JPH0439365A - Ink-jet recording and recording solution - Google Patents
Ink-jet recording and recording solutionInfo
- Publication number
- JPH0439365A JPH0439365A JP2146902A JP14690290A JPH0439365A JP H0439365 A JPH0439365 A JP H0439365A JP 2146902 A JP2146902 A JP 2146902A JP 14690290 A JP14690290 A JP 14690290A JP H0439365 A JPH0439365 A JP H0439365A
- Authority
- JP
- Japan
- Prior art keywords
- recording
- ink
- formula
- water
- receiving layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims abstract description 28
- 239000000463 material Substances 0.000 claims abstract description 23
- -1 amine salt Chemical group 0.000 claims abstract description 9
- 239000000049 pigment Substances 0.000 claims abstract description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 7
- 239000010703 silicon Substances 0.000 claims abstract description 7
- 239000012736 aqueous medium Substances 0.000 claims abstract description 6
- 239000011230 binding agent Substances 0.000 claims abstract description 6
- 239000011347 resin Substances 0.000 claims abstract description 6
- 229920005989 resin Polymers 0.000 claims abstract description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 4
- 150000001340 alkali metals Chemical group 0.000 claims abstract description 4
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical group [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000007788 liquid Substances 0.000 claims description 24
- 239000002585 base Substances 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract description 8
- 239000000758 substrate Substances 0.000 abstract description 4
- 238000004040 coloring Methods 0.000 abstract 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 abstract 1
- 238000007641 inkjet printing Methods 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 11
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- CYSGHNMQYZDMIA-UHFFFAOYSA-N 1,3-Dimethyl-2-imidazolidinon Chemical compound CN1CCN(C)C1=O CYSGHNMQYZDMIA-UHFFFAOYSA-N 0.000 description 1
- ZFPGARUNNKGOBB-UHFFFAOYSA-N 1-Ethyl-2-pyrrolidinone Chemical compound CCN1CCCC1=O ZFPGARUNNKGOBB-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- GCYHRYNSUGLLMA-UHFFFAOYSA-N 2-prop-2-enoxyethanol Chemical compound OCCOCC=C GCYHRYNSUGLLMA-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 238000001454 recorded image Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はインクジェット記録方式により、発色性、耐光
性、耐オゾン性に優れた記録画像を形成する記録方法及
びそれに用いる記録液に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a recording method for forming recorded images with excellent color development, light fastness, and ozone fastness by an inkjet recording method, and a recording liquid used therein.
（従来の技術）
インクジェット記録方式は、ランニングコストが安い、
低騒音である、カラー化が容易である等の種々の理由に
より最近、急速に発達して来ている。(Conventional technology) The inkjet recording method has low running costs.
Recently, it has been rapidly developed for various reasons such as low noise and easy colorization.
インクジェット記録においては、モノクロ記録や７色程
度のマルチカラー記録の場合、電子写真用紙、ファンホ
ールド紙、ストックフオーム紙、タイプライタ−用紙等
のいわゆる普通紙（ノンコート紙）が用いられることが
多いが、コンピューターグラフィックスやテレビ等のフ
ルカラー画像のハードコピーを撮る場合には、基材上に
シリカやゼオライトの様な顔料を塗工したいわゆるコー
ト紙が用いられる。In inkjet recording, so-called plain paper (non-coated paper) such as electrophotographic paper, fan-hold paper, stock form paper, and typewriter paper is often used for monochrome recording or multicolor recording of about 7 colors. When making hard copies of full-color images such as computer graphics and television, so-called coated paper, which is a substrate coated with a pigment such as silica or zeolite, is used.
しかしながらこの様なコート紙上に水溶性染料を用いて
記録した場合、原因は明らかにされていないが、耐光性
、耐オゾン性が著しく低下する。However, when recording on such coated paper using a water-soluble dye, the light fastness and ozone fastness are significantly reduced, although the cause is not clear.
この様な欠点を改良するために、例えば特開昭６４−７
５２８０、特開昭６４−７５２８２、特開昭６４−３６
４７９、特開昭６４−３６４８０、特開昭６４−１８６
８４、特開昭６４−１１８７７の様な特許が出願されて
いるが、前記の様な問題は未だ十分解決されていない。In order to improve such drawbacks, for example, Japanese Patent Application Laid-Open No. 64-7
5280, JP-A-64-75282, JP-A-64-36
479, JP-A-64-36480, JP-A-64-186
Although patents such as No. 84 and JP-A No. 64-11877 have been filed, the above-mentioned problems have not yet been satisfactorily solved.
（発明が解決しようとする課題）
本発明はコート紙のような基材上に含ケイ素顔料を塗工
した被記録材に、水溶性染料を用いてインクジェット方
式により記録を行う場合、耐光性、耐オゾン性に優れた
画像を形成するための記録方法及びそれに用いる記録液
を提供するものである。(Problems to be Solved by the Invention) The present invention aims at improving light resistance, when recording by an inkjet method using a water-soluble dye on a recording material such as a coated paper coated with a silicon-containing pigment. The present invention provides a recording method for forming an image with excellent ozone resistance and a recording liquid used therein.
（課題を解決するための手段）
本発明は、基材上に含ケイ素顔料とバインダー樹脂を含
むインク受容層を有する被記録材に、水性媒体及び下記
−数式〔１）
・・・ （１）
（式中、Ｃｕ −Ｐｃは銅フタロシアニン残基を表わし
、ｌは１又は２、ｍ及びｎはそれぞれ１〜３の整数を表
わし、且つｍ＋ｎは３又は４を表わし、Ｍはアルカリ金
属、アンモニウム又はアミン塩を表わす、）で示される
水溶性染料を含む記録液を用いて、インクジェット記録
方式により記録することを特徴とするインクジェット記
録方法及びその方法に使用する記録液を要旨とするもの
である。(Means for Solving the Problems) The present invention provides a recording material having an ink receiving layer containing a silicon-containing pigment and a binder resin on a base material, an aqueous medium and the following formula [1] ... (1) (In the formula, Cu-Pc represents a copper phthalocyanine residue, l represents 1 or 2, m and n each represent an integer of 1 to 3, and m+n represents 3 or 4, M represents an alkali metal, ammonium or The present invention provides an inkjet recording method characterized in that recording is performed by an inkjet recording method using a recording liquid containing a water-soluble dye represented by ), which represents an amine salt, and a recording liquid used in the method.
以下、本発明の詳細な説明する。The present invention will be explained in detail below.
本発明の記録液に使用する一般式（１）の染料の具体例
としては以下の様なものが挙げられる。Specific examples of the dye of general formula (1) used in the recording liquid of the present invention include the following.
Ｍ：ＨＮ（ＣｚＬＯＨ）ｓ
本発明のこれら染料化合物は特開昭６０−２０８６３５
号公報に記載の方法に準じて製造することができる。M:HN(CzLOH)s These dye compounds of the present invention are disclosed in JP-A-60-208635.
It can be manufactured according to the method described in the above publication.
記録液中の上記染料化合物の含有量としては、記録液全
重量に対して０．２〜１０％、好ましくは０．５〜５％
が挙げられる。The content of the dye compound in the recording liquid is 0.2 to 10%, preferably 0.5 to 5% based on the total weight of the recording liquid.
can be mentioned.
本発明の記録液に用いられる水性媒体の溶剤としては、
水の池水溶性有機溶剤として、エチレングリコール、プ
ロピレングリコール、ブチレングリコール、ジエチレン
グリコール、トリエチレングリコール、ポリエチレング
リコール（＃２００）ポリエチレングリコール（＃４０
０）、グリセリン、Ｎ−メチル−ピロリドン、Ｎ−エチ
ル−ピロリドン、Ｎ−ビニル−ピロリドン、１．３−ジ
メチル−イミダゾリジノン、エチレングリコールモノア
リルエーテル、エチレングリコールモノメチルエーテル
、ジエチレングリコール七ツメチルエーテル等を含有し
ているのが好ましく、水溶性有機溶剤の含有量としては
、記録液全重量に対し、１０〜５０重量％の範囲が挙げ
られる。As the solvent for the aqueous medium used in the recording liquid of the present invention,
Water Pond Water-soluble organic solvents include ethylene glycol, propylene glycol, butylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol (#200) and polyethylene glycol (#40).
0), glycerin, N-methyl-pyrrolidone, N-ethyl-pyrrolidone, N-vinyl-pyrrolidone, 1,3-dimethyl-imidazolidinone, ethylene glycol monoallyl ether, ethylene glycol monomethyl ether, diethylene glycol 7-methyl ether, etc. The content of the water-soluble organic solvent is preferably 10 to 50% by weight based on the total weight of the recording liquid.
又本発明の記録液は、上記の水溶性有機溶剤以外に消泡
剤、界面活性剤、尿素等を含有していても良い。尚記録
液のｐＨは６〜８が好ましい。Further, the recording liquid of the present invention may contain an antifoaming agent, a surfactant, urea, etc. in addition to the above-mentioned water-soluble organic solvent. The pH of the recording liquid is preferably 6 to 8.
本発明の被記録材に用いる基材としては得に制限されな
いが、通常、紙、プラスチックフィルムが挙げられる。The base material used for the recording material of the present invention is not particularly limited, but paper and plastic film are usually mentioned.
紙としては、セルロース及び填料からなる普通紙の他ポ
リオレフィン、ポリスチレン、ポリエチレンテレフタレ
ート等から作られた合成紙が用いられる。As the paper, in addition to plain paper made of cellulose and filler, synthetic paper made of polyolefin, polystyrene, polyethylene terephthalate, etc. can be used.
プラスチックフィルムとしては、ポリ塩化ビニル、ポリ
エチレンテレフタレート、ポリ（メチルメタ）アクリレ
ート、ポリスチレン、ポリフッ化ビニリデン等のフィル
ムが用いられる。As the plastic film, films of polyvinyl chloride, polyethylene terephthalate, poly(methyl meth)acrylate, polystyrene, polyvinylidene fluoride, etc. are used.
上記基材上に形成するインク受容層としての塗工層に用
いるバインダー樹脂は、親水性のものが好ましく、例え
ば、ポリビニルアルコール、デン粉、ゼラチン、カルボ
キシメチルセルロース、ヒドロキシエチルセルロース、
ポリウレタン、ポリビニルピロリドン等が用いられる。The binder resin used in the coating layer as an ink-receiving layer formed on the above-mentioned base material is preferably a hydrophilic one, such as polyvinyl alcohol, starch, gelatin, carboxymethyl cellulose, hydroxyethyl cellulose,
Polyurethane, polyvinylpyrrolidone, etc. are used.
その他塗工層の膜強度向上のため酢酸ビニルエマルジョ
ン、アクリルエマルジジン、ポリビニルアセタール等ヲ
併用することもできる。In addition, vinyl acetate emulsion, acrylic emulsion, polyvinyl acetal, etc. can also be used in combination to improve the strength of the coating layer.
本発明の被記録材上のインク受容層に使用する含ケイ素
系顔料としては、シリカ、ケイ酸カルシウム、ケイ酸ア
ルミニウム等が使用される。Silica, calcium silicate, aluminum silicate, etc. are used as the silicon-containing pigment used in the ink receiving layer on the recording material of the present invention.
又、軽質及び重質炭酸力マンシウム、タルク、水酸化ア
ルミニウム、二酸化チタン等の無機系顔料を併用するこ
とも可能であるが、その配合量は５０％以下にとどめる
のが好ましい。It is also possible to use inorganic pigments such as light and heavy mansium carbonate, talc, aluminum hydroxide, titanium dioxide, etc., but it is preferable to limit the blending amount to 50% or less.
含ケイ素顔料の粒子径は、通常１０〜１００ｎｉ＋、好
ましくは２０〜５０ｎｍであり、二酸化チタン粒子は０
．１〜ｌＯｕ■、好ましくは０．３〜５μ園の範囲のも
のが用いられる。The particle size of the silicon-containing pigment is usually 10 to 100 ni+, preferably 20 to 50 nm, and the particle size of titanium dioxide particles is 0.
．． A range of 1 to 1 μm, preferably 0.3 to 5 μm is used.
以上の様な成分からなる水性塗工液を調製する際、顔料
とバインダー樹脂の使用比率（重量）は１０／１〜２／
３の範囲が挙げられ、塗工液中の全固型分は１０〜４０
（重量）％の範囲が挙げられる。When preparing an aqueous coating liquid consisting of the above components, the ratio (weight) of pigment to binder resin is 10/1 to 2/2.
3, and the total solid content in the coating liquid is 10 to 40.
(weight)% range.
尚、塗工液を調製する際の溶媒としては、主に水が挙げ
られ、その他イソプロピルアルコール等の低級アルコー
ル類、メチルエチルケトン等の低級アルキルケトン類を
含んでいても良い。Incidentally, the solvent for preparing the coating liquid is mainly water, and may also contain lower alcohols such as isopropyl alcohol, and lower alkyl ketones such as methyl ethyl ketone.
この水性塗工液には分散剤、消泡剤、界面活性剤、耐水
化剤等の添加側を添加しても良い。Additives such as a dispersant, an antifoaming agent, a surfactant, and a waterproofing agent may be added to this aqueous coating liquid.
前記塗工液を前記基材上に塗工乾燥することによってイ
ンク受容層を有する被記録材を形成するが、塗工方法と
してはロールコータ−、ブレードコーター、エアナイフ
コーター、バーコータースリットリバースコーター、ダ
イコーター等が挙げられる。A recording material having an ink-receiving layer is formed by applying the coating liquid onto the base material and drying it. Coating methods include a roll coater, a blade coater, an air knife coater, a bar coater, a slit reverse coater, A die coater etc. are mentioned.
又基材上への塗工量は、５ｇ／ｒｒｆより少いとインク
吸収性が不十分となり易く、他方５０ｇ／ｒｒｒより多
いと表面発色性が不十分となり易いため、通常５〜５０
ｇ／イが好ましい。In addition, if the coating amount on the substrate is less than 5 g/rrf, the ink absorbency tends to be insufficient, while if it is more than 50 g/rrf, the surface color development tends to be insufficient, so it is usually 5 to 50.
g/i is preferred.
本発明の記録液を用いて上記の如き被記録材上にインク
ジェット方式により記録を行う。Using the recording liquid of the present invention, recording is performed on the recording material as described above by an inkjet method.
インクジェット記録方式には種々の形式があり、例えば
、インクの定常加圧によって連続的に噴出するインク流
を静電的に偏向させてオン・オフする連続噴射型（Ｓｗ
ｅｅ を方式、ｔｌｅｒｔｚ方式）と必要時のみインク
粒子を噴出するオンデマンド型があるが、後者において
は圧電素子を用いてノズルからインクを噴射する形式（
パルスジェット方式）や加熱により気泡を発生させその
圧力を用いてインキラノズルから噴射する形式（バブル
ジェット方式）が知られている。There are various types of inkjet recording methods. For example, there is a continuous jet recording method (Sw
There are two types: ee method, tlertz method) and on-demand method, which ejects ink particles only when necessary.The latter method uses a piezoelectric element to eject ink from a nozzle (
The pulse jet method) and the method in which air bubbles are generated by heating and the resulting pressure is used to inject the ink from an ink jet nozzle (bubble jet method) are known.
本発明に於てはこれらインクジェット方式を限定するも
のではないが、オンデマンド型式の装置を使用するのが
簡便である。Although the present invention is not limited to these inkjet methods, it is convenient to use an on-demand type device.
（効 果）
本発明の記録液を用いたインクジェット記録方法によれ
ば、コート紙等に耐光性及び耐オゾン性に優れたフルカ
ラー画像を形成することができる。(Effects) According to the inkjet recording method using the recording liquid of the present invention, a full-color image with excellent light resistance and ozone resistance can be formed on coated paper or the like.
（実施例）
以下本発明を実施例に従って説明するが、本発明はこれ
ら実施例に同等限定されるものではない。(Examples) The present invention will be described below according to Examples, but the present invention is not limited to these Examples.
実施例１
（１）被記録材の作成
ポリビニルピロリドン １０水
７０計
１００
上記の各成分を混合し、ホモジナイザーを用いて均一懸
濁状態とじ塗工液を調製した。Example 1 (1) Preparation of recording material Polyvinylpyrrolidone 10 water
70 total
100 The above components were mixed and a homogenizer was used to prepare a binding coating liquid in a uniform suspension state.
この塗工液を紙（坪量６４ｇ／ｒｒｆ）を基材とし、そ
の上に乾燥塗工量が２０ｇ／ｒｒｆとなる様バーコータ
ー法により塗工し、１１０℃、５分間乾燥して本発明の
被記録材を得た。This coating solution was coated onto paper (basis weight 64 g/rrf) using a bar coater method so that the dry coating amount was 20 g/rrf, and dried at 110°C for 5 minutes. A recording material of 100% was obtained.
（２） インク調製
〔重量％〕
前記！ＩｋＬ１の染料化合物 ３ポ
リエチレングリコール（＃２００） ２０計 １
００
上記組成から成る混合物を十分混合した後、１μのテフ
ロン製濾材を用いて加圧濾過してインクを調製した。(2) Ink preparation [wt%] Above! IkL1 dye compound 3 Polyethylene glycol (#200) 20 total 1
00 The mixture having the above composition was thoroughly mixed and filtered under pressure using a 1 μm Teflon filter medium to prepare an ink.
該インクを用い、インクジェットプリンター（商品名Ｉ
φ−７３０、シャープ■製）により、前記被記録材に記
録を行い下記の方法に従って評価を行った。Using the ink, an inkjet printer (product name I)
Recording was performed on the recording material using a φ-730 (manufactured by Sharp ■), and evaluation was performed according to the following method.
（ａ） 耐光性
室内光に被記録物を３ケ月さらした後の変退色ΔＥ９を
ＪＩＳ Ｚ ８７３０により求めた。その結果へＥ
”は、５と小さいものであった。(a) Light resistance Discoloration and fading ΔE9 after exposing the recorded material to room light for 3 months was determined according to JIS Z 8730. E to the result
” was small at 5.
又キセノンフェードメーター（スガ試験機■製造）によ
り８０時間露光後のΔＥ１は４と小さいものであった。Further, ΔE1 after 80 hours of exposure was as small as 4 using a xenon fade meter (manufactured by Suga Shikenki ■).
（ｂ） 耐オゾン性
オゾン２４ｐｐｓ＋を含有する空気中に９０分間曝露し
た際のΔＥ＊は８と小さいものであった。(b) Ozone resistance When exposed to air containing 24 pps+ of ozone for 90 minutes, ΔE* was as small as 8.
実施例２
（１）被記録材の作成
（２） インク調製
〔重量％〕
前記Ｎα２の染料化合物 ２．５ジエ
チレングリコール ２５水
７２．５計１００
実施例１と同様にして上記組成のインクを調製し、前記
被記録材に記録を行い、評価した結果、耐光性、耐オゾ
ン性のいずれも良好であった。Example 2 (1) Preparation of recording material (2) Ink preparation [wt%] Dye compound of Nα2 2.5 diethylene glycol 25 water
72.5 total 100 An ink having the above composition was prepared in the same manner as in Example 1, and recorded on the recording material. As a result of evaluation, both light resistance and ozone resistance were good.
ポリビニルアルコール ２０水
５５計
１００
実施例１と同様にして上記組成物からなるスラリーを調
製し、この塗工液を厚さ７５μのポリエチレンテレフタ
レートフィルム上に乾燥塗工量８ｇ／ｒｒｆとなる様ダ
イコーター法により塗゛工し、９０°Ｃ１１０分間乾燥
して本発明の被記録材を得た。Polyvinyl alcohol 20 water
55 total
100 A slurry consisting of the above composition was prepared in the same manner as in Example 1, and this coating liquid was applied onto a polyethylene terephthalate film with a thickness of 75 μm using a die coater method so that the dry coating amount was 8 g/rrf. The recording material of the present invention was obtained by drying at 90° C. for 110 minutes.
Claims (2)
ンク受容層を有する被記録材に、水性媒体及び下記一般
式〔 I 〕 ▲数式、化学式、表等があります▼ ・・・〔 I 〕 （式中、Ｃｕ−Ｐｃは銅フタロシアニン残基を表わし、
ｌは１又は２、ｍ及びｎはそれぞれ１〜３の整数を表わ
し、且つｍ＋ｎは３又は４を表わし、Ｍはアルカリ金属
、アンモニウム又はアミン塩を表わす。）で示される水
溶性染料を含む記録液を用いてインクジェット記録方式
により記録することを特徴とするインクジェット記録方
法。(1) A recording material having an ink receiving layer containing a silicon-containing pigment and a binder resin on a base material includes an aqueous medium and the following general formula [I] ▲Mathematical formula, chemical formula, table, etc.▼ ...[I] (In the formula, Cu-Pc represents a copper phthalocyanine residue,
l represents 1 or 2, m and n each represent an integer of 1 to 3, m+n represents 3 or 4, and M represents an alkali metal, ammonium or amine salt. ) An inkjet recording method characterized in that recording is performed by an inkjet recording method using a recording liquid containing a water-soluble dye represented by:
ンク受容層を有する被記録材用インクジェット記録液に
おいて、該記録液が水性媒体及び下記一般式〔 I 〕 ▲数式、化学式、表等があります▼ ・・・〔 I 〕 （式中、Ｃｕ−Ｐｃは銅フタロシアニン残基を表わし、
ｌは１又は２、ｍ及びｎはそれぞれ１〜３の整数を表わ
し、且つｍ＋ｎは３又は４を表わし、Ｍはアルカリ金属
、アンモニウム又はアミン塩を表わす。）で示される水
溶性染料を含むことを特徴とするインクジェット記録液
。(2) In an inkjet recording liquid for a recording material having an ink receiving layer containing a silicon-containing pigment and a binder resin on a base material, the recording liquid has an aqueous medium and the following general formula [I] ▲ Numerical formula, chemical formula, table, etc. Yes▼...[I] (In the formula, Cu-Pc represents a copper phthalocyanine residue,
l represents 1 or 2, m and n each represent an integer of 1 to 3, m+n represents 3 or 4, and M represents an alkali metal, ammonium or amine salt. ) An inkjet recording liquid characterized by containing a water-soluble dye represented by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14690290A JP2932615B2 (en) | 1990-06-05 | 1990-06-05 | Ink jet recording method and recording liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14690290A JP2932615B2 (en) | 1990-06-05 | 1990-06-05 | Ink jet recording method and recording liquid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0439365A true JPH0439365A (en) | 1992-02-10 |
| JP2932615B2 JP2932615B2 (en) | 1999-08-09 |
Family
ID=15418154
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14690290A Expired - Fee Related JP2932615B2 (en) | 1990-06-05 | 1990-06-05 | Ink jet recording method and recording liquid |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2932615B2 (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002060994A1 (en) * | 2001-01-31 | 2002-08-08 | Fuji Photo Film Co., Ltd. | Phthalocyanine compound, ink, ink for ink-jet recording, ink-jet recording method and method for improving ozone gas resistance of colored imaging material |
| WO2003062324A1 (en) * | 2002-01-22 | 2003-07-31 | Fuji Photo Film Co., Ltd. | Dye mixture and ink containing the same |
| EP1352754A2 (en) | 2002-04-09 | 2003-10-15 | Fuji Photo Film Co., Ltd. | Inkjet recording method |
| US6645281B2 (en) | 2000-03-30 | 2003-11-11 | Fuji Photo Film Co., Ltd. | Ink-jet ink and ink jet recording method |
| JP2004091790A (en) * | 2002-08-30 | 2004-03-25 | Eastman Kodak Co | Inkjet ink composition and printing method |
| US6716277B2 (en) | 2000-05-23 | 2004-04-06 | Fuji Photo Film Co., Ltd. | Ink for ink jet and ink jet recording method |
| US6756424B2 (en) | 2000-03-27 | 2004-06-29 | Fuji Photo Film Co., Ltd. | Coloring composition, ink-jet ink, and ink jet recording method |
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-
1990
- 1990-06-05 JP JP14690290A patent/JP2932615B2/en not_active Expired - Fee Related
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6800123B2 (en) | 2000-03-21 | 2004-10-05 | Fuji Photo Film Co., Ltd. | Ink-jet ink, method of manufacturing the same, and ink jet recording method |
| US6756424B2 (en) | 2000-03-27 | 2004-06-29 | Fuji Photo Film Co., Ltd. | Coloring composition, ink-jet ink, and ink jet recording method |
| US6645281B2 (en) | 2000-03-30 | 2003-11-11 | Fuji Photo Film Co., Ltd. | Ink-jet ink and ink jet recording method |
| US6716277B2 (en) | 2000-05-23 | 2004-04-06 | Fuji Photo Film Co., Ltd. | Ink for ink jet and ink jet recording method |
| WO2002060994A1 (en) * | 2001-01-31 | 2002-08-08 | Fuji Photo Film Co., Ltd. | Phthalocyanine compound, ink, ink for ink-jet recording, ink-jet recording method and method for improving ozone gas resistance of colored imaging material |
| US7087107B2 (en) | 2001-01-31 | 2006-08-08 | Fuji Photo Film Co., Ltd. | Phthalocyanine compound, ink, inkjet recording ink, ink-jet recording method and method for improving ozone gas resistance of color image material |
| AU2002226684B2 (en) * | 2001-01-31 | 2007-03-29 | Fuji Photo Film Co., Ltd. | Phthalocyanine compound, ink, ink for ink-jet recording, ink-jet recording method and method for improving ozone gas resistance of colored imaging material |
| AU2002226684C1 (en) * | 2001-01-31 | 2008-05-01 | Fuji Photo Film Co., Ltd. | Phthalocyanine compound, ink, ink for ink-jet recording, ink-jet recording method and method for improving ozone gas resistance of colored imaging material |
| WO2003062324A1 (en) * | 2002-01-22 | 2003-07-31 | Fuji Photo Film Co., Ltd. | Dye mixture and ink containing the same |
| US7211134B2 (en) | 2002-01-22 | 2007-05-01 | Fujifilm Corporation | Dye mixture and ink containing the same |
| AU2003202806B2 (en) * | 2002-01-22 | 2008-11-06 | Fuji Photo Film Co., Ltd. | Dye mixture and ink containing the same |
| EP1352754A2 (en) | 2002-04-09 | 2003-10-15 | Fuji Photo Film Co., Ltd. | Inkjet recording method |
| EP1525995A1 (en) | 2002-04-09 | 2005-04-27 | Fuji Photo Film Co., Ltd. | Inkjet recording method |
| JP2004091790A (en) * | 2002-08-30 | 2004-03-25 | Eastman Kodak Co | Inkjet ink composition and printing method |
| US8080099B2 (en) | 2008-03-25 | 2011-12-20 | Fujifilm Corporation | Ink composition, ink set, and image recording method |
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| Publication number | Publication date |
|---|---|
| JP2932615B2 (en) | 1999-08-09 |
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