JPS6385186A - Dyeing of cellulosic fiber cloth - Google Patents
Dyeing of cellulosic fiber clothInfo
- Publication number
- JPS6385186A JPS6385186A JP61226527A JP22652786A JPS6385186A JP S6385186 A JPS6385186 A JP S6385186A JP 61226527 A JP61226527 A JP 61226527A JP 22652786 A JP22652786 A JP 22652786A JP S6385186 A JPS6385186 A JP S6385186A
- Authority
- JP
- Japan
- Prior art keywords
- printing
- pattern
- dyeing
- printing paste
- urea
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004744 fabric Substances 0.000 title claims description 22
- 238000004043 dyeing Methods 0.000 title claims description 12
- 239000000835 fiber Substances 0.000 title description 4
- 238000007639 printing Methods 0.000 claims description 39
- 238000000034 method Methods 0.000 claims description 37
- 239000003795 chemical substances by application Substances 0.000 claims description 25
- 239000000985 reactive dye Substances 0.000 claims description 11
- 229920003043 Cellulose fiber Polymers 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000003513 alkali Substances 0.000 claims description 9
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 8
- 239000004202 carbamide Substances 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 5
- 239000000980 acid dye Substances 0.000 claims description 4
- 150000003945 chlorohydrins Chemical class 0.000 claims description 2
- 150000003242 quaternary ammonium salts Chemical group 0.000 claims description 2
- 238000004513 sizing Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 description 14
- 239000000975 dye Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 6
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 238000010025 steaming Methods 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 238000010018 discharge printing Methods 0.000 description 3
- 238000009940 knitting Methods 0.000 description 3
- 239000000661 sodium alginate Substances 0.000 description 3
- 235000010413 sodium alginate Nutrition 0.000 description 3
- 229940005550 sodium alginate Drugs 0.000 description 3
- 238000009941 weaving Methods 0.000 description 3
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 1
- VLRGXXKFHVJQOL-UHFFFAOYSA-N 3-chloropentane-2,4-dione Chemical compound CC(=O)C(Cl)C(C)=O VLRGXXKFHVJQOL-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000280258 Dyschoriste linearis Species 0.000 description 1
- 108010088249 Monogen Proteins 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical compound C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000010021 flat screen printing Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000003165 hydrotropic effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 238000009971 piece dyeing Methods 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 238000010019 resist printing Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
- 239000000984 vat dye Substances 0.000 description 1
- 235000001459 whitebark Nutrition 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Landscapes
- Coloring (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Abstract] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
産業上の利用分野
セルロース系繊維布帛にカチオン化処理を利用して複雑
な捺染模様を付与する方法に関する。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a method for imparting complex printing patterns to cellulose fiber fabrics using cationization treatment.
従来技術
セルロース系繊維布帛の染色性を高めるために、セルロ
ース繊維をカチオン化処理することは、例えば特開昭５
９−１７３３８７号公軸、特開昭６０−９９８０号公報
、特開昭６０−１３４０８０号公報、特開昭６０−２３
１８６７号公報などによって知られているが、その適用
法は、セルロース系繊維布帛に、カチオン化剤を浸漬法
又はパッド法により、全面に付着させ、アニオン染料に
よる染着性を向上させる、カチオン化処理した糸を、未
処理の糸又はアニオン化処理した糸と混紡し、編織後、
染色して霜降り効果を得る、或いはタオルにカチオン化
剤で印入れをし、その後に浸染して印を濃色に染め分け
るなどに限られていた。Prior Art In order to improve the dyeability of cellulose fiber fabrics, cationization treatment of cellulose fibers has been described, for example, in JP-A No. 5
Public axis No. 9-173387, JP-A-60-9980, JP-A-60-134080, JP-A-60-23
It is known from Publication No. 1867, etc., and its application method is to apply a cationizing agent to the entire surface of cellulose fiber fabric by dipping or padding to improve dyeability with anionic dyes. The treated yarn is blended with untreated yarn or anionized yarn, and after knitting and weaving,
The methods used were limited to dyeing the towel to create a marbling effect, or stamping the towel with a cationizing agent, and then dyeing the towel in dark colors.
しかし、全面にカチオン化された布帛への捺染法の適用
は、防抜染により全面に地染めをしだ場合を除いて、特
に白地や淡い着色地に直接捺染した場合、水洗によって
脱落した染料が裏面に染着するなど、汚染の問題が生じ
、品位の点で工程管理がかなり困難なものとなった。ま
た、カチオン化の効果も、適用される染料が増え、捺染
によって得られる模様が、従来より濃色かつ鮮明に染着
されるというだけであって、特に変化に富んだ製品が得
られるものでもなかった。However, when applying the printing method to cationized fabrics on the entire surface, unless the entire surface is ground-dyed using anti-discharge printing, especially when printing directly on white or lightly colored materials, the dye that comes off when washed with water cannot be applied. Contamination problems such as dyeing on the back side arose, making process control extremely difficult in terms of quality. In addition, the effect of cationization is that the number of dyes that can be applied increases, and the patterns obtained by printing are dyed in darker and more vivid colors than before, but it does not mean that products with a particularly rich variety can be obtained. There wasn't.
また、カチオン化処理した糸の使用では、後染めによっ
て、霜降り効果は得られるが、混紡糸の製造およびその
編織などに複雑な工程を要する割に、特別な意匠効果は
得難り、その商品展開には限度があり、更に、カチオン
化剤で印入れ後、浸°染した製品では印の染め分は効果
は得られるが、通常の着色抜染以上の効果は得られず、
いずれの場合も平面的な着色模様しか得られなかった。In addition, when using cationized yarn, a marbling effect can be obtained by piece dyeing, but it is difficult to obtain a special design effect because the production of blended yarn and its knitting and weaving require complicated processes. There is a limit to the development, and furthermore, products that are dyed after being stamped with a cationizing agent will be effective in dyeing the stamp, but will not be as effective as normal colored discharge printing.
In either case, only a flat colored pattern was obtained.
発明が解決しようとする問題
本発明は、このようなカチオン化処理を利用して、より
変化に富んだ、深みのある模様布帛を得る方法を提供す
ることを目的とする。Problems to be Solved by the Invention It is an object of the present invention to provide a method for obtaining patterned fabrics with greater variety and depth by utilizing such cationization treatment.
問題を解決するための手段
本発明の方法はセルロース系繊維布帛に、カチオン化剤
を含む処理液を模様状に印捺し、乾燥、熱処理、水洗後
、更に、着色捺染糊を模様状に印（奈することを共に使
用するものである。Means for Solving the Problems The method of the present invention involves printing a treatment liquid containing a cationizing agent in a pattern on a cellulose fiber fabric, drying, heat treating, and washing with water, and then printing a colored printing paste in a pattern ( It is used together with ``nasu''.
即ち、本発明では、セルロース系繊維布帛の表面を部分
的にカチオン化することにより、カチオン化部分と未処
理部分の染着性に差をもたせ、しかも、その後着色捺染
することによって、着色模様が部分的に染着されなかっ
たり、濃淡差をもって複雑に現れ、地紋を有する如き、
深みのある複雑な非常に妙味ある模様を形成しつる。That is, in the present invention, by partially cationizing the surface of the cellulose fiber fabric, a difference is created in the dyeability of the cationized portion and the untreated portion, and furthermore, by color printing after that, the colored pattern is created. Partially undyed, complex shading, and background patterns.
The vines form deep, complex, and very interesting patterns.
本発明で使用するカチオン化剤の種類は特に限定されず
、市販のものがいずれも使用できるが、第４級アンモニ
ウム塩型クロルヒドリン誘導体、例えば３−クロル−２
−ヒドロキシプロピルトリメチルアンモニウムクロライ
ド
Ｃ１０１１
の使用が、染色時の染着量及び固着率が高く、鮮明度及
び各種堅牢度に優れるので特に有用である。The type of cationizing agent used in the present invention is not particularly limited, and any commercially available one can be used, but quaternary ammonium salt type chlorohydrin derivatives, such as 3-chloro-2
The use of -hydroxypropyltrimethylammonium chloride C1011 is particularly useful because it has a high dyeing amount and fixation rate during dyeing, and is excellent in brightness and various fastnesses.
このカチオン化剤は次のようにセルロースと反応する。This cationizing agent reacts with cellulose as follows.
カチオン化剤は、アルカリ条件下でセルロースと反応す
るため、カチオン化処理液は一般にカチオン化剤、アル
カリ剤及び印捺用糊剤がら構成される。Since the cationizing agent reacts with cellulose under alkaline conditions, the cationizing treatment liquid generally includes the cationizing agent, an alkaline agent, and a printing paste.
カチオン化剤は３〜１５％（有効成分量）程度使用され
ればよいが、安定性、経済性を加味すると４〜８％であ
るのが好ましい、また、アルカリの使用量はカチオン化
剤の量に対して３０〜６０％でほぼ平衡に達するが、処
理の安定性及び処理液の経時安定性などを考慮するとカ
チオン化剤の量に対して４０±５％位であるのが好まし
い。The cationizing agent should be used in an amount of about 3 to 15% (active ingredient amount), but considering stability and economy, it is preferably 4 to 8%.Also, the amount of alkali used is Equilibrium is almost reached at 30 to 60% of the amount of the cationizing agent, but in consideration of the stability of the process and the stability of the treatment solution over time, it is preferably about 40±5% of the amount of the cationizing agent.
印捺用糊剤は耐アルカリ性を有し、カチオン化剤やアル
カリ剤の影口を受けＩｔい糊剤の中から選ばれればよい
が、特にアルギン酸ソーダ、高エーテル化ＣＭＣなどの
使用がよい。The printing paste may be selected from among adhesives that have alkali resistance and are resistant to the effects of cationizing agents and alkaline agents, but sodium alginate, highly etherified CMC, and the like are particularly preferred.
処理液の粘度は、印捺時の絵際のシャープ性を保持する
点などから（布帛の厚さ、前処理の差などによって変化
するが） ４，０００〜１０，０００ｃｐｓ位の間が良
好である。The viscosity of the processing liquid is preferably between 4,000 and 10,000 cps (this varies depending on the thickness of the fabric, differences in pre-treatment, etc.) in order to maintain the sharpness of the edges of the image during printing. be.
カチオン化処理′は、かかる処理液を用いて実施される
が、その印捺法はローラー、ロータリー、フラットスク
リーン捺染または手捺染、いずれによってもよい、（１
）カチオン化処理が連続的に継目なしに行える点、（２
）作業効率（加工速度）を考慮すれば、ローラー、ロー
タリー捺染が好ましい。The cationization treatment' is carried out using such a treatment liquid, and the printing method may be roller, rotary, flat screen printing, or hand printing. (1
) The cationization process can be performed continuously and seamlessly, (2)
) Considering work efficiency (processing speed), roller and rotary printing are preferred.
カチオン化処理液の印捺後の乾燥は、通常１００〜１２
０℃で実施され、その後、熱処理される。The drying time of the cationization treatment liquid after printing is usually 100 to 12
It is carried out at 0° C. and then heat treated.
熱処理は乾熱及び湿熱いずれによってもよく、乾熱処理
は１００〜１５０℃で１−１０分間、温熱処理は１００
〜１１０℃で３〜ｌＯ分間程度で十分である。温熱処理
によると白皮は良好であるが、処理収率が若干おちる傾
向があり、乾熱処理によると処理収率は良いが、高温の
場合に黄変する恐れがある。The heat treatment may be performed by either dry heat or wet heat, and the dry heat treatment is performed at 100 to 150 °C for 1 to 10 minutes, and the warm heat treatment is performed at 100 °C to 100 °C.
Approximately 3 to 10 minutes at ~110°C is sufficient. Warm heat treatment produces good white bark, but the yield tends to drop slightly. Dry heat treatment gives good yield, but there is a risk of yellowing at high temperatures.
熱処理後、水洗により糊剤を十分に脱落させ、必要に応
じて酸中和工程を設け、処理布を中性又は弱酸性にする
。After the heat treatment, the size agent is sufficiently removed by washing with water, and if necessary, an acid neutralization step is performed to make the treated cloth neutral or weakly acidic.
本発明では、以上の如く、模様状にカチオン化処理した
布帛に、更に捺染をして、カチオン化処理部分と非処理
部分の染着性の差によって、変化に富んだ模様を現出す
るものであるが、この捺染に適する染料としては、アニ
オン染料である酸性染料、含金染料、反応性染料、直接
染料及び建染染料などがある。特に反応性染料及び酸性
染料の使用が好ましい。In the present invention, as described above, the fabric that has been subjected to cationization treatment in a pattern is further printed to create a pattern rich in variation due to the difference in dyeability between the cationization treatment area and the untreated area. However, dyes suitable for this printing include anionic dyes such as acid dyes, metal-containing dyes, reactive dyes, direct dyes, and vat dyes. Particularly preferred is the use of reactive dyes and acid dyes.
捺染の方法としては、例えば
（１１酸性染料又は反応性染料（染料のみでアルカリ及
び尿素などのヒドロトロープ剤を添加しない）で、カチ
オン化処理とは別の柄を全面に印捺して、カチオン化処
理部分のみを染着する方法（未処理部分は全く染着され
ずに残る）、（２） 従来通りのアルカリ、尿素入り
の反応性染料組成物で印捺し、カチオン化処理部分と未
処理部分を濃淡に染め分け、地紋が存在するかのような
、深みのある、多色効果を表現する方法、（３１（１）
及び（２）を組み合わせて同時捺染し、より複雑な多色
効果を表現する方法、
などがあり、更に、防染法や抜染法などが併用されても
よい。As a printing method, for example, (11) an acid dye or a reactive dye (dye alone, no hydrotropic agent such as alkali or urea is added) is used to print a pattern different from the cationization treatment on the entire surface, and the cationization (2) A method of dyeing only the treated areas (the untreated areas remain completely undyed); (2) printing with a conventional reactive dye composition containing alkali and urea; cationized areas and untreated areas; A method of dyeing in different shades of light and shade to create a deep, multicolored effect that looks as if there is a ground pattern (31 (1)
There is a method of simultaneously printing by combining (2) and (2) to express a more complex multicolor effect.Furthermore, resist printing methods, discharge printing methods, etc. may also be used in combination.
捺染用の代表的なストックペーストの一例としては次の
組成からなるものがある。An example of a typical stock paste for textile printing has the following composition.
アルギン酸ソーダ ４０〜６０ｇ／ＩＩ乳化
剤 ５〜Ｌｕｇ／ｌターペン
８０〜２００ｇ／ｌポリ燐酸塩
５〜１０ｇ／Ｊまた、捺染用の色糊の処方
としては、次の如きものが例示できる。（１１の処方は
前記捺染法（１）で使用されるものであり、（２）の処
方は前記捺染法（２）で使用されるものである。Sodium alginate 40~60g/II emulsifier 5~Lug/l turpentine
80-200g/l polyphosphate
5 to 10 g/J Further, as the formulation of color paste for textile printing, the following can be exemplified. (Regulation number 11 is used in the textile printing method (1), and recipe (2) is used in the textile printing method (2).
＋１１ ＋２１染
料 ＸＸ
重曹 １５〜３０ｇ／ｌ尿
素 ５０〜２００ｇ／Ｊ糊剤
５００〜６００ ｇ／ｌ ５００〜６００ｇ
／＋！捺染における発色は、１４０−１５０℃で３〜６
分のベーキング、又は１００〜１０５℃で５〜１０分の
蒸熱処理で十分であるが、より鮮明な効果を得るために
は、蒸熱処理によるのが好ましい。+11 +21 Dye XX Baking soda 15-30g/l Urea 50-200g/J Paste 500-600 g/l 500-600g
/+! Color development in printing is 3-6 at 140-150℃.
Baking for 1 minute or steaming at 100 to 105° C. for 5 to 10 minutes is sufficient, but steaming is preferred in order to obtain a more vivid effect.
また、全面を（２）濃淡のみで表現する別の方法として
、ビニルスルホン型反応性染料のみで印捺後、二相相に
よるコールドフィックス法又はアルカリショック法で発
色すると濃淡効果はより明確に表現できる。Another method of expressing the entire surface with only shading (2) is to print only with a vinyl sulfone type reactive dye and then develop the color using a two-phase cold-fix method or alkali shock method to express the shading effect more clearly. can.
捺染、発色後の水洗は、通常の反応性染料の水洗法に従
うが、水洗時の耐汚染性や染色堅牢度を向上させるため
に、ソーダ灰／活性剤（アニオン性、例えばモノゲン）
によるソーピングを実施するのが効果的である。Washing with water after printing and color development follows the usual water washing method for reactive dyes, but in order to improve stain resistance and color fastness during washing, soda ash/activator (anionic, e.g. monogen) is used.
It is effective to perform soaping with
本発明では、カチオン化処理をｔＥ ３Ｑ、連続する小
円、小紋のような連続する地紋から一定しピートの大柄
まで、後に印捺される色柄に合わせて種々のデザインに
実施でき、また、ボーダー柄としてのカチオン化処理も
可能であるため、後の捺染法との組み合わせによって、
従来、得ることが出来なかったような複雑な非常に妙味
ある模様を極めて作業性よく得ることができる。In the present invention, the cationization process can be carried out in various designs according to the color pattern to be printed later, from continuous ground patterns such as tE 3Q, continuous small circles and small patterns to large patterns of constant peat, and Cationization treatment is also possible as a border pattern, so by combining it with the subsequent printing method,
Complex and very interesting patterns that could not be obtained conventionally can be obtained with extremely good workability.
実施例１
下記組成からなるカチオン処理液（室温における粘度５
．０ＯＯｃｐｓ） を４０ｘ４０／１２８ｘ６２の綿ブ
ロードに印捺し、１１０ ℃×２分乾燥した。Example 1 Cation treatment liquid consisting of the following composition (viscosity at room temperature: 5
．． 0OOcps) was printed on a 40x40/128x62 cotton broadcloth and dried at 110°C for 2 minutes.
−組一一成一
カ チオ ン化剤 （３−クロル−２−七Ｆロキシブロ
ビルトリメチルアン量ニウムクロライＦの６０ ％ ｔ
ｌｉ Ｗｉ ） １００ｇ／ １苛性
ソーダ（固形） ２５ｇ／ ｊ！ア
ルギン酸ソーダ（５％溶液） ５００ｇ／ １
印捺は、印捺部２−能、非印捺部２−一の縦縞状に彫刻
されたロータリースクリーンを用いて実施した。印捺、
乾燥後、１３０″ｃＸ３分のベーキング後、水洗し、更
に２ ｇ／ ｌの酢酸水溶液で中和し、弱酸性になった
ことを確認した。- Group 1-1 cationizing agent (60% of 3-chloro-2-7F roxybrobyl trimethylammonium chloride F)
li Wi ) 100g/1 Caustic soda (solid) 25g/j! Sodium alginate (5% solution) 500g/1
The printing was carried out using a rotary screen engraved with vertical stripes in the printing part 2-1 and the non-printing part 2-1. Stamp,
After drying, it was baked for 130''x3 minutes, washed with water, and further neutralized with a 2 g/l acetic acid aqueous solution to confirm that it had become weakly acidic.
この加工布に、下記組成からなる４種の色糊で、地型入
りの３色５ｃ■径の水玉柄をロータリースクリーン捺染
した。This processed cloth was rotary screen printed with a three-color, 5 cm diameter polka dot pattern with a ground pattern using four types of colored pastes having the following compositions.
１月ｊ工Ｑ＞
一監一鷹一 上１１±
セルマゾールＢｌａｃｋ Ｂ−Ｌ ８０ −−−
スミフィックスＲｅｄＢＳ −２０−一’
ＢｌｕｅＲ−−２０−
ＶｅｌＩｏｗ Ｒ２０
アルギン台糊 ｓｏｏ ｓｏｏ ｓｏｏ
ｓｏ。January J Engineering Q> First Superintendent One Takaichi Upper 11± Selmazol Black B-L 80 ---
Sumifix RedBS -20-1'
BlueR--20- VelIow R20 Algin stand glue soo soo soo
So.
スチーミング（１００’ｅ ｘ ６分）後、水洗、ソー
とングしたところ、カチオン化処理した部分のみが着色
し、非処理部分は白く残って、美しい白い縦縞と水玉柄
の非常に妙味ある模様布が得られた。After steaming (100'e x 6 minutes), washing with water and sawing, only the cationized areas were colored, while the untreated areas remained white, creating a very interesting pattern with beautiful white vertical stripes and polka dots. A cloth was obtained.
実施例２
実施例１のカチオン処理液を用いて、直径約１−一前後
の変形小玉の集合体で表現されたシャンブレー（霜降り
）調の彫刻柄を、ロータリー捺染機にて捺染し、乾燥し
た。Example 2 Using the cation treatment liquid of Example 1, a chambray-like sculptural pattern expressed by a collection of deformed beads with a diameter of about 1-1 was printed using a rotary printing machine and dried. .
１３０ ’ｅｘ３分ベーキングした後、拡布水洗機を用
いて水洗し、加工布が中性となったことをｆ！認した後
、下記組成からなる色糊を用いて、３ｃｍ幅の４色の縦
縞柄をローラ捺染した。After baking for 130'ex 3 minutes, wash with water using a spreading cloth washer and check that the processed cloth has become neutral. After approval, a 3 cm wide four-color vertical striped pattern was roller printed using a colored paste having the following composition.
兼ＪＬＩ±Ｑ）
」成 上１１１
シバクロン ブルー３Ｒ−Ｐ ２０ − − −タ
ーボイズブルー ＧＦ−Ｐ −２０−−スカーレ
フト ＧＲ−Ｐ −−２０−イＸロー ２
Ｇ−Ｐ −−−２０尿素
５０ ５０ ５０ ５０重炭酸ソーダ
２０ ２０ ２０ ２０台糊
ｓｏｏ ｓｏｏ ｓｏｏ ｓｏ。111 Shibacron Blue 3R-P 20 - - -Turboise Blue GF-P -20--Scar Left GR-P--20-IX Low 2
G-P ---20 urea
50 50 50 50 bicarbonate of soda
20 20 20 20 glue
soo soo soo so.
スチーミング（１００ｔ ｘ ６分）、水洗、ソーピン
グ後、乾燥したところ、カチオン処理部分が濃色に、非
処理部分が淡色に、非常にはっきり染め分けられ、シャ
ンブレー柄の地紋が織り柄で存在するかのような多色濃
淡模様が得られた。After steaming (100t x 6 minutes), washing with water, soaping, and drying, the cation-treated areas were dyed in a dark color and the non-treated areas were dyed in a light color, and the chambray pattern was present in the woven pattern. A multicolored shading pattern like this was obtained.
発明の効果
本発明の方法では、捺染法の組み合わせで、地組織に変
化があるかのような、深みのある非常に変化に富んだ模
様布帛を得ることができる。また、捺染法のみを使用す
るため、カチオン化処理を実施しているにもかかわらず
、汚染のない品質のよい捺染布を作業性よく得ることが
できる。Effects of the Invention According to the method of the present invention, by combining printing methods, it is possible to obtain a fabric with a deep and highly varied pattern that appears to have a variation in the ground texture. In addition, since only the printing method is used, it is possible to obtain a printed fabric of good quality without contamination with good workability despite the cationization treatment.
特許出願人 大同マルタ染工株式会社
代 理 人 新 実 健 部外１名
手続補正書
１．事件の表示 昭和６１年特許願第２２６５２７号２
、発明の名称 セルロース系繊維布帛の染色方法３、補
正をする者
事件との関係 特許出願人
氏名（名称） 大同マルタ染工株式会社４、代理人 〒
６０４
住所 京都市中京区御幸町道三条上る丸屋町３３０番地
の１
氏名 弁理士（５９６３）新 実 健 部 ：゛、１ノ
５、補正の対象 明細書、発明の詳細な説明の欄６、補
正の内容
＋１１ 明細書、第３頁下からｌＯ〜５行目、「セル
ロース系・・・或いは」とあるを［Ｉ）セルロース系繊
維布帛に、カチオン化剤を浸漬法又はパッド法により、
全面に付着させ、アニオン理した糸と交織し、或いはカ
チオン化処理した繊維と未処理の繊維又はアニオン化処
理した繊維の混紡し、該混紡糸を編織した後、得られた
布帛を染色して霜降り効果や染分は効果を得る、又は１
社）」と補正する。Patent Applicant: Daido Maruta Dyeing Co., Ltd. Agent: Takeshi Arata 1 outsider Procedural Amendment 1. Display of case 1985 patent application No. 226527 2
, Title of the invention Dyeing method for cellulose fiber fabric 3, Relationship to the case of the person making the amendment Name of patent applicant (name) Daido Malta Senko Co., Ltd. 4, Agent 〒
604 Address: 330-1 Maruyama-cho, Miyuki-cho, Michi-sanjo, Kagaru, Nakagyo-ku, Kyoto-shi Name: Patent attorney (5963) Shinji Ken Department: ゛, 1-5, Subject of amendment Description, Detailed explanation of the invention column 6, Amendment Contents + 11 In the specification, page 3, lines 10 to 5 from the bottom, the words "cellulose... or" are replaced with [I) A cationizing agent is applied to a cellulose fiber fabric by a dipping method or a pad method,
After adhering to the entire surface and interweaving with anion-treated yarns, or blending cationized fibers with untreated fibers or anionized fibers, knitting and weaving the blended yarns, the resulting fabric is dyed. Marbling effects and stains will have an effect or 1
Company)”.
（２） 同書、第４頁第１０行１、「霜降り効果」と
あるを「霜降り又は染分は効果」と補正する。(2) In the same book, page 4, line 10, the phrase "marbling effect" is amended to read "marbling or dyeing is an effect."
（３） 同書、第１０頁下から９行目、「二相相」と
あるを「二相法」と補正する。(3) In the same book, page 10, line 9 from the bottom, the phrase "two-phase phase" is amended to read "two-phase method."
（４） 同書、第１２頁第１行、「確認した。」とあ
るを「確認後、乾燥した。」と補正する。(4) In the same book, page 12, line 1, the phrase "confirmed." is amended to "after confirmation, it was dried."
（５） 同書、第１３頁第２〜３行、「確認した後、
」とある後に「１１０℃で２分間乾燥し、」と加入する
。(5) Ibid., page 13, lines 2-3, “After checking,
” and then add “Dry at 110°C for 2 minutes.”
Claims (7)
理液を模様状に印捺し、乾燥、熱処理、水洗後、更に、
着色捺染糊を模様状に印捺することを特徴とするセルロ
ース系繊維布帛の染色方法。(1) A treatment solution containing a cationizing agent is printed on a cellulose fiber fabric in a pattern, and after drying, heat treatment, and water washing, further
A method for dyeing cellulose fiber fabric, which is characterized by printing colored printing paste in a pattern.
ドリン誘導体である特許請求の範囲第１項記載の方法。(2) The method according to claim 1, wherein the cationizing agent is a quaternary ammonium salt type chlorohydrin derivative.
らなる特許請求の範囲第１項又は第２項記載の方法。(3) The method according to claim 1 or 2, wherein the treatment liquid comprises a cationizing agent, an alkaline agent, and a sizing agent.
の範囲第１項〜第３項いずれか１項記載の方法。(4) The method according to any one of claims 1 to 3, wherein the printing paste contains a reactive dye or an acid dye.
使用する特許請求の範囲第４項記載の方法。(5) The method according to claim 4, which uses a reactive dye printing paste that does not contain alkali or urea.
用する特許請求の範囲第４項記載の方法。(6) The method according to claim 4, which uses a reactive dye printing paste containing alkali and urea.
ルカリ、尿素を含有しない反応性染料捺染糊を共に使用
する特許請求の範囲第４項記載の方法。(7) The method according to claim 4, wherein a reactive dye printing paste containing alkali and urea and a reactive dye printing paste not containing alkali and urea are used together.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61226527A JPH0737713B2 (en) | 1986-09-24 | 1986-09-24 | Dyeing method for cellulose fiber cloth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61226527A JPH0737713B2 (en) | 1986-09-24 | 1986-09-24 | Dyeing method for cellulose fiber cloth |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6385186A true JPS6385186A (en) | 1988-04-15 |
| JPH0737713B2 JPH0737713B2 (en) | 1995-04-26 |
Family
ID=16846527
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61226527A Expired - Lifetime JPH0737713B2 (en) | 1986-09-24 | 1986-09-24 | Dyeing method for cellulose fiber cloth |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0737713B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06207383A (en) * | 1993-01-08 | 1994-07-26 | Kanebo Ltd | Multicolor printed fabric and its production |
| JP2005264370A (en) * | 2004-03-18 | 2005-09-29 | Fuji Spinning Co Ltd | Method for modifying and printing fabric |
| JP2005273108A (en) * | 2004-03-26 | 2005-10-06 | Fuji Spinning Co Ltd | Method for printing cellulosic fiber cloth |
| JP2006265783A (en) * | 2005-03-24 | 2006-10-05 | Nicca Chemical Co Ltd | Method for making it possible to dye non-dyeable yarn with dye used for nylon yarn or wool |
| CN102134806A (en) * | 2011-04-27 | 2011-07-27 | 广州湘中纺织助剂有限公司 | Salt-free rolling, baking, dying and low-temperature soaping method for fiber reactive dyes |
-
1986
- 1986-09-24 JP JP61226527A patent/JPH0737713B2/en not_active Expired - Lifetime
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06207383A (en) * | 1993-01-08 | 1994-07-26 | Kanebo Ltd | Multicolor printed fabric and its production |
| JP2005264370A (en) * | 2004-03-18 | 2005-09-29 | Fuji Spinning Co Ltd | Method for modifying and printing fabric |
| JP2005273108A (en) * | 2004-03-26 | 2005-10-06 | Fuji Spinning Co Ltd | Method for printing cellulosic fiber cloth |
| JP2006265783A (en) * | 2005-03-24 | 2006-10-05 | Nicca Chemical Co Ltd | Method for making it possible to dye non-dyeable yarn with dye used for nylon yarn or wool |
| CN102134806A (en) * | 2011-04-27 | 2011-07-27 | 广州湘中纺织助剂有限公司 | Salt-free rolling, baking, dying and low-temperature soaping method for fiber reactive dyes |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0737713B2 (en) | 1995-04-26 |
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