JPH04131277A - Dye thermal transfer recording method and recording intermediate material - Google Patents
Dye thermal transfer recording method and recording intermediate materialInfo
- Publication number
- JPH04131277A JPH04131277A JP2255793A JP25579390A JPH04131277A JP H04131277 A JPH04131277 A JP H04131277A JP 2255793 A JP2255793 A JP 2255793A JP 25579390 A JP25579390 A JP 25579390A JP H04131277 A JPH04131277 A JP H04131277A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- recording
- recording intermediate
- dye
- image
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 69
- 238000000034 method Methods 0.000 title claims abstract description 26
- 238000004043 dyeing Methods 0.000 claims abstract description 28
- 239000010410 layer Substances 0.000 claims description 153
- 229920005989 resin Polymers 0.000 claims description 27
- 239000011347 resin Substances 0.000 claims description 27
- 238000004040 coloring Methods 0.000 claims description 19
- 239000000314 lubricant Substances 0.000 claims description 14
- -1 siloxane methacrylate Chemical class 0.000 claims description 13
- 239000012790 adhesive layer Substances 0.000 claims description 8
- 239000010419 fine particle Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000000758 substrate Substances 0.000 claims description 6
- 230000009477 glass transition Effects 0.000 claims description 5
- 239000004840 adhesive resin Substances 0.000 claims 1
- 229920006223 adhesive resin Polymers 0.000 claims 1
- 230000001050 lubricating effect Effects 0.000 claims 1
- 239000003086 colorant Substances 0.000 abstract 1
- 238000010008 shearing Methods 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 37
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 229920001296 polysiloxane Polymers 0.000 description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
- 229920000178 Acrylic resin Polymers 0.000 description 6
- 239000004925 Acrylic resin Substances 0.000 description 6
- 239000010408 film Substances 0.000 description 6
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 229920002545 silicone oil Polymers 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- 229920002050 silicone resin Polymers 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000010687 lubricating oil Substances 0.000 description 3
- 229920001225 polyester resin Polymers 0.000 description 3
- 239000004645 polyester resin Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- 229930182556 Polyacetal Natural products 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000006757 chemical reactions by type Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 239000000986 disperse dye Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000006082 mold release agent Substances 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920006324 polyoxymethylene Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 235000010215 titanium dioxide Nutrition 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- XGDRLCRGKUCBQL-UHFFFAOYSA-N 1h-imidazole-4,5-dicarbonitrile Chemical compound N#CC=1N=CNC=1C#N XGDRLCRGKUCBQL-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004044 disperse dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 238000001454 recorded image Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Landscapes
- Electronic Switches (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は受像体の基質を選ばず、この上に高画質が記録
可能な染料熱転写記録方法及び記録中間体に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a dye thermal transfer recording method and a recording intermediate capable of recording high quality images on any image receptor substrate.
従負術
染料熱転写記録方法はカラー写真に匹敵する高画質画像
を提供できる唯一の小型・保守・即時性の優れた記録技
術である。これ（よ 薄いフィルム基材上に昇華性染料
を含む色材層をもうけた転写体と合成紙などの厚手フル
ム基材上に染着層をもうけた受像体を重ね、 熱記録ヘ
ッドを用いて昇華性染料を染着層に移行し染料分子の混
色画像を記録するものである。The dye thermal transfer recording method is the only compact, easy-to-maintain, and instant recording technology that can provide high-quality images comparable to color photography. This is done by layering a transfer body with a coloring layer containing a sublimable dye on a thin film base material and an image receptor with a dye layer on a thick film base material such as synthetic paper, and using a thermal recording head. A sublimable dye is transferred to a dyeing layer to record a mixed color image of dye molecules.
記録は一般面に受像体を駆動し 受像体と転写体間の摩
擦力で転写体を従動しておこなう。Recording is performed by driving the image receptor in the general plane, and causing the transfer body to follow due to the frictional force between the image receptor and the transfer body.
一方、色々な所に記録画像を添付するたム タックシー
トを用いる方法が提案されている。これは受像体が２枚
構造で、上層の染着層の形成された基材裏面に粘着材が
設けられて、これを下層の離型層を設けた支持体上に固
定化したものである。On the other hand, a method has been proposed that uses mutac sheets to attach recorded images to various locations. This image receptor has a two-layer structure, and an adhesive material is provided on the back side of the base material on which the upper dyeing layer is formed, and this is fixed onto a support material provided with the lower layer release layer. .
記録後、上層をはがし葉書等に添付して用いてぃ発明が
解決しようとする課題
前述のように染料熱転写記録方法による記録画像は特殊
紙の上に形成される。そのた八 ランニングコストが高
く本技術の普及を妨げていたまた 最近のマルチメディ
ア時代の情報は画像と文字が混在し それを複写機と同
じように普通紙に記録したいという強い要望が出されて
いる力丈従来の染料熱転写記録方法では普通紙上に高品
質の画像を得ることは不可能であっに
本発明は上記課題を解決する染料熱転写記録方法を提供
することを目的とする。After recording, the upper layer is peeled off and attached to a postcard or the like for use.Problems to be Solved by the InventionAs mentioned above, images recorded by the dye thermal transfer recording method are formed on special paper. (8) The high running costs hindered the spread of this technology.In addition, in the recent multimedia era, information is a mixture of images and text, and there has been a strong desire to record it on plain paper, just like copying machines. It is impossible to obtain high-quality images on plain paper using the conventional dye thermal transfer recording method.The object of the present invention is to provide a dye thermal transfer recording method that solves the above problems.
課題を解決するための手段
本発明（よ 基材上に少なくとも色材層を有する染料転
写体の色材層面と、基材上に離型層と少なくとも染着層
の積層構成を有する記録中間体の染着層面とを重ねて、
染料転写体と記録中間体の走行速度を独立制御して前記
染着層面に染料熱転写記録により画像を形成した後、受
像体と記録中間体の染着層面とを重飄 熱及び／または
圧力により前記染着層を受像体に転写させて画像を形成
することを特徴とする染料熱転写記録方法であり、また
基材上に少なくとも色材層を有する染料転写体の色材層
面と、基材上に離型層と少なくとも染着層の積層構成を
有する記録中間体の染着層面とを重ねて、染料転写体と
記録中間体の走行速度を独立制御して前記染着層面に染
料熱転写記録により画像を形成した後、受像体と記録中
間体の染着層面とを軍法 記録中間体の基材側から熱ヘ
ッドにより受像体上に記録された染着層を選択的に熱転
写し 受像体上に画像を形成することを特徴とする染料
熱転写記録方法である。さらに 厚み５０ミクロン以下
の基材上に離型層と少なくとも染着層の積層構成を有し
前記記録中間体の離型層とこの上の形成層間の剥離強
度か３ｇ／２５ｍｍ以上である記録中間体である。Means for Solving the Problems The present invention provides a recording intermediate having a laminated structure of a coloring material layer surface of a dye transfer body having at least a coloring material layer on a substrate, a release layer and at least a dyeing layer on the substrate. Overlap the dyed layer side of
After forming an image on the surface of the dyed layer by thermal dye transfer recording by independently controlling the running speeds of the dye transfer member and the recording intermediate, the image receptor and the dyed layer surface of the recording intermediate are heated and/or pressured. The dye thermal transfer recording method is characterized in that an image is formed by transferring the dyed layer to an image receptor, and the coloring material layer surface of a dye transfer body having at least a coloring material layer on a substrate, A release layer and a dyed layer surface of a recording intermediate having a laminated structure of at least a dyed layer are superimposed on each other, and the running speeds of the dye transfer body and the recording intermediate are independently controlled to perform dye thermal transfer recording on the dyed layer surface. After forming an image, the dyed layer recorded on the image receptor is selectively thermally transferred from the substrate side of the recording intermediate to the image receptor by a thermal head. This is a dye thermal transfer recording method characterized by forming an image. Furthermore, the recording intermediate has a laminated structure of a release layer and at least a dyed layer on a base material having a thickness of 50 microns or less, and the peel strength between the release layer of the recording intermediate and the forming layer thereon is 3 g/25 mm or more. It is the body.
作用
記録中間体の離型層上の染着層に記録された染料分子に
よる混色画像（よ 熱そして／または圧力により離型層
との界面ではがれて受像体上に転写される。このプロセ
スを実現するためには 安定な記録と、記録後の安定な
受像体への転写か必要である。A mixed color image created by the dye molecules recorded on the dyed layer on the release layer of the recording intermediate is peeled off at the interface with the release layer by heat and/or pressure and transferred onto the image receptor. To achieve this, it is necessary to have stable recording and stable transfer to an image receptor after recording.
離型層とこの上の形成層との界面は準安定状態で固定化
されているので、安定な記録のためには記録中間体と転
写体を独立に走行制御することが必要で、これにより記
録時にこの界面に働くせん断応力をやわら哄 界面での
剥離を防ぐことができる。同時に 記録中間体と転写体
間の摩擦係数を減少させることが必要である。転写体の
色材層上に滑性層を設けて実現できる。記録中間体の染
着層に滑性を付与しても可能である。Since the interface between the release layer and the forming layer above it is fixed in a quasi-stable state, it is necessary to independently control the running of the recording intermediate and transfer body for stable recording. By softening the shear stress acting on this interface during recording, peeling at the interface can be prevented. At the same time, it is necessary to reduce the coefficient of friction between the recording intermediate and the transfer member. This can be achieved by providing a slippery layer on the coloring material layer of the transfer body. It is also possible to impart lubricity to the dyed layer of the recording intermediate.
染着層のガラス転移温度を８０℃以下にすることにより
、記録後、受像体に容易に転写でき最終画像を得ること
ができる。特に 熱ヘッドを用いて記録された部分のみ
を選択的に転写できる。By setting the glass transition temperature of the dyed layer to 80° C. or lower, it is possible to easily transfer the image to a receiver after recording and obtain a final image. In particular, it is possible to selectively transfer only the recorded portion using a thermal head.
実施例
第１図に本発明による染料熱転写記録方法の１実施例を
示す。染料転写体１と記録中間体２は熱ヘッド３とドラ
ム（大きなプラテン）４または小さなプラテン４′の間
に挟着され 染料熱転写記録がおこなわれる。この隊
染料転写体ｌ及び記録中間体２の走行速度はそれぞれｖ
ｌ、、ｖ２のように独立に制御される。染料転写体１の
速度は９゜９′の制御系で、記録中間体２の速度は１０
，１０゛ の制御系で制御される。記録された記録中間
体上の染着層２３は７または８の熱圧力転写手段で受像
体５上に染着層２３の全部または一部か転写され 最終
画像６がえられる。７は熱ローラであり、記録された染
着層の部分的な選択転写は８の熱ヘッドが用いられる。Embodiment FIG. 1 shows an embodiment of the dye thermal transfer recording method according to the present invention. The dye transfer body 1 and recording intermediate body 2 are sandwiched between a thermal head 3 and a drum (large platen) 4 or a small platen 4', and thermal dye transfer recording is performed. this squad
The running speeds of the dye transfer body 1 and the recording intermediate body 2 are respectively v
l, , v2 are independently controlled. The speed of the dye transfer member 1 is controlled at 9°9', and the speed of the recording intermediate 2 is set at 10°.
, 10゛ control system. All or part of the dyed layer 23 on the recorded recording intermediate is transferred onto the image receptor 5 by seven or eight heat-pressure transfer means to obtain a final image 6. 7 is a thermal roller, and a thermal head 8 is used for partial selective transfer of the recorded dyed layer.
染料転写体１は基材１１の裏面に耐熱滑性層１３を形成
し表面に色材層１２が設けられたものである。基材１１
は厚み２ないし２０ミクロンの高分子フィルムが用いら
れる。−船釣に（よ ポリエチレンテレフタレート（Ｐ
ＥＴ）フィルムか用いられる力丈 芳香族ポリアミド（
アラミド）、ポリイミド、ポリカーボネート、ポリフェ
ニレンサルファイドミ ポリエーテルケトン、 トリア
セチルセルロー人 セロファン暮 成膜可能な樹脂によ
るフィルムも有用である。また これらの樹脂にカーボ
ン等の導電性粒子を混入し成膜した抵抗性フィルムを用
いてもよｌ、％ 色材層】２は少なく七も昇華性染料
と結着材から構成される。昇華性染料としては分散染法
油溶集糠 塩基性染料、カラーフォーマ−等が用いら
れる。特に インドアニリン慕 キノフタロン栗 ジシ
アノイミダゾール双 ジシアノメチン慕 トリシアノビ
ニル系等の分散染料が有効である。結着材にはポリエス
テル、ポリビニルブチラール、アクリルスチレン樹脂等
が用いられも 耐熱滑性層１３は熱ヘッド３と基材１１
間の潤滑性を付与するため設けられ 紫外線硬化樹脂
液状潤滑材、無機微粒子等で成膜される。The dye transfer body 1 has a heat-resistant slip layer 13 formed on the back surface of a base material 11, and a color material layer 12 provided on the front surface. Base material 11
A polymer film having a thickness of 2 to 20 microns is used. -For boat fishing (Polyethylene terephthalate (P)
Aromatic polyamide (ET)
Films made of resins that can be formed are also useful. Alternatively, a resistive film formed by mixing conductive particles such as carbon with these resins may be used.Coloring material layer 2 is composed of at least a sublimable dye and a binder. As the sublimable dye, disperse dyeing method, oil-soluble bran, basic dye, color former, etc. are used. Disperse dyes such as indoaniline quinophthalone dicyanoimidazole dicyanomethine tricyanovinyl are particularly effective. Polyester, polyvinyl butyral, acrylic styrene resin, etc. may be used as the binding material.
It is provided to provide lubricity between the ultraviolet curing resin
A film is formed using liquid lubricant, inorganic fine particles, etc.
記録中間体２は基材２１上に離型層２２と染着層２３が
積層構成される。基材２１は染料転写体の基材１１と同
様のものが用いられる。離型層２２はシリコーン樹脂や
弗素樹脂等を薄く形成したちへ または一般の樹脂に離
型材を混入・分散したもα または樹脂に離型材を反応
させたものが用いられる。シリコーン樹脂としてはコー
ティング用または剥離紙用の付加重合あるいは縮合重合
して成膜できるものか好ましｕ％ 弗素樹脂としはポ
リテトラフルオロエチレン、テトラフルオロエチレン・
パーフルオロアルキルビニルエーテル共重合体 ビニリ
デンフルオライド・ヘキサフルオロプロピレン系ゴム材
料、各種含弗素樹脂等が有効である。樹脂に添加させる
離型材としてｉｉ、各種のシリコーン系潤滑材、弗素系
界面活性材、パラフィン及びポリエチレン等のワックス
類 高級脂肪族アルコール、高級脂肪酸アミド及びエス
テル等がある。液状潤滑材として（よ ジメチルポリシ
ロキサン、メチルフェニルポリシロキサン、弗素シリコ
ーンオイル、その他の各種変性シリコーンオイル、 ２
種以上の反応性シリコーンオイルの反応物（例えば エ
ポキシ変性とカルボキシルまたはアミノ変性の反応物等
）がある。また 樹脂と潤滑材の反応型でもよく、例え
は ポリシロキサンをアクリル樹脂にグラフト重合させ
た水溶性ポリシロキサングラフトアクリル樹Ｂ’＝
シロ牛サンメタクリレートを末端または側鎖に付加した
アクリルシリコーン（シリコン）またはアクリルウレタ
ンシリコーン（シリコン）樹脂等も有効であも
染着層２３は少なくとも樹脂層で構成されている力（離
型性または滑性を付与してもよい。染料転写体の色材層
側に滑性または離型性が付与される時に（友 染着層２
３はほとんど樹脂のみで構成されてもよ賎 染着層は記
録後最終プロセスで受像体６に転写される必要があるた
敢 染着樹脂のガラス転移温度Ｔｇは記録に問題が生じ
ない限り低いことが好まししも 飽和ポリエステル樹脂
ポリアセタール樹脂 アクリル樹脂 ウレタン樹脂ポ
リアミド樹脂 及びこれらの複合系が有用である力（特
に これらのうちそのＴｇが８０℃以下が好ましい。染
着層の系としてのＴｇを下げるた嵌 及び染着層の選択
的な受像体への転写のだ敦 前述の滑性材または離型材
を添加することが効果的な場合も多１．％ 特に 末
端または側鎖にシロキサンメタアクリレートを有するア
クリルシリコーン（シリコン）樹脂を飽和ポリエステル
またはアクリル系樹脂に添加したものは 記録及び受像
体への染着層の転写効率が太きいく、染着層の選択転写
性も大きい。普通紙等表面性の粗い受像体への転写に１
友 染着層に微粒子を含ませてもよい。特に 染着層表
面から突出するシリカ、チタン白等の無機微粒子が効果
が大きい。The recording intermediate 2 has a release layer 22 and a dyeing layer 23 laminated on a base material 21 . The base material 21 used is the same as the base material 11 of the dye transfer body. The release layer 22 is made of a thin layer of silicone resin, fluororesin, or the like, or a general resin mixed with and dispersed with a release agent, or a resin reacted with a release agent. The silicone resin is preferably one that can be formed into a film by addition polymerization or condensation polymerization for coating or release paper.The fluororesin is polytetrafluoroethylene, tetrafluoroethylene, etc.
Perfluoroalkyl vinyl ether copolymers, vinylidene fluoride/hexafluoropropylene rubber materials, various fluorine-containing resins, etc. are effective. Examples of mold release agents added to the resin include various silicone-based lubricants, fluorine-based surfactants, waxes such as paraffin and polyethylene, higher aliphatic alcohols, higher fatty acid amides, and esters. As a liquid lubricant (dimethylpolysiloxane, methylphenylpolysiloxane, fluorosilicone oil, and various other modified silicone oils, etc.)
There are more than one type of reactive silicone oil reactants (eg, epoxy-modified and carboxyl or amino-modified reactants, etc.). It may also be a reaction type of resin and lubricant, for example, water-soluble polysiloxane grafted acrylic resin B'= which is obtained by graft polymerizing polysiloxane to acrylic resin.
Acrylic silicone (silicon) or acrylic urethane silicone (silicon) resin with Shirogyushan methacrylate added to the terminal or side chain is also effective, but the dyeing layer 23 has at least the strength (mold releasability or Smoothness may be imparted.When lubricity or release properties are imparted to the color material layer side of the dye transfer body (Friend Dyeing Layer 2
3 may be composed almost entirely of resin.The dyeing layer needs to be transferred to the image receptor 6 in the final process after recording.The glass transition temperature Tg of the dyeing resin is low as long as it does not cause recording problems. Saturated polyester resins, polyacetal resins, acrylic resins, urethane resins, polyamide resins, and composite systems thereof are useful (particularly, it is preferable that the Tg of these is 80°C or less. For lowering and selective transfer of the dyed layer to the image receptor, it is often effective to add the above-mentioned lubricating agent or mold release agent.1.% Siloxane methacrylate, especially at the terminal or side chain. When an acrylic silicone resin is added to a saturated polyester or acrylic resin, the transfer efficiency of the dyed layer to the recording and image receptor is high, and the selective transferability of the dyed layer is also high.Plain paper, etc. 1 for transfer to image receptors with rough surfaces
Fine particles may be included in the dyeing layer. Particularly effective are inorganic particles such as silica and titanium white that protrude from the surface of the dyed layer.
第２図に記録中間体の他の実施例を示す。離型層２２と
染着層２３の間に接着層２４が設けられている。これは
記録時に２２と２３の界面に作用するせん耐応力に対し
てこの界面で剥離しないようにするためである。染着層
には一般に離型材または潤滑材が含まれる場合がおおい
ので、その場合接着層２４の効果は特に犬きｔ、Ｘｏ
この接着材には飽和ポリエステル樹脂 ポリアセター
ル樹脂等染着層に用いられる樹脂か有効である。特に
記録時の高温下のせん耐応力にたえるた敦 樹脂のＴｇ
は染着層樹脂のそれと同等かより高いことがよく、 ６
０’Ｃないし８０６Ｃが望ましい。この接着層にシリカ
、チタン白等の微粒子を含ませると離型層との接着力を
大きくすることができる。FIG. 2 shows another embodiment of the recording intermediate. An adhesive layer 24 is provided between the release layer 22 and the dyeing layer 23. This is to prevent separation at this interface due to the shear stress that acts on the interface between 22 and 23 during recording. The dyeing layer generally contains a release agent or a lubricant in many cases, so in that case the effect of the adhesive layer 24 is particularly poor.
Resins used for the dyeing layer, such as saturated polyester resins and polyacetal resins, are effective for this adhesive. especially
Tg of Atsushi resin that withstands shear stress under high temperature during recording
is often equal to or higher than that of the dye layer resin, 6
0'C to 806C is desirable. When this adhesive layer contains fine particles of silica, titanium white, etc., the adhesive force with the release layer can be increased.
また 離型層に微粒子をふくませてもよい。ＪＩＳ
Ｋ ６８５４による接着材の剥離接着強さ試験法に準
する方法で、離型層・接着層間の剥離強度を評価すると
３ｇ７２５ｍｍ以上で剥離のない安定な記録を行なうこ
とができる。Further, the release layer may contain fine particles. JIS
When the peel strength between the release layer and the adhesive layer is evaluated using a method similar to the peel adhesion strength testing method for adhesives according to K 6854, stable recording without peeling can be performed at 3 g 725 mm or more.
第３図に染料転写体の他の実施例を示す。色材層１２上
に滑性層１４が設けられている。これにより、記録中間
体の離型層２２とその上の形成層２３または２４間のせ
ん断応力を減少し安定な記録をおこなえる。滑性層１４
は樹脂に潤滑材を混入・分散して形成される。潤滑材と
しては 各種のシリコーン系潤滑材、弗素系界面活性材
、パラフィン及びポリエチレン等のワックス類 高級脂
肪族アルコ−取 高級脂肪酸アミド及びエステル等があ
る。液状潤滑材として（表 ジメチルポリシロキサン、
メチルフェニルポリシロキサン、弗素シリコーン社製ノ
ｋ その他の各種変性シリコーンオイル、 ２種以上の
反応性シリコーンオイルの反応物（例えは エポキシ変
性とカルボキシルまたはアミノ変性の反応物等）かある
。まｔへ 樹脂と潤滑材の反応型でもよく、例え（′！
、ポリシロキサンをアクリル樹脂にグラフト重合させた
水溶性ポリシロキサングラフトアクリル樹脂 シロキサ
ンメタクリレートを末端または側鎖に付加したアクリル
シリコーン（シリコン）またはアクリルウレタンシリコ
ーン（シリコン）樹脂等も有効である。FIG. 3 shows another embodiment of the dye transfer body. A slippery layer 14 is provided on the coloring material layer 12. Thereby, the shear stress between the release layer 22 of the recording intermediate and the forming layer 23 or 24 thereon can be reduced, and stable recording can be performed. Slippery layer 14
is formed by mixing and dispersing a lubricant into resin. Examples of lubricants include various silicone-based lubricants, fluorine-based surfactants, waxes such as paraffin and polyethylene, higher aliphatic alcohols, higher fatty acid amides and esters, and the like. As a liquid lubricant (Table Dimethylpolysiloxane,
Examples include methylphenylpolysiloxane, manufactured by Fluorosilicone Co., Ltd., various other modified silicone oils, and reactants of two or more reactive silicone oils (for example, reactants of epoxy modification and carboxyl or amino modification). It may also be a reaction type of resin and lubricant, for example ('!
, a water-soluble polysiloxane graft acrylic resin in which polysiloxane is graft-polymerized to an acrylic resin, and acrylic silicone (silicon) or acrylic urethane silicone (silicon) resin in which siloxane methacrylate is added to the terminal or side chain are also effective.
受像体５はボンド紙や普通紙等のバルブ系用紙でもよく
、乳白ＰＥＴ、ユポ等の合成紙でもよく、パルプ紙とフ
ィルムの接着した基材でもよい。The image receptor 5 may be made of bulb paper such as bond paper or plain paper, synthetic paper such as opalescent PET or Yupo, or a base material made of pulp paper and film bonded together.
記録ヘッド３は普通のサーマルヘッド、通電ヘッド、
レーザーヘッド等か用いられる。ライン型サーマルヘッ
ドを用いた時の記録条件は ライン記録周期Ｔ：３３ｍ
５ないし４ｍｓ、印加パルス幅： １６ｍ５ないし２
ｍｓ、記録エネルギーＥ：８ないし６Ｊ／ｃｍ２でおこ
なわれる。The recording head 3 is a normal thermal head, a current-carrying head,
A laser head etc. is used. Recording conditions when using a line type thermal head: Line recording period T: 33m
5 to 4ms, applied pulse width: 16m5 to 2
ms, recording energy E: 8 to 6 J/cm2.
染料転写体１と記録中間体２の走行速度のＶｌとＶ２は
一般にはｖｌ＝ｖ２となるように独立の制御系９，９“
及び１０．１０’で制御され 記録中間体２の離型層２
２とその上の形成層間におおきなせん断応力か加わらな
いようにしている。The running speeds Vl and V2 of the dye transfer body 1 and the recording intermediate body 2 are generally controlled by independent control systems 9, 9'' so that vl=v2.
and 10. Controlled by 10', the release layer 2 of the recording intermediate 2
2 and the formed layer above it to prevent large shear stress from being applied.
染料転写体１上に滑性層１４が設けられている場合には
ｖｌ＜ｖ２となるような相対速度記録も可能である。When the slippery layer 14 is provided on the dye transfer body 1, relative speed recording such that vl<v2 is also possible.
記録された染着層の受像体５への熱転写は熱ロール７を
用いる時（よ 温度的１８０℃１速度１０ｍｍ／＆
圧力１００Ｋｇ／１ｃｍで行なわれも 熱ヘッド８にサ
ーマルヘッドを用いるとき（表記縁ヘッド３の最大記録
エネルギー以下で行なわれる。Thermal transfer of the recorded dyed layer to the image receptor 5 is carried out using a thermal roll 7 (temperature: 180°C, speed: 10mm/&
When a thermal head is used as the thermal head 8 (the recording is performed at a pressure of 100 kg/1 cm or less) (the recording is performed at a pressure lower than the maximum recording energy of the edge head 3).
以下、さらに具体的な実施例を示す。More specific examples will be shown below.
・染料転写体１の作製
裏面に２ミクロンの滑性耐熱層を設（す、表面に０．３
ミクロンのアンカー層を塗工した４ミクロンのＰＥＴフ
ィルムのアンカー層上に下記のインクをグラビアコータ
ーで固形厚１ミクロンになるように色材層を形成し九
（インク）
インドアニリン系分散染料 ２．５重量部アクリルスチ
レン樹脂 ４ 重量部アミド変性シリコーン油
０．０２重量部トルエン ２０重量
部２−ブタノン ２０重量部・記録中間体
２の作製
厚み１．２ ミクロンのＰＥＴフィルム上に離型層とし
て脱オキシム型シリコーン樹脂（ＰＲＸ３０５、東し・
ダウコーニング・シリコーン社製）１０重量服 トルエ
ン２０重量部からなる塗料をバコーターで厚み１ミクロ
ンに形成し旭 この離型層上に接着層としてポリビニル
ブチラール樹脂（ＢＬ−３、積木化学社製）１０重量服
トルエン５０重量部の塗料をバーコーターで厚み１ミ
クロンに成膜しな この上に染着層としてポリビニルブ
チラール樹脂（ＢＬ−８）６重量部 シロキサンメタア
クリレートを側鎖に有するアクリルシリコーン（シリコ
ン）樹脂（Ｆ−６Ａ、三洋化成工業社製）０．２重量部
ジ−ｎ−ブチル錫ジラウレート０．００４重量服 ト
ルエン及び２−ブタノンをそれぞれ１３重量部からなる
塗料をバーコーターで厚み２ミクロンになるよう成膜し
池上記の染料転写体１と記録中間体２を独立走行する機
構と、連続して受像体に染着層を転写する熱ローラー機
構を用いて、下記の条件で記録しボンド紙上に最終画像
を得を島
記録ヘッド： ライン型サーマルへラドライン記録速度
： ８ｍｓ
記録パルス幅：０−４ｍ５
最大記録エネルギー： ６、５ｊ／ｃｍ２熱ローラー
： 温度１８０℃２送り速度１０ｍｍ／枚 圧力１０Ｋ
ｇ
以上のようにしてボンド紙上に得られた画像は最大反射
濃度１．８以上の高品位なビクトリアル画像であった
発明の効果
以上のよう（′−，本発明によれば 従来高価な特殊紙
上にしか得られなかった高品位のビクトリアル画像を受
像体を選ばず実現できる。ボンド紙でも普通紙でも紙質
依存性の少ない記録を行なうことかできる。特に 高速
記録すなわち高温記録に対して杖 記録中間体の離型層
と染着層間で剥離することなく安定に記録でき、か２
記録された染着層が安定にどのような受像体にも熱転写
できる。・Preparation of dye transfer material 1 A 2 micron smooth heat-resistant layer is provided on the back surface, and a 0.3 micron smooth heat-resistant layer is provided on the surface.
On the anchor layer of a 4 micron PET film coated with a micron anchor layer, a coloring layer was formed using the following ink using a gravure coater to a solid thickness of 1 micron. (Ink) Indoaniline disperse dye 2. 5 parts by weight acrylic styrene resin 4 parts by weight amide modified silicone oil
0.02 parts by weight Toluene 20 parts 2-butanone 20 parts by weight Preparation thickness of recording intermediate 2 1.2 micron PET film as a release layer with oxime-free silicone resin (PRX305, Toshiba)
A coating consisting of 20 parts by weight of toluene was formed to a thickness of 1 micron using a vacuum coater. Polyvinyl butyral resin (BL-3, manufactured by Block Chemical Co., Ltd.) was applied as an adhesive layer on top of this release layer. Weight clothing: A coating containing 50 parts by weight of toluene is coated with a bar coater to a thickness of 1 micron.On top of this is a dyeing layer of 6 parts by weight of polyvinyl butyral resin (BL-8), which is made of acrylic silicone (silicon ) 0.2 parts by weight of resin (F-6A, manufactured by Sanyo Chemical Industries, Ltd.) 0.004 parts by weight of di-n-butyltin dilaurate A paint consisting of 13 parts by weight each of toluene and 2-butanone was coated with a bar coater to a thickness of 2 microns. Recording was carried out under the following conditions using a mechanism in which the dye transfer body 1 and recording intermediate 2 described above run independently and a heat roller mechanism that continuously transfers the dyed layer to the image receptor. Recording head: Rad line recording speed to line type thermal: 8ms Recording pulse width: 0-4m5 Maximum recording energy: 6.5J/cm2 Heat roller: Temperature: 180℃ 2 Feeding speed: 10mm/sheet Pressure 10K
g The image obtained on the bond paper as described above was a high-quality Victorian image with a maximum reflection density of 1.8 or more. High-quality Victorian images that could only be obtained on paper can be achieved regardless of the image receptor.Recording can be performed with less paper quality dependence on bond paper or plain paper.Especially useful for high-speed recording, that is, high-temperature recording. Stable recording is possible without peeling between the release layer and dyeing layer of the recording intermediate, and
The recorded dyed layer can be stably thermally transferred to any image receptor.
第１図は本発明の染料熱転写記録記録方法の説明＠ 第
２図は記録中間体の実施例を示す断面医第３図は染料転
写体の実施例を示す断面図である。
１・・・染料転写体 １１・・・基材、 １２・・・色
材凰 ２・・・記録中間体 ２１・・・基材、 ２２・
・・離型＃ ２３・・・染着層 ２４・接着＃ ５・・
・受像俟
代理人の氏名 弁理士 小鍜治 明
ほか２名
２ ゛
ｔ
！？
解ミ村◆ム写−イト
ま乙′ｔｔ１’ 関イ峯
女 像坏
ｌ−材
色キオ層
氷 オイ
第２図FIG. 1 is an explanation of the dye thermal transfer recording method of the present invention. FIG. 2 is a sectional view showing an embodiment of the recording intermediate. FIG. 3 is a sectional view showing an embodiment of the dye transfer material. DESCRIPTION OF SYMBOLS 1... Dye transfer body 11... Base material, 12... Coloring material 2... Recording intermediate body 21... Base material, 22...
・Release #23・Dyeing layer 24・Adhesion #5・・
・Name of the agent for the image: Patent attorney Akira Okaji and two others 2 ゛t! ? Demimura◆Musha - Ito Mao'tt1' Sekii Mine Onna Statue - Material color Kio layer ice Figure 2
Claims (20)
色材層面と、基材上に離型層と少なくとも染着層の積層
構成を有する記録中間体の染着層面とを重ねて行なう熱
転写記録方法において、染料転写体と記録中間体の走行
速度を独立制御することを特徴とする染料熱転写記録方
法。(1) The coloring material layer surface of a dye transfer body having at least a coloring material layer on a base material and the dyeing layer surface of a recording intermediate having a laminated structure of a release layer and at least a dyeing layer on a base material are overlapped. A dye thermal transfer recording method characterized in that the running speeds of a dye transfer member and a recording intermediate are independently controlled.
色材層面と、基材上に離型層と少なくとも染着層の積層
構成を有する記録中間体の染着層面とを重ねて、染料転
写体と記録中間体の走行速度を独立制御して前部染着層
面に染料熱転写記録により画像を形成した後、受像体と
記録中間体の染着層面とを重ね、熱及び／または圧力に
より前記染着層を受像体に転写させて画像を形成するこ
とを特徴とする染料熱転写記録方法。(2) Layering the coloring material layer surface of a dye transfer body having at least a coloring material layer on a base material and the dyeing layer surface of a recording intermediate having a laminated structure of a release layer and at least a dyeing layer on a base material; After forming an image on the front dyed layer surface by thermal dye transfer recording by independently controlling the running speeds of the dye transfer member and the recording intermediate, the image receiver and the dyed layer surface of the recording intermediate are overlapped and heated and/or A dye thermal transfer recording method characterized in that an image is formed by transferring the dyed layer to an image receptor using pressure.
色材層面と、基材上に離型層と少なくとも染着層の積層
構成を有する記録中間体の染着層面とを重ねて、染料転
写体と記録中間体の走行速度を独立制御して前記染着層
面に染料熱転写記録により画像を形成した後、受像体と
記録中間体の染着層面とを重ね、記録中間体の基材側か
ら熱ヘッドにより受像体上に記録された染着層を選択的
に熱転写し、受像体上に画像を形成することを特徴とす
る染料熱転写記録方法。(3) Layering the coloring material layer surface of a dye transfer body having at least a coloring material layer on a base material and the dyeing layer surface of a recording intermediate having a laminated structure of a release layer and at least a dyeing layer on a base material; After forming an image on the surface of the dyed layer by thermal dye transfer recording by independently controlling the running speeds of the dye transfer body and the recording intermediate, the image receiver and the dyed layer surface of the recording intermediate are overlapped, and the base of the recording intermediate is A dye thermal transfer recording method characterized by selectively thermally transferring a dyed layer recorded on an image receptor from the material side using a thermal head to form an image on the image receptor.
積層構成を有する染料転写体の滑性層面と、基材上に離
型層と少なくとも染着層の積層構成を有する記録中間体
の染着層面とを重ねて行なう熱転写記録方法において、 染料転写体と記録中間体の走行速度を独立制御すること
を特徴とする染料熱転写記録方法。(4) A recording intermediate having a lubricant layer surface of a dye transfer body having a laminated structure of at least a coloring material layer and at least a lubricant layer on a base material, and a laminated structure of a release layer and at least a dyeing layer on the base material. 1. A dye thermal transfer recording method in which the dyed layer surfaces of the dyed layer are overlapped, the dye thermal transfer recording method being characterized in that the running speeds of the dye transfer body and the recording intermediate are independently controlled.
の積層構成を有する染料転写体の滑性層面と、基材上に
離型層と少なくとも染着層の積層構成を有する記録中間
体の染着層面とを重ねて、染料転写体と記録中間体の走
行速度を独立制御して前記染着層面に染料熱転写記録に
より画像を形成した後、受像体と記録中間体の染着層面
とを重ね、熱及び／または圧力により前記染着層を受像
体に転写させて画像を形成することを特徴とする染料熱
転写記録方法。(5) A recording intermediate having a lubricant layer surface of a dye transfer body having a laminated structure of at least a coloring material layer and at least a lubricant layer on a base material, and a laminated structure of a release layer and at least a dyeing layer on the base material. After forming an image on the dyed layer surface by dye thermal transfer recording by independently controlling the running speed of the dye transfer member and the recording intermediate, the dyed layer surface of the image receptor and the recording intermediate are A dye thermal transfer recording method characterized in that an image is formed by overlapping the dyed layers and transferring the dyed layer to an image receptor using heat and/or pressure.
の積層構成を有する染料転写体の滑性層面と、基材上に
離型層と少なくとも染着層の積層構成を有する記録中間
体の染着層面とを重ねて、染料転写体と記録中間体の走
行速度を独立制御して前記染着層面に染料熱転写記録に
より画像を形成した後、受像体と記録中間体の染着層面
とを重ね、記録中間体の基材側から熱ヘッドにより受像
体上に記録された前記染着層を選択的に熱転写し、受像
体上に画像を形成することを特徴とする染料熱転写記録
方法。(6) A recording intermediate having a lubricant layer surface of a dye transfer body having a laminated structure of at least a coloring material layer and at least a lubricant layer on a base material, and a laminated structure of a release layer and at least a dyeing layer on the base material. After forming an image on the dyed layer surface by dye thermal transfer recording by independently controlling the running speed of the dye transfer member and the recording intermediate, the dyed layer surface of the image receptor and the recording intermediate are A dye thermal transfer recording method characterized in that the dyed layer recorded on the image receptor is selectively thermally transferred from the substrate side of the recording intermediate by a thermal head to form an image on the image receptor.
等しいか、より遅いことを特徴とする請求項１ないし６
のいずれかに記載の染料熱転写記録方法。(7) Claims 1 to 6 characterized in that the running speed of the dye transfer member is equal to or slower than the running speed of the recording intermediate.
The dye thermal transfer recording method according to any one of the above.
る請求項１ないし７のいずれかに記載の染料熱転写記録
方法。(8) The dye thermal transfer recording method according to any one of claims 1 to 7, wherein the thickness of the base material of the recording intermediate is 50 microns or less.
積層構成である請求項１ないし７のいずれかに記載の染
料熱転写記録方法。(9) The dye thermal transfer recording method according to any one of claims 1 to 7, wherein the recording intermediate has a laminated structure of a release layer, an adhesive layer, and a dyed layer on a base material.
強度が３ｇ／２５ｍｍ以上である請求項１ないし７のい
ずれかに記載の染料熱転写記録方法。(10) The dye thermal transfer recording method according to any one of claims 1 to 7, wherein the peel strength between the release layer of the recording intermediate and the forming layer thereon is 3 g/25 mm or more.
くとも染着層の積層構成を有し、記録中間体の離型層と
この上の形成層間の剥離強度が３ｇ／２５ｍｍ以上であ
る記録中間体。(11) It has a laminated structure of a release layer and at least a dyed layer on a base material with a thickness of 50 microns or less, and the peel strength between the release layer of the recording intermediate and the forming layer thereon is 3 g/25 mm or more. Recording intermediate.
ある請求項１１記載の記録中間体。(12) The recording intermediate according to claim 11, wherein the forming layer on the release layer of the recording intermediate is an adhesive resin layer.
請求項１１記載の記録中間体。(13) The recording intermediate according to claim 11, wherein the forming layer on the release layer of the recording intermediate is a dyed layer.
である請求項１１または１３記載の記録中間体。(14) The recording intermediate according to claim 11 or 13, wherein the dyed layer is a resin layer that does not contain a release agent or a release agent.
温度が８０℃以下である請求項１１ないし１４記載の記
録中間体。(15) The recording intermediate according to any one of claims 11 to 14, wherein the resin constituting the dyeing layer and the adhesive layer has a glass transition temperature of 80°C or lower.
脂を含む請求項１１、１２、または１５の記載記録中間
体。(16) The recording intermediate according to claim 11, 12, or 15, wherein the dyeing layer contains a siloxane methacrylate-based lubricating resin.
求項１１ないし１６のいずれかに記載の記録中間体。(17) The recording intermediate according to any one of claims 11 to 16, wherein the dyed layer contains fine particles protruding from the surface thereof.
温度と同等か、より高い樹脂である請求項１１ないし１
７のいずれかに記載の記録中間体。(18) Claims 11 to 1 wherein the adhesive layer is made of a resin whose glass transition temperature is equal to or higher than the glass transition temperature of the dyed layer.
7. The recording intermediate according to any one of 7.
請求項１１ないし１８のいずれかに記載の記録中間体。(19) The recording intermediate according to any one of claims 11 to 18, wherein the forming layer on the release layer of the recording intermediate contains fine particles.
ないし１９のいずれかに記載の記録中間体。(20) Claim 11 in which the release layer of the recording intermediate contains fine particles.
20. The recording intermediate according to any one of items 1 to 19.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2255793A JP2893907B2 (en) | 1990-09-25 | 1990-09-25 | Dye thermal transfer recording method and recording intermediate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2255793A JP2893907B2 (en) | 1990-09-25 | 1990-09-25 | Dye thermal transfer recording method and recording intermediate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04131277A true JPH04131277A (en) | 1992-05-01 |
| JP2893907B2 JP2893907B2 (en) | 1999-05-24 |
Family
ID=17283715
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2255793A Expired - Fee Related JP2893907B2 (en) | 1990-09-25 | 1990-09-25 | Dye thermal transfer recording method and recording intermediate |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2893907B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06127160A (en) * | 1992-10-21 | 1994-05-10 | Brother Ind Ltd | Re-transfer sheet |
| US5448282A (en) * | 1992-07-23 | 1995-09-05 | Matsushita Electric Industrial Co., Ltd. | Thermal transfer printing method and apparatus and intermediate sheet |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6381093A (en) * | 1986-09-24 | 1988-04-11 | Dainippon Printing Co Ltd | Method and apparatus for forming image on object |
| JPS6490772A (en) * | 1987-10-02 | 1989-04-07 | Dainippon Printing Co Ltd | Transfer recorder |
| JPH02113956A (en) * | 1988-10-24 | 1990-04-26 | Alps Electric Co Ltd | Thermal transfer printing method and thermal transfer printer |
-
1990
- 1990-09-25 JP JP2255793A patent/JP2893907B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6381093A (en) * | 1986-09-24 | 1988-04-11 | Dainippon Printing Co Ltd | Method and apparatus for forming image on object |
| JPS6490772A (en) * | 1987-10-02 | 1989-04-07 | Dainippon Printing Co Ltd | Transfer recorder |
| JPH02113956A (en) * | 1988-10-24 | 1990-04-26 | Alps Electric Co Ltd | Thermal transfer printing method and thermal transfer printer |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5448282A (en) * | 1992-07-23 | 1995-09-05 | Matsushita Electric Industrial Co., Ltd. | Thermal transfer printing method and apparatus and intermediate sheet |
| JPH06127160A (en) * | 1992-10-21 | 1994-05-10 | Brother Ind Ltd | Re-transfer sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2893907B2 (en) | 1999-05-24 |
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