšããŒç»å圢æç©è³ªãå«
ã¿ãèµ€æå éšãããŒã³ã¿ç»å圢æç©è³ªããèµ€å€æ
å éšãã·ã¢ã³ç»å圢æç©è³ªãå«ãããã«ããŠãã
ã°ããããã以å€ã®å¿ èŠã«å¿ããŠç°ãªã€ãçµåã
ãå¯èœã§ããã äžèšã®åå³ãçŽæ¥ã«å¯çãŸãã¯æ圱ããæ¹æ³ä»¥
å€ã«ãå æºã«ããç §å°ãããåå³ãå é»ç®¡ã
CCDãªã©ã®åå çŽ åã«ãããèªã¿ãšãã³ã³ããŠ
ãŒã¿ãŒãªã©ã®ã¡ã¢ãªãŒã«å ¥ãããã®æ å ±ãå¿ èŠã«
å¿ããŠå å·¥ããããããç»ååŠçãã»ã©ããã
åŸããã®ç»åæ å ±ãCRTã«åçããããããç»
åå æºãšããŠå©çšããããåŠçãããæ å ±ã«ããš
ã¥ããŠãçŽæ¥ïŒçš®LEDãçºå ãããŠé²å ããæ¹
æ³ãããã ãããã®é²å éã¯ãçšããããã²ã³åéã®çš®é¡
ããå¢æçšåºŠã«ãã€ãŠå€ãã€ãŠããã æ¬çºæã«ãããŠåæ§é²å åŸã®å ç±æ¹æ³ãšããŠã¯
åŸæ¥å ¬ç¥ã®æ¹æ³ãçšããããšãã§ãããäŸãã°ã
ããããã¬ãŒããªã©ã®ç±æ¿ãããã¯ãã©ã ã«æå
ææãçŽæ¥è§ŠããããããããŒãããŒã©ãŒãçšã
ãŠæ¬éããããããããšãã§ããã ãŸãé«æž©ã«å ç±ãã空æ°ãçšãããé«åšæ³¢å ç±
ãã¬ãŒã¶ãŒããŒã ã«ããå ç±ããããšãã§ããã
æå ææã«ãã€ãŠã¯èµ€å€ç·ããŒã¿ãŒãçšããŠå ç±
ããããšãã§ãããããã«é»ç£èªå°ã«ããçºçã
ã枊é»æµãå©çšããŠå ç±ããæ¹æ³ãå¿çšããããš
ãã§ããã ãŸããæå ææã«å¯ŸããŠäžæŽ»æ§ã®æ¶²äœãããšã
ã°ããçŽ ç³»ã®æ¶²äœãå ç±ãããã¹äžã§æå ææã
å ç±ããŠãè¯ãã ããã«ãäžèšã®å ç±æ段ãšã¯å¥ã«å ç±æºãæå
ææã«ããããããšã§å ç±ããŠããããããšã
ã°ãã«ãŒãã³ãã©ãã¯ãã°ã©ãã¢ã€ããªã©ã®å°é»
æ§ç²åã®å±€ãæå ææäžã«ããããéé»ããæã«
çºçãããžãŠãŒã«ç±ãå©çšããŠãããããã®éã®
å ç±æž©åºŠã¯äžè¬ã«80âã200âã奜ãŸããã¯100â
ã160âã§ããã æå ææãå ç±ãããã¿ãŒã³ãšããŠã¯ãçš®ã ã®
ãã¿ãŒã³ãå¿çšã§ãããäžå®æž©åºŠã§å ç±ããæ¹æ³
ãæãäžè¬çã§ããããæå ææã®ç¹æ§ã«ãã€ãŠ
ã¯å€æ®µéå ç±âããšãã°é«æž©çæéå ç±ã®åŸåŸã
ã«æž©åºŠãäœäžãããæ¹æ³âãæå¹ã§ããããã®å Ž
åã®å ç±æéã¯äžè¬ã«ïŒç§ãïŒåã奜ãŸããã¯ïŒ
ç§ããïŒåã§ããã å ç±ã«éããŠæå ææã空æ°é žåã®åœ±é¿ããã
ãããå Žåã«ã¯å ç±éšåšèŸºã®è±æ°ãŸãã¯äžæŽ»æ§ã¬
ã¹ãžã®çœ®æãæå¹ã§ããããŸãæå ææã®è¡šé¢ã
å ç±éšåãžçŽæ¥æ¥è§ŠãããŠããããã空æ°ã«ãã
ããŠããããæå ææè¡šé¢ã空æ°åŽã«ããŠçŸåã
ãå Žåã«ã¯æå ææäžããã®æ°Žåãæ®çºæåã®èž
çºãé²ãã ããä¿æž©ã®ç®çã§ã«ããŒããšãã€ãã
ã®ãæå¹ã§ããã çºæã®å ·äœçäœçšå¹æ æ¬çºæã«ããã°ãæ¯æäœäžã«å°ãªããšãæå æ§
ããã²ã³åéä¹³å€ãéå å€ãéåæ§ååç©ããã³
è²ç»å圢æç©è³ªãæãããã€ãããã®äžã®å°ãªã
ãšãéåæ§ååç©ãšè²ç»å圢æç©è³ªãšãåäžã®ã
ã€ã¯ãã«ãã»ã«ã«å°å ¥ãããç¶æ ã§å«æãããŠã
ããåæ§é²å ã«ããæœåã圢æããããã²ã³åé
ä¹³å€ãå¢æè²çŽ ã®ååšäžã§åœ¢æãããããã²ã³å
éç²åãå«ããããé«æ床ã§ãã€çµæå®å®æ§ã«åª
ããæå ææãåŸããããç¹ã«ãã®å¹æã¯ç·è²å
ããã³èµ€è²å ã«å¯ŸããŠé¡èã§ããã çºæã®å ·äœçå®æœäŸ 以äžãæ¬çºæã®å ·äœçå®æœäŸã瀺ããæ¬çºæã®
å¹æãããã«è©³çŽ°ã«èª¬æããã å®æœäŸ ïŒ ïŒ»æå æ§ããã²ã³åéä¹³å€ã®èª¿è£œïŒœ ä¹³å€(A)ã®èª¿è£œæ³ è¯ãæ¹æããŠãããŒã©ãã³æ°Žæº¶æ¶²ïŒæ°Ž1000mlã®
äžã«ãŒã©ãã³20ïœãšå¡©åãããªãŠã ïŒïœãšã溶解
ãããŠ75âã«ä¿æž©ãããã®ïŒã«èåã«ãªãŠã ãšå¡©
åãããªãŠã ãšãå«ãïŒåãããŠ0.59ã¢ã«ïŒæ°Žæº¶
液600mlãš0.59ã¢ã«ã®ç¡é žéãå«ã氎溶液600mlãš
ãåæã«çæµéã§40åãããŠæ·»å ããAgBr80ã¢
ã«ïŒ ã§ãµã€ãºã0.5ÎŒã®ç«æ¹äœååæ£å¡©èåéç²å
ãäœã€ãããã®ä¹³å€ãæ°ŽæŽãè±å¡©åŸããŒã©ãã³ïŒ
ïœãšæ°Ž200mlãå ããŠãPHã調ç¯ããããªç¡«é žã
ããªãŠã ãšå¡©åéé žããã³ãïŒâããããã·âïŒ
âã¡ãã«âïŒïŒïŒïŒ3aïŒïŒâããã©ã¶ã€ã³ãã³
ãçšããŠæé©ã®ååŠå¢æãè¡ã€ããä¹³å€ã®åéã¯
700ïœã§ãããããããŠåŸãããä¹³å€ã(A)ãšããã ä¹³å€(B)ã®èª¿è£œæ³ è¯ãæ¹æããŠãããŒã©ãã³æ°Žæº¶æ¶²ïŒæ°Ž1000mläž
ã«ãŒã©ãã³20ïœãšå¡©åãããªãŠã ïŒïœãšã溶解ã
ããŠ60âã«ä¿æž©ãããã®ïŒã«èåã«ãªãŠã ãšå¡©å
ãããªãŠã ãšãå«ãïŒåããŠ0.59ã¢ã«ïŒæ°Žæº¶æ¶²
600mlãš0.59ã¢ã«ã®ç¡é žéãå«ã氎溶液600mlãšã
åæã«çæµéã§25åãããŠæ·»å ããBr80ã¢ã«ïŒ
ã§ãµã€ãºã0.25ÎŒã®ç«æ¹äœååæ£å¡©èåéç²åã
äœã€ãããã®éããã²ã³åéç²å圢æéå§ãšåæ
ã«è²çŽ 0.16ïœãã¡ã¿ããŒã«400c.c.ã«æº¶è§£ãã液
ã15åãããŠãŒã©ãã³æ°Žæº¶æ¶²äžã«æ·»å ãããæ°Ž
æŽãè±å¡©åŸãŒã©ãã³ïŒïœãšæ°Ž200mlãå ããŠPHã
調ç¯ãããªç¡«é žãããªãŠã ãšå¡©åéé žãšïŒâãã
ããã·âïŒâã¡ãã«âïŒïŒïŒïŒ3aïŒïŒâããã©
ã¶ã€ã³ãã³ãçšããŠæé©ã®ååŠå¢æãè¡ã€ããä¹³
å€ã®åéã¯700ïœã§ããããã®æ§ã«ããŠåŸããã
ä¹³å€ã(B)ãšããã è²çŽ ä¹³å€(C)ã®èª¿è£œæ³ è¯ãæ¹æããŠãããŒã©ãã³æ°Žæº¶æ¶²ïŒæ°Ž1000mläž
ã«ãŒã©ãã³20ïœãšå¡©åãããªãŠã 10ïœãšã溶解ã
ããŠ75âã«ä¿æž©ãããã®ïŒã«èåã«ãªãŠã ãšå¡©å
ãããªãŠã ãšãå«ãïŒåããŠ0.59ã¢ã«ïŒæ°Žæº¶æ¶²
600mlãš0.59ã¢ã«ã®ç¡é žéãå«ã氎溶液600mlãšã
60åãããŠæ·»å ãBr55ã¢ã«ïŒ ã§å¹³åç²åãµã€ãº
ã0.65ÎŒã®ç«æ¹äœå¡©èåéç²åãäœã€ãããã®é
ç²å圢æéå§ïŒååã«è²çŽ 0.16ïœãã¡ã¿ããŒã«
160c.c.ã«æº¶è§£ããè²çŽ 溶液ããŒã©ãã³æ°Žæº¶æ¶²ã«æ·»
å ãããæ°ŽæŽãè±å¡©åŸãŒã©ãã³ïŒïœãšæ°Ž200mlã
å ããŠPHã調ç¯ããããªç¡«é žãããªãŠã ãšæ žé žå
解ç©ãçšããŠæé©ã®ååŠå¢æãè¡ã€ãã ä¹³å€ã®åéã¯700ïœã§ãããããããŠåŸããã
ä¹³å€ã(C)ãšããã è²çŽ ä¹³å€(D)ã®èª¿è£œæ³ åèšä¹³å€(B)ã®äœãæ¹ã«ãããŠããã®éçšããè²
çŽ ãããã²ã³åéç²å圢æäžã«ã¯æ·»å ããã代
ãã«åéã®è²çŽ ãååŠå¢æçµäºåŸãçŽã¡ã«æ·»å
ããä»ã¯ä¹³å€(B)ãšåæ§ã«ããŠèª¿è£œãããã®ãä¹³å€
(D)ãšããã ä¹³å€(E)ã®èª¿è£œæ³ åèšä¹³å€(C)ã®äœãæ¹ã«ãããŠããã®éçšããè²
çŽ ããŒã©ãã³æ°Žæº¶æ¶²ã«ã¯æ·»å ããã代ãã«åé
ã®è²çŽ ãååŠå¢æçµäºåŸçŽã¡ã«æ·»å ããä»ã¯ä¹³
å€(C)ãšåæ§ã«ããŠèª¿è£œãããã®ãä¹³å€(E)ãšããã ä¹³å€(D)ã®èª¿è£œæ³ åèšä¹³å€(B)ã®äœãæ¹ã«ãããŠããã®éçšããè²
çŽ ãããã²ã³åéç²å圢æäžã«ã¯æ·»å ããã代
ãã«åéã®è²çŽ ãååŠå¢æçµäºåŸãçŽã¡ã«æ·»å
ããä»ã¯ä¹³å€(B)ãšåæ§ã«ããŠèª¿è£œãããã®ãä¹³å€
(D)ãšããã ä¹³å€(E)ã®èª¿è£œæ³ åèšä¹³å€(C)ã®äœãæ¹ã«ãããŠããã®éçšããè²
çŽ ããŒã©ãã³æ°Žæº¶æ¶²ã«ã¯æ·»å ããã代ãã«åé
ã®è²çŽ ãååŠå¢æçµäºåŸçŽã¡ã«æ·»å ããä»ã¯ä¹³
å€(C)ãšåæ§ã«ããŠèª¿è£œãããã®ãä¹³å€(E)ãšããã ä¹³å€(F)ã®èª¿è£œæ³ æ°Ž600mlãå«ãããŒã«ãŒäžã«ããŒã©ãã³20ïœã
èåã«ãªãŠã 1.2ïœããã³25ïŒ ã¢ã³ã¢ãã¢æ°ŽïŒc.c.
ãå ¥ãæ¹æ溶解ãããããã®æº¶æ¶²ã50âã«ä¿ã¡ãª
ããç¡é žé100ïœãæ°Ž600mlã«æº¶è§£ããã液ããã³
èåã«ãªãŠã 116ïœãæ²åã«ãªãŠã ïŒïœãæ°Ž100ml
ã«æº¶è§£ããã液ãã³ã³ãããŒã«ãããã«ãžãšãã
æ³ã§æ¶²ã®pAgã8.9ã«ä¿ã¡ãªãã50åéã§æ·»å ã
ãããã®ãšãããã²ã³æº¶æ¶²ãšç¡é žé溶液ã®æ·»å é
å§ãšåæã«è²çŽ 0.15ïœãã¡ã¿ããŒã«75mlã«æº¶è§£
ããã液ã®æ·»å ãã¯ããã25åéã§å šéãæ·»å ã
ãã è²çŽ æ°ŽæŽãè±å¡©åŸãŒã©ãã³ïŒïœãšæ°Ž100mlãå ããŠ
PHã調補ããèåã«ãªãŠã ãå ããŠãpAgã0.3
ãšããã次ã«ããªç¡«é žãããªãŠã ãçšããŠæé©ã®
ååŠå¢æãè¡ããç²åãµã€ãº0.5ÎŒmããžã€ã¬ã€ã¢
圢ã§ãåé700ïœã®ãã³ã¯ãå¢ææ²èåéä¹³å€(F)
ãåŸãã ä¹³å€(G)ã®èª¿è£œæ³ æ°Ž600mlãå«ãããŒã«ãŒäžã«ããŒã©ãã³20ïœã
èåã«ãªãŠã 1.2ïœããã³ HOïŒâCH2ïŒâ2SïŒâCH2ïŒâ2SïŒâCH2ïŒâ2OH 0.5ïœãå ¥ãæ¹æ溶解ãããããã®æº¶æ¶²ã60âã«
ä¿ã¡ãä¹³å€(F)ã§çšããè²çŽ 0.15ïœãã¡ã¿ããŒã«
75mlã«æº¶è§£ããã液ãããã³è²çŽ 0.05ïœãã¡ã¿
ããŒã«125c.c.ã«æº¶è§£ããã液ãæ·»å ããã次ã«ç¡
é žé100ïœãæ°Ž600mlã«æº¶è§£ããã液ããã³èåã«
ãªãŠã 64ïœãæ²åã«ãªãŠã 10ïœãæ°Ž600mlã«æº¶è§£
ããã液ã50åéã§æ·»å ããã æ°ŽæŽãè±å¡©åŸãŒã©ãã³ïŒïœãšæ°Ž100mlãå ããŠ
PHã調補ããèåã«ãªãŠã ãå ããŠãpAgã8.5
ãšããã次ã«ããªç¡«é žãããªãŠã ãšïŒâãããã
ã·âïŒâã¡ãã«âïŒïŒïŒïŒ3aïŒïŒâããã©ã¶ã€
ã³ãã³ãçšããŠæé©ã®ååŠå¢æãè¡ããç²åãµã€
ãº0.3ÎŒããžã€ã¬ã€ã¢åœ¢ã§ãåé700ïœã®ãã³ã¯ã
å¢ææ²èåéä¹³å€(G)ãåŸãã è²çŽ ä¹³å€(H)ã®èª¿è£œæ³ åèšä¹³å€(F)ã®äœãæ¹ã«ãããŠãä¹³å€(F)ã§çšãã
è²çŽ ãããã²ã³åéç²å圢æäžã«æ·»å ããã代
ãã«åéã®è²çŽ ãååŠå¢æçµäºåŸçŽã¡ã«æ·»å ã
ãä»ã¯ä¹³å€(F)ãšåæ§ã«ããŠèª¿è£œãããã®ãä¹³å€(H)
ãšããã ä¹³å€(I)ã®èª¿è£œæ³ åèšä¹³å€(G)ã®äœãæ¹ã«ãããŠãä¹³å€(F)ã§çšãã
è²çŽ ããã³ä¹³å€(G)ã§çšããè²çŽ ããŒã©ãã³æº¶
液äžã«æ·»å ããã代ãã«åéã®è²çŽ ããã³ã
ååŠå¢æåŸçŽã ã¡ã«æ·»å ããä»ã¯ä¹³å€(G)ãšåæ§ã«
ããŠèª¿è£œãããã®ãä¹³å€(I)ãšããã ãã€ã¯ãã«ãã»ã«ã®èª¿è£œããã³æå ã·ãŒãã®
äœè£œïŒœ ããªã¡ãããŒã«ãããã³ããªã¢ã¯ãªã¬ãŒã28ïœ
ããã³ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãïŒïœã®ã¢ãããŒæ··å
ç©ã«å¡©åã¡ãã¬ã³ïŒïœäžã«æº¶è§£ããçºè²å€ã®ïŒâ
ãžãšãã«ã¢ããâïŒâã¯ãã«âïŒâã¢ããªããã«
ãªã©ã³2.1ïœãæ·»å ããã¢ãããŒæ··åç©ãšããã
ãã®ã¢ãããŒæ··åç©ã«ä¹³å€(A)ïŒïœãå ããŠæ··åã
ããã®ãæºåããã äžæ¹10ïŒ ã¢ã©ãã¢ãŽã 氎溶液17.5ïœã12ïŒ ã€ãœ
ããã¬ã³ïŒç¡æ°Žãã¬ã€ã³é žæ°Žæº¶æ¶²18.5ïœãèžçæ°Ž
26.5ïœã®æ··åç©ããç¡«é žã§PH3.5ã«èª¿è£œããæŽã«
å°¿çŽ 4.6ïœãã¬ãŸã«ã·ã³0.6ïœãå ãããã®æº¶æ¶²ã«
å ã®ããã²ã³åéãå«ãã¢ãããŒæ··åç©ãä¹³åå
æ£ãã3ÎŒãšãããã€ãã§36ïŒ ãã«ããªã³12.9ïœã
å ãæ¹æãã€ã€60âãŸã§ææž©ããïŒæéåŸã«ïŒïŒ
ç¡«é žã¢ã³ã¢ããŠã 氎溶液9.0ïœãå ããæŽã«60â
ã«ä¿ã¡ã€ã€ïŒæéæ¹æåŸå·åŽããããã®åŸ
NaOHã«ããPHã9.0ãšããã ããããŠåŸãã«ãã»ã«æ¶²ïŒïœã«15ïŒ ããªããã«
ã¢ã«ã³ãŒã«æ°Žæº¶æ¶²1.53ïœãèžçæ°Ž3.47ïœãã§ãã¶
ã0.57ïœããã³Î²âã¢ã»ãã«âïœâã¢ãã³ããšã
ã«ããã©ãžã³5.5mgãå ãå¡åžæ¶²ãšãããããã
ã³ãŒãã€ã³ã°ããã10ãçšããŠãã¢ãŒãçŽã«å¡åž
ãã50âã§15åé也ç¥ããæå ã·ãŒãïŒãåŸãã æå ã·ãŒãïŒã«ãããŠãä¹³å€(A)ã®ä»£ããã«ä¹³å€
(B)ã(I)ïŒè¡šïŒïŒãçšããŠäœè£œãããã®ããããã
æå ã·ãŒãïŒãïŒïŒè¡šïŒïŒãšããã ååã·ãŒãã®äœè£œïŒœ 21.8ïœã®æ°Žã«48ïŒ ã®SBRã©ããã¯ã¹0.6ïœã10
ïŒ ãšãŒãã«åã§ãã¶ã氎溶液ïŒïœãçé žäºé2.1
ïœãã±ã€é žãœãŒã50ïŒ æ°Žæº¶æ¶²1.3ïœããããµã¡ã¿
ãªã³é žãœãŒã0.1ïœãé žæ§çœå13ïœãå ãããã¢
ãžãã€ã¶ãŒã§15åéæ¹æããã ãããã³ãŒãã€ã³ã°ããã18ãçšããŠã¢ãŒãçŽ
ã«å¡åžãã100âã§ïŒåé也ç¥ããååã·ãŒãã
åŸãã ç»åã®åçããã³çµæ äžè¿°ã®æå ã·ãŒãã«ç·ç»ã®åçš¿ãä»ããŠããã
ã²ã³ã©ã³ããçšãã400ã700nmã®æ³¢é·ã®å ãç §
å°ãããé²å åŸããã®æå ã·ãŒãã120âã«ãŠ30
ç§éå ç±ãããããã«ããã®åŸæå ã·ãŒããšåå
ã·ãŒãã®å¡åžé¢ã察åããããã«éããŠãç·å§
100KgïŒcmã®å å§ããŒã©ãŒã«éãããæªé²å éšã®
ã«ãã»ã«ã¯ç Žå£ãããååã·ãŒãã«è»¢åãããã
転åãããéšåã¯æ¿åºŠ1.0ã®é®®æãªé»è²ç»åãäž
ããã é²å éšã«å¯Ÿå¿ããéšåã¯é²å éã«å¿ãæ¿åºŠãå€
åããããæ¿åºŠ0.1以äžãšãªãæäœé²å éããæ
床ãè©äŸ¡ããã ãŸããäžèšã®æå ã·ãŒãã25âã§ïŒã±æéä¿å
ãããã®ã«ã€ããŠãåæ§ã«ããŠæ床ãè©äŸ¡ããã çµæãè¡šïŒã«ç€ºãã ãªããçžå¯Ÿæ床ã¯ãæå ã·ãŒãïŒã®æ床ã100
ãšããŠè¡šç€ºããã
ãè¡šã
è¡šïŒãããç·è²å
ãŸãã¯èµ€è²å
ã«æå
æ§ããã€
ãã®ã«ã€ããŠæ¯ã¹ããšãæ¬çºæã®æå ã·ãŒãïŒã
ïŒãïŒãïŒã¯ãæ¯èŒã®æå ã·ãŒãïŒãïŒãïŒãïŒ
ãããã·ãŒãäœè£œçŽåŸã®æ床ãé«ãããã€çµæã«
ããæ床ã®äœäžãèããæ¹åãããããšããã
ãããŸããæå ã·ãŒãïŒã¯å¢æè²çŽ ã䜿çšããªã
äŸã§ããã®å Žåçµæã«ããæ床ã®äœäžãå°ããã å®æœäŸ ïŒ å®æœäŸïŒã§èª¿è£œããä¹³å€ãè¡šïŒã«ç€ºãããã«äœ¿
çšããå®æœäŸïŒã«ãããŠãã€ã¯ãã«ãã»ã«ã調補
ããéã«çšããçºè²å€ã®ïŒâãžãšãã«ã¢ããâïŒ
âã¯ãã«âïŒâã¢ããªããã«ãªã©ã³ãè¡šïŒã«ç€ºã
ãããªçºè²å€ã«å€ããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠ
ãã€ã¯ãã«ãã»ã«ïœãïœ ã調補ããã
ãã®ã«ã€ããŠæ¯ã¹ããšãæ¬çºæã®æå ã·ãŒãïŒã
ïŒãïŒãïŒã¯ãæ¯èŒã®æå ã·ãŒãïŒãïŒãïŒãïŒ
ãããã·ãŒãäœè£œçŽåŸã®æ床ãé«ãããã€çµæã«
ããæ床ã®äœäžãèããæ¹åãããããšããã
ãããŸããæå ã·ãŒãïŒã¯å¢æè²çŽ ã䜿çšããªã
äŸã§ããã®å Žåçµæã«ããæ床ã®äœäžãå°ããã å®æœäŸ ïŒ å®æœäŸïŒã§èª¿è£œããä¹³å€ãè¡šïŒã«ç€ºãããã«äœ¿
çšããå®æœäŸïŒã«ãããŠãã€ã¯ãã«ãã»ã«ã調補
ããéã«çšããçºè²å€ã®ïŒâãžãšãã«ã¢ããâïŒ
âã¯ãã«âïŒâã¢ããªããã«ãªã©ã³ãè¡šïŒã«ç€ºã
ãããªçºè²å€ã«å€ããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠ
ãã€ã¯ãã«ãã»ã«ïœãïœ ã調補ããã
ãè¡šã
ãã®ãããªãã€ã¯ãã«ãã»ã«ïœãïœ
ã®ãªããã
è¡šïŒã«ç€ºãããã«æ··åãããã®ã«15ïŒ ããªããã«
ã¢ã«ã³ãŒã«æ°Žæº¶æ¶²ïŒïœãèžçæ°ŽïŒïœããã³Î²âã¢
ã»ãã«âïœâã¢ããããšãã«ããã©ãžã³16.5mgã
å ããŠå¡åžæ¶²ãšããã³ãŒãã€ã³ã°ããã20ãçšã
ãŠã¢ãŒãçŽã«å¡åžã50âã§15åé也ç¥ããŠæå ã·
ãŒããåŸãããã®å Žå䜿çšãããã€ã¯ãã«ãã»ã«
ã«å¯Ÿå¿ãããŠæå ã·ãŒã10ã11ãšããïŒè¡šïŒïŒã ç»åã®åçã¯æå ã·ãŒãã«ã«ã©ãŒç»åã®åçš¿ã
ä»ããŠãããã²ã³ã©ã³ããçšãã400ã700nmã®
å ã§é²å ãã次ã«ãã®æå ã·ãŒãã120âã«ãŠ30
ç§éå ç±ãããæŽã«ãã®æå ã·ãŒããšååã·ãŒã
ïŒå®æœäŸïŒã§äœ¿çšãããã®ãšåãïŒã®å¡åžé¢ã察
æããããã«éããŠç·å§100KgïŒcmã®å å§ããŒã©
ãŒã«éãããããã«ããæªé²å éšã®ãã€ã¯ãã«ã
ã»ã«ã¯ç Žå£ããååã·ãŒãäžã«è»¢åãããåçš¿ãš
åãã«ã©ãŒç»åãåŸãããã®ããã»ã¹ã«ãããŠå
çç»åã®è²å³ãæå³çã«å€ãããå Žåã«ã¯é²å æ
ã«å ã®éè²ãç·è²ãèµ€è²ã®æåã®æ¯çããã€ã«ã¿
ãŒãçšããŠå€åãããããšã§ä»»æã®è²å³ã®ç»åã
åŸãããšãã§ããã ãŸããäœè£œçŽåŸã®æå ã·ãŒããçšããŠç»ååç
åŸã®ååã·ãŒãäžã®åå°æ¿åºŠãéãã€ã«ã¿ãç·ã
ã€ã«ã¿ãèµ€ãã€ã«ã¿ã§åã 1.0ãšãªãããã«é²å
æã®å ã®éãç·ãèµ€æåãã³ã³ãããŒã«ããã次
ã«ãããšå šãåãæ¡ä»¶ã§25âã§ïŒã±æçµæããã
æå ã·ãŒããçšããŠç»ååçãããæã®åå°æ¿åºŠ
ã枬å®ããããããŠãã®æ¿åºŠãäœè£œçŽåŸã®æ¿åºŠå€
1.0ã«å¯ŸããŠã©ã®ãããäžæïŒæ床äœäžãæå³ã
ãïŒãããã調ã¹ãããã®å Žåãåçç»åãã°ã¬
ã€ãšãªããããªæ¡ä»¶ã§è©Šéšããã ãã®çµæãè¡šïŒã«ç€ºãã
è¡šïŒã«ç€ºãããã«æ··åãããã®ã«15ïŒ ããªããã«
ã¢ã«ã³ãŒã«æ°Žæº¶æ¶²ïŒïœãèžçæ°ŽïŒïœããã³Î²âã¢
ã»ãã«âïœâã¢ããããšãã«ããã©ãžã³16.5mgã
å ããŠå¡åžæ¶²ãšããã³ãŒãã€ã³ã°ããã20ãçšã
ãŠã¢ãŒãçŽã«å¡åžã50âã§15åé也ç¥ããŠæå ã·
ãŒããåŸãããã®å Žå䜿çšãããã€ã¯ãã«ãã»ã«
ã«å¯Ÿå¿ãããŠæå ã·ãŒã10ã11ãšããïŒè¡šïŒïŒã ç»åã®åçã¯æå ã·ãŒãã«ã«ã©ãŒç»åã®åçš¿ã
ä»ããŠãããã²ã³ã©ã³ããçšãã400ã700nmã®
å ã§é²å ãã次ã«ãã®æå ã·ãŒãã120âã«ãŠ30
ç§éå ç±ãããæŽã«ãã®æå ã·ãŒããšååã·ãŒã
ïŒå®æœäŸïŒã§äœ¿çšãããã®ãšåãïŒã®å¡åžé¢ã察
æããããã«éããŠç·å§100KgïŒcmã®å å§ããŒã©
ãŒã«éãããããã«ããæªé²å éšã®ãã€ã¯ãã«ã
ã»ã«ã¯ç Žå£ããååã·ãŒãäžã«è»¢åãããåçš¿ãš
åãã«ã©ãŒç»åãåŸãããã®ããã»ã¹ã«ãããŠå
çç»åã®è²å³ãæå³çã«å€ãããå Žåã«ã¯é²å æ
ã«å ã®éè²ãç·è²ãèµ€è²ã®æåã®æ¯çããã€ã«ã¿
ãŒãçšããŠå€åãããããšã§ä»»æã®è²å³ã®ç»åã
åŸãããšãã§ããã ãŸããäœè£œçŽåŸã®æå ã·ãŒããçšããŠç»ååç
åŸã®ååã·ãŒãäžã®åå°æ¿åºŠãéãã€ã«ã¿ãç·ã
ã€ã«ã¿ãèµ€ãã€ã«ã¿ã§åã 1.0ãšãªãããã«é²å
æã®å ã®éãç·ãèµ€æåãã³ã³ãããŒã«ããã次
ã«ãããšå šãåãæ¡ä»¶ã§25âã§ïŒã±æçµæããã
æå ã·ãŒããçšããŠç»ååçãããæã®åå°æ¿åºŠ
ã枬å®ããããããŠãã®æ¿åºŠãäœè£œçŽåŸã®æ¿åºŠå€
1.0ã«å¯ŸããŠã©ã®ãããäžæïŒæ床äœäžãæå³ã
ãïŒãããã調ã¹ãããã®å Žåãåçç»åãã°ã¬
ã€ãšãªããããªæ¡ä»¶ã§è©Šéšããã ãã®çµæãè¡šïŒã«ç€ºãã
ãè¡šã
è¡šïŒãããæ¬çºæã®æå
ã·ãŒãã«ãããŠã¯ãçµ
æã§ã®æ床å€åãããªãã¡åäžæ¡ä»¶ã§ç»åãåç
ããæã®æ¿åºŠå€åã倧巟ã«æ¹è¯ã§ããããšããã
ãã 以äžããæ¬çºæã®å¹æã¯æããã§ããã
æã§ã®æ床å€åãããªãã¡åäžæ¡ä»¶ã§ç»åãåç
ããæã®æ¿åºŠå€åã倧巟ã«æ¹è¯ã§ããããšããã
ãã 以äžããæ¬çºæã®å¹æã¯æããã§ããã
Claims (1)
- ïŒ æ¯æäœäžã«å°ãªããšãæå æ§ããã²ã³åéä¹³
å€ãéå å€ãéåæ§ååç©ããã³è²ç»å圢æç©è³ª
ãæãããã€ãããã®äžã®å°ãªããšãéåæ§åå
ç©ãšè²ç»å圢æç©è³ªãšãåäžã®ãã€ã¯ãã«ãã»ã«
ã«å°å ¥ãããç¶æ ã§å«æãããæå ææã«ãã
ãŠãåæ§é²å ã«ããæœåã圢æããããã²ã³åé
ä¹³å€ãå¢æè²çŽ ã®ååšäžã§åœ¢æãããããã²ã³å
éç²åãå«ãããšãç¹åŸŽãšããæå ææã
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13974685A JPS62947A (ja) | 1985-06-26 | 1985-06-26 | æå ææ |
EP86107362A EP0203613B1 (en) | 1985-05-30 | 1986-05-30 | Light-sensitive material containing microcapsules and image-recording method using the same |
DE8686107362T DE3666634D1 (en) | 1985-05-30 | 1986-05-30 | Light-sensitive material containing microcapsules and image-recording method using the same |
US07/201,334 US4912011A (en) | 1985-05-30 | 1988-05-31 | Image-recording method comprising heating a light-sensitive material containing microcapsule |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13974685A JPS62947A (ja) | 1985-06-26 | 1985-06-26 | æå ææ |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS62947A JPS62947A (ja) | 1987-01-06 |
JPH0455497B2 true JPH0455497B2 (ja) | 1992-09-03 |
Family
ID=15252412
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP13974685A Granted JPS62947A (ja) | 1985-05-30 | 1985-06-26 | æå ææ |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS62947A (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59206645A (ja) * | 1983-05-10 | 1984-11-22 | Toyota Motor Corp | é»åå¶åŸ¡ãšã³ãžã³ã®ã¢ã€ãã«å転é床å¶åŸ¡æ¹æ³ |
JPH0658535B2 (ja) * | 1986-01-22 | 1994-08-03 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | æå æ§ãã€ã¯ãã«ãã»ã«ããã³æå ææ |
JPH0658536B2 (ja) * | 1986-03-11 | 1994-08-03 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | æå ææã®è£œé æ¹æ³ |
US10352995B1 (en) | 2018-02-28 | 2019-07-16 | Nxp Usa, Inc. | System and method of multiplexing laser triggers and optically selecting multiplexed laser pulses for laser assisted device alteration testing of semiconductor device |
-
1985
- 1985-06-26 JP JP13974685A patent/JPS62947A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS62947A (ja) | 1987-01-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0203613B1 (en) | Light-sensitive material containing microcapsules and image-recording method using the same | |
EP0174634B1 (en) | Image forming method | |
JPH0422507B2 (ja) | ||
JPH0422509B2 (ja) | ||
US4902599A (en) | Light-sensitive material | |
JPH0455498B2 (ja) | ||
JPH0578825B2 (ja) | ||
US4792514A (en) | Light-sensitive material | |
JPH0571090B2 (ja) | ||
JPH0455497B2 (ja) | ||
JPS62209444A (ja) | ç±çŸåçšæå ææ | |
JP3905234B2 (ja) | å éåæ§çµæç©åã³ãããçšããæå æç±èšé²ææ | |
JPS62195639A (ja) | æå ææ | |
JPH0312308B2 (ja) | ||
JPH0237351A (ja) | æå ææ | |
JPS63184738A (ja) | æå ææ | |
JP2524523B2 (ja) | ç»åèšé²æ¹æ³ | |
JPH0518417B2 (ja) | ||
JPH0519699B2 (ja) | ||
JPH02146041A (ja) | æå ææã®è£œé æ¹æ³ | |
JPH02240648A (ja) | æå ææ | |
JPH0658536B2 (ja) | æå ææã®è£œé æ¹æ³ | |
JPH02141756A (ja) | èšé²ææåã³èšé²æ¹æ³ | |
JPS6396652A (ja) | æå ææ | |
JPS63129338A (ja) | æå ææ |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
LAPS | Cancellation because of no payment of annual fees |