JPH0411084A - Specific surface silk fabric and production thereof - Google Patents
Specific surface silk fabric and production thereofInfo
- Publication number
- JPH0411084A JPH0411084A JP2112272A JP11227290A JPH0411084A JP H0411084 A JPH0411084 A JP H0411084A JP 2112272 A JP2112272 A JP 2112272A JP 11227290 A JP11227290 A JP 11227290A JP H0411084 A JPH0411084 A JP H0411084A
- Authority
- JP
- Japan
- Prior art keywords
- sericin
- fabric
- portions
- epoxy compound
- silk fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 40
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 108010013296 Sericins Proteins 0.000 claims abstract description 37
- 239000004593 Epoxy Substances 0.000 claims abstract description 25
- 150000001875 compounds Chemical class 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 238000007639 printing Methods 0.000 claims abstract description 13
- 238000009991 scouring Methods 0.000 claims abstract description 13
- 230000035699 permeability Effects 0.000 claims abstract description 12
- 238000001035 drying Methods 0.000 claims abstract description 7
- 239000003292 glue Substances 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- 238000010438 heat treatment Methods 0.000 abstract description 6
- 238000004513 sizing Methods 0.000 abstract description 6
- 238000004043 dyeing Methods 0.000 abstract description 5
- CUGZWHZWSVUSBE-UHFFFAOYSA-N 2-(oxiran-2-ylmethoxy)ethanol Chemical compound OCCOCC1CO1 CUGZWHZWSVUSBE-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 description 17
- 238000002834 transmittance Methods 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000000975 dye Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 206010061592 cardiac fibrillation Diseases 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 230000002600 fibrillogenic effect Effects 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 4
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 3
- 244000144730 Amygdalus persica Species 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 108010022355 Fibroins Proteins 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 235000006040 Prunus persica var persica Nutrition 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000009981 jet dyeing Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 235000010413 sodium alginate Nutrition 0.000 description 3
- 239000000661 sodium alginate Substances 0.000 description 3
- 229940005550 sodium alginate Drugs 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 240000007817 Olea europaea Species 0.000 description 2
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 159000000011 group IA salts Chemical class 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010259 potassium hydrogen sulphite Nutrition 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 229950011008 tetrachloroethylene Drugs 0.000 description 2
- OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 description 1
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 1
- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 description 1
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical compound C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 description 1
- 241000962141 Alsophila smithii Species 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229920000926 Galactomannan Polymers 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004368 Modified starch Substances 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- WXOMTJVVIMOXJL-BOBFKVMVSA-A O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)OS(=O)(=O)OC[C@H]1O[C@@H](O[C@]2(COS(=O)(=O)O[Al](O)O)O[C@H](OS(=O)(=O)O[Al](O)O)[C@@H](OS(=O)(=O)O[Al](O)O)[C@@H]2OS(=O)(=O)O[Al](O)O)[C@H](OS(=O)(=O)O[Al](O)O)[C@@H](OS(=O)(=O)O[Al](O)O)[C@@H]1OS(=O)(=O)O[Al](O)O Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)OS(=O)(=O)OC[C@H]1O[C@@H](O[C@]2(COS(=O)(=O)O[Al](O)O)O[C@H](OS(=O)(=O)O[Al](O)O)[C@@H](OS(=O)(=O)O[Al](O)O)[C@@H]2OS(=O)(=O)O[Al](O)O)[C@H](OS(=O)(=O)O[Al](O)O)[C@@H](OS(=O)(=O)O[Al](O)O)[C@@H]1OS(=O)(=O)O[Al](O)O WXOMTJVVIMOXJL-BOBFKVMVSA-A 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 229940105329 carboxymethylcellulose Drugs 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- YXOGSLZKOVPUMH-UHFFFAOYSA-N ethene;phenol Chemical group C=C.OC1=CC=CC=C1 YXOGSLZKOVPUMH-UHFFFAOYSA-N 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 229960002900 methylcellulose Drugs 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- GVVGQWPLZQAOSX-UHFFFAOYSA-N n'-(2-aminoethyl)ethane-1,2-diamine;sodium Chemical compound [Na].NCCNCCN GVVGQWPLZQAOSX-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 238000010020 roller printing Methods 0.000 description 1
- 238000010022 rotary screen printing Methods 0.000 description 1
- 229940034586 silk sericin Drugs 0.000 description 1
- 230000036548 skin texture Effects 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Decoration Of Textiles (AREA)
- Coloring (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は異色、異風合及び異透過性が同一表面上に混在
する特殊表面絹布およびその製造方法に関する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a special surface silk fabric in which different colors, different textures, and different permeabilities coexist on the same surface, and a method for producing the same.
（従来の技術）
従来から絹の物理的、化学的特性を生かして新しい風合
を絹に付与する方法は種々行なわれている。例えば濃厚
な塩水溶液を用いて爆縮させる方法、ストーンウォッシ
ュ加工等でフィブリル化させピーチスキン調風合を付与
する方法、樹脂をグラフトし増量させる方法、ホルマリ
ン等のアルデヒド類、クロム明ばん等の重金属塩類、メ
ラミンタンニン、反応染料で処理することや、あるいは
特開昭４７−３２１１０号公報記載の如くロダンカリ水
溶液に浸漬後エポキシ化合物のパークロルエチレン溶液
中で処理することや、あるいは特公昭５２−３９９３３
号公報記載の如くエポキシ化合物の水溶液あるいは水／
有機溶剤混合溶液でｐＨ９以下で６５℃以下で処理する
ことによりセリシンを定着する方法等がある。(Prior Art) Various methods have been used to impart new textures to silk by taking advantage of its physical and chemical properties. For example, implosion using a concentrated salt aqueous solution, fibrillation through stonewashing to give a peach skin texture, grafting resin to increase the volume, aldehydes such as formalin, chromium alum, etc. Treatment with heavy metal salts, melamine tannin, or reactive dyes, or treatment in a perchlorethylene solution of an epoxy compound after immersion in a rhodanpotash aqueous solution as described in JP-A No. 47-32110, or treatment in a perchlorethylene solution of an epoxy compound, or 39933
As described in the publication, an aqueous solution of an epoxy compound or water/
There is a method of fixing sericin by treating with an organic solvent mixed solution at pH 9 or lower and 65° C. or lower.
（発明が解決しようとする課Ｂ）
しかしながら前記の如く絹に新しい風合を付与する方法
はいずれも絹布の表面を一様に加工することを目的とし
ており、表面が一様でない加工を再現性よく行なうには
非常に複雑な技術を要する。(Problem B to be solved by the invention) However, as mentioned above, all of the methods for imparting a new texture to silk are aimed at uniformly processing the surface of silk cloth, and it is difficult to reproducibly process the surface to be uneven. It requires very complex techniques to do well.
また異なった風合にするため糊付や樹脂加工を印捺方式
で行なう方法もあるが、風合が粗硬になり、耐久性も悪
いという欠点を有する。更にこれら従来技術には異風合
のみならず異色及び異透過性が同一表面上に混在するも
のを追求したものはなかった。There is also a method of applying glue or resin processing using a printing method to create a different texture, but this has the drawbacks of a rough and hard texture and poor durability. Furthermore, none of these prior art attempts to create a surface in which not only different textures but also different colors and different permeabilities coexist on the same surface.
本発明はかかる問題点を解決するものであって、風合が
粗硬にならず、しかも耐久性のある風合を有し、しかも
同一表面に異風合、異色及び異透過性が混在する新しい
表面感覚を持つ特殊表面絹布およびその製造法を提供す
ることを目的とするものである。The present invention is intended to solve these problems, and is a new method that does not have a rough texture, has a durable texture, and has different textures, different colors, and different permeability on the same surface. The object of the present invention is to provide a special surface silk fabric with a surface feel and a method for producing the same.
（課題を解決するための手段）
上述の目的を達成するために本発明は次の様な構成を有
する。(Means for Solving the Problems) In order to achieve the above object, the present invention has the following configuration.
即ち第１番目の発明は絹布の少なくとも片面にセリシン
、エポキシ架橋部分がセリシン定着部分として模様状に
形成され、該セリシン定着部分がセリシン除去部分に比
較し濃色に染まっていると共に風合が硬くなっており、
且つ透過性が大きくなっていることを特徴とする特殊表
面絹布を要旨とし、また第２番目の発明はセリシンを付
着している未精練絹布の少なくとも片面に、エポキシ化
合物を含有する糊組成物を印捺し、乾＠後引き続き熱処
理し、次いで精練後引き続き染色することを特徴とする
特殊表面絹布の製造方法を要旨とする。That is, in the first invention, sericin and epoxy cross-linked parts are formed in a pattern on at least one side of a silk cloth as sericin-fixed parts, and the sericin-fixed parts are dyed in a darker color and have a harder texture than the parts from which sericin has been removed. has become,
The second invention is characterized by a special surface silk cloth characterized by high permeability, and the second invention is characterized in that a glue composition containing an epoxy compound is applied to at least one side of the unscoured silk cloth to which sericin is attached. The gist of this invention is a method for producing a special surface silk fabric, which is characterized by printing, drying, followed by heat treatment, and then scouring and subsequent dyeing.
以下、本発明の詳細な説明する。The present invention will be explained in detail below.
本発明に使用する絹布は、セリシンの付着している未精
練絹布であるが、セリシン量の多いものほど好ましく、
従って生糸からなる布が好ましい。The silk cloth used in the present invention is an unscoured silk cloth to which sericin is attached, and the higher the amount of sericin, the more preferable it is.
Therefore, cloth made of raw silk is preferred.
本発明に使用する糊組成物はエポキシ化合物糊剤及び水
からなる。エポキシ化合物の反応触媒は特に必要としな
いが、糊組成によって添加するとエポキシ化合物の使用
量を減らすことができる。The glue composition used in the present invention consists of an epoxy compound glue and water. Although a reaction catalyst of an epoxy compound is not particularly required, the amount of epoxy compound used can be reduced if it is added depending on the glue composition.
本発明に使用するエポキシ化合物は、
工程上好ましい。かかる水溶性エポキシ化合物としては
、エチレングリコール、ポリエチレングリコール、プロ
ピレングリコール、ポリプロピレングリコール、グリセ
リン、ソルビトール、ポリグリセロール、ペンタエリス
リトール、トリス（２−ヒドロキシエチル）イソシアヌ
レート、トリメチロールプロパン、ネオペンチルグリコ
ール、フェノールエチレンオキサイド、ラウリルアルコ
ールエチレンオキサイドのモノ及びポリグリシジルエー
テルが挙げられる。使用量は糊組成物の１〜２５重量％
、好ましくは２〜２０重置％である。The epoxy compound used in the present invention is preferable from the viewpoint of the process. Such water-soluble epoxy compounds include ethylene glycol, polyethylene glycol, propylene glycol, polypropylene glycol, glycerin, sorbitol, polyglycerol, pentaerythritol, tris (2-hydroxyethyl) isocyanurate, trimethylolpropane, neopentyl glycol, phenol ethylene. oxide, mono- and polyglycidyl ethers of lauryl alcohol ethylene oxide. The amount used is 1 to 25% by weight of the glue composition.
, preferably 2 to 20%.
触媒としては、中性塩や弱アルカリ性塩やアルカリ性塩
を用いることができるが、クエン酸ナトリウム、ジエチ
レントリアミンベンター酢＃５ナトリウム、塩化ナトリ
ウム等が好ましく用いられる。As the catalyst, neutral salts, weakly alkaline salts, and alkaline salts can be used, and sodium citrate, sodium diethylenetriamine venter vinegar #5, sodium chloride, etc. are preferably used.
使用量は種類により異なるが糊組成物の０〜１５重量％
である。The amount used varies depending on the type, but is 0 to 15% by weight of the glue composition.
It is.
糊剤としては、捺染に用いる糊を用いることができるが
、澱粉、加工澱粉、アルギン酸ナトリウム、メチルセル
ロース、カルボキシメチルセルロース、グアーガム、ガ
ラクトマンナン、さらに珪藻土やモン七１Ｊロナイト等
からなる鉱物系糊剤やそれらの配合品が好ましく、アル
ギン酸ナトリウム、高エーテル化度のカルボキシメチル
セルロース、鉱物系糊剤やそれらの配合品がエポキシ化
合物と反応せず、従って粘度を異常に変化させず、また
洗浄で除去できる点で特に好ましい。使用量は種類によ
り異なるが糊組成物の２〜１５重量％である。As the sizing agent, the sizing agent used for printing can be used, but starch, modified starch, sodium alginate, methyl cellulose, carboxymethyl cellulose, guar gum, galactomannan, mineral sizing agents such as diatomaceous earth and Mon-7 1J lonite, etc. Formulations of sodium alginate, carboxymethylcellulose with a high degree of etherification, mineral thickening agents, and formulations thereof are preferred because they do not react with epoxy compounds, do not abnormally change the viscosity, and can be removed by washing. Particularly preferred. The amount used varies depending on the type, but is 2 to 15% by weight of the glue composition.
かかるエポキシ化合物を含有する糊組成物を未精練絹布
に印捺する方法は、特に限定されないが、通常はローラ
捺染法、ロータリースクリーン捺染法、オートスクリー
ン捺染法等が用いられる。印捺量は印捺方法、糊組成、
布の種類により異なるがエポキシ樹脂が印捺部の布重量
に対して１〜２５重量％付与されることが好ましい。The method for printing the paste composition containing such an epoxy compound on unscoured silk cloth is not particularly limited, but roller printing, rotary screen printing, autoscreen printing, etc. are usually used. The amount of printing depends on the printing method, glue composition,
Although it varies depending on the type of cloth, it is preferable that the epoxy resin be applied in an amount of 1 to 25% by weight based on the weight of the cloth in the printed area.
かかる印捺を施した布は８０〜１２０℃で乾燥され次い
で熱処理される。熱処理は乾熱処理、温熱処理等の方法
を用いることができるが、１００〜１２０℃の飽和蒸気
または１００−１６０℃の過熱蒸気を用いて、５〜３０
分蒸熱することが好ましい、セリシンの定着率の点で飽
和蒸気による蒸熱が特に好ましい。The cloth with such printing is dried at 80 to 120°C and then heat treated. The heat treatment can be carried out by methods such as dry heat treatment or warm heat treatment, but it is possible to use saturated steam at 100-120°C or superheated steam at 100-160°C for 5-30°C.
Steaming with saturated steam is preferred, and steaming with saturated steam is particularly preferred in terms of the fixation rate of sericin.
かかる印捺、乾燥、熱処理を施し、セリシンエポキシ架
橋部分がセリシン定着部分として模様状に形成された布
は次に精練してセリシン未定着部分のセリシン及びセリ
シン定着部分の糊剤や未反応物を除去する。精練は精練
薬荊として石鹸。After such printing, drying, and heat treatment, the cloth in which the sericin epoxy crosslinked portion is formed into a pattern as the sericin-fixed portion is then scoured to remove the sericin from the sericin-unfixed portion and the glue and unreacted materials from the sericin-fixed portion. Remove. Scouring is soap as a scouring medicine.
アルカリ、石鹸アルカリ併用、酵素及び界面活性剤等を
用いることができる。これらの薬荊を用いて吊、ジンガ
ー等の方法で精練する。精練布には既に異風合、異透過
性が顕在化している。即ち、セリシン定着部分がセリシ
ン除去部分に比較し風合が硬くなっていると共に透過性
が大きくなっている。Alkali, a combination of soap and alkali, enzymes, surfactants, etc. can be used. These medicinal plants are used for scouring using methods such as hanging and zinger. The scouring cloth already has a different texture and different permeability. That is, the sericin-fixed portion has a harder texture and greater permeability than the sericin-removed portion.
かかる精練を施した布は次に酸性染料や、含金染料、ク
ロム染料１及応染料を用いて常法により染色する。セリ
シン定着部分がセリシン除去部分に比較して濃色となる
。The cloth subjected to such scouring is then dyed in a conventional manner using acid dyes, metal dyes, chromium dyes, and other dyes. The sericin-fixed area becomes darker than the sericin-removed area.
また、エポキシ化合物が模様状に形成された布またはそ
の後染色した布は、必要であればロータリワッシャーや
液流染色機を用いてフィブリル化処理を行なう、フィブ
リル化処理により、セリシン除去部分はフィブリル化し
、ピーチスキン調の風合となり、セリシン定着部分とセ
リシン除去部分の透過性の差が強調されるようになる。In addition, for fabrics with epoxy compounds formed in patterns or fabrics that have been dyed afterwards, fibrillation treatment can be performed using a rotary washer or jet dyeing machine if necessary. , the texture becomes peach skin-like, and the difference in permeability between the sericin-fixed area and the sericin-removed area is emphasized.
そしてセリシン定着部分とセリシン除去部分の風合の差
を強調するためには浴中柔軟側を加えてフィブリル化処
理をすることが好ましい。In order to emphasize the difference in texture between the sericin-fixed area and the sericin-removed area, it is preferable to add a soft side to the bath and perform fibrillation treatment.
本発明の絹布は、セリシン、エポキシ架橋部分がセリシ
ン定着部分として模様状に形成され、セリシン定着部分
がセリシン除去部分に比較し濃色に染まっていると共に
風合が硬くなっており、且つ透過性が大きくなっている
ことを本質とする。The silk cloth of the present invention has sericin and epoxy cross-linked parts formed in a pattern as sericin-fixed parts, and the sericin-fixed parts are dyed in a darker color and have a harder texture than the sericin-removed parts, and are transparent. The essence is that it is increasing.
（作用）
エポキシ化合物を印捺、乾燥し、熱処理することにより
、エポキシ化合物は絹のセリシンの水酸基やアミノ基や
カルボキシル基等の官能基と反応するようになる。(Function) By printing, drying, and heat-treating the epoxy compound, the epoxy compound comes to react with functional groups such as hydroxyl groups, amino groups, and carboxyl groups of silk sericin.
反応したものの一部は架橋し、セリシン、エポキシ架橋
部分を形成しセリシンは定着され、精練や染色あるいは
洗濯等の後工程によって除去されなくなり、即ち耐久性
がでてくるようになる。A portion of the reacted material crosslinks to form sericin and epoxy crosslinked portions, and the sericin is fixed and cannot be removed by post-processes such as scouring, dyeing, or washing, and thus becomes durable.
また一般的にセリシンはフィブロインに比して染料の吸
着がよく、そのためセリシン定着部分は濃色となる。風
合もセリシンはフィブロインに比して硬り、シやり感、
張り感があり、セリシン定着部分はその風合が残こせる
ようになる。またセリシンを除去しない組織物は除去し
たものに比し透明感が優っており、セリシン定着でその
特性が残こせ、セリシン除去部分即ちフィブロイン部分
に比して透過性が大となるのである。Additionally, sericin generally has better adsorption of dye than fibroin, and therefore the sericin-fixed area becomes dark colored. Regarding the texture, sericin is harder and has a softer feel than fibroin.
There is a feeling of tension, and the texture remains in the sericin-fixed area. In addition, tissues from which sericin has not been removed have a superior transparency than those from which sericin has been removed, and the sericin fixation retains this characteristic, resulting in greater permeability than the sericin-removed portions, that is, the fibroin portions.
（実施例） 以下、本発明を実施例に基づき詳細に説明する。(Example) Hereinafter, the present invention will be explained in detail based on examples.
実施例中、風合はＫＥＳ−ＦＢシステム（カトーテ、り
製）によりＢ値を測定し経、緯の平均値で示した。また
、染色濃度は測色機マクベスカラーアイＭＳ２０２０に
より所定波長のに／Ｓを測定した。また透過性は測色機
マクベスカラーアイＭＳ２０２０により所定波長の透過
率を測定した。In the examples, the texture was measured by measuring the B value using the KES-FB system (manufactured by Katote, Ri), and was expressed as the average value of the warp and weft. Further, the dyeing density was measured by /S at a predetermined wavelength using a colorimeter Macbeth Color Eye MS2020. Further, the transmittance at a predetermined wavelength was measured using a colorimeter Macbeth Color Eye MS2020.
実施例１
経糸に２１ｄ生糸を緯糸に２１ｄ生糸３本を撚り合わせ
た糸を用いて製織したフラットクレープにエポキシ化合
物としてエチレングリコールジグリシジールエーテル（
ブナコールＥＸ−８１０ナガセ化成製）１０重量％、触
媒として塩化ナトリウム１０重量％、糊剤として低粘度
タイプアルギン酸ナトリウムの元糊（７，５重量％液と
して調整）６０重量％、水２０重量％からなる糊組成物
（粘度１００００ＣＰ、ｐＨ１０，８）を１２０メソシ
ユのスクリーン型を備えたオートスクリーン捺染機にて
印捺し、乾燥後、次いでスタースチーマ−で１０２℃の
飽和蒸気で２０分間蒸熱し湯洗水洗、乾燥した。次にセ
リシン、エポキシ架橋部分がセリシン定着部分として模
様状に形成されたフラットクレープをマルセル石鹸５
ｇ／ｌ、珪酸ナトリウム（３０６Ｂｅ）５ｃｃ／ｆから
なる精練浴で１００℃で６０分精練し、セリシン未定着
部分のセリシンを溶解除去し湯洗、水洗、乾燥した。Example 1 Ethylene glycol diglycidyl ether (
Bunacol EX-810 manufactured by Nagase Kasei) 10% by weight, 10% by weight of sodium chloride as a catalyst, 60% by weight of low viscosity type sodium alginate base glue (adjusted as a 7.5% liquid) as a sizing agent, and 20% by weight of water. The paste composition (viscosity 10000CP, pH 10.8) was printed using an autoscreen printing machine equipped with a 120 mesh screen type, dried, and then steamed with saturated steam at 102°C for 20 minutes in a star steamer and washed with hot water. Washed with water and dried. Next, a flat crepe with sericin and epoxy cross-linked parts formed in a pattern as a sericin fixing part was added to Marcel Soap 5.
g/l, sodium silicate (306Be) for 60 minutes in a scouring bath consisting of 5 cc/f of sodium silicate (306Be) for 60 minutes to dissolve and remove unfixed sericin, followed by washing with hot water, water, and drying.
精練の際、未精練布から、セリシン定着部分とセリシン
除去部分の一部をそれぞれサンプリングして精練浴で同
時に精練したが、減量率はセリシン定着部分１．８％、
セリシン除去部分２４．５％であった。セリシン定着部
分はセリシン除去部分に比較して風合が硬く、透過性が
あった。尚、風合の違いはＫＥＳのＢ値で比較するとセ
リシン定着部分は０．０５１０ 、セリシン除去部分は
０、０１０８であり、また透過性の違いは波長４５Ｑｎ
ｍの透過率を比較するとセリシン定着部分は７．２２％
、セリシン除去部分は１．９５％であった。この布をＪ
ＩＳ Ｌ ０２１７ １０６法に準じて手洗い洗濯
したがＫＨＳＯ３値はセリシン定着部分０．０５１５
、セリシン除去部分０、０１１１であり、波長４６０
ｎｍの透過率はセリシン定着部分７，１８％、セリシン
除去部分１．９３％となり洗濯前と大差はなかった。During scouring, a part of the sericin-fixed part and a part of the sericin-removed part were each sampled from the unscoured cloth and scoured at the same time in a scouring bath, and the weight loss rate was 1.8% in the sericin-fixed part.
The sericin removed portion was 24.5%. The sericin-fixed area had a harder texture and was more permeable than the sericin-removed area. Furthermore, when comparing the B value of KES, the difference in texture is 0.0510 for the sericin-fixed area and 0.0108 for the sericin-removed area, and the difference in transmittance is at wavelength 45Qn.
Comparing the transmittance of m, the sericin fixed part is 7.22%.
, the sericin removed portion was 1.95%. This cloth
I washed it by hand according to IS L 0217 106 method, but the KHSO3 value was 0.0515 in the sericin-fixed area.
, the sericin removed portion is 0, 0111, and the wavelength is 460
The transmittance in nm was 7.18% in the sericin fixed area and 1.93% in the sericin removed area, which was not much different from before washing.
次に、精練布をＩｒｇａｌａｎ Ｙｅｌｌｏ＠２ＧＬ
（シバガイギーー社製）１％ｏ ｗ ｆ 、 Ｉｒｇａ
ｌａｎ Ｂｒｏｗｎ ２ＧＬ（シバガイギー■社製）０
．３％ｏ ｗ ｆ 、 Ｉｒｇａｌａｎ ＧｒｅｙＢＬ
（シバガイギー■社製）０．８％ｏｗｆからなる含金
染料を用いて吊で常法により染色を行ない、オリーブ色
に染色した。セリシン定着部分はセリシン除去部分に比
較して濃色に染まり、風合が硬く、透過性が大きくなっ
た。尚、濃度の違いは波長４６０ｎｍのに／Ｓで比較す
ると、セリシン定着部分は１８．２ 、セリシン除去部
分は１０．１であり、また風合の違いはＫＨＳＯ３値で
比較すると、セリシン定着部分は０．０４８２、セリシ
ン除去部分はＯ，Ｏｌ ０６であり、更に透過性の違い
は波長４６０ｎｍの透過率で比較すると、セリシン定着
部分は６．２０％、セリシン除去部分は１．９３９／６
であった。Next, the scouring cloth is Irgalan Yellow@2GL
(manufactured by Shiva Geigy) 1% o w f, Irga
lan Brown 2GL (manufactured by Shiba Geigy) 0
．． 3%ow f,Irgalan GrayBL
(manufactured by Shiba Geigy ■) Using a metal-containing dye consisting of 0.8% OWF, dyeing was carried out by hanging in a conventional manner to obtain an olive color. The sericin-fixed area was dyed darker, had a harder texture, and had greater permeability than the sericin-removed area. In addition, the difference in density is 18.2 in the sericin-fixed part and 10.1 in the sericin-removed part when compared with /S at a wavelength of 460 nm, and the difference in texture is compared by the KHSO3 value in the sericin-fixed part. 0.0482, the sericin removed part is O, Ol 06, and the difference in transmittance is when comparing the transmittance at a wavelength of 460 nm, the sericin fixed part is 6.20%, and the sericin removed part is 1.939/6
Met.
実施例２
実施例１でオリーブ色に染色した布を浴中柔軟剤（ファ
インソフ）ＡＱ−１００（第−工業製薬−社製）、１ｇ
／ｌ）を加えた加工浴でラスタム型液流染色機（凡用工
業製）を用いてフィブリル化処理し、タンブラ−乾燥し
て実施例２の製品を得た。尚、液流染色機の処理条件は
速度６０ｍ／分浴比１：３０．温度６０℃１時間３０分
であった。Example 2 The cloth dyed olive color in Example 1 was treated with 1 g of bath softener (Fine Soft) AQ-100 (manufactured by Dai-Kogyo Seiyaku Co., Ltd.).
The product of Example 2 was obtained by fibrillation treatment using a Rustum type jet dyeing machine (manufactured by Bonyo Kogyo Co., Ltd.) in a processing bath to which 1/l) was added, followed by tumble drying. The processing conditions of the jet dyeing machine are a speed of 60 m/bath ratio of 1:30. The temperature was 60°C for 1 hour and 30 minutes.
実施例２で得られた製品はセリシン除去部分がフィブリ
ル化されピーチスキン調になった。尚、風合の違いはＫ
ＥＳのＢ値で比較すると、セリシン定着部分は０．０５
１２、セリシン除去部分は０、０１０１ 、また透過性
の違いは波長４６０ ｎｍの透過率で比較すると、セリ
シン定着部分は６．１４％、セリシン除去部分は１．６
６％であった。In the product obtained in Example 2, the sericin-removed portion was fibrillated and had a peach skin tone. In addition, the difference in texture is K.
Comparing the B value of ES, the sericin fixed area is 0.05
12. The sericin-removed area is 0.0101, and the difference in transmittance is 6.14% for the sericin-fixed area and 1.6% for the sericin-removed area when comparing the transmittance at a wavelength of 460 nm.
It was 6%.
この布をＪＩＳ Ｌ ０２０７ １０５法に準じて
洗濯したがＫＥＳのＢ値はセリシン定着部分０、０５２
１ 、セリシン除去部分０．０１０１であり、波長４６
０ｎｍの透過率はセリシン定着部分６．１４％、セリシ
ン除去部分１．６６％となり洗濯前と大差はなかった。This cloth was washed according to the JIS L 0207 105 method, but the KES B value was 0.052 for the sericin fixed area.
1, the sericin removed portion is 0.0101, and the wavelength is 46
The transmittance at 0 nm was 6.14% in the sericin fixed area and 1.66% in the sericin removed area, which was not much different from before washing.
（発明の効果）
以上詳述したよう−に本発明に係る特殊表面絹布は、異
色、異風台及び異透過性が同一表面上に混在したファツ
ション性に優れたものであり、しかも風合が粗硬でなく
耐久性を存し、カジュアル用途等として頗る有用であり
、従来絹布が用い得なかった用途にも応用可能である。(Effects of the Invention) As detailed above, the special surface silk fabric according to the present invention has excellent fashionability with different colors, different patterns, and different permeability mixed on the same surface, and has a rough texture. It is not hard and durable, making it extremely useful for casual uses, and can be applied to uses where silk cloth could not be used conventionally.
また本発明方法は、特殊な装置を用いないで実施可能な
もので、その有用性は明らかである。Furthermore, the method of the present invention can be carried out without using special equipment, and its usefulness is obvious.
Claims (2)
部分がセリシン定着部分として模様状に形成され、該セ
リシン定着部分がセリシン除去部分に比較し濃色に染ま
っていると共に風合が硬くなっており、且つ透過性が大
きくなっていることを特徴とする特殊表面絹布。(1) Sericin and epoxy cross-linked parts are formed in a pattern on at least one side of the silk cloth as sericin-fixed parts, and the sericin-fixed parts are dyed in a darker color and have a harder texture than the sericin-removed parts, A special surface silk cloth characterized by high permeability.
片面に、エポキシ化合物を含有する糊組成物を印捺し、
乾燥後引き続き熱処理し、次いで精練後引き続き染色す
ることを特徴とする特殊表面絹布の製造方法。(2) printing a glue composition containing an epoxy compound on at least one side of the unscoured silk cloth to which sericin is attached;
A method for producing a special surface silk fabric, which is characterized in that it is subsequently heat treated after drying, and then dyed after scouring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2112272A JPH0411084A (en) | 1990-04-28 | 1990-04-28 | Specific surface silk fabric and production thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2112272A JPH0411084A (en) | 1990-04-28 | 1990-04-28 | Specific surface silk fabric and production thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0411084A true JPH0411084A (en) | 1992-01-16 |
Family
ID=14582554
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2112272A Pending JPH0411084A (en) | 1990-04-28 | 1990-04-28 | Specific surface silk fabric and production thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0411084A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999007934A1 (en) * | 1997-08-07 | 1999-02-18 | Kanehisa Inc. | Method of production of woven/knitted fabrics using sericin fixation yarn and woven/knitted fabric produced by the method |
| KR100397654B1 (en) * | 2000-07-18 | 2003-09-13 | 박건용 | Dyeing Method for Silk Fabrics |
-
1990
- 1990-04-28 JP JP2112272A patent/JPH0411084A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999007934A1 (en) * | 1997-08-07 | 1999-02-18 | Kanehisa Inc. | Method of production of woven/knitted fabrics using sericin fixation yarn and woven/knitted fabric produced by the method |
| KR100397654B1 (en) * | 2000-07-18 | 2003-09-13 | 박건용 | Dyeing Method for Silk Fabrics |
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