JPH0434103B2 - - Google Patents
Info
- Publication number
- JPH0434103B2 JPH0434103B2 JP6012683A JP6012683A JPH0434103B2 JP H0434103 B2 JPH0434103 B2 JP H0434103B2 JP 6012683 A JP6012683 A JP 6012683A JP 6012683 A JP6012683 A JP 6012683A JP H0434103 B2 JPH0434103 B2 JP H0434103B2
- Authority
- JP
- Japan
- Prior art keywords
- soluble
- alcohol
- water
- paper
- indicator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011230 binding agent Substances 0.000 claims description 9
- 239000000123 paper Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 238000004040 coloring Methods 0.000 claims description 7
- 239000004745 nonwoven fabric Substances 0.000 claims description 7
- 150000007524 organic acids Chemical class 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 238000004898 kneading Methods 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 239000000463 material Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000002585 base Substances 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 4
- 239000002966 varnish Substances 0.000 description 4
- 239000001856 Ethyl cellulose Substances 0.000 description 3
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 229920001249 ethyl cellulose Polymers 0.000 description 3
- 235000019325 ethyl cellulose Nutrition 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- JCYPECIVGRXBMO-UHFFFAOYSA-N 4-(dimethylamino)azobenzene Chemical compound C1=CC(N(C)C)=CC=C1N=NC1=CC=CC=C1 JCYPECIVGRXBMO-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229960005382 phenolphthalein Drugs 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- OORQUAGUOJMPCS-UHFFFAOYSA-N 4-[[4-(diethylamino)phenyl]diazenyl]benzenesulfonic acid Chemical compound C1=CC(N(CC)CC)=CC=C1N=NC1=CC=C(S(O)(=O)=O)C=C1 OORQUAGUOJMPCS-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- ATJXMQHAMYVHRX-CPCISQLKSA-N Ellagic acid Natural products OC1=C(O)[C@H]2OC(=O)c3cc(O)c(O)c4OC(=O)C(=C1)[C@H]2c34 ATJXMQHAMYVHRX-CPCISQLKSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- OBRMNDMBJQTZHV-UHFFFAOYSA-N cresol red Chemical compound C1=C(O)C(C)=CC(C2(C3=CC=CC=C3S(=O)(=O)O2)C=2C=C(C)C(O)=CC=2)=C1 OBRMNDMBJQTZHV-UHFFFAOYSA-N 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- CEQFOVLGLXCDCX-WUKNDPDISA-N methyl red Chemical compound C1=CC(N(C)C)=CC=C1\N=N\C1=CC=CC=C1C(O)=O CEQFOVLGLXCDCX-WUKNDPDISA-N 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- ZHFPEICFUVWJIS-UHFFFAOYSA-M sodium 2-hydroxy-5-[(3-nitrophenyl)diazenyl]benzoate Chemical compound [Na+].Oc1ccc(cc1C([O-])=O)N=Nc1cccc(c1)[N+]([O-])=O ZHFPEICFUVWJIS-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- PRZSXZWFJHEZBJ-UHFFFAOYSA-N thymol blue Chemical compound C1=C(O)C(C(C)C)=CC(C2(C3=CC=CC=C3S(=O)(=O)O2)C=2C(=CC(O)=C(C(C)C)C=2)C)=C1C PRZSXZWFJHEZBJ-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
- G01N31/22—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators
- G01N31/221—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators for investigating pH value
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Molecular Biology (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Biophysics (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Toys (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Description
【発明の詳細な説明】
本発明は、大気中においては無色であるが、水
中又は水を付着させることにより発色するシート
に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a sheet that is colorless in the atmosphere but develops color in water or when water is attached to it.
一般に塩基、酸指示薬は、アルカリ水溶液又は
酸性水溶液により発色する性質があり、従来、酸
性又はアルカリ性の水溶液を付けると発色する用
紙として、かくし絵などの玩具、答案用紙などの
練習用具等に利用されている。一方、水を付けた
だけで発色させたい場合は、指示薬とアルカリ、
又は酸性剤を同居させて置くと、それらが共に水
可溶の為、大気中に放置しておくだけで発色する
傾向がある。 Bases and acid indicators generally have the property of developing color when exposed to aqueous alkaline or acidic solutions, and have traditionally been used as paper that develops color when exposed to an acidic or alkaline aqueous solution, toys such as hidden pictures, practice tools such as answer sheets, etc. ing. On the other hand, if you want to develop color just by adding water, use an indicator and alkali,
Or, if acidic agents are placed together, they tend to develop color just by leaving them in the air because they are both water soluble.
本発明は、水又は水分だけで発色可能であり、
また大気中に放置して自然発色する現象のない水
中発色シートである。 The present invention can develop color using only water or moisture,
It is also an underwater coloring sheet that does not naturally develop color when left in the atmosphere.
本発明は、アルコール可溶性塩基指示薬及び水
溶液粉末アルカリ剤、又はアルコール可溶性酸指
示薬及び水溶性粉末有機酸と油溶性結着剤をアル
コール混合の油性溶剤を介在させて混練し、紙又
は不織布又はフイルムにコーテイングすることを
特徴とする水中発色シートである。 The present invention involves kneading an alcohol-soluble base indicator and an aqueous powdered alkaline agent, or an alcohol-soluble acid indicator and a water-soluble powdered organic acid, and an oil-soluble binder in the presence of an oily solvent mixed with alcohol, and then forming the mixture into paper, nonwoven fabric, or film. This is an underwater coloring sheet characterized by coating.
本発明において、アルコール可溶性の塩基指示
薬及びこれと反応して発色させる水溶性アルカリ
剤、又はアルコール可溶性の酸指示薬及びこれと
反応して発色させる水溶性有機酸を油溶性樹脂結
着剤中にアルコールを混合した油性溶剤を介在さ
せて、ボールミルによつて練肉し、ペースト状、
ワニス状の中に包み込むようにして発色ワニスを
製造するもので、指示薬は油性溶剤に混合したア
ルコール溶剤により溶解して結着剤中に混合して
おり、アルカリ剤又は有機酸は粉末状態のまま、
結着剤表面及び結着剤中に分散混合している。こ
のようにして得られる発色ワニスを、紙、不織布
あるいはフイルタにコーター又は印刷方式によつ
てコーテイングして、発色シートを得ることがで
きる。 In the present invention, an alcohol-soluble base indicator and a water-soluble alkali agent that reacts with it to develop a color, or an alcohol-soluble acid indicator and a water-soluble organic acid that reacts with it to develop a color, are mixed in an oil-soluble resin binder with alcohol. Mixed with an oily solvent, it is kneaded in a ball mill to form a paste,
Coloring varnish is produced by encasing it in a varnish-like substance, and the indicator is dissolved in an alcoholic solvent mixed with an oily solvent and mixed into the binder, while the alkaline agent or organic acid remains in powder form. ,
It is dispersed and mixed on the surface of the binder and in the binder. A coloring sheet can be obtained by coating paper, nonwoven fabric, or a filter with the coloring varnish thus obtained using a coater or printing method.
本発明に使用する紙としては、印刷用紙、クラ
フト紙、段ボール紙等があり、不織布としては、
ナイロン、又はポリエステル不織布等があり、フ
イルムとしてはポリエチレン、ポリプロピレン、
ポリエステル、ナイロン等がある。 Examples of paper used in the present invention include printing paper, kraft paper, corrugated paper, etc., and examples of nonwoven fabric include:
There are nylon and polyester nonwoven fabrics, and films include polyethylene, polypropylene,
There are polyester, nylon, etc.
また塩基指示薬としては、フエノールフタレイ
ン、チモールブルー、アリザリンエロー、クレゾ
ールレツド等、粉末アルカリ剤としては、炭酸ナ
トリウム、炭酸カリウム等、結着剤としては、エ
チルセルロース、ニトロセルロース、酢酸ビニ
ル、ポリビニルセルロース、ポリビニルアルコー
ル等、油性溶剤としては、イソプロピルアルコー
ル、ブチルアルコール、トルエン等があり、一
方、酸指示薬としては、メチルエロー、エチルオ
レンジ、グロモクレゾールグリーン、メチルレツ
ド等があり、粉末有機酸としては、シユウ酸、酒
石酸等がある。 Base indicators include phenolphthalein, thymol blue, alizarin yellow, and cresol red; powdered alkali agents include sodium carbonate and potassium carbonate; and binders include ethyl cellulose, nitrocellulose, vinyl acetate, and polyvinyl cellulose. , polyvinyl alcohol, etc. Oil-based solvents include isopropyl alcohol, butyl alcohol, toluene, etc., while acid indicators include methyl yellow, ethyl orange, glomocresol green, methyl red, etc., and powdered organic acids include sulfur There are acids, tartaric acid, etc.
本発明シートは、水中に浸すと結着剤に含有す
るアルコールに可溶な塩基又は酸指示薬としての
発色主剤と、アルカリ剤又は有機酸の発色助剤と
が、水に溶け、結着剤表面より水を吸収して、発
色主剤が助剤より解離したOH-又はH+イオンと
結合して発色する。 When the sheet of the present invention is immersed in water, the color-forming main agent as an alcohol-soluble base or acid indicator contained in the binder and the color-forming auxiliary agent of an alkaline agent or an organic acid dissolve in water, and the surface of the binder dissolves. By absorbing more water, the main coloring agent combines with the OH - or H + ions dissociated from the auxiliary agent to develop color.
＜実施例 １＞
純白ロール紙52ｇ／m2（金しやち：名古屋パル
プ（株）製）に、下記処方
フエノールフタレイン ……1g
炭酸ナトリウム ……10ｇ
エチルセルロースＮ−７（ハーキユレス社製）
……10ｇ
イソプロピルアルコール ……70c.c.
トルエン ……20c.c.
により、ボールミル（インキ練肉機）にて、水を
介在せずに24H混練してワニス化を行ない、これ
をグラビアベタ版（100μ版深）にて上記紙にコ
ーテイングして無色のシートを作成した。このシ
ート上に水数滴を滴下した所、その箇所が赤く発
色した。<Example 1> Pure white roll paper 52 g/m 2 (Kaneshiyachi: manufactured by Nagoya Pulp Co., Ltd.) was coated with the following formulation: Phenol phthalein ... 1 g Sodium carbonate ... 10 g Ethyl cellulose N-7 (manufactured by Hercules Co., Ltd.)
……10g Isopropyl alcohol ……70c.c. Toluene ……20c.c. In a ball mill (ink kneading machine), knead for 24 hours without the intervention of water to form a varnish, and make a gravure solid plate. (100μ plate depth) was coated on the above paper to create a colorless sheet. When a few drops of water were dropped on this sheet, the area turned red.
＜実施例 ２＞
ナイロンスパンボンド不織布（N5051：旭化成
（株）製）に、下記処方
メチルエロー ……1g
シユウ酸 ……8g
エチルセルロースＮ−７（ハーキユレス社製）
……10ｇ
イソプロピルアルコール ……70c.c.
トルエン ……20c.c.
により、ボールミル（インキ練肉機）にて水を介
在せずに24H混練して、ワニス化を行ない、これ
をグラビアベタ版（100μ版深）にて、上記不織
布上にコーテイングして黄色のシートを作成し
た。このシート上に水数滴を滴下した所、その箇
所が赤く発色した。<Example 2> The following formulation was applied to nylon spunbond nonwoven fabric (N5051: manufactured by Asahi Kasei Corporation): Methyl yellow...1g Oxalic acid...8g Ethyl cellulose N-7 (manufactured by Hercules)
...10g Isopropyl alcohol ...70c.c. Toluene ...20c. Knead for 24 hours in a ball mill (ink kneading machine) without the intervention of water to form a varnish, which is then used as a gravure solid plate. A yellow sheet was prepared by coating the above nonwoven fabric at a depth of 100 μm. When a few drops of water were dropped on this sheet, the area turned red.
Claims (1)
ル可溶性塩基指示薬及び水溶性粉末アルカリ剤、
又は、アルコール可溶性酸指示薬及び水溶性粉末
有機酸と、油溶性結着剤とを、アルコール混合の
油性溶剤を介在させて混練したペースト状、ワニ
ス状の発色材を、全面若しくは部分的に、印刷又
はコーテイングしたことを特徴とする水中発色シ
ート。1. An alcohol-soluble base indicator and a water-soluble powdered alkaline agent on paper, nonwoven fabric, or resin film,
Alternatively, a paste-like or varnish-like coloring material made by kneading an alcohol-soluble acid indicator, a water-soluble powdered organic acid, and an oil-soluble binder with an alcohol-mixed oil solvent interposed is printed on the entire surface or in part. Or an underwater coloring sheet characterized by being coated.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6012683A JPS59184861A (en) | 1983-04-06 | 1983-04-06 | Underwater coloring sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6012683A JPS59184861A (en) | 1983-04-06 | 1983-04-06 | Underwater coloring sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59184861A JPS59184861A (en) | 1984-10-20 |
| JPH0434103B2 true JPH0434103B2 (en) | 1992-06-04 |
Family
ID=13133122
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6012683A Granted JPS59184861A (en) | 1983-04-06 | 1983-04-06 | Underwater coloring sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59184861A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63234139A (en) * | 1987-03-23 | 1988-09-29 | Dainichi Color & Chem Mfg Co Ltd | Water sensitive sheet material |
| JP3451673B2 (en) * | 1993-10-25 | 2003-09-29 | 凸版印刷株式会社 | Ink composition for moisture indicator and recording medium using the same |
| BRPI0812662A2 (en) * | 2007-07-05 | 2014-12-23 | Dow Global Technologies Inc | "DISSOLVABLE FILM WITH DETECTION FUNCTIONALITY" |
| JP6740562B2 (en) * | 2014-11-26 | 2020-08-19 | 国立大学法人室蘭工業大学 | Humidity sensitive mixture |
-
1983
- 1983-04-06 JP JP6012683A patent/JPS59184861A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59184861A (en) | 1984-10-20 |
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