JPH04271345A - Device for processing silver halide photographic sensitive material and method for replenishing processing liquid - Google Patents
Device for processing silver halide photographic sensitive material and method for replenishing processing liquidInfo
- Publication number
- JPH04271345A JPH04271345A JP3283591A JP3283591A JPH04271345A JP H04271345 A JPH04271345 A JP H04271345A JP 3283591 A JP3283591 A JP 3283591A JP 3283591 A JP3283591 A JP 3283591A JP H04271345 A JPH04271345 A JP H04271345A
- Authority
- JP
- Japan
- Prior art keywords
- processing
- liquid
- tank
- replenishing
- silver halide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000012545 processing Methods 0.000 title claims abstract description 114
- 239000007788 liquid Substances 0.000 title claims abstract description 92
- 229910052709 silver Inorganic materials 0.000 title claims description 44
- 239000004332 silver Substances 0.000 title claims description 44
- 238000000034 method Methods 0.000 title claims description 41
- -1 silver halide Chemical class 0.000 title claims description 35
- 239000000463 material Substances 0.000 title claims description 27
- 238000011161 development Methods 0.000 claims abstract description 13
- 239000002699 waste material Substances 0.000 abstract description 15
- 230000007423 decrease Effects 0.000 abstract description 5
- 238000007599 discharging Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 35
- 239000003795 chemical substances by application Substances 0.000 description 21
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 15
- 239000000126 substance Substances 0.000 description 13
- 239000013078 crystal Substances 0.000 description 11
- 230000018109 developmental process Effects 0.000 description 11
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 8
- 230000035945 sensitivity Effects 0.000 description 8
- 239000004480 active ingredient Substances 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 7
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 230000006866 deterioration Effects 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- NDGRWYRVNANFNB-UHFFFAOYSA-N pyrazolidin-3-one Chemical class O=C1CCNN1 NDGRWYRVNANFNB-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 229910021607 Silver chloride Inorganic materials 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 3
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- GGZHVNZHFYCSEV-UHFFFAOYSA-N 1-Phenyl-5-mercaptotetrazole Chemical compound SC1=NN=NN1C1=CC=CC=C1 GGZHVNZHFYCSEV-UHFFFAOYSA-N 0.000 description 2
- BDOYKFSQFYNPKF-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetic acid;sodium Chemical compound [Na].[Na].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O BDOYKFSQFYNPKF-UHFFFAOYSA-N 0.000 description 2
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- ZFIQGRISGKSVAG-UHFFFAOYSA-N 4-methylaminophenol Chemical compound CNC1=CC=C(O)C=C1 ZFIQGRISGKSVAG-UHFFFAOYSA-N 0.000 description 2
- LRUDIIUSNGCQKF-UHFFFAOYSA-N 5-methyl-1H-benzotriazole Chemical compound C1=C(C)C=CC2=NNN=C21 LRUDIIUSNGCQKF-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 description 2
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 229910021612 Silver iodide Inorganic materials 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 229940045105 silver iodide Drugs 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 2
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- CBDMBBKKGFKNCA-UHFFFAOYSA-N 1,5-diphenylpyrazolidin-3-one Chemical compound N1C(=O)CC(C=2C=CC=CC=2)N1C1=CC=CC=C1 CBDMBBKKGFKNCA-UHFFFAOYSA-N 0.000 description 1
- HLESEOXHRZRIAG-UHFFFAOYSA-N 1-(1,3-benzothiazol-2-yl)pyrazolidin-3-one Chemical compound N1C(=O)CCN1C1=NC2=CC=CC=C2S1 HLESEOXHRZRIAG-UHFFFAOYSA-N 0.000 description 1
- SVJPLZNMCJQWPJ-UHFFFAOYSA-N 1-(4-methylphenyl)pyrazolidin-3-one Chemical compound C1=CC(C)=CC=C1N1NC(=O)CC1 SVJPLZNMCJQWPJ-UHFFFAOYSA-N 0.000 description 1
- XIWRQEFBSZWJTH-UHFFFAOYSA-N 2,3-dibromobenzene-1,4-diol Chemical compound OC1=CC=C(O)C(Br)=C1Br XIWRQEFBSZWJTH-UHFFFAOYSA-N 0.000 description 1
- DBCKMJVEAUXWJJ-UHFFFAOYSA-N 2,3-dichlorobenzene-1,4-diol Chemical compound OC1=CC=C(O)C(Cl)=C1Cl DBCKMJVEAUXWJJ-UHFFFAOYSA-N 0.000 description 1
- GPASWZHHWPVSRG-UHFFFAOYSA-N 2,5-dimethylbenzene-1,4-diol Chemical compound CC1=CC(O)=C(C)C=C1O GPASWZHHWPVSRG-UHFFFAOYSA-N 0.000 description 1
- HIGSPBFIOSHWQG-UHFFFAOYSA-N 2-Isopropyl-1,4-benzenediol Chemical compound CC(C)C1=CC(O)=CC=C1O HIGSPBFIOSHWQG-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 description 1
- XWKAZXKJYHZGAI-UHFFFAOYSA-N 2-acetyl-4,4-dimethyl-1-phenylpyrazolidin-3-one Chemical compound C1C(C)(C)C(=O)N(C(=O)C)N1C1=CC=CC=C1 XWKAZXKJYHZGAI-UHFFFAOYSA-N 0.000 description 1
- REFDOIWRJDGBHY-UHFFFAOYSA-N 2-bromobenzene-1,4-diol Chemical compound OC1=CC=C(O)C(Br)=C1 REFDOIWRJDGBHY-UHFFFAOYSA-N 0.000 description 1
- XXLXBIHEDAERSL-UHFFFAOYSA-N 2-butoxypentanedial Chemical compound CCCCOC(C=O)CCC=O XXLXBIHEDAERSL-UHFFFAOYSA-N 0.000 description 1
- IQKPRZPVTQHVOY-UHFFFAOYSA-N 2-methylpentanedial Chemical compound O=CC(C)CCC=O IQKPRZPVTQHVOY-UHFFFAOYSA-N 0.000 description 1
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- YSMHGANYTYAANX-UHFFFAOYSA-N 3-ethoxy-2-methoxypentanedial Chemical compound CCOC(CC=O)C(OC)C=O YSMHGANYTYAANX-UHFFFAOYSA-N 0.000 description 1
- LUNMJPAJHJAGIS-UHFFFAOYSA-N 3-methylpentanedial Chemical compound O=CCC(C)CC=O LUNMJPAJHJAGIS-UHFFFAOYSA-N 0.000 description 1
- GNHQQNHUGNIICU-UHFFFAOYSA-N 4,4-dihydroxy-2-methyl-1-phenylpyrazolidin-3-one Chemical compound C1C(O)(O)C(=O)N(C)N1C1=CC=CC=C1 GNHQQNHUGNIICU-UHFFFAOYSA-N 0.000 description 1
- SJSJAWHHGDPBOC-UHFFFAOYSA-N 4,4-dimethyl-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(C)(C)CN1C1=CC=CC=C1 SJSJAWHHGDPBOC-UHFFFAOYSA-N 0.000 description 1
- SOVXTYUYJRFSOG-UHFFFAOYSA-N 4-(2-hydroxyethylamino)phenol Chemical compound OCCNC1=CC=C(O)C=C1 SOVXTYUYJRFSOG-UHFFFAOYSA-N 0.000 description 1
- SRYYOKKLTBRLHT-UHFFFAOYSA-N 4-(benzylamino)phenol Chemical compound C1=CC(O)=CC=C1NCC1=CC=CC=C1 SRYYOKKLTBRLHT-UHFFFAOYSA-N 0.000 description 1
- DSVIHYOAKPVFEH-UHFFFAOYSA-N 4-(hydroxymethyl)-4-methyl-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(C)(CO)CN1C1=CC=CC=C1 DSVIHYOAKPVFEH-UHFFFAOYSA-N 0.000 description 1
- HDGMAACKJSBLMW-UHFFFAOYSA-N 4-amino-2-methylphenol Chemical compound CC1=CC(N)=CC=C1O HDGMAACKJSBLMW-UHFFFAOYSA-N 0.000 description 1
- FQQGQVUWBXURTA-UHFFFAOYSA-N 4-ethyl-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(CC)CN1C1=CC=CC=C1 FQQGQVUWBXURTA-UHFFFAOYSA-N 0.000 description 1
- ZZEYCGJAYIHIAZ-UHFFFAOYSA-N 4-methyl-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(C)CN1C1=CC=CC=C1 ZZEYCGJAYIHIAZ-UHFFFAOYSA-N 0.000 description 1
- FIARATPVIIDWJT-UHFFFAOYSA-N 5-methyl-1-phenylpyrazolidin-3-one Chemical compound CC1CC(=O)NN1C1=CC=CC=C1 FIARATPVIIDWJT-UHFFFAOYSA-N 0.000 description 1
- WSGURAYTCUVDQL-UHFFFAOYSA-N 5-nitro-1h-indazole Chemical compound [O-][N+](=O)C1=CC=C2NN=CC2=C1 WSGURAYTCUVDQL-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical class [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- GQUZTSGWULGOLE-UHFFFAOYSA-N C(C)(=O)O[C-]1NN(CC1=O)C1=CC=CC=C1 Chemical compound C(C)(=O)O[C-]1NN(CC1=O)C1=CC=CC=C1 GQUZTSGWULGOLE-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- WRUZLCLJULHLEY-UHFFFAOYSA-N N-(p-hydroxyphenyl)glycine Chemical compound OC(=O)CNC1=CC=C(O)C=C1 WRUZLCLJULHLEY-UHFFFAOYSA-N 0.000 description 1
- PCSMJKASWLYICJ-UHFFFAOYSA-N Succinic aldehyde Chemical compound O=CCCC=O PCSMJKASWLYICJ-UHFFFAOYSA-N 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- AJPXTSMULZANCB-UHFFFAOYSA-N chlorohydroquinone Chemical compound OC1=CC=C(O)C(Cl)=C1 AJPXTSMULZANCB-UHFFFAOYSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- JGEMYUOFGVHXKV-OWOJBTEDSA-N fumaraldehyde Chemical compound O=C\C=C\C=O JGEMYUOFGVHXKV-OWOJBTEDSA-N 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N hydroquinone methyl ether Natural products COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 230000001235 sensitizing effect Effects 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 229940001482 sodium sulfite Drugs 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- PODWXQQNRWNDGD-UHFFFAOYSA-L sodium thiosulfate pentahydrate Chemical compound O.O.O.O.O.[Na+].[Na+].[O-]S([S-])(=O)=O PODWXQQNRWNDGD-UHFFFAOYSA-L 0.000 description 1
- AMZPPWFHMNMIEI-UHFFFAOYSA-M sodium;2-sulfanylidene-1,3-dihydrobenzimidazole-5-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=C2NC(=S)NC2=C1 AMZPPWFHMNMIEI-UHFFFAOYSA-M 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 229940062627 tribasic potassium phosphate Drugs 0.000 description 1
- 229940001496 tribasic sodium phosphate Drugs 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Photographic Processing Devices Using Wet Methods (AREA)
Abstract
Description
【０００１】0001
【産業上の利用分野】本発明は、ハロゲン化銀写真感光
材料の現像処理装置に関するもので、詳しくは自動現像
機への処理液の補充量を低減し、低公害化した補充方法
に関するものである。[Field of Industrial Application] The present invention relates to a developing processing apparatus for silver halide photographic light-sensitive materials, and more particularly to a replenishing method that reduces the amount of processing liquid to be refilled into an automatic developing machine and reduces pollution. be.
【０００２】0002
【発明の背景】ハロゲン化銀写真感光材料の現像処理は
、現像液或は定着液などの処理液を貯留している浴槽中
に、露光後の感光材料を所定時間搬送、浸漬させて処理
しているのが普通である。BACKGROUND OF THE INVENTION The development of silver halide photographic light-sensitive materials is carried out by transporting and immersing the exposed light-sensitive material in a bath containing a processing solution such as a developer or fixer for a predetermined period of time. It is normal to have
【０００３】そのため、貯留されている処理液は、ラン
ニングによって液中の成分、量ともに消費されて疲労劣
化する。[0003] For this reason, the stored processing liquid is consumed by both the components and the amount thereof during running, and deteriorates due to fatigue.
【０００４】例えば現像液のようなアルカリ液の場合に
は、経時で空気中の炭酸ガスを吸収し、中和反応でアル
カリ度を低下して性能が著しく劣化される。For example, in the case of an alkaline solution such as a developer, it absorbs carbon dioxide gas from the air over time, and its alkalinity decreases through a neutralization reaction, resulting in a significant deterioration in performance.
【０００５】このような処理液の疲労、劣化を回復する
方法として例えば特開昭５０−１４４５０２号、同５４
−６２００４号、同５５−１１５０３９号および同５６
−１２６４５号などの各公報には、補充液を現像処理量
に応じて連続的又は間欠的に供給補充することにより、
処理液の疲労劣化を回復する手段が提案されている。[0005] As a method for recovering from such fatigue and deterioration of the processing solution, for example, Japanese Patent Laid-Open Nos. 50-144502 and 54
-62004, 55-115039 and 56
-12645 and other publications, by supplying and replenishing the replenisher continuously or intermittently according to the amount of development processing,
Means for recovering the fatigue deterioration of processing liquids have been proposed.
【０００６】しかし、この現像処理量に応じて、補充液
を補充しオーバーフローする方式では処理液を活性に保
つためには相当量の補充液を補充しなければならず、ま
たそれに応じてオーバーフローした処理液が排液として
生成される。 近年、ハロゲン化銀写真感光材料の処
理排液を低減することが低公害化の上で強く求められて
いる中で、排液又は廃液を生成することは好ましくない
。However, in the method of replenishing and overflowing the replenisher according to the amount of development processing, it is necessary to replenish a considerable amount of replenisher in order to keep the processing solution active, and overflow occurs accordingly. Processing liquid is produced as waste liquid. In recent years, there has been a strong demand for reducing the amount of waste liquid from processing silver halide photographic materials in order to reduce pollution, and it is not desirable to generate waste liquid or waste liquid.
【０００７】従来技術として、処理液の再生による有効
利用及び省資源上からのアプローチとして、例えば定着
液で銀を回収した後、再び定着液として再生使用する特
開昭５３−６０７３１号、同５５−１４８４９号などが
開示されている。As a conventional technique, as an approach from the viewpoint of effective utilization and resource saving by recycling the processing liquid, for example, Japanese Patent Laid-Open No. 53-60731 and No. 55 disclose that silver is recovered in a fixing liquid and then recycled and used again as a fixing liquid. -14849 etc. are disclosed.
【０００８】さらにＥＰ−０３３０４４２号では、カラ
ーペーパー用現像液のオーバーフロー液をカラーネガフ
ィルムの現像浴槽に戻して補充するリサイクルシステム
が開示されている。[0008] Furthermore, EP-0330442 discloses a recycling system in which the overflow liquid of a color paper developer is returned to the color negative film developer bath to replenish it.
【０００９】さらに当写真業界では処理の迅速化、安定
化及び低公害化は重要な課題であり、従来から処理装置
の数多くの研究がなされてきた。しかしながら、コスト
、装置の規模などから実用的なものは少なく、簡易で、
しかも写真性能になんらの悪影響を及ぼすことのない廃
液処理装置の開発が強く望まれていた。[0009]Furthermore, in the photographic industry, speeding up, stabilizing, and reducing pollution of processing are important issues, and many studies have been conducted on processing equipment. However, there are few practical ones due to cost, scale of equipment, etc., and it is simple.
Furthermore, there has been a strong desire to develop a waste liquid treatment device that does not have any adverse effects on photographic performance.
【００１０】0010
【発明の目的】従って本発明の第１の目的は、環境保護
上から写真処理廃液量を低減し、低公害化したハロゲン
化銀写真感光材料の処理装置及び処理液の補充方法を提
供することである。OBJECTS OF THE INVENTION Accordingly, the first object of the present invention is to provide a processing apparatus for silver halide photographic light-sensitive materials and a method for replenishing the processing solution, which reduce the amount of photographic processing waste liquid and reduce pollution from the viewpoint of environmental protection. It is.
【００１１】本発明の第２の目的は、処理液の補充量を
低減しても充分な均一平衡状態を保って現像不足、定着
不良或は固着物の発生などがないハロゲン化銀写真感光
材料の処理装置及び処理液の補充方法を提供することで
ある。A second object of the present invention is to provide a silver halide photographic light-sensitive material that maintains a sufficiently uniform equilibrium state even when the amount of replenishment of processing liquid is reduced, and does not suffer from insufficient development, poor fixing, or the occurrence of fixed substances. An object of the present invention is to provide a processing apparatus and a method for replenishing processing liquid.
【００１２】本発明の第３の目的は、オーバーフローで
廃棄していた従来の処理排液を、再利用し有効活用する
ハロゲン化銀写真感光材料の処理装置及び処理液の補充
方法を提供することである。その他の目的は以下の明細
から明らかとなる。A third object of the present invention is to provide a processing apparatus for silver halide photographic light-sensitive materials and a method for replenishing the processing solution, which reuses and effectively utilizes the conventional processing waste liquid that is discarded due to overflow. It is. Other objectives will become apparent from the description below.
【００１３】[0013]
【発明の構成】上記の本発明の目的は、以下により達成
されることを見い出し本発明を成すに至った。即ち、現
像処理中に処理液槽からオーバーフローしてきた処理液
を、該処理液槽へ再度補充する装置を有するハロゲン化
銀写真感光材料の処理装置及び処理液の補充方法によっ
て達成される。DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention has been accomplished by discovering that the above-mentioned objects of the present invention can be achieved by the following methods. That is, this can be achieved by a processing apparatus for silver halide photographic light-sensitive materials and a method for replenishing the processing liquid, which has a device for replenishing the processing liquid tank with the processing liquid that overflows from the processing liquid tank during the development process.
【００１４】以下、本発明を詳述する。The present invention will be explained in detail below.
【００１５】ハロゲン化銀写真感光材料の現像処理は、
処理液の補充をしながら自動現像機で処理されているの
が一般的である。The development process of silver halide photographic material is as follows:
Generally, the processing is carried out using an automatic processor while replenishing the processing solution.
【００１６】現在の補充方法による処理装置においては
、補充量によりオーバーフローする排液量が決まってく
るので、補充量を低減することにより解決できると考え
られるが、フィルムから処理液への添加剤の放出や、処
理液組成のフィルムへの吸着による処理液の持ち出し、
処理液中の主薬濃度の減少など、処理に充分な均一平衡
状態を保つことは困難である。特に定着液等では定着不
良や、定着槽周辺に固着物の発生など好ましくない状態
が起こり、現状の補充方法では補充量の低減に限界があ
る。In the processing equipment using the current replenishment method, the amount of overflowing liquid is determined by the amount of replenishment, so it is thought that the problem can be solved by reducing the amount of replenishment. removal of the processing solution due to release or adsorption of the processing solution composition onto the film;
It is difficult to maintain a uniform equilibrium state sufficient for processing due to a decrease in the concentration of the active ingredient in the processing solution. In particular, with fixing fluids, etc., undesirable conditions such as poor fixing and the formation of stuck substances around the fixing tank occur, and the current replenishment method has a limit in reducing the amount of replenishment.
【００１７】そこで、処理液の主薬濃度をあげる方法が
考えられる。現像液の場合、現像主薬濃度をあげて平衡
を保つ手段があるが、単に処理液中の主薬濃度を上げる
と画質が劣化する。定着液の場合、定着主薬をより多く
添加して定着力を向上させる方法、定着促進剤を添加す
る方法があるが前者は主薬濃度の溶解度の点から限界が
あり、後者の場合充分な定着促進剤となるものは、まだ
得られていない。[0017] Therefore, a method of increasing the concentration of the main agent in the processing liquid can be considered. In the case of a developing solution, there is a way to maintain equilibrium by increasing the concentration of the developing agent, but simply increasing the concentration of the developing agent in the processing solution deteriorates the image quality. In the case of a fixer, there are two methods: adding more fixing agent to improve the fixing power, and adding a fixing promoter, but the former has a limit due to the solubility of the main agent concentration, and the latter does not promote fixing sufficiently. A drug has not yet been obtained.
【００１８】また、処理枚数が少ない場合、例えば１日
、２日おきに処理するといった状態では処理の安定性が
劣化し、定着槽周辺部での固着物の発生が起こり易くな
る。そのため、処理液の補充は、必須要件となっている
。Further, when the number of sheets to be processed is small, for example, when processing is performed every one or two days, the stability of the processing deteriorates, and the occurrence of stuck substances in the vicinity of the fixing tank is likely to occur. Therefore, replenishment of the processing liquid has become an essential requirement.
【００１９】本発明において、感光材料の処理中に各処
理液槽からオーバーフローしてきた処理液は、その全部
又は一部を再度有効利用するために各処理液槽或は各補
充液槽へ連続的に戻すことに特徴を有する。In the present invention, the processing solution that overflows from each processing solution tank during the processing of photosensitive materials is continuously transferred to each processing solution tank or each replenisher tank in order to reuse all or part of it effectively. It is characterized by returning to
【００２０】本発明において、一度使用された処理液を
再度補充液として利用可能なのは、オーバーフローした
排液中の有効成分が、完全には消費されていないため残
存している有効成分を再度利用することができるからで
ある。[0020] In the present invention, the processing solution that has been used once can be reused as a replenisher because the active ingredients in the overflowing liquid have not been completely consumed, so the remaining active ingredients are used again. This is because it is possible.
【００２１】有効成分は自動現像機によっても異なるが
、現在市販されている自動現像機及びそれに使用されて
いる処理剤では、今まで排液として捨てられていた処理
液は、新液中の有効成分の１／２以上が残っていること
が分かった。これらの有効成分を再利用することは省資
源上或はコスト上からも有益である。Although the effective ingredients differ depending on the automatic processor, in the automatic processors currently on the market and the processing agents used in them, the processing solution that was previously discarded as waste liquid is replaced by the active ingredient in the new solution. It was found that more than 1/2 of the ingredients remained. Reusing these active ingredients is advantageous in terms of resource saving and cost.
【００２２】本発明に係る補充装置は、排液として捨て
てきたオーバーフロー処理液を、従来の補充（供給）新
液とブレンドし再利用することによって、処理液中の有
効成分を無駄なく消費することが可能であり、ハロゲン
化銀感光材料を処理するのに適切な量の処理剤を供給す
ることができる。また、今までより排液量を少なくする
ことができ、無公害な処理装置を提供することができた
。[0022] The replenishment device according to the present invention consumes the active ingredients in the treatment liquid without wasting it by blending and reusing the overflow treatment liquid that has been discarded as waste with the conventional new replenishment (supply) liquid. It is possible to supply an appropriate amount of processing agent for processing the silver halide photosensitive material. Furthermore, the amount of liquid discharged can be reduced compared to before, and a pollution-free treatment device can be provided.
【００２３】本発明に於ける処理液の補充量は現像処理
液の場合、処理される感光材料１ｍ２当たり５００ｍｌ
以下、好ましくは４５０ｍｌ〜１００ｍｌ、特に好まし
くは４００ｍｌ〜１５０ｍｌで実施される。定着液の補
充量は処理される感光材料１ｍ２当たり、８００ｍｌ以
下、好ましくは７００ｍｌ〜２００ｍｌ、特に好ましく
は６００ｍｌ〜３００ｍｌで実施される。In the present invention, the replenishment amount of the processing solution is 500 ml per 1 m2 of the photosensitive material to be processed in the case of the developing processing solution.
Hereinafter, the volume is preferably 450 ml to 100 ml, particularly preferably 400 ml to 150 ml. The fixing solution is replenished in an amount of 800 ml or less, preferably 700 ml to 200 ml, particularly preferably 600 ml to 300 ml, per m2 of photosensitive material to be processed.
【００２４】本発明の処理装置は、感材処理中に処理液
槽からオーバーフローしてきた処理液の一部又は全部を
、再度処理液槽へ補充するために、処理槽から処理剤が
排液としてオーバーフローすることのない処理装置及び
処理液の補充方法でなければならない。In the processing apparatus of the present invention, in order to replenish part or all of the processing solution that has overflowed from the processing solution tank during processing of the sensitive material, the processing agent is discharged from the processing tank as waste liquid. Processing equipment and processing solution replenishment methods must be designed to prevent overflow.
【００２５】ここで言う、処理槽から排液としてオーバ
ーフローすることのないという事は、オーバーフローす
る前に処理槽から処理槽容積より多くなる処理剤を抜き
取り別の槽へ移し変える、又はオーバーフローした処理
液を再度利用するためにオーバーフローした処理液を別
の槽へ移し変える事をいう。ここでいう、別の槽とは補
充液槽であっても処理液を再生するための槽であっても
よい。また、再生する槽から補充液槽へ移し変える工程
があってもよい。尚、ここで言う再生とは■現像液、定
着液中の銀を回収する。■現像液中のハロゲンイオンを
除去する等、処理液の性能を劣化させる因子をとり除く
事をいう。Here, the fact that there is no overflow from the treatment tank as waste liquid means that the treatment agent that exceeds the volume of the treatment tank is removed from the treatment tank before it overflows and transferred to another tank, or the treatment that overflows is prevented. Transferring overflowing processing liquid to another tank in order to use the liquid again. The other tank mentioned here may be a replenisher tank or a tank for regenerating the processing liquid. Further, there may be a step of transferring the liquid from the tank to be regenerated to the replenisher tank. Note that the term "regeneration" as used herein refers to (1) recovery of silver in the developer and fixer; ■Removal of factors that degrade the performance of the processing solution, such as removing halogen ions from the developer.
【００２６】本発明の好ましい実施態様としては、処理
中に排出される排液、或はオーバーフローして排出され
る排液、さらには補充液の添加によって浴槽より排出さ
れる排液などすべて処理中に排出される処理液を補充液
槽又は排液槽に戻す態様である。[0026] In a preferred embodiment of the present invention, all waste liquid discharged during processing, overflowing liquid, and even waste liquid discharged from the bathtub due to addition of replenishing liquid, etc. This is an embodiment in which the processing liquid discharged during the process is returned to the replenishing liquid tank or the draining liquid tank.
【００２７】補充液槽又は排液槽には、処理液槽に連結
した液輸送管によって制御された処理液が供給される。
処理液の疲労度と排液量を感光材料の処理量によって算
出し、自動的に補充量が液送管を通って新しく処理浴槽
に添加注入される態様が最も好ましい。A processing liquid is supplied to the replenishing liquid tank or the draining liquid tank, which is controlled by a liquid transport pipe connected to the processing liquid tank. Most preferably, the degree of fatigue of the processing solution and the amount of drained solution are calculated based on the processing amount of the photosensitive material, and a replenishment amount is automatically added and injected into the processing bath through the solution pipe.
【００２８】本発明に用いられる現像液には、現像剤と
して１、４−ジヒドロキシベンゼン類或は必要に応じて
ｐ−アミノフェノール系現像剤及び又はピラゾリドン類
を含有した現像液がベースとなる。The developer used in the present invention is based on a developer containing 1,4-dihydroxybenzenes or, if necessary, a p-aminophenol developer and/or pyrazolidones.
【００２９】１，４−ジヒドロキシベンゼン現像主薬と
してはハイドロキノン、クロロハイドロキノン、ブロム
ハイドロキノン、イソプロピルハイドロキノン、メチル
ハイドロキノン、２，３−ジクロロハイドロキノン、２
，５−ジクロロハイドロキノン、２，３−ジブロムハイ
ドロキノン、２，５−ジメチルハイドロキノンなどがあ
るが特にハイドロキノンが好ましい。 ｐ−アミノフ
ェノール系現像主薬としてはＮ−メチル−ｐ−アミノフ
ェノール、ｐ−アミノフェノール、Ｎ−（β−ヒドロキ
シエチル）−ｐ−アミノフェノール、Ｎ−（４−ヒドロ
キシフェニル）グリシン、２−メチル−ｐ−アミノフェ
ノール、ｐ−ベンジルアミノフェノール等があるが、な
かでもＮ−メチル−ｐ−アミノフェノールが好ましい。Examples of the 1,4-dihydroxybenzene developing agent include hydroquinone, chlorohydroquinone, bromohydroquinone, isopropylhydroquinone, methylhydroquinone, 2,3-dichlorohydroquinone,
, 5-dichlorohydroquinone, 2,3-dibromohydroquinone, 2,5-dimethylhydroquinone, etc., with hydroquinone being particularly preferred. Examples of p-aminophenol developing agents include N-methyl-p-aminophenol, p-aminophenol, N-(β-hydroxyethyl)-p-aminophenol, N-(4-hydroxyphenyl)glycine, and 2-methyl -p-aminophenol, p-benzylaminophenol and the like, among which N-methyl-p-aminophenol is preferred.
【００３０】本発明に用いることができるピラゾリドン
系化合物としては、例えば１−フェニル−３−ピラゾリ
ドン、１−フェニル−４，４−ジメチル−３−ピラゾリ
ドン、１−フェニル−４−エチル−３−ピラゾリドン、
１−フェニル−５−メチル−３−ピラゾリドン、１−フ
ェニル−４−メチル−３−ピラゾリドン、１−フェニル
−４−メチル−４−ヒドロキシメチル−３−ピラゾリド
ン、１−フェニル−４，４−ジヒドロキシメチル−３−
ピラゾリドン、１，５−ジフェニル−３−ピラゾリドン
、１−ｐ−トリル−３−ピラゾリドン、１−フェニル−
２−アセチル−４，４−ジメチル−３−ピラゾリドン、
１−ｐ−ヒドロキシフェニル−４，４−ジメチル−３−
ピラゾリドン、１−（２−ベンゾチアゾリル）−３−ピ
ラゾリドン、３−アセトキシ−１−フェニル−３−ピラ
ゾリドンなどのピラゾリドン系化合物を挙げることがで
きる。Examples of pyrazolidone compounds that can be used in the present invention include 1-phenyl-3-pyrazolidone, 1-phenyl-4,4-dimethyl-3-pyrazolidone, and 1-phenyl-4-ethyl-3-pyrazolidone. ,
1-phenyl-5-methyl-3-pyrazolidone, 1-phenyl-4-methyl-3-pyrazolidone, 1-phenyl-4-methyl-4-hydroxymethyl-3-pyrazolidone, 1-phenyl-4,4-dihydroxy Methyl-3-
Pyrazolidone, 1,5-diphenyl-3-pyrazolidone, 1-p-tolyl-3-pyrazolidone, 1-phenyl-
2-acetyl-4,4-dimethyl-3-pyrazolidone,
1-p-hydroxyphenyl-4,4-dimethyl-3-
Examples include pyrazolidone compounds such as pyrazolidone, 1-(2-benzothiazolyl)-3-pyrazolidone, and 3-acetoxy-1-phenyl-3-pyrazolidone.
【００３１】本発明に用いられる現像液には、現像処理
中に感光材料中のゼラチンと硬化反応して膜物性を強化
する硬膜剤を含有させることができる。硬膜剤としては
、下記のものを挙げることができる。グルタルアルデヒ
ド、α−メチルグルタルアルデヒド、β−メチルグルタ
ルアルデヒド、マレインジアルデヒド、サクシンジアル
デヒド、メトキシサクシンジアルデヒド、メチルサクシ
ンジアルデヒド、α−メトキシ−β−エトキシグルタル
アルデヒド、α−ｎ−ブトキシグルタルアルデヒド、α
，α−ジメトキシサクシンジアルデヒド、β−イソプロ
ピルサクシンジアルデヒド、α，α−ジエチルサクシン
ジアルデヒド、ブチルマレインジアルデヒド、又はこれ
らの重亜硫酸塩付加物などが用いられる。The developer used in the present invention can contain a hardening agent that hardens and reacts with gelatin in the light-sensitive material during development to strengthen the physical properties of the film. As the hardening agent, the following can be mentioned. Glutaraldehyde, α-methylglutaraldehyde, β-methylglutaraldehyde, maleic dialdehyde, succinic dialdehyde, methoxysuccinic dialdehyde, methylsuccinic dialdehyde, α-methoxy-β-ethoxyglutaraldehyde, α-n-butoxyglutaraldehyde ,α
, α-dimethoxysuccindialdehyde, β-isopropylsuccindialdehyde, α,α-diethylsuccindialdehyde, butylmaleindialdehyde, or bisulfite adducts thereof.
【００３２】本発明に用いられる現像液には、現像主薬
の保恒剤として亜硫酸塩（例えば亜硫酸ナトリウム）を
用いることができる。又、上記成分以外に用いられる添
加剤としては、臭化ナトリウム、沃化カリウムのごとき
現像抑制剤、エチレングリコール、ジエチレングリコー
ル、トリエチレングリコール、ジメチルホルムアミド、
メチルセロソルブ、ヘキシレングリコール、エタノール
、メタノールのごとき有機溶剤、１−フェニル−５−メ
ルカプトテトラゾール、２−メルカプトベンツイミダゾ
ール−５−スルホン酸ナトリウム塩等のメルカプト系化
合物、５−メチルベンツトリアゾール等のベンツトリア
ゾール系化合物などのカブリ防止剤を含んでもよく、更
に必要に応じて色調剤、界面活性剤、消泡剤、硬水軟化
剤、などを含んでもよい。[0032] In the developer used in the present invention, sulfite (eg, sodium sulfite) can be used as a preservative for the developing agent. Additionally, additives used in addition to the above components include development inhibitors such as sodium bromide and potassium iodide, ethylene glycol, diethylene glycol, triethylene glycol, dimethylformamide,
Organic solvents such as methyl cellosolve, hexylene glycol, ethanol, and methanol, mercapto compounds such as 1-phenyl-5-mercaptotetrazole, 2-mercaptobenzimidazole-5-sulfonic acid sodium salt, and benzene such as 5-methylbenztriazole. It may contain an antifoggant such as a triazole compound, and may further contain a toning agent, a surfactant, an antifoaming agent, a water softener, etc., if necessary.
【００３３】現像液のｐＨは、９．０〜１２でよく、好
ましくは９．０〜１１．５の範囲である。The pH of the developer may range from 9.0 to 12, preferably from 9.0 to 11.5.
【００３４】ｐＨの設定のために用いるアルカリ剤又は
緩衝剤としては水酸化ナトリウム、水酸化カリウム、炭
酸ナトリウム、炭酸カリウム、第三リン酸ナトリウム、
第三リン酸カリウムのごときｐＨ調節剤を含む。[0034] Examples of alkaline agents or buffers used for setting pH include sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, tribasic sodium phosphate,
Contains pH adjusting agents such as tribasic potassium phosphate.
【００３５】本発明において、定着液には、アルミニウ
ム化合物、チオ硫酸塩、亜硫酸塩や種々の酸、塩、定着
促進剤、湿潤剤、界面活性剤、キレート剤、硬膜剤等を
含有させることができる。その他定着液、現像液に用い
る添加剤は任意であり、処理条件、例えば液のｐＨや温
度等も任意である。In the present invention, the fixing solution may contain aluminum compounds, thiosulfates, sulfites, various acids, salts, fixing accelerators, wetting agents, surfactants, chelating agents, hardening agents, etc. Can be done. Other additives used in the fixer and developer are arbitrary, and processing conditions such as pH and temperature of the solution are also arbitrary.
【００３６】本発明に用いられるハロゲン化銀写真感光
材料としては、例えば汎用白黒感光材料、Ｘ線用感光材
料、印刷製版用感光材料、マイクロフィルム、カラーリ
バーサル感光材料など広範囲の感光材料に用いることが
できるが、好ましくはＸ線用感光材料のような白黒現像
処理である。The silver halide photographic light-sensitive material used in the present invention can be used in a wide range of light-sensitive materials, such as general-purpose black-and-white light-sensitive materials, X-ray light-sensitive materials, printing plate-making light-sensitive materials, microfilms, and color reversal light-sensitive materials. However, black and white processing such as X-ray photosensitive materials is preferred.
【００３７】本発明に用いられる感光材料のハロゲン化
銀乳剤は、ハロゲン化銀として通常使用される任意のも
のを用いることができる。又、写真乳剤中のハロゲン化
銀粒子の粒子サイズ分布は任意であるが、多分散或は単
分散であってもよい。As the silver halide emulsion of the light-sensitive material used in the present invention, any commonly used silver halide can be used. Further, the grain size distribution of the silver halide grains in the photographic emulsion is arbitrary, and may be polydisperse or monodisperse.
【００３８】写真乳剤中のハロゲン化銀粒子は、立方体
、八面体、１４面体、１２面体のような規則的（ｒｅｇ
ｕｌａｒ）な結晶体を有するものでもよく、又球状、板
状などのような変則的（ｉｒｒｅｇｕｌａｒ）な結晶形
をもつもの、或はこれらの結晶形の複合形をもつもので
もよく、種々の結晶形の粒子の混合から成っていてもよ
い。Silver halide grains in photographic emulsions have regular (regular) shapes such as cubes, octahedrons, tetradecahedrons, and dodecahedrons.
ular crystals, irregular crystal shapes such as spherical, plate-like, etc., or composites of these crystal shapes, and various crystals. It may consist of a mixture of particles of different shapes.
【００３９】又、例えばＰｂＯ のような酸化物結晶と
塩化銀のようなハロゲン化銀結晶を結合させた接合型ハ
ロゲン化銀結晶、エピタキシャル成長をさせたハロゲン
化銀結晶、（例えば臭化銀上に塩化銀、沃臭化銀、沃化
銀等をエピタキシャルに成長させる。）、六方晶形、正
八面体沃化銀に正六面体の塩化銀が配向重複した結晶な
どでもよい。[0039] Also, for example, a junction type silver halide crystal in which an oxide crystal such as PbO 2 and a silver halide crystal such as silver chloride are combined, a silver halide crystal grown epitaxially, (for example, a silver halide crystal grown on silver bromide), (Silver chloride, silver iodobromide, silver iodide, etc. are grown epitaxially.), a hexagonal crystal, a crystal in which a regular hexahedral silver chloride is oriented over a regular octahedral silver iodide, etc. may be used.
【００４０】又、アスペクト比が３以上の平板状粒子が
全投影面積の５０％以上を占めた乳剤を使用してもよい
。
平板状粒子に関しては詳しくは、特開昭５８−１２７９
２１号、同５８−１１３９２７号などに記載されている
。Further, an emulsion may be used in which tabular grains having an aspect ratio of 3 or more account for 50% or more of the total projected area. For details regarding tabular grains, see JP-A-58-1279.
No. 21, No. 58-113927, etc.
【００４１】又、特公昭４１−２０８６号に記載された
内部潜像型ハロゲン化銀粒子と表面潜像型ハロゲン化銀
粒子とを組合せて用いることもできる。It is also possible to use a combination of internal latent image type silver halide grains and surface latent image type silver halide grains described in Japanese Patent Publication No. 41-2086.
【００４２】本発明に用いられる感光材料のハロゲン化
銀粒子は、写真分野でよく知られている中性法、酸性法
、アンモニア法、順混合法、逆混合法、ダブルジェット
法、コントロールド・ダブルジェット法、コンバァージ
ョン法、コア／シェル法などの方法を適用して製造する
ことができる。 又ダブルジェット法の別の形式とし
て異なる組成の可溶性ハロゲン塩を各々独立に添加する
トリプルジェット法（例えば可溶性銀塩、可溶性臭素塩
及び可溶性沃素塩）も用いることができる。又、粒子を
銀イオン過剰の下において形成させる方法（いわゆる逆
混合法）を用いることもできる。さらに同時混合法の一
つの形式としてハロゲン化銀が生成される液相中のｐＡ
ｇを、一定に保ついわゆるコントロールド・ダブルジェ
ット法を用いることもでき、別々に形成した２種以上の
ハロゲン化銀乳剤を混合して用いてもよい。The silver halide grains of the light-sensitive material used in the present invention can be produced by a neutral method, an acid method, an ammonia method, a forward mixing method, a back mixing method, a double jet method, a controlled method, etc., which are well known in the photographic field. It can be manufactured by applying a method such as a double jet method, a conversion method, or a core/shell method. As another form of the double jet method, a triple jet method in which soluble halogen salts of different compositions are added independently (for example, soluble silver salt, soluble bromine salt, and soluble iodine salt) can also be used. Alternatively, a method in which particles are formed in an excess of silver ions (so-called back mixing method) can also be used. Furthermore, as a type of simultaneous mixing method, the pA in the liquid phase in which silver halide is produced is
A so-called controlled double jet method in which g is kept constant may be used, or two or more silver halide emulsions formed separately may be mixed and used.
【００４３】又、これらのハロゲン化銀粒子又はハロゲ
ン化銀乳剤中には、イリジウム、タリウム、パラジウム
、ロジウム、亜鉛、ニッケル、コバルト、ウラン、トリ
ウム、ストロンチウム、タングステン、プラチナの塩（
可溶性塩）の内、少なくとも１種類が含有していてもよ
い。These silver halide grains or silver halide emulsions also contain salts of iridium, thallium, palladium, rhodium, zinc, nickel, cobalt, uranium, thorium, strontium, tungsten, and platinum (
At least one type of soluble salts) may be contained.
【００４４】本発明に用いられるハロゲン化銀写真乳剤
には公知の写真用添加剤を使用することができる。Known photographic additives can be used in the silver halide photographic emulsion used in the present invention.
【００４５】公知の写真用添加剤としては例えば下表に
示したリサーチ・ディスクロヂャーのＲＤ−１７６４３
及びＲＤ−１８７１６に記載の化合物が挙げられる。Examples of known photographic additives include Research Disclosure's RD-17643 shown in the table below.
and the compounds described in RD-18716.
【００４６】
添 加 剤 ＲＤ−
１７６４３ ＲＤ−１８７１６
頁
分類 頁 分類
化学増感剤 ２３ Ｉ
ＩＩ ６４８− 右上 増感色
素 ２３ ＩＶ
６４８右−右上 現像促進剤
２９ ＸＸＩ
６４８− 右上 カブリ防止剤
２４ ＶＩ ６
４９− 右下 安定剤
〃
〃 色汚染防止剤 ２５
ＶＩＩ ６５０− 左−右 画
像安定剤 ２５ ＶＩＩ
紫外線呼吸剤 ２５〜２６ ＶＩ
Ｉ ６４９右〜６５０左 フィル
ター染料 〃
〃 増白剤
２４ Ｖ 硬化剤
２６ Ｘ
６５１左 塗布助剤 ２６〜
２７ ＸＩ ６５０右
界面活性剤 ２６〜２７ ＸＩ
６５０右 可塑剤
２７ ＸＩＩ
〃 スベリ剤
〃 スタチック防止剤 ２７
ＸＩＩ ６５０右 マ
ット剤 ２８ ＸＶ
Ｉ ６５０右 バインダー
２６ ＩＸ
６５１左Additive RD-
17643 RD-18716
Page classification Page classification
Chemical sensitizer 23 I
II 648- Upper right sensitizing dye 23 IV
648 Right-Top Right Development Accelerator
29 XXI
648- Upper right antifoggant
24 VI 6
49- Lower right stabilizer
〃
〃 Color stain prevention agent 25
VII 650- Left-Right Image Stabilizer 25 VII
UV breathing agent 25-26 VI
I 649 right ~ 650 left filter dye
〃 Whitening agent
24 V hardener
26 X
651 left Application aid 26~
27 XI 650 right
Surfactant 26-27 XI
650 right plasticizer
27 XII
〃 Slip agent
〃 Static inhibitor 27
XII 650 right matting agent 28 XV
I 650 right binder
26 IX
651 left
【００４７】[0047]
【実施例】以下本発明の実施例について説明する。但し
当然のことではあるが、本発明は以下述べる実施例によ
り限定されるものではない。[Examples] Examples of the present invention will be described below. However, it goes without saying that the present invention is not limited to the examples described below.
【００４８】実施例１
医療用Ｘ線フィルムのＳＲ−Ｇ（四ツ切）（コニカ〔株
〕製）を用いて１日に１００枚のランニング処理を行っ
た。Example 1 Using medical X-ray film SR-G (four-cut) (manufactured by Konica Corporation), 100 sheets were subjected to running treatment in one day.
【００４９】処理は下記の処理液を用い、図１に示した
処理液槽を備えた自動現像機を使用した。The processing was carried out using the following processing solution and an automatic developing machine equipped with the processing solution tank shown in FIG.
【００５０】図１（Ａ）は従来の自動現像機の処理液槽
と補充液槽を示した構成図で、（Ｂ）は本発明に係る自
動現像機の処理液槽と補充液槽を示した構成図である。FIG. 1(A) is a block diagram showing a processing liquid tank and a replenisher tank of a conventional automatic processor, and FIG. 1(B) shows a processing liquid tank and a replenisher tank of an automatic processor according to the present invention. FIG.
【００５１】図に於いて（１）は処理液槽を示しでおり
、（２）は補充液槽である。この（２）槽は（３）及び
（４）に示される液輸送管により結ばれている。この（
３）は補充液槽より補充液を処理液槽へ供給するための
液輸送管であり、（４）は処理液槽より補充液槽へ処理
液を供給するための液輸送管である。In the figure, (1) shows a processing liquid tank, and (2) shows a replenishing liquid tank. This (2) tank is connected by a liquid transport pipe shown in (3) and (4). this(
3) is a liquid transport pipe for supplying replenisher from the replenisher tank to the processing liquid tank, and (4) is a liquid transport pipe for supplying the processing liquid from the processing liquid tank to the replenisher tank.
【００５２】従って、処理液槽中にある処理液は、補充
液槽から補充液が供給されてもすぐに排液となることな
く、その有効成分が補充液として再利用可能になる。Therefore, even if the replenisher is supplied from the replenisher tank, the processing liquid in the processing liquid tank is not immediately drained, and its active ingredients can be reused as a replenisher.
【００５３】処理液の補充は表１に示した量を現像液と
定着液にそれぞれ補充した。The processing solution was replenished in the amounts shown in Table 1 to the developer and fixer.
【００５４】（現像液）
亜硫酸カリウム
７０ｇヒドロキシエチルエチレン
ジアミン
三酢酸三ナトリウム
８ｇ１，４−ジヒドロキシベンゼン
２８ｇ硼酸
１０ｇ５−メチルベンゾトリア
ゾール ０．０４ｇ１−フ
ェニル−５−メルカプトテトラゾール ０．０
１ｇメタ重亜硫酸ナトリウム
５ｇ酢酸（９０％）
１３
ｇトリエチレングリコール
１５ｇ１−フェニル−３−ピラゾリドン
１．２ｇ５−ニトロ
インダゾール
０．２ｇグルタルアルデヒド
４ｇエチレンジアミン
四酢酸２ナトリウム ２ｇ臭化カリ
ウム
４ｇ５−ニトロベンゾイミダゾール
１ｇ１ｌの水溶液に
し、水酸化ナトリウムでｐＨ１０．５の液とした。(Developer) Potassium sulfite
70g hydroxyethylethylenediaminetriacetic acid trisodium
8g 1,4-dihydroxybenzene 28g boric acid
10g 5-methylbenzotriazole 0.04g 1-phenyl-5-mercaptotetrazole 0.0
1g sodium metabisulfite
5g acetic acid (90%)
13
gtriethylene glycol
15g 1-phenyl-3-pyrazolidone 1.2g 5-nitroindazole
0.2g glutaraldehyde
4g Disodium ethylenediaminetetraacetic acid 2g Potassium bromide
4g5-nitrobenzimidazole
This was made into a 1 g 1 liter aqueous solution, and adjusted to pH 10.5 with sodium hydroxide.
【００５５】（定着液）
チオ硫酸ナトリウム−５水塩
４５ｇエチレンジアミン四酢酸２ナトリ
ウム ０．５ｇチオ硫酸アンモニウム
１５０
ｇ無水亜硫酸ナトリウム
８ｇ酢酸カリウム
１６ｇ硫酸アルミニウム１０〜１８水塩
１０ｇ硫酸（５０ｗｔ％）
５ｇクエン酸
１ｇ硼酸
７ｇ氷酢酸
５ｇ１ｌの水溶液にして氷酢酸を用いてｐ
Ｈを４．２とした。(Fixer) Sodium thiosulfate pentahydrate
45g Disodium ethylenediaminetetraacetic acid 0.5g Ammonium thiosulfate 150
g Anhydrous sodium sulfite
8g potassium acetate
16g Aluminum sulfate 10-18 hydrate
10g sulfuric acid (50wt%)
5g citric acid
1g boric acid
7g glacial acetic acid
Make 5g1l of an aqueous solution and add p
H was set to 4.2.
【００５６】尚、フィルムの現像は全処理時間が４５秒
であるローラー搬送型自動現像機による下記の処理工程
に従った。The film was developed according to the following processing steps using a roller conveyance type automatic developing machine with a total processing time of 45 seconds.
【００５７】
ランニング処理特性としては、スタート時と終了時
でのフィルムの感度、未露光部の残留銀量及び定着液槽
周辺部の固着物の有無を測定した。As for the running processing characteristics, the sensitivity of the film at the start and end, the amount of residual silver in the unexposed area, and the presence or absence of fixed substances around the fixer tank were measured.
【００５８】〔感度の評価方法〕感度の評価方法は、得
られた試料をＸ線写真用増感紙ＫＯ−２５０（コニカ〔
株〕製）ではさみ、ペネトロメーターＢ型（コニカメデ
ィカル〔株〕製）を介してＸ線照射後、本発明の現像処
理方法にて現像処理を行い、各試料について得られた特
性曲線からベース濃度＋カブリ濃度＋１．０における露
光量を求め、試料Ｎｏ．１の感度を１００として相対感
度で評価した。[Method for evaluating sensitivity] The method for evaluating sensitivity was to use an X-ray photographic intensifying screen KO-250 (Konica [
After X-ray irradiation using scissors (manufactured by Konica Medical Co., Ltd.) and X-ray irradiation using a penetrometer type B (manufactured by Konica Medical Co., Ltd.), development processing was performed using the development processing method of the present invention, and from the characteristic curves obtained for each sample. The exposure amount at base density + fog density + 1.0 was determined, and sample No. Relative sensitivity was evaluated with the sensitivity of 1 being 100.
【００５９】〔残留銀量の評価方法〕前記で作成した試
料を未露光のまま現像処理して残留銀評価用の試料を得
た。残留銀の評価は次の方法で行った。[Method for evaluating residual silver amount] The sample prepared above was developed without being exposed to light to obtain a sample for evaluation of residual silver. Evaluation of residual silver was performed by the following method.
【００６０】硫化ナトリウムの２．６×１０−３ｍｏｌ
／ｌ水溶液を残留銀評価液として上記の残留銀評価用フ
ィルム上に１滴滴下し、３分間保置後、液をよく拭きと
って、常温常湿下で１５時間放置した。2.6×10-3 mol of sodium sulfide
One drop of the /l aqueous solution as a residual silver evaluation solution was dropped onto the above film for residual silver evaluation, and after standing for 3 minutes, the liquid was thoroughly wiped off and left at room temperature and humidity for 15 hours.
【００６１】その後、ＰＤＡ−６５型濃度計（コニカ〔
株〕製）を用いて残留銀評価液を滴下した部分と、滴下
しない部分のブルー光の透過濃度を測定し、その差を持
って残留銀の目安とした。値が０．０３以下であれば問
題なく、それ以上であると銀画像が経時で変色したり濃
度低下を引き起こす。After that, PDA-65 type densitometer (Konica [
The transmittance density of blue light was measured in the area where the residual silver evaluation solution was dropped and the area where it was not dropped, and the difference was used as a measure of the residual silver. If the value is 0.03 or less, there is no problem; if it is more than 0.03, the silver image will discolor over time or cause a decrease in density.
【００６２】〔固着物の評価方法〕表中の固着物の評価
は、◎印は定着液槽のスクイズローラー部に固着物が全
く認められないことを表し、○印はほとんど認められな
い事を表す。×印は固着物の発生が認められ×の数が多
くなる程その程度が悪いことを意味する。得られた結果
を次の表１に示す。[Method for evaluating adhered substances] In the evaluation of adhered substances in the table, ◎ indicates that no adhered substances are observed on the squeeze roller part of the fixer tank, and ○ indicates that almost no adhered substances are observed. represent. The x mark indicates that the occurrence of adhered substances is observed, and the greater the number of x marks, the worse the degree of the occurrence. The results obtained are shown in Table 1 below.
【００６３】[0063]
【表１】[Table 1]
【００６４】[0064]
【表２】[Table 2]
【００６５】表１から明らかなように、比較試料に較べ
て本発明に係る試料は、補充量を減少しても感度の劣化
が少なく、定着不良に基づく残留銀と固着物の発生が僅
かであることが分かる。なお、リサイクルにより、処理
面積の１．５倍の性能を維持できるとすれば、見かけの
２／３量が事実上の補充量となる。As is clear from Table 1, compared to the comparative samples, the samples according to the present invention show less deterioration in sensitivity even when the amount of replenishment is reduced, and the generation of residual silver and fixed substances due to poor fixing is slight. I understand that there is something. Note that if the performance of 1.5 times the processing area can be maintained through recycling, the apparent 2/3 amount will be the de facto replenishment amount.
【００６６】実施例２
実施例１と同様な処理工程、処理装置にて次の表２に示
すような経時ランニング処理（１日おきに２ｍ２ずつ処
理）を行った場合のフィルムの感度、未露光部の残留銀
量及び定着液槽周辺部の固着物の有無を測定した。得ら
れた結果を次の表２に示したが、本発明に係る試料は、
苛酷な経時ランニング処理を行っても感度低下が少なく
、かつ残留銀や固着物がほとんど認められなかった。Example 2 Sensitivity of film and unexposed film when subjected to time running treatment (processed by 2 m2 every other day) as shown in Table 2 using the same processing steps and processing equipment as in Example 1. The amount of residual silver in the area and the presence or absence of fixed substances around the fixer tank were measured. The results obtained are shown in Table 2 below, and the samples according to the present invention were
Even after a severe running treatment over time, there was little decrease in sensitivity, and almost no residual silver or deposits were observed.
【００６７】[0067]
【表３】[Table 3]
【００６８】[0068]
【表４】[Table 4]
【００６９】[0069]
【発明の効果】本発明により、処理剤の経時保存性が良
く、かつ写真性能を劣化することのない処理装置及び処
理液補充方法を得られた。又、本発明により処理槽中で
の固化物の付着或は定着不良による残留銀の発生のない
装置を提供できた。Effects of the Invention According to the present invention, a processing device and a processing solution replenishment method have been obtained in which a processing agent has good storage stability over time and does not cause deterioration in photographic performance. Further, according to the present invention, it was possible to provide an apparatus that does not generate residual silver due to adhesion of solidified substances or poor fixation in the processing tank.
図１は本発明の実施例に用いた自動現像機の処理液槽と
補充液槽を示した構成図である。（Ａ）は従来の装置で
、（Ｂ）は本発明の処理液槽と補充液槽である。FIG. 1 is a block diagram showing a processing liquid tank and a replenishing liquid tank of an automatic processor used in an embodiment of the present invention. (A) is a conventional device, and (B) is a processing liquid tank and a replenishing liquid tank of the present invention.
Claims (1)
してきた処理液を、該処理液槽へ再度補充する装置を有
することを特徴とするハロゲン化銀写真感光材料の処理
装置及び処理液の補充方法。1. Processing apparatus for silver halide photographic light-sensitive materials and replenishment of processing liquid, characterized by having a device for replenishing the processing liquid tank with processing liquid overflowing from the processing liquid tank during development processing. Method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3283591A JPH04271345A (en) | 1991-02-27 | 1991-02-27 | Device for processing silver halide photographic sensitive material and method for replenishing processing liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3283591A JPH04271345A (en) | 1991-02-27 | 1991-02-27 | Device for processing silver halide photographic sensitive material and method for replenishing processing liquid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04271345A true JPH04271345A (en) | 1992-09-28 |
Family
ID=12369878
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3283591A Pending JPH04271345A (en) | 1991-02-27 | 1991-02-27 | Device for processing silver halide photographic sensitive material and method for replenishing processing liquid |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04271345A (en) |
-
1991
- 1991-02-27 JP JP3283591A patent/JPH04271345A/en active Pending
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