JPH04187580A - Production of ceramic product using colored glazing grain - Google Patents
Production of ceramic product using colored glazing grainInfo
- Publication number
- JPH04187580A JPH04187580A JP31320090A JP31320090A JPH04187580A JP H04187580 A JPH04187580 A JP H04187580A JP 31320090 A JP31320090 A JP 31320090A JP 31320090 A JP31320090 A JP 31320090A JP H04187580 A JPH04187580 A JP H04187580A
- Authority
- JP
- Japan
- Prior art keywords
- glaze
- mol
- colored
- grains
- viscosity index
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 27
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000000203 mixture Substances 0.000 claims abstract description 18
- 239000010438 granite Substances 0.000 claims abstract description 12
- 239000000049 pigment Substances 0.000 claims abstract description 12
- 239000002245 particle Substances 0.000 claims description 47
- 238000010304 firing Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 8
- 239000003082 abrasive agent Substances 0.000 claims description 2
- 239000006063 cullet Substances 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- 239000004576 sand Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052681 coesite Inorganic materials 0.000 abstract description 4
- 229910052593 corundum Inorganic materials 0.000 abstract description 4
- 229910052906 cristobalite Inorganic materials 0.000 abstract description 4
- 239000000377 silicon dioxide Substances 0.000 abstract description 4
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 4
- 229910052682 stishovite Inorganic materials 0.000 abstract description 4
- 229910052905 tridymite Inorganic materials 0.000 abstract description 4
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract description 4
- 150000001875 compounds Chemical class 0.000 abstract 2
- 238000001354 calcination Methods 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 8
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 6
- BYFGZMCJNACEKR-UHFFFAOYSA-N aluminium(i) oxide Chemical compound [Al]O[Al] BYFGZMCJNACEKR-UHFFFAOYSA-N 0.000 description 6
- 239000000155 melt Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000011449 brick Substances 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 3
- 239000012463 white pigment Substances 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- -1 ZrQ2 Chemical compound 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- 244000155172 Podocarpus elatus Species 0.000 description 1
- 235000003209 Podocarpus elatus Nutrition 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000001058 brown pigment Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- WHOPEPSOPUIRQQ-UHFFFAOYSA-N oxoaluminum Chemical compound O1[Al]O[Al]1 WHOPEPSOPUIRQQ-UHFFFAOYSA-N 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野コ
本発明は、表面に複数の着色釉粒よりなる斑点模様又は
御影模様の付いた陶磁器製品の製造方法に関するもので
ある。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a method for manufacturing a ceramic product whose surface has a spotted or granite pattern made of a plurality of colored glaze grains.
［従来の技術］
従来、陶磁器表面の装飾は、単一の釉薬だけを施釉し、
焼成することにより行われてきた。[Prior art] Traditionally, the surface of ceramics was decorated with only a single glaze.
This has been done by firing.
もっとも最近は、印刷による絵柄装飾、転写紙による模
様付けのほか、色の異なる複数の釉を多層に又は同時に
施釉したり、釉薬中に不溶性（耐火性）の粒子を分数さ
せたものを陶磁器表面に施し、焼成することによってそ
の表面に凹凸状の斑点模様を得ること等も行われるよう
になっている。Most recently, in addition to pattern decoration by printing and patterning with transfer paper, ceramic surfaces have been decorated with glazes of different colors in multiple layers or simultaneously, and with a fraction of insoluble (fire-resistant) particles in the glaze. It has also become possible to obtain uneven speckled patterns on the surface by applying it to the surface and firing it.
［発明が解決しようとする課題］
単一の釉薬を施す場合、陶磁器の表面は、単一の釉薬の
色を示すだけであり、また軸中に不溶性の粒子を分散さ
せた場合も粒子の粒径によって多少の差はあっても凹凸
状の斑点模様となるのみであり、近年の需要家の高級指
向、個性化指向、価値観の多様化等に対応した多色の斑
点模様や、御影模様等の複雑な模様を得ることは不可能
であった。[Problem to be solved by the invention] When a single glaze is applied, the surface of the ceramic only shows the color of the single glaze, and when insoluble particles are dispersed in the shaft, the color of the particles is also different. Even if there are some differences depending on the diameter, the pattern is only uneven and speckled.In recent years, multicolored speckled patterns and granite patterns have been created in response to consumers' preference for luxury, individualization, and diversification of values. It was impossible to obtain such complex patterns.
本発明は、従来の上記欠点を改良したものであって、陶
磁器の表面に特定の物性をもった着色釉粒を塗布した後
、焼成することによって陶磁器表面を装飾しようとする
ものであり、着色釉粒の物性（熔融粘性、粒径等）によ
って斑点模様又は御影模様等の多様な装飾を施した陶磁
器製品を得ようとするものである。The present invention improves the above-mentioned drawbacks of the conventional art, and attempts to decorate the surface of ceramics by applying colored glaze grains with specific physical properties to the surface of ceramics and then firing them. The aim is to obtain ceramic products with various decorations such as speckled patterns or granite patterns depending on the physical properties of the glaze particles (melt viscosity, particle size, etc.).
［課題を解決するための手段］
すなわち、本発明の方法は、
釉！ＪＡＦｉ５．がゼーゲル表示で示して、Ａ） Ａ
ｌ２Ｏ３０，５〜０９、ＳｉＯ２０５〜７、Ｒ’ＯＯ，
５〜１．０ 及びＲ２２００〜０．５であって、使用
温度１囲で粘性指数８〜１１のもの、
Ｂ） Ａｌ２Ｏ３０，２〜０．６．５１０２０゜５〜
７、Ｒ’ＯＯ，５〜１０ 及びＲ２２Ｏ０〜０．５であ
って、使用温度１囲で粘性指数５〜８のもの並びに
Ｃ） Ａｌ２Ｏ３０〜０．４、Ｓｉ０，０５〜７、
Ｒ１Ｏ０．５〜１．０ 及びＲ２２００〜０．５であ
って、使用温度１囲で粘性指数２〜５のもの
からなる群より選ばれた一種以上の基礎釉に着色顔料を
加えて得た着色釉粒の２種以上を糾み合わせて陶磁器素
地に施釉し、焼成することにより斑点又は御影模様の陶
磁器製品を得るものである。[Means for solving the problem] That is, the method of the present invention is: Glaze! JAFi5. is shown in Segel representation, A) A
l2O30,5~09, SiO205~7, R'OO,
5 to 1.0 and R2200 to 0.5, and a viscosity index of 8 to 11 at a working temperature of 1, B) Al2O30.2 to 0.6.51020°5 to
7, R'OO, 5-10 and R22O0-0.5, with a viscosity index of 5-8 at one temperature of use, and C) Al2O30-0.4, Si0,05-7,
Coloring obtained by adding a coloring pigment to one or more basic glazes selected from the group consisting of those with an R1O of 0.5 to 1.0 and an R2200 to 0.5 and a viscosity index of 2 to 5 at a working temperature of 1. Two or more types of glaze grains are mixed together, glazed on a ceramic base, and fired to obtain a ceramic product with a spotted or granite pattern.
本発明で用いる着色釉粒は、その−個か単色の単一粒あ
るいは一個の釉粒の中に複数の色釉か混ざったいわゆる
複合粉からなっていてもよい。The colored glaze grains used in the present invention may be composed of a single grain of a single color or a so-called composite powder in which a plurality of colored glazes are mixed in one glaze grain.
釉組成を構成する成分のうちではＡｌ２Ｏ３の量か特に
重要であり、Ａ）０．５〜０９モル、Ｂ）０．２〜０．
６モル及びＣ）Ｏ〜０４モルの３種のものが用いられる
。このＡｌ２Ｏ２の量は、８５０〜１３００℃の使用温
度範囲で釉粒の熔融粘性を、それぞれ釉粒の粘性指数範
囲であるＡ）８〜１１、Ｂ）５〜８及びＣ）２〜５に保
つことと関連して必要な条件であり、それぞれ下限のモ
ル数より小さいと粘性が小さすぎ、また上限のモル数よ
り大きいと粘性が大となりすぎるか、または釉粒が熔融
し難くなり、所期の斑点模様又は御影模様が得られない
のである。Among the components constituting the glaze composition, the amount of Al2O3 is particularly important; A) 0.5-0.09 mol, B) 0.2-0.00 mol.
Three types are used: 6 mol and C)O~04 mol. This amount of Al2O2 maintains the melt viscosity of the glaze particles within the viscosity index ranges of A) 8 to 11, B) 5 to 8, and C) 2 to 5 within the operating temperature range of 850 to 1300°C. These are necessary conditions in connection with this. If the number of moles is smaller than the lower limit, the viscosity will be too low, and if the number of moles is larger than the upper limit, the viscosity will be too high or the glaze particles will be difficult to melt, making it difficult to melt as desired. Therefore, it is not possible to obtain a speckled pattern or a granite pattern.
また、５ｉ０２の量については、特に目的とする模様現
出との関係では特に限定の必要はないか、８５０〜１３
００℃という使用温度１囲での釉粒の耐火度調整のため
０１５〜７モルとするのが好ましいので、本発明ではこ
の範囲で使用することとした。Also, regarding the amount of 5i02, there is no need to limit it especially in relation to the desired pattern appearance.850-13
In order to adjust the fire resistance of the glaze grains at a working temperature of 100° C., it is preferable to set the amount to 0.15 to 7 mol, so in the present invention, it is used within this range.
なお、その他の成分としては、Ｒ’ＯとしてＣａＯｌＭ
ｇＯ，Ｂａｄ、ＳｒＯ，ＺｎＯ及びＰｂＯ等が、またＲ
２□０としてはＬ１２０、Ｋ２Ｏ及びＮａ２Ｏがあり、
そのほかＳｎＯ２、ＴｉＯ２、ＺｒＱ２及びＢ２Ｏ３等
の酸性成分、及び■、Ｍｏ、ＷｌＹ及びＢｉ等の酸化物
を含んでいてもよい。In addition, other components include CaOIM as R'O.
gO, Bad, SrO, ZnO, PbO, etc. are also R
2□0 includes L120, K2O and Na2O,
In addition, it may contain acidic components such as SnO2, TiO2, ZrQ2, and B2O3, and oxides such as (2), Mo, WlY, and Bi.
ところで、本発明では、いずれにしても、着色釉粒の熔
融粘性の差を利用することによって多様な模様を現出さ
せるものであるが、着色釉粒を用いると、複数の色釉を
用いる場合よりも混合しやすく、施釉工稈の単純化が可
能であり、更に乾式施釉ができるため、エネルギー節減
、作業環境の美化等の利点がある。By the way, in the present invention, various patterns are created by utilizing the difference in melt viscosity of colored glaze grains, but when colored glaze grains are used, when a plurality of colored glazes are used, It is easier to mix than conventional glazes, the glazing process can be simplified, and dry glazing can be performed, which has the advantage of saving energy and making the work environment more beautiful.
また、この着色釉粒は、従来から行われている釉薬泥漿
中に分散させて施釉することも可能である。The colored glaze particles can also be dispersed in a glaze slurry, which is a conventional method, for glazing.
さらに、必要に応じて雲母、砂、ガラスカレット、砥材
又は鉱物粒等を添加成分として糾み合わせ使用すること
もできる。Furthermore, if necessary, mica, sand, glass cullet, abrasive material, mineral grains, etc. may be used in combination as additional components.
着色釉粒を用いることを特徴とする本発明において、着
色釉粒の物性は特に重要な条件である。In the present invention, which is characterized by using colored glaze particles, the physical properties of the colored glaze particles are particularly important conditions.
着色釉粒の熔融粘性は模様の多様性を与える。The melt viscosity of the colored glaze particles gives a variety of patterns.
釉粒の粘性は、一般に焼成温度と関係かあり、釉粒の化
学糺成によって様々な異なった挙動を示すものである。The viscosity of glaze grains is generally related to the firing temperature, and exhibits various different behaviors depending on the chemical bonding of the glaze grains.
この釉粒の熔融粘性は、一般に傾斜式ボタンテストによ
って測られているか、この傾斜式ボタンテストとは、水
平面に対して一定の角度に傾斜させた陶磁器素地の上に
、一定の大きさの円柱状のボタンに成形された釉薬を載
せ所定温度で焼成後、熔融したボタン状の釉薬が斜面に
７台って流下したときの拡がり幅を測定する方法である
。The melt viscosity of glaze grains is generally measured by the tilt button test.The tilt button test consists of measuring a circle of a certain size on a ceramic base tilted at a certain angle with respect to the horizontal plane. In this method, a shaped glaze is placed on a columnar button and fired at a predetermined temperature, and then the spread width is measured when the molten button-shaped glaze flows down a slope.
そして、このテストでは、ボタンの拡がり幅をＬとする
ときの１００／Ｌを粘性指数としてその粘性を示す尺度
としているか、本発明における粘性指数もこのテストに
よって得られた値である。In this test, 100/L, where L is the spread width of the button, is used as a viscosity index to indicate the viscosity, and the viscosity index in the present invention is also a value obtained by this test.
本発明者は、釉粒の焼成温度１囲内での粘性の差に着眼
し、更に粘性差を、釉粒の化学組成によって調整、制御
することにより、多様な装飾模様を得ることに成功した
ものである。The present inventor focused on the difference in viscosity of glaze grains within one range of firing temperature, and by further adjusting and controlling the viscosity difference by the chemical composition of glaze grains, the inventor succeeded in obtaining a variety of decorative patterns. It is.
各々の着色釉粒の組み合わせについて説明すると、
まず、熔融粘性の大きい着色釉粒を組み合わせた場合の
陶磁器表面の状態では、釉粒は、焼成によって熔融はし
ても各々の釉粒の粘性か大なるため各釉粒同士が混ざり
合わず、陶磁器表面には、境界の明瞭な斑点模様が現出
する。To explain the combination of each colored glaze grain, first, the state of the ceramic surface when colored glaze grains with high melt viscosity are combined, even if the glaze grains are melted by firing, the viscosity of each glaze grain is large. As a result, the glaze grains do not mix with each other, and a spotted pattern with clear boundaries appears on the ceramic surface.
また、熔融粘性の比較的大きい着色釉粒と熔融粘性の比
較的小さい着色釉粒とを糺み合わせた場合の状態では、
釉粒は焼成によって着色釉粒が境界で混ざり合ったり、
また熔融粘性の大きな釉粒の周囲を熔融粘性の小さな釉
粒の融液がとりまいたり、熔融粘性の大きな釉粒の間に
熔融粘性の小さな釉粒の融液が浸透しており、御影模様
が陶磁器表面に現れるのである。In addition, when colored glaze grains with relatively high melt viscosity and colored glaze grains with relatively low melt viscosity are glued together,
As the glaze grains are fired, the colored glaze grains mix together at the boundaries,
In addition, the glaze particles with large melt viscosity are surrounded by the melt of glaze particles with small melt viscosity, and the melt of glaze particles with small melt viscosity permeates between the glaze particles with large melt viscosity, resulting in a granite pattern. appears on the surface of the ceramic.
ここで、粒径や粒子の形状の差は、模様の大きさや複雑
さに影響を与えるが、これらは、着色釉粒の軟化温度と
熔融粘性との関連で適宜選択することが可能であるが、
粒径は、０．１ｍｍ〜３０ｍｍ程度が好ましく、形状と
しても特に限定はされないが、球状、板状、塊状等が好
ましい。Here, differences in particle size and particle shape affect the size and complexity of the pattern, but these can be selected appropriately in relation to the softening temperature and melt viscosity of the colored glaze particles. ,
The particle size is preferably about 0.1 mm to 30 mm, and the shape is not particularly limited, but spherical, plate-like, block-like, etc. are preferable.
着色釉粒の塗布方法は、陶磁器の乾燥素地に必要に応し
て下釉を流し掛け、スプレー掛け、浸漬掛は等によって
施し、その上へ必要に応じて接着剤、粘結剤を塗布後、
着色釉粒を散布し素地に接着させるのが適当であるか、
着色釉粒子に予め接着剤を付与させたり、着色釉粒を陶
磁器の乾燥素地上へ散布後接着剤を上から施すこと等の
方法も可能である。The method of applying colored glaze particles is to pour the underglaze onto the dry base of ceramics as necessary, apply it by spraying, dipping, etc., then apply adhesive or binder on top of it as necessary. ,
Is it appropriate to scatter colored glaze grains and adhere them to the base material?
It is also possible to apply an adhesive to the colored glaze particles in advance, or to spread the colored glaze particles onto a dry base of ceramics and then apply an adhesive from above.
また着色釉粒や下釉あるいは接着剤に界面活性剤等を添
加することによって、さらに模様に変化を与えることも
可能である。It is also possible to further change the pattern by adding a surfactant or the like to the colored glaze particles, underglaze, or adhesive.
さらに、本発明では、上記したように８５０〜１３００
℃での焼成を予定して着色釉粒を調製しているので、か
かる温度範囲で焼成される陶磁器製品に広く適用され、
例えば１２５０〜１３００℃で焼成される外装タイル、
洋食器、衛生陶器等、８５０〜１２００°Ｃで焼成され
る内装タイル、屋根瓦、レンガ、等の製造の際の模様現
出に利用できるのである。Furthermore, in the present invention, as described above, 850 to 1300
Since the colored glaze grains are prepared with the intention of firing at ℃, it can be widely applied to ceramic products that are fired in this temperature range.
For example, exterior tiles fired at 1250-1300°C,
It can be used to create patterns in the production of Western tableware, sanitary ware, interior tiles, roof tiles, bricks, etc. that are fired at 850 to 1200°C.
［実施例］ 以下実施例により本発明を更に詳しく説明する。[Example] The present invention will be explained in more detail with reference to Examples below.
実施例１
１）’ｓ％の白色顔料を含み白に着色されたＡｌｚＯ３
０，８モル、ＳｉＯ２２，５モル、Ｃａ００．４２モル
、Ｂａ０Ｏ，０６モル、ＭｇＯ０，０８モル、Ｚｎ００
．２４モル及びＫｚＯ十ＮＡ２０ ｏ、２０モルの釉
組成を有し、粘性指数１０，１で粒径０．５〜２ｍｍの
釉粒の６５％と、
Ａ２）７％のグレー顔料を含みグレーに着色されたＡ１
２０３０．６５モル、ＳｉＯ２２，７モル、Ｃａ００．
５０モル、ＢａＯ０，０５モル、Ｍｇ００．１１モル、
ＺｎＯ０，１４モル及びに２０ ＋ Ｎ ａ ２０ ０
． ２０モルの釉組戎を有し、粘性指数９．９で粒径０
．５〜２ｍｍの釉粒の３０％と、
Ｂ１）８％の黒顔料を含み黒に着色されたＡ１２０３０
．５５モル、５ｉＯｚ２．０モル、Ｃａ００．４０モル
、ＢａＯ０，１０モル、Ｍｇ００．１５モルＺｎＯ０，
２０モル及びに２０ ＋ Ｎ ａ ２０ ０ 、 １５
モルの釉糺成を有し、粘性指数７．８で粒径０１〜３ｍ
ｍの釉粒の５％とを
あらかじめ混合しておく。Example 1 1) AlzO3 colored white containing 's% white pigment
0.8 mol, SiO2 2.5 mol, Ca00.42 mol, Ba0O,06 mol, MgO0.08 mol, Zn00
．． It has a glaze composition of 24 mol and 20 mol of KzO and 20 mol of KzO, and contains 65% of the glaze grains with a viscosity index of 10.1 and a particle size of 0.5 to 2 mm, and A2) 7% of gray pigment, colored gray. A1
2030.65 mol, SiO2 2.7 mol, Ca00.
50 mol, BaO 0.05 mol, Mg 00.11 mol,
ZnO 0.14 mol and 20 + Na 20 0
．． It has a 20 mol glaze, a viscosity index of 9.9 and a particle size of 0.
．． A12030 colored black, containing 30% of 5-2mm glaze grains and B1) 8% black pigment.
．． 55 mole, 5iOz2.0 mole, Ca00.40 mole, BaO0.10 mole, Mg00.15 mole ZnO0,
20 mol and 20 + N a 20 0, 15
It has a glaze composition of mol, a viscosity index of 7.8, and a particle size of 01 to 3 m.
Mix in advance with 5% of the glaze particles of m.
乾燥タイル素地上に接着剤（水溶性セルロースの２％水
溶液）を塗布し、その後あらかしめ混合された着色釉粒
を散布し、ローラハースキルンにて最高温度１２５０°
Ｃに８０分間焼成して御影模様を有する装飾タイルを得
た。Adhesive (2% aqueous solution of water-soluble cellulose) is applied to the dry tile base, and then the mixed colored glaze particles are sprinkled and heated in a roller hearth kiln at a maximum temperature of 1250°.
A decorative tile having a granite pattern was obtained by firing for 80 minutes.
実施例２
Ａ３）１０％の白色顔料を含み白に着色されたＡｌ２Ｏ
３０，８モル、ＳｉＯ□ ４，５モル、Ｃａ００．３８
モル、ＢａＯ０，２１モル、Ｍｇ００．２６モル及びに
２０＋Ｎａ２Ｏ０゜１５モルの釉組成を有し、粘性指数
９５で粒径０．１〜５ｍｍの釉粒の８５％と、
Ａ、）６％の黒色顔料を含み黒に着色されたＡｌ２Ｏ３
０，７モル、Ｓｔｏ、 ３．５モル、Ｃａ００．４４モ
ル、ＢａＯ０，１２モル、Ｍｇ００．０８モル、５ｒＯ
Ｏ，１６モル及びに２０＋Ｎａ２Ｏ０，２０モルの釉ｈ
ｐ’ｙを有し、粘性指数８．９で粒径０，５〜１．５ｍ
ｍの釉粒の１５％とを
あらかじめ混合しておく。Example 2 A3) Al2O colored white with 10% white pigment
30.8 mol, SiO□ 4.5 mol, Ca00.38
85% of the glaze particles with a viscosity index of 95 and a particle size of 0.1 to 5 mm, and A,) 6% black. Al2O3 containing pigments and colored black
0.7 mol, Sto, 3.5 mol, Ca00.44 mol, BaO0.12 mol, Mg00.08 mol, 5rO
Glaze of O, 16 mol and 20 + Na2O 0,20 mol h
p'y, viscosity index 8.9, particle size 0.5-1.5 m
Mix in advance with 15% of the glaze particles of m.
乾燥タイル素地上へ下釉（１２７０’Ｃ焼成用ブラウン
マツト釉、６％のブラウンｆｉｌ＝Ｊを含みＡｌ２Ｏ！
０．５５モル、５ｉ０２ ２．５モル、Ｃａ００．
４５モル、Ｂａ００．０７モル、Ｍｇ００．０８モルＺ
ｎ０Ｏ，１９モル及びに２０＋Ｎａ２Ｏ０，２１モルの
釉耗成を有する。）を流し掛けで施釉し乾燥後、接着剤
（水溶性セルロースの２％水溶液）を塗布し、更にその
上へあらかしめ混合された着色釉粒を散布し、トンネル
キルンにて最高温度１２７０℃に１８時間焼成して斑点
模様を有する装飾タイルを得た。Lower glaze on the dry tile base (brown pine glaze for firing at 1270'C, containing 6% brown fil=J and Al2O!
0.55 mol, 5i02 2.5 mol, Ca00.
45 mol, Ba 00.07 mol, Mg 00.08 mol Z
It has a glaze abrasion composition of 19 moles of n0O and 21 moles of 20+Na2O. ) and after drying, apply adhesive (2% aqueous solution of water-soluble cellulose), sprinkle mixed colored glaze particles on top, and heat to a maximum temperature of 1270℃ in a tunnel kiln. After firing for 18 hours, a decorative tile with a spotted pattern was obtained.
実施例３
Ａ５）８％のピンク顔料を含みピンクに着色されたＡｌ
２Ｏ３（１５８モル、５１０２６．０モル、ＢａＯ０，
２６モル、ＭｇＯ０２７モル及びＬｉ２Ｏ＋に、○十Ｎ
ａ２Ｏ０，４７モルの釉ＭＡ成を有し、粘性指数１０５
て粒径０５〜４ｍｍの釉粒の６７％と、
Ｂ２）５％のブラウン顔料を含みブラウンに着色された
Ａｌ２０ｇ０１．４５モル、５１０２５゜２モル、Ｂａ
Ｏ０，３４モル、ＭｇＯ０，３０モル及びＬｉｚＯ＋に
２０＋Ｎａ２Ｏ，０，３６モルかつＢ２Ｏ３０，３５モ
ルの釉組成を有し、粘性指数７．６で粒径０．１〜３０
ｍｍの釉粒の２８％と、
Ｃ１）９％の黒顔料を含み黒に着色されたＡｌ２０３０
．３モル、５１０２３．１モル、Ｂａ０Ｏ１０５モル、
ＭｇＯ０，１５モルＣａＯ０，３４、ＰｂＯ０，２１及
びＬｌ。Ｏ＋ Ｋ ２０十Ｎａ２Ｏ０，２５モルの釉組
成を有し、粘性指数４．９で粒径０．２〜１５ｍｍの釉
粒の５％とを
あらかじめ混合しておく。Example 3 A5) Pink colored Al containing 8% pink pigment
2O3 (158 mol, 51026.0 mol, BaO0,
26 mol, MgO027 mol and Li2O+, ○1N
Glaze MA composition of a2O0, 47 mol, viscosity index 105
67% of the glaze particles with a particle size of 05 to 4 mm; B2) 20 g of brown colored Al containing 5% brown pigment, 1.45 mol, 51025° 2 mol, Ba
It has a glaze composition of 0.34 mol of O, 0.30 mol of MgO, and 20 + 0.36 mol of Na2O in LizO+ and 0.36 mol of B2O, and has a viscosity index of 7.6 and a particle size of 0.1 to 30.
Al2030 colored black containing 28% of mm glaze grains and C1) 9% black pigment
．． 3 moles, 51023.1 moles, Ba0O105 moles,
MgO0,15 mol CaO0,34, PbO0,21 and Ll. O+K has a glaze composition of 200 and 0.25 moles of Na2O, and is premixed with 5% of glaze particles with a viscosity index of 4.9 and a particle size of 0.2 to 15 mm.
乾燥レンガ素地上へ下釉（１１００’Ｃ焼践用グレー光
沢釉、７％のグレー顔料を含みＡｌ２Ｏ。Underglaze on dry brick base (1100'C gray gloss glaze, containing 7% gray pigment, Al2O.
０．３モル、ＳｉＯ２３，１モル、ＣａＯＯ。0.3 mol, SiO23, 1 mol, CaOO.
６モル、Ｐｂ００．１５及びＬｉ２Ｏ＋に２０＋Ｎａ２
Ｏｏ、２５モルの釉糺成を有する。）をスプレーで施釉
し乾燥後、接着剤（水溶性セルロースの２％水溶液）を
塗布し、更にその上へあらかじめ混合された着色釉粒を
散布後、上釉（１１００℃焼成用透明釉、Ｂ料を含まず
Ａｌ２０３０３モル、Ｓｉ０．２．９モル、Ｃａ０Ｏ，
５２モル、Ｂａ００．２０モル及びＬｉ２Ｏ＋に２０＋
Ｎａ２Ｏ０，２８モルの釉ＭＡ成を有する。）を流し掛
（すで施釉し、トンネルキルンで最高温度１１００°Ｃ
に３２時間焼成して御影模様を有する装飾レンガを得た
。6 mol, Pb00.15 and Li2O+ to 20+Na2
Oo, with a glaze size of 25 moles. ) was spray glazed and dried, then an adhesive (2% aqueous solution of water-soluble cellulose) was applied, and pre-mixed colored glaze particles were sprinkled on top of the glaze. 20303 mol of Al, 0.2.9 mol of Si, Ca0O,
52 mol, Ba00.20 mol and 20+ in Li2O+
The glaze MA composition is 0.28 mol of Na2O. ) is poured and glazed in a tunnel kiln at a maximum temperature of 1100°C.
The bricks were fired for 32 hours to obtain decorative bricks with a granite pattern.
実施例４
Ｂ３）１０％のピンク顔料を含みピンクに着色されたＡ
ｌ２Ｏ３０，５モル、８１０２４．１モル、Ｃａ００．
３６モル、ＢａＯ０，１８モル、Ｋ２０＋ＮａｘＯＯ，
４６モル及びＢ２０ｊ０．９モルの釉組戎を有し、粘性
指数６．３で粒径０．１−２０ｍｍの釉粒の２５％と、
Ｃ２）６％のベージュ顔料を含みへ−ソユに着色された
Ａ１□０３０．１１モル、８１０２２゜９モル、ＣａＯ
０４０モル、ＰｂＯ０，２６モル、ＫｚＯ＋Ｎａ２Ｏ０
，３４モル及びＢ２０、１８モルの釉組成を有し、粘性
指数３８で粒径０５〜２ｍｍの釉粒の７５％とをあらか
しめ混合しておく。Example 4 B3) A colored pink containing 10% pink pigment
l2O30.5 mol, 81024.1 mol, Ca00.
36 mol, BaO0.18 mol, K20+NaxOO,
25% of the glaze particles with a viscosity index of 6.3 and a particle size of 0.1-20 mm,
C2) Containing 6% beige pigment, colored A1□030.11 mol, 81022°9 mol, CaO
040 mol, PbO0.26 mol, KzO+Na2O0
, 34 moles and B20, 18 moles, and 75% of the glaze particles having a viscosity index of 38 and a particle size of 05 to 2 mm are mixed in advance.
素焼されたタイル素地の上へ下釉（８８０℃焼成用白マ
ット釉、２％の白顔料を含み白に着色されたＡｌ２Ｏ３
０，１１モル、ＳｉＯ２１，８モル、Ｃａ００．３５モ
ル、ＰｂＯ０，６１に２０＋Ｎａ２Ｏ０，０４モル、Ｂ
２Ｏ３０，５モル及びＴｌＯ２０，８モルの釉組成を有
する。Lower glaze (white matte glaze for firing at 880℃, colored white containing 2% white pigment) on the unglazed tile base.
0.11 mole, SiO21.8 mole, Ca00.35 mole, PbO0.61 to 20 + Na2O0.04 mole, B
It has a glaze composition of 2O30.5 mol and TlO20.8 mol.
）をスプレーで施釉し乾燥後、接着剤を塗布し、更にそ
の上へあらかしめ混合された着色釉粒を散布し、電気炉
にて８８０℃に３０分間焼成して御影模様を有する装飾
タイルを得た。) is spray glazed and after drying, an adhesive is applied, and colored glaze grains are sprinkled on top of the glaze, and then baked in an electric furnace at 880℃ for 30 minutes to create a decorative tile with a granite pattern. Obtained.
［発明の効果］
■ 陶磁器の表面に様々な物性の着色釉粒を施すことに
よって、斑点模様、御影模様の陶磁器を得ることかでき
る。[Effects of the Invention] ■ By applying colored glaze grains with various physical properties to the surface of ceramics, it is possible to obtain ceramics with speckled or granite patterns.
■ 着色釉粒を予め混合しておくことかできるため、釉
の塗布工程を単純化できる。■ Colored glaze particles can be mixed in advance, simplifying the glaze application process.
■ 乾式施釉を基本にしているため、省エネルギー化や
作業環境の改善が図れる等の利点がある。■ Since it is based on dry glazing, it has the advantage of saving energy and improving the working environment.
■ この方法は、陶磁器製品に広く適用できるため有用
である。■ This method is useful because it can be widely applied to ceramic products.
Claims (2)
〜７、Ｒ＾１Ｏ０．５〜１．０及びＲ＾２＿２Ｏ０〜０
．５であって、使用温度範囲で粘性指数８〜１１のもの
、 Ｂ）Ａｌ＿２Ｏ＿３０．２〜０．６、ＳｉＯ＿２０．５
〜７、Ｒ＾１Ｏ０．５〜１．０及びＲ＾２＿２Ｏ０〜０
．５であって、使用温度範囲で粘性指数５〜８のもの並
びに Ｃ）Ａｌ＿２Ｏ＿３０〜０．４、ＳｉＯ＿２０．５〜７
、Ｒ＾１Ｏ０．５〜１．０及びＲ＾２＿２Ｏ０〜０．５
であって、使用温度範囲で粘性指数２〜５のもの からなる群より選ばれた一種以上の基礎釉に着色顔料を
加えて得た着色釉粒の２種以上を組み合わせて陶磁器素
地に施釉し、焼成することを特徴とする斑点又は御影模
様付き陶磁器製品の製造方法。(1) The glaze composition is shown in Segel representation, A) Al_2O_30.5-0.9, SiO_20.5
~7, R^1O0.5~1.0 and R^2_2O0~0
．． 5 and has a viscosity index of 8 to 11 in the operating temperature range, B) Al_2O_30.2 to 0.6, SiO_20.5
~7, R^1O0.5~1.0 and R^2_2O0~0
．． 5 and has a viscosity index of 5 to 8 in the operating temperature range, and C) Al_2O_30 to 0.4, SiO_20.5 to 7.
, R^1O0.5~1.0 and R^2_2O0~0.5
A ceramic base is glazed with a combination of two or more colored glaze particles obtained by adding a colored pigment to one or more basic glazes selected from the group consisting of those with a viscosity index of 2 to 5 within the operating temperature range. , a method for producing ceramic products with speckled or granite patterns, characterized by firing.
ット、砥材又は鉱物粒を組み合わせ焼成する請求項１記
載の方法。(2) The method according to claim 1, wherein two or more of the colored glaze particles are further combined with mica, sand, glass cullet, abrasive material, or mineral particles and fired.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2313200A JP3034015B2 (en) | 1990-11-19 | 1990-11-19 | Manufacturing method of ceramic products using colored glaze |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2313200A JP3034015B2 (en) | 1990-11-19 | 1990-11-19 | Manufacturing method of ceramic products using colored glaze |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04187580A true JPH04187580A (en) | 1992-07-06 |
| JP3034015B2 JP3034015B2 (en) | 2000-04-17 |
Family
ID=18038311
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2313200A Expired - Lifetime JP3034015B2 (en) | 1990-11-19 | 1990-11-19 | Manufacturing method of ceramic products using colored glaze |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3034015B2 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0672754A (en) * | 1992-07-08 | 1994-03-15 | Iwafuku Ceramics:Kk | Production of brick |
| JP2000319082A (en) * | 1999-05-10 | 2000-11-21 | Toto Ltd | Sanitary ware |
| CN100443436C (en) * | 2006-12-05 | 2008-12-17 | 罗杰华 | Process of making ceramic tile with partially polished surface and accumulated grains |
| JP2009001458A (en) * | 2007-06-21 | 2009-01-08 | Ikebukuro Horo Kogyo Kk | Glaze composition for glass lining |
| CN106045577A (en) * | 2016-05-30 | 2016-10-26 | 泉州阳光创艺陶瓷股份有限公司 | Medium-temperature snowflake glaze ceramic and manufacturing method thereof |
| CN111875353A (en) * | 2020-06-17 | 2020-11-03 | 东莞市唯美陶瓷工业园有限公司 | Temperature-adjusting slurry for improving firing temperature of spot brick, spot brick and manufacturing method thereof |
| CN114163225A (en) * | 2021-12-23 | 2022-03-11 | 广西蒙娜丽莎新材料有限公司 | Preparation method of ceramic tile with super matte effect |
| CN114634374A (en) * | 2022-03-09 | 2022-06-17 | 德清诺贝尔陶瓷有限公司 | Slurry for producing digital slurry distribution decorative rock plate |
-
1990
- 1990-11-19 JP JP2313200A patent/JP3034015B2/en not_active Expired - Lifetime
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0672754A (en) * | 1992-07-08 | 1994-03-15 | Iwafuku Ceramics:Kk | Production of brick |
| JP2000319082A (en) * | 1999-05-10 | 2000-11-21 | Toto Ltd | Sanitary ware |
| CN100443436C (en) * | 2006-12-05 | 2008-12-17 | 罗杰华 | Process of making ceramic tile with partially polished surface and accumulated grains |
| JP2009001458A (en) * | 2007-06-21 | 2009-01-08 | Ikebukuro Horo Kogyo Kk | Glaze composition for glass lining |
| CN106045577A (en) * | 2016-05-30 | 2016-10-26 | 泉州阳光创艺陶瓷股份有限公司 | Medium-temperature snowflake glaze ceramic and manufacturing method thereof |
| CN111875353A (en) * | 2020-06-17 | 2020-11-03 | 东莞市唯美陶瓷工业园有限公司 | Temperature-adjusting slurry for improving firing temperature of spot brick, spot brick and manufacturing method thereof |
| CN111875353B (en) * | 2020-06-17 | 2022-11-01 | 东莞市唯美陶瓷工业园有限公司 | Temperature-adjusting slurry for improving firing temperature of spot brick, spot brick and manufacturing method thereof |
| CN114163225A (en) * | 2021-12-23 | 2022-03-11 | 广西蒙娜丽莎新材料有限公司 | Preparation method of ceramic tile with super matte effect |
| CN114163225B (en) * | 2021-12-23 | 2023-03-10 | 广西蒙娜丽莎新材料有限公司 | Preparation method of ceramic tile with super matte effect |
| CN114634374A (en) * | 2022-03-09 | 2022-06-17 | 德清诺贝尔陶瓷有限公司 | Slurry for producing digital slurry distribution decorative rock plate |
| CN114634374B (en) * | 2022-03-09 | 2023-09-01 | 德清诺贝尔陶瓷有限公司 | Slurry for digital slurry distribution decoration rock plate production |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3034015B2 (en) | 2000-04-17 |
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